EMBOSSED MULTI-PLY TISSUE PRODUCT
20220275584 · 2022-09-01
Inventors
- Tsutama Satake Neto (Mogi das Cruzes, BR)
- Jorge Alonso Duran (Sao Paulo, BR)
- Patricia Câmara Mileo (Sao Paulo, BR)
Cpc classification
B32B29/005
PERFORMING OPERATIONS; TRANSPORTING
B32B3/28
PERFORMING OPERATIONS; TRANSPORTING
B31F1/07
PERFORMING OPERATIONS; TRANSPORTING
D21H27/40
TEXTILES; PAPER
B31F2201/0782
PERFORMING OPERATIONS; TRANSPORTING
International classification
D21H27/40
TEXTILES; PAPER
B31F1/07
PERFORMING OPERATIONS; TRANSPORTING
B32B29/00
PERFORMING OPERATIONS; TRANSPORTING
B32B3/28
PERFORMING OPERATIONS; TRANSPORTING
D21H27/00
TEXTILES; PAPER
Abstract
Disclosed are multi-ply embossed tissue products having improved softness, strength, embossment clarity and/or embossment height compared to prior art embossed tissue products. The multi-ply tissue products may comprise an embossed tissue ply having a basis weight less than about 25 grams per square meter (gsm) and relatively deep embossments, such as an embossment height from about 500 to about 1,000 μm and relatively narrow bottom portions compared to top portions. The combination of these elements provides an aesthetically pleasing and well-defined embossment, while improving important tissue product properties such as sheet and roll bulk and softness.
Claims
1. A multi-ply tissue product comprising first and second tissue plies, the first ply having embossed and unembossed regions, the embossed regions comprising a plurality of first embossments arranged in an embossing pattern and defining a dome-like region there between, the unembossed region having an upper surface lying in a first tissue product surface plane and the dome-like structure having an upper surface lying in a second tissue product surface plane, wherein the second tissue product surface plane is at least 100 μm above the first tissue product surface plane.
2. The multi-ply tissue product of claim 1 further comprising a second ply having a plurality of second embossments disposed thereon, wherein at least one of the plurality of second embossments nests into the dome-like structure and is bounded by at least two spaced apart first embossments.
3. The multi-ply tissue product of claim 2 further comprising a third ply disposed between the first and second plies, wherein the third ply comprises embossments registered with the first embossments and the third ply is bonded to the first ply.
4. The multi-ply tissue product of claim 2 wherein the first embossments are discrete dot embossments, and the second embossments are discrete embossments.
5. The multi-ply tissue product of claim 1 wherein the tissue product has a geometric mean tensile (GMT) strength from about 800 to about 1,500 g/3″ and a basis weight from about 30 to about 80 grams per square meter (gsm).
6. The multi-ply tissue product of claim 1 wherein the tissue product has sheet bulk from about 7.0 to about 11 cubic centimeters per gram (cc/g).
7. The multi-ply tissue product of claim 1 wherein the tissue product is spirally wound around a core to yield a rolled tissue product having a roll bulk from about 8.0 to about 13 cc/g.
8. The multi-ply tissue product of claim 1 wherein the first embossments have a H.sub.100 from 700 to about 1,000 μm.
9. The multi-ply tissue product of claim 1 wherein the first embossments have a ratio of average width at 100% height (W.sub.100) to W.sub.25 from about 3.00 to about 4.00.
10. The multi-ply tissue product of claim 1 wherein the first embossments have a ratio of average width at 50% height (W.sub.50) to W.sub.25 is greater than about 1.40.
11. The multi-ply tissue product of claim 1 wherein the product has a basis weight less of about 60 gsm or less and a GMT less than about 1,600 g/3″ and the first dot embossments have a W.sub.50 less than about 1,000 μm and an average height at 50% (H.sub.50) greater than about 350 μm.
Description
BRIEF DESCRIPTION OF DRAWINGS
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DEFINITIONS
[0038] As used herein the term “tissue web” refers to a structure comprising a plurality of fibers such as, for example, papermaking fibers and more particularly pulp fibers, including both wood and non-wood pulp fibers, and synthetic staple fibers. A non-limiting example of a tissue web is a wet-laid sheet material comprising pulp fibers.
[0039] As used herein the term “tissue product” refers to products made from tissue webs and includes, bath tissues, facial tissues, paper towels, industrial wipers, foodservice wipers, napkins, medical pads, and other similar products. Tissue products may comprise one, two, three or more plies.
[0040] As used herein the term “layer” refers to a plurality of strata of fibers, chemical treatments, or the like, within a ply.
[0041] The term “ply” refers to a discrete product element. Individual plies may be arranged in juxtaposition to each other. The term may refer to a plurality of web-like components such as in a multi-ply facial tissue, bath tissue, paper towel, wipe, or napkin.
[0042] As used herein, the term “basis weight” generally refers to the bone dry weight per unit area of a tissue and is generally expressed as grams per square meter (gsm). Basis weight is measured using TAPPI test method T-220.
[0043] As used herein, the term “caliper” is the representative thickness of a single sheet (caliper of tissue products comprising two or more plies is the thickness of a single sheet of tissue product comprising all plies) measured in accordance with TAPPI test method T402 using an EMVECO 200-A Microgage automated micrometer (EMVECO, Inc., Newberg, Oreg.). The micrometer has an anvil diameter of 2.22 inches (56.4 mm) and an anvil pressure of 132 grams per square inch (per 6.45 square centimeters) (2.0 kPa).
