Gasification unit, a method for producing a product gas and use of such a method
11459518 · 2022-10-04
Assignee
Inventors
- Rasmus Østergaard Gadsbøl (Allerød, DK)
- Ulrik Birk Henriksen (Soborg, DK)
- Jesper Ahrenfeldt (Frederiksvaerk, DK)
Cpc classification
C10J2300/1807
CHEMISTRY; METALLURGY
C10J3/66
CHEMISTRY; METALLURGY
International classification
Abstract
Disclosed is a gasification unit (1) for producing a product gas. The gasification unit (1) comprises a co-current or counterflow pyrolysis unit (2) including a pyrolysis gas outlet (3) arranged at an upper part (4) of the pyrolysis unit (2) and a pyrolysis gas inlet (5) arranged at a lower part (6) of the pyrolysis unit (2). The gasification unit (1) further comprises a co-current or counterflow gasifier (7) including a product gas outlet (8) arranged at an upper part (9) of the gasifier (7) and a gasifier inlet (10) arranged at a lower part of the gasifier (7) and coke moving means (12) for allowing pyrolyzed coke (13) to move from the pyrolysis unit (2) to the gasifier (7). The gasification unit (1) also comprises recycling means (14) arranged to guide at least a part of the pyrolysis gas produced in the pyrolysis unit (2) from the pyrolysis gas outlet (3) and back to the pyrolysis gas inlet (5) and heating device (15) comprising an input conduit (16) arranged to guide pyrolysis gas from the pyrolysis gas outlet (3) to a combustion unit (17) in the heating device (15), wherein the combustion unit (17) is arranged to least a partially oxidize the pyrolysis gas from the pyrolysis unit (2), and wherein the heating device (15) comprises an output conduit (18) arranged to guide heating gas generated by the partial oxidization in the combustion unit (17) to the gasifier inlet (10), where in the heating device (15) is arranged external to the pyrolysis unit (2) and the gasifier (7) and wherein said gasification unit (1) further comprises heat exchange means (19) arranged for heating at least a portion of the pyrolysis gas before it enters the pyrolysis unit (2) through said pyrolysis gas inlet (5) by means of at least a part of the product gas exiting said gasifier (7) through said product gas outlet (8). Furthermore, a method for producing a product gas in a gasification unit (1) and use of such a method is disclosed.
Claims
1. A gasification unit for producing a product gas, said gasification unit comprising, a co-current or counterflow pyrolysis unit comprising a pyrolysis gas outlet arranged at an upper part of said pyrolysis unit and a pyrolysis gas inlet arranged at a lower part of said pyrolysis unit, a co-current or counterflow gasifier comprising a product gas outlet arranged at an upper part of said gasifier and a gasifier inlet arranged at a lower part of said gasifier, a coke mover for allowing pyrolyzed coke to move from said pyrolysis unit to said gasifier, a recycler arranged to guide at least a part of the pyrolysis gas produced in said pyrolysis unit from said pyrolysis gas outlet and back to said pyrolysis gas inlet as recycled pyrolysis gas, and a heating device comprising an input conduit arranged to guide pyrolysis gas from said pyrolysis gas outlet to a combustion unit in said heating device, wherein said combustion unit is arranged to at least partially oxidize said pyrolysis gas from said pyrolysis unit, and wherein said heating device comprises an output conduit arranged to guide heating gas generated by said partial oxidization in said combustion unit to said gasifier inlet, wherein said heating device is arranged external to said pyrolysis unit and said gasifier and wherein said gasification unit further comprises a heat exchanger arranged for heating at least a portion of said recycled pyrolysis gas passing through said recycler before it reenters said pyrolysis unit through said pyrolysis gas inlet by at least a part of the product gas exiting said gasifier through said product gas outlet and wherein said recycler is arranged to guide said recycled pyrolysis gas from said pyrolysis gas outlet and back to said pyrolysis gas inlet without said recycled pyrolysis gas passing through said combustion unit in said heating device.
2. A gasification unit according to claim 1, wherein said pyrolysis gas is heated by said product gas in the heat exchanger.
3. A gasification unit according to claim 1, wherein said pyrolysis gas is heated in a first heat exchanger and said product gas delivers heat in a second heat exchanger and wherein a separate fluid flow ensures heat transfer between said first and said second heat exchangers.
4. A gasification unit claim 1, wherein said heat exchanger comprises at least one plate heat exchanger.
5. A gasification unit claim 1, wherein said gasification unit comprises a cooler for cooling said heating gas to a temperature between 600° C. and 1,200° C., preferably between 700° C. and 1,100° C. and most preferred between 800° C. and 1,000° C. before it enters said gasifier.
6. A gasification unit according to claim 5, wherein said cooler adds steam to said heating gas and/or adds product gas to said heating gas to cool said heating gas.
