Method of producing honeycomb green body or fired article, bearer and method of producing the same
11459180 · 2022-10-04
Assignee
Inventors
Cpc classification
B28B3/269
PERFORMING OPERATIONS; TRANSPORTING
B28B11/16
PERFORMING OPERATIONS; TRANSPORTING
B65G29/00
PERFORMING OPERATIONS; TRANSPORTING
B65G31/00
PERFORMING OPERATIONS; TRANSPORTING
B28B13/04
PERFORMING OPERATIONS; TRANSPORTING
C04B38/0009
CHEMISTRY; METALLURGY
International classification
B28B13/04
PERFORMING OPERATIONS; TRANSPORTING
B28B11/16
PERFORMING OPERATIONS; TRANSPORTING
B65G29/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A bearer for bearing a honeycomb green body includes a solid main body provided with a groove in which a concave arc surface extends along one direction; and a single-layer or multi-layer sponge layer attached to the arc surface of the groove. The sponge layer is curved along the arc surface of the groove and has a bearing surface curved along the arc surface.
Claims
1. A method of producing a honeycomb green body, the method comprising: an extruder extruding through a die a honeycomb green body so that a lattice of cell-walls is formed in accordance with a structure of the die, the lattice of cell-walls defining a plurality of cells extending in an extrusion direction of the honeycomb green body by the extruder, the number of cells per 1 cm.sup.2 in a plane perpendicular to the extrusion direction being 30 to 180, and a thickness of the cell-walls being 0.05 to 0.30 mm; and a bearer bearing at a vertically downward position the honeycomb green body extruded from the extruder, wherein the bearer comprises: a solid main body provided with a groove in which an arc surface recessed vertically downward extends along the extrusion direction, the solid main body including chemical wood; and a single-layer or multi-layer sponge layer attached to the arc surface of the groove, the sponge layer being curved along the arc surface of the groove and having a bearing surface curved along the arc surface.
2. The method of producing a honeycomb green body according to claim 1, wherein the sponge layer includes at least urethane or polyethylene.
3. The method of producing a honeycomb green body according to claim 1, wherein the sponge layer is an open cell sponge layer.
4. The method of producing a honeycomb green body according to claim 1, wherein a value of 25% hardness of the bearing surface of the sponge layer based on JIS K 6401 standard is equal to or less than 130N.
5. The method of producing a honeycomb green body according to claim 1, wherein a thickness of the sponge layer is between 10 mm and 20 mm.
6. The method of producing a honeycomb green body according to claim 1, wherein shore hardness of the arc surface is 40 to 70 HS.
7. The method of producing a honeycomb green body according to claim 1, wherein the maximum depth of the groove is equal to or greater than 35 cm.
8. The method of producing a honeycomb green body according to claim 1, wherein the sponge layer of a single layer is provided onto the recessed arc surface of the solid main body.
9. The method of producing a honeycomb green body according to claim 1, further comprising: cutting the honeycomb green body borne by the bearer.
10. The method of producing a honeycomb green body according to claim 1, wherein a density of the solid main body is in a range of 0.1 g/cm.sup.3 to 0.65 g/cm.sup.3.
11. The method of producing a honeycomb green body according to claim 1, wherein a diameter of the honeycomb green body is equal to or greater than 70 cm.
12. The method of producing a honeycomb green body according to claim 11, wherein the diameter of the honeycomb green body is equal to or greater than 115 cm.
13. The method of producing a honeycomb green body according to claim 12, wherein the diameter of the honeycomb green body is equal to or greater than 170 cm.
