POWDER COATING HAVING ULTRA-HIGH WEATHER-RESISTANT AND MATTING EFFECTS

Abstract

A powder coating having ultra-high weather-resistant and matting effects includes a first powder coating component A and a second powder coating component B which are dry-mixed into a whole and have different curing speeds. The raw materials of the first powder coating component A include a first polyester resin and a curing agent capable of undergoing a curing reaction with the first polyester resin; raw materials of the second powder coating component B include a second polyester resin and an acrylic resin containing epoxy groups, and the acrylic resin is capable of undergoing a curing reaction with the second polyester resin; an acid value of the first polyester resin is not less than 15, and an acid value of the second polyester resin is not less than 15.

Claims

1. A powder coating having ultra-high weather-resistant and matting effects, comprising a first powder coating component A and a second powder coating component B which are dry-mixed into a whole and have different curing speeds, wherein raw materials of the first powder coating component A comprise a first polyester resin and a curing agent capable of undergoing a curing reaction with the first polyester resin; raw materials of the second powder coating component B comprise a second polyester resin and an acrylic resin containing epoxy groups, and the acrylic resin is capable of undergoing a curing reaction with the second polyester resin; an acid value of the first polyester resin is not less than 15, and an acid value of the second polyester resin is not less than 15.

2. The powder coating of claim 1, wherein the acid value of the first polyester resin is not less than 25, and/or the acid value of the second polyester resin is not less than 25.

3. The powder coating of claim 1, wherein a difference between the acid value of the first polyester resin and the acid value of the second polyester resin is not less than 10.

4. The powder coating of claim 1, wherein the raw materials of the second powder coating component B further comprise a third polyester resin capable of undergoing a curing reaction with the acrylic resin, and an acid value of the third polyester resin is less than that of the second polyester resin.

5. The powder coating of claim 4, wherein the raw materials of the second powder coating component B further comprise a curing agent capable of undergoing a curing reaction with the second polyester resin and/or the third polyester resin.

6. The powder coating of claim 1, wherein an acid value range of the first polyester resin is 45-80, and/or an acid value range of the second polyester resin is 45-80, and/or an epoxy equivalent range of the acrylic resin is 400-700.

7. The powder coating of claim 1, wherein a viscosity of the first polyester resin and/or the second polyester resin at 200° C. is not greater than 3000 Pas.

8. The powder coating of claim 1, wherein a viscosity of the first polyester resin and/or the second polyester resin at 200° C. falls within the range of 1500-2500 Pas.

9. The powder coating of claim 1, wherein the first polyester resin is the same as the second polyester resin.

10. The powder coating of claim 1, wherein a ratio of weight parts of the first powder coating component A to weight parts of the second powder coating component B is between 0.2:1 and 5:1.

11. The powder coating of claim 1, wherein the first polyester resin accounts for no less than 40 wt. % of the first powder coating component A, and the curing agent accounts for no less than 2 wt. % of the first powder coating component A.

12. The powder coating of claim 1, wherein the second polyester resin accounts for no less than 40 wt. % of the second powder coating component B, and weight parts of the acrylic resin are less than those of the second polyester resin.

13. The powder coating of claim 1, wherein the acrylic resin accounts for no less than 40 wt. % of the second powder coating component B, and weight parts of the second polyester resin are less than those of the acrylic resin.

Description

DETAILED DESCRIPTION

[0027] An embodiment of the disclosure provides a powder coating having ultra-high weather-resistant and matting effects, comprising a first powder coating component A and a second powder coating component B which are dry-mixed into a whole and have different curing speeds. Raw materials of the first powder coating component A comprise a first polyester resin and a curing agent capable of undergoing a curing reaction with the first polyester resin. Raw materials of the second powder coating component B comprise a second polyester resin and an acrylic resin containing epoxy groups, and the acrylic resin is capable of undergoing a curing reaction with the second polyester resin. An acid value of the first polyester resin is not less than 15, and an acid value of the second polyester resin is not less than 15.

