ENERGY EFFICIENT VPSA SYSTEM WITH DIRECT DRIVE HIGH SPEED CENTRIFUGAL COMPRESSORS
20220258094 · 2022-08-18
Inventors
- Andrew C. Rosinski (Orchard Park, NY, US)
- Nicholas R. Stuckert (Grand Island, NY)
- Yang Luo (Amherst, NY)
Cpc classification
Y02C20/40
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B01D53/0476
PERFORMING OPERATIONS; TRANSPORTING
B01D2259/40007
PERFORMING OPERATIONS; TRANSPORTING
B01D53/0446
PERFORMING OPERATIONS; TRANSPORTING
B01D2253/1085
PERFORMING OPERATIONS; TRANSPORTING
B01D2259/40009
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
The invention relates to a method and system for improving PSA/VPSA plant energy efficiency during times of reduced production demand and capital efficiency through optimizing feed, vacuum, and centrifugal product compressors to achieve lower energy consumption and lower unit gas product production cost. More specifically, the present invention relates to a new energy efficient PSA/VPSA turn down process and system which employs high speed direct drive centrifugal product compressor to achieve desired production. Significant lower energy consumption can be achieved by employing lower flow, and lower adsorption top pressure in the lower production range.
Claims
1. A method for improving the energy efficiency of adsorptive gas separation system during the times of reduced product demand, wherein system comprises: a. at least one vessel containing at least one adsorption bed comprising at least one adsorption material, and b. at least one compressor, wherein the at least one adsorption bed is configured for cyclical pressurization and depressurization during operation for separation of components of a feed gas mixture into at least a first component and a second component by selective adsorption of said first component into said adsorption bed comprising at least one adsorbent, said method comprising the following steps on a cyclic basis: I. raising the pressure of a feed gas to said bed during the adsorption steps of the cycle to an adsorption pressure so as to enable adsorption of said first component by said adsorbent, said adsorbent exhibiting a mass transfer coefficient of >=12/s and an intrinsic N.sub.2 diffusivity of >3.5×10.sup.−6 m2/s at 1.5 bar and 300 k, II. depressurizing said bed during the desorption steps of said cycle to a desorption pressure so as to desorb said first component from said adsorbent, the ratio of pressures of said adsorption pressure to said desorption pressure in a range of from about 1.5 to 6.0; wherein during times of reduced product demand, said method comprises lowering the top adsorption pressure to a range of from about 75% to 90% of design maximum operation pressure of said at least one adsorption vessel to lower production capacity while achieving higher energy efficiency.
2. The method of claim 1, wherein the system is a PSA or a VPSA system configured to recover at least one gas selected from the group comprising: O.sub.2, N.sub.2, CO.sub.2, H.sub.2, Ar, or helium.
3. The method of claim 2, wherein said intrinsic diffusivity of said adsorbent for said first component is equal to or greater than 4.0×10.sup.−6 m.sup.2/sec and said ratio of the adsorption pressure to the desorption pressure ranges from about 1.5 to about 3.5 for a VPSA system and from about 3.0 to about 6.0 in a PSA system.
4. The method of claim 2, wherein said feed gas is air, said first component is nitrogen and said second component is oxygen, wherein said adsorbent is a type X zeolite with a SiO2/Al2 O3 ratio less than or equal to 2.5 and exchanged with Li (>70%), and or mixed cation zeolites.
5. (canceled)
6. The method of claim 1 which comprises one or more beds in series or parallel, wherein at least one bed in feed mode while the others are in regeneration mode and wherein the said at least one compressor is a positive displacement type compressor, a rotodynamic type compressor or centrifugal compressor.
7. (canceled)
8. The method of claim 6 wherein the said at least one compressor is a positive displacement type compressor, wherein the top adsorbent vessel pressure of said at least one adsorbent vessel is lowered while maintaining control over the product flow rate by reducing the pressure restriction in the system by increasing the opening of product control the product make valves and/or the equalization valves.
9. The method of claim 8 wherein said at least one compressor is driven by an associated motor, wherein the at least one compressor is a rotary-lobe blower and the associated motor is an induction motor.
