LAYER SYSTEM FOR COATING A BIPOLAR PLATE, BIPOLAR PLATE, AND FUEL CELL

Abstract

A layer system (1, 1′, 1″, Ia) for coating a bipolar plate (10) or an electrode unit (10a, 10b), including at least one first layer (2, 2a, 2b), at least one second layer (3), and at least one cover layer (4, 4a, 4b) arranged on the at least one second layer (3) made of a doped tetrahedral amorphic carbon ta-C:X, wherein as the dopant X, at least one element is provided from the group including titanium, niobium, tungsten, zirconium, tantalum, hafnium, molybdenum, copper, silicon, platinum, palladium, ruthenium, iridium, silver, boron, nitrogen, phosphor, fluorine, hydrogen, and oxygen, and the dopant X is provided in the cover layer (4, 4a, 4b) in a concentration of >0 to 20 at.-%. A bipolar plate (10) or an electrode unit (10a, 10b) having such a layer system and a fuel cell (100) and a redox flow cell (110) are also provided.

Claims

1. A layer system for coating a bipolar plate or an electrode unit, the layer system comprising: at least one first layer, at least one second layer; and at least one cover layer arranged on the at least one second layer that is made of doped, tetrahedral amorphous carbon ta-C:X, wherein as a dopant X at least one element is provided from the group comprising: titanium, niobium, tungsten, zirconium, tantalum, hafnium, molybdenum, copper, silicon, platinum, palladium, ruthenium, iridium, silver, boron, nitrogen, phosphorus, fluorine, hydrogen, or oxygen, and the dopant X is provided in the cover layer in a concentration of >0 to 20 at. %.

2. The layer system according to claim 1, wherein the at least one first layer is a metallic layer that is formed from at least one element from the group comprising: titanium, niobium, hafnium, zirconium, or tantalum.

3. The layer system according to claim 2, wherein the at least one first layer is formed from a titanium-niobium alloy.

4. The layer system according to claim 3, wherein the titanium-niobium alloy has a niobium content in the range from 20 to 60 at.-%.

5. The layer system according to claim 1, wherein the at least one second layer is a metallic layer doped with at least one non-metal and formed from at least one element from the group comprising: titanium, niobium, hafnium, zirconium, or tantalum, and the at least one non-metal is formed by at least one element from the group comprising: nitrogen, carbon, fluorine, boron, hydrogen, or oxygen.

6. The layer system according to claim 1, wherein at least one of the at least one first layer or the at least one second layer have a layer thickness in a range from 20 nm to 900 nm.

7. The layer system according to claim 1, wherein the at least one cover layer has a layer thickness in a range from 5 nm to 4.5 μm.

8. A bipolar plate having an anode side and a cathode side, the bipolar plate comprising: a metallic substrate and the layer system according to claim 1, having a structure of the bipolar plate in the following order: the metallic substrate, the at least one first layer, the at least one second layer, and second layers, and the at least one cover layer.

9. A fuel cell, comprising at least one of the bipolar plates according to claim 8.

10. The fuel cell according to claim 9, further comprising at least one polymer electrolyte membrane.

11. An electrode unit, comprising: a substrate and the layer system according to claim 1, having a structure of the electrode unit in the order: a metallic substrate, the at least one first layer, the at least one second layer, and the at least one cover layer.

12. A redox flow cell, comprising: at least one of the electrode units according to claim 11, a first reaction space and a second reaction space wherein each of the first and second reaction spaces is in contact with in each case one of the electrode units and is in a region of the layer system, and the first and second reaction spaces are separated from one another by a polymer electrolyte membrane.

13. The bipolar plate of claim 8, further comprising a gas diffusion layer between the metallic substrate and the at least one first layer.

14. The bipolar plate of claim 8, wherein the at least one first layer and the at least one second layer are provided in an alternating arrangement of the first layers and the second layers.

15. The fuel cell of claim 8, wherein the fuel cell is an oxygen-hydrogen fuel cell or an electrolyzer.

16. The electrode unit of claim 11, wherein the at least one first layer and the at least one second layer are provided in an alternating arrangement of the first layers and the second layers.

17. A bipolar plate having an anode side and a cathode side, the bipolar plate comprising: a substrate; at least one first layer; at least one second layer; and at least one cover layer arranged on the at least one second layer that is made of doped, tetrahedral amorphous carbon ta-C:X, wherein as a dopant X at least one element is provided from the group comprising: titanium, niobium, tungsten, zirconium, tantalum, hafnium, molybdenum, copper, silicon, platinum, palladium, ruthenium, iridium, silver, boron, nitrogen, phosphorus, fluorine, hydrogen, or oxygen, and the dopant X is provided in the cover layer in a concentration of >0 to 20 at. %.

18. The bipolar plate of claim 17, wherein a structure of the bipolar plate is arranged in the following order: the substrate, the at least one first layer, the at least one second layer, and the at least one cover layer.

19. The bipolar plate of claim 17, wherein the at least one first layer and the at least one second layer are provided in an alternating arrangement of the first layers and the second layers.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0031] FIGS. 1 to 8 are intended to exemplify layer systems according to the disclosure and a bipolar plate formed therewith as well as fuel cell and electrode unit and a redox flow cell. In the figures:

[0032] FIG. 1 shows a first layer system on a metallic substrate

[0033] FIG. 2 shows a second layer system on a metallic substrate

[0034] FIG. 3 shows a third layer system on a metallic substrate

[0035] FIG. 4 shows a fourth layer system on a metallic substrate having a gas diffusion layer

[0036] FIG. 5 shows a bipolar plate with a layer system

[0037] FIG. 6 shows a fuel cell or a fuel cell system

[0038] FIG. 7 shows an electrode unit with a layer system, an

[0039] FIG. 8 schematically shows a redox flow cell having an electrode unit.