[0028] In this embodiment, the first powder coating component A and the second powder coating component B which are dry-mixed are provided. A polyester curing system with an acid value not less than 15 is specifically used as the first powder coating component A to implement high weather resistance, and a polyester and acrylic resin curing system with an acid value not less than 15 is specifically used as the second powder coating component B to implement high weather resistance. Importantly, after the dry-mixed first powder coating component A and second powder coating component B are cured to form the coating, because curing reaction speeds of the first powder coating component A and the second powder coating component B are different and the polyester resin is incompatible with the acrylic resin, a fine smooth surface of the cured coating can be ensured, and the matte coating product with gloss not greater than 10° can be obtained. In addition, it is verified through practice that the sprayed and cured coating in this embodiment has excellent ultra-high weather-resistant effects. Specifically, after a xenon lamp test for 1500 hours, the gloss retention of the coating remains at 90% or above, which is a technical effect that a matte weather-resistant powder product in the existing technologies cannot achieve.

[0029] Optionally, the acid value of the first polyester resin and/or the acid value of the second polyester resin are/is not less than 25. Preferably, the acid value of the first polyester resin and/or the acid value of the second polyester resin are/is not less than 30. Further preferably, the acid value of the first polyester resin and/or the acid value of the second polyester resin are/is not less than 40. In this implementation, the acid value range of the first polyester resin is 45-80, and/or the acid value range of the second polyester resin is 45-80, and/or an epoxy equivalent range of the acrylic resin is 400-700. It is verified through test that when this application is implemented, a polyester resin with a larger acid value and an acrylic resin with a lower epoxy equivalent can bring more excellent, stable and reliable weather-resistant effects. In addition, the matting effects finally achieved by the powder coating in this embodiment can be further flexibly adjusted.

[0030] In this embodiment, the following preference for a ratio of weight parts of raw materials are further provided. The curing speed can be effectively adjusted by using the preference for the ratio of weight parts of raw materials, and the matting effects finally achieved by the powder coating in this embodiment are achieved through further adjustment, comprising the following:

[0031] In a class of this embodiment, a ratio of weight parts of the first powder coating component A to weight parts of the second powder coating component B is between 0.2:1 and 5:1. Further preferably, in this implementation, the first polyester resin accounts for no less than 40 wt. % of the first powder coating component A, and the curing agent accounts for no less than 2 wt. % of the first powder coating component A.

[0032] In a class of this embodiment, in an implementation of this application, the second polyester resin accounts for no less than 40 wt. % of the second powder coating component B, the acrylic resin accounts for no more than 45 wt. % of the second powder coating component B, and weight parts of the acrylic resin are less than those of the second polyester resin. This implementation has lower raw material costs and excellent matting effects.

[0033] In a class of this embodiment, in another implementation of this application, the acrylic resin accounts for no less than 40 wt. % of the second powder coating component B, and weight parts of the second polyester resin are less than those of the acrylic resin. This implementation has more excellent weather-resistant effects, but has higher raw material costs.

[0034] In a class of this embodiment, when this application is implemented, viscosity of the first polyester resin and/or the second polyester resin at 200° C. is not greater than 3000 Pas, and viscosity of the first polyester resin and/or the second polyester resin at 200° C. falls within the range of 1500-2500 Pas. Preferably, the first polyester resin is the same as the second polyester resin, so that types of raw materials can be effectively reduced.

[0035] In another preferred solution, the first polyester resin is different from the second polyester resin, and a difference between an acid value of the first polyester resin and an acid value of the second polyester resin is not less than 10. Preferably, a difference between an acid value of the first polyester resin and an acid value of the second polyester resin is not less than 15. Through the design adjustment of the specific acid value difference between the first polyester resin and the second polyester resin, the difference between the curing reaction speeds of the first powder coating component A and the second powder coating component B can be further adjusted, so that matting effects are further improved.

