FOAMABLE COMPOSITIONS AND METHODS FOR FABRICATING ARTICLES WITHIN A CABLE DESIGN

Abstract

A foamable composition includes a base polymer, talc blended with the base polymer, and a citrate compound blended with the base polymer. The foamable composition is usable as an insulator, a separator and a jacket for cables, such as communications cable. The foamable composition can include conductive inclusions in the foamable composition.

Claims

1. A composition, comprising: a base polymer, talc blended with the base polymer, and a citrate compound blended with the base polymer.

2. The composition of claim 1, wherein the concentration of the talc in the composition is in a range of about 3% to about 16%.

3. The composition of claim 1, wherein a concentration of the citrate compound in the composition is in a range of about 0.01% to about 1% by weight.

4. The composition of claim 1, wherein a concentration of the base polymer is in a range of about 50% to about 95% by weight.

5. The composition of claim 1, wherein the base polymer comprises a fluoropolymer.

6. The composition of claim 5, wherein the fluoropolymer is polyvinylidene fluoride (PVDF), ethylene chlorotrifluoroethylene (ECTFE), ethylene tetrafluoroethylene (ETFE) or combinations thereof.

7. The composition of claim 1, wherein the base polymer comprises a perfluoropolymer.

8. The composition of claim 7, wherein the perfluoropolymer is tetrafluoroethylene/perfluoromethylvinyl ether copolymer (MFA), hexafluoropropylene/tetrafluoroethylene copolymer (FEP), perfluoroalkoxy (PFA), perfluoroalkoxyalkane or combinations thereof.

9. The composition of claim 1, wherein the polymer is polyphenylenesulfide (PPS), polyetherimide (PSU), polyphenylsulfone (PPSU), polyethersulfone (PES/PESU), polyetheretherketone (PEEK), polyaryletherketone (PAEK), polyetherketoneketone (PEKK), polyetherketone (PEK), cyclic olefin copolymer (COC), polycarbonate (PC) polyphenylene ether (PPE), liquid crystal polymer (LCP), a polyolefins, polyethylene (PE), polypropylene (PP), cyclic olefin copolymer (COC), polycarbonate (PC), polyphenylene ether (PPE), liquid crystal polymer (LCP), polymethyl methacrylate (PMMA), aliphatic or semi-aromatic polyamides (NYLON) or combinations thereof.

10. The composition of claim 1, wherein the polymer is a fluoropolymer, a perfluoropolymer, polyphenylenesulfide (PPS), polyetherimide (PSU), polyphenylsulfone (PPSU), polyethersulfone (PES/PESU), polyetheretherketone (PEEK), polyaryletherketone (PAEK), polyetherketoneketone (PEKK), polyetherketone (PEK), cyclic olefin copolymer (COC), polycarbonate (PC) polyphenylene ether (PPE), liquid crystal polymer (LCP), a polyolefins, polyethylene (PE), polypropylene (PP), cyclic olefin copolymer (COC), polycarbonate (PC), polyphenylene ether (PPE), liquid crystal polymer (LCP), polymethyl methacrylate (PMMA), aliphatic or semi-aromatic polyamides (NYLON) or combinations thereof.

11. The composition of claim 1, wherein the citrate compound is calcium citrate, potassium citrate, zinc citrate or combinations thereof.

12. The composition of claim 1, further comprising a nucleating agent.

13. The composition of claim 12, wherein the nucleating agent is PTFE (polytetrafluoroethylene), boron nitride, zinc borate, zinc oxide, titanium dioxide or combinations thereof.

14. The composition of claim 12, wherein a concentration of the nucleating agent is in a range of about 0.1% to about 3% by weight.

15. The composition of claim 1, further comprising wax.

16. The composition of claim 15, wherein the wax is Aclyn wax.

17. The composition of claim 16, wherein a concentration of the Aclyn wax is in a range of about 0.1% to about 0.75%.

18. The composition of claim 1, wherein the composition is tube extruded, semi-pressure extruded or pressure extruded at an extrudate pressure of less than any of 3500 psi or 2500 psi.

19. A process for fabricating a foamed article, comprising: heating a composition comprising a base polymer, talc blended with the base polymer, and a citrate compound blended with the base polymer to a temperature sufficient to cause decomposition of talc to generate a gas for foaming the composition.

20. The process of claim 19, further comprising extruding the heated composition to form the foamed article.

21. The process of claim 19, wherein the temperature is at least about 500° F.

22. The process of claim 26, wherein the citrate compound is calcium citrate, potassium citrate, zinc citrate or combinations thereof.

23. The process of claim 19, wherein the concentration of the talc in the composition is in a range of about 3% to about 16%.

24. The process of claim 19, wherein a concentration of the citrate compound in the composition is in a range of about 0.01% to about 1% by weight.

25. The process of claim 19, wherein a concentration of the base polymer is in a range of about 50% to about 98.5% by weight.

26. The process of claim 19, wherein the base polymer is a fluoropolymer.

27. The process of claim 26, wherein the fluoropolymer is polyvinylidene fluoride (PVDF), ethylene chlorotrifluoroethylene (ECTFE) or ethylene tetrafluoroethylene (ETFE) or combinations thereof.

28. The process of claim 19, wherein the base polymer is a perfluoropolymer.

29. The process of claim 28, wherein the fluoropolymer is tetrafluoroethylene/perfluoromethylvinyl ether copolymer (MFA), hexafluoropropylene/tetrafluoroethylene copolymer (FEP), perfluoroalkoxy (PFA), perfluoroalkoxyalkane or combinations thereof.

30. The process of claim 19, wherein the base polymer is an engineering resin or engineering polymer.

31. The process of claim 30, wherein the engineering polymer is polyphenylenesulfide (PPS), polyetherimide (PEI), polysulfone (PSU), polyphenylsulfone (PPSU), polyethersulfone (PES/PESU), polyetheretherketone (PEEK), polyaryletherketone (PAEK), polyetherketoneketone (PEKK), polyetherketone (PEK), or polyolefins such as polyethylene (PE), polypropylene (PP), cyclic olefin copolymer (COC), polycarbonate (PC), polyphenylene ether (PPE), liquid crystal polymer (LCP), polymethyl methacrylate (PMMA), aliphatic or semi-aromatic polyamides (NYLON) or combinations thereof.

