SUPERALLOY POWDER, PART AND METHOD FOR MANUFACTURING THE PART FROM THE POWDER

Abstract

A nickel-based superalloy powder comprising, by mass percent, 14.00 to 15.25% chromium, 14.25 to 15.75% cobalt, 3.9 to 4.5% molybdenum, 4.0 to 4.6% aluminum, 3.0 to 3.7% titanium, 0 to 200 ppm carbon, the remainder consisting of nickel and unavoidable impurities. Component made from the powder and manufacturing process of the component.

Claims

1. Nickel-based superalloy powder comprising, by mass percent, 14.00 to 15.25% chromium, 14.25 to 15.75% cobalt, 3.9 to 4.5% molybdenum, 4.0 to 4.6% aluminum, 3.0 to 3.7% titanium, 0 to 0.10 copper, 0 to 0.50 iron, 0 to 200 ppm carbon, the remainder consisting of nickel and unavoidable impurities.

2. Nickel-based superalloy powder according to claim 1, comprising 5 to 200 ppm carbon.

3. Nickel-based superalloy powder according to claim 1, having a D90 particle size of less than or equal to 75 μm measured by laser diffraction according to the ISO 13320 standard.

4. Nickel-based superalloy powder according to claim 1, having a spherical morphology.

5. Component made from the nickel-based superalloy powder according to claim 1, the component comprising less than 700 ppm carbon.

6. Component according to claim 5, the component being obtained by a powder injection molding process. (Currently Amended) Component according to claim 5, wherein the average grain size is greater than or equal to ASTM6 as measured according to the ASTM E112-13 standard.

8. Manufacturing process of a component from a nickel-based superalloy powder according to claim 1, comprising the following steps: mixing the nickel-based superalloy powder with at least two binders to obtain a mixture; injection molding the mixture in a mold to obtain a green component; debinding the green component to obtain a debonded component; sintering the debonded component to obtain a sintered component; and heat treating the sintered component comprising a step of growing the grains so that the average size of the grains is greater than or equal to ASTM6 measured according to the ASTM E112-13 standard and a step of precipitating a γ′ phase.

9. Manufacturing process according to claim 8, wherein the sintering step is performed with a temperature step comprised between 1 h and 6 h.

10. Manufacturing process according to claim 8, wherein the grain growth step is carried out with a temperature step greater than or equal to 1 h and less than or equal to 20 h.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0037] Other features and advantages of the present disclosure will emerge from the following description of embodiments, given by way of non-limiting examples, with reference to the appended figures.

[0038] FIG. 1 is a flowchart showing the steps of a process for manufacturing a component from a nickel-based superalloy powder of the present disclosure.

[0039] FIG. 2A is a micrograph of a component obtained by the process of FIG. 1 from a superalloy powder comprising more than 200 ppm carbon, after the sintering step.

[0040] FIG. 2B is a micrograph of the component of FIG. 2A after a grain growth step.

[0041] FIG. 3A is a micrograph of a component obtained by the process of FIG. 1 from a superalloy powder comprising less than 200 ppm carbon.

[0042] FIG. 3B is a micrograph of the component of FIG. 3A after a grain growth step.

DETAILED DESCRIPTION

[0043] FIG. 1 schematically shows a process for manufacturing 100 a component from a nickel-based superalloy powder comprising between 0 and 200 ppm carbon, preferably between 5 and 200 ppm carbon.

EXAMPLES

[0044] Two superalloy powder compositions were studied, a composition comprising 160 ppm carbon (Example 1) and a composition similar to the composition of Example 1 but comprising 740 ppm carbon (Example 2).

[0045] The respective compositions of Examples 1 and 2 (Ex1 and Ex2 ) are given in Table 1 in mass percent, the remainder consisting of nickel and unavoidable impurities.

[0046] Example 1 further comprises, as unavoidable impurities, 0.060% by mass silicon and 0.030% by mass oxygen.

[0047] Example 2 further comprises, as unavoidable impurities, 0.050% by mass silicon, 0.022% by mass oxygen and 0.014% by mass manganese.

