Optical ribbon with printing between opaque primary layer and colored secondary layer
11391902 · 2022-07-19
Assignee
Inventors
- David Wesley Chiasson (Edmonton, CA)
- Ching-Kee Chien (Horseheads, NY)
- Gregory Alan Mills (Clemmons, NC, US)
Cpc classification
International classification
Abstract
Disclosed here are embodiments of an optical fiber ribbon. In the optical fiber ribbon, a plurality of optical fibers are arranged in a row. The optical fibers are embedded in a primary matrix. The primary matrix comprises a base resin and an opacifier pigment. A secondary matrix is disposed around the primary matrix, and a layer of printing is disposed between the primary matrix and the secondary matrix. The secondary matrix has a contrast ratio of from 0.2 to 0.9 as measured according to ASTM D2805. Embodiments of a method of preparing an optical fiber ribbon are also disclosed in which optical fibers are arranged in a row and embedded in a primary matrix. Characteristics of the optical fibers is printed onto the primary matrix, and the primary matrix is coated with a secondary matrix having a contrast ratio of from 0.2 to 0.9 according to ASTM D2805.
Claims
1. An optical fiber ribbon, comprising: a plurality of optical fibers arranged in a row; a primary matrix into which the plurality of optical fibers are embedded, wherein the primary matrix comprises a base resin and an opacifier pigment; a secondary matrix disposed around the primary matrix; a layer of printing disposed between the primary matrix and the secondary matrix; wherein the secondary matrix has a contrast ratio of from 0.2 to 0.9 as measured according to ASTM D2805.
2. The optical fiber ribbon of claim 1, wherein the primary matrix is white.
3. The optical fiber ribbon of claim 2, wherein the opacifier pigment is at least one of TiO.sub.2, BaSO.sub.4, ZnO or ZnS.
4. The optical fiber ribbon of claim 1, wherein the primary matrix is black.
5. The optical fiber ribbon of claim 4, wherein the layer of printing comprises dots of yellow ink or white ink.
6. The optical fiber ribbon of claim 1, wherein the primary matrix is gray.
7. The optical fiber ribbon of claim 6, wherein the opacifier pigment comprises a combination of at least one of TiO.sub.2, BaSO.sub.4, ZnO or ZnS and carbon black.
8. The optical fiber ribbon of claim 1, wherein the secondary matrix is blue with a hue angle of 220 to 270 according to CIE L*c*h* and wherein the secondary matrix comprises a contrast ratio of 0.5 to 0.7 according to ASTM D2805.
9. The optical fiber ribbon of claim 1, wherein, according to CIE L*c*h*, the secondary matrix is orange with a hue angle of 50 to 80 or brown with a hue angle of 30 to 80 and wherein the secondary matrix comprises a contrast ratio of 0.3 to 0.6 according to ASTM D2805.
10. The optical fiber ribbon of claim 1, wherein the secondary matrix is green with a hue angle of 120 to 190 according to CIE L*c*h* and wherein the secondary matrix comprises a contrast ratio of 0.3 to 0.7 according to ASTM D2805.
11. The optical fiber ribbon of claim 1, wherein the secondary matrix is slate with a hue angle of 0 to 360 according to CIE L*c*h* and wherein the secondary matrix comprises a contrast ratio of 0.3 to 0.5 according to ASTM D2805.
12. The optical fiber ribbon of claim 1, wherein the secondary matrix is white with a hue angle of 0 to 360 according to CIE L*c*h* and wherein the secondary matrix comprises a contrast ratio of 0.2 to 0.7 according to ASTM D2805.
13. The optical fiber ribbon of claim 1, wherein, according to CIE L*c*h*, the secondary matrix is red with a hue angle of 46 to 71, black with a hue angle of from 0 to 360, yellow with a hue angle of 73 to 98, violet with a hue angle of 60 to 85, or aqua with a hue angle of 67 to 92 and wherein the secondary matrix comprises a contrast ratio of 0.5 to 0.8 according to ASTM D2805.
14. The optical fiber ribbon of claim 1, wherein the secondary matrix is rose with a hue angle of 59-84 according to CIE L*c*h* and wherein the secondary matrix comprises a contrast ratio of 0.6 to 0.9 according to ASTM D2805.
15. The optical fiber ribbon of claim 1, wherein an average minimum thickness between a surface of an optical fiber of the plurality of the optical fibers and an outer surface of the primary matrix is from 5 μm to 15 μm.