32. The process of claim 30 wherein the polymer is a fluoropolymer, a perfluoropolymer and polyphenylenesulfide (PPS), polyetherimide (PEI), polysulfone (PSU), polyphenylsulfone (PPSU), polyethersulfone (PES/PESU), polyetheretherketone (PEEK), polyaryletherketone (PAEK), polyetherketoneketone (PEKK), polyetherketone (PEK), or polyolefins such as polyethylene (PE), polypropylene (PP), cyclic olefin copolymer (COC), polycarbonate (PC), polyphenylene ether (PPE), liquid crystal polymer (LCP), polymethyl methacrylate (PMMA), aliphatic or semi-aromatic polyamides (NYLON) or combinations thereof.

33. The process of claim 19, wherein the composition is in the form of a pellet.

34. The process of claim 20, wherein the step of extruding the heated composition comprises pressure extruding the heated composition.

35. The process of claim 20, wherein the step of extruding the heated composition comprises semi-pressure extruding the heated composition.

36. The process of claim 20, wherein the step of extruding the heated composition comprises tube extruding the heated composition.

37. The process of claim 34, wherein the step of pressure extruding comprises maintaining a pressure to which the heated composition is subjected is less than about 3500 psi.

38. The process of claim 37, wherein the step of pressure extruding comprises maintain the pressure to which the heated composition is subjected is less than about 2500 psi.

39. The composition of claim 1, including electrically conductive inclusions in the composition.

40. The composition of claim 39, wherein the electrically conductive inclusions are silver, aluminum, copper, gold, bronze, tin, zinc, iron, nickel, indium, gallium, stainless steel, tin alloys, gallium alloys, zinc alloys, copper oxide, bronze oxide, tin oxide, zinc oxide, zinc-doped indium oxide, indium tin oxide, nickel oxide, aluminum oxide, multiple metals, multiple metal alloys, multiple metal oxides, conductive carbons, carbon nanotubes, single-walled carbon nanotubes, carbon fullerenes, carbon fibers, nickel coated carbon fibers, single or multi wall graphene, carbon fibers or combinations thereof.

41. The composition of claim 40, wherein the electrically conductive inclusions comprise a volume fraction of the composition in a range of about 1% to about 40%.

Description

DESCRIPTION OF THE DRAWINGS

[0040] FIG. 1A is an illustration of foamable pellets in accordance with an embodiment of the present disclosure;

[0041] FIG. 1B is an illustration of foamable pellets having conductive inclusions in accordance with an embodiment;

[0042] FIG. 2A is a simplified flow diagram of a method for forming a foamed composition;

[0043] FIG. 2B illustrates a cable having a foamed insulation;

[0044] FIG. 2C illustrates a foamed separator;

[0045] FIG. 2D illustrates a foamed tape separator;

[0046] FIG. 3A is a simplified flow diagram of a method for forming a foamed composition having conductive inclusions;

[0047] FIGS. 3B and 3C illustrate a tape (FIG. 3B) and a separator (FIG. 3C) that have been extruded into a discontinuous foamed cable shield (FIG. 3B) and a separator (FIG. 3C);

[0048] FIG. 4 depicts a foamed separator;

[0049] FIG. 5 illustrates an example of a communications cable having a separator defining four channels for carrying transmission media;

[0050] FIG. 6 is a cross-sectional illustration of a cable having five channels and carrying various types of media, including power;

[0051] FIG. 7 illustrates another example of a communications cable having a separator defining four channels for carrying transmission media;

[0052] FIG. 8 is still another example of a cable having a co-extruded foamed polymeric semi-conductive inner jacket shielding layer;

[0053] FIG. 9 is an illustration of a foamed tape having conductive inclusions to wrap around pairs of conductors or to wrap around a separator (with pairs of conductors);

[0054] FIGS. 10 and 11 illustrate the measurement of AC and/or DC conductivity across the length of a separator; and

[0055] FIG. 12 illustrates a plurality of conductors disposed in respective channels defined or provided by the separator in a cable.

DETAILED DESCRIPTION

[0056] The present disclosure generally provides foamable polymeric compositions, which can be extruded as an insulation, separator, tape and/or jacket in a wide range of cables as disclosed herein. In particular, it has been found that the use of talc together with a citrate compound, such as a citrate salt, in a polymeric composition can advantageously provide enhanced small and closed cell foaming for multiple aspects of the cable design. In other words, it has been found that talc and the citrate compound can act synergistically to provide enhanced foaming. In some embodiments, the compositions according to the present disclosure are compounded into a plurality of pellets to ultimately be extruded as foamed insulation, foamed separator, foamed tape and/or foamed jacket.

[0057] Various terms are used herein according to their ordinary meanings. For additional clarity, the following terms are further defined below.

[0058] The term “talc” as used herein refers generally to natural or synthetic hydrated magnesium silicate compounds. In some embodiments, talc mineral comprises magnesium hydrosilicate represented by the formula: 3MgOSiO.sub.2H.sub.2O, where in some cases SiO.sub.2 is about 64.5 weight percent, MgO is about 31.9 weight percent and H.sub.2O is about 4.75 weight percent. In some cases, talc can include other minerals such as magnesite, chlorite, magnetite, carbonate, and dolomite. The term “engineered resin” or “engineered polymer” as used herein refers to any of the following polymers: polyphenylenesulfide (PPS), polyetherimide (PEI), polysulfone (PSU), polyphenylsulfone (PPSU), polyethersulfone (PES/PESU), polyetheretherketone (PEEK), polyaryletherketone (PAEK), polyetherketoneketone (PEKK), polyetherketone (PEK), or polyolefins such as polyethylene (PE), polypropylene (PP), cyclic olefin copolymer (COC), polycarbonate (PC), polyphenylene ether (PPE), liquid crystal polymer (LCP), polymethyl methacrylate (PMMA), aliphatic or semi-aromatic polyamides (NYLON) and/or combinations thereof.

[0059] The term “about” as used herein is intended to indicate a variation of at most 10%.

[0060] The term “foamed article” as used herein refers to an article of manufacture that includes a plurality of cellular structures.

[0061] The term “foamable rate”, “foam rate,” or “foaming rate” are used herein interchangeably and refer to the ratio of the volume of cells in a cellular structure, e.g., a cellular separator or tape, relative to the total volume of the structure.