[0044] As used herein, the term “sheet bulk” refers to the quotient of the caliper (μm) divided by the bone dry basis weight (gsm). The resulting sheet bulk is expressed in cubic centimeters per gram (cc/g). Tissue products prepared according to the present invention generally have a sheet bulk greater than about 7.0 cc/g, more preferably greater than about 8.0 cc/g and still more preferably greater than about 9.0 cc/g, such as from about 7.00 to about 11.0 cc/g, such as from about 8.00 to about 10.0 cc/g.
[0045] As used herein, the term “slope” refers to the slope of the line resulting from plotting tensile versus stretch and is an output of the MTS TestWorks™ in the course of determining the tensile strength as described in the Test Methods section herein. Slope is reported in the units of grams (g) per unit of sample width (inches) and is measured as the gradient of the least-squares line fitted to the load-corrected strain points falling between a specimen-generated force of 70 to 157 grams (0.687 to 1.540 N) divided by the specimen width. Slopes are generally reported herein as having units of kilograms per sample width, such as kg/3″.
[0046] As used herein, the term “geometric mean slope” (GM Slope) generally refers to the square root of the product of machine direction slope and cross-machine direction slope. GM Slope generally is expressed in units of kg.
[0047] As used herein, the terms “geometric mean tensile” (GMT) refers to the square root of the product of the machine direction tensile strength and the cross-machine direction tensile strength of the web.
[0048] As used therein the term “dot embossment” means an embossment that exhibits an aspect ratio of about 1:1. Non-limiting examples of dot embossments are embossments having a circular, oval, square, or triangular cross-sectional shape.
[0049] As used herein the term “Average Height at 100%” (H.sub.100) for a given embossment 24 (as illustrated in
[0050] As used herein the term “Average Height at 50%” (H.sub.50) for a given embossment 24 (as illustrated in
[0051] As used herein the term “Average Height at 25%” (H.sub.25) for a given embossment 24 (as illustrated in
[0052] As used herein the term “Area at 100%” (A.sub.100) for a given embossment 24 (as illustrated in
[0053] As used herein the term “Area at 50%” (A.sub.50) for a given embossment 24 (as illustrated in
[0054] As used herein the term “Area at 25%” (A.sub.25) for a given embossment 24 (as illustrated in
[0055] As used here the term “Average Width at 100% Height” (W.sub.100) for a given embossment 24 (as illustrated in
W.sub.100 typically has units of microns (μm) and is measured as described in the Test Methods section below.
[0056] As used here the term “Average Width at 50% Height” (W.sub.50) generally refers to the average width of the embossment near its midpoint. For a given embossment 24 (as illustrated in
W.sub.50 typically has units of microns (μm) and is measured as described in the Test Methods section below.
[0057] As used here the term “Average Width at 25% Height” (W.sub.25) generally refers to the average width of the embossment at 25% of its height. For example, as illustrated in
W.sub.50 typically has units of microns μm and is measured as described in the Test Methods section below.
DETAILED DESCRIPTION
[0058] The present invention provides a multi-ply embossed tissue product having improved softness, strength, embossment clarity and/or embossment height compared to prior art embossed tissue products. Accordingly, in one embodiment the present invention provides a multi-ply tissue product comprising an embossed tissue ply having a basis weight less than about 25 grams per square meter (gsm), such as from about 10 to about 25 gsm and more preferably from about 15 to about 20 gsm, and a plurality of embossments disposed thereon.
[0059] Preferably the embossments are shaped and sized to provide the tissue product with improved pattern clarity and definition. As such, the embossments may be relatively deep having a H.sub.100, measured as described herein, greater than about 500 μm, such as from about 500 to about 1,000 μm. Further, the embossments may have relatively wide top portions compared to the bottom portions, which are relatively narrow. The relative dimension of the embossment top and bottom portions may be defined as the ratio of W.sub.100 to W.sub.25 and measured as described herein. For example, the product may comprise a plurality of embossments having a ratio of W.sub.100 to W.sub.25 greater than about 3.0, such as from about 3.0 to about 4.0. The combination of these elements provides an aesthetically pleasing and well-defined embossment, while improving important tissue product properties such as sheet and roll bulk and softness.
[0060] The tissue products of the present invention generally comprise two, three or four tissue plies made by well-known wet-laid papermaking processes such as, for example, creped wet pressed, modified wet pressed, creped through-air dried (CTAD) or uncreped through-air dried (UCTAD). For example, creped tissue webs may be formed using either a wet pressed or a modified wet pressed process such as those disclosed in U.S. Pat. Nos. 3,953,638, 5,324,575 and 6,080,279, the disclosures of which are incorporated herein in a manner consistent with the instant application. In these processes the embryonic tissue web is transferred to a Yankee dryer, which completes the drying process, and then creped from the Yankee surface using a doctor blade or other suitable device.
[0061] In other instances, the tissue plies may be manufactured by a through-air dried process known in the art. In such processes the embryonic web is noncompressively dried. For example, textured tissue plies may be formed by either creped or uncreped through-air dried processes. Particularly preferred are uncreped through-air dried webs, such as those described in U.S. Pat. No. 5,779,860, the contents of which are incorporated herein in a manner consistent with the present disclosure.
