Crosslinkable Polymeric Composition and Coated Conductor

Abstract

Provided is a composition, which contains (A) a silane functionalized ethylene-based polymer, (B) a hindered phenol antioxidant, and (C) an aromatic amine-aromatic sulfonic acid salt. A coated conductor including a conductor and a coating which contains said composition on the conductor is also provided.

Claims

1. A composition comprising: (A) a silane functionalized ethylene-based polymer; (B) a hindered phenol antioxidant; and (C) an aromatic amine-aromatic sulfonic acid salt.

2. The composition of claim 1, wherein the aromatic amine-aromatic sulfonic acid salt has a Structure (I) ##STR00024## wherein Y is an integer from 1 to 3; R.sup.1 is selected from the group consisting of an aryl group, a substituted aryl group, an alkyl group, or a substituted alkyl group; R.sup.2 is selected from the group consisting of an aryl group, and a substituted aryl group; R.sup.3 is selected from the group consisting of an aryl group, a substituted aryl group, an alkyl group, a substituted alkyl group, or hydrogen; R.sup.4 is selected from the group consisting of an aryl group, and a substituted aryl group; and X is an integer from 1 to 4.

3. The composition of claim 1, wherein the aromatic amine-aromatic sulfonic acid salt has a molar ratio of sulfur to nitrogen of 1:1.

4. The composition of claim 1, wherein the silane functionalized polyolefin is selected from the group consisting of a silane-grafted ethylene-based polymer and an ethylene/silane copolymer.

5. The composition of claim 1, comprising (A) from 30 wt % to 99 wt % silane functionalized ethylene-based polymer; (B) from 0.03 wt % to 1 wt % hindered phenol antioxidant; and (C) from 0.05 wt % to 5 wt % aromatic amine-aromatic sulfonic acid salt.

6. The composition of claim 1, wherein the composition is crosslinkable.

7. The composition of claim 1, wherein the composition has a hot creep after curing in a water bath at 90° C. for 3 hours of less than 100%.

8. The composition of claim 1, wherein the composition has a hot creep after curing in ambient environment for 168 hours of less than 100%.

9. The composition of claim 1, wherein the composition exhibits an isobutylene reduction of at least 50% compared to the same composition containing the aromatic sulfonic acid of the aromatic amine-aromatic sulfonic acid salt, instead of the salt.

10. A coated conductor comprising a conductor; and a coating on the conductor, the coating comprising the composition of claim 9.

11. A process for moisture curing a silane functionalized ethylene-based polymer comprising: (A) providing an aromatic amine-aromatic sulfonic acid salt; (B) mixing the aromatic amine-aromatic sulfonic acid salt with a hindered phenol antioxidant to form a catalyst composition; (C) contacting a silane functionalized ethylene-based polymer with the catalyst composition to form a crosslinkable composition; and (D) exposing the crosslinkable composition to moisture cure conditions to form a crosslinked composition.

12. The process of claim 11, wherein the (B) mixing and the (C) contacting occur simultaneously.

13. The process of claim 11, wherein the (B) mixing comprises forming a masterbatch comprising the aromatic amine-aromatic sulfonic acid salt; the hindered phenol antioxidant; and a carrier polyolefin.

14. The process of claim 11 comprising (A) providing the aromatic amine-aromatic sulfonic acid salt having a Structure (I) ##STR00025## wherein Y is an integer from 1 to 3; R.sup.1 is selected from the group consisting of an aryl group, a substituted aryl group, an alkyl group, or a substituted alkyl group; R.sup.2 is selected from the group consisting of an aryl group, and a substituted aryl group; R.sup.3 is selected from the group consisting of an aryl group, a substituted aryl group, an alkyl group, a substituted alkyl group, or hydrogen; R.sup.4 is selected from the group consisting of an aryl group, and a substituted aryl group; and X is an integer from 1 to 4.

15. The process of claim 11 comprising (A) providing the aromatic amine-aromatic sulfonic acid salt having a molar ratio of sulfur to nitrogen of 1:1.

Description

DETAILED DESCRIPTION

[0050] The present disclosure provides a composition. The composition contains (A) a silane functionalized ethylene-based polymer, (B) a hindered phenol antioxidant, and (C) an aromatic amine-aromatic sulfonic acid salt.

[0051] In an embodiment, the (C) aromatic amine-aromatic sulfonic acid salt has the following Structure (I):

##STR00001##

wherein Y is an integer from 1 to 2, or 3; R.sup.1 is selected from an aryl group, a substituted aryl group, an alkyl group, or a substituted alkyl group; R.sup.2 is selected from an aryl group, and a substituted aryl group; R.sup.3 is selected from an aryl group, a substituted aryl group, an alkyl group, a substituted alkyl group, or hydrogen; R.sup.4 is selected from an aryl group, and a substituted aryl group; and X is an integer from 1 to 2, or 3, or 4.

[0052] A. Silane Functionalized Ethylene-Based Polymer

[0053] The composition includes a silane functionalized ethylene-based polymer. A “silane functionalized ethylene-based polymer” is a polymer that contains silane and equal to or greater than 50 wt %, or a majority amount, of polymerized ethylene, based on the total weight of the polymer. Nonlimiting examples of suitable silane functionalized polyolefin include ethylene/silane copolymer, silane-grafted polyethylene (Si-g-PE), and combinations thereof.

[0054] An “ethylene/silane copolymer” is formed by the copolymerization of ethylene and a hydrolysable silane monomer (such as a vinyl alkoxysilane monomer). In an embodiment, the ethylene/silane copolymer is prepared by the copolymerization of ethylene, a hydrolysable silane monomer and, optionally, an unsaturated ester. The preparation of ethylene/silane copolymers is described, for example, in U.S. Pat. Nos. 3,225,018 and 4,574,133, each incorporated herein by reference.

[0055] A “silane-grafted polyethylene” (or “Si-g-PE”) is formed by grafting a hydrolysable silane monomer (such as a vinyl alkoxysilane monomer) onto the backbone of a base polyethylene. In an embodiment, grafting takes place in the presence of a free-radical generator, such as a peroxide. The hydrolysable silane monomer can be grafted to the backbone of the base polyethylene (i) prior to incorporating or compounding the Si-g-PE into a composition used to make a final article, such as a coated conductor (also known as a SIOPLAS™ process), or (ii) simultaneously with the extrusion of a composition to form a final article (also known as a MONOSIL™ process, in which the Si-g-PE is formed in situ during melt blending and extrusion). In an embodiment, the Si-g-PE is formed before the Si-g-PE is compounded with aromatic amine-aromatic sulfonic acid salt, hindered phenol antioxidant, and other optional components. In another embodiment, the Si-g-PE is formed in situ by compounding a polyethylene, hydrolysable silane monomer, and peroxide initiator, along with aromatic amine-aromatic sulfonic acid salt, hindered phenol antioxidant, and other optional components.

[0056] The base polyethylene for the Si-g-PE may be any ethylene-based polymer disclosed herein. Nonlimiting examples of suitable ethylene-based polymers include ethylene homopolymers and ethylene-based interpolymers containing one or more polymerizable comonomers, such as an unsaturated ester and/or an α-olefin. In an embodiment, the ethylene-based polymer is selected from a low density polyethylene (LDPE), a high density polyethylene (HDPE), and combination thereof.

[0057] The hydrolysable silane monomer used to make an ethylene/silane copolymer or a Si-g-PE is a silane-containing monomer that will effectively copolymerize with ethylene to form an ethylene/silane copolymer or graft to an ethylene-based polymer to form a Si-g-PE. Exemplary hydrolysable silane monomers are those having the following Structure (A):

##STR00002##

wherein R′ is a hydrogen atom or methyl group; x and y are 0 or 1 with the proviso that when x is 1, y is 1; n is an integer from 1 to 12 inclusive, or n is an integer from 1 to 4, and each R″ independently is a hydrolysable organic group such as an alkoxy group having from 1 to 12 carbon atoms (e.g., methoxy, ethoxy, butoxy), aryloxy group (e.g., phenoxy), aralkoxy group (e.g., benzyloxy), aliphatic acyloxy group having from 1 to 12 carbon atoms (e.g., formyloxy, acetyloxy, propanoyloxy), amino or substituted amino groups (alkylamino, arylamino), or a lower alkyl group having 1 to 6 carbon atoms inclusive, with the proviso that not more than one of the three R″ groups is an alkyl.

[0058] Nonlimiting examples of suitable hydrolysable silane monomers include silanes that have an ethylenically unsaturated hydrocarbyl group, such as vinyl, allyl, isopropenyl, butenyl, cyclohexenyl or gamma-(meth)acryloxy allyl group, and a hydrolysable group, such as, for example, a hydrocarbyloxy, hydrocarbonyloxy, or hydrocarbylamino group. Examples of hydrolysable groups include methoxy, ethoxy, formyloxy, acetoxy, propionyloxy, and alkyl or arylamino groups.

[0059] In an embodiment, the hydrolysable silane monomer is an unsaturated alkoxy silane such as vinyl trimethoxy silane (VTMS), vinyl triethoxy silane, vinyl triacetoxy silane, gamma-(meth)acryloxy, propyl trimethoxy silane, and mixtures of these silanes.

[0060] Nonlimiting examples of suitable unsaturated esters used to make an ethylene/silane copolymer include alkyl acrylate, alkyl methacrylate, or vinyl carboxylate. Nonlimiting examples of suitable alkyl groups include methyl, ethyl, n-propyl, i-propyl, n-butyl, t-butyl, etc. In an embodiment, the alkyl group has from 1, or 2 to 4, or 8 carbon atoms. Nonlimiting examples of suitable alkyl acrylates include ethyl acrylate, methyl acrylate, t-butyl acrylate, n-butyl acrylate, and 2-ethylhexyl acrylate. Nonlimiting examples of suitable alkyl methacrylates include methyl methacrylate and n-butyl methacrylate. In an embodiment, the carboxylate group has from 2 to 5, or 6, or 8 carbon atoms. Nonlimiting examples of suitable vinyl carboxylates include vinyl acetate, vinyl propionate, and vinyl butanoate.

