ELECTRODE BODY, ELECTROLYTIC CAPACITOR PROVIDED WITH ELECTRODE BODY, AND METHOD FOR PRODUCING ELECTRODE BODY
20220262576 · 2022-08-18
Inventors
Cpc classification
International classification
Abstract
An electrode body which achieves not only high initial capacitance of an electrolyte capacitor but also achieves stable capacitance even after being exposed to high temperature environment, and the electrolyte capacitor including the electrode body are provided. The electrode body is used for a negative electrode of the electrolyte capacitor, and the electrode body includes a negative electrode foil formed by a valve action metal, and a carbon layer formed on the negative electrode foil. The carbon layer includes a first spherical carbon and a second spherical carbon, and the first spherical carbon has a BET specific surface area larger than the second spherical carbon.
Claims
1. An electrode body used for a negative electrode of an electrolyte capacitor, the electrode body comprising: a negative electrode foil formed by a valve action metal; and a carbon layer formed on the negative electrode foil, wherein: the carbon layer includes a first spherical carbon and a second spherical carbon, and the first spherical carbon has a BET specific surface area larger than the second spherical carbon.
2. The electrode body according to claim 1, wherein a mixture ratio (A:B) of the first spherical carbon (A) and the second spherical carbon (B) is from 90:10 to 30:70.
3. The electrode body according to claim 1, wherein: an enlarged surface layer is formed on a surface of the negative electrode foil, and the carbon layer is formed on the enlarged surface layer,
4. The electrode body according claim 3, wherein: the enlarged surface layer and the carbon layer are pressure-welded to each other, and the carbon layer enters the enlarged surface layer.
5. The electrode body according to claim 3, wherein; concave and convex shape is formed in an interface between the enlarged surface layer and the carbon layer, and the concave and convex shape is compressed and deformed by pressing.
6. The electrolyte capacitor comprising the negative electrode comprising the electrode body according to claim 1.
7. A method for producing an electrode body used for a negative electrode of an electrolyte capacitor, the method comprising: forming a carbon layer on a negative electrode foil which is formed by a valve action metal and which an enlarged surface layer is formed on a surface thereof; and pressing the carbon layer on the negative electrode foil, wherein: the carbon layer includes a first spherical carbon and a second spherical carbon, and the first spherical carbon has a BET specific surface area larger than the second spherical carbon.
8. The electrode body according to claim 2, wherein: an enlarged surface layer is formed on a surface of the negative electrode foil, and the carbon layer is formed on the enlarged surface layer.
9. The electrode body according to claim 8, wherein: the enlarged surface layer and the carbon layer are pressure-welded to each other, and the carbon layer enters the enlarged surface layer.
10. The electrode body according to claim 9, wherein: concave and convex shape is formed in an interface between the enlarged surface layer and the carbon layer, and the concave and convex shape is compressed and deformed by pressing.
11. The electrolyte capacitor comprising the negative electrode comprising the electrode body according to claim 9.
12. The electrode body according to claim 8, wherein: concave and convex shape is formed in an interface between the enlarged surface layer and the carbon layer, and the concave and convex shape is compressed and deformed by pressing.
13. The electrolyte capacitor comprising the negative electrode comprising the electrode body according to claim 12.
14. The electrolyte capacitor comprising the negative electrode comprising the electrode body according to claim 8.
15. The electrolyte capacitor comprising the negative electrode comprising the electrode body according to claim 2.
16. The electrode body according to claim 4, wherein: concave and convex shape is formed in an interface between the enlarged surface layer and the carbon layer, and the concave and convex shape is compressed and deformed by pressing.