7. A gasification unit claim 1, wherein said co-current or counterflow pyrolysis unit is arranged on top of said co-current or counterflow gasifier.
8. A gasification unit claim 1, wherein said coke mover comprises a screw conveyor.
9. A method for producing a product gas in a gasification unit, said method comprising the steps of: feeding fuel to a co-current or counterflow pyrolysis unit, circulating at least a part of the pyrolysis gas produced by said fuel in said pyrolysis unit directly back into said pyrolysis unit as recycled pyrolysis gas to form a flow of recycled pyrolysis gas up through said fuel, heating at a heating device said pyrolysis gas before it re-enters said pyrolysis unit, pyrolyzing said fuel by said re-entering heated pyrolysis gas, enabling that said pyrolyzed fuel in said pyrolysis unit is moved to a gasifier, combusting at a combustion unit in the heating device, at least a part of said pyrolysis gas outside said pyrolysis unit and said gasifier to form heating gas, and guiding said heating gas into said gasifier to heat said pyrolyzed fuel to produce a product gas, wherein said recycled pyrolysis gas is heated by said product gas before said pyrolysis gas re-enters said pyrolysis unit; wherein said recycled pyrolysis gas is guided from said pyrolysis gas outlet and back to a pyrolysis gas inlet without said recycled pyrolysis gas passing through the combustion unit in the heating device.
10. A method according to claim 9, wherein said pyrolysis gas is heated by said product gas by guiding said pyrolysis gas and said product gas through the heat exchanger.
11. A method according to claim 9, wherein said pyrolysis gas is heated by said product gas by guiding said pyrolysis gas through a first heat exchanger and guiding said product gas through second heat exchanger and establish a separate fluid flow between said first and said second heat exchangers to transfer heat between said first and said second heat exchangers.
12. A method according to claim 9, wherein between 1% and 95%, preferably between 5% and 70% and most preferred between 10% and 50% of the pyrolysis gas produced by said fuel in said pyrolysis unit is circulated back into said pyrolysis unit to form a flow of pyrolysis gas up through said fuel.
13. Use of a method according to claim 9 for producing a product gas from biomass in a gasification unit.
Description
FIGURES
(1) The invention will be described in the following with reference to the figures in which
(2)
(3)
DETAILED DESCRIPTION
(4)
(5) The units 1 illustrated in
(6) In this embodiment fuel 23 is guided into pyrolysis unit 2 through a fuel inlet 24 at an upper part 4 of the pyrolysis unit 2.
(7) In this embodiment, the fuel 23 is wood chips but in another embodiment the fuel could be (raw or pre-dried) animal slurry, (raw or pre-dried) sewage, surplus material from biochemical production or food production, another natural plant material or any other form of organic material or fossil fuel.
(8) At the top 4 of the pyrolysis unit 2 the operation temperature will typically be around 250-300° C. but as the fuel 23 moves downwards inside the pyrolysis unit 2 the temperature rises to 500° C. or more at the bottom 6 of the pyrolysis unit 2. At the lower part 6 of the pyrolysis unit 2 the fuel is transformed into pyrolyzed coke 13 and it will fall through the grate device 25 on which the fuel 23 rests in the pyrolysis unit 2.
(9) In the embodiment disclosed in
(10) In the embodiment disclosed in
(11) In this embodiment, the pressure inside the gasifier 7 is at least slightly higher than the pressure inside the pyrolysis unit 2—or at least slightly higher than the pressure just above the coke moving means 12—that the risk of pyrolysis gas traveling into the gasifier 7 via coke moving means 12 or other is substantially eliminated.
(12) In the upper part 9 of the gasifier 7 the temperature is in this embodiment 700-750° C. but it will rise as the pyrolyzed coke 13 travels down through the gasifier 7 to around 950° C. before the gasified material is removed as ash material or gasifier coke through an ash outlet 26 at the bottom 11 of the gasifier 7.
(13) It should be underlined that the temperature examples mentioned above and below are specific examples relating to a specific type of wood chip being used as fuel 23 in this embodiment. However, if different fuel 23 was used some of the temperatures might be higher or lower.
(14) In the pyrolysis units 2 the produced pyrolysis gas will travel upwards and leave the pyrolysis units 2 through the pyrolysis gas outlet 3. From there the pyrolysis gas travels through filtering means 20 in which dust and minor particles are removed from the gas. After the filtering means 20 the pyrolysis gas is divided into two different flow directions with one guiding the some of the pyrolysis gas back to the pyrolysis units 2 and with the other guiding the remaining pyrolysis gas towards the gasifier 7. Recycling means 14 comprising a fan (or another type of flow generator) arranged to generate a pyrolysis gas flow and pipes arranged to guide the pyrolysis gas will thereby guide a part of the pyrolysis gas produced in the pyrolysis unit 2 from the pyrolysis gas outlet 3 and back to the pyrolysis gas inlet 5. However, before the recycled pyrolysis gas enters the pyrolysis units 2 the pyrolysis gas is heated so that when it enters the pyrolysis gas it has a temperature of around—or preferably above −500° C.
