Semiconductor Device with Oxide-Nitride Stack
20220293531 · 2022-09-15
Assignee
Inventors
- Kiraneswar Muthuseenu (Tempe, AZ, US)
- Samuel Anderson (Tempe, AZ, US)
- Takeshi Ishiguro (Fukushima, JP)
Cpc classification
H01L23/552
ELECTRICITY
H01L29/0653
ELECTRICITY
H01L21/823462
ELECTRICITY
H01L21/26586
ELECTRICITY
H01L21/823481
ELECTRICITY
H01L29/0634
ELECTRICITY
H01L21/2007
ELECTRICITY
International classification
H01L23/552
ELECTRICITY
H01L21/762
ELECTRICITY
H01L21/8234
ELECTRICITY
H01L29/06
ELECTRICITY
Abstract
A semiconductor device includes a semiconductor layer with opposing first and second main surfaces and a first column extending from the first main surface and having a first concentration of a dopant of the first conductivity type. A trench with a sidewall and bottom extends at least partially through the semiconductor layer from the first main surface. A second column between the trench sidewall and the first column has a second concentration of a dopant of a second conductivity type and is formed in the semiconductor layer and extends from the first main surface. A trench oxide layer is in contact with at least the trench sidewall and the trench bottom. A trench nitride layer covers the trench oxide layer at least on the trench sidewall. A dielectric seal material seals the trench proximate the first main surface of the semiconductor layer such that the trench is air-tight.
Claims
1. A method of making a semiconductor device, comprising: providing a semiconductor layer; forming a first trench at least partially through the semiconductor layer; forming a first oxide layer over a surface of the semiconductor layer and over a sidewall of the first trench; and forming a first nitride layer over the first oxide layer.
2. The method of claim 1, further comprising: forming a second trench at least partially through the semiconductor layer; forming a first column of semiconductor material in the semiconductor layer between the first trench and second trench; and forming a second column of semiconductor material in the semiconductor layer between the first trench and second trench.
3. The method of claim 1, further comprising: removing a portion of the first oxide layer and first nitride layer to expose the surface of the semiconductor layer; and forming a source/drain region proximate to the surface of the semiconductor layer.
4. The method of claim 3, further comprising: forming a second oxide layer over the surface of the semiconductor layer; forming a second nitride layer over a portion of the second oxide layer; and forming a gate electrode over a portion of the second nitride layer.
5. The method of claim 1, further comprising forming a source/drain region proximate to the surface of the semiconductor layer prior to forming the first oxide layer and first nitride layer.
6. The method of claim 1, further comprising: forming a body contact region proximate to the surface of the semiconductor layer and adjacent to the sidewall of the first trench; and forming a body region proximate to the surface of the semiconductor layer and adjacent to the sidewall of the first trench and surrounding the source/drain region and the body contact region.
7. A method of making a semiconductor device, comprising: providing a semiconductor layer; forming a first trench into the semiconductor layer; forming an oxide layer over a surface of the semiconductor layer and over a sidewall of the first trench; and forming a nitride layer over the oxide layer.
8. The method of claim 7, further comprising: forming a second trench into the semiconductor layer; forming a first column of semiconductor material in the semiconductor layer between the first trench and second trench; and forming a second column of semiconductor material in the semiconductor layer between the first trench and second trench.
9. The method of claim 7, further comprising: removing a portion of the nitride layer and oxide layer to expose the surface of the semiconductor layer; and forming a source/drain region proximate to the surface of the semiconductor layer.
10. The method of claim 9, further comprising: forming a gate oxide layer over the surface of the semiconductor layer; forming a gate nitride layer over a portion of the gate oxide layer; and forming a gate electrode over a portion of the gate nitride layer.
11. The method of claim 7, further comprising forming a source/drain region proximate to the surface of the semiconductor layer prior to forming the oxide layer and nitride layer.
12. The method of claim 7, further comprising: forming a body contact region proximate to the surface of the semiconductor layer and adjacent to the sidewall of the first trench; and forming a body region proximate to the surface of the semiconductor layer and adjacent to the sidewall of the first trench and surrounding the source/drain region and the body contact region.
13. The method of claim 7, further including forming the oxide layer over a bottom surface of the first trench.
14. A semiconductor device, comprising: a semiconductor layer; a first trench formed into the semiconductor layer; a first oxide layer formed over a surface of the semiconductor layer and over a sidewall of the first trench; and a first nitride layer formed over the first oxide layer.