17. The electrolyte capacitor comprising the negative electrode comprising the electrode body according to claim 16.
18. The electrolyte capacitor comprising the negative electrode comprising the electrode body according to claim 4.
19. The electrolyte capacitor comprising the negative electrode comprising the electrode body according to claim 5.
20. The electrolyte capacitor comprising the negative electrode comprising the electrode body according to claim 3.
Description
EMBODIMENTS
[0035] An electrode body according to the present disclosure and an electrolyte capacitor using the electrode body for a negative electrode will be described. In the present embodiments, the electrolyte capacitor including an electrolytic solution is described as an example, however, it is not limited thereto. The electrode body may be applied to electrolyte capacitors including electrolytic solution, solid electrolyte layers such as conductive polymers, gel electrolytes, or electrolytes in which electrolytic solution is used together with solid electrolyte layers and gel electrolytes.
Electrolyte Capacitor
[0036] An electrolyte capacitor is a passive element which stores and discharges electrical charge according to capacitance. The electrolyte capacitor has a wound-type or laminated-type capacitor element. The capacitor element is formed by arranging the electrode bodies to face each other via a separator and impregnating the electrode bodies with the electrolytic solution. In the electrolyte capacitor, negative-electrode-side capacity is produced by the electric double-layer effect occurring at an interface between the electrode body used at the negative-electrode side and the electrolytic solution. In addition, positive-electrode-side capacity is produced by the dielectric polarization effect at the electrode body used at the positive-electrode side. In below, the electrode body used at the negative-electrode side is referred to as a negative electrode body and the electrode body used at the positive-electrode side is referred to as a positive electrode foil.
[0037] A dielectric oxide film layer where the dielectric polarization effect occurs is formed on a surface of the positive electrode foil. A carbon layer where causes the electric double-layer effect to occur at the negative electrode body and the electrolytic solution on a surface of the negative electrode body. The electrolytic solution is present between the positive electrode foil and the negative electrode body, and closely contacts the dielectric oxide film layer of the positive electrode foil and the carbon layer of the negative electrode body. The separator is present between the positive electrode foil and the negative electrode body, and retains the electrolytic solution, to prevent short-circuit of the positive electrode foil and the negative electrode body.
Negative Electrode Body
[0038] The negative electrode body has two-layered structures of a negative electrode foil and the carbon layer. The negative electrode foil becomes a current-collector, and it is preferable that an enlarged surface layer is formed on a surface of the negative electrode foil. The carbon layer includes carbon material as the main material. The carbon layer and the enlarged surface layer closely contact each other to form the two-layered structure of the negative electrode foil and the carbon layer.
[0039] The negative electrode foil is a long foil body formed of valve action metal. The valve action metal may be aluminum, tantalum, niobium, titanium, hafnium, zirconium, zinc, tungsten, bismuth, and antimon, etc. The purity of the valve action metal is preferably equal to or more than about 99%, however, impurities such as silicon, iron, copper, magnesium, and zinc may be included. For the negative electrode foil, for example, so-called. H material that is aluminum material which has the thermal refining symbol of H defined by JIS H0001, and so-called O material that is aluminum material which has the thermal refining symbol of O defined by JIS H0001 may be used. When the metal foil with high rigidity formed of H material is used, the deformation of the negative electrode foil due to a pressing process described later can be suppressed.
[0040] The valve action metal is extended, and an enlargement process is performed to a surface of the valve action metal to form the negative electrode foil. The enlarged surface layer is formed by electrolytic etching, chemical etching, or sandblasting, etc., or is formed by vapor depositing or sintering metal particles etc., to the metal foil. The electrolytic etching may be DC etching or AC etching, etc. In addition, in the chemical etching, the metal foil is immersed in acidic solution or alkaline solution. The formed enlarged surface layer is a layer region having tunnel-shaped etching pits dug from a foil surface toward a foil core, or spongy etching pits, Note that the etching pit may be formed to penetrate the negative electrode foil.
