LIQUID CRYSTAL MIXTURE AND LIGHT MODULATING DEVICE

Abstract

Disclosed herein is a liquid crystal mixture applied in light compounds selected from the group of compounds of formula (I), component B comprised of one or more compounds selected from the group of compounds of formula (II), and component C comprised of one or more the liquid crystal mixture, wherein the liquid crystal mixture has higher stability of electrical performance and the light modulating device has improved optical performance.

##STR00001##

Claims

1. A liquid crystal mixture applied in light modulating devices, comprising: component A comprised of one or more compounds selected from the group of compounds of formula I
R.sub.1-MG.sub.1-X-MG.sub.2-R.sub.2  I; component B comprised of one or more compounds selected from the group of compounds of formula II ##STR00041## and component C comprised of one or more chiral compounds, wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each independently denote —H, —F, —Cl or a chain alkyl group with 1 to 25 C atoms where one or more H atom may be independently substituted by halogen and one or more nonadjacent —CH.sub.2— may be independently replaced by —O—, —CH═CH—, —CH═CF— or —CF═CF—, MG.sub.1 and MG.sub.2 each independently denote a mesogenic group, X is a straight-chain or branched alkyl group with 3-40 C atoms where one or more —CH.sub.2— may be independently replaced by —O—, —CH(F)—, —CH(Cl)— or —CH═CH— in such a manner that no two —O— or double bonds are adjacent to one another, H.sub.1, H.sub.2 and H.sub.3 each independently denote a ring structure selected from the group of ##STR00042## and their mirror structures where one or more H atoms may be independently substituted by halogen or a alkyl group with 1-10 C atoms, A.sub.1 and A2 each independently denote —CF.sub.2O—, —OCF.sub.2—, —CH.sub.2O—, —OCH2—, —CH═CH—, —CF.sub.2CF.sub.2—, —CF═CF—, —CH═CF—, a single bond or —(CH.sub.2).sub.a— where a is an even number between 2-10, m is 0,1 or 2, n is 1, 2 or 3, o is 1 or 2, and m+n+o is no more than 5.

2. The liquid crystal mixture as defined in claim 1, wherein the component B is more than 40% by weight of the liquid crystal mixture.

3. The liquid crystal mixture as defined in claim 1, wherein the mesogenic group is each independently selected from the group of formula III ##STR00043## wherein, H.sub.4, H.sub.5, H.sub.6 and H.sub.7 each independently denote a ring structure selected from the group of ##STR00044## and their mirror structures, wherein one or more H atoms of the ring structures may be independently substituted by halogen or a chain alkyl group with 1-7 C atoms where one or more nonadjacent —CH.sub.2— may be replaced by —O— and one or more H atom may be substituted by F or Cl, A.sub.3, A.sub.4 and As each independently denote —CF.sub.2O—, —OCF.sub.2, —CH.sub.2O—, —OCH.sub.2—, —CH.sub.2CH.sub.2—, —CF.sub.2CF.sub.2—, —CH═CH—, —CF═CF—, —CH═CF— or a single bond, p and q each independently denote 0 or 1.

4. The liquid crystal mixture as defined in claim 3, wherein the mesogenic group each independently comprises at least two six-membered rings.

5. The liquid crystal mixture as defined in claim 4, wherein the mesogenic group is each independently selected from the group of ##STR00045## and their mirror structures, wherein 1-4 H atoms of the six-membered ring may be independently substituted by F, Cl or a chain alkyl group with 1-7 C atoms where one or more nonadjacent —CH.sub.2— may be replaced by —O— and one or more H atom may be substituted by F.

6. The liquid crystal mixture as defined in claim 1, wherein X is selected of formula IV ##STR00046## where Y.sub.1 and Y.sub.2 each independently denote —O— or a single bond, and s is an odd number between 3 and 13.

7. The liquid crystal mixture as defined in claim 1, wherein R.sub.1 and R.sub.2 each independently denote —H, —F, —Cl, —OCF.sub.3, —OCHF.sub.2, —CF.sub.3 or an unsubstituted chain alkyl or alkoxyl group with 1 to 10 C atoms.