15. The semiconductor device of claim 14, further comprising: a second trench formed into the semiconductor layer; a first column of semiconductor material formed in the semiconductor layer between the first trench and second trench; and a second column of semiconductor material formed in the semiconductor layer between the first trench and second trench.
16. The semiconductor device of claim 14, further including a source/drain region formed proximate to the surface of the semiconductor layer.
17. The semiconductor device of claim 14, further comprising: a second oxide layer formed over the surface of the semiconductor layer; a second nitride layer formed over a portion of the second oxide layer; and a gate electrode formed over a portion of the second nitride layer.
18. The semiconductor device of claim 17, further including an insulating layer formed over the gate electrode.
19. The semiconductor device of claim 14, further comprising: a body contact region formed proximate to the surface of the semiconductor layer and adjacent to the sidewall of the first trench; and a body region formed proximate to the surface of the semiconductor layer and adjacent to the sidewall of the first trench and surrounding the source/drain region and the body contact region.
20. The semiconductor device of claim 14, wherein the first oxide layer covers a bottom surface of the first trench.
Description
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
[0023] The following detailed description of preferred embodiments of the invention will be better understood when read in conjunction with the appended drawings. For the purpose of illustration, there are shown in the drawings embodiments which are presently preferred. It should be understood, however, that the invention is not limited to the precise arrangements and instrumentalities shown.
[0024] In the drawings:
[0025]
[0026]
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[0030]
[0031]
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[0041]
DETAILED DESCRIPTION OF THE INVENTION
[0042] Certain terminology is used in the following description for convenience only and is not limiting. The words “right”, “left”, “lower”, and “upper” designate directions in the drawings to which reference is made. The words “inwardly” and “outwardly” refer to directions toward and away from, respectively, the geometric center of the device and designated parts thereof. The terminology includes the above-listed words, derivatives thereof, and words of similar import. Additionally, the words “a” and “an”, as used in the claims and in the corresponding portions of the specification, mean “at least one.” Unless stated otherwise, terms such as “first” and “second” are used to arbitrarily distinguish between the elements such terms describe. Thus, these terms are not necessarily intended to indicate temporal or other prioritization of such elements.
[0043] It should also be understood that the terms “about,” “approximately,” “generally,” “substantially” and like terms, used herein when referring to a dimension or characteristic of a component of the invention, indicate that the described dimension/characteristic is not a strict boundary or parameter and does not exclude minor variations therefrom that are functionally similar. At a minimum, such references that include a numerical parameter would include variations that, using mathematical and industrial principles accepted in the art (e.g., rounding, measurement or other systematic errors, manufacturing tolerances, etc.), would not vary the least significant digit.
[0044] As used herein, reference to conductivity will be limited to the embodiment described. However, those skilled in the art know that p-type conductivity can be switched with n-type conductivity and the device would still be functionally correct (i.e., a first or a second conductivity type). Therefore, where used herein, reference to n or p can also mean either n or p or p and n can be substituted therefor.
[0045] Furthermore, n.sup.+ and p.sup.+ refer to heavily doped n and p regions, respectively; n.sup.++ and p.sup.++ refer to very heavily doped n and p regions, respectively; n.sup.− and p.sup.− refer to lightly doped n and p regions, respectively; and n.sup.−− and p.sup.−− refer to very lightly doped n and p regions, respectively. However, such relative doping concentration terms should not be construed as limiting.
[0046] Referring to
[0047] At least one, and preferably more, trenches 20 are formed to extend at least partially through the semiconductor layer 14 from the first main surface 14a thereof. Each trench 20 includes a sidewall 20a and a bottom 20b. In the embodiment shown in
[0048] A trench oxide layer 22 is preferably in contact with at least the sidewall 20a and the bottom 20b of the trench 20. In the embodiment of
[0049] A dielectric seal material 26 preferably seals the trench 20 proximate to the first main surface 14a of the semiconductor layer 14 such that the trench 20 is air-tight. The dielectric seal material 26 is shown in the embodiment of
[0050] Highly doped (e.g., n.sup.+) regions serving as source/drain regions 28 may be formed at the first main surface 14a of the semiconductor layer 14. Similarly, highly doped (e.g., p.sup.+) regions serving as body contact regions 30 may be formed at the first main surface 14a of the semiconductor layer 14 adjacent the sidewall 20a of the trench 20 (preferably between the source/drain region 28 and the trench 20). A body region 32 (such as a p doped region) may be formed at the first main surface 14a of the semiconductor layer 14 and adjacent the sidewall 20a of the trench 20, preferably surrounding the source/drain region 28 and the body contact region 30. As shown in the embodiment of
[0051] A gate electrode 34 may be provided spaced apart from the first main surface 14a of the semiconductor layer 14. For example, a gate oxide layer 36 may be formed over at least a portion of the first main surface 14a of the semiconductor layer 14 between adjacent trenches 20. Preferably, a gate nitride layer 38 is formed over at least a portion of the gate oxide layer 36. The gate electrode 34 is then formed on at least a portion of the gate nitride layer 38 (although a thin oxide layer (not shown) may be deposited on the gate nitride layer 38 before formation of the gate electrode 34). An inter-dielectric oxide layer 40 may be formed over the gate electrode 34. A metal source/drain electrode 42 preferably connects with the source/drain region 28.
