ELECTROMAGNETIC WAVE GENERATOR BASED ON NON-LINEAR COMPOSITE MATERIALS
20220298324 · 2022-09-22
Assignee
Inventors
Cpc classification
C08K2201/014
CHEMISTRY; METALLURGY
International classification
Abstract
A transmission line is disclosed which includes a first conductor, a second conductor, a composite disposed between the first conductor and the second conductor, the composite includes non-linear inclusions comprising one or more of non-linear dielectric and non-linear magnetic inclusions mixed in a matrix material, wherein the non-linear dielectric inclusions are selected from the group consisting of barium strontium titanate (BST), barium titanate, strontium titanate, barium zirconate titanate, lead zirconate titanate, lead titanate, lithium niobate, potassium niobate, lead scandium tantalate, strontium barium niobate, and combinations thereof, and the non-linear magnetic inclusions are selected from the group consisting of nickel zinc ferrite (NZF), manganese zinc ferrite, cobalt ferrite, manganese ferrite, zinc ferrite, nickel ferrite, and combinations thereof, wherein the non-linear inclusions by volume are about 25% NZF, about 10% BST/15% NZF, and about 15% BST/10% NZF, and wherein the first conductor, the second conductor, and the composite form a capacitor.
Claims
1. A composite, comprising: non-linear inclusions comprising one or more of non-linear dielectric and non-linear magnetic inclusions mixed in a matrix material, wherein the non-linear dielectric inclusions are selected from the group consisting of barium strontium titanate (BST), barium titanate, strontium titanate, barium zirconate titanate, lead zirconate titanate, lead titanate, lithium niobate, potassium niobate, lead scandium tantalate, strontium barium niobate, and combinations thereof, and the non-linear magnetic inclusions are selected from the group consisting of nickel zinc ferrite (NZF), manganese zinc ferrite, cobalt ferrite, manganese ferrite, zinc ferrite, nickel zinc ferrite, and combinations thereof, wherein the non-linear inclusions by volume are about 25% NZF, about 10% BST/15% NZF, and about 15% BST/10% NZF.
2. The composite of claim 1, wherein the permittivity of the composite is between about 2.1 to about 1000.
3. The composite of claim 1, wherein the permeability of the composite is between about 1.5 to about 15.
4. The composite of claim 1, wherein the matrix material is selected from the group consisting of silicon, ceramic, polydimethylsiloxane, and a combination thereof.
5. A transmission line, comprising: a first conductor; a second conductor; and a composite disposed between the first conductor and the second conductor; the composite, comprising: non-linear inclusions comprising one or more of non-linear dielectric and non-linear magnetic inclusions mixed in a matrix material, wherein the non-linear dielectric inclusions are selected from the group consisting of barium strontium titanate (BST), barium titanate, strontium titanate, barium zirconate titanate, lead zirconate titanate, lead titanate, lithium niobate, potassium niobate, lead scandium tantalate, strontium barium niobate, and combinations thereof, and the non-linear magnetic inclusions are selected from the group consisting of nickel zinc ferrite (NZF), manganese zinc ferrite, cobalt ferrite, manganese ferrite, zinc ferrite, nickel ferrite, and combinations thereof, wherein the non-linear inclusions by volume are about 25% NZF, about 10% BST/15% NZF, and about 15% BST/10% NZF; and wherein the first conductor, the second conductor, and the composite form a capacitor.
6. The transmission line of claim 5, wherein the composite has a permittivity of between about 2.1 to about 1000.
7. The transmission line of claim 5, wherein the composite has a permeability of between about 1.5 to about 15.
8. The transmission line of claim 5, wherein the matrix material is selected from the group consisting of silicon, ceramic, polydimethylsiloxane, and a combination thereof.
9. The transmission line of claim 5, wherein the first and the second conductors are disposed in a coaxial configuration.
10. The transmission line of claim 5, wherein the first and the second conductors are disposed in a planar configuration.