[0036] In a class of this embodiment, the raw materials of the second powder coating component B further comprise a third polyester resin capable of undergoing a curing reaction with the acrylic resin, an acid value of the third polyester resin is less than that of the second polyester resin, and the raw materials of the second powder coating component B further comprise a curing agent capable of undergoing a curing reaction with the second polyester resin and/or the third polyester resin. In this embodiment, the third polyester resin curing system with a curing speed different from that of the second polyester resin is provided, which can further ensure stable and reliable matting effects of this embodiment.

[0037] To ensure coating effects and give consideration to mechanical properties of the coating in this embodiment, the applicant suggested that preferably, viscosity of the first polyester resin, the second polyester resin, and the third polyester resin should all fall within a low-viscosity range, and is generally suggested to be not greater than 3000 Pas, and preferably, not greater than 2500 Pas.

[0038] To specifically describe the technical effects of implementation of this application and the achieved technical effects, in this application, the following comparative implementation processes are elaborated:

[0039] Preferably, the powder coating having ultra-high weather-resistant and matting effects in this embodiment can be produced with reference to Table 1 below for the raw material parameter ratio in specific implementation:

TABLE-US-00001 TABLE 1 Weight parts of raw materials in embodiments of this application First powder Second powder coating coating Types of raw materials Specific specification component A component B First polyester Carboxyl-terminated polyester 40-80 parts / resin resin, with an acid value not less than 15 mg KOH/g, commercially available Second polyester Carboxyl-terminated polyester / 20-80 parts, the resin resin, with an acid value not less same as the first than 15 mg KOH/g, commercially polyester resin available Third polyester Carboxyl-terminated polyester /  0-25 parts resin resin, with an acid value not less than 15 mg KOH/g, commercially available Acrylic resin The epoxy equivalent range is / 10-50 parts containing epoxy 400-700 g/eq. groups Curing agent Hydroxyalkylamide curing agent,  2-20 parts  0-10 parts commercially available Leveling agent Acrylic ester, commercially  0-1 part  0-1 part available Benzoin Commercially available  0-1 part  0-1 part PE wax Commercially available  0-1 part  0-1 part Carbon black Commercially available  0-1 part  0-1 part Barium sulfate Commercially available Balance Balance

[0040] During specific implementation, the same carboxyl-terminated polyester resin may be selected as the second polyester resin and the first polyester resin to reduce types of raw materials, or different carboxyl-terminated polyester resins with an acid value difference not less than 10 may be selected. The first powder coating component A and the second powder coating component B are separately produced by using a known powder coating production process, and then the first powder coating component A and the second powder coating component B are dry-mixed at a weight part ratio of between 0.2:1 and 5:1, to obtain a powder coating having ultra-high weather-resistant and matting effects.

[0041] In this application, the following multiple embodiments and comparative examples are made separately according to the foregoing raw material ratio table to compare and verify technical effects:

Embodiment 1

[0042] A raw material formula of Embodiment 1 is shown in Table 2 below.

TABLE-US-00002 TABLE 2 Raw material formula of Embodiment 1 First powder Second powder coating coating Types of raw materials Specific specification component A component B First The resin has an acid value  60 parts / carboxyl-terminated of 40-80 mg KOH/g, and polyester resin is produced from TIGER. Second The resin has an acid value / 55 parts, the carboxyl-terminated of 40-80 mg KOH/g, and same as the first polyester resin is produced from TIGER. polyester resin Third The resin has an acid value / / carboxyl-terminated of 18-25 mg KOH/g, and polyester resin is produced from TIGER. Acrylic resin The epoxy equivalent /  15 parts containing epoxy range is 400-700 g/eq, and groups the resin is produced from Anderson. Curing agent Hydroxyalkylamide curing  15 parts / agent, commercially available Leveling agent Acrylic ester,   1 part   1 part commercially available Benzoin Commercially available 0.5 part 0.5 part Degassing agent PE wax, commercially 0.3 part 0.3 part available Carbon black Commercially available   1 part   1 part Barium sulfate Commercially available Balance Balance

[0043] Raw materials of the first powder coating component A and the second powder coating component B are prepared according to the formula of Table 2, the components are separately produced by using a known powder coating production process, and then the first powder coating component A and the second powder coating component B are dry-mixed at a weight part ratio of 1:1 to obtain a powder coating having ultra-high weather-resistant and matting effects.