[0052]
[0053] Referring to
[0054] The semiconductor layer 14 is formed such that the second main surface 14b is disposed on the semiconductor substrate 12. In some embodiments, the semiconductor layer 14 may be epitaxially grown on a surface of the semiconductor substrate 12 and may be a lightly doped n.sup.− or intrinsically n doped silicon layer. The epitaxial growth or deposition may occur in a suitable reaction chamber at a temperature of up to about 1200° C. to a desired thickness. Other methods for forming the semiconductor layer 14 on the semiconductor substrate 12, such as by bonding, annealing, and the like, may be used.
[0055] The trenches 20 are formed in the first main surface 14a of the semiconductor layer 14. The trenches 20 are preferably etched using deep reactive ion etching (DRIE). DRIE utilizes an ionized gas, or plasma, such as, for example, sulfur hexafluoride (SF.sub.6), to remove material from the semiconductor layer 14. DRIE technology permits deeper trenches 20 with straighter sidewalls. Other techniques for forming the trenches 18 can be used, however, such as plasma etching, reactive ion etching (RIE), sputter etching, vapor phase etching, chemical etching, or the like.
[0056] A mask (not shown) is selectively applied over the main surface 14a of the semiconductor layer 14. The mask may be created by deposition of a layer of photoresist or in some other manner well known to those skilled in the art. The developed photoresist is removed, and undeveloped photoresist remains in place as is known in the art. For simplification, the mask refers to the material used to prevent certain areas of a semiconductor from being etched, doped, coated or the like. In certain embodiments, a thin layer of oxide or other dielectric material (not shown) may be applied to the first main surface 14a prior to formation of the mask. The trenches 20 are formed in the areas not covered by the mask. After the trenching process, the mask is removed using techniques known in the art.
[0057] The sidewalls 20a of each trench 20 can be smoothed, if needed, using, for example, one or more of the following process steps: (i) an isotropic plasma etch may be used to remove a thin layer of silicon (typically 100-1000 Angstroms) from the trench 20 surfaces or (ii) a sacrificial silicon dioxide layer may be grown on the surfaces of the trench 20 and then removed using an etch such as a buffered oxide etch or a diluted hydrofluoric (HF) acid etch. The use of the smoothing techniques can produce smooth trench surfaces with rounded corners while removing residual stress and unwanted contaminates. However, in embodiments where it is desirable to have vertical sidewalls and square corners, an anisotropic etch process will be used instead of the isotropic etch process discussed above. Anisotropic etching, in contrast to isotropic etching, generally means different etch rates in different directions in the material being etched.
[0058] If necessary, the sidewalls 20a of the trenches 20 are implanted or doped with an n-type dopant, which may occur at predetermined angles, to form the n columns 16. The implantation angles are determined by the width of the trenches 20 and the desired doping depth, and are typically from about 2° to 12° (−2° to −12°) from vertical. The implant is done at angles so that the bottom 20b of each trench 20 is not implanted. Preferably, the implantation occurs at least partially, and preferably entirely, between the first main surface 14a and the semiconductor substrate 12. The implant is performed at an energy level of about 30-200 kilo-electron-Volts (KeV) with dose ranges from about 1E13 to 1E14 cm.sup.−2 (i.e., about 1×10.sup.13 to 1×10.sup.14 cm.sup.−2). Consequently, a dopant of the first conductivity type (e.g., n-type) is implanted into the semiconductor layer 14 to form doped regions of the first conductivity type having a doping concentration lower than that of the heavily doped semiconductor substrate 12. The doping may occur with the aid of a mask (not shown) placed over the first main surface 14a of the semiconductor layer 14.
