METHODS AND SYSTEMS FOR FABRICATION OF VERTICAL FIN-BASED JFETS
20220254918 · 2022-08-11
Assignee
Inventors
- Clifford Drowley (Santa Clara, CA, US)
- Hao Cui (Santa Clara, CA, US)
- Andrew P. Edwards (Santa Clara, CA, US)
- Subhash Srinivas Pidaparthi (Santa Clara, CA, US)
Cpc classification
H01L29/41791
ELECTRICITY
H01L29/785
ELECTRICITY
H01L29/1066
ELECTRICITY
H01L29/66803
ELECTRICITY
International classification
H01L29/417
ELECTRICITY
H01L29/423
ELECTRICITY
Abstract
A vertical FET device includes a semiconductor structure comprising a semiconductor substrate, a first semiconductor layer coupled to the semiconductor substrate, and a second semiconductor layer coupled to the first semiconductor layer. The vertical FET device also includes a plurality of fins. Adjacent fins of the plurality of fins are separated by a trench extending into the second semiconductor layer and each of the plurality of fins includes a channel region disposed in the second semiconductor layer. The vertical FET also includes a gate region extending into a sidewall portion of the channel region of each of the plurality of fins, a source metal structure coupled to the second semiconductor layer, a gate metal structure coupled to the gate region, and a drain contact coupled to the semiconductor substrate.
Claims
1. A vertical FET device comprising: a semiconductor structure comprising a semiconductor substrate, a first semiconductor layer coupled to the semiconductor substrate, and a second semiconductor layer coupled to the first semiconductor layer; a plurality of fins, wherein adjacent fins of the plurality of fins are separated by a trench extending into the second semiconductor layer and wherein each of the plurality of fins includes a channel region disposed in the second semiconductor layer; a gate region extending into a sidewall portion of the channel region of each of the plurality of fins; a source metal structure coupled to the second semiconductor layer; a gate metal structure coupled to the gate region; and a drain contact coupled to the semiconductor substrate.
2. The vertical FET device of claim 1 further comprising a drift region disposed in the first semiconductor layer.
3. The vertical FET device of claim 1 wherein the gate region extends along a horizontal surface of the first semiconductor layer.
4. The vertical FET device of claim 1 wherein the gate region extends along vertical surfaces of the plurality of fins.
5. The vertical FET device of claim 1 wherein sidewalls of the plurality of fins include an undiffused section.
6. The vertical FET device of claim 1 wherein the gate region comprises a p-GaN gate layer.
7. The vertical FET device of claim 1 wherein a dopant concentration between the gate region and the first semiconductor layer is 1-3×10.sup.19 atoms/cm.sup.3.
8. The vertical FET device of claim 1 wherein the gate region comprises a junction depth between 25 and 50 nm.
9. A method for manufacturing a vertical FET device, the method comprising: providing a semiconductor substrate; epitaxially growing a first semiconductor layer coupled to the semiconductor substrate; epitaxially growing a second semiconductor layer coupled to the first semiconductor layer; forming a patterned hard mask coupled to the second semiconductor layer; etching the second semiconductor layer and a portion of the first semiconductor layer to form a plurality of fins; applying a diffusion dopant layer; applying a sacrificial planarization layer on the diffusion dopant layer; selectively etching the sacrificial planarization layer to expose the diffusion dopant layer; removing an exposed portion of the diffusion dopant layer and the sacrificial planarization layer; performing a thermal treatment to diffuse the diffusion dopant layer into the first semiconductor layer and form a diffused gate layer; removing the diffusion dopant layer and the patterned hard mask; forming a source metal structure coupled to a top surface of the second semiconductor layer; forming a gate metal structure coupled to the diffused gate layer; and forming a drain contact coupled to a bottom surface of the semiconductor substrate.
10. The method of claim 9 further comprising forming an edge termination for the diffused gate layer overlaying a top surface of the first semiconductor layer.
11. The method of claim 9 wherein the diffusion dopant layer comprises a metal layer formed with a p-type dopant.
12. The method of claim 9 wherein selectively etching the sacrificial planarization layer comprises a reactive-ion etch.
13. The method of claim 9 wherein a dopant metallurgical concentration between the diffusion dopant layer and the first semiconductor layer is 1-3×10.sup.19 atoms/cm.sup.3.
14. The method of claim 9 wherein the diffused gate layer extends along a portion of sidewalls of the second semiconductor layer.
15. The method of claim 9 wherein the drain contact comprises titanium, aluminum, or a combination thereof.
16. A method for manufacturing a conformal-gate vertical FET device, the method comprising: providing a semiconductor structure including a substrate, a first semiconductor layer, and a second semiconductor layer; forming a plurality of fins having sidewall surfaces in a portion of the first semiconductor layer and the second semiconductor layer, wherein the plurality of fins are separated by trenches; growing a third semiconductor layer coupled to the sidewall surfaces of the plurality of fins, wherein the third semiconductor layer includes a dopant and comprises a recessed gate region; and forming a source metal, a gate metal, and a drain contact.
17. The method of claim 16 further comprising performing a thermal treatment to activate the dopant in the recessed gate region.
18. The method of claim 16 wherein the third semiconductor layer extends along a portion of the sidewall surfaces of the plurality of fins.
19. The method of claim 16 further comprising forming an edge termination for the recessed gate region overlaying a top surface of the first semiconductor layer.
20. The method of claim 16 wherein the third semiconductor layer comprises a conformal layer.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF SPECIFIC EMBODIMENTS
[0029] Embodiments of the present disclosure will be described more fully hereinafter with reference to the accompanying drawings. The disclosure may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. The features may not be drawn to scale, some details may be exaggerated relative to other elements for clarity. Like numbers refer to like elements throughout.
[0030] Embodiments of the present invention relate to vertical-fin-based field effect transistor (FET) devices. More particular, embodiments of the present invention relate to a vertical FET device with improved routing resistance, reduced lithography requirements, and improved voltage characteristics. Merely by way of example, embodiments of the present invention relate to a vertical FET, devices including vertical FETs, and methods for manufacturing such vertical FET devices.
[0031] Embodiments of the present disclosure are described herein with reference to cross-section illustrations that are schematic illustrations of idealized embodiments (and intermediate structures) of the invention. The thickness of layers and regions in the drawings may be exaggerated for clarity. Additionally, variations from the shapes of the illustrations as a result, for example, of manufacturing techniques and/or tolerances, are to be expected. Thus, embodiments of the invention should not be construed as limited to the particular shapes of regions illustrated herein but are to include deviations in shapes that result, for example, from manufacturing. In the following drawings, the bottom portion of the fins are shown as having a 90 degrees angle with the surface of the graded doping region, i.e., the fins are shown as having a cross-sectional rectangular shape. It is understood that the bottom portion of the fins may have rounded or curved features. Thus, the regions illustrated in the figures are schematic in nature and their shapes are not intended to illustrate the actual shape of a region of a device and are not intended to limit the scope of the invention.
[0032]
[0033] Referring to
[0034] Referring to
[0035] Referring to
[0036] Referring to
[0037] In one embodiment, after forming the fins 112, a cleaning process is carried using a tetramethylammonium hydroxide (TMAH) solution of about 25% by weight, at a temperature of about 85° C., and for a duration of about 30 minutes. In another embodiment, prior to performing a cleaning using the TMAH solution, a pre-cleaning such as piranha clean using a H.sub.2SO.sub.4:H.sub.2O in a volume ratio 2:1 for 2 minutes may also be performed.