10. The method of claim 7 wherein said at least one compressor is a centrifugal feed compressor optionally comprising inlet guide vanes, wherein the top pressure of said at least one adsorbent vessel is lowered by lowering the feed flow to the adsorption vessel, wherein said lower feed flow is achieved by lowering compressor speed of said centrifugal compressor, or adjusting the angles of inlet guide vanes of said compressor, or a combination of both.
11. A method for operating a PSA or VPSA adsorption system for gas separation said system comprising: a. at least one vessel containing at least one adsorption bed comprising at least one adsorption material, wherein the at least one bed is configured for cyclical pressurization and depressurization during operation; b. at least one compressor configured to be driven by an associated motor comprising a direct drive high-speed permanent magnet or high-speed induction motor designed for variable-speed operation; and c. means for receiving data signals for conditions in the system and for communicating to the high-speed induction motor driving the at least one centrifugal compressor in response to the conditions such that the at least one centrifugal compressor can operate at a designated speed; and d. a product compressor configured to deliver the desired product pressure at average and peak production capacity, wherein during times of reduced product demand, said method comprises lowering the top adsorption pressure to a range of from about 75% to 90% of design operation pressure of said at least one adsorption vessel to lower production capacity while achieving higher energy efficiency.
12. The method of claim 11 wherein the said product compressor is a centrifugal compressor driven by direct drive, high-speed permanent magnetic motor or high-speed induction motor, and the speed and pressure ratio of the said compressor can be increased to achieve the desired product pressure and flow.
13. The method of claim 11 wherein the said at least one compressor is a positive displacement type compressor, wherein the top adsorbent vessel pressure of said at least one adsorbent vessel is lowered while maintaining control over the product flow rate by reducing the pressure restriction in the system by increasing the opening of product control the product make valves and/or the equalization valves.
14. The method of claim 12 wherein said at least one compressor is a centrifugal feed compressor optionally comprising inlet guide vanes, wherein when product demand is lower than the average production requirements of the system the top pressure of said at least one adsorbent vessel is lowered by lowering the feed flow to the adsorption vessel, wherein said lower feed flow is achieved by lowering compressor speed of said centrifugal compressor, or adjusting the angles of inlet guide vanes of said compressor, or a combination of both.
15. The method of claim 14, wherein said centrifugal compressor and/or said product compressor are driven by a direct drive high-speed permanent magnetic motor or high-speed induction motor, wherein the associated motors of the centrifugal compressor and/or product compressor are in communication with at least one associated variable-frequency drive and the at least one associated variable-frequency drive is in communication with the means for receiving data signals and wherein the associated motors of the at least one centrifugal compressor and/or product compressor are in communication with at least one associated variable-frequency drive and the at least one associated variable-frequency drive is in communication with the means for receiving data signals.
16. (canceled)
17. The method of claim 16, wherein the means for receiving data signals is configured to determine the pressure ratio (outlet pressure/inlet pressure) for the at least one centrifugal compressor and/or the product compressor.
18. The method of claim 17, wherein the means for receiving data signals communicates during operation to the associated high-speed permanent magnetic motor or high-speed induction motor of the at least one centrifugal compressor and/or the product compressor a speed at which to operate in response to the pressure ratio and the inlet temperature for the at least one centrifugal compressor and/or product compressor.
19. The method of claim 18, wherein the associated high-speed permanent magnet or induction motor is directly coupled to the at least one feed centrifugal compressor such that the at least one feed centrifugal compressor can be operated at or near a predetermined efficiency line, wherein the predetermined efficiency line is a best efficiency line represented by the loci of points that correspond to peak efficiency points of the compressor operating curves at different speeds and process conditions of the at least one feed centrifugal compressor.
20. (canceled)
21. (canceled)
22. The method of claim 11, wherein the PSA or VPSA system comprises a system for recovering at least one gas selected from the group comprising: O.sub.2, N.sub.2, CO.sub.2, H.sub.2, Ar, or helium.
23. The method of claim 22 wherein said system is a VPSA system and the turn down energy efficiency for said VPSA process is improved by lowering the top adsorption pressure in said system, increasing feed flow to the system and/or lowering cycle time.
24. The method of claim 23 wherein turn down range is extended through direct drive high-speed direct drive VFD controlled multiple stage centrifugal compressor, the employment of inlet guide vane, control of the angle of inlet guide vane, varying stage pressure ratio via varying stage speeds, or combination of the any above.