[0061] In an embodiment, the silane functionalized ethylene-based polymer contains from 0.1 wt %, or 0.5 wt %, or 1.0 wt %, or 1.5 wt % to 2.0 wt %, or 2.5 wt % or 3.0 wt %, or 4.0 wt %, or 5.0 wt % silane, based on the total weight of the silane functionalized ethylene-based polymer.

[0062] In an embodiment, the silane functionalized ethylene-based polymer contains, consists essentially of or consists of: (i) from 50 wt %, or 60 wt %, or 70 wt %, or 80 wt %, or 90 wt %, or 95 wt % to 97 wt %, or 98 wt %, or 99 wt %, or less than 100 wt % ethylene; and (ii) a reciprocal amount of silane, or from greater than 0 wt %, or 1 wt %, or 2 wt %, or 3 wt %, to 5 wt %, or 10 wt %, or 20 wt %, or 30 wt %, or 40 wt %, or 50 wt % silane, based on the total weight of the silane functionalized ethylene-based polymer.

[0063] In an embodiment, the silane functionalized ethylene-based polymer has a density from 0.850 g/cc, or 0.910 g/cc, or 0.920 g/cc to 0.922 g/cc, 0.925 g/cc, or 0.930 g/cc, or 0.950 g/cc, or 0.965 g/cc. In another embodiment, the silane functionalized ethylene-based polymer has a density from 0.850 g/cc to 0.965 g/cc, or from 0.900 g/cc to 0.950 g/cc, or from 0.920 g/cc to 0.925 g/cc.

[0064] In an embodiment, the silane functionalized ethylene-based polymer has a melt index (MI) from 0.1 g/10 min, or 0.5 g/10 min, or 1.0 g/10 min, or 1.5 g/10 min to 2 g/10 min. or 5 g/10 min. or 10 g/10 min, or 15 g/10 min, or 20 g/10 min, or 30 g/10 min, or 40 g/10 min, or 50 g/10 min. In another embodiment, the functionalized ethylene-based polymer has a melt index (MI) from 0.1 g/10 min to 50 g/10 min, or from 0.5 g/10 min to 10 g/10 min, or from 0.5 g/10 min to 5 g/10 min.

[0065] In an embodiment, the silane functionalized ethylene-based polymer is an ethylene/silane copolymer. The ethylene/silane copolymer contains ethylene and the hydrolyzable silane monomer as the only monomeric units. In another embodiment, the ethylene/silane copolymer optionally includes a C.sub.3, or C.sub.4 to C.sub.6, or C.sub.8, or C.sub.10, or C.sub.12, or C.sub.16, or C.sub.18, or C.sub.20 α-olefin; an unsaturated ester, and combinations thereof. In an embodiment, the ethylene/silane copolymer is an ethylene/unsaturated ester/silane reactor copolymer. Nonlimiting examples of suitable ethylene/silane copolymers include SI-LINK™ DFDA-5451 NT and SI-LINK™ AC DFDB-5451 NT, each available from The Dow Chemical Company.

[0066] The ethylene/silane reactor copolymer may comprise two or more embodiments disclosed herein.

[0067] In an embodiment, the silane functionalized ethylene-based polymer is a Si-g-PE.

[0068] The base ethylene-based polymer for the Si-g-PE includes from 50 wt %, or 55 w %, or 60 wt %, or 65 wt %, or 70 wt %, or 80 wt %, or 90 wt %, or 95 wt % to 97 wt %, or 98 wt %, or 99 wt %, or 100 wt % ethylene, based on the total weight of the base ethylene-based polymer.

[0069] In an embodiment, the base ethylene-based polymer for the Si-g-PE is an ethylene/α-olefin copolymer. The α-olefin contains from 3, or 4 to 6, or 8, or 12, or 20 carbon atoms. Nonlimiting examples of suitable α-olefin include propylene, butene, hexene, and octene. In an embodiment, the ethylene-based copolymer is an ethylene/octene copolymer. When the ethylene-based copolymer is an ethylene/α-olefin copolymer, the Si-g-PE is a silane-grafted ethylene/α-olefin copolymer. Nonlimiting examples of suitable ethylene/α-olefin copolymers useful as the base ethylene-based polymer for the Si-g-PE include the ENGAGE™ and INFUSE™ resins available from the Dow Chemical Company.

[0070] Blends of silane functionalized ethylene-based polymers may also be used, and the silane-functionalized ethylene-based polymer(s) may be diluted with one or more other polyolefins to the extent that the polyolefins are (i) miscible or compatible with one another, and (ii) the silane functionalized ethylene-based polymer(s) constitutes from 30 wt %, or 40 wt %, or 50 wt %, or 55 wt %, or 60 wt %, or 70 wt %, or 80 wt %, or 90 wt %, or 95 wt %, or 99 wt % to less than 100 wt % of the blend (based on the combined weight of the polyolefins, including the silane functionalized ethylene-based polymer).

[0071] The silane functionalized ethylene-based polymer may comprise two or more embodiments disclosed herein.

[0072] B. Hindered Phenol Antioxidant

[0073] The composition contains a hindered phenol antioxidant.

[0074] A “hindered phenol antioxidant” is a primary antioxidant that acts as a radical scavenger. The hindered phenol antioxidant contains a phenol group. Nonlimiting examples of suitable hindered phenol antioxidants include pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate); 1,3,5-trimethyl-2,4,6-tris-(3,5-di-tert-butyl-4-hydroxybenzyl)-benzene; pentaerythrityl tetrakis-3(3,5-di-tert-butyl-4-hydroxyphenyl)-propionate; n-octadecyl-3(3,5-di-tert-butyl-4-hydroxyphenyl)-propionate; 4,4′-methylenebis(2,6-tert-butyl-phenol); 4,4′-thiobis(6-tert-butyl-o-cresol); 2,6-di-tertbutylphenol; 6-(4-hydroxyphenoxy)-2,4-bis(n-octyl-thio)-1,3,5 triazine; di-n-octylthio)ethyl 3,5-di-tert-butyl-4-hydroxy-benzoate; and sorbitol hexa[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)-propionate]; and combinations thereof. Such hindered phenol antioxidants are commercially available from BASF and include IRGANOX™ 565, 1010, 1076 and 1726.

[0075] In an embodiment, the hindered phenol antioxidant is pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate), commercially available as IRGANOX™ 1010 from BASF.

[0076] The hindered phenol antioxidant may comprise two or more embodiments disclosed herein.

[0077] C. Aromatic Amine-Aromatic Sulfonic Acid Salt

[0078] The composition contains an aromatic amine-aromatic sulfonic acid salt.

[0079] An “aromatic amine-aromatic sulfonic acid salt,” or “AS-ASAS,” is a salt compound formed from an aromatic amine and an aromatic sulfonic acid. The AS-ASAS may be a mono-amine, a di-amine, or a tri-amine. The AS-ASAS excludes salt compounds formed from linear amines and/or branched amines. Further, the AS-ASAS excludes salt compounds formed from linear sulfonic acids and/or branched sulfonic acids.

[0080] An “aromatic amine” is a compound having the following Structure (II):

##STR00003##

wherein R.sup.5 is selected from an aryl group, a substituted aryl group, an alkyl group, or a substituted alkyl group; R.sup.6 is selected from an aryl group, and a substituted aryl group; R.sup.7 is selected from an aryl group, a substituted aryl group, an alkyl group, a substituted alkyl group, or hydrogen; and X is an integer from 1 to 2, or 3, or 4.

[0081] In an embodiment, in Structure (II), R.sup.5 is selected from a C.sub.6-C.sub.40 aryl group, a substituted C.sub.6-C.sub.40 aryl group, a C.sub.1-C.sub.40 alkyl group, or a substituted C.sub.1-C.sub.40 alkyl group; R.sup.6 is selected from a C.sub.6-C.sub.40 aryl group, and a substituted C.sub.6-C.sub.40 aryl group; R.sup.7 is selected from a C.sub.6-C.sub.40 aryl group, a substituted C.sub.6-C.sub.40 aryl group, a C.sub.1-C.sub.40 alkyl group, a substituted C.sub.1-C.sub.40 alkyl group, or hydrogen; and X is an integer from 1 to 2, or 3, or 4.

[0082] Nonlimiting examples of suitable aromatic amines include 4,4′-bis (alpha, alpha-dimethylbenzyl) diphenylamine; N1-(4-methylpentan-2-yl)-N4-phenylbenzene-1,4-diamine, N,N-diphenyl-p-phenylenediamine; di([1,1′-biphenyl]-4-yl)amine; (2,2,4-trimethyl-1,2-dihydroquinoline); 9,9-Dimethyl-9,10-dihydroacridine; N-Phenyl-2-naphthylamine; N1,N4-di(naphthalen-2-yl)benzene-1,4-diamine; N,N′-Bis-(1,4-Dimethylpentyl)-P-Phenylenediamine; N,N′-di-sec-butyl-1,4-phenylenediamine; N-Isopropyl-N′-phenyl-1,4-phenylenediamine; 6-Ethoxy-2,2,4-trimethyl-1,2-dihydroquinoline, and combinations thereof.

[0083] An “aromatic sulfonic acid” is a compound having the following Structure (III):

##STR00004##

wherein R.sup.8 is selected from an aryl group and a substituted aryl group.

