COMPOSITION FOR DYEING KERATIN FIBERS AND USE THEREOF

Abstract

A dye package comprises: (A) a dyeing composition comprising: (I) a colorant composition comprising at least one oxidative dye(s); and (II) a developer composition comprising at least one oxidant; and (B) an AMPS composition, wherein the AMPS composition is placed in a chamber separate from the dyeing composition (A).

Claims

1: A dye package comprising: (A) a dyeing composition (A) comprising: (I) a colorant composition (I), comprising: i) at least one oxidative dye(s); and (II) a developer composition (II), comprising: ii) at least one oxidant; and (B) an AMPS composition (B) comprising an AMPS polymer; wherein the AMPS composition (B) is placed in a chamber separate from the dyeing composition (A).

2: The dye package according to claim 1, wherein the developer composition (II) is placed separate from the colorant composition (I).

3: The dye package according to claim 1, wherein the oxidative dye comprises one or more oxidation bases selected from the group consisting of para-phenylenediamines, bis(phenyl)alkylenediamines, para-aminophenols, meta-aminophenols, ortho-aminophenols, heterocyclic bases, and the addition salts thereof, and mixtures thereof; and/or wherein the oxidative dye further comprises one or more couplers to be combined with the oxidation base, which is selected from the group consisting of meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene-based couplers heterocyclic couplers, and the addition salts thereof, and mixtures thereof.

4: The dye package according to claim 1, wherein the colorant composition (I) further comprises a reducer for use as an antioxidant, which is selected from the group consisting of thioglycolic acid, dithio glycolic acid, thiolactic acid, thiomalic acid, the salts thereof, and a mixture thereof; and/or wherein the colorant composition (I) comprises a further antioxidant selected from a natural exogenous phytochemical antioxidant, flavonoid, vitamin such as vitamin C and/or E and a derivative thereof, tocopherols, tocotrienol phenol, carotenoid, anthocyanin, dihydrochalcone, phenylpropanoid, chalcone, curcuminoid, tannin, stilbenoid, coumarin, carotenoid, or a mixture thereof.

5: The dye package according to claim 1, wherein the antioxidant is used in an amount of from 0.001 to 10% by weight relative to the total weight of the colorant composition (I).

6: The dye package according to claim 1, wherein the oxidative dye comprises one or more oxidation bases in an amount from 0.0001% to 10% by weight relative to the total weight of the composition (I); and/or the oxidative dye further comprises one or more couplers in an amount from 0.0001% to 10% by weight relative to the total weight of the composition (I).

7: The dye package according to claim 1, wherein the oxidant is selected from the group consisting of hydrogen peroxide, urea peroxide, alkali metal bromates, peroxy salts; and a polymer type complex capable of releasing hydrogen peroxide.

8: The package according to claim 1, wherein the concentration of the oxidant is from 0.1% by weight to 50% by weight based on the weight of the composition (II).

9: The package according to claim 1, wherein the AMPS composition (B) comprises an AMPS polymer, optionally crosslinked comprising at least the acrylamido-2-methylpropanesulfonic acid monomer.

10: The package according to claim 9, wherein the AMPS polymer is selected from sodium acrylamido-2-methylpropanesulfonate homopolymer, or ammonium polyacryloyldimethyl taurate homopolymer, AMPS/hydroxyethyl acrylate copolymer, or ammonium acryloyldimethyltaurate/steareth-25 methacrylate crosspolymer.

11: The package according to claim 9, wherein the AMPS polymer is present in amounts ranging from 0.01% to 10% by weight by weight relative to the total weight of the composition (I) and/or the composition (II).

12: The package according to claim 1, wherein the colorant composition (I) and the developer composition (II) are used at a ratio by weight of 1:3 to 3:1.

13: A process of slowing down reactions of dye or intermediates thereof, characterized in mixing an AMPS polymer with the dye.

14: The process according to claim 13, wherein the AMPS polymer is mixed with the dye before application of the dye, or the AMPS polymer is applied to the position to which the dye has been applied for less than 10 minutes.

15: A process of dyeing keratin fibers, comprising applying a composition to the keratin fibers, wherein the composition comprises an AMPS polymer.

16: A method for reducing stain of a dye, comprising addition of an AMPS polymer.