[0062] In still other instances the tissue plies may be manufactured by a process including the step of using pressure, vacuum, or air flow through the wet web (or a combination of these) to conform the wet web into a shaped fabric and subsequently drying the shaped sheet using a Yankee dryer, or series of steam heated dryers, or some other means, including but not limited to tissue made using the ATMOS process developed by Voith or the NTT process developed by Metso; or fabric creped tissue, made using a process including the step of transferring the wet web from a carrying surface (belt, fabric, felt, or roll) moving at one speed to a fabric moving at a slower speed (at least 5 percent slower) and subsequently drying the sheet. Those skilled in the art will recognize that these processes are not mutually exclusive, e.g., an uncreped TAD process may include a fabric crepe step in the process.
[0063] The instant multi-ply tissue product may be constructed from two or more plies that are manufactured using the same or different tissue making techniques. In a particularly preferred embodiment, the multi-ply tissue product comprises three plies where each of the plies comprises a wet-pressed tissue ply, where each ply has a basis weight greater than about 10.0 gsm, such as from about 10.0 to about 20.0 gsm, such as from about 12.0 to about 16.0 gsm.
[0064] Regardless of the tissue making process used to produce the individual plies, the resulting multi-ply tissue product has a first surface having a plurality of first embossments. As shown in
[0065] The first embossments 24 may be a dot emboss element having a generally circular shape at the tissue surface 22. A dot emboss element, such as the first embossment 24, can be characterized by having a depth relative to the surface of the respective sheet surface 22 and a total embossment length to total embossment width (or an aspect ratio) of about 1. The first embossments 24 may be further arranged to provide the appearance of discontinuous lines 30, which are further arranged to form an embossed element 32 in the form of a flower. The embossed elements 32 are further arranged relative to one another to form a pattern 40 on the tissue surface 22.
[0066] Generally, the embossing pattern may comprise a plurality of embossing elements 32 having the same, similar or different shapes. Suitable embossing element shapes may include, for example, geometric shapes, organic shapes, abstract shapes, characters, and branding. In certain instances, the embossing elements may be geometric shapes, such as squares, octagons, pentagons, diamonds, triangles, circles, and the like. In other instances, the embossing element may be an organic shape that is illustrative of a natural object such as a leaf, a flower, a snowflake, or the like. In still other instances the embossing element may be an abstract shape, which may be derived from an actual object but not be immediately recognizable as such by a consumer.
[0067] With continued reference to
[0068] With reference now to
[0069] The embossing elements may be arranged and sized to provide the product with an embossed pattern having a total embossed surface area ranging from about 5 to about 40 percent, more preferably ranging from about 8 to about 35 percent, even more preferably ranging from about 20 to about 25 percent. In a preferred embodiment, only embossed elements that are completely disposed upon the tissue sheet surface are utilized for the calculation of total embossed area.
[0070] Without desiring to be bound by theory, providing a tissue product having an embossed area ranging from about 5 about 40 percent, and more preferably from about 8 to about 25 percent, and an embossed pattern consisting essentially of organic shaped embossed elements formed from dot emboss elements communicates to the consumer that the product is soft and cushiony. Additionally, at the foregoing embossed areas and shapes the emboss pattern has an aesthetic quality that does not appear overly complicated but simplistic and natural.
[0071] The multi-ply embossed tissue products of the present invention may have a basis weight from about 20 to about 80 gsm, such as from about 30 to about 65 gsm, such as from about 42 to about 60 gsm. In certain instances, the multi-ply embossed tissue products may comprise two, three or four tissue plies where the basis weight of each individual tissue plie is less than about 25 gsm, such as from about 10 to about 20 gsm, such as from about 10 to about 15 gsm.
[0072] In certain instances, the multi-ply embossed tissue products of the present invention may have a geometric mean tensile (GMT) strength from about 800 to about 1,800 g/3″, such as from about 800 to about 1,600 g/3″, such as from about 800 to about 1,500 g/3″. In certain instances, the multi-ply embossed tissue products may comprise two, three or four tissue plies where the GMT of each individual tissue plie is less than about 600 g/3″, such as from about 200 to about 425 g/3″, such as from about 350 to about 550 g/3″.
[0073] In other instances, the multi-ply embossed tissue products of the present invention may have a sheet bulk greater than about 7.00 cc/g, such as from about 7.00 to about 11.0 cc/g, such as from about 8.00 to about 10.0 cc/g. In certain instances, at the foregoing sheet bulks, the tissue products may have a sheet caliper greater than about 1,000 μm, such as from about 1,000 to about 2,000 μm, such as from about 1,000 to about 1,800 μm.
[0074] The foregoing multi-ply tissue products may be converted into rolled tissue products, such as rolled bath tissue products, comprising a multi-ply embossed tissue web spirally wound about a core. Such rolled tissue products may comprise a plurality of connected, but perforated, multi-ply tissue sheets that may be separated from adjacent sheets. Rolled tissue product may have a roll bulk greater than about 8.00 cc/g, such as from about 8.50 to about 15.0 cc/g, such as from about 9.00 to about 13.0 cc/g.