[0062] With reference to FIG. 1A, in some embodiments, the present disclosure provides a plurality of pellets 10, each of which includes a base polymer 12 as well as talc 14 and a citrate compound 16, such as a citrate salt, distributed through the polymer. In some embodiments, the talc can have a weight concentration in a range of about 1% to about 30%. By way of example, the talc can be present in the composition, e.g., in the pellets 10, at a weight concentration of about 2% to about 25%, or in a range of about 3% to about 15%, or in a range of about 4% to about 10%. Further, in some embodiments, the weight concentration of the citrate compound 16 in the composition, e.g., in the pellets 10, can be in a range of about 0.01% to about 1%, or in a range of about 0.02% to about 0.9%, or in a range of about 0.03% to about 0.8%, or in a range of about 0.04% to about 0.7%, or in a range of about 0.05% to about 0.6%, or in a range of about 0.06% to about 0.5%. Further, the weight concentration of the base polymer in the composition, e.g., the pellets 10, can be, for example, in a range of about 40% to about 98.5% by weight, e.g., in a range of about 50% to about 95%, or in a range of about 60% to about 90%.

[0063] A variety of base polymers can be employed in a composition according to the present teachings. By way of example, in some embodiments, the base polymer can be a fluoropolymer, more specifically, polyvinylidene fluoride (PVDF), ethylene chlorotrifluoroethylene (ECTFE) or ethylene tetrafluoroethylene (ETFE). In some embodiments, the fluoropolymer can be a perfluoropolymer. Examples of these suitable base polymers include, tetrafluoroethylene/perfluoromethylvinyl ether copolymer (MFA), hexafluoropropylene/tetrafluoroethylene copolymer (FEP), perfluoroalkyl substances (PFAS), and perfluoroalkoxy alkane (PFA), and combinations thereof. The term “engineered resin” or “engineered polymer” as used herein refers to any of the following polymers: polyphenylenesulfide (PPS), polyetherimide (PEI), polysulfone (PSU), polyphenylsulfone (PPSU), polyethersulfone (PES/PESU), polyetheretherketone (PEEK), polyaryletherketone (PAEK), polyetherketoneketone (PEKK), polyetherketone (PEK), or polyolefins such as polyethylene (PE), polypropylene (PP), cyclic olefin copolymer (COC), polycarbonate (PC), polyphenylene ether (PPE), liquid crystal polymer (LCP), polymethyl methacrylate (PMMA), aliphatic or semi-aromatic polyamides (NYLON) and/or combinations thereof and/or a combination of fluoropolymers, perfluoropolymers and any of the listed engineered resins herein.

[0064] In some embodiments, the citrate compound can be a citrate salt. Some suitable examples of citrate salts include, without limitation, calcium citrate, potassium citrate, zinc citrate and combinations thereof.

[0065] The combination of the talc and the citrate compound advantageously allows enhanced foaming of the pellets 10. By way of example, pellets containing a combination of talc and a citrate salt according to the present disclosure can be foamed at a much higher rate than similar pellets with only talc as the foaming agent. By way of example, in some embodiments, a pellet according to the present disclosure is foamable at a foaming rate of at least about 20%, or at least about 30%, or at least about 40%, or at least about 50%, or at least about 60%, or at least about 70%.

[0066] In some embodiments, the foaming of the compositions according to the present disclosure can result in a foamed article, such as a separator or tape suitable for use in a communications cable, which includes a plurality of cellular structures distributed therein. In some embodiments, at least about 20%, or at least about 30%, or at least about 40%, or at least about 50%, or at least about 60%, or at least about 70%, or all of the cellular structures can be in the form of closed cells. Further in some embodiments, such cellular structures can have a maximum size in a range of about (0.5 mils to 5 mils, i.e., 0.0005 inches to 0.005 inches).

[0067] With reference to FIG. 1B, schematically, a plurality of pellets is shown according to an embodiment, in which the pellets include a base polymer, the foaming agent e.g. (talc, citrates) as well as electrically conductive inclusions. The inclusions can include metallic particulate in varying shapes or sizes and metallic as well as carbon fiber, fullerenes, or single wall or multi-wall graphene. All of which are discussed herein.

[0068] With reference to FIG. 2A, a step chart process for fabricating a foamed article is disclosed, which includes heating a composition comprising a base polymer, talc blended with the base polymer, and a citrate compound blended with the base polymer to a temperature sufficient to cause decomposition of at least talc so as to generate a gas for foaming the composition. By way of example, the composition can be heated to a temperature of at least about 400° F., or at least about 500° F., or at least about 600° F., or at least about 700° F. In some embodiments, the heated composition can be extruded to form a foamed insulation as shown in FIG. 2B. Alternatively, a foamed separator illustrated in FIG. 2C or a foamed tape illustrated in FIG. 2D can be formed. Alternatively, the foamed separator or tape may serve a dual function and incorporate the required attributes of a discontinuous shield by the addition of compounding the metal inclusions and/or carbon fibers of single wall or multi-wall graphene into the foamable pellets prior to extrusion. FIG. 3A illustrates a process flow of denoting the compounding of both the chemical foaming agents along with the metal inclusions and/or carbon fibers of single wall or multi-wall graphene. From those pellets, as illustrated in FIG. 3B, a tape can be extruded into a discontinuous foamed cable shield and/or as illustrated in FIG. 3C, a separator can be extruded into a discontinuous foamed cable shield.

[0069] FIG. 4 schematically depicts a foamed article 20, in the form of a separator suitable for use in a communications cable, which is formed using methods according to the present disclosure. The separator 20 includes a central portion 22 from which a plurality of arms 24 extend that provide a plurality of channels 28 in which a variety of media, such as insulated twisted copper pairs, can be disposed. The separator 20 can be formed of a polymer, such as those disclosed herein, in which a plurality of cellular structures are distributed. In this embodiment, the cellular structures are in the form of gas-filled cavities. In some embodiments, the maximum size of these cellular structures, e.g., the diameter of the cellular structures when they have a spherical form, can be, for example, in a range of about 0.5 mil to 5 mil (about 0.0005 inches to 0.005 inches).