[0041] In the carbon layer, the carbon material is a mixture of spherical carbons with different specific surface area calculated by BET theory (hereinafter, referred to as BET specific surface area). One of the spherical carbons with BET specific surface larger than the other of spherical carbons is called a large specific surface spherical carbon. Also, the other of the spherical carbons with BET specific surface smaller than the large specific surface spherical carbon is called a small specific surface spherical carbon. For example, the large specific surface spherical carbon and the small specific surface spherical carbon may be carbon black. The carbon black may be ketjen black, acetylene black, furnace black, channel black, and thermal black, etc. Combinations of types of the large specific surface spherical carbon and the small specific surface spherical carbon are not particularly limited.
[0042] The carbon layer formed by mixing the large specific surface spherical carbon and the small specific surface spherical carbon becomes an electric double-layer active material layer shows the negative-electrode-side capacity with the large specific surface spherical carbon and the small specific surface spherical carbon as the active material. Accordingly, high capacitance of large specific surface spherical carbon and excellent thermal stability of the small specific surface spherical carbon revealed, and demerits of the two are complemented. That is, the combination of the large specific surface spherical carbon and the small specific surface spherical carbon has high capacitance and reduces the difference between the initial capacitance and the capacitance after being exposed to high temperature environment, that is, the capacitance change rate, even when the electrolyte capacitor is used at low frequency range and high frequency range compared with an electrolyte capacitor in which a film of metal nitrides is formed on the negative electrode foil.
[0043] The initial capacitance is capacitance at normal temperature, such as around 20° C., after the electrolyte capacitor is assembled has undergone an aging process, and the capacitance after being exposed to high temperature environment is capacitance after being exposed, for example, to high temperature environment of 125° C. for a long time such as 278 hours. The capacitance change rate is a change rated of the capacitance after being exposed to high temperature environment relative to the initial capacitance.
[0044] Note that a lower limit of the BET specific surface area of the large specific surface spherical carbon, an upper limit of the BET specific surface area of the small specific surface spherical carbon, a difference between the BET specific surface area of the large specific surface spherical carbon and the small specific surface spherical carbon, a ratio of the BET specific surface area of the large specific surface spherical carbon and the small specific surface spherical carbon, and primary particle diameters of t the large specific surface spherical carbon and the small specific surface spherical carbon are not particularly limited.
[0045] However, a mixture ratio (A:B) of the large specific surface spherical carbon (A) and the small specific surface spherical carbon (B) is preferably 90:10 to 30:70. When mixing the small specific surface spherical carbon in an amount of equal to or more than the mixture ratio of 90:10, the capacitance change rate in high temperature environment and at high frequency range can be further suppressed. Meanwhile, when mixing the small specific surface spherical carbon in an amount of equal to or more than the mixture ratio of 30:70, the initial capacitance may become small depending on the combination of the large specific surface spherical carbon and the small specific surface spherical carbon compared with when the small specific surface spherical carbon in an amount of equal to or less than the mixture ratio of 30:70. Note that the mixture ratio is a configuration ratio of carbon components included in solid components in the carbon layer.
[0046] Furthermore, the BET specific surface area of the large specific surface spherical carbon is preferably equal to or more than 133 m.sup.2/g and equal to or less than 1270 m.sup.2/g, and is more preferably equal to or more than 133 m.sup.2/g and equal to or less than 800 m.sup.2/g. Also, the BET specific surface area of the small specific surface spherical carbon is preferably equal to or more than 39 m.sup.2/g and equal to or less than 377 m.sup.2/g, and is more preferably equal to or more than 39 m.sup.2/g and equal to or less than 254 m.sup.2/g.
[0047] As the carbon material, the large specific surface spherical carbon and the small specific surface spherical carbon are mainly used, and other material such as little amount of activated carbon and carbon nanotube may be included. The specific surface area of the activated carbon and the carbon nanotube is large because pi electrons are delocalized. Furthermore, other spherical carbon with BET specific surface area in between the large specific surface spherical carbon and the small specific surface spherical carbon may be further added.