[0059] The doping may be performed by one of ion implantation, solid diffusion, liquid diffusion, spin-on deposits, plasma doping, vapor phase doping, laser doping, or the like. Doping with boron B results in a more p-type region, doping with phosphorus P results in a more n-type region and doping with arsenic Ar results in a more n-type region. Other dopants may be utilized, such as antimony Sb, bismuth Bi, aluminum Al, indium In, gallium Ga or the like depending on the material and the desired strength of the doping. Preferably, the doping is performed by ion implantation.
[0060] Following implanting, a drive-in step at a temperature of up to 1200° C. may be performed for up to 12 hours. It should be recognized that the temperature and time are selected to sufficiently drive in the implanted dopant. But, the energy level used to perform ion implantation, as described above, may be high enough to sufficiently drive in the dopants without departing from the present invention. If the semiconductor layer 14 is already adequately doped for purposes of the resulting n column 16, then these steps may be omitted.
[0061] A similar doping step preferably occurs with respect to the sidewalls 20a of the trenches 20, but with a dopant of the opposite conductivity type (e.g., p-type), to form the p columns 18 that separate the n column 16 from the trench 20.
[0062] Referring to
[0063] Referring to
[0064] In an alternative embodiment, shown in
[0065] Referring to
[0066] Referring to
[0067] Referring to
[0068] The source/drain regions 28 may also be formed proximate the first main surface 14a of the semiconductor layer 14 and within the body regions 32. The source/drain regions 28 are preferably a heavily doped n.sup.+ type region, which may be formed using techniques similar to those described above for formation of the body regions 32. The orientation of the source/drain region 28 with respect to the body region 32 is not limited and can be varied depending upon the desired configuration of the device 10. Further, there is no limit to the order in which the two regions 28, 32 may be formed. Moreover, additional regions, such as a body-contact region 30 (preferably a heavily doped p.sup.+ type region) adjacent the source/drain region 28 and within the body region 30, preferably also adjacent the sidewall 20a of the trench 20, may be formed according to the methods described above.
[0069] The gate oxide layer 36 may be formed over the active areas on the first main surface 14a of the semiconductor layer 14, and the gate nitride layer 38 may be formed over at least a portion of the gate oxide layer 36. The gate oxide and nitride layers 36, 38 may be formed according to the same techniques described above with respect to the trench oxide and nitride layers 22, 24. The gate electrode 34 is then formed over at least a portion of the gate nitride layer 38 and may be composed of, for example, a metal, a doped polysilicon, an amorphous silicon, or a combination thereof, and formed by conventional techniques.
[0070] It should be noted that while the drawings and description show the gate oxide layer 36, gate nitride layer 38, and gate electrode 34 being formed after the source/drain region 28, body-contact region 30, and body region 32, it is also possible to form the source/drain region 28 (or others) after the gate oxide layer 36, gate nitride layer 38, and gate electrode 34. Such an order can allow the source/drain region 28, for example, to self-align with the gate electrode 34. Accordingly, one skilled in the art will recognize that various steps described herein may be performed in different orders while achieving the same end result.
[0071] Referring to
[0072]
[0073] Referring to
[0074] The gate oxide layer 136 is formed over the first main surface 114a of the semiconductor layer 114, and the gate nitride layer 138 is formed over at least a portion of the gate oxide layer 136, at least in the regions where the gate electrode(s) 134 are to be disposed. The gate electrode 134 is thereafter formed over at least a portion of the gate nitride layer 138. The inter-dielectric oxide 140 (not shown in
[0075] Referring to
[0076] Referring to
[0077] In an alternative embodiment, shown in
[0078] Referring to
[0079] Referring to
[0080] Embodiments described herein can be applied to all types of semiconductor devices utilizing deep trenches, and are therefore not limited just to the types of power MOSFETs described above. For example,
[0081] Those skilled in the art will recognize that boundaries between the above-described operations are merely illustrative. The multiple operations may be combined into a single operation, a single operation may be distributed in additional operations and operations may be executed at least partially overlapping in time. Further, alternative embodiments may include multiple instances of a particular operation, and the order of operations may be altered in various other embodiments.
[0082] While specific and distinct embodiments have been shown in the drawings, various individual elements or combinations of elements from the different embodiments may be combined with one another while in keeping with the spirit and scope of the invention. Thus, an individual feature described herein only with respect to one embodiment should not be construed as being incompatible with other embodiments described herein or otherwise encompassed by the invention.
[0083] It will be appreciated by those skilled in the art that changes could be made to the embodiments described above without departing from the broad inventive concept thereof. It is understood, therefore, that this invention is not limited to the particular embodiments disclosed, but it is intended to cover modifications within the spirit and scope of the present invention as defined by the appended claims.