14. A method of producing a honeycomb fired article including: an extruder extruding through a die a honeycomb green body so that a lattice of cell-walls is formed in accordance with a structure of the die, the lattice of cell-walls defining a plurality of cells extending in an extrusion direction of the honeycomb green body by the extruder, the number of cells per 1 cm.sup.2 in a plane perpendicular to the extrusion direction being 30 to 180, and a thickness of the cell-walls being 0.05 to 0.30 mm; a bearer bearing at a vertically downward position the honeycomb green body extruded from the extruder, and firing the honeycomb green body, wherein the bearer comprises: a solid main body provided with a groove in which an arc surface recessed vertically downward extends along the extrusion direction, the solid main body including chemical wood; and a single-layer or multi-layer sponge layer attached to the arc surface of the groove, the sponge layer being curved along the arc surface of the groove and having a bearing surface curved along the arc surface.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Hereinafter, non-limiting embodiments of the present disclosure will be described with reference to
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DETAILED DESCRIPTION OF THE INVENTION
(10) In the following descriptions, a plurality of features described for a bearer, a method of producing the same, a method of producing a honeycomb green body would be understood as individual features independent to other features, additionally to as combination with other features. The respective features would be understood as individual features without requiring combination with other features, but could be understood as combination with one or more other features. Describing all combinations of individual features would be redundant for a skilled person, and thus omitted. The individual features would be identified by a language of “In some cases”. The individual features would be understood as a universal feature that is effective not only to a bearer, a method of producing the same, a method of producing a honeycomb green body disclosed in the present application, but also effective to other various bearers, methods of producing the same, methods of producing a honeycomb green body not particularly described in the present specification.
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(12) A method of producing a honeycomb green body 90 according to the present disclosure includes a step in which an extruder 10 extrudes through its die 19 a honeycomb green body 90, and a step in which a bearer 20 bears at a vertically downward position the honeycomb green body 90 extruded from the extruder 10. The produced honeycomb green body 90 extends along a predetermined direction (Z-axis in
(13) Note that, in
(14) Raw material fed into the extruder 10 is a clay and is, in some cases, a clay including a raw material that will be cordierite (2MgO2Al.sub.2 O.sub.3 5SiO.sub.2) through being fired. The clay may include an organic binder and a dispersion medium such as water which will be removed through a step of degreasing. Therefore, the honeycomb green body 90 extruded from the extruder 10 has a soft clayey. The raw material that will be cordierite (2MgO2Al.sub.2 O.sub.3 5SiO.sub.2) through being fired may be referred as a cordierite precursor. The cordierite precursor has a chemical composition which includes 40-60 mass % of silica, 15-45 mass % of alumina, and 5-30 mass % of magnesia. The cordierite precursor may be a mixture of plural inorganic raw materials selected from a group consisting of talc, kaolin, calcined kaolin, alumina, aluminum hydroxide, and silica. The organic binder may include at least one material selected from a group consisting of agar, hydroxypropylmethylcellulose, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, and polyvinyl alcohol. When a ceramic molded green body includes a cordierite precursor, a firing temperature may be set between 1380-1450° C. or 1400-1440° C. A time window of firing may be 3-10 hours.
(15) Raw material fed into the extruder 10 includes at least ceramic powder, water and binder. Additionally or alternatively, the raw material is a slurry in which ceramic powder, water and binder are mixed. The ceramic powder may be at least one selected from a group consisting of cordierite precursor, silicon carbide, silicon-silicon carbide based composite material, mullite, alumina, aluminum titanate, silicon nitride, and cordierite-silicon carbide based composite material. Use of these material would enhance mechanical strength and heat-resistance. In a case where cordierite is used for the cell-walls 91, 92 of the honeycomb green body 90, a honeycomb structure with low coefficient of thermal expansion and superior heat-shock resistance property would be obtained. Note that, the “silicon-silicon carbide based composite material” is a material formed using silicon carbide (SiC) as an aggregate and silicon (Si) as a bonding material.
(16) The bearer 20 according to the present disclosure has a solid main body 21 provided with a groove 24 in which a concave arc surface 22 extends along one direction, and a sponge layer 25 attached to the arc surface 22 of the groove 24. The sponge layer 25 can be single-layer or multi-layer. The sponge layer 25 is curved along the arc surface 22 of the groove 24 and has a bearing surface 26 curved along the arc surface 22. Such a bearer 20 would allow easier process and higher accuracy for approximating the surface shape or curvature of the bearing surface 26 of the bearer 20 to a target surface shape or curvature. The sponge layer 25 is an elastic porous plastic layer. Therefore, impact caused when the outer peripheral wall 94 of the honeycomb green body 90 touches the bearing surface 26 of the sponge layer 25 is absorbed by elastic deformation of the sponge layer 25, thus avoiding or suppressing a local deformation in the inward region of the honeycomb green body 90 relative to the outer peripheral wall 94.