[0075] In certain instances, the present invention provides a multi-ply tissue product comprising a first embossed tissue ply having a basis weight from about 13 to about 20 gsm and a first and a second surface, the first surface having a plurality of dot embossments disposed thereon. The dot embossments are arranged to form an embossed element, a plurality of which may further be arranged to form an embossed pattern on the first surface of the first embossed tissue ply. The dot embossments forming the element may be separated and spaced apart from one another to define cushion regions there between.
[0076] The tissue product may comprise a cushion region supported by a pillow-like embossment disposed on an opposing tissue ply forming a portion of the multi-ply tissue product, as will be described in more detail below. The existence of the cushion regions, which are supported by opposing pillow-like embossments generates the visual appearance of soft cushions and improves the perceived softness of the product.
[0077] Moreover, the product has good mechanical properties, such as GMT, as well as good caliper and bulk. The properties of three- and four-ply tissue products prepared according to the present invention are summarized in Table 1, below.
TABLE-US-00001 TABLE 1 Inventive Four-Ply Inventive Three-Ply Rolled Tissue Product Rolled Tissue Product Basis Wt. (gsm) 58 50 Sheet caliper (mm) 0.694 0.533 Sheet bulk (cc/g) 11.2 9.9 Roll bulk (cc/g) 10.2 10.1 Kershaw Firmness (mm) 9.30 10.51
[0078] With reference now to
[0079] The embossments 24a, 24b may have an elongated shape having opposed side walls 41, 43 and a bottom portion 45, which may be substantially planar or curvilinear. The embossments 24 have an embossment height (H) that is generally the distance between the upper surface plane 50 of an unembossed region 38 and the surface plane 52 of the upper surface of the embossment bottom portion 45.
[0080] The embossments may be relatively wide near the tissue surface. For example, the embossments may have a cross-sectional dimension near the upper surface of the product from about 0.070 and about 0.40 mm.sup.2. The cross-sectional geometry of the embossments at the surface of the tissue product may be selected from a variety of geometric shapes, such as, for example, circular or oval. In a particularly preferred embodiment, the embossments are similarly shaped and have a circular cross-sectional shape.
[0081] Between the spaced apart first embossments 24a, 24b are dome-like structures 36. The dome-like structure 36 has an upper surface lying in a second upper surface plane 54. In certain instances, the second upper surface plane 54 may lie above the first upper surface plane 50, providing the tissue product upper surface with at least two different planes. For example, the tissue product 20 may comprise unembossed regions 38 having an upper surface lying in a first surface plane 50 and dome-like structures 36 disposed between embossments 24a, 24b and lying in a second surface plane 54, wherein the second tissue product surface plane 54 is above the first tissue product surface plane 50.
[0082] As will be discussed in more detailed below, in certain instances, to elevate the dome-like structure 36 above the unembossed area 38, the structure 36 may be supported by a second embossment 25. The second embossment 25 may be disposed on a third (bottom) tissue ply 35 and registered with the first embossments 24a, 24b, such that the second embossment 25 nests into the dome-like structure 36 and is bounded by the first embossments 24a, 24b.
[0083] The product may further comprise a middle ply. The middle ply may comprise embossments arranged in an embossing pattern similar to the first ply embossing pattern. The first and second plies may be plied together such that the embossments are registered with one another. The embossments may be registered with one another by embossing the first and second plies in a single step. For example, the first and second plies may be plied together and then passed through a single embossing nip. In certain preferred embodiments the top and middle plies are not adhesively attached to one another, rather the plies are attached mechanically by embossing. In a particularly preferred embodiment, such as that illustrated in
[0084] With continued reference to
[0085] In certain instances, such as illustrated in
[0086] With reference now to
[0087] As illustrated in the cross-sectional profile of
[0088] With reference now to
[0089] As illustrated in the cross-sectional profile of
[0090] With reference to
[0091] As illustrated in
[0092] Generally, the embossed tissue products are an improvement over prior art embossed tissue products, particularly in terms of embossment pattern clarity and definition. Without being bound by any particular theory, it is believed that the improvement in pattern clarity and definition is attributable, in-part, to first embossments that are relatively deep with broad top portions and relatively narrow bottom portions. For example, the first embossments may have a H.sub.100 (a measurement of embossment depth) from about 700 to about 1,000 μm and a W.sub.25 (a measurement of size of the embossment at is bottom portion) less than about 600 μm, such as less than about 500 μm, such as from about 300 to about 600 μm. In other instances, the first embossments may have ratios of W.sub.100 to W.sub.25 (measurements of the relative size of an embossment at its top and bottom portions) greater than about 3.0, such as greater than about 3.25, such as greater than about 3.5, such as from about 3.0 to about 4.0.
[0093] The novel features of the present tissue products compared to those of the prior art are further summarized in Table 2, below.