[0070] In some embodiments, the volume of the cellular structures is at least about 20%, or at least about 30%, or at least about 40%, or at least about 50% of the volume of the separator. Further, in some embodiments, at least about 30%, or at least about 50%, or at least about 70%, or at least about 90% of the cellular structures or all of the cellular structures can be in the form of closed cells.

[0071] By way of further illustration, FIG. 5 schematically illustrates an example of a communications cable 1000, which includes a separator 1002 providing four channels 1004, 1006, 1008, and 1010 in any or all of which one or more transmission media can be positioned. In this embodiment, the separator 1002 has a substantially crossweb shape, though in other embodiments, the separator 1002 can have other shapes. In this embodiment, in each of the channels provided by the separator, a twisted pair of conductors can be disposed, where each conductor is surrounded by an insulation (the insulation obscures the view of the conductors in this figure).

[0072] The cable further includes a jacket 1014 within which the crossweb separator as well as the insulated twisted pairs of conductors are housed.

[0073] The entire cable design, that is the jacket 1014, the crossweb or tape separator 1002, and the insulation, also shown in FIG. 2B, can be foamed from the aforementioned chemical foaming ingredients and pelletized via compounding with fluoropolymers including polyvinylidene fluoride (PVDF), ethylene chlorotrifluoroethylene (ECTFE), or ethylene tetrafluoroethylene or the perfluoropolymers of tetrafluoroethylene/perfluoromethylvinyl ether copolymer (MFA), hexafluoropropylene/tetrafluoroethylene copolymer (FEP), perfluoroalkoxy substances (PFAS), and perfluoroalkoxyalkane (PFA), and combinations thereof, for optimum cable design performance. In some additional embodiments, any of the jacket 1014, the crossweb or tape separator 1002, and the insulations 1012 can be formed of a “engineered resin” as used herein and referring to any of the following polymers: polyphenylenesulfide (PPS), polyetherimide (PEI), polysulfone (PSU), polyphenylsulfone (PPSU), polyethersulfone (PES/PESU), polyetheretherketone (PEEK), polyaryletherketone (PAEK), polyetherketoneketone (PEKK), polyetherketone (PEK), or polyolefins such as polyethylene (PE), polypropylene (PP), cyclic olefin copolymer (COC), polycarbonate (PC), polyphenylene ether (PPE), liquid crystal polymer (LCP), polymethyl methacrylate (PMMA), or aliphatic or semi-aromatic polyamides (NYLON) and/or combinations thereof, and/or a combination of fluoropolymers, perfluoropolymers and/or any of the disclosed engineered resins. In any case, compounded foamable pellets can be derived from these base materials for the optimization of cable design, for example, 5G globally and more specifically for power over ethernet (PoE), and the Internet of Thing (IoT).

[0074] Within a cable design, one or all of the support separator as shown in FIG. 2C, tape separator as shown in FIG. 2D, insulation 1012 as shown in FIG. 5, and/or the jacket 1014 as also shown in FIG. 5 can have a polymeric foamed structure. For example, the foamed structure can include a plurality of air pockets that are distributed within the support separator, tape separator, insulation, and/or the jacket.

[0075] In some embodiments, the polymeric foamed structure of any of the separator, the tape separator, the conductor insulation(s) and the jacket can exhibit a foaming rate (i.e., a ratio of the volume of the cellular structures, for example, air pockets, distributed throughout the component relative to the total volume of that component) in a range of about 20% to about 60%, for example in a range of about 40% to about 50%. In some embodiments, the maximum dimension of the cellular structures (e.g. their diameters) can be, for example, in a range of about 0.0005 inches to about 0.005 inches.

[0076] In some embodiments, at least one of the twisted pairs of the conductors disposed in one of the channels provided by the separator 1002 can carry both communication data as well as electrical power. By way of example, such a twisted pair can be formed of copper wires having a gauge (AWG) in a range of 8 AWG to 28 AWG, and more typically in a range of 16 to 24 AWG, for example, 18 AWG for power and 23 AWG for data. This allows for higher amperage to, for example, power LED lighting, which is a further example of the need for foam insulation, foam support separators, foam tape separators and/or foam jackets as a solution to minimize or dissipate heat within cabling and transfer heat to adjacent cables when bundled together in raceways of commercial building cabling networks.

[0077] It has been unexpectedly found that in some embodiments in which the jacket 1014 has a foamed polymeric structure, the jacket is printable with, for example, letters, characters, and/or symbols, on the jacket using ink or other known techniques. By way of example, when the jacket is formed of foamed FEP, the jacket can be printable whereas a jacket formed of solid FEP is not printable.

[0078] FIG. 6 schematically depicts an embodiment of a hybrid copper fiber cable design providing data communications and power. In this cable all of the components, such as copper insulation, fiber buffer, support separator or tape, and/or jacket may be foamed or solid. The support separator 2002 provides five channels for receiving transmission media. In this embodiment, the support separator 2002 has a flap-top configuration that allows for complete or partial closure of the channels (the dimensions provided in the figure are for illustrative purposes only and may not be to scale), and is not meant to limit alternative sizes of various components of the communication cable design. Four twisted pairs of conductors 2004A-D are disposed in four of the channels, and two buffered optical fibers 2006A are disposed in the fifth channel. In this embodiment, the twisted pairs of conductors are formed of 23 AWG copper wires, which allows for the transmission of communication data as well as electrical power.

[0079] Similar to the previous embodiment, the twisted pairs of conductors are covered with insulation 2012. Further, the optical fibers 2006A are surrounded by buffers 2014A. With continued reference to FIG. 6, a jacket 2016 surrounds the separator, the twisted pairs of conductors, and the optical fibers.

[0080] Any of the components of the communications cable 2000 shown in FIG. 6, individually or in combination with one or more other components, can be formed of a solid or a foamed polymeric material as described herein. By way of example, in some embodiments, the insulation(s) 2012 as well as the buffer 2014A can be formed as a foamed polymeric structure. In some embodiments, all components of the communications cable, including the support separator, the insulation(s), the buffers, and the jacket can be formed as a foamed polymer structure. Similar to the previous embodiment, in some embodiments, the foamed components of the communication cable 2000 can exhibit a foaming rate, e.g., in a range of about 20% to about 60%, or in a range of about 40% to about 50%. Further, in some such embodiments, the cellular structures of the foam (such as the air pockets) can exhibit a maximum dimension in a range of about 0.0005 inches to about 0.005 inches.