16. The optical fiber ribbon of claim 1, wherein a thickness of the secondary matrix is from 5 μm to 50 μm.
17. The optical fiber ribbon of claim 1, wherein the plurality of optical fibers is at least four optical fibers and wherein each optical fiber has a longitudinal axis that is coplanar with the other optical fibers in the row.
18. A method of preparing an optical fiber ribbon, comprising the steps of: arranging a plurality of optical fibers in a row; embedding the plurality of optical fibers into a primary matrix, wherein the primary matrix comprises a base resin and an opacifier pigment; printing information regarding characteristics of the optical fiber ribbon onto the primary matrix; and coating the primary matrix with a secondary matrix, wherein the secondary matrix comprises a contrast ratio of from 0.2 to 0.9 as measured according to ASTM D2805.
19. The method of claim 18, comprising the step of selecting the secondary matrix to be blue with a hue angle of 220 to 270 according to CIE L*c*h* and wherein the secondary matrix comprises a contrast ratio of 0.5 to 0.7 according to ASTM D2805.
20. The method of claim 18, comprising the step of selecting, according to CIE L*c*h*, the secondary matrix to be orange with a hue angle of 50 to 80 or brown with a hue angle of 30 to 80 and wherein the secondary matrix comprises a contrast ratio of 0.3 to 0.6 according to ASTM D2805.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
(5) Referring generally to the figures, various embodiments of an optical fiber ribbon having an opacifying primary matrix, a colored secondary matrix, and printing between the primary matrix and the secondary matrix are provided. As will be discussed more fully below, the opacifying primary matrix reduces an intensity of colors of optical fibers embedded in the primary matrix. In this way, the primary matrix provides a high contrast background, which allows the printing to be more easily discerned. Additionally, the secondary matrix provides a color-tinted outer layer for identification purposes without obscuring the underlying printing. In this way, the printing can be protected from abrasion by the secondary matrix while remaining legible for cable installers, technicians, and other handlers. In essence, the optical fiber ribbons according to the present disclosure achieve the goal of providing clearly discernable identification information by separating the functions of opacity and color between the primary matrix and the secondary matrix, respectively.
(6) In contrast to some designs that include opacifiers and colorants in the same matrix layer, the designs discussed herein have separate matrix layers for opacifiers and colorants with printing disposed between these matrix layers. Thus, the opacifying primary matrix does not include a colorant. Applicant has found that a ribbon with printing between an underlying opacifying primary matrix layer and an overlying colorant secondary matrix layer maintain the legibility of the printing better than a ribbon with opacifiers and colorants included in the same layer. These and other aspects and advantages will be discussed in relation to the embodiments provided below. These embodiments are provided by way of illustration and not by way of limitation.
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(9) Thus, the primary matrix 14 includes an opacifier to create a contrasting background for the printing 18. In a particular embodiment, the primary matrix 14 includes a pigment, ink, dye, or other colorant as an opacifier. In embodiments, the pigment changes the color of the primary matrix 14 to white, gray, or black.
(10) In terms of the CIE L*c*h* color space, using a white opacifier causes the lightness (L*) values for all of the optical fibers to increase, which makes the color whiter, and the saturation (chroma—c*) decreases, which decreases the intensity of the colors. The hue angle h* for the colors remains the same. By increasing lightness and decreasing chroma, the optical fibers 12 become less visible through the primary matrix 14. In this way, the printing 18 is able to contrast more with the underlying primary matrix 14.
(11) As can be seen in
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(13) As can be seen in
(14) In order to provide a high level of hiding power (along with adequate mechanical properties), the primary matrix 14 is composed of a base resin having a pigment dispersed therein. In embodiments, the base resin is a polymer material that is curable. In a particular embodiment, the base resin is a UV-curable resin comprising an oligomer component, a reactive diluent monomer component, and a photoinitiator. In embodiments, the oligomer is one or more acrylated, methacrylated, or vinyl functional oligomer, and in embodiments, the oligomer has an aliphatic urethane or epoxy backbone. In embodiments, the oligomer comprises 30 wt % to about 80 wt % of the UV-curable resin. In embodiments, the reactive diluent monomer component is one or more reactive diluent monomers having 1 to 5 functional groups of, e.g., acrylate, methacrylate, vinyl ether, or vinyl. In embodiments, the reactive diluent monomer comprises 5 wt % to 65 wt % of the UV-curable resin. In embodiments, the photoinitiator comprises from 0.1 wt % to 10 wt % of the UV-curable resin. In embodiments, the UV-curable resin may also include a variety of other additives in an amount of 0 wt % to 10 wt %, such as antioxidants, catalysts, lubricants, low molecular weight non-crosslinking resins, adhesion promoters, and stabilizers. In embodiments, the base resin comprises from 85 wt % to 99 wt % of the primary matrix 14, and the pigment comprises the remaining 1 wt % to 15 wt % of the primary matrix 14.