[0084] Nonlimiting examples of suitable aromatic sulfonic acids include naphthalene sulfonic acid; dodecylbenzenesulfonic acid (DBSA); 4-methylbenzenesulfonic acid; naphthalene-2-sulfonic acid; 4-dodecylbenzene sulfonic acid; P-toluenesulfonic acid; 2,4,6-trimethylbenzenesulfonic acid; 2,4,6-trichlorobenzenesulfonic acid; naphthalene-2-sulfonic acid; naphthalene-1-sulfonic acid; 4-methylbenzenesulfonic acid; benzene sulfonic acid, substituted naphthalene-1-sulfonic acid, substituted naphthalene-2-sulfonic acid; 4-(tert-butyl)benzenesulfonic acid, and combinations thereof.

[0085] The AS-ASAS has the following Structure (I):

##STR00005##

wherein Y is an integer from 1 to 2, or 3; R.sup.1 is selected from an aryl group, a substituted aryl group, an alkyl group, or a substituted alkyl group; R.sup.2 is selected from an aryl group, and a substituted aryl group; R.sup.3 is selected from an aryl group, a substituted aryl group, an alkyl group, a substituted alkyl group, or hydrogen; R.sup.4 is selected from an aryl group, and a substituted aryl group; and X is an integer from 1 to 2, or 3, or 4.

[0086] In an embodiment, in Structure (I): Y is from 1 to 2; X is from 1 to 2, or from 1 to 3, or from 1 to 4; R.sup.1 is selected from a C.sub.6-C.sub.40, or C.sub.6-C.sub.20, or C.sub.6-C.sub.15, or C.sub.6 aryl group; a substituted C.sub.6-C.sub.40, or C.sub.6-C.sub.20, or C.sub.6-C.sub.15, or C.sub.6 aryl group; a C.sub.1-C.sub.40, or C.sub.1-C.sub.20, or C.sub.1-C.sub.10, or C.sub.4-C.sub.8 alkyl group; or a substituted C.sub.1-C.sub.20, or C.sub.1-C.sub.10, or C.sub.4-C.sub.8 alkyl group; R.sup.2 is selected from a C.sub.6-C.sub.40, or C.sub.6-C.sub.20, or C.sub.6-C.sub.15, or C.sub.6 aryl group; and a substituted C.sub.6-C.sub.40, or C.sub.6-C.sub.20, or C.sub.6-C.sub.15, or C.sub.6 aryl group; R.sup.3 is selected from a C.sub.6-C.sub.40, or C.sub.6-C.sub.20, or C.sub.6-C.sub.15, or C.sub.6 aryl group; a substituted C.sub.6-C.sub.40, or C.sub.6-C.sub.15, or C.sub.6C aryl group; a C.sub.1-C.sub.40, or C.sub.1-C.sub.20, or C.sub.1-C.sub.10, or C.sub.4-C.sub.8 alkyl group; a substituted C.sub.1-C.sub.40, or C.sub.1-C.sub.20, or C.sub.1-C.sub.10, or C.sub.4-C.sub.8 alkyl group; or hydrogen, and R.sup.4 is selected from a C.sub.6-C.sub.40, or C.sub.6-C.sub.20, or C.sub.6-C.sub.15, or C.sub.6 aryl group; and a substituted C.sub.6-C.sub.40, or C.sub.6-C.sub.20, or C.sub.6-C.sub.15, or C.sub.6 aryl group.

[0087] In an embodiment, the AS-ASAS has a molar ratio of sulfur to nitrogen from 0.8:1, or 1:1 to 1.3:1. In another embodiment, the AS-ASAS has a molar ratio of sulfur to nitrogen of 1:1.

[0088] Nonlimiting examples of suitable AS-ASAS are depicted below in Table C, and include the Structures (IV)-(XI), and combinations thereof.

TABLE-US-00003 TABLE C AS-ASAS Structures [00006] Structure (IV) [00007] Structure (V) [00008] Structure (VI) [00009] Structure (VII) [00010] Structure (VIII) [00011] Structure (IX) [00012] Structure (X) [00013] Structure (XI)

[0089] In an embodiment, the AS-ASAS is selected from Structure (IV), Structure (V), Structure (VI), Structure (VII), Structure (VIII), and Structure (XI).

[0090] In an embodiment, the AS-ASAS is selected from Structure (IV), Structure (V), Structure (VI), and Structure (VII).

[0091] In an embodiment, the AS-ASAS is selected from Structure (IX) and Structure (X).

[0092] In an embodiment, the AS-ASAS is selected from Structure (IV) and Structure (IX).

[0093] In an embodiment, the AS-ASAS is selected from Structure (VI), Structure (VIII), Structure (X), and Structure (XI).

[0094] The AS-ASAS is not polymeric. In other words, the AS-ASAS is void of, or substantially void of, dimers, trimers, and tetramers of the aromatic amine.

[0095] In an embodiment, the AS-ASAS is synthesized by mixing the aromatic amine with the aromatic sulfonic acid in an organic solvent or a wax, for a period of from one, or two to three, or four, or five, or six hours at room temperature (23-25° C.). Nonlimiting examples of suitable organic solvent include dichloromethane, toluene, and combinations thereof.

[0096] The aromatic amine-aromatic sulfonic acid salt (AA-ASAS) may comprise two or more embodiments disclosed herein.

[0097] D. Optional Additive

[0098] In an embodiment, the composition includes (A) the silane functionalized ethylene-based polymer, (B) the hindered phenol antioxidant, (C) the aromatic amine-aromatic sulfonic acid salt, and (D) one or more optional additives.

[0099] Nonlimiting examples of suitable optional additives include antioxidants (other than the (B) hindered phenol antioxidant), colorants, corrosion inhibitors, lubricants, wax, silanol condensation catalysts, ultra violet (UV) absorbers or stabilizers, anti-blocking agents, coupling agents, compatibilizers, plasticizers, fillers, processing aids, moisture scavengers, scorch retardants, metal deactivators, siloxanes, crosslinking coagents, extends oils, and polyolefins (other than the (A) silane functionalized ethylene-based polymer), and combinations thereof.

[0100] In an embodiment, the composition includes an antioxidant that is different than the (B) hindered phenol antioxidant. A nonlimiting example of a suitable antioxidant is a phosphite antioxidant, such as IRGAFOS™ 168, available from BASF. In an embodiment, the composition contains from 0 wt %, or 0.01 wt % to 0.5 wt %, or 1.0 wt %, or 2.0 wt %, or 3.0 wt % antioxidant, based on total weight of the composition.

[0101] In an embodiment, the composition includes a wax. The wax may be used to reduce the melt viscosity of the composition. Nonlimiting examples of suitable wax include ethylene-based polymer wax, propylene-based polymer wax, paraffin wax, microcrystalline wax, by-product polyethylene wax, Fischer-Tropsch wax, oxidized Fischer-Tropsch wax, functionalized wax such as hydroxy stearamide wax and fatty amide wax, and combinations thereof.

[0102] In an embodiment, the composition includes silanol condensation catalyst, such as Lewis and Brønsted acids and bases. A “silanol condensation catalyst” promotes crosslinking of the silanol functionalized polyolefin. Lewis acids are chemical species that can accept an electron pair from a Lewis base. Lewis bases are chemical species that can donate an electron pair to a Lewis acid. Nonlimiting examples of suitable Lewis acids include the tin carboxylates such as dibutyl tin dilaurate (DBTDL), and various other organo-metal compounds such as lead naphthenate, zinc caprylate and cobalt naphthenate. Nonlimiting examples of suitable Lewis bases include the primary, secondary and tertiary amines. These catalysts are typically used in moisture cure applications. In an embodiment, the composition includes from 0 wt %, or 0.001 wt % to 0.1 wt %, or 1.0 wt % silanol condensation catalyst, based on the total weight of the composition. During the MONOSIL™ process, the silanol condensation catalyst is typically added to the reaction-extruder so that it is present during the grafting reaction of silane to the polyolefin backbone to form the in situ Si-g-PE. As such, the silane functionalized ethylene-based polymer may experience some coupling (light crosslinking) before it leaves the extruder with the completion of the crosslinking after it has left the extruder, typically upon exposure to moisture (e.g., a sauna bath or a cooling bath) and/or the humidity present in the environment in which it is stored, transported or used.

[0103] In an embodiment, the composition includes an ultra violet (UV) absorber or stabilizer. A nonlimiting example of a suitable UV stabilizer is a hindered amine light stabilizer (HALS), such as 1,3,5-Triazine-2,4,6-triamine, N,N-1,2-ethanediylbisN-3-4,6-bisbutyl(1,2,2,6,6-pentamethyl-4-piperidinyl)amino-1,3,5-triazin-2-ylaminopropyl-N,N-dibutyl-N,N-bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-1,5,8,12-tetrakis[4,6-bis(n-butyl-n-1,2,2,6,6-pentamethyl-4-piperidylamino)-1,3,5-triazin-2-yl]-1,5,8,12-tetraazadodecane, which is commercially available as SABO™ STAB UV-119 from SABO S.p.A. of Levate, Italy. In an embodiment, the composition contains from 0 wt %, or 0.001% to 0.01 wt %, or 1.0 wt %, or 3.0 wt % UV absorber or stabilizer, based on total weight of the composition.

[0104] In an embodiment, the composition includes a metal deactivator. Metal deactivators suppress the catalytic action of metal surfaces and traces of metallic minerals. Metal deactivators convert the traces of metal and metal surfaces into an inactive form, e.g., by sequestering. Nonlimiting examples of suitable metal deactivators include 1,2-bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamoyl)hydrazine, 2,2′-oxamindo bis[ethyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], and oxalyl bis(benzylidenehydrazide) (OABH). In an embodiment, the composition contains from 0 wt %, or greater than 0 wt %, or 0.01 wt % to 0.05 wt %, or 1 wt %, or 10 wt % metal deactivator, based on the total weight of the composition.