Embodiment 2

[0044] A raw material formula of Embodiment 2 is shown in Table 3 below.

TABLE-US-00003 TABLE 3 Raw material formula of Embodiment 2 First powder Second powder coating coating Types of raw materials Specific specification component A component B First The resin has an acid value  50 parts / carboxyl-terminated of 40-80 mg KOH/g, and is polyester resin produced from TIGER. Second The resin has an acid value / 50 parts, the carboxyl-terminated of 40-80 mg KOH/g, and is same as the first polyester resin produced from TIGER. polyester resin Third The resin has an acid value /  10 parts carboxyl-terminated of 18-25 mg KOH/g, and is polyester resin produced from TIGER. Acrylic resin containing The epoxy equivalent range /  10 parts epoxy groups is 400-700 g/eq, and the resin is produced from Anderson. Curing agent Hydroxyalkylamide curing  20 parts   5 parts agent, commercially available Leveling agent Acrylic ester, commercially   1 part   1 part available Benzoin Commercially available 0.5 part 0.5 part Degassing agent PE wax, commercially 0.3 part 0.3 part available Carbon black Commercially available   1 part   1 part Barium sulfate Commercially available Balance Balance

[0045] Raw materials of the first powder coating component A and the second powder coating component B are prepared according to the formula of Table 3, the components are separately produced by using a known powder coating production process, and then the first powder coating component A and the second powder coating component B are dry-mixed at a weight part ratio of 0.5:1 to obtain a powder coating having ultra-high weather-resistant and matting effects.

Embodiment 3

[0046] A raw material formula of Embodiment 3 is shown in Table 4 below.

TABLE-US-00004 TABLE 4 Raw material formula of Embodiment 3 First powder Second powder coating coating Types of raw materials Specific specification component A component B First The resin has an acid value  40 parts / carboxyl-terminated of 40-80 mg KOH/g, and is polyester resin produced from TIGER. Second The resin has an acid value / 80 parts, the carboxyl-terminated of 40-80 mg KOH/g, and is same as the first polyester resin produced from TIGER. polyester resin Third The resin has an acid value / / carboxyl-terminated of 18-25 mg KOH/g, and is polyester resin produced from TIGER. Acrylic resin The epoxy equivalent range / 20 parts containing epoxy is 400-700 g/eq, and the groups resin is produced from Anderson. Curing agent Hydroxyalkylamide curing  10 parts / agent, commercially available Leveling agent Acrylic ester, commercially   1 part / available Benzoin Commercially available 0.5 part / Degassing agent PE wax, commercially 0.3 part / available Carbon black Commercially available   1 part / Barium sulfate Commercially available Balance /

[0047] Raw materials of the first powder coating component A and the second powder coating component B are prepared according to the formula of Table 4, the components are separately produced by using a known powder coating production process, and then the first powder coating component A and the second powder coating component B are dry-mixed at a weight part ratio of 2:1 to obtain a powder coating having ultra-high weather-resistant and matting effects.

Embodiment 4

[0048] A raw material formula of Embodiment 4 is shown in Table 5 below.