8. The liquid crystal mixture as defined in claim 1, wherein the chiral compound is selected from the group of ##STR00047## ##STR00048##

9. A light modulating device comprising the liquid crystal mixture as defined in claim 1, including two stable states: a transparent state where substantially all incident light goes through and a light scattering state where substantially all incident light is scattered.

10. The light modulating device as defined in claim 9, wherein the component A is 1%-60% by weight of the liquid crystal mixture.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0038] These and other features and advantages of the present invention will be better understood by reference to the following detailed description of an illustrative embodiment of the present disclosure when read in conjunction with the accompanying drawings, wherein:

[0039] FIG. 1 is a schematic, illustrative view of the structure of the light modulating device according to one embodiment;

[0040] FIG. 2 is a schematic, illustrative view of the structure of the light modulating device according to another embodiment;

[0041] FIG. 3 is a schematic, illustrative view of the structure of the light modulating device according to another embodiment.

DETAILED DESCRIPTION OF THE INVENTION

[0042] The following description of the disclosed embodiments is provided in detail to enable any person skilled in the art to fully understand the present invention. However, it will be apparent to those skilled in the art to readily make or use the present invention without these specific details. In other examples, well-known structures and devices are shown in the block diagram. In this regard, the description of the different illustrative exemplary embodiments presented herein are for the purpose of illustration and description and are not intended to be exhaustive or limited to the inventive concept. Accordingly, the scope of the invention is not to be limited by the specific embodiments described above, and is subject only to the scope of the appended claims.

[0043] The present invention discovers a liquid crystal mixture which can be applied in light modulating devices. The liquid crystal mixture comprises: component A comprised of one or more compound selected from the group of compounds of formula I: R.sub.1-MG.sub.1-X-MG.sub.2-R.sub.2; component B comprised of one or more compounds selected from the group of compounds of formula II:

##STR00017##

[0044] and component C comprised of one or more chiral compounds, wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each independently denote —H, —F, —Cl or a chain alkyl group with 1 to 25 C atoms where one or more H atom may be independently substituted by halogen and one or more nonadjacent —CH.sub.2— may be independently replaced by —O—, —CH═CH—, —CH═CF— or —CF═CF—; MG.sub.1 and MG.sub.2 each independently denote a mesogenic group; X is a straight-chain or branched alkyl group with 3-40 C atoms where one or more —CH.sub.2— may be independently replaced by —O—, —CH(F)—, —CH(Cl)— or —CH═CH— in such a manner that no two —O— or double bonds are adjacent to one another; H.sub.1, H.sub.2 and H.sub.3 each independently denote a ring structure selected from the group of

##STR00018##

[0045] and their minor structures where one or more H atoms may be independently substituted by halogen or a alkyl group with 1-10 C atoms; A.sub.1 and A.sub.2 each independently denote —CF.sub.2O—, —OCF.sub.2—, —CH.sub.2O—, —OCH.sub.2—, —CH═CH—, —CF.sub.2CF.sub.2—, —CF═CF—, —CH═CF—, a single bond or —(CH.sub.2).sub.a— where a is an even number between 2-10; m is 0,1 or 2, n is 1, 2 or 3, o is 1 or 2, and m+n+o is no more than 5.

[0046] The mesogenic group is selected from the group of formula III:

##STR00019##

[0047] wherein H.sub.4, H.sub.5, H.sub.6 and H.sub.7 each independently denote a ring structure selected from the group of

##STR00020##

[0048] and their minor structures, wherein one or more H atoms of the ring structures may be independently substituted by halogen or a chain alkyl group with 1-7 C atoms where one or more nonadjacent —CH.sub.2— may be replaced by —O— and one or more H atom may be substituted by F or Cl; A.sub.3, A.sub.4 and A.sub.5 each independently denote —CF.sub.2O—, —OCF.sub.2—, —CH.sub.2O—, —OCH.sub.2—, —CH.sub.2CH.sub.2—, —CF.sub.2CF.sub.2—, —CH═CH—, —CF═CF—, —CH═CF— or a single bond; p and q each independently denote 0 or 1.

