Method of Forming a Shaped Article

Abstract

A method of forming shaped articles by welding.

Claims

1. A method of forming a shaped article wherein said article comprises at least two parts which are chemically bonded, the method comprising: assembling at least two non-chemically bonded parts in a cavity of a tool to form an assembly of the at least two parts, wherein said cavity is adapted to receive the assembly of at least two parts in the form of the shaped article; sealing the cavity of the tool; melting the assembly of at least two parts to chemically bond the at least two parts together to form the shaped article.

2. The method according to claim 1, wherein the shaped article is cooled following chemical bonding of the least two parts.

3. The method according to claim 1, wherein the cavity is shaped to match the outer surface profile of the assembly of the at least two parts.

4. The method according to claim 1, wherein the cavity is scaled to be larger in volume compared with the assembly of the at least two parts at about 20° C.

5. The method according to claim 1, wherein the cavity is scaled to be larger in volume compared with the assembly of the at least two parts at 20° C. by about 0.5-6 vol %.

6. The method according to claim 1, wherein the at least two non-chemically bonded parts are assembled to form an interface between the at least two non-chemically bonded parts and following melting the chemical bond is formed across the entire interface.

7. The method according to claim 1, wherein pressure is exerted on the at least two parts by the tool cavity during formation of the chemically bonded shaped article.

8. The method according to claim 1, wherein the tool is provided in more than one part to enable access to the cavity and for the at least two non-chemically bonded parts to be assembled in the cavity and removed therefrom following formation of the chemically bonded shaped article.

9. The method according to claim 1, wherein the at least two chemically bonded parts each possess different material properties for example any one or more of different permittivity properties, density, magnetic permeability, conductivity, antimicrobial, catalytic, modulus or colour.

10. The method according to claim 1, wherein the at least two parts are thermoplastic.

11. The method according to claim 1, wherein the at least two parts are polymer which may comprise a filler material.

12. The method according to claim 11, wherein the polymer is selected from one or more or any combination of polyethylene (PE), polypropylene (PP), Acrylonitrile Butadiene Styrene (ABS), Polyoxymethylene (POM), Poly(methyl methacrylate) (PMMA), Cyclic Olefin Copolymer (COC), Cyclic Olefin Polymer (COP), Ethylene Methacrylate (EMA), Ethylene tetrafluoroethylene (ETFE), Ethylene-vinyl acetate (EVA), Fluorinated ethylene propylene (FEP), Polycarbonate (PC), Liquid Crystal Polymer (LCP), Polyamide (PA), Polyaryletherketone (PAEK), polyamide-imide (PAI), Polybutylene succinate (PBS), Polybutylene terephthalate (PBT), Polyethylene terephthalate (PET), Polyether ether ketone (PEEK), Polyethylenimine (PEI), Polyetherketone (PEK), Polyethylene naphthalate (PEN), Polysulphone (PSU), Polyimide (PI), Poly(lactic acid) (PLA), polymethylpentene (PMP), Polyphenylene Ether (PPE), Polyphenylene sulphide (PPS), Polystyrene (PS), Polyvinyl chloride (PVC), Polyvinylidene fluoride (PVDF), Styrene acrylonitrile (SAN), or Thermoplastic polyurethane (TPU).

13. The method according to claim 11, wherein the polymer is selected from polyethylene and the polyethylene is selected from LDPE, or MDPE, or LLDPE or HDPE.

14. The method according to claim 11, wherein the amount of filler is 0.5 vol % to 60 vol % based on the volume of the filled polymer.

15. The method according to claim 11, wherein the at least two parts are in the form of layers.

16. The method according to claim 1, wherein at least one of the at least two parts possesses a doubly curved surface or an irregular shape.

17. The method according to claim 1, wherein the shaped article is a functional component.

18. The method according to claim 1, wherein the shaped article is selected from a radome, RF lens, Luneburg lens, retro-reflector, RF waveguide, RF filter, RF resonator, metamaterial structure, refraction structure, diffraction structure, scattering structure or forms a part thereof.

19. The method according to claim 1, wherein the shaped article is selected from an electronic or electromechanical sensor, actuator, solenoid, motor, acoustic sound dampening cladding and mounts, multi-material enclosure, power tool component, pharmaceutical components such as prosthetics, implants, drug delivery systems, applicators, catheters, or forms a part thereof.