(15) In this embodiment, the recycled pyrolysis gas is heated by means of a heat exchanger 19 enabling that the pyrolysis gas is being heated by the product gas leaving the gasifier 7. In
(16) In this embodiment the heat exchanger means 19 are plate heat exchangers but in another embodiment one or more of the heat exchangers 19 could also or instead be a shell heat exchange, a tube heat exchanger, a coil heat exchanger or other.
(17) The other part of the pyrolysis gas will simultaneously travel towards the gasifier 7 through an input conduit 16 arranged to guide the pyrolysis gas from the pyrolysis gas outlet 3 to a combustion unit 17 in a heating device 15.
(18) In the embodiment disclosed in
(19) In the combustion unit 17 the pyrolysis gas is partially oxidized in that air, oxygen enriched air or pure oxygen is added to the pyrolysis gas through an oxidation inlet 28 so that a part of the pyrolysis gas is combusted, which in turn will raise the temperature of the resulting heating gas to around 1,150° C. (or at least typically in the 900-1300° C. range) before the heating gas leaves the heating device 15 through an output conduit 18 arranged to guide the heating gas to a gasifier inlet 10 of the gasifier 7. Heating the gas to this relative high temperature level ensures a more efficient tar decomposition.
(20) However, heating gas that is this hot might damage the gasifier 7 and particularly the grate device 25 on which the pyrolyzed coke 13 rests in the gasifier 7 and in this embodiment the heating gas is therefore cooled to around 900-1,000° C. (preferably around 950° C.) before it enters the gasifier 7. In this embodiment, the heating gas is cooled by means of cooling means 21 including means for blowing steam into the heating gas through a cooling inlet 29. However, in another embodiment the cooling means 21 could also or instead be enabled otherwise—such as by blowing CO2, H2, CH4, biogas or other into the heating gas or by means of cooling tubes, a cooling shawl, a heat exchanger or other.
(21) The cooled heating gas now enters the gasifier through the gasifier inlet 10 at the bottom 11 of the gasifier 7 from where it will flow upwards and thereby gasify the pyrolyzed coke to form a gas mixture named product gas which leaves the gasifier through the product gas outlet 8 arranged at the top 9 of the gasifier 7.
(22) In this embodiment, some of the produced product is returned by means of a return conduit 30 so that it re-enters the gasifier 7 through the gasifier inlet 10 to help cooling the heating gas before it enters the gasifier 7.
(23) It should be noted that the term “partial oxidation” in this embodiment means that some oxygen is added to the pyrolysis gas but not enough to fully combust the pyrolysis gas completely. I.e. in this specific embodiment enough oxygen is added that all the pyrolysis gas is approximately 35% combusted (which is a more correct way to put it than saying that 35% of the pyrolysis gas is combusted). However, in another embodiment the partial oxidation involves adding enough oxygen to combust all the pyrolysis gas between 10% and 60%, preferably between 25% and 50%. Furthermore, it should be noted that the oxygen may be added in the form of pure liquid or gaseous oxygen, an oxygen containing compound—such as air, methanol or other, a mixture of oxygen and water vapor, a mixture of oxygen and CO2 and/or in another form and/or mixed with another gas or vapor.
(24) The invention has been exemplified above with reference to specific examples of pyrolysis units 2, gasifiers 7, coke moving means 12 and other. However, it should be understood that the invention is not limited to the particular examples described above but may be designed and altered in a multitude of varieties within the scope of the invention as specified in the claims.
LIST
(25) 1. Gasification unit
(26) 2. Counterflow pyrolysis unit
(27) 3. Pyrolysis gas outlet
(28) 4. Upper part of pyrolysis unit
(29) 5. Pyrolysis gas inlet
(30) 6. Lower part of pyrolysis unit
(31) 7. Gasifier
(32) 8. Product gas outlet
(33) 9. Upper part of gasifier
(34) 10. Gasifier inlet
(35) 11. Lower part of gasifier
(36) 12. Coke moving means
(37) 13. Pyrolyzed coke
(38) 14. Recycling means
(39) 15. Heating device
(40) 16. Input conduit
(41) 17. Combustion unit
(42) 18. Output conduit
(43) 19. Heat exchange means
(44) 20. Filtering means
(45) 21. Cooling means
(46) 22. Screw conveyor
(47) 23. Fuel
(48) 24. Fuel inlet
(49) 25. Grate device
(50) 26. Ash outlet
(51) 27. Flow generator
(52) 28. Oxidation inlet
(53) 29. Cooling inlet
(54) 30. Return conduit