[0049] Preferably, the mesogenic group each independently comprises at least two six-membered rings. More preferably, the mesogenic group is each independently selected from the group of

##STR00021##

[0050] and their minor structures, wherein 1-4 H atoms of the six-membered ring may be independently substituted by F, Cl or a chain alkyl group with 1-7 C atoms where one or more nonadjacent —CH.sub.2— may be replaced by —O— and one or more H atom may be substituted by F. More preferably, 1-4 H atoms of the six-membered ring may be independently substituted by F, Cl, CH.sub.3 or OCH.sub.3.

[0051] Preferably, X is a straight-chain or branched alkyl group with 5-25 C atoms where one or more —CH.sub.2— may be independently replaced by —O—, —CH(F)—, —CH(Cl)— or —CH═CH— in such a manner that no two —O— or double bonds are adjacent to one another. More preferably, X is a straight-chain or branched alkyl group with 5-15 C atoms where one or more —CH.sub.2— may be independently replaced by —O—, —CH(F)—, —CH(Cl)— or —CH═CH—in such a manner that no two —O— or double bonds are adjacent to one another. More preferably, X is selected of formula IV:

##STR00022##

[0052] where Y.sub.1 and Y.sub.2 each independently denote —O— or a single bond, and s is an odd number between 3 and 13.

[0053] Preferably, R.sub.1 and R.sub.2 each independently denote —H, —F, —Cl, —OCF.sub.3, —OCHF.sub.2, —CF.sub.3 or an unsubstituted chain alkyl or alkoxyl group with 1 to 10 C atoms. More preferably, R.sub.1 and R.sub.2 each independently denote —F, —Cl, —O—CF.sub.3 or an unsubstituted chain alkyl or alkoxyl group with 1 to 5 C atoms.

[0054] Preferably, the compound of formula I is selected from the group of compounds I-1 to I-21:

##STR00023## ##STR00024## ##STR00025##

[0055] Preferably, the compound of formula II is selected from the group of compounds II-1 to II-24:

##STR00026## ##STR00027## ##STR00028## ##STR00029##

[0056] The chiral compounds can induce the spiral twisting of nematic liquid crystal molecules, forming chiral nematic liquid crystal (cholesteric liquid crystal). Preferably, the chiral compound is selected from the group of:

##STR00030## ##STR00031##

[0057] Generally, the liquid crystal mixture was prepared in accordance with the ratio specified in the following examples. The preparation is carried out in accordance with a conventional method in the art. In detail, each component is weighed according to its corresponding mass percentage, and placed in a glass bottle. After a magnetic stiffing bar is added, the bottle is placed on a heating magnetic stirrer, and the liquid crystal mixture is heated and stirred until completely melting to form an isotropic transparent solution. The temperature at this point has reached the clear point of the liquid crystal mixture. If the liquid crystal mixture contains a light-sensitive compound, the liquid crystal mixture must be heated to the clear point in the dark. The liquid crystal mixture continues to be heat in the temperature for 30 minutes to ensure uniform mixing, and then the liquid crystal continues to be stirred for another 2 hours. In order to ensure sufficient and stable miscibility of the liquid crystal mixture, as well as, forming of liquid crystal state in an appropriate temperature range, the mass percentage of component B in the liquid crystal mixture should be more than 40%. Preferably, the mass percentage of the component B in the liquid crystal mixture is 40%-95%. The mass percentage of component A in the liquid crystal is 1%-60%. Preferably, the mass percentage of component A is 10%-50% in the liquid crystal mixture.