20. The method according to claim 1, wherein the shaped article is an optical lens or an RF frequency lens.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0031] This and other aspects of the present invention will now be described in more detail, with reference to the appended drawing(s) showing embodiments(s) of the invention.

[0032] FIGS. 1a and 1b show the centre cross section of a tool for use in accordance with the present invention suitable for carrying out the method of forming a shaped article.

[0033] FIG. 2 shows an example of an assembly of parts in cross-section and an orthographic projection of the corresponding tool design in accordance with the present invention.

[0034] FIG. 3 shows an example of an assembly of parts in cross-section and an orthographic projection of the corresponding tool design in accordance with the present invention. The assembly of parts comprises an undercut and the corresponding modifications to the tool design are highlighted.

DETAILED DESCRIPTION OF THE INVENTION

[0035] The present invention will now be described more fully hereinafter with reference to the accompanying drawings, in which currently preferred embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided for thoroughness and completeness, and fully convey the scope of the invention to the skilled person. Like reference numerals in the drawings refer to like elements throughout.

[0036] Though the present application may tend to focus on the construction of multi-layered (RF) lens structures it will be appreciated that the techniques described herein are applicable to any multi-layered/multi-part assembly comprising (thermoplastic) parts and particularly complex shaped articles which would be difficult to manufacture by alternative means.

[0037] The methods in accordance with the present invention may be suitable for use in a broad range of applications including making: electronic or electromechanical sensors, actuators, solenoids, motors, acoustic sound dampening claddings and mounts, multi-material enclosures, power tool components and pharmaceutical components such as prosthetics, implants, drug delivery systems, applicators and catheters.

[0038] The methods in accordance with the present invention may be suitable for use in RF applications such as making: RF lenses (e.g. a Luneburg lens), retro-reflectors, RF waveguides, RF filters, RF resonators, metamaterial structures, refraction structures, diffraction structures, or scattering structures.

[0039] The tool for use in accordance with the present invention may be subjected to certain design parameters for controlling the balance of conditions within the tool cavity. The tool typically provides a sealed pressurised environment. Pressure serves to eliminate or reduce any gaps between parts in the assembly and hence the shaped article which is formed in accordance with the present invention, resulting from geometrical tolerances of the manufacturing process from which the parts were made, and to provide sufficient bond pressure to bring the parts into intimate contact and provide high strength chemical bonds. Preferably, material flow is reduced or even more preferably eliminated to preserve the geometry of the parts being welded and to control the geometry of the interfaces in the final shaped article which may be referred to herein as the welded assembly which is, after the welding process, one single object which can no longer be separated into its constituent parts. The assembly of non bonded parts before the welding process is performed is referred to herein as the assembly of parts.

[0040] The present inventors have found that optimum results may be achieved by using a welding temperature which is within ±5° C. of the melting temperature of the at least two parts. If parts are used of different materials (e.g. different polymers), then the melting point of the material possessing the highest melting point is used as the welding temperature (or a higher temperature). The temperature may be minimised to minimise expansion but should be high enough to adequately soften the parts to allow part interfaces to move together in an interference fit and, for the case when polymers are used, polymer chains to form the required chemical bond.

[0041] At the optimum weld temperature, the tool cavity may be scaled (typically uniformly in x, y and z directions) so as to be larger in volume than the room temperature volume of the assembly of parts. This is to prevent excessive pressure and leakage out of the cavity but also allows for the shaped article to be easily inserted into the tool cavity before welding and to shrink back from the cavity wall during cooling and re-solidification, releasing the shaped article cleanly from the walls of the cavity (eliminating flash contamination on the surface of the tool which would need to be cleaned before subsequent welding of another part) and allowing for easy removal of the welded assembly. Scaling ratios by a volume of about 0.5-6% are preferred, more preferably about 0.5-3%, even more preferably about 1-2%. These scaling ratios are suitable for use with parts made from Low Density Polyethylene (LDPE), Medium Density Polyethylene (MDPE), Linear Low Density Polyethylene (LLDPE), High Density Polyethylene (HDPE) and Polypropylene (PP). The optimum ratio may depend on the thermal expansion of the constituent parts (e.g. polymer), volume % loading of filler, thermal expansion of the filler material and the geometry of the part(s), the thermal expansion coefficient of the tool materials and the welding temperature (range).