[0081] More specifically, to meet the North American NEC standards for cabling, the insulation 1012 can be formed of foamed FEP for plenum applications and can be formed of foamed FR polyolefin for riser applications. Further, in some such embodiments, a foamed fiber optic buffer for critical high temperature applications or plenum cable applications may use the chemical foamed formulation for PEEK polyetheretherketone or FEP, MFA, PFA perfluoropolymers or blends thereof, such as blends of PEEK/PFA.

[0082] FIG. 7 schematically depicts an embodiment of a cable 5000 for devices such as wireless access points (WAP) that require both a communication cable for data communication and power. That is that cable, with or without a support separator 5002 provides a plurality of channels for receiving transmission media 5004 (which are a plurality of insulated twisted pairs of conductors in this embodiment). In some embodiments, the transmission media positioned in at least one of the channels can include one or more buffered optical fibers and/or typically higher gauge wire (e.g., from about 23 AWG to 16 AWG) in any of the channels.

[0083] A polymeric separator tape 5006 can at least partially, and in some embodiments completely, wrap around the separator 5002 if necessary, and the associated copper insulated transmission media 5004 (which can vary from about 16 AWG to 24 AWG. In this embodiment, the foamed tape 5006 is formed as a flexible polymeric sheet or so-called tape in which a plurality of conductive inclusions 5006a are distributed within the foamed tape. In some embodiments, the inclusions can be electrically conductive elements (e.g., micron shaped particles) that are distributed throughout the polymeric tape. By way of example, such electrically conductive inclusions can include, without limitation, silver, aluminum, copper, gold, bronze, tin, zinc, iron, nickel, indium, gallium, or stainless steel. In some embodiments, the electrically conductive inclusions can include metal alloys, such as tin alloys, gallium alloys, or zinc alloys. In other embodiments, the electrically conductive inclusions can include metal oxides, such as copper oxide, bronze oxide, tin oxide, zinc oxide, zinc-doped indium oxide, indium tin oxide, nickel oxide, or aluminum oxide. In some embodiments, some of the electrically conductive inclusions are formed of one material while others are formed by a multiple or at least two other metals and/or conductive carbon. In some embodiments, the electrically conductive inclusions are formed of metals and are substantially free of any metal oxides. Further, in some embodiments, the electrically conductive inclusions can include carbon nanotubes, such as single-walled carbon nanotubes. Additionally, metallic materials may be blended with carbon-based materials. By way of example, the metal particulate or inclusions may include silver, aluminum, copper, gold, bronze, tin, zinc, iron, nickel, indium, gallium, and/or stainless steel. In some embodiments, the electrically conductive inclusions can include metal alloys, such as tin alloys, gallium alloys, and/or stainless steel.

[0084] FIG. 7 depicts 5006 as a foamed discontinuous shield not requiring grounding and having the dual functionality of being a foamed polymer or blended polymers as well as a conductive discontinuous tape shield mitigating electromagnetic fields of pair to pair crosstalk and/or alien cross talk from adjacent cabling. The separator crossweb or separator tape may be foamed as well and optionally have the conductive inclusions so as to become a discontinuous tape shield, characteristic of an aluminum mylar, albeit not needing to be grounded which is a typical need of the installer when traditional aluminum mylar shielded cables are installed. A foamed discontinuous shielding tape used in concert or wrapped around a shielded support separator tape would enable an individually shielded twisted pair (ISTP) cable design. This ISTP design is widely used in Europe. Alternatively, a crossweb support separator can be foamed in this embodiment and utilize a conductive discontinuous foam tape to surround the pairs and foamed separator. Such a design is widely used in the North American cable market and would characteristically be defined as foil tape shield with unshielded individual pairs (F/UTP). In some embodiments, the electrically conductive inclusions can have a maximum dimension (e.g., a length and/or a cross-sectional dimension) in a range of about 10 microns to about 6000 microns, e.g., in a range of about 600 microns to about 1000 microns.

[0085] Furthermore, such conductive inclusions can be incorporated in any of the separators, tapes and/or, in an embodiment, as a coextruded jacket as disclosed previously, and other configurations, to, for example, enhance the shielding properties of these components without the need to ground the cable.

[0086] By way of example, FIG. 8 illustrates a cable jacket 150 according to an embodiment of the disclosure that has an elongated tubular shape, which extends from a proximal end 156 to a distal end 154. The elongated tubular shape of the cable jacket forms a shell, e.g., a polymeric shell, having an interior layer 152 adapted for housing one or more conductors. A plurality of metal inclusions and/or carbon-based inclusions 152 are distributed throughout the cable's inner polymetric jacket 150. In some embodiments, the metal and or carbon-based inclusions 152 are distributed via a coextrusion underneath the jacket and are distributed substantially uniformly within the inner diameter of the cable jacket 150.

[0087] In some embodiments, the cable jacket may comprise one or more different polymers, for example, a blend of one or more fluoropolymer, perfluoropolymers, and or engineered polymers or combinations thereof. In some cases, the metal inclusions can exhibit a variety of different shapes and/or be formed of different metals and carbon-based materials. In some embodiments, one type of the metal inclusions primarily reflects electromagnetic radiation within a frequency range (eg, 1 MHz to about 10 GHz) incident thereon while the other type of metal inclusions primarily absorbs the incident radiation in that wavelength range. In this manner, effective shielding of conductors via flexible support tapes, support separators and or inner coextruded jacket linings can accomplish the goal of discontinuous shields for twisted pair cable. The flexible foamed discontinuous shielding tape maybe used singularly or multiply with foamed support separators and/or inner foamed coextruded jacket lining.

[0088] The co-extruded foamed polymeric semi-conductive inner jacket shielding layer that surrounds the foamed support separator (in which the transmission media is disposed in the channels) may or may not need a foamed wrapped shielding tape (5006 in FIG. 7) based on the redundancy, although the added benefit may be a higher efficient shield for electromagnetic incidents with the duality of foamed discontinuous shielding tape working in conjunction with the co-extruded foamed discontinuous shield as a secondary overall jacket in a single pass extrusion. FIG. 9 illustrates an optional discontinuous shielded foamed tape wrap with metal/carbon-based inclusions that is foamed to provide an individual shield for each pair (ISTP) or an overall shield (F/UTP). Similar to the separator, tapes or wire insulation, the jacket and these tapes depicted in FIGS. 7-9 can be formed from compounded pellets utilizing a variety of polymers as carriers to include fluoropolymers, perfluoropolymers, and engineered resins, such as those polymers previously disclosed herein.