TABLE-US-00005 TABLE 5 Raw material formula of Embodiment 4 First powder Second powder coating coating Types of raw materials Specific specification component A component B First The resin has an acid  70 parts / carboxyl-terminated value of 40-80 mg polyester resin KOH/g, and is produced from TIGER. Second The resin has an acid / 40 parts, the carboxyl-terminated value of 40-80 mg same as the first polyester resin KOH/g, and is produced polyester resin from TIGER. Third The resin has an acid /  15 parts carboxyl-terminated value of 18-25 mg polyester resin KOH/g, and is produced from TIGER. Acrylic resin The epoxy equivalent /  20 parts containing epoxy range is 400-700 g/eq, groups and the resin is produced from Anderson. Curing agent Hydroxyalkylamide  18 parts   8 parts curing agent, commercially available Leveling agent Acrylic ester,   1 part   1 part commercially available Benzoin Commercially available 0.5 part 0.5 part Degassing agent PE wax, commercially 0.3 part 0.3 part available Carbon black Commercially available   1 part   1 part Barium sulfate Commercially available Balance Balance

[0049] Raw materials of the first powder coating component A and the second powder coating component B are prepared according to the formula of Table 5, the components are separately produced by using a known powder coating production process, and then the first powder coating component A and the second powder coating component B are dry-mixed at a weight part ratio of 0.2:1 to obtain a powder coating having ultra-high weather-resistant and matting effects.

Embodiment 5

[0050] A raw material formula of Embodiment 5 is shown in Table 6 below.

TABLE-US-00006 TABLE 6 Raw material formula of Embodiment 5 First powder Second powder coating coating Types of raw materials Specific specification component A component B First The resin has an acid value 80 parts / carboxyl-terminated of 40-80 mg KOH/g, and is polyester resin produced from TIGER. Second The resin has an acid value / 80 parts; the resin is carboxyl-terminated of 40-80 mg KOH/g, and is different from the polyester resin produced from TIGER. first polyester resin, and the difference between the acid value of the resin and the acid value of the first polyester resin is not less than 10. Third The resin has an acid value / / carboxyl-terminated of 18-25 mg KOH/g, and is polyester resin produced from TIGER. Acrylic resin The epoxy equivalent range /  15 parts containing epoxy is 400-700 g/eq, and the groups resin is produced from Anderson. Curing agent Hydroxyalkylamide curing 20 parts / agent, commercially available Leveling agent Acrylic ester, commercially /   1 part available Benzoin Commercially available / 0.5 part Degassing agent PE wax, commercially / 0.3 part available Carbon black Commercially available /   1 part Barium sulfate Commercially available / Balance

[0051] Raw materials of the first powder coating component A and the second powder coating component B are prepared according to the formula of Table 6, the components are separately produced by using a known powder coating production process, and then the first powder coating component A and the second powder coating component B are dry-mixed at a weight part ratio of 0.8:1 to obtain a powder coating having ultra-high weather-resistant and matting effects.

Embodiment 6

[0052] A raw material formula of Embodiment 6 is shown in Table 7 below.

TABLE-US-00007 TABLE 7 Raw material formula of Embodiment 6 First powder Second powder coating coating Types of raw materials Specific specification component A component B First The resin has an acid value of 80 parts / carboxyl-terminated 30-40 mg KOH/g, and is polyester resin produced from TIGER. Second The resin has an acid value of /  80 parts carboxyl-terminated 40-80 mg KOH/g, and is polyester resin produced from TIGER. Third The resin has an acid value of / / carboxyl-terminated 18-25 mg KOH/g, and is polyester resin produced from TIGER. Acrylic resin The epoxy equivalent range is /  15 parts containing epoxy 400-700 g/eq, and the resin is groups produced from Anderson. Curing agent Hydroxyalkylamide curing agent, 20 parts / commercially available Leveling agent Acrylic ester, commercially /   1 part available Benzoin Commercially available / 0.5 part Degassing agent PE wax, commercially available / 0.3 part Carbon black Commercially available /   1 part Barium sulfate Commercially available / Balance

[0053] Raw materials of the first powder coating component A and the second powder coating component B are prepared according to the formula of Table 7, the components are separately produced by using a known powder coating production process, and then the first powder coating component A and the second powder coating component B are dry-mixed at a weight part ratio of 1:1 to obtain a powder coating having ultra-high weather-resistant and matting effects.