(17) The target surface shape or curvature of the bearing surface 26 would be determined geometrically based on the surface shape or curvature of the outer peripheral surface 95 of the honeycomb green body 90. In some cases where the honeycomb green body 90 is shaped like a cylinder, the target value of curvature of the bearing surface 26 would be slightly less than the curvature of the outer peripheral surface 95 of the honeycomb green body 90. Note that, when the bearer 20 bears a honeycomb green body 90 extruded from the extruder 10, an extending direction of the groove 24 is parallel to the extrusion direction of the honeycomb green body 90 by the extruder 10, and thus it could be said that the groove 24 extends along the extrusion direction.
(18) The solid main body 21 is more suitable to be machined than the sponge layer 25. Therefore, the groove 24, in turn the arc surface 22 could be highly precisely formed in the solid main body 21. The single-layer or multi-layer sponge layer 25 is attached to such a highly surface-controlled arc surface 22, allowing the sponge layer 25 to be curved along the arc surface 22. As a result, a bearing surface 26 can be formed that is curved along the arc surface 22 of the solid main body 21. The arc surface 22 can be formed precisely, and variation in thickness of the sponge layer 25 would be within a given tolerance range. Therefore, the surface shape or curvature of the bearing surface 26 can be closer to a target surface shape or curvature. Also, the surface shape or curvature of the bearing surface 26 of the sponge layer 25 can be finely set by relatively simple process such as attaching the sponge layer 25 on to the solid main body 21. Note that, the sponge layer 25 may be attached to the solid main body 21 via adhesive or double-face adhesive tape. Also considered may be influences that the thickness of the adhesive or the thickness of the double-face adhesive tape gives to the surface shape or curvature of the bearing surface 26.
(19) It may be envisioned that water content of the raw material fed into the extruder 10 would be lowered to avoid or suppress the inward (radially inward) local deformation of the honeycomb green body relative to the outer peripheral wall. However, in such a case, porosity of a honeycomb fired article obtained by firing the honeycomb green body may be lowered, and therefore it would never be employed as a fundamental solution. The honeycomb fired article may be used as an exhaust gas purifying product, for example.
(20) In connection with the honeycomb green body 90, the number of cells per 1 cm.sup.2 in a plane perpendicular to the extrusion direction of the honeycomb green body 90 by the extruder 10 may be 30 to 180, and the thickness of the cell-wall 91, 92 may be 0.05 to 0.30 mm. The thickness of the cell-wall can be measured by an image analyzer (Product Name “NEXIV, VMR-1515” produced by Nikon), for example. In some cases, the number of cells per 1 cm.sup.2 is equal to or less than 150, or the number of cells per 1 cm.sup.2 is equal to or less than 93, or the number of cells per 1 cm.sup.2 is equal to or less than 62. In some cases, the thickness of the cell-wall 91, 92 is equal to or less than 0.30 mm or 0.1 mm or 0.08 mm. Honeycomb green bodies 90 with such a thinner cell-wall thickness and larger cell size may be well borne by the bearer 20 of the present disclosure, avoiding or suppressing reduction of production yield.
(21) In some cases, a width or diameter perpendicular to the extending direction (z-axis in
(22) The solid main body 21 may include or consist of material that allows accurate machining for the surface shape or curvature of the arc surface 22 of the groove 24. For example, the solid main body 21 includes or consists of at least one material selected from a group consisting of a styrene-foam, porous polyurethane resin, and chemical wood. Shore hardness of the arc surface 22 of the groove 24 of the solid main body 21 may be 40 to 70 HS. The sponge layer 25 would be suitably attached to the arc surface 22 having an appropriate hardness. Density of the solid main body 21 may be in a range of 0.1 g/cm.sup.3 to 0.65 g/cm.sup.3.
(23) The maximum depth D24 of the groove 24 may be equal to or greater than 35 cm. The maximum depth D24 of the groove 24 depends simply on a width or diameter of the honeycomb green body 24 to be borne by the bearer 20. The great maximum depth D24 of the groove 24 is an indication of difficulty for the bearer 20 to bear the honeycomb green body 90 without the local deformation.
(24) The sponge layer 25 may include or consist of soft or flexible material that allows the sponge layer 25 to have a bearing surface 26 curved along the arc surface 22 of the solid main body 21. The sponge layer 25 includes or consists of at least urethane or polyethylene. The sponge layer 25 may be an open cell sponge layer. The sponge layer 25 may be a urethane foam layer or polyethylene foam layer. The sponge layer 25 may be a sponge rubber layer. The sponge rubber includes or consists of at least one material selected from a group consisting of urethane rubber, nitrile rubber, chloroprene rubber, ethylene rubber, silicone rubber, and fluorine rubber.
