Block and unit for storing thermal energy
11408685 · 2022-08-09
Assignee
Inventors
- Fabrice Chopard (Paris, FR)
- Paul Bline (Paris, FR)
- Boris Chauvet (Paris, FR)
- Christophe Dominiak (Paris, FR)
Cpc classification
Y02E60/14
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F28D20/025
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28D20/021
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28D2020/0021
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28D2020/0082
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F28D20/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
A modular block for storing thermal energy having a bottom wall and lateral walls defining a chamber. The lateral walls are made from a mouldable material. First thermal management elements are disposed in the chamber, which has at least one communication passage to the outside environment to allow a refrigerating fluid or a heat-transfer fluid a in heat exchange relationship with the first thermal management elements to pass into and out of the chamber. The modular block has second thermal management elements arranged laterally around the lateral walls or included in the mouldable material of the lateral walls for the thermal management of the chamber. The first thermal management elements are separated from the second thermal management elements by a part of the mouldable material of the lateral walls.
Claims
1. A modular block for a unit adapted to store thermal energy, the modular block comprising: a bottom wall; and lateral walls comprising a mouldable material and joined to the bottom wall, the bottom wall and the lateral walls defining a chamber and separating said chamber from an outside environment, wherein the chamber: is closed on a bottom side by the bottom wall and open on a top side opposite the bottom side, encloses a volume in which are disposed first thermal management elements for storing and releasing thermal energy, and has at least one communication passage between the outside environment and the chamber to allow a refrigerating fluid or a heat-transfer fluid in heat exchange relationship with said first thermal management elements to pass into and out of the chamber, and wherein: the modular block further comprises second thermal management elements arranged laterally around the lateral walls or included in the mouldable material of the lateral walls for the thermal management of the chamber, the second thermal management elements comprising a thermally insulating material arranged in hermetic pockets that are under a partial vacuum or filled with a gas having a thermal conductivity lower than 26 mW/m.Math.K, and each of the first thermal management elements are separated from each of the second thermal management elements by at least a part of the mouldable material of the lateral walls.
2. The modular block according to claim 1, further comprising a sealing surface surrounding said top side for providing sealing in relation to the refrigerating fluid or the heat-transfer fluid.
3. The modular block according to claim 1, wherein the hermetic pockets include a series of said hermetic pockets jointed by flexible intermediate portions between two successive hermetic pockets to allow articulation of the two successive hermetic pockets relative to each other.
4. The modular block according to claim 1, wherein said first thermal management elements are arranged in said chamber such that circulation spaces for the refrigerating fluid or the heat-transfer fluid remain between the first thermal management elements.
5. The modular block according to claim 1, wherein said first thermal management elements are arranged in said chamber in a patternless manner.
Description
(1) If necessary, the invention will be better understood and other characteristics, details and advantages thereof will further appear upon reading the following description given by way of non-limiting example and in reference to the appended drawings, wherein:
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(8) It must be considered that the examples of operational solutions presented hereafter and the versions illustrated may be combined with one another. Mixtures of solutions may thus be easily deduced therefrom, such as, for example,
(9) The diagrams in the figures (in particular
(10) Of modular construction, the unit 1 includes: a plurality of structures or modules 3, each provided with a body 330 having a peripheral wall 5 and a bottom 29 surrounding an inner volume (or chamber) 7 where the refrigerating or heat-transfer fluid 9 is present, for having circulated in said volumes under the action of circulation means 11, and elements 13 for storing and restoring (subsequently) thermal energy, at least one layer or element 15 containing a PCM that can be arranged in the peripheral wall 5 (for example, in at least one (quasi) peripheral cavity 17 of said wall, as shown in
(11) The modules 3 are arranged along a stacking axis 27. And each bottom 29 is transverse to the peripheral wall 5 (by joining the sides) and here opposite, along the axis 27, to an opening 31 through which can be placed or removed from the corresponding volume 7 the elements 13 that may be balls or spheres.
(12) As shown in
(13) In this regard, the embodiment in
(14) Each pocket will contain at least one thermal insulating material 23, and will extend laterally (transversally to the axis 27) around a volume 7 (preferably all around), to thermally insulate same from the outside (EXT) with the content thereof, the layers 15/23 defining elements for the thermal management of the temperature in the volumes 7.