Description
DETAILED DESCRIPTION OF THE FIGURES
[0017]
[0018]
DETAILED DESCRIPTION OF THE INVENTION
[0019] Centrifugal technology is based on dynamic compression. In a dynamic compressor, gas, such as air, oxygen, nitrogen, or other gases, is drawn between the blades of a rapidly rotating impeller and accelerates to high velocity. The air is then discharged through a diffuser where the kinetic energy is transformed into static pressure. Most dynamic compressors are turbo compressors with an axial or radial flow pattern and are designed for larger volume flow rates. The performance of a dynamic compressor is very much dependent on environmental conditions such as: [0020] 1) Inlet temperature [0021] 2) Inlet pressure [0022] 3) Relative humidity (RH) [0023] 4) Cooling water temperature
[0024] Decreasing the inlet temperature of the air increases air density resulting in higher free air delivery (Actual Cubic per Minute, ACFM), higher power consumption of the compressor and higher available turndown range. Likewise, increasing inlet temperature of the air decreases air density resulting in lower free air delivery (ACFM), lower power consumption of the compressor and smaller available turndown range.
[0025] A decrease in inlet pressure will reduce the density of the air at the compressor intake. As with higher temperatures, it will result in lower free air delivery, lower power consumption and smaller available turndown. And increase in inlet pressure will increase the density of the air at the compressor intake, resulting in result in higher free air delivery, higher power consumption and higher available turndown.
[0026] The addition of water vapor to the air makes air humid and reduces the density of the air. This is due to the molar mass of water being less than that of air. Accordingly, an increase in relative humidity reduces flow and power, and a decrease in RH will increase flow and power.
[0027] Finally, the cooling water temperatures affect the intake such that colder water increases flow and power, and warmer water reduces flow and power.
[0028] PSA/VPSA plants are typically designed and sized to meet maximum production requirement at highest ambient temperature conditions. However, PSA/VPSA plants often run at lower than design capacity due to changes in customer demand and ambient conditions, reducing the efficiency of the turn down operation.
[0029] To improve the plant energy efficiency when customer demand is lower than the design capacity, the present invention proposes a new turn down method whereby the flow and top adsorption pressure are lowered to achieve lower unit energy consumption. With the lower flow and lower inlet suction pressure to the product compressor, the final desired product pressure can be achieved through increasing motor speed and increasing stage pressure ratio(s) with variable speed controlled centrifugal compressor driven by either high speed permanent magnet motor or induction motor. The proposed process and system are beneficial for PSA/VPSA plants that employ either Roots or centrifugal feed and/or vacuum compressors, but most benefits are expected from the plants employing centrifugal machines.
[0030] In one embodiment the claimed invention relates to a method for improving the energy efficiency of adsorptive gas separation system during the times of reduced product demand, wherein system comprises: [0031] a. at least one vessel containing at least one adsorption bed comprising at least one adsorption material, and [0032] b. at least one compressor,
[0033] wherein the at least one adsorption bed is configured for cyclical pressurization and depressurization during operation for separation of components of a feed gas mixture into at least a first component and a second component by selective adsorption of said first component into said adsorption bed comprising at least one adsorbent, said method comprising the following steps on a cyclic basis: [0034] I. raising the pressure of a feed gas to said bed during the adsorption steps of the cycle to an adsorption pressure so as to enable adsorption of said first component by said adsorbent, said adsorbent exhibiting a mass transfer coefficient of >=12/s and an intrinsic N2 diffusivity of 3.5×10.sup.−6 m2/s at 1.5 bar and 300 k, [0035] II. depressurizing said bed during the desorption steps of said cycle to a desorption pressure so as to desorb said first component from said adsorbent, the ratio of pressures of said adsorption pressure to said desorption pressure in a range of from about 1.5 to 6.0;
wherein during times of reduced product demand, said method comprises lowering the top adsorption pressure to a range of from about 75% to 90% of design maximum operation pressure of said at least one adsorption vessel to lower production capacity while achieving higher energy efficiency.
[0036] From Table 1 it can be seen that reducing the top pressure to 90% of design operational top pressure reduces production to 80% of normal production. Normal production refers to contract specified oxygen production of the system.