[0042] The volume of the parts can be readily calculated from measurement of the part masses if the density of the materials used to make the parts (e.g. polymers) is known. The expansion rate of the materials may be measured using techniques such as thermal mechanical analysis.

[0043] When the welded assembly (i.e. the shaped article) is to be cooled, typically the outer surface temperature of the welded assembly will drop below the glass transition temperature, below the heat deflection temperature, or below the Vicat softening temperature before the welded assembly can be removed. To some extent this will be dependent on the nature of the (polymer) materials and the geometry of the welded assembly (or shaped article).

[0044] The heating time may be reduced by the use of any of inductive tool heating, contacting opposite surfaces (e.g. top and bottom) of the tool to heated elements, e.g. platens, heating the tool to a temperature higher than the weld temperature which will increase the rate of heat flow, or by using fluid channels within the tooling to allow for the use of Rapid Temperature Control (RTC) tooling (which typically uses circulating fluid, or pressurised steam to quickly heat and cool the tool), or by inserting pre-heated parts into pre-heated tools.

[0045] Welding time can be considered to be instantaneous once the heat has been conducted through the entire volume of the assembly of parts via the surface of the tool cavity through to the centre of the assembly of parts, such that the entire volume of the assembly of parts is at or above the required weld temperature. In reality, the welding process takes a finite time but this time is so much smaller than the required time for heat conduction so as to be considered instantaneous.

[0046] Reduced cooling time can be achieved by moving the tool to a refrigerated environment once the weld cycle is complete, immersing the tool in a cooling fluid, or via the use of RTC tooling. RTC tooling can significantly decrease cycle time at the expense of the energy required to provide the rapid changes in temperature.

[0047] Both the heating and cooling time can be reduced by designing the shaped article with a (central) cored hole through which a metal pin protruding from the tool cavity can be inserted during assembly of the tool and arranging the assembled parts. As the thermal conductivity of metals is significantly higher than that of polymers, this allows heat flow in from the centre of the assembly as well as the circumference and effectively reduces the distance over which the heat flows through a low thermal conductivity polymer.

[0048] To reduce manufacturing cost and facilitate the method being scalable to high volume manufacture (with, for example, many assemblies per minute being welded) then robotic assembly/disassembly of parts and tools may be used. Advantageously, the tool design concepts described herein are amenable to robotic manipulation. Conveyorised continuous ovens or paternoster ovens or RTC cooling may be used to allow high throughput. The method in accordance with the present invention is suitable for use in preparing shaped articles of any architecture and/or geometry.

[0049] A paternoster oven provides advantages in that each shelf can be designed with an integral clamping mechanism to provide tool closure forces for a stack of one or more tools. This oven may have a heating phase during raising of the stack of tools, followed by a cooling phase during the descent of the stack of tools.

[0050] The method in accordance with the present invention has a number of advantages in connection with the assembly of multi-part, complex shaped articles. All voids from mis-matched part tolerances are eliminated or reduced during the welding process, meaning part tolerances can be relaxed, thus further reducing manufacturing costs. The method is insensitive to the number of parts and the architecture of the assembly or shaped article. This means equipment and factory lines do not need to specialise on one single product design (as is the case for example with multi-shot moulding and to a lesser extent other polymer welding techniques). This is helpful to reduce capital expenditure for multiple product lines or new product launches. Geometrical tolerances are also well controlled.

[0051] The method in accordance with the present invention is applicable to any assembly of thermoplastic parts in a range of industries where conventional polymer welding techniques, over-moulding, multi-shot moulding, or chemical adhesive bonding is found to have limitations. In particular, the method is well suited to thick assemblies, or assemblies of many parts which would otherwise require many assembly steps and multiple pieces of bespoke equipment and tooling. Another advantage of the present invention for thick assemblies is that the slow cooling rate, inherent in the process, leads to thorough annealing and growth of crystallites (in semi-crystalline polymers), giving rise to a reduction in residual stress and potential for changes in geometry and warpage in high service temperature environments.

[0052] The method in accordance with the present invention is well suited for use with functional polymer parts, which might be heavily loaded with any one or more of a range of filler materials including those which provide one or more of the following functions: dielectric, magnetic, conductive, antimicrobial, catalytic, high/low density as required, antimicrobial, catalytic, high/low modulus as required, or colour. Such heavily filled polymers would be difficult to weld using conventional polymer welding techniques.