11. A system for generating electromagnetic waves, comprising: a voltage source; and a transmission line coupled to the voltage source; the transmission line, comprising: a first conductor; a second conductor; and a composite disposed between the first conductor and the second conductor; the composite, comprising: non-linear inclusions comprising one or more of non-linear dielectric and non-linear magnetic inclusions mixed in a matrix material, wherein the non-linear dielectric inclusions are selected from the group consisting of barium strontium titanate (BST), barium titanate, strontium titanate, barium zirconate titanate, lead zirconate titanate, lead titanate, lithium niobate, potassium niobate, lead scandium tantalate, strontium barium niobate, and combinations thereof, and the non-linear magnetic inclusions are selected from the group consisting of nickel zinc ferrite (NZF), manganese zinc ferrite, cobalt ferrite, manganese ferrite, zinc ferrite, nickel ferrite, and combinations thereof, wherein the non-linear inclusions by volume are about 25% NZF, about 10% BST/15% NZF, and about 15% BST/10% NZF, wherein the voltage source has a ground that is coupled to second conductor of the transmission line; wherein the first conductor, the second conductor, and the composite form a capacitor; wherein the capacitor in the transmission line is charged by the voltage source and when quickly discharged, generates an electromagnetic wave;
12. The system of claim 11, wherein the composite has a permittivity between about 2.1 to about 1000.
13. The system of claim 11, wherein the composite has a permeability between about 1.5 to about 15.
14. The system of claim 11, wherein the matrix material is selected from the group consisting of silicon, ceramic, polydimethylsiloxane, and a combination thereof).
15. The system of claim 11, wherein the first and the second conductors are disposed in a coaxial configuration.
16. The system of claim 11, wherein the first and the second conductors are disposed in a planar configuration.
17. The system of claim 11, the voltage source generates a pulse having a low side and a high side such that the high side of the pulse accelerates within the transmission line and meets the low side of the pulse, generating the electromagnetic waves.
18. The system of claim 11, the voltage source is a DC source, and the system further comprises a current limiting resistor before the transmission line and a switch after the transmission line that is configured to short the first conductor to the second conductor via an electrical load to thereby cause the transmission line, generating the electromagnetic waves.
19. The system of claim 18, wherein the electrical load is an antenna or an impedance matching resistor.
20. The system of claim 11, wherein the electromagnetic waves constitute a high-power microwave burst.
Description
BRIEF DESCRIPTION OF DRAWINGS
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DETAILED DESCRIPTION
[0030] For the purposes of promoting an understanding of the principles of the present disclosure, reference will now be made to the embodiments illustrated in the drawings, and specific language will be used to describe the same. It will nevertheless be understood that no limitation of the scope of this disclosure is thereby intended.
[0031] In the present disclosure, the term “about” can allow for a degree of variability in a value or range, for example, within 10%, within 5%, or within 1% of a stated value or of a stated limit of a range.
[0032] In the present disclosure, the term “substantially” can allow for a degree of variability in a value or range, for example, within 90%, within 95%, or within 99% of a stated value or of a stated limit of a range.
[0033] A novel approach is presented herein to generate electromagnetic waves, e.g. high-power microwaves, from a non-linear transmission line (NLTL). Towards this end, the present disclosure describes a system and method for generating high-power microwaves (HPM) with fewer auxiliary systems than conventional systems of the prior art. A compact HPM system is thus disclosed that utilizes a composite based hybrid NLTL as a pulse forming line (PFL) and HPM source as a single device. The NLTL includes a composite material as a dielectric material disposed in a coaxial configuration (i.e., cross section represents a center conductor surrounded by the composite material as a dielectric and the composite is surrounded by a shield conductor) or planar (i.e., two laterally separated conductors separated by the composite material as the dielectric). The present disclosure provides a variety of different combinations of materials that constitute the composite material, including nickel zinc ferrite (NZF) and barium strontium titanate (BST) inclusions loaded in a polydimethylsiloxane (PDMS) host material to provide magnetic field dependent permeability and electric field dependent permittivity, respectively. Non-limiting examples include: about 25% NZF, about 10% BST/15% NZF, and about 15% BST/10% NZF. By constructing the NLTL in a coaxial geometry, this device uses the capacitance, inductance, and length of the NLTL to generate a fast rise-time high voltage pulse with microwave oscillations both during and after the pulse upon exceeding a threshold charging voltage. The output frequency of the NLTLs with said composite material ranged from 950 MHz to 2.2 GHz during the pulse for 25% NZF, 10% BST/15% NZF, and 15% BST/10% NZF composites and was 1 GHz after the pulse for the 10% BST/15% NZF and 15% BST/10% NZF volume loadings. The oscillations generated after the pulse were much higher in amplitude and achieved 160 kW at a 15 kV charging voltage for the 15% BST/10% NZF composite-based NLTL.