[0038]
[0039] Referring to
[0040] Referring to
[0041] Referring to
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[0043] Referring to
[0044] Referring
[0045] Referring to
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[0047] Method 400 also includes forming a first III-nitride epitaxial layer, for example, a 5-12 μm thick first III-nitride epitaxial layer (e.g., an N− GaN epitaxial layer deposited on the III-nitride substrate (404)). The first III-nitride epitaxial layer is epitaxially grown on the III-nitride substrate at a temperature between 950 and 1100° C. and is characterized by a first dopant concentration, e.g., N-type doping with a dopant concentration of about 1×10.sup.16 atoms/cm.sup.3. In some embodiments, the first III-nitride epitaxial layer is a drift layer including a uniformly doped region (layer) on the III-nitride substrate and a graded doping region (layer) on the uniformly doped region. In an embodiment, the uniformly doped region has a thickness of about 10.5 μm, and the graded doping region has a thickness of about 0.3 μm. In an embodiment, the surface of substrate is miscut from the c-plane at an angle to facilitate high-quality epitaxial growth for high-voltage operation of the drift layer.
[0048] Method 400 further includes forming a second III-nitride epitaxial layer on the first III-nitride epitaxial layer (406). In an embodiment, the second III-nitride epitaxial layer is epitaxially grown on the first III-nitride epitaxial layer with a thickness of about 0.7-0.9 μm and is characterized by a second dopant concentration, e.g., N-type doping. The second dopant concentration is higher than the first dopant concentration in some embodiments. In an embodiment, the second dopant concentration is about 1.3×10.sup.17 atoms/cm.sup.3. In an embodiment, the second III-nitride epitaxial layer has a more highly doped surface layer, e.g., about 1-3×10.sup.18 atoms/cm.sup.3, with a thickness of 30-100 nm.
[0049] Method 400 further includes forming and patterning a hard mask layer on the second III-nitride epitaxial layer (408). In some embodiments, the hard mask layer may be a dielectric material such as silicon nitride, silicon dioxide, silicon oxynitride, silicon-aluminum nitride or the like. The dielectric material may be deposited by LPCVD, PECVD, ALD or the like. In some embodiments, the hard mask layer is a composite hard mask including a metal layer on the second III-nitride epitaxial layer and a dielectric hard mask layer on the metal layer. In some embodiments, the metal layer is a refractory metal, refractory metal alloy, or refractory metal nitride (e.g., TiN). The hard mask layer may be patterned using photolithography in combination with an RIE process. In some embodiments utilizing a composite hard mask, the dielectric hard mask layer is first patterned, and then the patterned dielectric hard mask is used as a hard mask to pattern the metal layer.
[0050] Method 400 further includes forming a recess region in the second III-nitride epitaxial layer using the patterned hard mask and an etch process, e.g., an RIE process (410). In an embodiment, the etched recess extends into the first III-nitride epitaxial layer to form fins separated by trenches. In an embodiment, the etched recess extends partially (e.g., 0.1 μm) into the graded layer at the top of the first III-nitride epitaxial layer. In an embodiment, the etch process further includes a wet etch process (e.g., using a TMAH solution of about 25% by weight, at a temperature of about 85° C., and for a duration of about 30 minutes) that can anisotropically etch the III-nitride layers. In another embodiment, prior to performing an etch step using the TMAH solution, a pre-cleaning such as piranha clean using a H.sub.2SO.sub.4:H.sub.2O in a volume ratio 2:1 for 2 minutes may also be performed.
[0051] Method 400 further includes applying a layer of a diffusion dopant material to the surfaces of the fins and the patterned hard mask (412). In some embodiments, the layer of diffusion dopant material may include either a metal layer formed with a p-type dopant (e.g., Mg, Zn, combinations thereof, and the like) or a metallic oxide layer formed with a p-type dopant (e.g., MgO, ZnO, combinations thereof, and the like), in contact with the exposed III-nitride surfaces of the fins. In some embodiments, the thickness of the metal or metallic oxide layer is 50-100 nm. In some embodiments, the layer of diffusion dopant material may further include a second layer of dielectric material (e.g., SiO.sub.2, Si.sub.3N.sub.4 or the like) disposed on the metal or metallic oxide layer.
[0052] Method 400 further includes performing a thermal treatment to diffuse the p-type dopant into the exposed surfaces of the first and second III-nitride semiconductor layers (414). The resulting channel can have a width of the fin width minus twice the diffusion depth. In some embodiments, the thermal treatment may be performed in a furnace at temperatures from 900° C. to 1100° C. In some embodiments, the thermal treatment may be performed in a rapid thermal annealer at temperatures from 1000° C. to 1450° C. In some embodiments the thermal treatment may be performed at a high ambient pressure (e.g., at 1 GPa in a N.sub.2 ambient), with or without the protective layer. In some embodiments the heating may be a result of a series of rapid pulses (e.g. microwave).
[0053] Method 400 further includes removal of the diffusion dopant material (416). In some embodiments, the removal is performed using a wet etch.
[0054] Method 400 further includes removing the patterned hard mask on the top surface of the second III-nitride layer (418). In some embodiments where a composite hard mask layer is used, the top dielectric layer may be removed, leaving the metal layer.
[0055] Method 400 further includes forming a source contact structure on the top surface of the second III-nitride layer (420). In some embodiments, the metal hard mask layer is left in place, and the source contact structure is formed on top of the metal hard mask layer. In some embodiments, the source contact structure is formed using titanium and aluminum.
[0056] Method 400 further includes forming a forming a gate contact structure on that exposed surface portion of the diffused gate layer overlaying the top surface of the first III-nitride epitaxial layer (422). The gate contact structure may include nickel, gold, palladium, platinum, molybdenum, and the like.
[0057] The resulting structure resulting from method 400 can present various advantages. For example, the gate contact structure can be recessed, which may allow for thicker metallization. As a result, the routing resistance can be reduced. Additionally, a portion of the channel can extend below the etch interface of the second III-nitride epitaxial layer and the first III-nitride epitaxial layer, which may allow for shorter fins. Starting with lithographic size constraints and diffusing the gate into the structure can lead to a narrower channel, can be pinched off at a lower threshold voltage. In addition, the fins can be made wider, which can reduce lithography requirements of the fins. This may also increase the ability to align the source contact to the fin.
[0058] Additionally, for enhancement mode devices, the fin width can be small and utilize light doping. For example, enhancement mode devices can have a fin width of 0.5 μm with doping of approximately 10.sup.16 dopants/cm.sup.3. The resulting structure resulting from method 400 can include fin widths of 0.2 μm with doping of approximately 10.sup.17 dopants/cm.sup.3 and threshold voltages in the range of 0.5 V-1.8 V. As a result, the performance of enhancement mode devices can be increased in comparison with conventional devices.
[0059] Method 400 further includes forming a junction-terminated edge (“edge termination”) for the p-GaN layer at the lateral edges of the device active region (424). In some cases, the p-GaN layer is connected to the gate, in others to the source. In some embodiments, this edge termination is formed using a tapered junction.
[0060] Method 400 further includes forming a drain contact at the bottom side of the substrate by forming a metallic contact to the bottom side of substrate (426).
[0061] It should be appreciated that the specific steps illustrated in
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[0063] Referring to
[0064] Referring to
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[0066] Referring to
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[0068] Referring to
[0069] Referring to
[0070] Referring to
[0071] Referring to
[0072] Referring to
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[0074] Method 600 also includes forming a first III-nitride epitaxial layer, for example, a 5-12 μm thick first III-nitride epitaxial layer (e.g., an N− GaN epitaxial layer deposited on the III-nitride substrate (604). The first III-nitride epitaxial layer is epitaxially grown on the III-nitride substrate at a temperature between 950 and 1100° C. and is characterized by a first dopant concentration, e.g., N-type doping with a dopant concentration of about 1×10.sup.16 atoms/cm.sup.3. In some embodiments, the first III-nitride epitaxial layer is a drift layer including a uniformly doped region (layer) on the III-nitride substrate and a graded doping region (layer) on the uniformly doped region. In an embodiment, the uniformly doped region has a thickness of about 10.5 μm, and the graded doping region has a thickness of about 0.3 μm. In an embodiment, the surface of substrate is miscut from the c-plane at an angle to facilitate high-quality epitaxial growth for high-voltage operation of the drift layer.