[0037] The design operational top pressure is defined as the maximum pressure achieved by any vessel during a cycle in order to achieve contract specified oxygen production (within a 5% margin) at contract specified power consumption (within a 5% margin) during contract specified ambient conditions (Temperature+/−2 C, pressure+/−0.05 bar, humidity(+/−15%, etc.). This usually corresponds to the lowest cost of production of oxygen with a given set of equipment. In this invention, the novel benefit is that during times of reduced consumption the claimed method reduces the relative power consumption of the system by fully utilizing the system capital. The operating costs are now lower with this new method, and substantially lower than traditional methods to operate at reduction production compared to the contract design case.
[0038] Feed unload time is the time that the feed compressor vents to atmosphere. The feed unload step is the step where the feed compressor is venting to atmosphere. In common operation, adsorbent vessels typically engage in an equalization step at this time where gas from one vessel is passed to a second vessel or to a tank that can hold the gas.
[0039] Pressure ratio for VPSA is 2.3 to 6 with typical range of 2.5 to 3.5. Pressure ratio for PSA is 3 to 8 with typical range of 4-6.
[0040] In some embodiments, at least one adsorbent bed is cyclically pressurized by at least one feed compressor and sometimes evacuated by at least one vacuum compressor, with at least one feed compressor or the at least one vacuum compressor being a centrifugal compressor driven by an associated high-speed induction motor designed for variable high-speed operation. In such embodiments, the compressor that is not a centrifugal compressor can be a rotary-lobe blower driven by the induction motor.
[0041] In some embodiments of the present invention, the adsorbent bed is cyclically pressurized by at least one feed centrifugal compressor driven by an associated high-speed induction variable-speed motor and, evacuated by at least one vacuum centrifugal compressor driven by an associated high-speed induction variable-speed motor. More specifically and in accordance with the present invention, the centrifugal feed compressor(s) and/or centrifugal vacuum compressor(s) are driven by direct drive high-speed induction motors for variable-speed operation such that the compressor and high-speed induction motor combination(s) can accelerate from low-speed to high-speed and decelerate from high-speed to low-speed in rapid rates required by shorter cycle times of current PSA or VPSA systems and processes.
[0042] Use of variable-speed controlled high-speed permanent magnet or induction motors allows for an order of magnitude improvement over conventional low-speed induction motor/gearbox systems in their ability to accelerate and slow down the centrifugal compressor in a PSA or VPSA process. Using high-speed motors allows for the elimination of the necessity for gearboxes and thus likewise allows for the elimination of the necessity of lube oil systems. The centrifugal compressor(s) can thus be supported on oil free bearings. Furthermore, in some embodiments, the proposed drive systems of the present invention are expected to be more efficient by over 7 percentage points with the elimination of gear and bearing oil friction losses, lube oil system losses, and an improved ability to lead/lag power.
[0043] To achieve the high efficiency of centrifugal compressors, it is essential that the compressors are operated along a peak efficiency line. The peak efficiency line is a line drawn on a compressor performance map. As discussed herein, a compressor performance map (pressure ratio vs. mass flow at various speeds) is generated from the isentropic work coefficient at various speeds for a specific inlet temperature to the compressor. The peak efficiency line represents the loci of points that correspond to all the peak efficiency points of the compressor operating curves at different speeds. By operating along the peak efficiency line, the compressor(s) can be operated at its most efficient mode in terms of power consumption.
[0044] The performance map(s) can also be in the form of lookup or reference tables generated from the isentropic work coefficient. The performance maps and resulting best efficiency lines can be stored in a programmable logic controller (PLC) and integrated with the PSA and or VPSA systems.
[0045] While not to be construed as limiting, the present invention is implemented in PSA or VPSA adsorption processes that separate gases, such as air into oxygen and nitrogen. Other gas separations processes that can benefit from the use of the present invention include, but are not limited to, PSA and or VPSA separations involving the recovery of gases such as O.sub.2, N.sub.2, CO.sub.2, H.sub.2 or He.