[0034] According to one embodiment, composites with BST or NZF spherical inclusions mixed in a silicone matrix were manufactured at volume fractions ranging from 5% to 25%. The dielectric and magnetic parameters were measured from 1-4 GHz using a coaxial airline. The relative permittivity increased from 2.74±0.01 for the polydimethylsiloxane (PDMS) host material to 7.45±0.33 after combining PDMS with a 25% volume fraction of BST inclusions. The relative permittivities of BST and NZF composites were relatively constant across all measured frequencies. The relative permeability of the composites increased from 1.001±0.001 for PDMS to 1.43±0.04 for a 25% NZF composite at 1 GHz. The relative permeability of the 25% NZF composite decreased from 1.43±0.05 at 1 GHz to 1.17±0.01 at 4 GHz. The NZF samples also exhibited low dielectric and magnetic loss tangents from 0.005±0.01 to 0.091±0.015 and 0.037±0.001 to 0.20±0.038, respectively, for all volume fractions, although the dielectric loss tangent did increase with volume fraction. For BST composites, all volume fraction changes of at least 5% yielded statistically significant changes in permittivity; no changes in BST volume fraction yielded statistically significant changes in permeability. For NZF composites, the change in permittivity was statistically significant when the volume fraction varied by more than 5% and the change in permeability was statistically significant for variations in volume fraction greater than 10%. The DC electrical breakdown strength of NZF composites decreased exponentially with increasing volume fraction of NZF, while BST composites exhibited no statistically significant variation with volume fraction. It should be noted that adding as little as 10% BST to the NZF composite increased the electrical breakdown strength greater than 800%, as shown in Table 1.
TABLE-US-00001 TABLE 1 DC dielectric breakdown threshold in kV/cm for composites with various volume loadings of BST and NZF in a PDMS matrix. NZF Volume Fraction (%) * 0 5 10 15 BST Volume 0 710.42 ± 279.07 kV/cm 395.68 ± 111.041 133.51 ± 14.58 49.90 ± 8.64 Fraction (%) 5 838.86 ± 73.72 567.59 ± 247.00 392.24 ± 155.37 N/A 10 585.15 ± 229.28 597.53 ± 68.15 428.50 ± 13.58 401.20 ± 150.73 15 644.29 ± 111.25 N/A 423.75 ± 103.53 N/A * Values are reported as the average of four measurements with error determined by standard deviation. Samples labeled N/A were not tested.
[0035] NLTLs are traditionally comprised of ferromagnetic or ferroelectric materials. Traditional gyromagnetic NLTLs utilizing ferromagnetic materials, whose permeability varies with magnetic field, rely on the precession of the magnetic moments, described by the Landau-Lifshitz-Gilbert equation, around an effective magnetic field to produce electromagnetic waves. Ferroelectric materials, whose permittivity varies with electric field, have a permanent polarization vector due to an offset titanium atom in the crystalline lattice. When the material is near the Curie temperature, the offset atom can move to alternate stable positions, thus rotating the polarization vector. When the temperature exceeds the Curie temperature, the material is in a paraelectric state, meaning that the asymmetry of the lattice disappears and the titanium atom is centered in the cubic lattice. The hysteretic behavior of the ferroelectric state is not present in the paraelectric state, although the material exhibits significant non-linearity with the permittivity decreasing with increasing electric field. Adding strontium atoms to barium titanate (BT) to form barium strontium titanate (BST) decreases the Curie temperature from 123° C. to 25° C., permitting room temperature operation. Common ferroelectric materials include BT, strontium titanate (ST), and BST.