[0048] The negative electrode body may be formed by producing slurry including material of the carbon layer, forming the enlarged surface layer on the negative electrode foil, then applying the slurry on the enlarged surface area, and drying and pressing the negative electrode foil. Typically, the enlarged surface area layer is formed by DC etching or AC etching in which DC or Ac is applied to the negative electrode foil in acidic aqueous solution such as nitric acid, sulfuric acid, and hydrochloric acid.
[0049] Regarding the carbon layer, firstly, powder of the large specific surface spherical carbon and the small specific surface spherical carbon is dispersed in solution. A dispersant such as sodium carboxymethyl cellulose (CMC-Na) may be included in the solution to facilitate the dispersion, and the solution may be stirred and air contaminated in the solution by stirring may be defoamed to improve the degree of dispersion. After the dispersion is completed, a binder is added to the solution, and the solution is further stirred or stirred and defoamed to produce the slurry. Other solution may be added as appropriate. Then, the slurry is applied on the enlarged surface layer, and the enlarged surface layer is dried, and then pressed by the predetermined pressure to layer the carbon layer on the enlarged surface area.
[0050] By pressing, the carbon layer is compressed, and air gaps in the carbon layer can be easily eliminated. By eliminating the air gaps in the carbon layer, the carbon layer becomes dense and adhesion of the carbon layer is ensured. Furthermore, an interface between the carbon layer and the enlarged surface layer becomes an uneven-shape by the pressing, such that the adhered area of the carbon layer and the enlarged surface layer increases, and the capacitance increased. In addition, by the pressing, the carbon layer is pressure-welded to and enters the enlarged surface layer, for example, like the carbon layer entering as far as the etching pits of the enlarged surface area, further improving the adhesion such that the resistance tends to become low.
[0051] Solvent is alcohols such as methanol, ethanol, and 2-propanol, hydrocarbon solvent, aromatic solvent, amide solvent such as N-methyl-2-pyrrolidone (NMP) and N,N-dimethylformamide (DMF), water, and, mixtures thereof, As a dispersion method, mixers, jet mixing (jet impingement), ultracentrifugation, or others such as ultrasonic processing, etc., are used. The binder may be styrene-butadiene rubber, vinylidene polyfluoride, or polytetrafluoroethylene.
[0052] When performing porous treatment such as activation processing and aperture processing to the large specific surface spherical carbon and the small specific surface spherical carbon, conventionally known activation processing such as gas activation processing and chemical activation processing may be used. Gas used in the gas activation processing may be water vapor, air, carbon monoxide, carbon dioxide, hydrogen chloride, oxygen, or combinations thereof. Chemical agents used in the chemical processing may be hydroxides of alkali metal such as sodium hydroxide and potassium hydroxide, hydroxides of alkali earth metal, such as calcium hydroxide, inorganic acid such as boric acid, phosphoric acid, sulfuric acid, and hydrochloric acid, and inorganic salts such as zinc chloride. Heat processing is performed at the time of activation processing as necessary.
Positive Electrode Foil
[0053] Next, the positive electrode foil is a long foil body formed of valve action metal. The purity of the positive electrode foil is desirably about 99.9%. The positive electrode foil is formed by etching an extended foil, or formed by sintering powder of the valve action metal, or formed by vapor depositing a film of metal particles, etc., on a foil. The surface of the positive electrode foil has an enlarged surface layer or a porous structure layer.
[0054] Typically, the dielectric oxide film layer formed on the positive electrode foil is an oxide film formed on a surface layer of the positive electrode foil, and when the positive electrode foil is formed of aluminum, the dielectric oxide film layer is an oxidized aluminum layer which is an oxidized porous structure region. The dielectric oxide film layer is formed by chemical treatment in which voltage is applied in solution without halogen ions, such as acid like ammonium borate, ammonium phosphate, and ammonium adipate, or acidic aqueous solution thereof. Note that a natural oxide film layer may be formed on the negative electrode foil, or the dielectric oxide film layer may be intentionally formed on the negative electrode foil.