[0058] After that, the uniformly mixed liquid crystal mixture is poured into an empty liquid crystal cell prepared according to various design requirements by a vacuum-filled method, and then the cell is sealed by a UV adhesive, forming a light modulating device. The light modulating device has two stable states: a transparent state and a light scattering state. In the transparent state, the chiral nematic liquid crystal (cholesteric liquid crystal) molecules are substantially aligned parallel to the device substrate, and the helical axis thereof is perpendicular to the device substrate to form the planar texture of cholesteric liquid crystal. In this state, the incident light transmits through the light modulating device substantially unaffected. While in the light scattering state, the cholesteric liquid crystal molecules form a focal conic texture, and the incident light is substantially scattered, causing large haze. By selecting a suitable driving voltage, the light modulating device may be switched between the transparent state and the light scattering state, where the haze is measured using a WGT-S type haze meter to determine its optical performance.

[0059] The structure of the light modulating device is shown in FIG. 1, wherein the first transparent substrate 101 and the second transparent substrate 102 may be made of a hard material (such as transparent glass) or a flexible material (such as PET, PEN, PC, PP, PMMA, PBT, PVC, PI, cellulose, etc.). The invention is not limited to this, and other materials with light transmission conforming to the requirements may also be used. The liquid crystal layer 103 is disposed between the first transparent substrate 101 and the second transparent substrate 102, which contains the liquid crystal mixture. The first transparent electrode 104 is disposed between the first transparent substrate 101 and the liquid crystal layer 103, while the second transparent electrode 105 is disposed between the second transparent substrate 102 and the liquid crystal layer 103. Depending on its materials, the transparent electrodes may be classified into carbon-based conductive films, metallic nanowire conductive films, and metallic oxide conductive films. In the following examples, the materials of the first transparent electrode 104 and the second transparent electrode 105 is ITO. The thickness of the liquid crystal layer 103 is 5-60 micrometers.

[0060] In some embodiments, a first alignment layer 106 may be disposed between the first transparent electrode 104 and the liquid crystal layer 103, as shown in FIG. 2. The alignment layer 106 serves to align the liquid crystal molecules in the liquid crystal layer 103 in a predetermined pattern. In some embodiments, as shown in FIG. 3, a second alignment layer 107 may be further disposed between the second transparent electrode 105 and the liquid crystal layer 103. Depending on the pretilt angle (i.e. the angle between the long axis of the liquid crystal molecules and the surface of the alignment layer when the liquid crystal molecules are sequentially arranged on the surface of the alignment layer), the alignment layer can be classified into homogenous alignment where the long axis is substantially parallel to the surface, such as IPS, TN or STN type, or heterogeneous alignment where the long axis is substantially vertical to the surface, such as VA type.

[0061] Under the external environment (such as long-term UV exposure, extreme temperature changes, exposure to moisture or dust, etc.), the liquid crystal materials are easy to decompose and release ions. Excessive ion charges will reduce the voltage holding rate (VHR) and resistivity of the liquid crystal materials, therefore affecting the electro-optic performance. Meanwhile, excessive ion charges are accumulated on the contact surface between the liquid crystal layer and the alignment layer, causing the effective voltage applied on the liquid crystal molecules decreases with the accumulation of ion charges. As a result, the liquid crystal molecules cannot be rapidly rotated in the moment of voltage switching, affecting the stability and uniformity of optical performance of the light modulating device. In the following examples, the stability of electrical performance of the liquid crystal mixture is revealed by measuring the drop in resistivity of the liquid crystal mixture. The resistivity is measured in the initial state, after UV irradiation (wavelength: 365 nm, light intensity: 85 mW/cm.sup.2, exposure time: 1 hour) and after heat treatment (temperature: 150° C., time: 1 hour). The instrument used in the measurements is INSTEC ALCR-HR1 resistance meter.

[0062] In the following examples, the component of the liquid crystal mixture, the optical performance of the light modulating device and the stability of electrical performance of the liquid crystal mixture will be described in detail. The first transparent substrate 101 and the second transparent substrate 102 in the following examples are transparent glasses, and the first transparent electrode 104 and the second transparent electrode 105 are ITO. There are two alignment layer which are both VA type.