[0075] Method 600 further includes forming a second III-nitride epitaxial layer on the first III-nitride epitaxial layer (606). In an embodiment, the second III-nitride epitaxial layer is epitaxially grown on the first III-nitride epitaxial layer with a thickness of about 0.7-0.9 μm and is characterized by a second dopant concentration, e.g., N-type doping. The second dopant concentration is higher than the first dopant concentration in some embodiments. In an embodiment, the second dopant concentration is about 1.3×10.sup.17 atoms/cm.sup.3. In an embodiment, the second III-nitride epitaxial layer has a more highly doped surface layer, e.g., about 1-3×10.sup.18 atoms/cm.sup.3, with a thickness of 30-100 nm.
[0076] Method 600 further includes forming and patterning a hard mask layer on the second III-nitride epitaxial layer (608). In some embodiments, the hard mask layer may be a dielectric material such as silicon nitride, silicon dioxide, silicon oxynitride, silicon-aluminum nitride or the like. The dielectric material may be deposited by LPCVD, PECVD, ALD or the like. In some embodiments, the hard mask layer is a composite hard mask including a metal layer on the second III-nitride epitaxial layer and a dielectric hard mask layer on the metal layer. In some embodiments, the metal layer is a refractory metal, refractory metal alloy, or refractory metal nitride (e.g., TiN). The hard mask layer may be patterned using photolithography in combination with an RIE process. In some embodiments with a composite hard mask, the dielectric hard mask layer is first patterned, and then the patterned dielectric hard mask is used as a hard mask to pattern the metal layer.
[0077] Method 600 further includes forming a recess region in the second III-nitride epitaxial layer using the patterned hard mask by an etch process, e.g., an RIE process (610). In an embodiment, the etched recess extends into the first III-nitride epitaxial layer to define fins separated by trenches. In an embodiment, the etched recess extends partially (e.g., 0.1 μm) into the graded layer at the top of the first III-nitride epitaxial layer.
[0078] Method 600 further includes applying a layer of a diffusion dopant material to the surfaces of the fins and the patterned hard mask (612). In some embodiments, the layer of diffusion dopant material may include either a metal layer formed with a p-type dopant (e.g., Mg, Zn, combinations thereof, and the like) or a metallic oxide layer formed with a p-type dopant (e.g., MgO, ZnO, combinations thereof, and the like), in contact with the exposed III-nitride surfaces of the fins. In some embodiments, the thickness of the metal or metallic oxide layer is 50-100 nm. In some embodiments, the layer of diffusion dopant material may further include a second layer of dielectric material (e.g., SiO.sub.2, Si.sub.3N.sub.4 or the like) disposed on the metal or metallic oxide layer.
[0079] Method 600 further includes applying a sacrificial planarization material (614) to fill in the trenches and provide a substantially planar surface above the fins. In some embodiments, the sacrificial planarization material is a polymer. In some embodiments, the sacrificial planarization material is a photoresist. In some embodiments, the sacrificial planarization material is a spin-on glass.
[0080] Method 600 further includes etching back the sacrificial planarization material (616) to expose a portion of the diffusion dopant material on the sidewall of the fins. The exposed portion of the diffusion dopant material may be controlled by the etch depth of the etchback. After the etchback, the exposed diffusion dopant material may be selectively removed (616). In this manner, the height of the diffusion dopant material on the sidewall may be controlled to a height less than that of the fin sidewall.
[0081] Method 600 further includes removing the sacrificial planarization material (618). For example, if the sacrificial planarization material is a polymer or photoresist, an oxygen plasma may be used to remove the sacrificial planarization material.
[0082] Method 600 further includes performing a thermal treatment to diffuse the p-type dopant into the exposed surfaces of the first and second III-nitride semiconductor layers (620). In some embodiments, the thermal treatment may be performed in a furnace at temperatures from 900° C. to 1100° C. In some embodiments, the thermal treatment may be performed in a rapid thermal annealer at temperatures from 1000° C. to 1450° C. In some embodiments the thermal treatment may be performed at a high ambient pressure (e.g., at 1 GPa in a N.sub.2 ambient), with or without the protective layer. In some embodiments the heating may be a result of a series of rapid pulses (e.g. microwave).
[0083] Method 600 further includes removal of the diffusion dopant material (622). In some embodiments, the removal is performed using a wet etch.
[0084] Method 600 further includes removing the patterned hard mask on the top surface of the second III-nitride layer (624). In some embodiments where a composite hard mask layer is used, the top dielectric layer may be removed, leaving the metal layer.
[0085] Method 600 further includes forming a source contact structure on the top surface of the second III-nitride layer (626). In some embodiments, the metal hard mask layer is left in place, and the source contact structure is formed on top of the metal hard mask layer. In some embodiments, the source contact structure is formed using titanium and aluminum.
[0086] Method 600 further includes forming a forming a gate contact structure on that exposed surface portion of the diffused gate layer overlaying the top surface of the first III-nitride epitaxial layer (628). The gate contact structure may include nickel, gold, palladium, platinum, molybdenum, and the like.
[0087] Method 600 further includes forming a junction-terminated edge (“edge termination”) for the p-GaN layer at the lateral edges of the device active region (630). In some cases, the p-GaN layer is connected to the gate, in others to the source. In some embodiments, this edge termination is formed using a tapered junction.
[0088] Method 600 further includes forming a drain contact at the bottom side of the substrate by forming a metallic contact to the bottom side of substrate (632).
[0089] It should be appreciated that the specific steps illustrated in
[0090]
[0091] Referring to
[0092] Referring to
[0093] Referring to
[0094] Referring to
[0095] Referring to
[0096]
[0097] Referring to
[0098] Referring to
[0099] Referring to
[0100] The stages illustrated in of
[0101]
[0102] Method 900 also includes forming a first III-nitride epitaxial layer, for example, a 5-12 μm thick first III-nitride epitaxial layer (e.g., an N− GaN epitaxial layer deposited on the III-nitride substrate (904). The first III-nitride epitaxial layer is epitaxially grown on the III-nitride substrate at a temperature between 950 and 1100° C. and is characterized by a first dopant concentration, e.g., N-type doping with a dopant concentration of about 1×10.sup.16 atoms/cm.sup.3. In some embodiments, the first III-nitride epitaxial layer is a drift layer including a uniformly doped region (layer) on the III-nitride substrate and a graded doping region (layer) on the uniformly doped region. In an embodiment, the uniformly doped region has a thickness of about 10.5 μm, and the graded doping region has a thickness of about 0.3 μm. In an embodiment, the surface of substrate is miscut from the c-plane at an angle to facilitate high-quality epitaxial growth for high-voltage operation of the drift layer.
[0103] Method 900 further includes forming a second III-nitride epitaxial layer on the first III-nitride epitaxial layer (906). In an embodiment, the second III-nitride epitaxial layer is epitaxially grown on the first III-nitride epitaxial layer with a thickness of about 0.7-0.9 μm and is characterized by a second dopant concentration, e.g., N-type doping. The second dopant concentration is higher than the first dopant concentration in some embodiments. In an embodiment, the second dopant concentration is about 1.3×10.sup.17 atoms/cm.sup.3. In an embodiment, the second III-nitride epitaxial layer has a more highly doped surface layer, e.g., about 1-3×10.sup.18 atoms/cm.sup.3, with a thickness of 30-100 nm.