Embodiment 7

[0054] A raw material formula of Embodiment 7 is shown in Table 8 below.

TABLE-US-00008 TABLE 8 Raw material formula of Embodiment 7 First powder Second powder coating coating Types of raw materials Specific specification component A component B First The resin has an acid 80 parts / carboxyl-terminated value of 25-30 mg polyester resin KOH/g, and is commercially available. Second The resin has an acid /  50 parts carboxyl-terminated value of 15-25 mg polyester resin KOH/g, and is commercially available. Third The resin has an acid / / carboxyl-terminated value of 18-25 mg polyester resin KOH/g, and is produced from TIGER. Acrylic resin The epoxy equivalent /  45 parts containing epoxy range is 400-700 g/eq, groups and the resin is produced from Anderson. Curing agent Hydroxyalkylamide 20 parts / curing agent, commercially available Leveling agent Acrylic ester, /   1 part commercially available Benzoin Commercially available / 0.5 part Degassing agent PE wax, commercially / 0.3 part available Carbon black Commercially available /   1 part Barium sulfate Commercially available / Balance

[0055] Raw materials of the first powder coating component A and the second powder coating component B are prepared according to the formula of Table 8, the components are separately produced by using a known powder coating production process, and then the first powder coating component A and the second powder coating component B are dry-mixed at a weight part ratio of 3:1 to obtain a powder coating having ultra-high weather-resistant and matting effects.

Embodiment 8

[0056] A raw material formula of Embodiment 8 is shown in Table 9 below.

TABLE-US-00009 TABLE 9 Raw material formula of Embodiment 8 First powder Second powder coating coating Types of raw materials Specific specification component A component B First The resin has an acid 80 parts / carboxyl-terminated value of 15-25 mg polyester resin KOH/g, and is commercially available. Second The resin has an acid / 45 parts, the same as the carboxyl-terminated value of 15-25 mg first carboxyl-terminated poltester resin KOH/g, and is polyester resin commercially available. Third The resin has an acid /  15 parts carboxyl-terminated value of 18-25 mg polyester resin KOH/g, and is produced from TIGER. Acrylic resin The epoxy equivalent /  30 parts containing epoxy range is 400-700 g/eq, groups and the resin is produced from Anderson. Curing agent Hydroxyalkylamide 20 parts 4 parts; this curing agent curing agent, can be cured with the commercially available second carboxyl-terminated polyester resin and the third carboxyl-terminated polyester resin simultaneously. Leveling agent Acrylic ester, /   1 part commercially available Benzoin Commercially available / 0.5 part Degassing agent PE wax, commercially / 0.3 part available Carbon black Commercially available /   1 part Barium sulfate Commercially available / Balance

[0057] Raw materials of the first powder coating component A and the second powder coating component B are prepared according to the formula of Table 9, the components are separately produced by using a known powder coating production process, and then the first powder coating component A and the second powder coating component B are dry-mixed at a weight part ratio of 1:1 to obtain a powder coating having ultra-high weather-resistant and matting effects.

Embodiment 9

[0058] The implementation solution of Embodiment 9 is the same as that of Embodiment 1, except that in Embodiment 9, a first powder coating component A and a second powder coating component B are dry-mixed at a weight part ratio of 0.4:1 to obtain a powder coating having ultra-high weather-resistant and matting effects.

Embodiment 10

[0059] The implementation solution of Embodiment 10 is the same as that of Embodiment 1, except that in Embodiment 10, a first powder coating component A and a second powder coating component B are dry-mixed at a weight part ratio of 0.2:1 to obtain a powder coating having ultra-high weather-resistant and matting effects.

Embodiment 11

[0060] The implementation solution of Embodiment 11 is the same as that of Embodiment 1, except that in Embodiment 11, a first powder coating component A and a second powder coating component B are dry-mixed at a weight part ratio of 3:1 to obtain a powder coating having ultra-high weather-resistant and matting effects.