TABLE-US-00002 TABLE 2 H.sub.100 H.sub.50 H.sub.25 W.sub.100 W.sub.50 W.sub.25 Product Product Type Mfg. (μm) (μm) (μm) (μm) (μm) (μm) W.sub.100:W.sub.50 W.sub.100:W.sub.25 W.sub.50:W.sub.25 Just One Towel Essity 669 334 167 1314 1070 979 1.23 1.34 1.09 Scott Calorie Light Towel K-C 730 365 183 1848 1254 1067 1.47 1.73 1.17 Sparkle Towel G-P 792 396 198 1862 1371 1157 1.36 1.62 1.19 Scott Clean Care Bath Tissue K-C 466 233 116 1348 602 474 2.25 2.88 1.28 Angel Soft Bath Tissue G-P 765 383 191 1190 763 613 1.56 1.94 1.24 Inventive 1 Bath Tissue — 803 402 201 2193 928 591 2.36 3.71 1.57 Inventive 2 Bath Tissue — 710 355 177 1585 691 491 2.29 3.23 1.41
[0094] The tissue products of the present invention, in particular embodiments, may be manufactured by a process whereby the top and bottom plies are embossed such that when they are combined, the first embossments of the top ply form dome-like regions there between and the second embossments of the bottom ply are nested within, and support, the dome-like regions. This requires an embossing process in which the top and bottom plies are embossed in a synchronized manner in order to ensure the desired nesting arrangement.
[0095] To produce multi-ply tissue products, multiple base tissue sheets are prepared and then combined using well known processing machines (converting machines) which include operations such as unwinding the base tissue sheets, calendering, printing, embossing, bonding of individual plies to be combined together as well as cutting, perforation and folding. It is particularly preferred that one or more base sheets are embossed during formation of the product. An embossing process is carried out in the nip between an embossing roll, also referred to herein as a patterned roll, and an anvil roll, also referred to herein as a counter roll. The embossing roll can have protrusions on its circumferential surface leading to embossments in the paper web.
[0096] In certain embodiments the tissue products of the present invention may be manufactured from two or more base sheet webs, such as two, three or four base sheet webs that are combined together and embossed using an embossing technique commonly referred to as DESL (Double Embossing Single Lamination), which in certain instances may be arranged so as to provide a nested configuration, as described in more detail below. In the DESL process, a first web is directed through the nip between an embossing roll and an anvil roll. In this nip the web is provided with an embossing pattern. Thereafter, an application roll for adhesive applies adhesive to those parts of the first web at which there are protruding embossing elements in the embossing roll. The adhesive is transported from an adhesive bath via an adhesive transfer roll to the application roll. A second web is transported to the first web and adhesively bonded to the first web in the nip between the so-called marrying roll and the embossing roll. The adhesive bonding takes place at those portions at which the adhesive was applied.
[0097] The process further comprises an additional pair of rolls consisting of a second embossing roll and a second anvil roll. The additional pair of rolls serves to emboss the second web before it is adhesively bonded to the first web using the marrying roll. Typically, the additional pair of rolls is placed close to the first pair of rolls and the marrying roll. Especially when using the so-called Nested-method, such close arrangement is important. The Nested-method can be considered as a special case of the general DESL-manufacturing method. For the Nested-method the embossing elements of the first embossing roll and the embossing elements of the second embossing roll are arranged such that the embossed elements of the first embossed ply and the embossed elements of the second embossed ply fit into each other similar to a gearing system. This serves to achieve a mutual stabilization of the two plies. However, for the DESL manufacturing method such correlation between the embossed elements of the first, upper ply, and the second, lower ply, does not have to apply.
[0098] Turning now to
[0099]
[0100] The embossing operation of the present invention utilizes an embossing roll and an anvil that create a nip pressure, when engaged with one another to form an embossing nip, sufficient to create deformations (embossments) in a fibrous structure present within the embossing nip. The embossing roll generally comprises a plurality of protrusions on its outer surface where the protrusions form an embossing pattern. For example, as illustrated in
[0101] In particular embodiments, the embossing roll is made of metal, especially steel, hard plastics materials or hard rubber. In case of plastics, very hard plastic material can be preferred, alternatively a resin material is also possible. In particular embodiments, the anvil roll is made of rubber like EPDM or NBR (acrylonitrile-butadiene rubber), paper or steel. The rubber can have a hardness between 20 and 85 Shore A, preferably between 35 and 60 Shore A and most preferably a hardness of about 45 Shore A.
[0102] The embossing roll may be made by any suitable process known in the art. Non-limiting examples of suitable processes include laser engraving hard plastic (ebonite) or ceramic or other material suitable for laser ablation to remove material and create embossing elements, chemical engraving of steel or other materials to remove material and create embossing elements, machining aluminum or steel or other metals to remove material and create embossing elements, metallizing processes to build up embossing elements, sintering processes to build up embossing elements and/or other means known in the art to remove material or build up material and achieve a surface topography with the desired pattern and clearances between mating embossing elements.
[0103] The bottom ply 101, also referred to herein as the third ply, is unwound from a third parent roll 107 and introduced into the nip 120 formed between a second embossing roll 121 and a second anvil roll 122 which form a second embossing station. As regards the possible materials for the second embossing roll 121 and a second anvil roll 122, the same materials as described above with reference to the first embossing roll 111 and the first anvil roll 112 also apply. Upon passing through the embossing nip 120 the bottom ply 101 is provided with a second embossing pattern, which is preferably different than the pattern applied by the first embossing station. The embossing pattern is imparted to the bottom ply 101 by contacting it with a plurality of second protuberances 125 disposed on the second embossing roll 121.