[0104] Method 900 further includes forming and patterning a hard mask layer on the second III-nitride epitaxial layer (908). In some embodiments, the hard mask layer may be a dielectric material such as silicon nitride, silicon dioxide, silicon oxynitride, silicon-aluminum nitride or the like. The dielectric material may be deposited by LPCVD, PECVD, ALD or the like. In some embodiments, the hard mask layer is a composite hard mask including a metal layer on the second III-nitride epitaxial layer and a dielectric hard mask layer on the metal layer. In some embodiments, the metal layer is a refractory metal, refractory metal alloy, or refractory metal nitride (e.g., TiN). The hard mask layer may be patterned using photolithography in combination with an RIE process. In some embodiments with a composite hard mask, the dielectric hard mask layer is first patterned, and then the patterned dielectric hard mask is used as a hard mask to pattern the metal layer.
[0105] Method 900 further includes forming a recess region in the second III-nitride epitaxial layer using the patterned hard mask by an etch process, e.g., an RIE process (910), to form fins separated by trenches. In an embodiment, the etched recess extends into the first III-nitride epitaxial layer. In an embodiment, the etched recess extends partially (e.g., 0.1 μm) into the graded layer at the top of the first III-nitride epitaxial layer.
[0106] Method 900 further includes applying a sacrificial coating layer to the surfaces of the fins and the patterned hard mask (912) to create a substantially planar surface. In some embodiments, the sacrificial coating layer is a spin-on glass. In some embodiments, the sacrificial coating layer is silicon dioxide. In some embodiments, the sacrificial coating layer is deposited using PECVD. In some embodiments, the top surface of the sacrificial coating layer is 1-2 μm above the top surface of the patterned hard mask.
[0107] Method 900 further includes etching back the sacrificial coating layer to expose the patterned hard mask and a portion of the sidewalls of the fins (914). In some embodiments, the etch is performed using a fluorine-containing plasma.
[0108] Method 900 further includes depositing a conformal dielectric layer on the exposed surfaces of the patterned hard mask, the fin sidewalls, and the sacrificial coating layer (916). In some embodiments, the conformal dielectric layer is one of silicon nitride, silicon-aluminum nitride, or aluminum nitride. In some embodiments, the conformal dielectric layer is deposited by one of PECVD, LPCVD, or ALD.
[0109] Method 900 further includes performing a directional (anisotropic) etch of the conformal dielectric layer (918) to leave a “spacer” layer on the sidewalls of the patterned hard mask and a portion of the fin sidewalls. In some embodiments, the directional etch is performed using an RIE process.
[0110] Method 900 further includes removal of the sacrificial coating layer (920) to expose the remaining portions of the fin sidewalls and the trench bottom regions. In some embodiments, the sacrificial coating layer is removed using a wet etch.
[0111] Method 900 further includes applying a layer of a diffusion dopant material to the surfaces of the fins and the patterned hard mask (922). In some embodiments, the layer of diffusion dopant material may include either a metal layer formed with a p-type dopant (e.g., Mg, Zn, combinations thereof, and the like) or a metallic oxide layer formed with a p-type dopant (e.g., MgO, ZnO, combinations thereof, and the like), in contact with the exposed III-nitride surfaces of the fins. In some embodiments, the thickness of the metal or metallic oxide layer is 50-100 nm. In some embodiments, the layer of diffusion dopant material may further include a second layer of dielectric material (e.g., SiO.sub.2, Si.sub.3N.sub.4 or the like) disposed on the metal or metallic oxide layer.
[0112] Method 900 further includes performing a thermal treatment to diffuse the p-type dopant into the exposed surfaces of the first and second III-nitride semiconductor layers (924). In some embodiments, the thermal treatment may be performed in a furnace at temperatures from 900° C. to 1100° C. In some embodiments, the thermal treatment may be performed in a rapid thermal annealer at temperatures from 1000° C. to 1450° C. In some embodiments the thermal treatment may be performed at a high ambient pressure (e.g., at 1 GPa in a N.sub.2 ambient). In some embodiments the heating may be a result of a series of rapid pulses (e.g. microwave).
[0113] Method 900 further includes removal of the diffusion dopant material (926). In some embodiments, the removal is performed using a wet etch.
[0114] Method 900 further includes removing the patterned hard mask on the top surface of the second III-nitride layer (928). Optionally, the spacer may also be removed. In some embodiments where a composite hard mask layer is used, the top dielectric layer may be removed, leaving the metal layer.
[0115] Method 900 further includes forming a source contact structure on the top surface of the second III-nitride layer (930). In some embodiments, the metal hard mask layer is left in place, and the source contact structure is formed on top of the metal hard mask layer. In some embodiments, the source contact structure is formed using titanium and aluminum.
[0116] Method 900 further includes forming a forming a gate contact structure on that exposed surface portion of the diffused gate layer overlaying the top surface of the first III-nitride epitaxial layer (932). The gate contact structure may include nickel, gold, palladium, platinum, molybdenum, and the like.
[0117] Method 900 further includes forming a junction-terminated edge (“edge termination”) for the p-GaN layer at the lateral edges of the device active region (934). In some cases, the p-GaN layer is connected to the gate, in others to the source. In some embodiments, this edge termination is formed using a tapered junction.
[0118] Method 900 further includes forming a drain contact at the bottom side of the substrate by forming a metallic contact to the bottom side of substrate (936).
[0119] It should be appreciated that the specific steps illustrated in
[0120]
[0121] Referring to
[0122] The stages illustrated in
[0123]
[0124] Method 1100 also includes forming a first III-nitride epitaxial layer, for example, a 5-12 μm thick first III-nitride epitaxial layer (e.g., an N− GaN epitaxial layer deposited on the III-nitride substrate (1104). The first III-nitride epitaxial layer is epitaxially grown on the III-nitride substrate at a temperature between 950 and 1100° C. and is characterized by a first dopant concentration, e.g., N-type doping with a dopant concentration of about 1×10.sup.16 atoms/cm.sup.3. In some embodiments, the first III-nitride epitaxial layer is a drift layer including a uniformly doped region (layer) on the III-nitride substrate and a graded doping region (layer) on the uniformly doped region. In an embodiment, the uniformly doped region has a thickness of about 10.5 μm, and the graded doping region has a thickness of about 0.3 μm. In an embodiment, the surface of substrate is miscut from the c-plane at an angle to facilitate high-quality epitaxial growth for high-voltage operation of the drift layer.
[0125] Method 1100 further includes forming a second III-nitride epitaxial layer on the first III-nitride epitaxial layer (1106). In an embodiment, the second III-nitride epitaxial layer is epitaxially grown on the first III-nitride epitaxial layer with a thickness of about 0.7-0.9 μm and is characterized by a second dopant concentration, e.g., N-type doping. The second dopant concentration is higher than the first dopant concentration in some embodiments. In an embodiment, the second dopant concentration is about 1.3×10.sup.17 atoms/cm.sup.3. In an embodiment, the second III-nitride epitaxial layer has a more highly doped surface layer, e.g., about 1-3×10.sup.18 atoms/cm.sup.3, with a thickness of 30-100 nm.
[0126] Method 1100 further includes forming and patterning a hard mask layer on the second III-nitride epitaxial layer (1108). In some embodiments, the hard mask layer may be a dielectric material such as silicon nitride, silicon dioxide, silicon oxynitride, silicon-aluminum nitride or the like. The dielectric material may be deposited by LPCVD, PECVD, ALD or the like. In some embodiments, the hard mask layer is a composite hard mask including a metal layer on the second III-nitride epitaxial layer and a dielectric hard mask layer on the metal layer. In some embodiments, the metal layer is a refractory metal, refractory metal alloy, or refractory metal nitride (e.g., TiN). The hard mask layer may be patterned using photolithography in combination with an RIE process. In some embodiments with a composite hard mask, the dielectric hard mask layer is first patterned, and then the patterned dielectric hard mask is used as a hard mask to pattern the metal layer.