[0063] In the following examples, the group structures of the liquid crystal molecules are represented by the codes listed in Table 1, and the codes and structures of component C are listed in Table 2. The ratios all refer to mass percentages.

TABLE-US-00001 TABLE 1 the code for groups of liquid crystal Code Group structure H [00032] O —O— P [00033] P.sup.11 [00034] P.sup.12 [00035] P.sup.21 [00036] R.sup.22 [00037] Q —CF2O— F —F N —CN E [00038] n —C.sub.nH.sub.2n+1 or —C.sub.nH.sub.2n—

[0064] where, if n=3, the group is —C.sub.3H.sub.7 (at the end of formula) or —C.sub.3H.sub.6— (in the middle of formula).

TABLE-US-00002 TABLE 2 The code and structure of other additives Code Structure L-4 [00039] R05 [00040]

COMPARATIVE EXAMPLE

[0065]

TABLE-US-00003 TABLE 3 formula of liquid crystal mixture Component Ratio/% 5PPN 20.0 3PP.sup.11PN 16.0 2PPN 7.0 5HPPN 9.0 5PPPN 4.0 5OPPN 16.0 6OPPN 8.0 4PEP.sup.11N 15.0 L04 5.0 Total 100

TABLE-US-00004 TABLE 4 optical performance data for the light modulating device and electrical performance data for the liquid crystal mixture Electrical performance Optical performance Resistivity (10.sup.12 Ω-cm) Cell gap/μm 20 Initial state 0.260 Initial state 0.150 Haze in the 48.0 After UV 0.004 After heating 0.006 transparent state/% irradiation treatment Haze in the light 79.7 Drop 98.46% Drop 96.00% scattering state/%

Example 1

[0066]

TABLE-US-00005 TABLE 5 formula of liquid crystal mixture Component Ratio/% Component A FP.sup.12P9PP.sup.11F 15.0 Component B 3PP.sup.11P2 4.0 3HPP.sup.21F 4.0 5HPP.sup.21F 8.0 3HPP11F 4.0 5HPP.sup.11F 4.0 3PP.sup.11P.sup.21F 8.0 3HHPP.sup.21F 8.0 3HHP.sup.11P.sup.21F 8.0 3PP.sup.21QP.sup.21F 8.0 3PP.sup.11P.sup.21QP.sup.21F 8.0 4PP.sup.11P.sup.21QP.sup.21F 8.0 5PP.sup.11P.sup.21QP.sup.21F 8.0 Component C L04 5.0 Total 100

TABLE-US-00006 TABLE 6 optical performance data for the light modulating device and electrical performance data for the liquid crystal mixture Electrical performance Optical performance Resistivity (10.sup.12 Ω-cm) Cell gap/μm 20 Initial state 11.33 Initial state 10.97 Haze in the 7.6 After UV 4.69 After heating 5.31 transparent state/% irradiation treatment Haze in the light 78.2 Drop 58.61% Drop 51.60% scattering state/%

Example 2

[0067]

TABLE-US-00007 TABLE 7 formula of liquid crystal mixture Component Ratio/% Component A FP.sup.12P7PP.sup.11F 29.9 Component B 3HPO1 1.2 3PP.sup.11P2 3.1 3HPP.sup.21F 4.3 5HPP.sup.21F 7.9 2PP.sup.11P.sup.21F 2.4 3PP.sup.11P.sup.21F 6.1 3HHPP.sup.21F 4.9 3HHP.sup.11P.sup.21F 1.8 3PP.sup.11P.sup.21QP.sup.21F 9.8 4PP.sup.11P.sup.21QP.sup.21F 9.8 5PP.sup.11P.sup.21QP.sup.2IF 9.8 Component C L04 9.0 Total 100

TABLE-US-00008 TABLE 8 optical performance data for the light modulating device and electrical performance data for the liquid crystal mixture Electrical performance Optical performance Resistivity (10.sup.12 Ω-cm) Cell gap/μm 20 Initial state 11.80 Initial state 11.44 Haze in the 0.8 After UV 6.20 After heating 6.27 transparent state/% irradiation treatment Haze in the light 75.3 Drop 47.46% Drop 45.19% scattering state/%