Separator
[0055] The separator may be cellulose such as kraft, manila hemp, esparto, hemp, rayon, and combination papers thereof, polyester-based resins such as polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, and derivatives thereof, polytetrafluoroethylene-based resins, poly vinylidene fluoride-based resins, vinylon-based resins, polyamide-based resins such as aliphatic polyamide, semi-aromatic polyamide, and fully aromatic polyamide, polyimide-based resins, polyethylene resins, polypropylene resins, trimethylpentane resins, polyphenylene sulfide-based resins, and acryl resins. These resins may be used in single or in combination, or may be mixed and used with cellulose.
Electrolytic Solution
[0056] The electrolytic solution is mixture solution in which solutes are dissolved in solvents and to which additives are added if necessary. The solvent maybe water, protic polar solvents, or protic polar solvents. Representatively, the protic polar solvent may be monohydric alcohols, polyhydric alcohols, oxyalcohol compounds, and water. Representatively, the aprotic polar solvent may be sulfones, amides, lactones, cyclic amides, nitriles, and oxides.
[0057] The monohydric alcohol may be ethanol, propanol, butanol, pentanol, hexanol, cyclobutanol, cyclopentanol, cyclohexanol, and benzyl alcohol. The polyhydric alcohol and the oxyalcohol compound may be ethylene glycol, propylene glycol, glycerin, methyl cellosolve, ethyl cellosolve, methoxypropylene glycol, and dlmethoxy propanol. The sulfone may be dimethylsulfone, ethylmethylsulfone, diethylsulfone, sulfolane, 3-methylsulfone, and 2,4-dimethylsulfolane. The amide may be N-methylformamide, N,N-dimethylformamide, N-ethylformamide, N,N-diethylformamide, N-methylacetamide, N,N-dimethylacetamide, N-ethylacetamide, N,N-diethyl acetamide, and hexamethylphosphoricamide. The lactone and the cyclic amide may be γ-butyrolactone, γ-valerolactone, δ-valerolavtone, N-methyl-2-pyrrolidone, ethylene carbonate, propylene carbonate, butylene carbonate, and isobutylene carbonate. The nitrile may be acetonitrile, 3-methoxypropionitrile, and glutaronitrile. The oxides may be dimethyl sulfoxide. These may be used as the solvent in single or in combination of two or more.
[0058] The solute included in the electrolytic solution includes anion components and cation components, and typically, the components are organic acid or salts thereof, inorganic acid or salts thereof, or composite compound of organic acid and inorganic acid or ion dissociative salts thereof. The components are used in single or in combination. The acid that is the anion and the base that is the cation may be separately added to the electrolytic solution as the solute components.
[0059] The organic acid that is the anion component in the electrolytic solution may be carboxylic acid such as oxalic acid, succinic acid, glutaric acid, pimelic acid, suberic acid, sebacic acid, phthalic acid, isophthalic acid, terephthalic acid, maleic acid, adipic acid, benzoic acid, toluic acid, enanthic acid, malonic acid, 1,6-decanedicarboxylic acid, 1,7-octanedicarboxylic acid, azelaic acid, undecanedioic acid, dodecanedioic acid, and tridecanedioic acid, phenols, and sulfones. In addition, the inorganic acid may be boric acid, phosphoric acid, phosphorus acid, hypo phosphorus acid, carbonic acid, and silicic acid, the composite compound of organic acid and inorganic acid may be borodisalicylic acid, borodioxalic acid, and borodiglycolic acid.