Comparison Examples of Foamable Pellets

[0089] A comparison of pellets formed from a blend of FEP polymer and talc were compared to pellets formed from a blend of talc and calcium citrate. The concentration of the FEP polymer in each blend was about 94% by weight. In the FEP/talc blended pellets the concentration of talc was about 3.75% by weight and in the FEP/talc/calcium citrate pellets, the concentration of talc was about 3.75% and the concentration of calcium citrate was about 0.05% by weight. Both the FEP/talc and FEP/talc/calcium citrate pellets also included a process aid, such as a wax, for example, Aclyn wax at about 0.05% by weight. It is to be understood that the use of a process aid, such as a wax, for example, Aclyn wax is optional, and that in some pellets it may not be used. The blends (that is, the FEP/talc/wax (i.e., Aclyn wax) and FEP/talc/calcium citrate/wax (i.e., Aclyn wax)) were compounded to produce a plurality of pellets of each blend. The blends or batches of pellets were processed separately at the process parameters indicated in Table 2, below. The processing of the pellets was performed on 1.5″ high-temperature extruder with a general-purpose screw with a 26:1 L/D. The various components that make up the blend were mixed together on the line and put directly into the hopper of the extruder.

TABLE-US-00002 TABLE 2 Process Parameters and Results for Forming Foamable Pellet Comparison FEP base polymer + FEP base 3.75% talc + polymer + Blend 0.5% citrate 3.75% talc Diameter (in.) 0.04 0.04 Wire Diameter (in.) 0.0226 0.0226 Die (in.) 0.185 0.185 Tip (in.) 0.092 0.085 DDR 23:1 23:1 DRB 1.01 1.03 Crosshead Canterbury Canterbury Screen Pack 20/40/60 20/40/60 Screw General Purpose General Purpose Zone 1 (F) 580 580 Zone 2 (F) 680 680 Zone 3 (F) 720 720 Zone 4 (F) 730 730 Clamp (F) 730 730 Valve (F) 730 730 Head (F) 730 730 Die (F) 730 730 Melt Temperature (F.) 670 670 RPM 30 24 Capstan Setting 15 30 Run Speed (FPM) 303 606 Pressure 860 945 Vacuum −1.2 −1.10 Pre-Heat 34.6 45.4 Insulation S.G. 0.89 1.45 Foam Rate 59% 32% Avg. Cell Size (in.) 0.0023 0.0009 Air Gap 6 in 6 in

TABLE-US-00003 TABLE 3 Machine Parameters for Forming Foamable Pellet Comparison Wall Thickness (inches) 0.00955 Wire OD (inches) 0.0226 Die OD (inches) 0.042 Gum Space (inches) 0.25 Clamp Temperature (° F.) 730 Valve (° F.) 735 Head (° F.) 740 Die (° F.) 740

[0090] The results in Table 2, specifically, the foam rate and average cell size show that the use of talc together with citrate results in a much-enhanced foam rate relative to using only talc. In particular, a foam rate of 59% was observed for pellets containing both talc and citrate while a foam rate of 32% was observed for pellets

[0091] The foamed insulation as well as the extrusion process exhibited a number of advantageous properties. For example, at a thickness of 0.008 inches, which is consistent with communication insulation wall thicknesses, there were no spark failures, thus meeting the Underwriters Laboratory (UL) test protocol at 1250 volts. And, with respect to processing, the insulation process at 0.008 inches can be run at greater than 800 feet per minute in a pressure extrusion set-up. The extrusion process forms a closed cell on both the inner skin and the outer skin when forming an insulation over a conductor. The foamed insulation exhibited a tensile strength greater than about 2000 psi, an elongation greater than about 150%, and a foam rate of 35%.

[0092] The polymer carriers for foamable and conductive shielding disclosed herein as generally described as fluoropolymers, perfluoropolymers, or engineered resins and include polyolefins and/or combinations thereof. These polymers, incorporating foaming agent(s), as well as a shielding agent within a compounded pelletized material are useful to produce separators and/or tapes will provide a dual functionality and can be finely tuned as to a materials conductivity. Examples of the materials for separators, tapes, and/or co-extruded inner jacket liner include fluoropolymers such as PVDF, ECTFE and ETFE, perfluoropolymers, such as FEP, MFA and PFA, and “engineered polymers” including, more specifically, polyphenylenesulfide (PPS), polyetherimide (PEI), polysulfone (PSU), polyphenylsulfone (PPSU), polyethersulfone (PES/PESU), polyetheretherketone (PEEK), polyaryletherketone (PAEK), polyetherketoneketone (PEKK), polyetherketone (PEK), or polyolefins such as polyethylene (PE), polypropylene (PP), cyclic olefin copolymer (COC), polycarbonate (PC), polyphenylene ether (PPE), liquid crystal polymer (LCP), polymethyl methacrylate (PMMA), aliphatic or semi-aromatic polyamides (NYLON), and/or combinations of fluoropolymers, perfluoropolymers and any of the aforementioned engineered resins.

[0093] The combination of fluoropolymers, perfluoropolymers and any of the listed engineered resins are examples of suitable thermoplastics that maybe extruded into separators and/or tapes that may functionally be incorporated into the discussed cables as discontinuous shields. The following chart depicts the formulation combining the aforementioned foamed formula in combination with conductive pellets.

Working Examples

[0094] To further illustrate various aspects of the present disclosure, the following working examples are provided. These examples are provided for illustrative purposes only and are not intended necessarily to present optimal practice of the disclosure and/or optimal results that may be obtained by practicing the aspects of the present disclosure.