Example 3

[0068]

TABLE-US-00009 TABLE 9 formula of liquid crystal mixture Component Ratio/% Component A FP.sup.12P7PP.sup.11F 29.0 FPP.sup.12O7OP.sup.11PF 1.0 Component B 3PP.sup.11P2 3.3 3HPP.sup.21F 3.3 5HPP.sup.21F 6.5 3HP.sup.11P.sup.21F 3.3 3HPP.sup.11F 3.3 3PP.sup.11P.sup.21F 5.2 3HHPP.sup.21F 6.5 4HHPP.sup.21F 6.5 3PP.sup.21QP.sup.21F 6.5 3PP.sup.11P.sup.21QP.sup.21F 7.6 4PP.sup.11P.sup.21QP.sup.21F 6.5 5PP.sup.11P.sup.21QP.sup.21F 6.5 Component C L04 5.0 Total 100

TABLE-US-00010 TABLE 10 optical performance data for the light modulating device and electrical performance data for the liquid crystal mixture Electrical performance Optical performance Resistivity (10.sup.12 Ω-cm) Cell gap/μm 20 Initial state 13.70 Initial state 12.99 Haze in the 1.2 After UV 6.59 After heating 6.86 transparent state/% irradiation treatment Haze in the light 79.9 Drop 51.90% Drop 47.19% scattering state/%

Example 4

[0069]

TABLE-US-00011 formula of liquid crystal mixture Component Ratio/% Component A FP.sup.12P7PP.sup.11F 10.0 FP.sup.12P9PP.sup.11F 10.0 FP.sup.12P.sup.11PP.sup.11F 10.0 Component B 3PP.sup.11P2 3.3 3HPP.sup.21F 3.3 5HPP.sup.21F 6.5 3HPP.sup.11F 3.2 5HPP.sup.11F 3.2 3PP.sup.11P.sup.21F 6.5 3HHPP.sup.21F 6.5 3HHP.sup.11P.sup.21F 6.5 3PP.sup.21QP.sup.21F 6.5 3PP.sup.11P.sup.21QP.sup.21F 6.5 4PP.sup.11P.sup.21QP.sup.21F 6.5 5PP.sup.11P.sup.21QP.sup.21F 6.5 Component C L04 5.0 Total 100

TABLE-US-00012 TABLE 12 optical performance data for the light modulating device and electrical performance data for the liquid crystal mixture Electrical performance Optical performance Resistivity (10.sup.12 Ω-cm) Cell gap/μm 50 Initial state 12.50 Initial state 13.08 Haze in the 5.7 After UV 5.93 After heating 6.89 transparent state/% irradiation treatment Haze in the light 91.2 Drop 52.56% Drop 47.32% scattering state/%

Example 5

[0070]

TABLE-US-00013 TABLE 13 formula of liquid crystal mixture Component Ratio/% Component A FP.sup.12P7PP.sup.11F 28.0 3HP7PH3 1.0 FPPP7PPPF 1.0 Component B 3PP.sup.11P2 3.3 3HPP.sup.21F 3.3 5HPP.sup.21F 6.5 3HPP.sup.11F 3.2 5HPP.sup.11F 3.2 3PP.sup.11P.sup.21F 6.5 3HHPP.sup.21F 6.5 3HHP.sup.11P.sup.21F 6.5 3PP.sup.21QP.sup.21F 6.5 3PP.sup.11P.sup.21QP.sup.21F 6.5 4PP.sup.11P.sup.21QP.sup.21F 6.5 5PP.sup.11P.sup.21QP.sup.21F 6.5 Component C L04 5.0 Total 100