[0104] The process may further comprise an application device 145, which may include an applicator roll 147 for applying functional substances 148 to the second ply 102 after it exits the first embossing nip 110. Such applicator devices are well known in the art and commonly used for the application of adhesives or colored substances. For example, the process may comprise an applicator roll 147 which contacts the protrusions on the second ply 102 while supported by the first embossing roll 111.
[0105] In a particularly preferred embodiment, an adhesive is applied by the application device, which may comprise an adhesive applicator roll running against the first embossing roll. For laminating the single webs of material together, different types of adhesive can be used. Suitable adhesives are, inter alia, glue on the basis of starch or modified starch like, for example, methyl cellulose or carboxylated methyl cellulose, and adhesively acting polymers on the basis of synthetic resins, caoutchouc, polypropylene, polyisobutylene, polyurethane, polyacrylates, polyvinyl acetate or polyvinyl alcohol. Such adhesives can also contain coloring agents in order to improve the optical appearance of the finished products. Frequently, water-based glues are used for laminating together paper layers.
[0106] The first embossing roll 111 and the second embossing roll 121 are operated in registration with one another which means that both rolls have to be operated in a synchronized manner such that the embossed third ply 101 leaving the second embossing roll 121 can be directed in a predetermined positional relationship onto the first and second plies 102, 103 still on the surface of the first embossing roll 111. In this way, the first, second and third plies 101, 102, 103 are combined to form a subunit—the bottom ply embossments nest into the dome-like structures formed by the embossing pattern of the first and second plies.
[0107] Further, a marrying roll 152 runs against the first embossing roll 111 such that the subunit including the first and second plies 102, 103 and optionally a glue applied to a part of the surface of the second ply 102 can be brought in contact with the bottom ply 101. In this manner the bottom ply 101 is laminated to the middle ply 102 in a third nip 124 formed between the first embossing roll 111 and the marrying roll 152.
[0108] In use, the embossments formed on the bottom ply by the second embossing roll are registered with the dome-like structures disposed on an upper tissue ply. Registration in this manner is possible since the first embossing roll and the second embossing roll are preferably run in registration with one another. To facilitate this arrangement, the second embossing roll may be provided with a plurality of discrete, oval-shaped protrusions that generate the second embossments on the at least one bottom ply. The second embossments nest into the dome-like structures of the upper ply and may be arranged to stabilize the dome-like structures.
[0109] With reference now to
[0110] When used to manufacture a tissue product, the embossing elements, which in the illustrated embodiment are a plurality of discrete circular protrusions 202 arranged to form elements 205, form a discontinuous line embossment in the tissue ply where the embossments are relatively deep with relatively broad upper portions and narrow lower portions. The elements 205 may further be designed such that they have an unembossed area that may form dome-like structures in the resulting tissue product. The portion of the embossing pattern 200 corresponding to the dome-like structures, generally identified as 215 in
[0111] Between adjacent elements 205, the pattern 200 may include regions 220 that are substantially free from embossing elements. Such regions may correspond to unembossed regions of the resulting embossed first ply exemplified by reference numeral 38 in
[0112] An embossing element 205 useful in embossing a tissue ply, particularly a top ply in a multi-ply product, is illustrated in further detail in
[0113]
[0114] In addition to the discrete protrusions 302 forming the element perimeter 320, the embossing element 305 may further comprise a plurality of discrete protrusions, such as protrusions 314a-314c, generally disposed within the perimeter 320. The protrusions may be arranged such that they stabilize the dome-like structures of an upper tissue ply when producing a multi-ply tissue product according to the present invention.
Test Methods
Microscopy
[0115] Tissue products produced according to the present invention may be analyzed by microscopy as described herein. Particularly, the three-dimensional surface topography and embossments may be analyzed by generating and analyzing product 3-D surface maps and cross-sections, such as those illustrated in
[0116] The tissue product sample to be analyzed should be an undamaged, flat, and include representative embossments. A normal sheet of bath tissue, approximately 4 inches×4 inches in size, works well.
[0117] A three-dimensional image of the sample is obtained as follows:
[0118] 1. Turn the digital microscope on and follow standard procedures for XY stage Initialization [Auto].
[0119] 2. Turn the microscope magnification to ×100.
[0120] 3. Place the tissue product sample on the stage with the first embossments facing up toward the lens.
[0121] 4. If the fabric does not lie flat, place weights as needed along the perimeter to make fabric lie flat against the stage surface.
[0122] 5. Use the focus adjustment to bring the fabric into sharp focus.
[0123] 6. Select “Stitching” in the main menu. Select “3D stitching.”
[0124] 7. Set the stitching method by selecting “Stitch around the current position.”
[0125] 8. Select the Z set to set the upper and lower composition range. The upper limit should be set by going higher than the highest focal point that is clear. The lower limit should be set by going lower than the lowest focal point that is clear. After setting the upper and lower range, click OK.
[0126] 9. Select “Start stitching” to begin accusation of the image.
[0127] 10. In the 3D menu, select “Height/Color view” to identify dome-like features with the highest degree of topography.
[0128] 11. In the 3D menu, select “Profile.”
[0129] 12. With the “Profile line” tab selected obtain a cross-section of the tissue sample identified in Step 10, select “Line” and using the cursor to draw a line across the identified portion of the sample. The line should bisect at least three adjacent first embossments, such as line A-A of
[0130] To measure various embossment parameters, such as minimum and maximum heights and the distanced there between:
[0131] 13. Select “Assist Tools.”