[0105] In an embodiment, the composition includes a filler. Nonlimiting examples of suitable fillers include zinc oxide, zinc borate, zinc molybdate, zinc sulfide, carbon black, organo-clay, and combinations thereof. The filler may or may not have flame retardant properties. In an embodiment, the filler is coated with amaterial (such as stearic acid) that will prevent or retard any tendency that the filler might otherwise have to interfere with the silane cure reaction. In an embodiment, the composition contains from 0 wt %, or 0.01 wt % to 1.0 wt %, or 3.0 wt %, or 5.0 wt % filler, based on total weight of the composition.

[0106] In an embodiment, the composition includes a processing aid. Nonlimiting examples of suitable processing aids include oils, organic acids (such as stearic acid), and metal salts of organic acids (such as zinc stearate). In an embodiment, the composition contains from 0 wt %, or 0.01 wt % to 1.0 wt %, or 3.0 wt % processing aid, based on total weight of the composition.

[0107] In an embodiment, the composition includes a moisture scavenger. Moisture scavengers remove or deactivate unwanted water in the composition to prevent unwanted (premature) crosslinking and other water-initiated reactions in the composition during storage or at extrusion conditions. Nonlimiting examples of moisture scavengers include organic compounds selected from ortho esters, acetals, ketals or silanes such as alkoxy silanes. In an embodiment, the moisture scavenger is an alkoxy silane (e.g., hexadecyltrimethoxysilane). The alkoxy silane moisture scavenger is not grafted to or copolymerized with a polyolefin. The moisture scavenger is present in an amount from 0 wt %, or greater than 0 wt %, or 0.01 wt % to 0.2 wt %, or 1.0 wt %, based on the total weight of the composition.

[0108] In an embodiment, the composition includes a siloxane. A nonlimiting example of a suitable siloxane is a polydimethylsiloxane (PDMS), such as dimethylvinylsilyl terminated polydimethylsiloxane. In an embodiment, the composition contains from 0.2 wt %, or 0.5 wt % to 1.0 wt %, or 5.0 wt % siloxane, based on the total weight of the composition.

[0109] In an embodiment, the composition includes a crosslinking coagent. A “crosslinking coagent” is a substance that improves the crosslinking efficiency of a composition. A nonlimiting example of a suitable crosslinking coagent is triallyl isocyanurate (TAIC). In an embodiment, the composition contains from 0 wt %, or greater than 0 wt %, or 0.1 wt % to 0.5 wt %, or 1.0 wt % crosslinking coagent, based on the total weight of the composition.

[0110] In an embodiment, the composition includes a polyolefin that is different than the (A) silane functionalized ethylene-based polymer. Nonlimiting examples of suitable polyolefins include ethylene-based polymer, propylene-based polymer, and combinations thereof. Nonlimiting examples of suitable ethylene-based polymer include LDPE, ethylene/ethyl acrylate (EEA) copolymer, and combinations thereof. In an embodiment, the polyolefin is not functionalized. In an embodiment, the composition contains from 0 wt %, or 1 wt %, or 3 wt % to 5 wt %, or 10 wt %, or 15 wt %, or 20 wt %, or 50 wt %, or 70 wt % polyolefin, based on the total weight of the composition. In another embodiment, the composition contains from 1 wt % to 70 wt %, or from 1 wt % to 10 wt %, or from 1 wt % to 5 wt % polyolefin (such as LDPE and/or EEA copolymer), based on the total weight of the composition. In an embodiment, the polyolefin is a carrier polyolefin that is combined with the (B) hindered phenol antioxidant and/or the (C) AS-ASAS to form a catalyst masterbatch, and then the catalyst masterbatch is combined with the (A) silane-functionalized ethylene-based polymer to form the composition.

[0111] In an embodiment, the composition contains from 0 wt %, or greater than 0 wt %, or 0.001 wt % to 0.01 wt %, or 0.1 wt %, or 0.5 wt %, or 1.0 wt %, or 2.0 wt %, or 5.0 wt %, or 10.0 wt %, or 15.0 wt %, or 20.0 wt % additive, based on the total weight of the composition.

[0112] The additive may comprise two or more embodiments disclosed herein.

[0113] E. Composition

[0114] The composition contains (A) the silane functionalized ethylene-based polymer, (B) the hindered phenol antioxidant, (C) the aromatic amine-aromatic sulfonic acid salt (AS-ASAS), and, optionally, (D) an additive. In an embodiment, the AS-ASAS has the Structure (I).

[0115] In an embodiment, the composition is a crosslinkable composition. In a further embodiment, the composition is a moisture curable composition. In other words, the composition is capable of crosslinking upon exposure to moisture (e.g., a sauna bath or a cooling bath) and/or the humidity present in the environment in which it is stored, transported or used. Moisture cure conditions include the presence of water (e.g., as a bath or humidity present in the environment), and a temperature of from 20° C., or 23° C. to 25° C. to 30° C.

[0116] In an embodiment, the composition is a crosslinked composition. The crosslinked composition is formed by crosslinking the crosslinkable composition. In an embodiment, the crosslinking of the crosslinkable composition begins in an extruder. In another embodiment, crosslinking is delayed until the crosslinkable composition is extruded, such as upon a conductor. Crosslinking of the crosslinkable composition is initiated and/or accelerated through exposure to humid environment (e.g., ambient conditions or cure in a sauna or water bath). In an embodiment, crosslinking of the crosslinkable composition is initiated and/or accelerated through exposure to moisture. The crosslinked composition includes bonds between the silane functionalized ethylene-based polymer chains.

[0117] In an embodiment, the composition contains, consists essentially of, or consists of: (A) the silane functionalized ethylene-based polymer, (B) the hindered phenol antioxidant, (C) the AS-ASAS, and, optionally, (D) an additive.

[0118] In an embodiment, the composition contains from 30 wt %, or 40 wt %, or 50 wt %, or 60 wt %, or 70 wt %, or 80 wt %, or 90 wt % to 95 wt %, or 97 wt %, or 98 wt %, or 99 wt % silane functionalized ethylene-based polymer, based on the total weight of the composition.

[0119] In an embodiment, the composition contains from 0.03 wt %, or 0.05 wt %, or 0.09 wt % to 0.10 wt % or 0.2 wt %, or 0.5 wt % or 1.0 wt % hindered phenol antioxidant, based on the total weight of the composition.

[0120] In an embodiment, the composition contains from 0.05 wt %, or 0.08 wt %, or 0.10 wt %, or 0.11 wt % to 0.16 wt %, or 0.20 wt %, or 0.50 wt %, or 1.0 wt %, or 2.0 wt %, or 3.0 wt %, or 4.0 wt %, or 5.0 wt % AS-ASAS, based on the total weight of the composition.

[0121] In an embodiment, the composition contains, consists essentially of, or consists of: (A) from 30 wt % to 99 wt %, or from 50 wt % to 99 wt %, or from 80 wt % to 99 wt %, or from 90 wt % to 99 wt %, or from 90 wt % to 95 wt % functionalized ethylene-based polymer (such as ethylene/silane copolymer); (B) from 0.03 wt % to 1.0 wt %, or from 0.03 wt % to 0.5 wt %, or from 0.05 wt % to 0.2 wt %, or from 0.09 wt % to 0.10 wt % hindered phenol antioxidant; (C) from 0.05 wt % to 5.0 wt %, or from 0.05 wt % to 1.0 wt %, or from 0.05 wt % to 0.50 wt %, or from 0.10 wt % to 0.20 wt %, or from 0.11 wt % to 0.16 wt % AS-ASAS (such as the AS-ASAS having the Structure (I)); and (D) from 0 wt % to 20 wt %, or from greater than 0 wt % to 20 wt %, or from greater than 0 wt % to 10 wt % additive, based on the total weight of the composition. In a further embodiment, the composition is a crosslinkable composition.

[0122] In an embodiment, the composition has a hot creep after curing in a water bath at 90° C. for 1 hour of less than 160%, or less than 130%, or less than 110%, or less than 100%, or less than 50%; or from 0%, or 40% to 50%, or 100%, or 110%, or 120%, or 160%. In an embodiment, the composition has a hot creep after curing in a water bath at 90° C. for 3 hours of less than 150%, or less than 130%, or less than 110%, or less than 100%, or less than 80%, or less than 70%, or less than 40%; or from 0%, or 20%, or 30% to 40%, or 70%, or 80%, or 100%, or 110%, or 130%, or 150%. In an embodiment, the composition has a hot creep after curing in a water bath at 90° C. for 6 hours of less than 150%, or less than 100%, or less than 80%; or from 0%, or 20%, or 50%, or 70% to 75%, or 80%, or 100%, or 150%.

[0123] In an embodiment, the composition has a hot creep after curing in ambient environment for 69 hours of less than 100%, or less than 70%; or from 0%, or 20%, or 50% to 70%, or 100%. In an embodiment, the composition has a hot creep after curing in ambient environment for 90 hours of less than 110%, or less than 100%, or less than 80%; or from 0%, or 20%, or 50% to 70%, or 105%, or 110%. In an embodiment, the composition has a hot creep after curing in ambient environment for 100 hours of less than 140%; or from 0%, or 20%, or 50%, or 70% to 130%, or 150%. In an embodiment, the composition has a hot creep after curing in ambient environment for 168 hours of less than 140%, or less than 100%, or less than 90%, or less than 60%; or from 0%, or 20%, or 50% to 60%, or 95%, or 100%, or 130%, or 140%. In an embodiment, the composition has a hot creep after curing in ambient environment for 230 hours of less than 100%, or less than 80%, or less than 60%, or less than 55%; or from 0%, or 20% to 55%, or 60%, or 80%, or 100%.