(15) The, or each, layer 15 containing a PCM may be arranged in the quasi-perimetric cavities 17 of the wall 5 or all around said wall, in particular within the pockets 19.
(16) In said solution with pockets 19 arranged laterally around the wall 5, a peripheral envelope (sleeve or sheath) 38 of mechanical protection open at both ends, for example made of hard plastic, envelops the modules 3, the parts 32, 34, 36 and the pockets 19, which are therefore interposed between the walls 5 and said sheath. Extending around the protrusions 22 and the thermally insulating elements under controlled atmosphere 19, the sleeve 38 participates in retaining the elements 19 in the spaces 24, as shown in
(17) The retaining protrusions 22 may be in a plurality of portions. Thus, in particular, it can be seen in
(18) Typically, the bodies 330 of the modules 3 will have angles and the retaining protrusions 22 will be like rods extending in the angles, as illustrated.
(19) Unlike the above, rather than therefore be hollow such as a clip, the removable portion 22b could have a protrusion towards an outer hollow of the fixed portion 22a to engage therewith. Another possibility: the two portions 22a, 22b would only form one to define a protrusion integral with the wall 5.
(20) The peripheral walls 5 and bottoms 29 of the modules or structures 3, which may be integral, may in particular be made of polyamide, of another rigid polymer (medium or high-density polyethylene, for example), or of composite (filled with fibres), or even of metal.
(21) Passages 30 communicating at least two by two, in the bottoms 29, enable the fluid 9 (which may be water or oil, or even a gas, such as air), to circulate, from an inlet 33 to an outlet 35, between the modules or structures 3. Said fluid 9 will globally circulate along the axis 27.
(22) Where this is necessary, since the open structures 3 can be arranged in particular back to back (
(23) The inlet 33 and outlet 35, which pass through the portions 32, 34, 36 if same exist, to lead into the respective volumes 7, define connection elements as shown in
(24) Again, for the sealing in relation to the fluid 9, a first sealing surface 39 (that may be provided with a seal 41) surrounds the opening 31 of each chamber 3, which opening is therefore located transversally to the axis 27, opposite the bottom 29.
(25) Attachment means 40, such as axial tie rods, will moreover be preferably provided to engage with the bodies of the modules 3 in order to provide an attachment between said bodies placed in contact and facing. After that, the sleeve 38 will be externally put in place.
(26) The bodies 330 being attached together, along the axis 27 in the stacked arrangement considered, the first sealing surface 39 will therefore be pressed either against a second sealing surface defined externally at the location of the bottom 29 of an adjacent body, in a relative arrangement of the bodies back to back, or against the first sealing surface of such an adjacent body, in a relative arrangement of the bodies face to face. At least one seal (not shown) will be arranged on one side and/or the other.
(27) In place of the tie rods and seals, it is possible to provide a welded or bonded solution of the modules together, along the axis 27.
(28) It will be understood that the assembly 1 will be thermally efficient thanks to the PCM/thermal insulation compound that makes it possible to associate: a thermal insulation of the modules in relation to the outside (EXT), a retarding effect related to the changes of states of the PCM.
(29) The thermally insulating material 23 may be a glass wool, a polyurethane or polyisocyanurate foam, or even more favourably a porous, or even nano-porous material, such as a silica or an organic aerogel or the pyrolate thereof impregnated in a porous network and arranged in a vacuum enclosure, to therefore define at least the vacuum insulation panel VIP already mentioned.
(30) As a material 15, or constitution of elements 13 contained in each inner volume 7 and with which the fluid 9 is in heat exchange relationship, a rubber composition such as described in EP2690141 can be provided, namely a crosslinked composition based on at least one room temperature vulcanising “RTV” silicone elastomer and including at least one phase change material (PCM), said at least one silicone elastomer having a viscosity measured at 25° C. according to the standard ISO 3219 which is less than or equal to 5000 mPa.Math.s. In said composition, the elastomer matrix will mainly consist (i.e. according to an amount greater than 50 phr, preferably greater than 75 phr) of one or more “RTV” silicone elastomers. Thus, said composition could have the elastomer matrix thereof including one or more silicone elastomers according to a total amount greater than 50 phr and optionally one or more other elastomers (i.e. other than “RTV” silicones) according to a total amount lower than 50 phr.