[0132] 14. Select “Max” tool to identify the maximum point to the right of the first embossment, such as point 49a to the right of the first embossment 24a of
[0133] 15. Select “Max” tool to identify the maximum point to the left of the first embossment, such as point 47a to the left of the first embossment 24a of
[0134] 16. Select “Min” tool to identify the minimum point in the first embossment, such as point 45a of the first embossment 24a of
[0135] 17. Select “MidPoint” tool to determine the midpoint between the maximum peak on the right side of the first embossment and the first embossment minimum, such as the point M2 between the embossment minimum 45 and right side maximum 49 of the first embossment 24 of
[0136] 18. Select “MidPoint” tool to determine the midpoint between the maximum peak on the left side of the first embossment and the first embossment minimum, such as the point M1 between the embossment minimum 45 and left side maximum 47 of the first embossment 24 of
[0137] 19. Select “MidPoint” tool to determine the midpoint between the midpoint determined in step 17 and the minimum of the first embossment. This point is 25 percent of the distance between the maximum peak on the right side of the first embossment and the first embossment minimum, such as the point Q2 between the embossment minimum 45 and right side maximum 49 of the second embossment 24 of
[0138] 20. Select “MidPoint” tool to determine the midpoint between the midpoint determined in step 18 and the minimum of the first embossment. This point is 25 percent of the distance between the maximum peak on the left side of the first embossment and the first embossment minimum, such as the point Q1 between the embossment minimum 45 and left side maximum 47 of the second embossment 24 of
[0139] To calculate the cross-sectional area of various portions of the embossments, such as A.sub.100, A.sub.50 and A.sub.25:
[0140] 21. Select “Assist Tools.”
[0141] 22. Select “CrsSct(bottom).” Check “Measure at arbitrary point” box.
[0142] 23. Select the maximum point to the right of the first embossment (step 14), select the maximum point to the left of the first embossment (step 15). Set the right line to the right of the right side wall of the embossment. Set the left line to the left of the left side wall of the embossment. This value is A.sub.100.
[0143] 24. Select the midpoint to the right of the first embossment (step 17), select midpoint to the left of the first embossment (step 18). Set the right line to the right of the right side wall of the embossment. Set the left line to the left of the left side wall of the embossment. This value is A.sub.50.
[0144] 25. Select the midpoint of the midpoint to the right of the first embossment (step 19), select midpoint of the midpoint to the left of the first embossment (step 20). Set the right line to the right of the right side wall of the embossment. Set the left line to the left of the left side wall of the embossment. This value is A.sub.25.
[0145] To measure the height of the embossments:
[0146] 26. In the Measurement Tools, ensure the “Measure” tab is selected.
[0147] 27. Select the “Pt-Pt” tool, then select Vertical from the pull-down menu.
[0148] 28. Select the maximum point to the right of the first embossment (step 14), then select the minimum point (Step 16), then click on the place on the screen to display the measurement. This value will be used to calculate H.sub.100 as described below and is the height (H2) between points 45 and 49 of
[0149] 29. Select the maximum point to the left of the first embossment (step 15), then select the minimum point (Step 16), then click on the place on the screen to display the measurement. This value will be used to calculate H.sub.100 as described below and is the height (H1) between points 45 and 47 of
[0150] 30. Select the midpoint to the right of the embossment (step 17), then select the minimum point (step 16), then click on the place on the screen to display the measurement. This value will be used to calculate H.sub.50 as described below and is the height (H4) between points 45 and M2 of
[0151] 31. Select the midpoint to the left of the embossment (step 18), then select the minimum point (step 16), then click on the place on the screen to display the measurement. This value will be used to calculate H.sub.50 as described below and is the height (H3) between points 45 and M1 of
[0152] 32. Select the midpoint of the midpoint to the right of the embossment (step 19), then select the minimum (step 16), then click on the place on the screen to display the measurement. This value will be used to calculate H.sub.25 as described below and is the height (H6) between points 45 and Q2 of
[0153] 33. Select the midpoint of the midpoint to the left of the embossment (step 20), then select the minimum (step 16), then click on the place on the screen to display the measurement. This value will be used to calculate H.sub.25 as described below and is the height (H5) between points 45 and Q1 of
[0154] Various parameters of the tissue product may be calculated from the foregoing measurements as indicated below:
[0155] 34. To calculate H.sub.100 average the values measured in steps 28 and 29.
[0156] 35. To calculate H.sub.50 average the values measured in steps 30 and 31.
[0157] 36. To calculate H.sub.25 average the values measured in steps 32 and 33.
[0158] 37. To calculate W.sub.100 divide A.sub.100 (step 23) by H.sub.100 (as determined in step 34).
[0159] 38. To calculate W.sub.50 divide A.sub.50 (step 24) by H.sub.50 (as determined in step 35).
[0160] 39. To calculate W.sub.25 divide A.sub.25 (step 25) by H.sub.25 (as determined in step 36).