[0124] In an embodiment, the composition has a hot creep after curing in a water bath at 90° C., (i) for 1 hour of less than 160%, or less than 130%, or less than 110%, or less than 100%, or less than 50%; and/or (ii) for 3 hours of less than 150%, or less than 130%, or less than 110%, or less than 100%, or less than 80%, or less than 70%, or less than 40%; and/or (iii) for 6 hours of less than 150%, or less than 100%, or less than 80%. In an embodiment, the composition has a hot creep after curing in ambient environment, (i) for 69 hours of less than 100%, or less than 70%; and/or (ii) for 90 hours of less than 110%, or less than 100%, or less than 80%; and/or (iii) for 100 hours of less than 140%; and/or (iv) for 168 hours of less than 140%, or less than 100%, or less than 90%, or less than 60%; and/or (v) for 230 hours of less than 100%, or less than 80%, or less than 60%, or less than 55%. A low hot creep is advantageous in wire and cable applications because it demonstrates that the composition has crosslinked (i.e., cured).

[0125] In an embodiment, the AS-ASAS, the hindered phenol antioxidant, and a carrier polyolefin are combined to form a masterbatch. Then, the masterbatch is combined with the silane-functionalized ethylene-based polymer to form the composition. In an embodiment, the masterbatch (also referred to as a “catalyst masterbatch”) contains, consists essentially of, or consists of: (i) from 0.05 wt %, or 0.10 wt %, or 0.50 wt %, or 1.0 wt %, or 2.0 wt %, or 2.3 wt % to 3.2 wt %, or 4.0 wt %, or 5.0 wt %, or 10 wt % AS-ASAS; (ii) from 0.03 wt %, or 0.05 wt %, or 0.10 wt %, or 0.50 wt %, or 1.0 wt %, or 1.50 wt %, or 1.90 wt % to 2.0 wt %, or 3.0 wt %, or 4.0 wt % hindered phenol antioxidant; and (iii) from 86 wt %, or 90 wt %, or 94 wt % to 96 wt %, or 99 wt %, or 99.92 wt % carrier polyolefin (such as EEA copolymer and/or LDPE), based on the total weight of the masterbatch. In a further embodiment, the carrier polyolefin is a blend of EEA copolymer and LDPE at a weight ratio of 1:1, based on the total weight of the blend.

[0126] In an embodiment, the composition, or the masterbatch, exhibits an isobutylene reduction of at least 50% compared to the same composition, or masterbatch containing the aromatic sulfonic acid of the aromatic amine-aromatic sulfonic acid salt, instead of the salt. In an embodiment, the composition, or the masterbatch, exhibits an isobutylene reduction as measured by HSGC with Sample Preparation Method 1 of at least 50% compared to the same composition, or masterbatch containing the aromatic sulfonic acid of the aromatic amine-aromatic sulfonic acid salt, instead of the salt. In another embodiment, the composition, or the masterbatch, exhibits an isobutylene reduction as measured by HSGC with Sample Preparation Method 2 of at least 50% compared to the same composition, or masterbatch containing the aromatic sulfonic acid of the aromatic amine-aromatic sulfonic acid salt, instead of the salt.

[0127] In an embodiment, the composition, or the masterbatch, exhibits an isobutylene generation peak area of less than 6,000,000 per gram (g.sup.−1), or less than 5,000,000 g.sup.−1, or less than 4,000,000 g.sup.−1; or from 0 g.sup.−1 to 6,000,000 g.sup.−1, or from 1,000 g.sup.−1 to 6,000,000 g.sup.−1, or from 500,000 g.sup.−1 to 6,000,000 g.sup.−1, or from 500,000 g.sup.−1 to 5,000,000 g.sup.−1, as measured by HSGC with Sample Preparation Method 1.

[0128] In an embodiment, the composition, or the masterbatch, exhibits an isobutylene generation peak area of less than 1.4×10.sup.11 per mole of sulfur (mol.sup.−1), or less than 1.2×10.sup.11 mol.sup.−1, or less than 1.0×10.sup.11 mol.sup.−1, or less than 5.0×10.sup.10 mol.sup.−1; or from 0 mol.sup.−1 to 1.4×10.sup.11 mol.sup.−1, or from 1.0×10.sup.7 mol.sup.−1 to 1.4×10.sup.11 mol.sup.−1, or from 1.0×10.sup.10 mol.sup.−1 to 1.4×10.sup.11 mol.sup.−1, as measured by HSGC with Sample Preparation Method 1.

[0129] In an embodiment, the composition, or the masterbatch, exhibits an isobutylene generation peak area of less than 1,000,000 per gram (g.sup.−1), or less than 100,000 g.sup.−1, or less than 80,000 g.sup.−1, or less than 75,000 g.sup.−1; or from 0 g.sup.−1 to 1,000, g.sup.−1, or from 100 g.sup.−1 to 100,000 g.sup.−1, or from 100 g.sup.−1 to 80,000 g.sup.−1, or from 100 g.sup.−1 to 75,000 g.sup.−1, as measured by HSGC with Sample Preparation Method 2.

[0130] In an embodiment, the composition, or the masterbatch, exhibits an isobutylene generation peak area of less than 1.8×10.sup.9 per mole of sulfur (mol.sup.−1), or less than 1.7×10.sup.9 mol.sup.−1, or less than 1.6×10.sup.9 mol.sup.−1, or less than 1.5×10.sup.9 mol.sup.−1 or from 0 mol.sup.−1 to 1.8×10.sup.9 mol.sup.−1, or from 1.0×10.sup.6 mol.sup.−1 to 1.80×10.sup.9 mol.sup.−1, or from 1.0×10.sup.6 mol.sup.−1 to 1.70×10.sup.9 mol.sup.−1, as measured by HSGC with Sample Preparation Method 2.

[0131] Low isobutylene generation (e.g., a peak area of less than 6,000,000 g.sup.−1 and/or a peak area of less than 1.4×10.sup.11 mol.sup.−1, as measured by HSGC with Sample Preparation Method 1) is advantageous because isobutylene is toxic. Therefore, a reduction in isobutylene generation leads to improved safety in handling the composition and masterbatch, as well as decreased production costs. Furthermore, isobutylene is generated in the present composition and masterbatch as a result of decomposition of the hindered phenolic antioxidant. Therefore, reduced isobutylene generation indicates that decomposition of the hindered phenolic antioxidant is advantageously reduced, or avoided.

[0132] In an embodiment, the composition contains, consists essentially of, or consists of:

[0133] (i) from 1 wt % to 5 wt %, or 10 wt %, or 20 wt %, or 40 wt %, or 50 wt % catalyst masterbatch, based on the total weight of the composition, and the catalyst masterbatch containing, consisting essentially of, or consisting of: (a) from 0.05 wt %, or 0.10 wt %, or 0.50 wt %, or 1.01 wt %, or 2.01 wt %, or 2.3 wt % to 3.2 wt %, or 4.0 wt %, or 5.0 wt %, or 10 wt % AS-ASAS (such as an AS-ASAS having the Structure (I) and a molar ratio of sulfur to nitrogen of 1:1); (b) from 0.03 wt %, or 0.05 wt %, or 0.10 wt %, or 0.50 wt %, or 1.0 wt %, or 1.50 wt %, or 1.90 wt % to 2.0 wt %, or 3.0 wt %, or 4.0 wt % hindered phenol antioxidant; and (c) from 86 wt %, or 90 wt %, or 94 wt % to 96 wt %, or 99 wt %, or 99.92 wt % carrier polyolefin (such as EEA copolymer and/or LDPE), based on the total weight of the masterbatch;

[0134] (ii) from 50 wt %, or 60 wt %, or 80 wt %, or 90 wt %, or 95 wt % to 99 wt % silane-functionalized ethylene-based polymer (e.g., ethylene/silane copolymer);

[0135] the catalyst masterbatch has one, some, or all of the following properties: (a) an isobutylene reduction as measured by HSGC with Sample Preparation Method 1 of at least 50% compared to the same masterbatch containing the aromatic sulfonic acid of the aromatic amine-aromatic sulfonic acid salt, instead of the salt; and/or (b) an isobutylene reduction as measured by HSGC with Sample Preparation Method 2 of at least 50% compared to the same masterbatch containing the aromatic sulfonic acid of the aromatic amine-aromatic sulfonic acid salt, instead of the salt; and/or (c) an isobutylene generation peak area from 0 g.sup.−1 to 6,000,000 g.sup.−1, or from 1,000 g.sup.−1 to 6,000,000 g.sup.−1, or from 500,000 g.sup.−1 to 6,000,000 g.sup.−1, or from 500,000 g.sup.−1 to 5,000,000 g.sup.−1, as measured by HSGC with Sample Preparation Method 1; and/or (d) an isobutylene generation peak area of from 0 mol.sup.−1 to 1.4×10.sup.11 mol.sup.−1, or from 1.0×10.sup.7 mol.sup.−1 to 1.4×10.sup.11 mol.sup.−1, or from 1.0×10.sup.10 mol.sup.−1 to 1.4×10.sup.11 mol.sup.−1, as measured by HSGC with Sample Preparation Method 1; and/or (e) an isobutylene generation peak area from 0 g.sup.−1 to 1,000,000 g.sup.−1, or from 100 g.sup.−1 to 100,000 g.sup.−1, or from 100 g.sup.−1 to 80,000 g.sup.−1, or from 100 g.sup.−1 to 75,000 g.sup.−1, as measured by HSGC with Sample Preparation Method 2; and/or (f) an isobutylene generation peak area of from 0 mol.sup.−1 to 1.8×10.sup.9 mol.sup.−1, or from 1.0×10.sup.6 mol.sup.−1 to 1.80×10.sup.9 mol.sup.−1, or from 1.0×10.sup.6 mol.sup.−1 to 1.70×10.sup.9 mol.sup.−1, as measured by HSGC with Sample Preparation Method 2; and

[0136] the composition has one, some, or all of the following properties: (A) a hot creep after curing in a water bath at 90° C., (A1) for 1 hour of less than 160% or less than 130%, or less than 110%, or less than 100%, or less than 50%; and/or (A2) for 3 hours of less than 150%, or less than 130%, or less than 110%, or less than 100% or less than 80%, or less than 70%, or less than 40%; and/or (A3) for 6 hours of less than 150%, or less than 100%, or less than 80%, and/or (B) a hot creep after curing in ambient environment, (B1) for 69 hours of less than 100%, or less than 70%; and/or (B2) for 90 hours of less than 110%, or less than 100%, or less than 80%; and/or (B3) for 100 hours of less than 140%; and/or (B4) for 168 hours of less than 140%, or less than 100%, or less than 90%, or less than 60%; and/or (B5) for 230 hours of less than 100%, or less than 80%, or less than 60%, or less than 55%.