[0053] The method in accordance with the present invention is also well suited for preparing complex, irregular and/or doubly curved shapes of varying section thickness which can be difficult to weld using conventional welding techniques. The shaped articles formed in accordance with the method of the invention may be suitable for use in a broad range of applications including in making: electronic or electromechanical sensors, actuators, solenoids, motors, acoustic sound dampening claddings and mounts, multi-material enclosures, power tool components and pharmaceutical components such as prosthetics, implants, drug delivery systems, applicators and catheters.

[0054] The methods in accordance with the present invention may be suitable for use in RF applications such as making: RF lenses (e.g. a Luneburg lens), retro-reflectors, RF waveguides, RF filters, RF resonators, metamaterial structures, refraction structures, diffraction structures, or scattering structures.

[0055] The tool for use in connection with the method of the present invention is preferably constructed of two parts with a split line to allow for opening and insertion of constituent parts and removal from the cavity of the shaped article. The split line may be in a form so it does not act as a leak path for molten material from the assembly of parts out of the tool cavity. A parallel faced butt joint may be used to eliminate leakage. The tool for use in connection with the method of the present invention may be constructed of more than two parts.

[0056] The two tool parts or halves (which may be designated as core and cavity) may be inserted in a press (e.g. a platen press) to provide the clamping force to maintain closure of the tool during welding. The present inventors have found that clamping forces of about 20 tonnes are adequate for a shaped article with an assembly area parallel to the plane of the split line of approximately 30 cm.sup.2. The platens of the press can furthermore be heated (by electric elements or oil for example) to provide the tool heating required to bring the parts of the weld assembly up to the required temperature. Threaded bolts or bayonet fittings (which may be alternated) can be incorporated into the tool design to maintain the required closure force during the weld cycle. This has the advantage that the tools may be mobile and can be moved through a heat source such as a conveyorised oven. By way of example, M8 bolts (e.g. 8 in total) provide sufficient closure force for tool sizes up to about 150 mm diameter.

[0057] Another and preferred approach to seal the tool split line is to extend the bore of the cavity part of the tool. The core part of the tool may then form a piston which fits into the extended bore (for example an overlap of about 25 mm has been found to be adequate.) The material of the core/piston part of the tool is preferably chosen to have a higher thermal expansion than the material of the cavity/bore part of the tool. Preferably, aluminium is used for the piston/core and steel for the cavity/bore. At the weld temperature, the piston thus expands to close the gap between the two tool parts (or halves) and provides an interference seal which has been found to resist leakage from exceptionally high internal cavity pressures. The softer material of the core and cavity parts may be surface treated to ensure its surface hardness is similar to the harder material to prevent wear and damage to the piston/bore and extend the life of the tool. For example, aluminium pistons may be hard anodized. By using different materials, increased cavity pressures are obtainable resulting in improved bond strengths. Thermal expansion forces from the assembly of parts (which can act to open the tool) are easier to resist with this tool design. A simpler bayonet design or fewer bolts may be required as the cavity pressure does not apply directly against the tool closure forces.

[0058] FIGS. 1a and 1b are schematic (cross-sectional) representations of a tool suitable for use in carrying out the method of forming a shaped article in accordance with the present invention. The tool represented generally in FIG. 1a at (1), comprises a first part indicated generally at (5) and a second part indicated generally at (10). The tool is shown in an open position in FIG. 1(b) and is essentially made from the two main parts (5, 10). In FIG. 1(a) a cavity is depicted at (15) formed by the two parts (5), (10) being brought together. In order to form the shaped article, at least two parts, e.g. filled thermoplastic polymer (not shown) are arranged in the cavity (15). The two parts of the cavity when the tool is an open position are indicated at (15a) and (15b). The at least two parts of the shaped article may be assembed in (15a) and/or (15b). In the embodiments depicted in FIGS. 1a and 1b, the tool is split to essentially form a core part and a piston part. The areas (25) may be made from material possessing a higher thermal expansion such as aluminium and the areas (28) may be made from a material possessing a lower thermal expansion such as steel. When the two main parts (5,10) are brought together in a heated environment a sealing face is formed between them indicated at (30, 30′), facilitated by the expansion of the material possessing a higher thermal expansion (25).