Sheet Bulk
[0161] Sheet Bulk is calculated as the quotient of the dry sheet caliper (μm) divided by the basis weight (gsm). Dry sheet caliper is the measurement of the thickness of a single tissue sheet measured in accordance with TAPPI test methods T402 and T411 om-89. The micrometer used for carrying out T411 om-89 is an Emveco 200-A Tissue Caliper Tester (Emveco, Inc., Newberg, Oreg.). The micrometer has a load of 2 kilo-Pascals, a pressure foot area of 2,500 square millimeters, a pressure foot diameter of 56.42 millimeters, a dwell time of 3 seconds, and a lowering rate of 0.8 millimeters per second.
Tensile
[0162] Tensile testing was done in accordance with TAPPI test method T-576 “Tensile properties of towel and tissue products (using constant rate of elongation)” wherein the testing is conducted on a tensile testing machine maintaining a constant rate of elongation and the width of each specimen tested is 3 inches. More specifically, samples for dry tensile strength testing were prepared by cutting a 3±0.05 inch (76.2±1.3 mm) wide strip in either the machine direction (MD) or cross-machine direction (CD) orientation using a JDC Precision Sample Cutter (Thwing-Albert Instrument Company, Philadelphia, Pa., Model No. JDC 3-10, Serial No. 37333) or equivalent. The instrument used for measuring tensile strengths was an MTS Systems Sintech 11S, Serial No. 6233. The data acquisition software was an MTS TestWorks® for Windows Ver. 3.10 (MTS Systems Corp., Research Triangle Park, N.C.). The load cell was selected from either a 50 Newton or 100 Newton maximum, depending on the strength of the sample being tested, such that the majority of peak load values fall between 10 to 90 percent of the load cell's full scale value. The gauge length between jaws was 4±0.04 inches (101.6±1 mm) for facial tissue and towels and 2±0.02 inches (50.8±0.5 mm) for bath tissue. The crosshead speed was 10±0.4 inches/min (254±1 mm/min), and the break sensitivity was set at 65 percent. The sample was placed in the jaws of the instrument, centered both vertically and horizontally. The test was then started and ended when the specimen broke. The peak load was recorded as either the “MD tensile strength” or the “CD tensile strength” of the specimen depending on direction of the sample being tested. Ten representative specimens were tested for each product or sheet and the arithmetic average of all individual specimen tests was recorded as the appropriate MD or CD tensile strength of the product or sheet in units of grams of force per 3 inches of sample. The geometric mean tensile (GMT) strength was calculated and is expressed as grams-force per 3 inches of sample width. Tensile energy absorbed (TEA) and slope are also calculated by the tensile tester. TEA is reported in units of gmcm/cm.sup.2. Slope is recorded in units of kg. Both TEA and Slope are directionally dependent and thus MD and CD directions are measured independently. Geometric mean TEA and geometric mean slope are defined as the square root of the product of the representative MD and CD values for the given property.
[0163] Multi-ply products were tested as multi-ply products and results represent the tensile strength of the total product. For example, a two-ply product was tested as a two-ply product and recorded as such. A basesheet intended to be used for a two-ply product was tested as two plies and the tensile recorded as such. Alternatively, a single ply may be tested, and the result multiplied by the number of plies in the final product to get the tensile strength.
Embodiments
[0164] In a first embodiment the present invention provides a multi-ply tissue product comprising a first ply having a first surface and a plurality of discrete, spaced apart, dot embossments disposed thereon and a plurality of dome-like structures disposed between the spaced apart dot embossments and a second ply having a first surface and a plurality of discrete embossments disposed thereon, wherein the dot embossments have a height (H.sub.100) greater than 500 μm and an average width at 25% height (W.sub.25) less than about 600 μm.
[0165] In a second embodiment the present invention provides the product of the first embodiment wherein the tissue product has a geometric mean tensile (GMT) strength from about 800 to about 1,700 g/3″.
[0166] In a third embodiment the present invention provides the product of the first or the second embodiments wherein the tissue product consists of three plies and has a basis weight from about 30 to about 50 grams per square meter (gsm).
[0167] In a fourth embodiment the present invention provides the product of any one of the foregoing embodiments wherein the first and second plies have a basis weight from about 10 to about 20 gsm.
[0168] In a fifth embodiment the present invention provides the product of any one of the foregoing embodiments wherein the tissue product has a sheet bulk from about 7.0 to about 11.0 cubic centimeters per gram (cc/g).
[0169] In a sixth embodiment the present invention provides the product of any one of the foregoing embodiments wherein the tissue product is spirally wound around a core to yield a rolled tissue product having a roll bulk from about 8.0 to about 13.0 cc/g.
[0170] In a seventh embodiment the present invention provides the product of any one of the foregoing embodiments wherein the dot embossments have a H.sub.100 from 700 to about 1,000 μm.
[0171] In an eighth embodiment the present invention provides the product of any one of the foregoing embodiments wherein the dot embossments have a ratio of average width at 100% height (W.sub.100) to W.sub.25 from about 3.00 to about 4.00.
[0172] In a ninth embodiment the present invention provides the product of any one of the foregoing embodiments wherein the dot embossments have a ratio of average width at 50% height (W.sub.50) to W.sub.25 greater than about 1.40.
[0173] In a tenth embodiment the present invention provides the product of any one of the foregoing embodiments wherein the tissue product has a basis weight of about 60 gsm or less and a GMT less than about 1,500 g/3″ and the dot embossments have a W.sub.50 less than about 1,000 μm and an average height at 50% (H.sub.50) greater than about 350 μm.