DETAILED DESCRIPTION

[0040] FIG. 1 shows, in a sectional view, an exemplary embodiment of a first layer system 1 according to the disclosure on a metallic substrate 5. A first layer 2 made of a TiNb alloy is located on the substrate 5. A second layer 3 made of TiNbN or TiNbCN is located on the first layer 2. On the second layer 3 there is at least one cover layer 4 made of ta-C:H (dopant X=hydrogen) and/or ta-C:H:O (dopants X=hydrogen and oxygen) or ta-C:H:O:Si (dopants X=hydrogen and oxygen and silicon).

[0041] FIG. 2 shows, in a sectional view, an exemplary embodiment of a second layer system 1′ according to the disclosure on a metallic substrate 5. On the substrate 5 there is a first layer 2a made of titanium and a further first layer 2b made of a TiHf alloy. A second layer 3 made of TiHfN or TiHfCN is located on the further first layer 2b. On the second layer 3 there is a cover layer 4 made of ta-C:Ir (dopant X=iridium) or ta-C:Ru (dopant X=ruthenium).

[0042] FIG. 3 shows, in a sectional view, an exemplary embodiment of a third layer system 1″ according to the disclosure on a metallic substrate 5. A first layer 2 made of titanium is located on the substrate 5. A second layer 3 made of TiBN is located on the first layer 2. A first cover layer 4a made of ta-C:B (dopant X=boron) is located on the second layer 3. A second cover layer 4b made of ta-C:Ta (dopant X=tantalum) is located on the first cover layer 4a. Alternatively, the first and the second cover layer 4a, 4b can be applied alternately and each in a number n>2.

[0043] FIG. 4 shows, in a sectional view, an exemplary embodiment of a fourth layer system 1 according to the disclosure on a metallic substrate 5 which has a gas diffusion layer 6. A first layer 2 made of a TiNb alloy is located on the gas diffusion layer 6. A second layer 3 made of TiNbN or TiNbCN is located on the first layer 2. On the second layer 3 there is at least one cover layer 4 made of ta-C:H (dopant X=hydrogen) and/or ta-C:H:O (dopants X=hydrogen and oxygen) or ta-C:H:O:Si (dopants X=hydrogen and oxygen and silicon).

[0044] FIG. 5 shows a bipolar plate 10 having a layer system 1, which here has a metallic substrate 5 or a metallic carrier plate made of stainless steel. The layer system 1 covers the bipolar plate 10 on both sides. The layer system 1 has a total thickness in the range of 20 nm to 5 μm. The bipolar plate 10 has an inflow region 11 with openings 8 and an outlet region 12 with further openings 8′ which are used to supply a fuel cell with process gases and to remove reaction products from the fuel cell. The bipolar plate 10 also has a gas distribution structure 9 on each side, which for

[0045] FIG. 6 schematically shows a fuel cell system 100′ comprising a plurality of fuel cells 100. Each fuel cell 100 comprises a polymer electrolyte membrane 7 which is adjacent to both sides of bipolar plates 10, 10′. The same reference symbols as in FIG. 5 indicate identical elements.

[0046] FIG. 7 shows an electrode unit 10a in a three-dimensional view comprising a metallic substrate 5 and a layer system 1a on the substrate 5. A flow field 9a is embossed into the substrate 5, so that a three-dimensional structuring of the surface of the electrode unit 10a results.

[0047] FIG. 8 schematically shows a redox flow cell 110 or a redox flow battery having a redox flow cell 110. The redox flow cell 110 comprises two electrode units 10a, 10b, a first reaction space 13a and a second reaction space 13b, wherein each reaction space 13a, 13b is in contact with one of the electrode units 10a, 10b. The electrode units 10a, 10b each have a flow field 9a which is arranged facing the respective adjacent reaction space 13a, 13b. The layer system 1a (see FIG. 7) covers the surface in contact with the reaction space 13a, 13b with the flow field 9a of the substrate 5 of the respective electrode unit 10a, 10b. The reaction spaces 13a, 13b are separated from one another by a polymer electrolyte membrane 7. A liquid anolyte 14a is pumped from a tank 15a via a pump 16a into the first reaction space 13a and passed between the electrode unit 10a and the polymer electrolyte membrane 7. A liquid catholyte 14b is pumped from a tank 15b via a pump 16b into the second reaction space 13b and passed between the electrode unit 10b and the polymer electrolyte membrane 7. An ion exchange takes place across the polymer electrolyte membrane 7, wherein electrical energy is released due to the redox reaction at the electrode units 10a, 10b.

LIST OF REFERENCE SYMBOLS

[0048] 1, 1′, 1″, 1a Layer system [0049] 2, 2a, 2b First layer [0050] 3 Second layer [0051] 4, 4a, 4b Cover layer [0052] 5 Metallic substrate [0053] 6 Gas diffusion layer [0054] 7 Polymer electrolyte membrane [0055] 8, 8′ Opening [0056] 9 Gas distribution structure [0057] 9a Flow field [0058] 10, 10′ Bipolar plate [0059] 10a, 10b Electrode unit [0060] 11 Inflow region [0061] 12 Outlet region [0062] 13a, 13b Reaction space [0063] 14a Anolyte [0064] 14b Catholyte [0065] 15a, 15b Tank [0066] 16a, 16b Pump [0067] 100 Fuel cell [0068] 100′ Fuel cell system [0069] 110 Redox flow cell