[0046] A VPSA plant typically has 3 pieces of rotating equipment as illustrated in
[0047] VPSA plants are conventionally designed to meet maximum production requirements even though customers often require lesser amount of oxygen production most of the time. Consequently, VPSA plants are routinely operated at turn down mode. Having an energy efficient turn down method enables VPSA plant to achieve high energy efficiency over operating window of plant and reduces the energy cost.
[0048] Typical VPSA plant turn down operation is accomplished through intermittently running the plant by extending certain cycle step time without changing the feed flow, adsorption and desorption pressure range. This mode of operation has inherently higher unit power since the motor and compressor are still running while the system is not producing product. Alternatives are to turn the motor and compressor off when the plant is not running however this is neither practiced nor preferred because of machine control and wear from frequent startup and shutdowns due to the short VPSA cycle steps.
[0049] Conventional VPSA turn down is accomplished through feeding the same amount of flow and extending the cycle time. If the goal is to produce 80% of oxygen product, one can use the conventional VPSA turn down method by simply extending the cycle time while keeping the feed flow and top pressure the same, the energy consumption and oxygen recovery from turn down is less than the normal production. In other words, tune down performance is not as efficient as if the plant is producing 100% production.
[0050] An improved more energy efficient method of producing, as an example, 80% oxygen product is to lower top adsorption pressure. One skilled in the art would typically expect low top pressure would yield negative VPSA performance results, since the adsorption capacity is reduced at lower top adsorption pressure. To compensate the lower adsorption capacity from the lower top pressure, one has to increase the feed flow and shorten the cycle, both would contribute to the negative recovery impact. However, the energy saving benefit from the lower top pressure surprisingly out weights the negative impacts of recovery drop from the increased feed flow and shorter cycle.
[0051] A further improvement to the turn down method is to provide lower feed flow and reduce top pressure to take advantage of reduced feed velocity to the adsorbent vessel to maximize the recovery. The lower top pressure from the adsorbent vessel translates into the lower suction pressure of the oxygen product compressor. By employing the direct drive variable high speed centrifugal product compressor, one can speed up the motor to increase the pressure ratio from the compressor, therefore achieve the same product pressure as if the suction pressure remains the same level.
[0052] In a VPSA system, the top pressure of the adsorbent vessel can be lowered while maintaining control over the product flow rate by reducing the pressure restriction in the system. This can be accomplished by increasing the opening of product control valve 68 (at all times), valve 62/64 (during product make of the corresponding bed) or valve 60 (during product make) further. This will inherently increase the flow rate which can to be balanced by increasing the feed unload time. This can be done by decreasing total adsorption/product make step time or increasing the feed unload step time. Increasing the feed unload step time has the side effect of lowering the vacuum pressure, which may be desirable in some situations where the system may run more efficiently. This is plant specific and evaluated on a case by case basis as it can be affected by adsorbent characteristics, loading procedure, vessel construction, plant piping layout, etc. If a product centrifugal compressor is being used, this product machine speed can be increased to enable a lower suction pressure. This can be used in combination with or before changing the pressure restriction in valves 68, 62/64 or 60. Flow rate balancing will still need to be accomplished by adjusting the feed unload time.
[0053] Additional top pressure and flowrate adjustment can be accomplished if the VPSA feed/vacuum compressors are variable, one example being a centrifugal compressor with a variable frequency drive. In these cases, the compressor(s) can be slowed to produce a lower pressure ratio while still maintaining a constant flowrate. In order to balance the lower top pressure either valves 68, 62/64 or 60 or a centrifugal product compressor or some combination therein must still be adjusted. But the cycle timing does not need to change to balance the flowrate as the machine is adjusting the flowrate already. Adjustments in a PSA system are substantially the same with the exception that a PSA system does not have a vacuum compressor.
[0054] Additional top pressure and flowrate adjustment can be accomplished if the VPSA feed/vacuum compressors are variable, one example being a centrifugal compressor with a variable frequency drive. In these cases, the compressor(s) can be slowed to produce a lower pressure ratio while still maintaining a constant flowrate.
[0055] If a product centrifugal compressor is being used, this product machine speed can be increased to enable a lower suction pressure. This can be used in combination with or before changing the pressure restriction in valves 68, 62/64 or 60 shown in
[0056] The new proposed turn down method achieves significant energy consumption reduction over conventional constant feed flow turn down method as illustrated by simulation results in Table 1.