TABLE-US-00014 TABLE 14 optical performance data for the light modulating device and electrical performance data for the liquid crystal mixture Electrical performance Optical performance Resistivity (10.sup.12 Ω-cm) Cell gap/μm 20 Initial state 13.40 Initial state 12.57 Haze in the 6.1 After UV 6.54 After heating 6.32 transparent state/% irradiation treatment Haze in the light 78.8 Drop 51.19% Drop 49.72% scattering state/%

Example 6

[0071]

TABLE-US-00015 TABLE 15 formula of liquid crystal mixture Component Ratio/% Component A FP.sup.12P7PP.sup.11F 30.0 FP.sup.12P9PP.sup.11F 5.0 Component B 3PP.sup.11P2 3.0 3HPP.sup.21F 3.0 5HPP.sup.21F 6.5 3HPP.sup.11F 3.0 5HPP.sup.11F 3.0 3PP.sup.11P.sup.21F 6.5 3HHPP.sup.21F 6.5 3HHP.sup.11P.sup.21F 6.5 3PP.sup.21QP.sup.21F 6.5 3PP.sup.11P.sup.21QP.sup.21F 6.5 4PP.sup.11P.sup.21QP.sup.21F 6.5 5PP.sup.11P.sup.21QP.sup.21F 6.5 Component C R05 1.0 Total 100

TABLE-US-00016 TABLE 4 optical performance data for the light modulating device and electrical performance data for the liquid crystal mixture Electrical performance Optical performance Resistivity (10.sup.12 Ω-cm) Cell gap/μm 20 Initial state 12.90 Initial state 11.94 Haze in the 1.1 After UV 6.01 After heating 6.23 transparent state/% irradiation treatment Haze in the light 75.8 Drop 53.41% Drop 47.82% scattering state/%

Example 7

[0072]

TABLE-US-00017 TABLE 17 formula of liquid crystal mixture Component Ratio/% Component A FP.sup.12P7PP.sup.11F 30.0 FP.sup.12P11PP.sup.11F 10.0 Component B 3PP.sub.11P2 2.8 3HPP.sup.21F 2.8 5HPP.sup.21F 5.5 3HPP.sup.11F 2.7 5HPP.sup.11F 2.7 3PP.sup.11P.sup.21F 5.5 3HHPP.sup.21F 5.5 3HHP.sup.11P.sup.21F 5.5 3PP.sup.21QP.sup.21F 5.5 3PP.sup.11P.sup.21QP.sup.21F 5.5 4PP.sup.11P.sup.21QP.sup.21F 5.5 5PP.sup.11P.sup.21QP.sup.21F 5.5 Component C L04 5.0 Total 100

TABLE-US-00018 TABLE 18 optical performance data for the light modulating device and electrical performance data for the liquid crystal mixture Electrical performance Optical performance Resistivity (10.sup.12 Ω-cm) Cell gap/μm 20 Initial state 11.70 Initial state 11.32 Haze in the 1.0 After UV 6.05 After heating 6.07 transparent state/% irradiation treatment Haze in the light 68.8 Drop 48.29% Drop 46.38% scattering state/%

[0073] From the above examples and comparative example, it is demonstrated that the light modulating device containing the liquid crystal mixture of the present invention has a significantly low haze in the transparent state and an ultra-high haze in the light scattering state, thereby providing high light transmittance while keeping sufficient privacy and isolation. Meanwhile, After UV irradiation or heating treatment, the drop degree of resistivity in examples 1-7 is significantly smaller than that in the comparative example, indicating stability of electrical performance of the liquid crystal mixture in examples 1-7 is improved.

[0074] While several particular exemplary embodiments have been described above in detail, the disclosed embodiments are considered illustrative rather than limiting. Those skilled in the art will readily realize that alternatives, modifications, variations, improvements, and substantial equivalents are possible without substantially departing from the novelty spirits or scope of the present disclosure. Thus, all such alternatives, modifications, variations, improvements, and substantial equivalents are intended to be embraced within the scope of the present disclosure as defined by the appended claims.

INDUSTRIAL APPLICABILITY

[0075] The liquid crystal mixture of the present invention can be applied to the field of liquid crystal.