(31) In particular, a material based on paraffin, eutectic fatty acid (myristic-capric) or eutectic hydrated salt (calcium chloride+potassium) could also be used as a constituent material, alone or not, of the aforementioned elements. Alternatively, the PCM of the elements cited could be based on fatty acid, paraffin, or eutectic or hydrated salt. In fact, the choice of the material and the packaging thereof in each element concerned, in particular the dispersion thereof within a polymer matrix, will depend on the intended application and the expected results.
(32) A priori the elements 13, here individualised, such as the spheres mentioned, will be arranged loosely in the volumes 7. The size ratio of the individualised structures/dimensions of each sub-volume will therefore be defined accordingly, in order preferably to optimise the exchange surfaces of the elements 13/fluid 9.
(33) Thus, the elements 13 of PCM type will not be tubes or, preferably, will be arranged in a patternless manner and not in an organised manner (as they are in US 2011/0030915), in order to promote the conditions of implementation (no storage) and the residence times of the fluid in the chambers, in exchange relationship with said elements 13, in particular promoting a circulation with many meanders due to the obstacles constituted by said elements 13 through the axial circulation 27 of the fluid.
(34) As it is important that the elements 13 of PCM type exchange broadly with the fluid 9, the PCM 15 of the thermal management elements (15, 19, 23) arranged around the chambers or volumes 7 must form one or more panels (structure peripherally continuous or not as shown in the figures, in particular 2, 3, 11) which without contact with any refrigerating or heat-transfer fluid, will work thermally according to said exchanges made in the chambers.
(35) This is why the PCM 15 of the peripheral elements is called “thermal management”: same participates in the thermal management of the chambers. This is not the case of the tubes 2b in US 2011/0030915.
(36) Thus, peripherally arranged around the chambers or volumes 7, said material placed in the deformable or flexible envelopes thereof, such as 37, 51, will favourably form one or more walls or panels 19 for the thermal management.
(37) If the peripheral insulating pockets 19 follow one another continuously around a wall 5, and although this is not strictly imposed (a form closed thereon, as a sleeve being possible), it will a priori be preferred that the elements 19-21 define together an articulable panel 50 (as in
(38) Independently of a discontinuous or not embodiment of the pockets 19, the following presents, in reference in particular to
(39) It can thus be seen that in both a continuous and discontinuous solution, each pocket 19 under controlled atmosphere can then include (as seen in exploded view in
(40) It should be noted that two layers 15 (or 15a, 15b) containing one or more PCM could (as shown in
(41) The porous thermal insulation 23 that could therefore be nanostructure, will therefore be confined in a flexible sheet 49 or 53 which will not allow water vapour or gases to pass through. The VIP obtained will be emptied of the air thereof to obtain, for example, a pressure of a few millibars, then may be sealed. Typically, the thermal conductivity A of such a VIP will be 0.004/0.008 W/m.Math.K. The use of vacuum insulation panels should make it possible to achieve a thermal resistance R=5 m.sup.2.Math.K/W with only 20 mm of insulation.
(42) A possible composition of the material 23 is the following: 80-85% of silica dioxide (SiO2), 15-20% of silicon carbide (SiC) and possibly 5% of other products (binder/fillers). A thickness of 0.4 to 3 cm is possible. Examples, that can be applied here, of VIP and super-insulating material are furthermore provided in PCT/FR2014/050267 and in WO2014060906 (porous material), respectively.
(43) The solutions presented above must enable, in an acceptable volume and weight in particular by aeronautical or automobile manufacturers, rapid storage of an available thermal energy after approximately 6-10 minutes, the retention of said energy for 12 to 15 hours, before the rapid release thereof, typically a few minutes (in particular less than 2-3 minutes), for example to an engine during a cold start phase.
(44) The flexible sheets 49, 53 of the VIP may typically be made in the form of a multilayer film comprising polymer films (PE and PET) and aluminium in, for example, laminated (sheet of thickness of around ten micrometres) or metallised (vacuum deposition of a film of a few tens of nanometres) form. The metallisation can be carried out on one face or on both faces of a PE film and a plurality of metallised PE films can be compounded to form a single film. Example of design of the film: —PE inner sealing, approximately 40 μm—Al vacuum metallisation, approx. 0.04 μm—PET outer layer, approximately 60 μm.
(45) If the references 49 and/or 53 designate a wall(s) or metal plate(s), see also pocket 19 with metal walls 490 in
(46) In case b) above where there is a double sheet: inner 53 and outer 49, the sheet 49 may, however, therefore only be a simple polymer film, such as a PE 0.05 to 0.2 mm thick, the object of this outer sheet 49 can then only be to create a simple bag for containing/joining together the elements or blankets 15 and 23.