[0137] It is understood that the sum of the components in each of the foregoing compositions yields 100 weight percent (wt %).

[0138] In an embodiment, the composition is void of or substantially void of, propylene-based polymer, such as silane functionalized propylene-based polymer and maleic acid functionalized propylene-based polymer.

[0139] In an embodiment, the composition is void of, or substantially void of, sulfonate esters and/or esters of sulfonic acid.

[0140] In an embodiment, the composition is void of, or substantially void of, epoxy resin.

[0141] The composition may comprise two or more embodiments disclosed herein.

[0142] F. Coated Conductor

[0143] The present disclosure provides a coated conductor. The coated conductor includes a conductor and a coating on the conductor, the coating including a composition containing (A) silane functionalized ethylene-based polymer, (B) hindered phenol antioxidant. (C) AS-ASAS, and, optionally, (D) an additive.

[0144] The composition may be any composition disclosed herein.

[0145] In an embodiment, the composition is a crosslinked composition.

[0146] In an embodiment, the coating is an insulation sheath for a conductor. In another embodiment, the coating is a jacket for a conductor.

[0147] The process for producing a coated conductor includes heating the composition to at least the melting temperature of the silane functionalized ethylene-based polymer, and then extruding the polymeric melt blend onto the conductor. The term “onto” includes direct contact or indirect contact between the polymeric melt blend and the conductor. The polymeric melt blend is in an extrudable state. During and/or after extrusion, crosslinking occurs to form a crosslinked composition.

[0148] The coating is located on the conductor. The coating may be one or more inner layers such as an insulating layer. The coating may wholly or partially cover or otherwise surround or encase the conductor. The coating may be the sole component surrounding the conductor. When the coating is the sole component surrounding the conductor, the coating may serve as a jacket and/or an insulation. In an embodiment, the coating is the outermost layer on the coated conductor. Alternatively, the coating may be one layer of a multilayer jacket or sheath encasing the metal conductor. In an embodiment, the coating directly contacts the conductor. In another embodiment, the coating directly contacts an insulation layer surrounding the conductor.

[0149] In an embodiment, the coating directly contacts the conductor. The term “directly contacts,” as used herein, is a coating configuration whereby the coating is located immediately adjacent to the conductor, the coating touches the conductor, and no intervening layers, no intervening coatings, and/or no intervening structures, are present between the coating and the conductor.

[0150] In another embodiment, the coating indirectly contacts the conductor. The term “indirectly contacts,” as used herein, is a coating configuration whereby an intervening layer, an intervening coating, or an intervening structure, is present between the coating and the conductor. Nonlimiting examples of suitable intervening layers, intervening coatings, and intervening structures include insulation layers, moisture barrier layers, buffer tubes, and combinations thereof. Nonlimiting examples of suitable insulation layers include foamed insulation layers, thermoplastic insulation layers, crosslinked insulation layers, and combinations thereof.

[0151] In an embodiment, the composition contains carbon black, and the coating is a semiconductive layer on a conductor.

[0152] The coating is crosslinked. In an embodiment, crosslinking of the crosslinkable composition begins in the extruder, but only to a minimal extent. In another embodiment, crosslinking is delayed until the crosslinkable composition is extruded upon the conductor. Crosslinking of the crosslinkable polymeric composition can be initiated and/or accelerated through exposure to humid environment (e.g., ambient conditions or cure in a sauna or water bath). In an embodiment, crosslinking of the crosslinkable composition is initiated and/or accelerated through exposure to moisture.

[0153] In an embodiment, the coated conductor is selected from a fiber optic cable, a communications cable (such as a telephone cable, a local area network (LAN) cable, or a small form-factor pluggable (SFP) cable), a power cable, wiring for consumer electronics, a power charger wire for cell phones and/or computers, computer data cords, power cords, appliance wiring material, home interior wiring material, consumer electronic accessory cords, and any combination thereof.

[0154] The coated conductor may comprise two or more embodiments disclosed herein.

[0155] G. Process

[0156] The present disclosure provides a process for moisture curing a silane-functionalized ethylene-based polymer. The process includes (A) providing an aromatic amine-aromatic sulfonic acid salt (AS-ASAS); (B) mixing the aromatic amine-aromatic sulfonic acid salt with a hindered phenol antioxidant to form a catalyst composition; (C) contacting a silane functionalized ethylene-based polymer with the catalyst composition to form a crosslinkable composition; and (D) exposing the crosslinkable composition to moisture cure conditions to form a crosslinked composition.

[0157] Moisture cure conditions include the presence of water (e.g., as a bath or humidity present in the environment), and a temperature of from 20° C., or 23° C. to 25° C. to 30° C.

[0158] In an embodiment, the (B) mixing the AS-ASAS with a hindered phenol antioxidant to form a catalyst composition and the (C) contacting a silane functionalized ethylene-based polymer with the catalyst composition to form a crosslinkable composition occur simultaneously. In other words, the AS-ASAS, hindered phenol antioxidant, and silane functionalized ethylene-based polymer are simultaneously blended to form the crosslinkable composition.

[0159] In an embodiment, the (B) mixing the AS-ASAS with a hindered phenol antioxidant to form a catalyst composition includes forming a masterbatch containing, consisting essentially of, or consisting of (i) the AS-ASAS (such as the AS-ASAS having the Structure (I), with a sulfur to nitrogen molar ratio of 1:1), (ii) the hindered phenol antioxidant, and (iii) a carrier polyolefin. The masterbatch and the carrier polyolefin may be any respective masterbatch (also referred to as a catalyst masterbatch) and carrier polyolefin disclosed herein. In an embodiment, the carrier polyolefin is a blend of EEA copolymer and LDPE.

[0160] In an embodiment, the process includes synthesizing the AS-ASAS by mixing the aromatic amine with the aromatic sulfonic acid in an organic solvent or a wax, for a period of from one, or two to three, or four, or five, or six hours at room temperature (23-25° C.). Nonlimiting examples of suitable organic solvent include dichloromethane, toluene, and combinations thereof.

[0161] The process may comprise two or more embodiments disclosed herein.

[0162] By way of example, and not limitation, some embodiments of the present disclosure will now be described in detail in the following examples.

Examples

[0163] The materials used in the examples are provided in Table 1 below.

TABLE-US-00004 TABLE 1 Materials Component Specification Source SI-LINK ™ ethylene/silane copolymer The Dow Chemical DFDA-5451 NT density = 0.922 g/cc; melt index = 1.5 g/10 min Company DXM-205 ethylene/ethyl acrylate (EEA) copolymer The Dow Chemical 19 wt % ethyl acrylate; melt index = 20 g/10 min; Company density = 0.93 g/cc DXM-446 low density polyethylene (LDPE); CAS 9002-88-4; The Dow Chemical density = 0.92 g/cc; melt index = 2.3 g/10 min Company IRGANOX ™ 1010 hindered phenol antioxidant; CAS 6683-19-8; BASF pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4- hydroxyphenyl)propionate NACURE ™ B201 aromatic sulfonic acid; naphthalene sulfonic acid King Industries, Inc. DBSA aromatic sulfonic acid; CAS 27176-87-0; Energy Chemical dodecylbenzenesulfonic acid (DBSA) 4- aromatic sulfonic acid; 4-methylbenzenesulfonic Shanghai Haohong methylbenzenesulfonic acid monohydrate, 95% solution; CAS 6192-52-5 Biomedical acid monohydrate Technology Co., Ltd naphthalene-2-sulfonic aromatic sulfonic acid; naphthalene-2-sulfonic Shanghai Macklin acid acid, 98%; CAS 120-18-3 Biochemical Co., Ltd. trifluoromethanesulfonic trifluoromethanesulfonic acid, 99%; Energy Chemical acid CAS 1493-16-6 methanesulfonic acid methanesulfonic acid, 99%; CAS 75-75-2 Shanghai Macklin Biochemical Co., Ltd. naphthalene-1-sulfonic naphthalene-1-sulfonic acid, 98%; CAS 85-47-2 China Langchem Inc. acid NAUGARD ™ 445 aromatic amine; CAS 10081-67-1 Energy Chemical bis(4-(2-phenylpropan-2-yl)phenyl)amine di([1,1′-biphenyl]- aromatic amine; CAS 102113-98-4 Bide Pharmatech Ltd 4-yl)amine di([1,1′-biphenyl]-4-yl)amine, 97% AO 4020 aromatic amine; N1-(4-methylpentan-2-yl)-N4- Tianjin Heowns phenylbenzene-1,4-diamine, 98%; CAS 793-24-8 Biochem LLC AO 124 polymerized amine; CAS 26780-96-1 Bide Pharmatech Ltd polymerized 1,2-dihydro-2,2,4-trimethylquinoline mixture of dimer (50-65 wt %), trimer (25-40 wt %), and tetramer (8-15 wt %) diisobutylamine diisobutylamine, 99%; CAS 110-96-3 Merck diisopropylamine diisopropylamine, 99%; CAS 108-18-9 Merck

[0164] A. Catalyst Salt Synthesis

[0165] The catalyst salts of Table 2 are synthesized by combining 10 mmol amine with 10 mmol acid in a reaction flask that contains 100 mL dichloromethane. For amines containing more than one amino group, the amount of acid within the reaction mixture is varied to achieve the desired stoichiometric ratio between the sulfonic acid and amino groups.