[0060] At least one salt of the organic acid, the inorganic acid, and the composite compound of organic acid and inorganic acid may be ammonium salts, quaternary ammonium salts, quaternarized aminidium salts, amine salts, sodium salts, and potassium salts. Quaternary ammonium ions of the quaternary ammonium salt may be tetramethylammonium, triethylmethylammonium, and tetraethylammonium. The quaternized aminidium salt may he ethyldimethylimidazolium and tetramethylimidazolium. Amines of the amine salt may be primary amines, secondary amines, and tertiary amines, The primary amine may be methylamine, ethylamine, and propylamine. The secondary amine may be dimethylamine, diethylamine, ethylmethylamine, and dibutylamine. The tertiary amine may be trimethylamine, triethylamine, tributylamine, ethyldimethylamine, and ethyldiisopropylamine,
[0061] Furthermore, other additives may be added to the electrolytic solution. The additive may be polyethylene glycol, complex compounds of boric acid and polysaccharides (such as mannitol and sorbitol), complex compounds of boric acid and polyhydric alcohol, boric acid esters, nitro compounds (such as o-nitrobenzoic acid, m-nitrobenzoic acid, p-nitrobenzoic acid, o-nitrophenol, m-nitrophenol, and p-nitrophenol), phosphoric acid esters, and colloidal silica. The additive may be added in single or in combination of two or more.
[0062] The electrolytic capacitor using the electrolytic solution is described above, however, when the solid electrolyte is used, the solid electrolyte is conducted by the carbon layer in contact with the current collector, and the capacitance of the electrolyte capacitor is formed by the positive-electrode-side capacity due to the dielectric polarization effect. In addition, when the solid electrolyte may be conductive polymers such polythiophenes like polyethylenedioxythiophene, polypyrroles, and polyanilines.
EMBODIMENT
[0063] In below, the present disclosure is described in more detail based on examples. Note that the present disclosure is not limited to the below examples. Firstly, electrolyte capacitors of reference examples and comparative example 1 were produced in an aspect of laminated cells as described below.
[0064] The common producing procedures for the electrolyte capacitor was as follows. Firstly, for the negative electrode body, to produce a dispersant-containing aqueous solution, carbon material was added to CMC-Na aqueous solution. In the dispersant-containing aqueous solution, 1.67 wt % of CMC-Na relative to the entire aqueous solution excepting the carbon material was included. After the carbon material was added, to perform dispersion processing, the aqueous solution was stirred for three minutes at rotation speed of 2000 rpm by a mixer (THINKY MIXER from THINKY COPORATION), was defoamed for 30 seconds at 2500 rpm by the mixer (THINKY MIXER from THINKY COPORATION), and then was stirred for three minutes at rotation speed of 2000 rpm by the mixer (THINKY MIXER from THINKY COPORATION).
[0065] After the dispersion processing of the carbon material, water and 2-propanol were added as solvents, and the dispersion processing was performed again to adjust the carbon material solid content concentration to be a predetermined amount. After the dilution by the addition of the solvents, SBR (BM-400B from ZEON CORPORATION) aqueous solution was added as a binder and was mixed to produce a slurry. SBR occupied 40 wt % of the SBR aqueous solution. A formulation ratio (A:B:C) of the carbon material (A), the binder (B), and CMC-Na (C) in the produced slurry was 84:10:6. A formulation ratio (A:B) of water (A) and 2-propanol (B) was 87:13. Also in the dispersion processing performed again, similarly to the dispersion processing, the aqueous solution was stirred for three minutes at rotation speed of 2000 rpm by a mixer (THINKY MIXER from THINKY COPORATION), was defoamed for 30 seconds at 2500 rpm by the mixer (THINKY MIXER from THINKY COPORATION), and then was stirred for three minutes at rotation speed of 2000 rpm by the mixer (THINKY MIXER from THINKY COPORATION).
[0066] Meanwhile, an aluminum foil from which an electrode lead plate had been drawn out was prepared as a negative electrode foil, and the slurry was uniformly applied on the negative electrode foil. Current was applied to the negative electrode foil in hydrochloric acid beforehand to form an enlarged surface layer. The slurry was applied on the enlarged surface area. Then, after the slurry was dried, pressure of 150 kNcm.sup.−2 was applied by vertical pressing to fox the carbon layer on the negative electrode foil.