[0127] Method 1100 further includes forming a recess region in the second III-nitride epitaxial layer using the patterned hard mask by an etch process, e.g., an RIE process (1110), to form fins separated by trenches. In an embodiment, the etched recess extends into the first III-nitride epitaxial layer. In an embodiment, the etched recess extends partially (e.g., 0.1 μm) into the graded layer at the top of the first III-nitride epitaxial layer.
[0128] Method 1100 further includes applying a sacrificial coating layer to the surfaces of the fins and the patterned hard mask (1112) to create a substantially planar surface. In some embodiments, the sacrificial coating layer is a spin-on glass. In some embodiments, the sacrificial coating layer is silicon dioxide. In some embodiments, the sacrificial coating layer is deposited using PECVD. In some embodiments, the top surface of the sacrificial coating layer is 1-2 μm above the top surface of the patterned hard mask.
[0129] Method 1100 further includes etching back the sacrificial coating layer to expose the patterned hard mask and a portion of the sidewalls of the fins (1114). In some embodiments, the etch is performed using a fluorine-containing plasma.
[0130] Method 1100 further includes depositing a conformal dielectric layer on the exposed surfaces of the patterned hard mask, the fin sidewalls, and the sacrificial coating layer (1116). In some embodiments, the conformal dielectric layer is one of silicon nitride, silicon-aluminum nitride, or aluminum nitride. In some embodiments, the conformal dielectric layer is deposited by one of PECVD, LPCVD, or ALD.
[0131] Method 1100 further includes performing a directional (anisotropic) etch of the conformal dielectric layer (1118) to leave a “spacer” layer on the sidewalls of the patterned hard mask and a portion of the fin sidewalls. In some embodiments, the directional etch is performed using an RIE process.
[0132] Method 1100 further includes removal of the sacrificial coating layer (1120) to expose the remaining portions of the fin sidewalls and the trench bottom regions. In some embodiments, the sacrificial coating layer is removed using a wet etch.
[0133] Method 1100 further includes exposing the structure to an ambient containing a gaseous p-type dopant precursor to form a doped p-GaN gate layer using diffusion (1122). In some embodiments, the p-type dopant precursor gas is e.g., bis-cyclo-penta-dienyl-magnesium in an ammonia-rich ambient in a MOCVD reactor, at temperatures between 950° C. and 1150° C. and pressures between 100 mTorr and 1 atmosphere. In some embodiments, the diffused junction depth is between 50 and 100 nm. In some embodiments, the peak concentration of the p-type dopant is between 5×10.sup.18 and 3×10.sup.19 atoms/cm.sup.3.
[0134] Method 1100 further includes removing the patterned hard mask on the top surface of the second III-nitride layer (1124). Optionally, the dielectric spacer may also be removed. In some embodiments where a composite hard mask layer is used, the top dielectric layer may be removed, leaving the metal layer.
[0135] Method 1100 further includes forming a source contact structure on the top surface of the second III-nitride layer (1126). In some embodiments, the metal hard mask layer is left in place, and the source contact structure is formed on top of the metal hard mask layer. In some embodiments, the source contact structure is formed using titanium and aluminum.
[0136] Method 1100 further includes forming a forming a gate contact structure on that exposed surface portion of the diffused gate layer overlaying the top surface of the first III-nitride epitaxial layer (1128). The gate contact structure may include nickel, gold, palladium, platinum, molybdenum, and the like.
[0137] Method 1100 further includes forming a junction-terminated edge (“edge termination”) for the p-GaN layer at the lateral edges of the device active region (1130). In some cases, the p-GaN layer is connected to the gate, in others to the source. In some embodiments, this edge termination is formed using a tapered junction.
[0138] Method 1100 further includes forming a drain contact at the bottom side of the substrate by forming a metallic contact to the bottom side of substrate (1132).
[0139] It should be appreciated that the specific steps illustrated in
[0140]
[0141] In
[0142] Referring to
[0143] Referring to
[0144] Referring to
[0145] The stages illustrated in
[0146]
[0147] Method 1300 also includes forming a first III-nitride epitaxial layer, for example, a 5-12 μm thick first III-nitride epitaxial layer (e.g., an N− GaN epitaxial layer deposited on the III-nitride substrate (1304). The first III-nitride epitaxial layer is epitaxially grown on the III-nitride substrate at a temperature between 950 and 1100° C. and is characterized by a first dopant concentration, e.g., N-type doping with a dopant concentration of about 1×10.sup.16 atoms/cm.sup.3. In some embodiments, the first III-nitride epitaxial layer is a drift layer including a uniformly doped region (layer) on the III-nitride substrate and a graded doping region (layer) on the uniformly doped region. In an embodiment, the uniformly doped region has a thickness of about 10.5 μm, and the graded doping region has a thickness of about 0.3 μm. In an embodiment, the surface of substrate is miscut from the c-plane at an angle to facilitate high-quality epitaxial growth for high-voltage operation of the drift layer.
[0148] Method 1300 further includes forming a second III-nitride epitaxial layer on the first III-nitride epitaxial layer (1306). In an embodiment, the second III-nitride epitaxial layer is epitaxially grown on the first III-nitride epitaxial layer with a thickness of about 0.7-0.9 μm and is characterized by a second dopant concentration, e.g., N-type doping. The second dopant concentration is higher than the first dopant concentration in some embodiments. In an embodiment, the second dopant concentration is about 1.3×10.sup.17 atoms/cm.sup.3. In an embodiment, the second III-nitride epitaxial layer has a more highly doped surface layer, e.g., about 1-3×10.sup.18 atoms/cm.sup.3, with a thickness of 30-100 nm.
[0149] Method 1300 further includes forming and patterning a hard mask layer on the second III-nitride epitaxial layer (1308). In some embodiments, the hard mask layer may be a dielectric material such as silicon nitride, silicon dioxide, silicon oxynitride, silicon-aluminum nitride or the like. The dielectric material may be deposited by LPCVD, PECVD, ALD, or the like. In some embodiments, the hard mask layer is a composite hard mask including a metal layer on the second III-nitride epitaxial layer and a dielectric hard mask layer on the metal layer. In some embodiments, the metal layer is a refractory metal, refractory metal alloy, or refractory metal nitride (e.g., TiN). The hard mask layer may be patterned using photolithography in combination with an RIE process. In some embodiments with a composite hard mask, the dielectric hard mask layer is first patterned, and then the patterned dielectric hard mask is used as a hard mask to pattern the metal layer.
[0150] Method 1300 further includes forming a recess region in the second III-nitride epitaxial layer using the patterned hard mask by an etch process, e.g., an RIE (process (1310), to form fins separated by trenches. In an embodiment, the etched recess extends into the first III-nitride epitaxial layer. In an embodiment, the etched recess extends partially (e.g., 0.1 μm) into the graded layer at the top of the first III-nitride epitaxial layer.
[0151] Method 1300 further includes implanting p-type dopant material into the surfaces of the fins (1312). In some embodiments, the implanted dopant is Mg, Zn, Be, Ca, combinations thereof, and the like. In some embodiments, the implantation is performed at multiple tilt angles to allow implantation into all exposed surfaces of the fin sidewall. In some embodiments, the dopant material is implanted to a depth of 50-100 nm.
[0152] Method 1300 further includes depositing a protective layer to encapsulate the implanted surface (1314). In some embodiments, the protective layer is a dielectric (e.g., silicon nitride, aluminum nitride, silicon-aluminum nitride, etc.). In some embodiments, the protective layer has a thickness between 50 and 100 nm.