(47) It should also be noted that the/each envelope 37, 51 may typically be formed of two sheets or walls arranged on either side of said material elements 15 and 23 and joined together, as in 49a, 49b in
(48) In any case, an advantage of said sheets directly in contact with one another at the location of the intermediate portions 21, as illustrated, if same are a plurality, (or of said sheet if same is unique) is that advantage can be taken of the physical continuous thereof at the location of said portions 21 to create therein an articulation area (however fixed if there is integration into the thickness of the wall 5, as in
(49) However, the simple use of said flexible (or manually deformable) sheets or walls will create a discontinuity of thermal insulation between the two consecutive pockets 19 thus joined.
(50) In some cases, the intermediate portions 21 could have significant surfaces that are all the more troublesome in terms of thermal bridges; but it may also be necessary to place a panel 50 or a sleeve 47 in support, for example to position same correctly in relation to the environment thereof.
(51) All the more in these cases, there may be a benefit in defining a bulging portion 59 between two articulation areas 21 (each formed by the aforementioned flexible sheet(s) applied against one another), each area being itself joined laterally on one side to the pocket 19 concerned, this regularly or not in the chain, as shown in
(52) Each bulging portion 59 may contain a thermal insulation 23, for example as a blanket. It may, for example, be of flexible product, as a blanket, known as Spaceloft®, a SIAP (Super Insulation at Atmospheric Pressure) proposed by the company ISOLProducts with a thermal conductivity: λ=0.01 to 0.02 W/m.Math.K. A PCM layer 15 (
(53) Nevertheless, in said solution with bulging portion(s) 59, the intermediate portions 21 are not fully thermally insulating.
(54) Also, it is proposed (as illustrated in
(55) In the example of
(56) Thicker than the impregnated fabrics and the portions 21, for example more than 2.5 to 3 times thicker, and for example formed in a block, as illustrated, the pockets 19 of thermally insulating material 23 will typically be stiffer than the flexible articulation structures 79.
(57) The thermal insulation of the structure(s) 79 will typically be different than same of the pockets 19, for example of flexible type as a blanket (see hereafter).
(58) So that the panel 50 thus formed acquires the VIP constitution thereof, under partial vacuum, of course such a vacuum will be created, with sealing, after the layers or plates of porous material 23, 81 have all been enveloped by the sealed flexible sheets 49.
(59) To produce the structures 79, it will be possible in particular to use a flexible polymeric mesh support (for example an organic or inorganic woven or non-woven fabric, or a web) such as a polyester or a polyamide of a few mm thick impregnated with an aerogel 81, for example silica, or the pyrolysed version thereof (pyrolysed aerogel, it being specified that said pyrolysed alternative applies to each case of the present description wherein a porous thermally insulating material is concerned).
(60) For information, an insulation structure presented above with VIP pockets 19 with for core material a nano-porous aerogel or the pyrolysed version thereof may have a thermal conductivity lower than 10 mW.Math.m−1. K−1 for an internal pressure of 2 to 5 to 10.sup.−3 Pa. The negative pressure in the pockets, or even the portions 21, may be that usual of VIP: 10.sup.−3 to 10.sup.3 Pa.
(61) In connection with, in particular
(62) If there are two layers of said material, the second layer will be, where the two layers exist, arranged around the first layer, with interposition of the material 23 between same and different change of state temperatures.
(63) If there is only one layer of said material 15, it will therefore be favourably surrounded by the material layer 23, at the location of the pockets 19, and by the material 81 if the flexible intermediate portions 21 are provided. In several figures, INT the side of the volume 7 and EXT the (environment) outside have also been marked.
(64) It should also be noted that the pockets 19 will not necessarily be strictly flat. Thus, a curve shape is possible, as shown in the example in
(65) As illustrated in
(66)
(67) Preferably, as alternatives or complements to the walls 29, the passages 30 between the bodies will be favourably offset from one passage to the next, parallel to the axis 27, as illustrated in
(68) In the variant in
(69) Each partition 29 interrupting at one of the lateral ends thereof before reaching the wall 5, this is where each passage 30 is created which, in connection with the partition concerned and preferably an alternation in the lateral end thus open, forms a baffle. Arrived at the last sub-volume, the fluid leaves the body through the pierced bottom. Each sub-volume contains elements 13.