[0067] Furthermore, etching processing was performed on the aluminum foil to form a dielectric oxide film layer with nominal chemical voltage of 4 V.sub.fs and obtain, the aluminum foil with projected area of 2.1 cm.sup.2 as the positive electrode foil. The capacity of the positive electrode foil was 386 μFcm.sup.−2. Then the negative electrode body and the positive electrode foil were arranged to face each other via a rayon separator, were impregnated with electrolytic solution to produce a laminated cell with rated voltage of 2.9 V, and the common chemical processing was performed again. The electrolytic solution was produced by using tetramethylimidazolinium phthalic acid as a solute and γ-butyrolactone as a solvent. In the chemical processing performed again, current of 3.35 V was applied to all electrolyte capacitors for 60 minutes under an environment of 105° C.
[0068] Differences between the examples and the reference examples were the carbon material, and the carbon material and formulation ratio in the examples and the reference examples are described in Table 1. below. In Table 1, CB1 and CB2 indicate spherical carbons. In Table 1, a spherical carbon with BET specific surface area of 39 m.sup.2/g is acetylene black (HS-100 from Denka Company Limited), a spherical carbon with BET specific surface area of 133 m.sup.2/g is acetylene black (FX-35 from Denka Company Limited), a spherical carbon with BET specific surface area of 254 m.sup.2/g is furnace black (XC-72 from Cabot Corporation), a spherical carbon with BET specific surface area of 377 m.sup.2/g is ketjen black (EC200L from Lion Corporation), a spherical carbon with BET specific surface area of 800 m.sup.2/g is ketjen black (EC300J from Lion Corporation), and a spherical carbon with BET specific surface area of 1270 m.sup.2/g is ketjen black (EC600JD from Lion Corporation).
TABLE-US-00001 TABLE 1 BET Specific BET Specific Surface Area Surface Area of Spehrical of Spehrical Mixture Carbon (CB1) Carbon (CB2) Ratio [m.sup.2/g] [m.sup.2/g] (CB1:CB2) Example 1 800 90:10 Example 2 70:30 Example 3 50:50 Example 4 30:70 Example 5 10:90 Example 6 800 377 90:10 Example 7 70:30 Example 8 50:50 Example 9 30:70 Example 10 10:90 Example 11 1270 30 10:90 Reference 39 — 100:0 Example 1 Reference 133 — 100:0 Example 2 Reference 254 — 100:0 Example 3 Reference 377 — 100:0 Example 4 Reference 800 — 100:0 Example 5 Reference 1270 — 100:0 Example 6 Reference Titanium Nitride (TiN) Example 7
[0069] A electrolyte capacitor of the comparative example 1 was produces as follows as the laminated cell. That is, an aluminum foil which had not been processed by etching was used as current collectors, a titanium nitride layer was formed on the aluminum foil by electron beam deposition, and the aluminum foil on which the titanium nitride layer had been formed was used as the negative electrode body. A positive electrode foil, composition of separator and electrolytic solution, and the producing method and condition were the same as the electrolyte capacitors of the respective examples.
Product Test
[0070] Capacitance of the electrolyte capacitors of the examples, the reference examples, and the comparative example 1 was measured. In a product test, capacitance (Cap) at the time of charging and discharging 120 Hz and 10 kHz at 20° C. was measured as the initial capacitance. Also, capacitance (Cap) at the time of charging and discharging 120 Hz and 10 kHz at 20° C. after applying a load of 2.4 V for 278 hours at high temperature environment of 125° C. was measured as the capacitance after being exposed high temperature environment. The result was indicated in below Tables 2 and 3. Tables 2 and 3 indicate change rates (ΔCap) of the capacitance after being exposed high temperature environment relative to the initial capacitance for each frequency.