[0153] Method 1300 further includes performing a thermal treatment to activate the implanted p-type dopant (1316). In some embodiments, the thermal treatment may be performed in a furnace at temperatures from 1000° C. to 1200° C. In some embodiments, the thermal treatment may be performed in a rapid thermal annealer at temperatures from 1000° C. to 1450° C. In some embodiments the thermal treatment may be performed at a high ambient pressure (e.g., at 1 GPa in a N.sub.2 ambient), with or without the protective layer. In some embodiments the heating may be a result of a series of rapid pulses (e.g. microwave).
[0154] Method 1300 further includes removal of the protective layer (1318). In some embodiments, the removal is performed using a wet etch.
[0155] Method 1300 further includes forming a source contact structure on the top surface of the second III-nitride layer (1320). In some embodiments, the metal hard mask layer is left in place, and the source contact structure is formed on top of the metal hard mask layer. In some embodiments, the source contact structure is formed using titanium and aluminum.
[0156] Method 1300 further includes forming a forming a gate contact structure on that exposed surface portion of the implanted gate layer overlaying the top surface of the first III-nitride epitaxial layer (1322). The gate contact structure may include nickel, gold, palladium, platinum, molybdenum, and the like.
[0157] Method 1300 further includes forming a junction-terminated edge (“edge termination”) for the p-GaN layer at the lateral edges of the device active region (1324). In some cases, the p-GaN layer is connected to the gate, in others to the source. In some embodiments, this edge termination is formed using a tapered junction. In some embodiments, the implanted regions can be utilized to form the edge termination structure.
[0158] Method 1300 further includes forming a drain contact at the bottom side of the substrate by forming a metallic contact to the bottom side of substrate (1326).
[0159] It should be appreciated that the specific steps illustrated in
[0160]
[0161] In
[0162] The stages illustrated in
[0163]
[0164] Method 1500 also includes forming a first III-nitride epitaxial layer, for example, a 5-12 μm thick first III-nitride epitaxial layer (e.g., an N− GaN epitaxial layer deposited on the III-nitride substrate (1504). The first III-nitride epitaxial layer is epitaxially grown on the III-nitride substrate at a temperature between 950 and 1100° C. and is characterized by a first dopant concentration, e.g., N-type doping with a dopant concentration of about 1×10.sup.16 atoms/cm.sup.3. In some embodiments, the first III-nitride epitaxial layer is a drift layer including a uniformly doped region (layer) on the III-nitride substrate and a graded doping region (layer) on the uniformly doped region. In an embodiment, the uniformly doped region has a thickness of about 10.5 μm, and the graded doping region has a thickness of about 0.3 μm. In an embodiment, the surface of substrate is miscut from the c-plane at an angle to facilitate high-quality epitaxial growth for high-voltage operation of the drift layer.
[0165] Method 1500 further includes forming a second III-nitride epitaxial layer on the first III-nitride epitaxial layer (1506). In an embodiment, the second III-nitride epitaxial layer is epitaxially grown on the first III-nitride epitaxial layer with a thickness of about 0.7-0.9 μm and is characterized by a second dopant concentration, e.g., N-type doping. The second dopant concentration is higher than the first dopant concentration in some embodiments. In an embodiment, the second dopant concentration is about 1.3×10.sup.17 atoms/cm.sup.3. In an embodiment, the second III-nitride epitaxial layer has a more highly doped surface layer, e.g., about 1-3×10.sup.18 atoms/cm.sup.3, with a thickness of 30-100 nm.
[0166] Method 1500 further includes forming and patterning a hard mask layer on the second III-nitride epitaxial layer (1508). In some embodiments, the hard mask layer may be a dielectric material such as silicon nitride, silicon dioxide, silicon oxynitride, silicon-aluminum nitride or the like. The dielectric material may be deposited by LPCVD, PECVD, ALD or the like. In some embodiments, the hard mask layer is a composite hard mask including a metal layer on the second III-nitride epitaxial layer and a dielectric hard mask layer on the metal layer. In some embodiments, the metal layer is a refractory metal, refractory metal alloy, or refractory metal nitride (e.g., TiN). The hard mask layer may be patterned using photolithography in combination with an RIE process. In some embodiments with a composite hard mask, the dielectric hard mask layer is first patterned, and then the patterned dielectric hard mask is used as a hard mask to pattern the metal layer.
[0167] Method 1500 further includes forming a recess region in the second III-nitride epitaxial layer using the patterned hard mask by an etch process, e.g., an RIE process (1510), to form fins separated by trenches. In an embodiment, the etched recess extends into the first III-nitride epitaxial layer. In an embodiment, the etched recess extends partially (e.g., 0.1 μm) into the graded layer at the top of the first III-nitride epitaxial layer.
[0168] Method 1500 further includes applying a sacrificial coating layer to the surfaces of the fins and the patterned hard mask (1512) to create a substantially planar surface. In some embodiments, the sacrificial coating layer is a spin-on glass. In some embodiments, the sacrificial coating layer is silicon dioxide. In some embodiments, the sacrificial coating layer is deposited using PECVD. In some embodiments, the top surface of the sacrificial coating layer is 1-2 μm above the top surface of the patterned hard mask. In some embodiments, the sacrificial coating layer is omitted, and step 1514 is not performed.
[0169] Method 1500 further includes etching back the sacrificial coating layer to expose the patterned hard mask and a portion of the sidewalls of the fins (1514). In some embodiments, the etch is performed using a fluorine-containing plasma.
[0170] Method 1500 further includes depositing a conformal dielectric layer on the exposed surfaces of the patterned hard mask, of fin sidewalls, and the sacrificial coating layer (1516). In some embodiments, the conformal dielectric layer is one of silicon nitride, silicon-aluminum nitride, or aluminum nitride. In some embodiments, the conformal dielectric layer is deposited by one of PECVD, LPCVD, or ALD.
[0171] Method 1500 further includes performing a directional (anisotropic) etch of the conformal dielectric layer (1518) to leave a “spacer” layer on the sidewalls of the patterned hard mask and a portion of the fin sidewalls. In some embodiments, the directional etch is performed using an RIE process. In embodiments where the sacrificial coating layer is omitted, the spacer is present on the entire fin sidewall.
[0172] Method 1500 further includes removal of the sacrificial coating layer (1520) to expose the remaining portions of the fin sidewalls and the trench bottom regions. In some embodiments, the sacrificial coating layer is removed using a wet etch.
[0173] Method 1500 further includes implanting p-type dopant material into the surfaces of the fins (1522). In some embodiments, the implanted dopant is Mg, Zn, Be, Ca, combinations thereof, and the like. In some embodiments, the implantation is performed at multiple tilt angles to allow implantation into exposed surfaces of the fin sidewall. In some embodiments, the dopant material is implanted to a depth of 50-100 nm.
[0174] Method 1500 further includes depositing a protective layer to encapsulate the implanted surface, followed by a thermal treatment to activate the implanted p-type dopant material (1524). In some embodiments, the protective layer is a dielectric (e.g., silicon nitride, aluminum nitride, silicon-aluminum nitride, etc.). In some embodiments, the protective layer has a thickness between 50 and 100 nm. In some embodiments, the thermal treatment may be performed in a furnace at temperatures from 1000° C. to 1200° C. In some embodiments, the thermal treatment may be performed in a rapid thermal annealer at temperatures from 1000° C. to 1450° C. In some embodiments the thermal process may be performed at a high ambient pressure (e.g., at 1 GPa in a N.sub.2 ambient), with or without the protective layer. In some embodiments the heating may be a result of a series of rapid pulses (e.g. microwave).
[0175] Method 1500 further includes removal of the protective layer (1526). In some embodiments, the removal is performed using a wet etch.