(25) Density or porosity may also be set appropriately for realizing suitable softness or elasticity of the sponge layer 25. For example, the sponge layer 25 may have a density of 10-40 g/cm.sup.3. The density of the sponge layer 25 is 10-30 g/cm.sup.3 or 10-15 g/cm.sup.3 in some cases.
(26) Hardness of the bearing surface 26 of the sponge layer 25 is desired to be set appropriately. In some cases, a value of 25% hardness of the bearing surface 26 of the sponge layer 25 based on JIS K 6401 standard is equal to or less than 130N, preferably equal to or less than 60N. The 25% hardness is a measurement of load (Newton) when 25% thickness is maintained for 20 seconds relative to the original thickness while the sponge layer 25 is pressed, after the sponge layer 25 is firstly compressed to 75% thickness of the original thickness and the sponge layer 25 recovers to its original shape.
(27) The thickness W25 of the sponge layer 25 may be equal to or greater than 10 mm or 20 mm. If the thickness of the sponge layer 25 is too thin, there is a possibility that sufficient shock absorbing ability of the sponge layer 25 cannot be obtained. If the thickness of the sponge layer 25 is too thick, there is a possibility that a difference between the curvature of the arc surface 22 and the curvature of the bearing surface 26 can be larger.
(28) If a single-layer sponge layer 25 is arranged onto the concave arc surface 22 of the solid main body 21, process of producing the bearer 20 would be simplified, and the surface shape or curvature of the bearing surface 26 would be easily brought closer to a target surface shape or curvature.
(29) The process of producing a honeycomb green body may further include cutting the honeycomb green body 90 borne by the bearer 20. The honeycomb green body 90 may be cut by a wire hung by a pair of bobbins 32 (See
(30) With reference to
(31) As shown in
(32) As shown in
(33) As shown in
(34) As shown in
(35) Method of producing a bearer 20 for bearing a honeycomb green body 90 will be described with reference to
(36) In some cases, the sponge layer 25 in a flat state is laminated onto the sheet member 28 in a flat state. This would effectively suppress a variation in thickness of the sponge layer 25 in a plane.
(37) Length L25 of the sponge layer 25 shown in
(38) Method of producing a bearer 20 may additionally include a step of peeling the sheet member 28 off the sponge layer 25 that has been attached to the arc surface 22 (See
(39) The sheet member 28 may be a flexible solid or non-porous rubber sheet and optionally has a thickness of 0.2-1.0 mm. The sponge layer 25 may be laminated onto the sheet member 28 via a double-face adhesive tape having a lower adhesion and the like. In contrast, the sponge layer 25 is relatively firmly laminated onto the arc surface 22 of the solid main body 21 via an adhesive or a double-face adhesive tape. Therefore, the sheet member 28 can be smoothly or easily peeled off the sponge layer 25 (See
Working Example
(40) In a working example, the honeycomb green body extruded from the extruder had 93 cells per 1 cm.sup.2 and 0.064 mm of cell-wall thickness. Diameter perpendicular to the extending direction (z-axis in
(41) TABLE-US-00001 CHART 1 Material of Density of Thickness of 25% sponge layer sponge layer sponge layer hardness Working urethane 13 g/cm.sup.3 10 mm 59N example 1 Working urethane 20 g/cm.sup.3 10 mm 110N example 2 Working urethane 26 g/cm.sup.3 10 mm 130N example 3
(42) TABLE-US-00002 CHART 2 Material of solid Density of solid Maximum Shore main body main body Depth hardness Working Chemical Wood 0.55 g/cm.sup.3 108 mm 55HS example 1 Working Chemical Wood 0.55 g/cm.sup.3 108 mm 55HS example 2 Working Chemical Wood 0.55 g/cm.sup.3 108 mm 55HS example 3
(43) TABLE-US-00003 CHART 3 Yield Rate Working 100% example 1 Working 100% example 2 Working 100% example 3 Comparative 0% example 1
(44) Based on the above teachings, a skilled person would be able to add various modifications to the respective embodiments.