[0036] To demonstrate the concept of a low-footprint electromagnetic wave generating NLTL, a coaxial NLTL was reduced to practice using a 1 in copper tube with an internal diameter of 0.75 in as the outer conductor and a 0.5 in copper rod as the center conductor resulting in a 10Ω impedance NLTL. The composites were made by weighing the base (Part A PDMS SYLGARD 184) and adding the required amounts of NZF (FP350 PPT TECHNOLOGIES) and BST (HBS-8000 TPL INC.) to achieve the proper volume loading. The mixtures were then stirred by hand for 5 min to incorporate the powders into the PDMS base. We next placed the mixtures in a planetary centrifuge (THINKY AR100) for 5 min at 400 rpm to thoroughly mix the composites. Composites containing BST were then placed in an ultrasonic bath for 4 h to break up any conglomerations of powder. We added a curing agent at a ratio of 1:10 mass of the PDMS base, and mixed by hand for 5 min. The mixtures were then placed in a vacuum chamber at <20 kPa for 30 min to remove any air bubbles that may have been introduced. The samples were then poured slowly into the outer conductor at an angle to mitigate any addition of air into the mixture. Next, we placed the outer conductor with the composite into the vacuum chamber for 5 min at <20 kPa to remove any air that had been introduced. The center conductor was then slowly inserted into the line and was centered by an aluminum block. Again, the mixture with the center conductor inserted was placed in the vacuum chamber for 5 min at <20 kPa to remove any gas that may have been introduced. Finally, we placed another aluminum block on top of the line to ensure the center conductor was centered and placed the line in an oven (THERMO SCIENTIFIC HERATHERM OGS180) at 100° C. for 2 h to cure.
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[0038] Alternatively, instead of using a switch to generate the shockwave, a pulse generator may be used in place of the DC voltage source 202. In this embodiment, the current limiting resistor 204 is removed and the pulse generator is directly coupled to the NLTL 206. By adjusting the current which dictates the magnetic field within the NLTL 206 and the voltage of the pulse generator which dictates the electric field, the permittivity of dielectric (i.e., composite material between the first and second conductors of the NLTL 206) is varied. In so doing, the leading edge of the pulse within the NLTL 206 accelerates until it meets the lagging edge which again causes the desired shockwave.
[0039] The NLTLs of the present disclosure were modeled using LT SPICE to estimate the frequency produced by the NLTL and the location of the generated oscillations relative to the pulse. The current dependent inductance was modeled by defining the flux through the inductor. The magnetic field dependence of the permeability of the NZF composites is given by
μ(I)=(μ.sub.i−μ.sub.s)[1−tanh.sup.2(H/H.sub.s)]+μ.sub.s, (1)
where μ.sub.i is the initial permeability,
μ.sub.s is the saturation permeability (taken to be unity here),
H is the applied magnetic field, and
H.sub.s is the magnetic field at which the ferrite saturates, set to 2200 G. We used the curve fitting tool in MATLAB to fit previous experimental measurements of composite permeability to equation (1) with
[0040] The voltage dependent capacitance was calculated based on the voltage dependent permittivity, given by
ϵ(V)=(ϵ.sub.i−ϵ.sub.SAT)[1−tanh.sup.2((V−V.sub.0)/V.sub.SAT)]+ϵ.sub.SAT, (2)
where ϵ.sub.i is the initial permittivity,
ϵ.sub.SAT is the saturated permittivity, which is taken to be the previously measured permittivity of the composites with the given volume fraction of NZF,
V.sub.SAT is the voltage at which saturation begins, and V is the voltage. The capacitance and inductance values for each volume fraction are given in Table 2.
TABLE-US-00002 TABLE 2 Initial and saturated capacitance and inductance values per inch for the constructed composite NLTLs C.sub.0 C.sub.SAT L.sub.0 L.sub.SAT Volume Fraction (pF/in) (pF/in) (nH/in) (nH/in) 25% NZF 20.9 20.9 2.99 2.06 10% BST/15% NZF 23.9 14.4 2.46 2.06 15% BST/10% NZF 25.2 13.3 2.30 2.06
[0041] Referring to
[0042] Simulation results are shown in
[0043] Referring to
[0044]
[0045] Referring to
[0046] The 25% NZF composite-based NLTL was tested at different voltages to determine the output frequency of oscillations.
[0047] The generated oscillations were centered around 950 MHz and occur at the peak of the output waveform, in agreement with the simulations. Referring to
[0048] These measurements were repeated for a 10% BST/15% NZF composite-based NLTL. Referring to
[0049] Referring to
[0050] Referring to
[0051] Referring to
[0052] Referring to
[0053] Those having ordinary skill in the art will recognize that numerous modifications can be made to the specific implementations described above. The implementations should not be limited to the particular limitations described. Other implementations may be possible.