(70) In both cases (
(71)
(72)
(73) The circuit 70 defines here an oil circulation path whereon are arranged, in fluid communication with one another, an oil sump 74 and functional components of the engine to be oiled, such as the bearings of connecting rods and of the crankshaft, but also of the camshaft and the driving device thereof, 76. The sump 74, the vessel (a priori metal) of which is screwed under the engine block 720, with a seal, contains the oil necessary for the lubrication of the moving parts of the lower engine and of the upper engine. The oil is drawn by the strainer of the oil pump 78 which distributes same under pressure, preferably via an oil filter, to the various components (crankshaft, connecting rods, camshaft, etc.). The oil can then go back down again by simple gravity; arrows 80. The sump is equipped at the lowest point thereof with a bleed screw with sealing washer, dedicated to the periodic oil change of the engine.
(74) Three non-limiting assemblies are more specifically shown.
(75) In the first, illustrated in
(76) In the second assembly in
(77) It will be understood that above the term “oil” is to be understood in the broad sense, as “a lubricating fluid for the engine”. And it will also be noted that it is advantageous for the lubrication circuit 70 of the engine to therefore define a circulation path for the lubricating fluid whereon will be arranged the means (11 or 78) for circulating the lubricating fluid, the sump 74, functional components (such as 76) of the engine to be lubricated, to be placed in heat exchange relationship with the fluid 9 coming from the unit 1, and the unit 1 containing at least the volume 7: which contains the elements 13 for storing and subsequent releasing thermal energy, of PCM type, placed in a heat exchange relationship with said lubricating fluid 9, and around which are therefore arranged at least the first and second layers 15, 23.
(78)
(79) In the storer-exchanger 1/3 of said embodiment, the volume 7 is devoid of baffles (no wall arranged through the volume, in particular). By circulating around and/or in the elements 13 of PCM type that occupy the main part of said volume 7, the lubricant will heat exchange with same.
(80) Laterally all around, but also under same (wall 29) and above, via for example the cover 86, the volume 7 is surrounded by a thermal management compound with PCM layers 15/thermal insulation 23 and with pockets 19, which can be integrated with the walls or arranged in lining.
(81) In the third assembly, as illustrated in
(82) Said sump 74 can as previously be screwed to the engine block, under same, and the lubricant may of course circulate therein, a pump 11 providing said circulation and an inlet/outlet connection of the lubricant provided.
(83) Above, between the insulated sump 74 and the base of the engine block 720, a cover 86 may be arranged/interposed.
(84) The interior of the volume 7 in said version must be imagined as same also referenced 7 in
(85) Providing a vehicle lubricant tank according to one of the last two versions above, that can therefore be used to heat the lubricant when the outside temperature is cold, for example −5 to 10° C., and when the vehicle is stopped at said temperature for, for example, 6 to 8 hours was a challenge.
(86) The solutions in
(87) Indeed, the goal has been achieved if compared to existing sumps, it was possible in said versions to increase the internal volume of the sump 74 for example by 20 to 40% (typically V1=2.5 to 4 L and V2=1 to 2 L), with: in the lubricant sump 74 and circulation of lubricant stopped, said elements 13 that are immersed in a first volume of lubricant (V1) outside (here above) of which therefore extends a second volume of lubricant (V2) lower than the first volume, this without necessarily baffles 12 in the volume V1 filled with said elements 13, and with the strict thermal management provided by the compound 15/23 under vacuum.
(88) In practice, it will then be possible to provide that, during a motor start, the PCM(s) of said elements 13 are then still hot: same will have retained the latent heat from the end of the preceding operation of the engine block provided with said lubricant sump. The first volume of lubricant (V1) will therefore be hotter than the second (V2), by heat exchange with the elements 13 being immersed inside.
(89) The external volume of lubricant (V2) being lower than the first volume (V1), it has been possible to make multiplication and extension of the PCM/fluid exchange areas unnecessary; hence the proposed absence of baffles 12 in
(90) In this way, at the start of a new cycle (after the aforementioned stop due to cold weather), by gradual mixing via the circulation in the circuit, the total lubricant in circulation (V1+V2) may be rapidly globally hot, with advantages in terms of efficiency of the engine to be lubricated and limitation of pollutants.