17: A composition for dyeing keratin fibers, while reducing the stain in areas other than the keratin fibers, wherein the composition comprises an AMPS polymer

Description

EXAMPLES

[0309] The ingredient amounts/concentrations in the compositions/formulas described below are expressed in 0 by weight, relative to the total weight of each composition/formula.

Example 1

[0310] The colorant composition I-A hereinafter was prepared, from the ingredients indicated in the table 1 below (in which the contents were indicated in wt % of materials with regard to the total weight of the composition):

TABLE-US-00001 TABLE 1 Ingredients I-A Thioglycolic acid 0.6 Ammonium hydroxide 5 Erythorbic acid 2.5 Sodium metabisulfite 1.3 Ethanolamine 1.2 Edta 0.2 2,4-diaminophenoxyethanol HCl 0.03 Resorcinol 0.3 M-aminophenol 0.1 P-phenylenediamine 1. Phenyl methyl pyrazolone 0.6 Glycol distearate 2 Cetearyl alcohol 11.5 Fragrance 0.70 Hexadimethrine chloride 5 Polyquaternium-22 3.7 Propylene glycol 10 Lauric acid 3 Laureth-12 7 Deceth-3 10 oleth-30 4 Water QS

[0311] The developer compositions II-A-C hereinafter were prepared, from the ingredients indicated in the table 2 below (in which the contents were indicated in wt % of materials with regard to the total weight of the composition), and a comparative developer composition II-D, which did not comprise the AMPS, was also prepared:

TABLE-US-00002 TABLE 2 Ingredients II-A II-B II-C II-D Hydrogen peroxide 12 12 12 12 Tetrasodium etidronate 0.2 0.2 0.2 0.2 Tetrasodium pyrophosphate 0.04 0.04 0.04 0.04 Ammonium polyacryloyldimethyl taurate 1 2 3 0 (AMPS) Sodium salicylate 0.04 0.04 0.04 0.04 Glycerin 0.5 0.5 0.5 0.5 Trideceth-2 carboxamide mea 1 1 1 1 Cetearyl alcohol (and) ceteareth-25 3 3 3 3 Water QS to QS to QS to QS to 100 100 100 100

Example 2

[0312] Other colorant compositions I-B and I-C hereinafter were prepared, from the ingredients indicated in the table 3 below (in which the contents were indicated in wt % of materials with regard to the total weight of the composition):

TABLE-US-00003 TABLE 3 Ingredients I-B I-C SODIUM LAURYL SULFATE 1.24 MINERAL OIL/PARAFFINUM LIQUIDUM 60. SODIUM METABISULFITE 1 1 2,4-DIAMINOPHENOXYETHANOL HCl 0.1 0.1 ERYTHORBIC ACID 2 2 CAPRYLYL/CAPRYL GLUCOSIDE 5 TOLUENE-2,5-DIAMINE (and) THIOGLYCERIN 2 2 THIOGLYCOLIC ACID 0.5 0.5 ETHANOLAMINE 3.3 3.3 RESORCINOL 0.8 0.8 p-AMINOPHENOL (and) SODIUM METABISULFITE 0.5 0.5 2-METHYLRESORCINOL 0.3 0.3 PHENYL METHYL PYRAZOLONE 0.5 0.5 EDTA 0.2 0.2 HYDROXYPROPYL GUAR 1 SODIUM POLYACRYLOYLDIMETHYL TAURATE 1 1 GLYCERIN 5 SODIUM LAURETH SULFATE 2 ACRYLATES/PALMETH-25 ACRYLATE COPOLYMER 3.5 WATER/AQUA QS QS

Example 3

[0313] For application, composition I-A was mixed with compositions II-A˜D with a weight ratio of 1:1.5, to provide mixtures A-D. 20 g of the mixtures A-D were each poured in the palm of the hair dressers, who applied the products (mixtures A-D) immediately onto the middle-length hair, i.e., hair length was at the shoulder. The hair was massaged and foam was formed.

[0314] At the time of 0, 2.5, 5, 7.5 and 10 minutes, the hair was taken a picture, respectively. As shown in FIG. 1, it was clear to see that at each time point, the hair dyed with the mixtures A˜C comprising AMPS had a color lighter than that dyed with mixture D without AMPS. That is, clear water effects were observed for the mixture D, which represented combinations of composition I-A with composition II-A˜C, respectively, compared with mixture D.

[0315] Similarly, compositions I-B and I-C, in combination with composition II-A, were subjected to an application same as that for composition I-A, and clear water effects were also observed.