[0176] Method 1500 further includes removing the patterned hard mask on the top surface of the second III-nitride layer (1528). Optionally, the spacer may also be removed. In some embodiments where a composite hard mask layer is used, the top dielectric layer may be removed, leaving the metal layer.
[0177] Method 1500 further includes forming a source contact structure on the top surface of the second III-nitride layer (1530). In some embodiments, the metal hard mask layer is left in place, and the source contact structure is formed on top of the metal hard mask layer. In some embodiments, the source contact structure is formed using titanium and aluminum.
[0178] Method 1500 further includes forming a forming a gate contact structure on that exposed surface portion of the implanted gate layer overlaying the top surface of the first III-nitride epitaxial layer (1532). The gate contact structure may include nickel, gold, palladium, platinum, molybdenum, and the like.
[0179] Method 1500 further includes forming a junction-terminated edge (“edge termination”) for the p-GaN layer at the lateral edges of the device active region (1534). In some cases, the p-GaN layer is connected to the gate, in others to the source. In some embodiments, this edge termination is formed using a tapered junction.
[0180] Method 1500 further includes forming a drain contact at the bottom side of the substrate by forming a metallic contact to the bottom side of substrate (1536).
[0181] It should be appreciated that the specific steps illustrated in
[0182]
[0183] Referring to
[0184] The stages illustrated in
[0185]
[0186] Method 1700 also includes forming a first III-nitride epitaxial layer, for example, a 5-12 μm thick first III-nitride epitaxial layer (e.g., an N− GaN epitaxial layer deposited on the III-nitride substrate (1704). The first III-nitride epitaxial layer is epitaxially grown on the III-nitride substrate at a temperature between 950 and 1100° C. and is characterized by a first dopant concentration, e.g., N-type doping with a dopant concentration of about 1×10.sup.16 atoms/cm.sup.3. In some embodiments, the first III-nitride epitaxial layer is a drift layer including a uniformly doped region (layer) on the III-nitride substrate and a graded doping region (layer) on the uniformly doped region. In an embodiment, the uniformly doped region has a thickness of about 10.5 μm, and the graded doping region has a thickness of about 0.3 μm. In an embodiment, the surface of substrate is miscut from the c-plane at an angle to facilitate high-quality epitaxial growth for high-voltage operation of the drift layer.
[0187] Method 1700 further includes forming a second III-nitride epitaxial layer on the first III-nitride epitaxial layer (1706). In an embodiment, the second III-nitride epitaxial layer is epitaxially grown on the first III-nitride epitaxial layer with a thickness of about 0.7-0.9 μm and is characterized by a second dopant concentration, e.g., N-type doping. The second dopant concentration is higher than the first dopant concentration in some embodiments. In an embodiment, the second dopant concentration is about 1.3×10.sup.17 atoms/cm.sup.3. In an embodiment, the second III-nitride epitaxial layer has a more highly doped surface layer, e.g., about 1-3×10.sup.18 atoms/cm.sup.3, with a thickness of 30-100 nm.
[0188] Method 1700 further includes forming and patterning a hard mask layer on the second III-nitride epitaxial layer (1708). In some embodiments, the hard mask layer may be a dielectric material such as silicon nitride, silicon dioxide, silicon oxynitride, silicon-aluminum nitride or the like. The dielectric material may be deposited by LPCVD, PECVD, ALD or the like. In some embodiments, the hard mask layer is a composite hard mask including a metal layer on the second III-nitride epitaxial layer and a dielectric hard mask layer on the metal layer. In some embodiments, the metal layer is a refractory metal, refractory metal alloy, or refractory metal nitride (e.g., TiN). The hard mask layer may be patterned using photolithography in combination with an RIE process. In some embodiments with a composite hard mask, the dielectric hard mask layer is first patterned, and then the patterned dielectric hard mask is used as a hard mask to pattern the metal layer.
[0189] Method 1700 further includes forming a recess region in the second III-nitride epitaxial layer using the patterned hard mask by an etch process, e.g., an RIE process (1710). In an embodiment, the etched recess extends into the first III-nitride epitaxial layer. In an embodiment, the etched recess extends partially (e.g., 0.1 μm) into the graded layer at the top of the first III-nitride epitaxial layer.
[0190] Method 1700 further includes selective area regrowth of a conformal, p-doped III-nitride epitaxial layer on the exposed surfaces of the first and second semiconductor layers in the fins (1712). In an embodiment, the regrowth is performed using MOCVD. In an embodiment, the p-type dopant is Mg. In an embodiment, the regrowth is performed in an NH.sub.3 ambient. In an embodiment, the regrowth is performed at pressures between 50 mbar and 600 mbar. In an embodiment, the regrowth is performed at temperatures between 850° C. and 950° C. In some embodiments, the regrown epitaxial layer has a thickness on the sidewalls of the trench of between 50-150 nm. In some embodiments, the p-type dopant concentration is between 5×10.sup.18 and 3×10.sup.19 atoms/cm.sup.3.
[0191] Method 1700 further includes a thermal treatment to activate the p-type dopant in the regrown III-nitride epitaxial layer (1714). In some embodiments, the thermal treatment may be performed in a furnace at temperatures from 600° C. to 800° C. In some embodiments, the thermal treatment may be performed in a rapid thermal annealer at temperatures from 700° C. to 850° C.
[0192] Method 700 further includes removing the patterned hard mask on the top surface of the second III-nitride layer (1716). In some embodiments where a composite hard mask layer is used, the top dielectric layer may be removed, leaving the metal layer.
[0193] Method 1700 further includes forming a source contact structure on the top surface of the second III-nitride layer (1718). In some embodiments, the metal hard mask layer is left in place, and the source contact structure is formed on top of the metal hard mask layer. In some embodiments, the source contact structure is formed using titanium and aluminum.
[0194] Method 1700 further includes forming a forming a gate contact structure on the conformal III-nitride layer (1720). The gate contact structure may include nickel, gold, palladium, platinum, molybdenum, and the like.
[0195] Method 1700 further includes forming a junction-terminated edge (“edge termination”) for the p-GaN layer at the lateral edges of the device active region (1722). In some cases, the p-GaN layer is connected to the gate, in others to the source. In some embodiments, this edge termination is formed using a tapered junction.
[0196] Method 1700 further includes forming a drain contact at the bottom side of the substrate by forming a metallic contact to the bottom side of substrate (1724).
[0197] It should be appreciated that the specific steps illustrated in
[0198]
[0199] Referring to
[0200] A thermal treatment can be performed to activate the p-type dopant in the regrown epitaxial layer 1832. In some embodiments, the thermal treatment may be performed in a furnace at temperatures from 600° C. to 800° C. In some embodiments, the thermal treatment may be performed in a rapid thermal annealer at temperatures from 700° C. to 850° C.
[0201] The stages illustrated in
[0202]
[0203] Method 1900 also includes forming a first III-nitride epitaxial layer, for example, a 5-12 μm thick first III-nitride epitaxial layer (e.g., an N− GaN epitaxial layer deposited on the III-nitride substrate (1904). The first III-nitride epitaxial layer is epitaxially grown on the III-nitride substrate at a temperature between 950 and 1100° C. and is characterized by a first dopant concentration, e.g., N-type doping with a dopant concentration of about 1×10.sup.16 atoms/cm.sup.3. In some embodiments, the first III-nitride epitaxial layer is a drift layer including a uniformly doped region (layer) on the III-nitride substrate and a graded doping region (layer) on the uniformly doped region. In an embodiment, the uniformly doped region has a thickness of about 10.5 μm, and the graded doping region has a thickness of about 0.3 μm. In an embodiment, the surface of substrate is miscut from the c-plane at an angle to facilitate high-quality epitaxial growth for high-voltage operation of the drift layer.