[0166] The reaction mixture is stirred for two hours at room temperature (23-25° C.). Then, the solution is evaporated using a rotary evaporator under a reduced pressure of 0.1 MPa at 35° C. for 15 minutes, and the catalyst salt solid product is obtained and dried over a vacuum at room temperature (23-25° C.) for a period of 6 hours.

[0167] The amine, acid, and resulting catalyst salts are provided in Table 2. As shown in Table 2, Ex Salt 1-4, Ex Salt 7, Ex Salt 9, Ex Salt 11, and Ex Salt 15 each is an AA-ASAS.

[0168] B. Catalyst Salt Masterbatch Preparation and Pelletization

[0169] DXM-205 (EEA copolymer) and DXM-446 (LDPE) are fed in equal amounts (i.e., a 1:1 weight ratio) into a Brabender mixer set at a temperature of 120° C. and a rotator speed of 15 rotations per minute (rpm). Then, one of the catalyst salts of Table 2 and IRGANOX™ 1010 (hindered phenol antioxidant) are fed into the mixer, and the masterbatch composition is mixed for three minutes at a temperature of 120° C. and a rotator speed of 50 rpm.

[0170] After mixing, the Catalyst Salt Masterbatch is fed into a Brabender single-screw extruder set at 120° C., and pelletized.

[0171] Each Catalyst Salt Masterbatch contains 4.4 mmol/100 g sulfonic groups, based on the respective catalyst salt masterbatch. The composition of each Catalyst Salt Masterbatch is provided below in Table 3.

[0172] Catalyst Salt Masterbatches of Table 3 are measured for isobutylene by HSGC or by GC, after Sample Preparation Method 1 or Sample Preparation Method 2 as described above in the Test Methods section. The results are provided in Tables 4A and 4B below. In the tables, “NM” indicates a value was not measured.

[0173] As shown in Table 4B, the catalyst master batch MB21 (which contains DBSA) generates two times the amount of isobutylene than catalyst master batch MB19 (which contains naphthalene sulfonic acid), as measured by GC and Sample Preparation Method 2. This suggests that DBSA tends to decompose hindered phenol antioxidants at a faster rate than naphthalene sulfonic acid. However, as shown in Table 4A, catalyst master batch MB2 (which contains Ex Salt 2, an AA-ASAS formed using DBSA and NAUGARD™ 445), surprisingly generates much lower isobutylene compared to catalyst master batch MB19 (which contains naphthalene sulfonic acid). Not wishing to be bound by any particular theory, it is believed that at least 50% isobutylene reduction can be achieved by using the aromatic amine-aromatic sulfonic acid salt instead of corresponding sulfonic acid.

TABLE-US-00005 TABLE 2 Catalyst Salts Molar ratio Cata- sulfur lyst to Salt nitro- No. Amine Acid Catalyst Salt Structure gen Ex NAUGARD ™ 4-methyl- Structure (IV) of Table C 1:1 Salt 1 445 benzene sulfonic acid Ex NAUGARD ™ DBSA Structure (V) of Table C 1:1 Salt 2 445 Ex NAUGARD ™ naphthalene- Structure (VI) of Table C 1:1 Salt 3 445 1- sulfonic acid Ex NAUGARD ™ naphthalene- Structure (VII) of Table C 1:1 Salt 4 445 2- sulfonic acid CS Salt 5 NAUGARD ™ 445 trifluoro- methane- sulfonic acid [00014] 1:1 CS Salt 6 NAUGARD ™ 445 mathane- sulfonic acid [00015] 1:1 Ex di([1,1′- naphthalene- Structure (VIII) of Table C 1:1 Salt 7 biphenyl]-4- 1- yl)amine sulfonic acid CS Salt 8 di([1,1′- biphenyl]-4- yl)amine methane- sulfonic acid [00016] 1:1 Ex AO 4020 4-methyl- Structure (IX) of Table C 1:1 Salt 9 benzene sulfonic acid CS Salt 10 AO 4020 4-methyl- benzene- sulfonic acid [00017] 2:1 Ex AO 4020 naphthalene- Structure (X) of Table C 1:1 Salt 11 1- sulfonic acid CS Salt 12 AO 4020 naphthalene- 1- sulfonic acid [00018] 2:1 CS Salt 13 AO 4020 Methyl Sulfonic Acid [00019] 1:1 CS Salt 14 AO 4020 Methyl Sulfonic Acid [00020] 2:1 Ex AO 4020 naphthalene- Structure (XI) of Table C 1:1 Salt 15 1- sulfonic acid CS Salt 16 diisopropyl- amine naphthalene- 1- sulfonic acid [00021] 1:1 CS Salt 17 diisobutyl- amine naphthalene- 1- sulfonic acid [00022] 1:1 CS Salt 18 AO 124 naphthalene- 1- sulfonic acid [00023] 1:1

TABLE-US-00006 TABLE 3 Catalyst Salt Masterbatches* MB MB MB MB MB MB MB MB MB MB MB 1 2 3 4 5 6 7 8 9 10 11 DXM-205 47.75 47.42 47.69 47.68 47.92 47.92 47.86 48.11 47.68 48.06 47.53 (EEA) DXM-446 47.75 47.42 47.69 47.68 47.92 47.92 47.86 48.11 47.68 48.06 47.53 (LDPE) IRGANOX ™ 1.97 1.97 1.97 1.97 1.97 1.97 1.97 1.97 1.97 1.97 1.97 1010 Ex Salt 1 2.52 — — — — — — — — — — Ex Salt 2 — 3.20 — — — — — — — — — Ex Salt 3 — — 2.65 — — — — — — — — Ex Salt 4 — — — 2.68 — — — — — — — CS Salt 5 — — — — 2.19 — — — — — — CS Salt 6 — — — — — 2.19 — — — — — Ex Salt 7 — — — — — — 2.31 — — — — CS Salt 8 — — — — — — — 1.82 — — — Ex Salt 9 — — — — — — — — 2.67 — — CS Salt 10 — — — — — — — — — 1.92 — Ex Salt 11 — — — — — — — — — — 2.98 CS Salt 12 — — — — — — — — — — — CS Salt 13 — — — — — — — — — — — CS Salt 14 — — — — — — — — — — — Ex Salt 15 — — — — — — — — — — — CS Salt 16 — — — — — — — — — — — CS Salt 17 — — — — — — — — — — — CS Salt 18 — — — — — — — — — — — NACURE ™ — — — — — — — — — — — B201 NAUGARD ™ — — — — — — — — — — — 445 DBSA — — — — — — — — — — — Total wt % 100 100 100 100 100 100 100 100 100 100 100 MB MB MB MB MB MB MB MB MB MB MB 12 13 14 15 16 17 18 19 20 21 22 DXM-205 47.98 48.02 48.02 47.57 48.34 48.28 48.20 47.61 47.74 48.305 47.43 (EEA) DXM-446 47.98 48.02 48.02 47.57 48.34 48.28 48.20 47.61 47.74 48.305 47.43 (LDPE) IRGANOX ™ 1.97 1.97 1.97 1.97 1.97 1.97 1.97 1.97 1.97 1.97 1.97 1010 Ex Salt 1 — — — — — — — — — — — Ex Salt 2 — — — — — — — — — — — Ex Salt 3 — — — — — — — — — — — Ex Salt 4 — — — — — — — — — — — CS Salt 5 — — — — — — — — — — — CS Salt 6 — — — — — — — — — — — Ex Salt 7 — — — — — — — — — — — CS Salt 8 — — — — — — — — — — — Ex Salt 9 — — — — — — — — — — — CS Salt 10 — — — — — — — — — — — Ex Salt 11 — — — — — — — — — — — CS Salt 12 2.08 — — — — — — — — — — CS Salt 13 — 2.00 — — — — — — — — — CS Salt 14 — — 2.00 — — — — — — — — Ex Salt 15 — — — 2.89 — — — — — — — CS Salt 16 — — — — 1.35 — — — — — — CS Salt 17 — — — — — 1.47 — — — — — CS Salt 18 — — — — — — 1.64 — — — — NACURE ™ — — — — — — — 2.80 2.80 — — B201 NAUGARD ™ — — — — — — — — 1.75 — 1.75 445 DBSA — — — — — — — — — 1.42 1.42 Total wt % 100 100 100 100 100 100 100 100 100 100 100 *Amounts in Table 3 are in weight percent, based on the total weight of the Catalyst Salt Masterbatch. CS = Comparative Sample

TABLE-US-00007 TABLE 4A Isobutylene Measurement by HSGC and Sample Preparation Method 1. MB1 MB2 MB3 MB5 MB15 MB19 Peak Area(HSGC)/Weight, g.sup.−1 2.58E+06 4.57E+06 1.60E+06 2.45E+07 6.06E+05 8.19E+06 Peak Area (HSGC) per mol Sulfur, 5.86E+10 1.04E+11 3.63E+10 5.56E+11 1.38E+10 1.86E+11 mol.sup.−1

TABLE-US-00008 TABLE 4B Isobutylene Measurement by HSGC or GC, and Sample Preparation Method 2. MB4 MB7 MB8 MB11 MB13 MB19 MB21 HSGC Measurement Peak Area (HSGC)/ 6.56E+04 7.13E+04 2.70E+05 5.58E+04 8.05E+04 1.02E+06 NM Weight, g.sup.−1 Peak Area (HSGC) per 1.49E+09 1.62E+09 6.13E+09 1.27E+09 1.83E+09 2.32E+10 NM mol Sulfur, mol.sup.−1 GC Measurement Peak Area (GC)/Weight, NM NM NM NM NM 1.77E+06 3.53E+06 g.sup.−1 Peak Area (GC) per mol NM NM NM NM NM 4.02E+10 8.02E+10 Sulfur, mol.sup.−1

[0174] C. Composition Preparation

[0175] SI-LINK™ DFDA-5451 NT (ethylene/silane copolymer) pellets and Catalyst Salt Masterbatch (of Table 3) pellets are dry blended to form a dry blend with 95 wt % SI-LINK™ DFDA-5451 NT and 5 wt % Catalyst Salt Masterbatch, based on the total weight of the dry blend. The dry blend is fed into a Brabender single-screw extruder set at 160° C., and are mixed until the composition is in a molten form. Then, the composition is extruded into a tape having a thickness of 1 mm.