(15) In embodiments of the UV-curable resin, the oligomers may be based on an aliphatic polyether polyol, which is reacted with an aliphatic polyisocyanate and then acrylated. In embodiments, the photoinitiator may include at least one photoinitiating compound selected from the group consisting of bis-acyl phosphine oxide; hydroxycyclohexylphenyl ketone; hydroxymethylphenylpropanone; dimethoxyphenylacetophenone; 2-methyl-1,4-(methyl thio)phenyl-2-morpholino-propanone-1; 1-(4-isopropylphenyl)-2-hydroxy-2-methylpropan-1-one; 4-(2-hydroxyethyoxy)phenyl-(2-hydroxy-2-propyl)ketone; 1-(4-dodecyl phenyl)-2-hydroxy-2-methylpropan-1-one; diethoxyacetophenone; 2,2-di-sec-butoxy-acetophenone; diethoxyphenyl acetophenone; bis(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentylphosphine oxide; 2,4,6-trimethylbenzoyldiphenylphosphine oxide; 2,4,6-trimethylbenzoylethoxyphenylphosphine oxide; and mixtures thereof.
(16) Further, in embodiments, examples of suitable reactive diluent monomers include (but are not limited to) isobornyl acrylate; C.sub.6-C.sub.12 hydrocarbon diol diacrylates; C.sub.6-C.sub.12 hydrocarbon diol dimethacrylates; tripropylene glycol diacrylate; tripropylene glycol dimethacrylate; neopentyl glycol, diacrylate; neopentyl glycol dimethacrylate; neopentyl glycol propoxylate diacrylate; neopentyl glycol propoxylate dimethacrylate; neopentyl glycol ethoxylate diacrylate; neopentyl glycol ethoxylate dimethacrylate; bisphenol A ethoxylate diacrylate; bisphenol A ethoxylate dimethacrylate; bisphenol A propoxylate diacrylate; bisphenol A propoxylate dimethacrylate; phenoxyethyl acrylate; phenoxyethyl methacrylate; phenoxyethyl ethoxylate acrylate; phenoxyethyl ethoxylate methacrylate; phenoxyethyl propoxylate acrylate; phenoxyethyl propoxylate methacrylate; polyethylene glycol nonylphenylether acrylate; polyethylene glycol nonylphenylether methacrylate; polypropylene glycol nonylphenylether acrylate; polypropylene glycol nonylphenylether methacrylate; isooctyl methacrylate; octyl acrylate; octyl methacrylate; decyl acrylate; decyl methacrylate; isodecyl acrylate; isodecyl methacrylate; lauryl acrylate; lauryl methacrylate; tridecyl acrylate; tridecyl methacrylate; palmitic acrylate; palmitic methacrylate; stearyl acrylate; stearyl methacrylate; cetyl acrylate; cetyl methacrylate; tetrahydrofurfuryl acrylate; tetrahydrofurfuryl methacrylate; isobornyl acrylate; isobornyl methacrylate; dicyclopentenyl acrylate; dicyclopentenyl methacrylate; dicyclopentenyl ethoxylate acrylate; dicyclopentenyl ethoxylate methacrylate; dicyclopentenyl propoxylate acrylate; dicyclopentenyl propoxylate methacrylate; N-vinyl amides and mixtures thereof. Most preferred compounds include isobornyl acrylate, isocyanurate acrylate and particularly tris-hydroxyethyl isocyanurate triacrylate.
(17) A variety of suitable pigments can be dispersed in the UV-base resin. For a white primary matrix 14, exemplary pigments include TiO.sub.2, BaSO.sub.4, ZnO or ZnS. For a black primary matrix 14, an exemplary pigment is carbon black. For a gray primary matrix 14, the pigment may be a combination of white and black pigments.
(18) The secondary matrix 16 is applied to the outer surface of the primary matrix 14. As discussed above, the secondary matrix 16 is tinted with a colorant so as to provide an identification element to the optical fiber ribbon 10. However, the secondary matrix 16 is also configured to be semi-transparent such that the printing 18 can be seen beneath the secondary matrix 16. As considered herein, the level of transparency of the secondary matrix is selected so as to achieve a desired contrast ratio according to ASTM D2805 of the secondary matrix 16. As used herein, “contrast ratio” is defined as “the ratio of the reflectance of a film on a black substrate to that of an identical film on a white substrate.” In performing a contrast ratio test according to ASTM D2805, the material tested is spread in an even layer over a test card having both a section of white background and a section of black background. Using reflectometry, the reflectance over the white section and the black section is measured. The ratio of these reflectances is the contrast ratio.