[0204] Method 1900 further includes forming a second III-nitride epitaxial layer on the first III-nitride epitaxial layer (1906). In an embodiment, the second III-nitride epitaxial layer is epitaxially grown on the first III-nitride epitaxial layer with a thickness of about 0.7-0.9 μm and is characterized by a second dopant concentration, e.g., N-type doping. The second dopant concentration is higher than the first dopant concentration in some embodiments. In an embodiment, the second dopant concentration is about 1.3×10.sup.17 atoms/cm.sup.3. In an embodiment, the second III-nitride epitaxial layer has a more highly doped surface layer, e.g., about 1-3×10.sup.18 atoms/cm.sup.3, with a thickness of 30-100 nm.
[0205] Method 1900 further includes forming and patterning a hard mask layer on the second III-nitride epitaxial layer (1908). In some embodiments, the hard mask layer may be a dielectric material such as silicon nitride, silicon dioxide, silicon oxynitride, silicon-aluminum nitride or the like. The dielectric material may be deposited by LPCVD, PECVD, ALD or the like. In some embodiments, the hard mask layer is a composite hard mask including a metal layer on the second III-nitride epitaxial layer and a dielectric hard mask layer on the metal layer. In some embodiments, the metal layer is a refractory metal, refractory metal alloy, or refractory metal nitride (e.g., TiN). The hard mask layer may be patterned using photolithography in combination with an RIE process. In some embodiments with a composite hard mask, the dielectric hard mask layer is first patterned, and then the patterned dielectric hard mask is used as a hard mask to pattern the metal layer.
[0206] Method 1900 further includes forming a recess region in the second III-nitride epitaxial layer using the patterned hard mask by an etch process, e.g., an RIE process (1910). In an embodiment, the etched recess extends into the first III-nitride epitaxial layer. In an embodiment, the etched recess extends partially (e.g., 0.1 μm) into the graded layer at the top of the first III-nitride epitaxial layer.
[0207] Method 1900 further includes applying a sacrificial coating layer to the surfaces of the fins and the patterned hard mask (1912) to create a substantially planar surface. In some embodiments, the sacrificial coating layer is a spin-on glass. In some embodiments, the sacrificial coating layer is silicon dioxide. In some embodiments, the sacrificial coating layer is deposited using PECVD. In some embodiments, the top surface of the sacrificial coating layer is 1-2 μm above the top surface of the patterned hard mask.
[0208] Method 1900 further includes etching back the sacrificial coating layer to expose the patterned hard mask and a portion of the sidewalls of the fins (1914). In some embodiments, the etch is performed using a fluorine-containing plasma.
[0209] Method 1900 further includes depositing a conformal dielectric layer on the exposed surfaces of the patterned hard mask, the fin sidewalls, and the sacrificial coating layer (1916). In some embodiments, the conformal dielectric layer is one of silicon nitride, silicon-aluminum nitride, or aluminum nitride. In some embodiments, the conformal dielectric layer is deposited by one of PECVD, LPCVD, or ALD.
[0210] Method 1900 further includes performing a directional (anisotropic) etch of the conformal dielectric layer (1918) to leave a “spacer” layer on the sidewalls of the patterned hard mask and a portion of the fin sidewalls. In some embodiments, the directional etch is performed using an RIE process.
[0211] Method 1900 further includes removal of the sacrificial coating layer (1920) to expose the remaining portions of the fin sidewalls and the trench bottom regions. In some embodiments, the sacrificial coating layer is removed using a wet etch.
[0212] Method 1900 further includes selective area regrowth of a conformal, p-doped III-nitride epitaxial layer on the exposed surfaces of the first and second semiconductor layers in the fins (1922). The p-doped III-nitride epitaxial layer is a dopant of the opposite type to the first and second III-nitride layers. In some embodiments, the regrowth is performed using MOCVD. In some embodiments, the p-type dopant is Mg. In some embodiments, the regrowth is performed in an NH.sub.3 ambient. In some embodiments, the regrowth is performed at pressures between 50 mbar and 600 mbar. In some embodiments, the regrowth is performed at temperatures between 850° C. and 950° C. In some embodiments, the regrown epitaxial layer has a thickness on the sidewalls of the trench of between 50-150 nm. In some embodiments, the p-type dopant concentration is between 5×10.sup.18 and 3×10.sup.19 atoms/cm.sup.3.
[0213] Method 1900 further includes a thermal treatment to activate the p-type dopant in the regrown III-nitride epitaxial layer (1924). In some embodiments, the thermal treatment may be performed in a furnace at temperatures from 600° C. to 800° C. In some embodiments, the thermal treatment may be performed in a rapid thermal annealer at temperatures from 700° C. to 850° C.
[0214] Method 1900 further includes removing the patterned hard mask on the top surface of the second III-nitride layer (1926). Optionally, the spacer may also be removed. In some embodiments where a composite hard mask layer is used, the top dielectric layer may be removed, leaving the metal layer.
[0215] Method 1900 further includes forming a source contact structure on the top surface of the second III-nitride layer (1928). In some embodiments, the metal hard mask layer is left in place, and the source contact structure is formed on top of the metal hard mask layer. In some embodiments, the source contact structure is formed using titanium and aluminum.
[0216] Method 1900 further includes forming a forming a gate contact structure on that exposed surface portion of the regrown gate layer overlaying the top surface of the first III-nitride epitaxial layer (1930). The gate contact structure may include nickel, gold, palladium, platinum, molybdenum, and the like.
[0217] Method 1900 further includes forming a junction-terminated edge (“edge termination”) for the p-GaN layer at the lateral edges of the device active region (1932). In some cases, the p-GaN layer is connected to the gate, in others to the source. In some embodiments, this edge termination is formed using a tapered junction.
[0218] Method 1900 further includes forming a drain contact at the bottom side of the substrate by forming a metallic contact to the bottom side of substrate (1934).
[0219] It should be appreciated that the specific steps illustrated in
[0220] It should be understood that the drawings are not drawn to scale, and similar reference numbers are used for representing similar elements. As used herein, the terms “example embodiment,” “exemplary embodiment,” and “present embodiment” do not necessarily refer to a single embodiment, although it may, and various example embodiments may be readily combined and interchanged, without departing from the scope or spirit of the present invention. Furthermore, the terminology as used herein is for the purpose of describing example embodiments only and is not intended to be a limitation of the invention. In this respect, as used herein, the term “in” may include “in” and “on”, and the terms “a”, “an” and “the” may include singular and plural references. Furthermore, as used herein, the term “by” may also mean “from”, depending on the context. Furthermore, as used herein, the term “if” may also mean “when” or “upon”, depending on the context. Furthermore, as used herein, the words “and/or” may refer to and encompass any possible combinations of one or more of the associated listed items.
[0221] It will be understood that, although the terms “first,” “second,” “third,” etc. may be used herein to describe various elements, components, regions, layers, and/or sections, these elements, components, regions, layers, and/or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer, or section from another region, layer or section. Thus, a first element, component, region, layer, or section discussed below could be termed a second element, component, region, layer, or section without departing from the teachings of the present invention.
[0222] The term “horizontal” as used in this application is defined as a plane parallel to the conventional plane or surface of a wafer or substrate, regardless of the orientation of the wafer or substrate. The term “vertical” refers to a direction perpendicular to the horizontal as defined above. Prepositions, such as “on”, “side” (as in “sidewall”), “below”, “above”, “higher”, “lower”, “over”, and “under” are defined with respect to the conventional plane or surface being on the top surface of the wafer or substrate, regardless of the orientation of the wafer or substrate. It will be understood that these terms are intended to encompass different orientations of the device in addition to the orientation depicted in the figures.
[0223] Although embodiments of the present disclosure have been described in detail, it should be understood that various modifications, substitutions and variations can be made hereto without departing from the scope of the invention as defined by the appended claims.