TABLE-US-00001 TABLE 1 VPSA performance summary of turndown methods: Unit Power Feed KW/ Cycle Turn Down Flow Production Top MTPD Time Methods Air Oxygen Pressure O2 Sec Recovery VPSA 100% 100% 100% 100% 100% 100% VPSA- 100% 80% 100% 110% 140% 96% Traditional TD VPSA- 110% 80% 90% 95% 70% 90% New TD Lower Top P, More Feed F VPSA- 75% 80% 90% 85% 100% 105% New TD Lower Top P, Lower Feed F
[0057] The invention can be implemented in a (Vacuum) Pressure Swing Adsorption system with various PSA/VSA/VPSA cycles. A pressure swing adsorption system separates components of a feed gas mixture into at least a first component and a second component by selective adsorption of said first component into a bed of adsorbent. The pressure swing adsorption cycle consists of the basic steps of raising the pressure of feed gas during adsorption steps to an adsorption top pressure so as to enable adsorption of first component, depressurizing said bed during the desorption steps to a desorption pressure.
[0058] The desired low pressure is >than about 0.1 atm and the desired high pressure is <about 100 atm. In another embodiment the low pressure in the cycle is ≥0.3 atm and the high pressure in the cycle that is ≤6 atm.
[0059] A ratio of pressures of said adsorption pressure to said desorption pressure for oxygen VPSA referenced in this invention is typically less than 6.0, in one embodiment ranging from about 1.5 to about 6, in another embodiment from about 1.5 to about 3.5.
[0060] The PSA/VPSA systems which the proposed turn down method are beneficial can comprise a single adsorption bed, two adsorption beds in a single train, wherein one adsorption bed is in feed mode while the other adsorption bed is in regeneration mode, or multiple adsorption beds beyond two beds.
[0061] A variety of adsorbents can be used in the process of the invention. In one embodiment a LiX adsorbent can be used. In another embodiment any faujasite type with any cation of Li, Ca, Na, K or mixed cation configuration can be employed. This invention works with high rate adsorbents defined as a mass transfer coefficient of >=12/s and an intrinsic N.sub.2 diffusivity of >3.5×10.sup.−6 m2/s at 1.5 bar and 300 k.
[0062] The percent energy improvement will be impacted by the base system configuration and referenced adsorbent, and compression machine efficiencies. The above simulations results are illustrative of the invention using LiX adsorbent with exhibiting a mass transfer coefficient of >=12/s and an intrinsic N.sub.2 diffusivity of >3.5×10.sup.−6 m.sup.2/s at 1.5 bar and 300 k for achieving oxygen product from air feed.
[0063] Various alternatives and modifications can be devised by those skilled in the art without departing from the invention. Accordingly, the present invention is intended to embrace all such alternatives, modifications and variances which fall within the scope of the appended claims.
[0064] With the lower top pressure from the adsorb vessel, the suction pressure to the product compressor will be lower than if VPSA employs the conventional constant feed and constant top adsorption pressure methods.
[0065] With the lower flow and inlet suction pressure into the product compressor, the final desired pressure can be achieved through increased motor speed and increased stage pressure ratio. For the centrifugal product compressor with high speed motor and VFD, the compressor operates at the design point of the compressor (pressure, flow, and speed). one can increase the flow from this machine by increasing the speed while maintaining the same outlet pressure.
[0066]
[0067] For a centrifugal compressor with high-speed motor and VFD, the compressor can speed up with lower flow to increase the pressure ratio and achieve the desired higher final pressure. This concept is shown in
[0068] For a single stage direct drive high speed centrifugal compressor, the range of the turn down may be extended through the combination of varying compressor speed and varying recirculation flow to address the reduced feed flow and lower suction pressure.
[0069] The turn down range can be extended by employing inlet guide vane and varying angles of the inlet guide vane.
[0070] The described turn method of increasing motor speed and increasing compressor stage pressure ratio can be extended to multiple stage compressors with further extended operating range.
[0071] With lower feed flow and lower suction pressure, one can lower the first stage pressure ratio, increase pressure ratios for second and/or third stages to achieve the desired final pressure. Pressure ratio change can be accomplished through varying compressor speeds through direct drive high speed motor.