Embodiment 12

[0061] The implementation solution of Embodiment 12 is the same as that of Embodiment 1, except that in Embodiment 12, a first powder coating component A and a second powder coating component B are dry-mixed at a weight part ratio of 5:1 to obtain a powder coating having ultra-high weather-resistant and matting effects.

[0062] Certainly, in the other implementations of this embodiment, a first powder coating component A and a second powder coating component B at other weight part ratios can also be used for dry mixing, to also achieve excellent matting and ultra-high weather-resistant technical effects. These weight part ratios should not be regarded as a specific technical feature of this application, and a person skilled in the art can make specific ratio selection as actually required.

Comparative Example 1

[0063] A weather-resistant matting powder coating proposed by the patent No. CN101787239B is directly used in Comparative Example 1.

Comparative Example 2

[0064] A weather-resistant matting powder coating proposed by the patent No. CN1219006C is directly used in Comparative Example 2.

Comparative Example 3

[0065] A weather-resistant matting powder coating proposed by the patent No. CN109486373A is directly used in Comparative Example 3.

Comparative Example 4

[0066] A weather-resistant matting powder coating proposed by the patent No. CN104046214A is directly used in Comparative Example 4.

Comparative Example 5

[0067] A weather-resistant matting powder coating proposed by the patent No. CN103131308A is directly used in Comparative Example 5.

[0068] After the powder coatings in Embodiments 1-12 and the powder coatings in Comparative Examples 1-5 were electrostatically sprayed under the same conditions and completely cured, the applicant conducted comparative tests on the correspondingly obtained coatings. Test results are shown in Table 10 below.

TABLE-US-00010 TABLE 10 Comparison of technical effects between the embodiments and the comparative examples Gloss retention Appearance after resistance to (visual a xenon lamp for comparison) Gloss (60°) Impact resistance 1500 hours Embodiments Flat, fine, and 10° or below Impact-resistant for ≥90% 1-12 smooth both front and back surfaces Comparative Flat, fine, but 10° or below Impact-resistant for Less than 30% Example 1 unsmooth both front and back surfaces Comparative Flat, fine, but 10° or below Impact-resistant for Less than 30% Example 2 unsmooth both front and back surfaces Comparative Flat, fine, but 10° or below Impact-resistant for Less than 30% Example 3 unsmooth both front and back surfaces Comparative Flat, fine, but 10° or below Impact-resistant for Less than 30% Example 4 unsmooth both front and back surfaces Comparative Flat, fine, and 18-45° Impact-resistant for ≥90% Example 5 smooth both front and back surfaces

[0069] Note: In Table 10 above, the appearance is judged by visual comparison, a gloss test standard is ISO 2813-2014, an impact resistance test standard is ISO 6272-2-2011, a xenon lamp test standard is ISO 16474-2-2013, and a 60° test angle is used for a gloss test for the gloss retention.

[0070] In addition, through comparison of weather-resistant effects of Embodiments 1-12, it can be found that the gloss retentions in Embodiments 1-6 and Embodiments 9-12 can still remain at 90% or above after resistance to a xenon lamp for 2500 hours, indicating that a polyester resin with a larger acid value has higher weather resistance. Embodiments 2,4,5, and 8 can bring more excellent matting effects by designing the acid value difference and adding the third polyester resin curing system.

[0071] It is clear to a person skilled in the art that the disclosure is not limited to the details of the foregoing example embodiments, and the disclosure can be implemented in other specific forms without departing from the spirit or essential features of the disclosure. Therefore, the embodiments should be regarded in all respects as examples rather than as restrictive, and the scope of the disclosure is defined by the appended claims rather than the foregoing descriptions. Therefore, all changes falling within the meanings and scope of equivalent elements of the claims are included in the disclosure.

[0072] It will be obvious to those skilled in the art that changes and modifications may be made, and therefore, the aim in the appended claims is to cover all such changes and modifications.