[0095] Conductive elements were combined with foamable base polymers as described in examples 1-8 in Table 4 below, in a melt compounder and extruded into pelletized form. More specifically, aluminum (Al) pellets marketed under the trade designation Silvet 220-20-E, aluminum flakes marketed under the trade designation K101 (600 micron by 1000 micron rectangular pellets with a 25 micron thickness), stainless steel (SS) pellets marketed under the trade designation STAPA WM REFLEXAL 212/80, and copper powder marketed under the trade designation BR-83 UP COPPER were used as conductive elements. These conductive elements were incorporated into polyolefins and used as the initial carrier for blending into fluoropolymer, and/or engineered polymers. In Examples 1 to 4 chemical foaming agents were added to form foamable discontinuous shielding for use in a support separator, tape separator and/or co-extruded inner jacketing layer.

TABLE-US-00004 TABLE 4 Metal Formulations Indicating Conductive, Formulation for Discontinuous Shields Formulation 1 2 3 4 General Aluminum (Al) Al Flakes Al Flakes & Stainless Steel (SS) Description Pellets Al Pellets Pellets & Al Pellets Specific 75% LDPE 75% LDPE 75% LDPE, 15% 75% LDPE, 15% Recipe & 25% & 25% K101 Al Beki-Shield SIL VET 220-20-E K101 Al Flakes Flakes & GR75/C12-E/6 & Al Pigment 10% SIL VET 10% SIL VET 220-20-E Al 220-20-E Al Pigment Pigment Source SILBERLINE Transmet Transmet BEKAERT & Corporation Corporation & SILBERLINE SILBERLINE Specific 1.0396 1.0861 1.0641 1.0838 Gravity Tensile (psi) 2892 1203 1960 1600 Elongation 55% 46% 64% 109% % Metallic 20% 28% 22%  19% Content Formulation 5 6 7 8 General Al Powder Al Powder & Copper Copper & Al Description SS Pellets Pellets Specific 75% HDPE, 10% 75% HDPE, 10% 75% HDPE & 25% 75% HDPE, 10% Recipe STAPA WM SAPAWM BR-83 UP BR-83 UP REFLEXAL REFLEXAL COPPER COPPER, & 15% 212/80 212/80, & 15% SIL VET Beki-Shield 220-20-E Al GR75/C12-E/6 Pigment Source ECKART ECKART & ECKART ECKART & BEKAERT SILBERLINE Specific 1.0693 1.0782 1.209 1.1149 Gravity Tensile (psi) 2719 3093 2802 3381 Elongation 55% 36% 46%  46% % Metallic 20% 19% 25%  22% Content

[0096] It will be appreciated that a variety of techniques can be used to form the above polymeric compositions. In some embodiments, a base polymer is a fluoropolymer, e.g., PVDF or a perfluoropolymer, e.g., FEP or an engineered polymer, e.g., PEEK, that can be melted by exposure to elevated temperature, e.g., a temperature of at least about 500° F., and electrically conductive inclusions, e.g., metal particles, can be blended in with the melted base polymer. Further, in some embodiments, a chemical foaming agent and/or a nucleating agent can also be blended in the melted base polymer. In most embodiments, the blend can then be pelletized and later extruded for separator tapes, support separator crosswebs and/or inner liners of jackets. For example, an extruder, e.g., a twin-screw extruder, can be used to melt, blend and pelletize the polymer compositions. The design of the extruder can be such that there is sufficient heat and mechanical energy to fully thermally melt the polymer composition with proper distribution and dispersion during mixing for homogeneity, but yet mild enough to keep the processing temperature of the composition compound below that in which foaming occurs. The composition can be strand extruded and pelletized or alternatively formed in an underwater pelletizing process. Furthermore, a mixture of pellets can be used e.g. 1% to 20% foaming additives as previously described and tumble blended with 0.3% to 25% conductive inclusions. The above polymeric compositions can be processed by extrusion to form various articles. For example, in some embodiments, the pellets having both metal inclusions and a chemical foaming agent can be extruded to form conductive cellular articles, i.e., separator tapes, support crossweb separators or a co-extruded jacket layer.

Separators and Tapes

[0097] In one aspect, the present disclosure provides separators, e.g., for use in telecommunications cables, that include a plurality of electrically conductive inclusions, e.g., metal and carbon conductive particles, that are distributed therein to provide shielding of electromagnetic radiation. In some embodiments, such separators can be formed into predefined shapes, e.g., by extrusion via a die. For example, a die with a cross-shaped opening can be used to form an elongated separator that has an elongated cross-shaped form. In other embodiments, the separators can be in the form of flexible tapes extruded on wide width extrusion machinery, for example, 60 inches and subsequently slit into tape rolls, for example, a 1 inch tape, for use in cables, that can be cigarette folded or spiral wrapped onto a typical 4 pair Category 6, 6e, or 6A communications cable.

[0098] While in some embodiments the metal inclusions are distributed substantially uniformly within the body of the separator. In other embodiments, the spatial distribution of the metal inclusions can be non-uniform. By way of example, in some embodiments, the density of the metal inclusions in the proximity of the channel walls of the separator can be greater than the density in the central portion of the separator. As discussed in more detail below, the metal inclusions facilitate shielding the conductors disposed in the channels from one another, thereby minimizing and preferably eliminating cross-talk between conductors. In many embodiments, the separator is particularly effective in lowering the cross-talk in a frequency range of about 1 MHz to about 40 GHz, or in a range of about 1 MHz to about 10 GHz, or in a range of about 1 MHz to about 2 GHz, or in a range of about 1 MHz to about 1.5 GHz between the conductors disposed in neighboring channels. In other embodiments, the support separator and/or tape separator tape is particularly effective in lowering cross-talk in a frequency range of about 500 MHz to about 1 GHz, in a range of about 500 MHz to about 10 GHz, in a range of about 1 MHz to about 40 GHz, in a range of about 1 MHz to about 0 GHz, in a range of about 1 MHz to about 2 GHz, or in a range of about 1 MHz to about 1.5 GHz. These frequency ranges are particularly useful for tape separators and/or traditional mylar (PET)/aluminum foil tapes or in cables used for high speed data transmission. For example, to transmit information through cable at higher bit rates, a higher bandwidth is required which, in turn, requires transmission of signals at higher frequencies. The current data cabling performance requirements are defined by ANS1-TIA-568-C.2. One performance requirement for communications cables is known as “attenuation to crosstalk ratio, far end” (ACRF), which is a measure of how much signal is received at the far end of a given cable as a ratio of the interfering signal induced by adjacent conductor pairs in the cable.