(19) The contrast ratio can be adjusted by varying the amount of colorant (e.g., dye, pigment, ink, etc.) used in the composition of the secondary matrix 16 and by varying the thickness of the secondary matrix 16. For example, for a given composition, the contrast ratio of the secondary matrix 16 will increase as the thickness of the secondary matrix 16 increases. Additionally, for a given thickness, the contrast ratio of the secondary matrix 16 will increase as the amount of colorant pigment in the composition of the secondary matrix 16 increases. Table 1 provides the colors of the secondary matrix 16 as defined according the CIE L*c*h* color space, and Table 2 provides the contrast ratio ranges to achieve the desired level of transparency to be able to clearly discern the printing 18 beneath the secondary matrix 16 while still being able to identify the color of the ribbon 10.
(20) TABLE-US-00001 TABLE 1 Secondary Matrix Color (>100 μm on White Background) Chroma (C*) Secondary Color Lightness (L*) (Full saturation) Hue Angle (h*) Blue 55-80 60 220-270 Orange 57-82 60 50-80 Green 70-95 60 120-190 Brown 54-79 60 30-80 Slate 61-86 60 0-360 White 78-98 60 0-360 Red 46-71 60 330-50 Black 0-10 60 0-360 Yellow 73-98 60 70-120 Violet 60-85 60 260-330 Rose 59-84 60 0-25 Aqua 67-92 60 180-230
(21) TABLE-US-00002 TABLE 2 Contrast Ratio of Secondary Matrix as tested according to ASTM 2805 Film thickness Contrast Ratio Material (microns) (C.sub.w) White Primary 20-300 0.2-0.7 Black Ink 20-300 0.8-0.98 Yellow Ink 20-300 0.5-0.7 Secondary Color Blue 20-300 0.5-0.7 Orange 20-300 0.3-0.6 Green 20-300 0.3-0.7 Brown 20-300 0.3-0.6 Slate 20-300 0.3-0.5 White 20-300 0.2-0.7 Red 20-300 0.5-0.8 Black 20-300 0.5-0.8 Yellow 20-300 0.5-0.8 Violet 20-300 0.5-0.8 Rose 20-300 0.6-0.9 Aqua 20-300 0.5-0.8
(22) As shown in the embodiment of
(23) In embodiments, the composition of the secondary matrix 16 is a pigment based color dispersion. In embodiments, the pigments are dispersed in a base resin, such as the embodiments of the base resin described above with respect to the primary matrix 14. A variety of pigments are suitable for use in the pigment-based color dispersion. An exemplary black pigment includes carbon black. Exemplary white pigments include TiO.sub.2, BaSO.sub.4, ZnO or ZnS. Exemplary yellow pigments include diarylide yellow and diazo-based pigments. Exemplary blue pigments include phthalocyanine blue, basic dye pigments, and phthalocyanines. Exemplary red pigments include anthraquinone (red), napthole red, monoazo-based pigments, quinacridone pigments, anthraquinone, and perylenes. Exemplary green pigments include phthalocyanine green and nitroso-based pigments. Exemplary orange pigments include monoazo- and diazo-based pigments, quinacridone pigments, anthraquinones and perylenes. Exemplary violet pigments include quinacrinode violet, basic dye pigments and carbazole dioxazine based pigments. The colors of aqua, brown, gray, and rose can be formulated by combining the pigments of the other colors listed above.
(24) Thus, with reference to the exemplary embodiment shown in
(25) Unless otherwise expressly stated, it is in no way intended that any method set forth herein be construed as requiring that its steps be performed in a specific order. Accordingly, where a method claim does not actually recite an order to be followed by its steps or it is not otherwise specifically stated in the claims or descriptions that the steps are to be limited to a specific order, it is in no way intended that any particular order be inferred. In addition, as used herein, the article “a” is intended to include one or more than one component or element, and is not intended to be construed as meaning only one.
(26) It will be apparent to those skilled in the art that various modifications and variations can be made without departing from the spirit or scope of the disclosed embodiments. Since modifications, combinations, sub-combinations and variations of the disclosed embodiments incorporating the spirit and substance of the embodiments may occur to persons skilled in the art, the disclosed embodiments should be construed to include everything within the scope of the appended claims and their equivalents.