TABLE-US-00002 TABLE 2 Initial Capacitance After Being Exposed Spherical Spherical Capacitance in High Temperature Environment ΔCap (B/A × 100) Carbon (CB1) Carbon (CB2) Mixture Ratio Cap(μF): A Cap(μF): B [%] [m.sup.2/g] [m.sup.2/g] (CB1:CB2) 120 Hz 10 kHz 120 Hz 10 kHz 120 Hz 10 kHz Reference Example 5 800 — 100:0 321 159 285 115 −10.8 −28.1 Example 1 800 39 99:10 337 189 302 144 −10.4 −0.3 Example 2 70:30 339 138 300 144 −11.6 −9.9 Example 3 50:50 318 150 186 138 −0.8 −0.3 Example 4 30:70 283 145 256 133 −0.4 −0.4 Example 5 10:90 238 124 218 126 −0.3 −1.5 Reference Example 1 39 — 100:0 197 115 189 189 −4.5 −4.5 Example 6 800 377 90:10 324 161 287 142 −11.8 −11.6 Example 7 70:30 316 159 283 143 −10.5 −9.6 Example 8 50:50 312 138 363 144 −9.3 −9.1 Example 9 30:70 318 150 287 139 −9.8 −11.7 Example 10 10:90 277 141 277 116 −11.5 −17.3 Reference Example 4 377 — 100:0 365 146 287 116 −9.8 −20.3 Example 11 1270 39 10:90 286 138 239 124 −8.1 −4.6 Reference Example 8 1270 — 100:0 353 108 238 53 −28.3 −70.1 Comparative Example 1 Titanium Nitride (TIN) 235 96 187 73 −26.5 −24.4
TABLE-US-00003 TABLE 3 Capacitance After Being Exposed Initial Capacitance in High Temperature Environment ΔCap (B/A × 100) BET Specific Surface Area Cap(μF): A Cap(μF): B [%] [m.sup.2/g] 120 Hz 10 kHz 120 Hz 10 kHz 120 Hz 10 kHz Reference Example 1 39 197 115 189 108 −4.3 −6.5 Reference Example 2 133 270 144 253 127 −6.5 −11.7 Reference Example 3 254 287 149 261 130 −9.1 −12.7 Reference Example 4 377 285 146 257 116 −9.8 −20.3 Reference Example 5 800 321 159 286 115 −10.8 −28.1 Reference Example 6 1270 333 108 238 32 −28.3 −70.1 Comparative Example 1 Titanium Nitride (TIN) 235 96 187 73 −20.5 −24.4
[0071] Furthermore, based on the above two tables,
[0072] As indicated in Table 2, it was observed that the examples 1 to 11 were more excellent than the comparative example 1 in all of the initial capacitance at low frequency range, the initial capacitance at high frequency range, the capacitance at low frequency range after being exposed high temperature environment, the capacitance at high frequency range after being exposed high temperature environment, the change rate of the capacitance after being exposed high temperature environment relative to the initial capacitance at low frequency range, and the capacitance at high frequency range after being exposed high temperature environment, the change rate of the capacitance after being exposed high temperature environment relative to the initial capacitance at high frequency range.
[0073] In particular, as indicated in Table 2, although the examples 1 to 5 included the large surface area spherical carbon in the carbon layer similarly to the reference example 5, the examples 1 to 5 had dramatically excellent ΔCap comparable to the reference example 1 that did not include the large surface area spherical carbon at all. In addition, as illustrated in
[0074] Furthermore, as indicated in Table 2, although the examples 6 to 10 included the large surface area spherical carbon in the carbon layer similarly to the reference example 5, the examples 6 to 10 had dramatically excellent ΔCap exceeding the reference example 4 that did not include the large surface area spherical carbon at all. In addition, as illustrated in
[0075] That is, by mixing the large surface area spherical carbon which has high capacitance and in which ΔCap easily gets worse, and the small surface area spherical carbon in which the capacitance tends to become low and which has excellent ΔCap, it was observed that advantages of the large surface area spherical carbon and the small surface area spherical carbon were rather improved, complementing disadvantages of each other.