[0059] FIG. 2 shows an example of an assembly of parts in cross-section and an orthographic projection corresponding tool design in accordance with the present invention. In FIG. 2, a plan view of a tool design is shown generally at (50) and indicating the Section cuts at A-A and B-B. In Sections A-A and B-B indicated generally at (60) and (55) respectively, a cavity is depicted at (65). An assembly of parts is indicated generally at (70) which comprises a number of parts or layers. The assembly of parts indicated at (70) does not possess an undercut. The tool is essentially made from two parts (67, 68). The tool part (68) is preferably made from aluminium and the tool part, i.e. the bore (67) from steel. The tool part (68) forms a piston which slides inside the bore (67) and, owing to the higher thermal expansion of aluminium, forms an interference fit at faces (75) and (75′) which provides a seal to contain the assembly of parts (70) inside the resulting cavity (65).

[0060] FIG. 3 shows an example of an assembly of parts in cross-section and an orthographic projection corresponding tool design in accordance with the present invention. In FIG. 3, a plan view of a tool design is shown generally at (80) and indicating the Section cuts at A-A and B-B. In Sections A-A and B-B indicated generally at (85) and (90) respectively, a cavity is depicted at (93) and (95) respectively. An assembly of parts is indicated generally at (100) which comprises a number of parts or layers. The assembly of parts indicated at (100) possesses an undercut. The tool is essentially made from two parts (91, 92). The tool part (92) is preferably made from aluminium and the tool part (91) from steel. Feature (92) forms a piston which slides inside the feature (91) which forms a bore and, owing to the higher thermal expansion of aluminium, forms an interference fit at faces (105) and (105′) which provides a seal to contain the assembly of parts (100) inside the resulting cavity (93) and (95). The part is oriented such that the undercut in shape is aligned to the axis in which the piston (92) is moved in to the bore (91). Thus the tool can be disassembled with one axial motion and is amendable to automation by robot for example for an undercut geometry.

Examples

[0061] The part assembly geometry shown in FIG. 3 (100) was welded using the tool geometry shown in FIG. 3. The parts were constructed from compounds of LLDPE (Exxon Mobil LL6101) strontium titanate (Thermograde SrTiO.sub.3 Grade E) varying from 18.6% to 1.7% by volume between different parts of the assembly. Compounds of alternate parts in the assembly structure were dyed using a small amount of chrome oxide colourant to provide optical contrast for post welding inspection and injection moulded on a Travin TP1 injection moulding press as separate parts prior to assembly. The parts were assembled and positioned in the tool cavity shown of tool half (92) by hand. The bore of tool half (91) was then positioned over the piston of tool half (92) and 8 M8 bolts tightened with a torque wrench to a torque value of 23 N/m to secure the two tool halves together. The tool assembly was then placed in a fan assisted box oven at a temperature of 130° C. for 4.5 hours. The assembly was removed from the oven after this time and allowed to cool in air for 60 minutes before being disassembled. Upon removal of tool half (91) from tool half (92), the welded assembly was revealed and all parts were found to be fully bonded to one another but not to the cavity surfaces, from which they had shrunk back from during cooling. Measurement of the diameter of the welded assembly at different angles showed the shaped article was concentric within a tolerance of +/−50 μm. The welded assembly was cut in half using a woodworking band saw and polished to the half diameter plane using a woodworking sanding wheel. The polished surface was then inspected using an optical scanner and the cross section geometry of the assembly laid over this image using CorelDraw 2D drawing software. The geometry was found to be within +/−200 microns of the nominal assembly geometry at all interfaces and the discrepancies seen were attributable to tolerance in the assembled moulded parts at the injection moulding stage due to polymer shrinkage.

[0062] The person skilled in the art realizes that the present invention is by no means limited to the preferred embodiments described above. On the contrary, many modifications and variations are possible within the scope of the appended claims.

[0063] Additionally, variations to the disclosed embodiments can be understood and effectuated by the skilled person in practicing the claimed invention, from a study of the drawings, the disclosure, and the appended claims. In the claims, the word “comprising” does not exclude other elements or steps, and the indefinite article “a” or “an” does not exclude a plurality. The mere fact that certain features are recited in mutually different dependent claims does not indicate that a combination of these features cannot be used to advantage.