[0176] At least one tape for each sample is placed into a water bath set at a temperature of 90° C. Samples are tested for hot creep after sitting in the water bath for 1 hour, 3 hours, and 6 hours. Sample compositions that are crosslinkable undergo cure in the water bath.

[0177] At least one tape for each sample is placed on a workbench in ambient environment (room temperature of 23-25° C., 50% relative humidity). Samples are tested for hot creep after sitting in ambient environment for 69 hours, 90 hours, 100 hours, 168 hours, and 230 hours. Sample compositions that are crosslinkable undergo cure in the ambient environment.

[0178] The composition of each sample, and the results are provided below in Table 5.

[0179] As shown in Table 5, CS 6, CS 8, CS 13, and CS 14 each contains (A) ethylene/silane copolymer (SI-LINK™ DFDA-5451 NT), (B) hindered phenol antioxidant (IRGANOX™ 1010), and (C) an aromatic amine-linear sulfonic acid salt (CS Salt 6, CS Salt 8, CS Salt 13, and CS Salt 14). CS 6, CS 8, CS 13, and CS 14 each lacks an aromatic amine-aromatic sulfonic acid salt. CS 6, CS 8, CS 13, and CS 14 each broke during hot creep testing at all time lengths-indicating that the compositions are not cured. Consequently, CS 6, CS 8, CS 13, and CS 14 are not moisture crosslinkable compositions.

TABLE-US-00009 TABLE 5 Compositions Ex Ex Ex Ex CS CS Ex CS Ex CS Ex 1 2 3 4 5 6 7 8 9 10 11 DFDA- 95 95 95 95 95 95 95 95 95 95 95 5451 NT MB1 5 — — — — — — — — — — MB2 — 5 — — — — — — — — — MB3 — — 5 — — — — — — — — MB4 — — — 5 — — — — — — — MB5 — — — — 5 — — — — — — MB6 — — — — — 5 — — — — — MB7 — — — — — — 5 — — — — MB8 — — — — — — — 5 — — — MB9 — — — — — — — — 5 — —  MB10 — — — — — — — — — 5 —  MB11 — — — — — — — — — — 5  MB12 — — — — — — — — — — —  MB13 — — — — — — — — — — —  MB14 — — — — — — — — — — —  MB15 — — — — — — — — — — —  MB16 — — — — — — — — — — —  MB17 — — — — — — — — — — —  MB18 — — — — — — — — — — —  MB19 — — — — — — — — — — —  MB20 — — — — — — — — — — —  MB21 — — — — — — — — — — —  MB22 — — — — — — — — — — — Total wt % 100 100 100 100 100 100 100 100 100 100 100 Hot Creep (%) Water  1 hr 157 NM 40 120 NM B 103 B NM B NM Bath  3 hr 108 32 32 67 82 B 68 B NM B 127 Ambient  6 hr NM NM NM NM 72 B NM B 75 B 145 Env..sup.1  69 hr NM 67 NM NM NM B NM B NM B NM  90 hr NM 70 105 NM 115 B NM B NM B NM 100 hr 130 NM NM NM NM B NM B NM B NM 168 hr 83 55 85 NM NM B NM B NM B NM 230 hr 53 NM NM NM 60 B NM B NM B NM CS CS CS Ex CS CS CS CS CS CS CS 12 13 14 15 16 17 18 19 20 21 22 DFDA- 95 93 95 95 95 95 95 95  95  95  95 5451 NT MB1 — — — — — — — — — — — MB2 — — — — — — — — — — — MB3 — — — — — — — — — — — MB4 — — — — — — — — — — — MB5 — — — — — — — — — — — MB6 — — — — — — — — — — — MB7 — — — — — — — — — — — MB8 — — — — — — — — — — — MB9 — — — — — — — — — — —  MB10 — — — — — — — — — — —  MB11 — — — — — — — — — — —  MB12 5 — — — — — — — — — —  MB13 — 5 — — — — — — — — —  MB14 — — 5 — — — — — — — —  MB15 — — — 5 — — — — — — —  MB16 — — — — 5 — — — — — —  MB17 — — — — — 5 — — — — —  MB18 — — — — — — 5 — — — —  MB19 — — — — — — — 5 — — —  MB20 — — — — — — — —  5 — —  MB21 — — — — — — — — —  5 —  MB22 — — — — — — — — — —  5 Total wt % 100 100 100 100 100 100 100 100 100 100 100 Hot Creep (%) Water  1 hr B B B NM B B B 38  25  <70    <43   Bath  3 hr B B B NM B B B 18 NM NM NM Ambient  6 hr B B B 73 B B B NM NM NM NM Env..sup.1  69 hr B B B NM B B B 75  .sup. 85.sup.2  .sup. 48.sup.3  .sup. 75.sup.3  90 hr B B B NM B B B NM NM NM NM 100 hr B B B NM B B B 62 NM NM NM 168 hr B B B 130 B B B NM NM NM NM 230 hr B B B NM B B B NM NM NM NM *Amounts in Table 5 are in weight percent, based on the total weight of the crosslinkable composition. CS = Comparative Sample .sup.3Measured at 71 hours B = sample broke, including the composition is not cured .sup.1Hot Creep after curing in ambient environment .sup.2Measured at 72 hours

[0180] CS 16 and CS 17 each contains (A)ethylene/silane copolymer (SI-LINK™ DFDA-5451 NT), (B) hindered phenol antioxidant (IRGANOX™ 1010), and (C) a linear amine-aromatic sulfonic acid salt (CS Salt 16 and CS Salt 17). CS 16 and CS 17 each lacks an aromatic amine-aromatic sulfonic acid salt. CS 16 and CS 17 each broke during hot creep testing at all time lengths-indicating that the compositions are not cured. Consequently, CS 16 and CS 17 are not moisture crosslinkable compositions.

[0181] CS 18 contains (A) ethylene/silane copolymer (SI-LINK™ DFDA-5451 NT), (B) hindered phenol antioxidant (IRGANOX™ 1010), and (C) a polymeric aromatic amine-aromatic sulfonic acid salt (CS Salt 18). CS 18 lacks a non-polymeric an aromatic amine-aromatic sulfonic acid salt. CS 18 broke during hot creep testing at all time lengths-indicating that the composition is not cured. Consequently, CS 18 is not a moisture crosslinkable composition.

[0182] CS 19 contains (A) ethylene/silane copolymer (SI-LINK™ DFDA-5451 NT), (B) hindered phenol antioxidant (IRGANOX™ 1010), and (C) aromatic sulfonic acid (NACURE™ B201). CS 19 lacks an aromatic amine-aromatic sulfonic acid salt. As shown in Tables 4A and 4B, the catalyst masterbatch contained in CS 19 (MB19) exhibits an isobutylene generation peak area of greater than 6,000,000 per gram (8,190,000 per gram) measured by HSGC and Sample Preparation Method 1. Consequently, CS 19 is dangerous to produce and handle.

[0183] CS 10, CS 12, and CS 14 each contains (A) ethylene/silane copolymer (SI-LINK™ DFDA-5451 NT), (B) hindered phenol antioxidant (IRGANOX™ 1010), and (C) an aromatic amine-aromatic sulfonic acid salt that has a molar ratio of sulfur to nitrogen greater than 1.3:1 (2:1)(CS Salt 10, CS Salt 12, and CS Salt 14). CS 10, CS 12, and CS 14 each broke during hot creep testing at all time lengths-indicating that the compositions are not cured. Consequently, CS 10, CS 12, and CS 14 are not moisture crosslinkable compositions.

[0184] In contrast, a composition (Ex 1-Ex 4, Ex 7, Ex 9, Ex 11, and Ex 15) containing (A) ethylene/silane copolymer (SI-LINK™ DFDA-5451 NT), (B) hindered phenol antioxidant (IRGANOX™ 1010), and (C) an aromatic amine-aromatic sulfonic acid salt that has a molar ratio of sulfur to nitrogen greater than 1:1 surprisingly exhibits suitable hot creep (e.g., a hot creep of 130% or less after gaining in ambient environment for 168 hours)—indicating that the compositions are crosslinkable—while also exhibiting safe levels of isobutylene generation (e.g., an isobutylene generation peak area of less than 6,000,000 per gram measured by HSGC and Sample Preparation Method 1.

[0185] It is specifically intended that the present disclosure not be limited to the embodiments and illustrations contained herein, but include modified forms of those embodiments including portions of the embodiments and combinations of elements of different embodiments as come within the scope of the following claims.