TABLE-US-00001 TABLE 1 Cr Co Mo Al Ti Cu Fe C Ex1 14.72 15.06 4.3 4.4 3.6 0.03 0.20 0.0160 Ex2 15.01 14.30 4.5 4.2 3.5 0.03 0.14 0.0740

[0048] During the mixing step 102, the superalloy powder is mixed with at least two binders, a thermoplastic primary binder which gives the mixture rheological properties allowing the mixture to be injected into the mold and a secondary binder which gives the green component a mechanical strength allowing the green component to be handled after demolding.

[0049] Typically, the loading ratio of the mixture, i.e., the volume of powder in relation to the total volume (powder+additives) is comprised between 60 and 70%. The additives comprise binders and other additives.

[0050] In the embodiment described, the ratio of primary binder to secondary binder is 2:1 by mass, i.e., the mixture comprises twice as much primary binder as secondary binder by mass.

[0051] As non-limiting examples of thermoplastic primary binders, mention may be made of paraffin, carnauba wax, beeswax, peanut oil, acetanilide, antipyrine, naphthalene, polyoxymethylene resin (POM).

[0052] As non-limiting examples of secondary binders, mention may be made of polyethylene (PE), polypropylene (PP), polystyrene (PS), polyamides (PA), polyethylene vinyl acetate (PE-VA), polyethyl acrylate (PEA), polyphthalamides (PPA).

[0053] As non-limiting examples of other additives, mention may be made of stearic acid, oleic acid and esters thereof, and phthalic acid esters.

[0054] The step of injection molding 104 the mixture in a mold to obtain a green component is then performed in a known manner.

[0055] The debinding step 106 is generally performed in two substeps, a first substep 106A of debinding the primary binder. This step of debinding the primary binder 106A is generally performed at a temperature comprised between 30° C. and 100° C. and by means of a solvent. The solvent may, for example, be water.

[0056] The secondary binder is always present and gives the component a mechanical strength that allows it to be handled.

[0057] The second debinding substep 106B is a thermal step, i.e., a step in which the component is heated to burn off the secondary binder and obtain the debonded component.

[0058] This second substep 106B is, for example, performed during the temperature rise for sintering of the component. For example, the thermal debinding step 106B is performed between 400° C. and 700° C. with a step comprised between 30 minutes and 10 hours.

[0059] In the sintering step 108, the debonded components densified. For example, the component is sintered at 1230° C. to 1300° C. for 5 h.

[0060] FIGS. 2 and 3 show the microstructures of Example 2 and Example 1, respectively. It may be seen that after the sintering step 108 and before the heat treatment step 110, the average grain size is about ASTM8 for Example 2 while its about ASTM4 for Example 1, measured according to the ASTM E112-13 standard.

[0061] The sintered components then heat treated. The heat treatment step 110 comprises a step of growing grains 110A such that the average grain sizes greater than or equal to ASTM6, preferably greater than or equal to ASTMS, more preferably greater than or equal to ASTM4, measured according to the ASTM E112-13 standard and a step of precipitating a γ′ phase 110B.

[0062] Typically, after the grain growth step 110A, for Example 2, the average grain size is about ASTM6 for a grain growth step 110A performed at 1275° C. for 10 h.

[0063] After the grain growth step 110A, for Example 1, the average grain size is about ASTM3 for a grain growth step 110A performed at 1275° C. for 5 h.

[0064] After the grain growth step 110A, the heat treatment step 110 comprises the step of precipitating a γ′ phase 110B. This step of precipitating a γ′ phase 110B does not change the average grain size.

[0065] Between the sintering step 108 and the heat treatment step 110, the component may be brought down to room temperature.

[0066] Between the grain growth step 110A and the precipitation step 110B, the component may be brought down to room temperature.

[0067] The component obtained from the superalloy powder of Example 1 has better high-temperature creep behavior than the component obtained from the superalloy powder of Example 2. By way of indication, at 950° C., all test conditions being constant, a service life between 2 to 2.5 times longer is observed for the component obtained from the superalloy powder of Example 1 than for the component obtained from the superalloy powder of Example 2. The tests a uniaxial tensile creep test, conducted to failure, according to the NF EN ISO 204 standard.

[0068] Although the present disclosure has been described with reference to a specific example embodiment, its obvious that various modifications and changes may be made to these examples without departing from the general scope of the invention as defined by the claims. Furthermore, individual features of the various embodiments discussed may be combined in additional embodiments. Consequently, the description and drawings should be considered in an illustrative rather than a restrictive sense.