[0099] The cables incorporate the support separators, separator tapes, and other materials according to embodiments of the present disclosure can reduce cross talk at a given frequency, thereby enabling high performance cable properties.

[0100] In some embodiments, certain types of the metal and/or carbon-based inclusions will primarily reflect electromagnetic radiation within a frequency range (e.g., a frequency range of about 1 MHz to about 10 GHz) while the other type of metal inclusions primarily absorb the incident radiation in that frequency range. In this manner, effective shielding of conductors, e.g., twisted-pair wires, housed in foamed discontinuous conductive tape separator and/or foamed discontinuous conductive support separators e.g., crossweb type extruded profiles or tape wrap around the cable, will achieve shielding effectiveness and not require grounding based on the absorption effect within the foamed polymers and the discontinuity.

[0101] In some embodiments, the foamed discontinuous support separator as seen in FIG. 10 and the foamed discontinuous tape support separator as seen in FIG. 11 exhibit an axial DC (direct current) electrical conductivity that is in a range of about 1×10.sup.3 Siemens/meter to about 3.5×10.sup.7 Siemens/meter. Such an axial DC electrical conductivity (o) can be measured between the proximal end and the distal end of the crossweb support separator number by applying a DC voltage (V) between the proximal and distal ends of the crossweb separator, e.g., by employing a voltage source and measuring the DC current (I) flowing axially (i.e., in a direction from the proximal end to the distal end or vice versa) by using a DC current meter. Ohm's law can then be used to determine the DC electrical conductivity according to the following relation:

σ=I/V  Equation #1

where,
σ denotes electrical conductivity,
V denotes DC voltage applied across the separator, and
I denotes DC current flowing through the separator in response to application of the voltage V

[0102] In some embodiments, the separator FIG. 10 or tape FIG. 11, exhibits an AC (alternating current) conductivity (symbol) (defined as the inverse of AC impedance) in a range of about 1×10.sup.3 Siemens/meter to about 3.5×10.sup.7 Siemens/meter for frequencies in a range of about 1 MHz to about 40 GHz. The AC conductivity can be measured by applying an AC voltage axially across the separator (e.g., between the proximal end 20 and the distal end 30) and measuring the AC current through the separator 20 by using an AC current meter. The AC (o) conductivity can then be determined by using the following relation:

σ=I max/V max  Equation #2

where,
σ denotes electrical conductivity
I max denotes the maximum of the measured AC current, and
V max denotes the maximum of the measured AC voltage.

[0103] In some embodiments, the materials used to form the support separator or separator tape can exhibit a sheet resistance in a range of about 1×10.sup.−5 ohms per square to about 1×10.sup.5 ohms per square, or preferably about 10 ohms per square. It will be appreciated that the sheet resistance of a material will change depending on the thickness of the material. For example, sheet resistance (ohms per square) multiplied by the material's thickness in centimeters equals the volume resistivity of the material (ohms-cm). As such, the volume resistivity needed to achieve a given sheet resistance will depend on the thickness of the material in question. For example, a thicker material will provide the same volume resistivity with a less conductive material than a thinner material that is more conductive. As a more specific example, a tape with a thickness of 0.0254 cm (0.010 inches) can have a volume resistivity of 0.254 ohms-cm and a surface resistance of 10 ohms per square. If the thickness of the tape is reduced to 0.0127 cm (0.005 inches), the volume resistivity is reduced by half to 0.127 ohms-cm to achieve the same surface resistance of 10 ohms per square.

[0104] As shown schematically in FIG. 12, a plurality of conductors 84A-D (collectively conductors 84) can be disposed in respective channels 82A-D defined or provided by the separator 10. The conductors can be, for example, twisted pairs of wires. The foamed discontinuous shield support separator and/or foamed discontinuous shield tape (such as that shown in FIG. 9) minimizes, and preferably eliminates, cross-talk between the conductors disposed in different channels. For example, when conductors 84 are used to transmit telecommunications data at rates up to about 100 Gbits/sec, or in a range of about 1 Mbit/sec to about 100 Gbits/sec, or in a range of about 1 Mbit/sec to about 40 Gbits/sec, the metal inclusions 50, e.g., facilitate electromagnetic shielding of the conductors disposed in neighboring channels from one another. The shielding can in turn minimize, and preferably eliminate, the cross-talk between the neighboring conductors at frequencies corresponding to those emitted by the conductors, e.g., frequencies in a range of about 500 MHz to about 1 GHz or frequencies in a range of about 500 MHz to about 10 GHz. And, as shown in FIG. 9, the flexible foamed discontinuous shield tape may alternatively be used to wrap each pair or wrap all of the pairs versus the traditional continuous aluminum mylar shielding that requires grounding.

[0105] While the illustrated separators have a cruciform shaped cross-sectional profile, in other embodiments the separator can have other shapes. Examples of separators are disclosed in US Publication No. 2010/0206609, filed Apr. 6, 2010, entitled “High Performance Support-Separators for Communications Cables Providing Shielding for Minimizing Alien Crosstalk,” US Publication No. 2007/0151745, filed Mar. 2, 2007, entitled “High Performance Support-Separators for Communications Cables,” US Publication No. 2008/0066947, filed Jul. 16, 2004, entitled “Support Separators for Communications Cable,” and U.S. Pat. No. 7,098,405, filed May 1, 2002, entitled, “High Performance Support-Separator for Communications Cables,” the teachings of which are each incorporated herein by reference in their entirety.

[0106] It will also be appreciated by those skilled in the art that the process of extruding the various components of the cables permits extreme flexibility in process techniques and steps. For example, all of the constituents of the polymeric composition (the polymer, talc, citrate, wax (e.g., Aclyn wax), nucleating agents, etc.) can be compounded into each pellet for extrusion. Alternately, a batch of pellets can include some of the constituents (such as the some of the polymer and talc), while another batch of pellets can include others of the constituents (such as some of the polymer and the citrate, the wax (e.g., Aclyn wax) and the nucleating agent), which batches of pellets are mixed in the extruder. Still other alternately, some of the pellets can include different concentrations of one or more constituents so that a wide variety of composition characteristics can be obtained as suitable for the specific application.