Containers for pressurizing a liquid and methods of use thereof
11407575 · 2022-08-09
Assignee
Inventors
Cpc classification
B01F23/23
PERFORMING OPERATIONS; TRANSPORTING
B65D81/3255
PERFORMING OPERATIONS; TRANSPORTING
B01F33/40
PERFORMING OPERATIONS; TRANSPORTING
A23V2002/00
HUMAN NECESSITIES
B01F23/237
PERFORMING OPERATIONS; TRANSPORTING
B01F23/2364
PERFORMING OPERATIONS; TRANSPORTING
B65D81/2053
PERFORMING OPERATIONS; TRANSPORTING
B65D85/72
PERFORMING OPERATIONS; TRANSPORTING
B67D2001/0821
PERFORMING OPERATIONS; TRANSPORTING
B01F35/754251
PERFORMING OPERATIONS; TRANSPORTING
International classification
B65D81/20
PERFORMING OPERATIONS; TRANSPORTING
B67D1/00
PERFORMING OPERATIONS; TRANSPORTING
B01F33/40
PERFORMING OPERATIONS; TRANSPORTING
B65D85/72
PERFORMING OPERATIONS; TRANSPORTING
B65D81/32
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The invention provides containers for pressuring an aqueous liquid with a gas to increase the concentration of the gas in the aqueous liquid. The container employs one or more moveable sections to reduce the accessible volume of the container, e.g., allowing gases such as H2 to become supersaturated within an aqueous liquid.
Claims
1. A container capable of holding an aqueous liquid, comprising: a) a housing comprising a hollow chamber with a first end and a second end, with a longitudinal axis extending therebetween; b) a moveable section configured to reduce an accessible volume of the hollow chamber; and c) a liquid passageway fluidically connected to the hollow chamber; wherein the hollow chamber is separated into two sub-chambers that are fluidically connected; and (i) wherein the two sub-chambers are connected by a first one-way valve and a second one-way valve oriented oppositely or (ii) wherein the two sub-chambers comprise an inner sub-chamber and an outer sub-chamber and the inner sub-chamber is disposed inside the outer sub-chamber.
2. The container of claim 1, wherein the first or second end is sealed with a cover.
3. The container of claim 2, wherein the cover is configured to translate the moveable section.
4. The container of claim 1, wherein the moveable section translates perpendicular to the longitudinal axis or wherein the moveable section translates along the longitudinal axis.
5. The container of claim 1, wherein the two sub-chambers are releasably connected with one or more mating features.
6. The container of claim 1, wherein the moveable section is configured to reduce the volume of one sub-chamber.
7. The container of claim 1, wherein the two sub-chambers comprise the inner sub-chamber and the outer sub-chamber, and the moveable section is connected to a plunger in the inner sub-chamber.
8. A method for pressurizing an aqueous liquid, comprising: a) providing a container of claim 1; b) inserting into the hollow chamber an aqueous liquid and a gas-evolving composition, wherein gas evolves from the gas-evolving composition; and c) forcing evolved gas back into the aqueous liquid.
9. The method of claim 8, wherein step (c) comprises reducing a headspace above the aqueous liquid in the hollow chamber by translating the moveable section.
10. A kit comprising: a) a housing comprising a hollow chamber with a first end and a second end, with a longitudinal axis extending therebetween, a moveable section configured to reduce an accessible volume of the hollow chamber, and a liquid passageway fluidically connected to the hollow chamber; b) a cover for sealing the chamber; and c) an insert for housing dissolvable compositions comprising a liquid permeable membrane configured to permit liquid flow while retaining a solid composition.
11. The kit of claim 10, wherein the moveable section translates perpendicular to the longitudinal axis or wherein the moveable section translates along the longitudinal axis.
12. The kit of claim 10, wherein the cover is configured to translate the moveable section.
13. The kit of claim 10, wherein the hollow chamber is separated into two sub-chambers that are fluidically connected.
14. The kit of claim 13, wherein the two sub-chambers are releasably connected and/or wherein the moveable section is configured to reduce the volume of one sub-chamber and/or wherein the two sub-chambers are connected by a first one-way valve and a second one-way valve oriented oppositely.
15. The kit of claim 14, wherein the two sub-chambers are connected by the first one-way valve and the second one-way valve, and the first one-way valve and the second one-way valve open at a threshold pressure or are user controlled.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1)
(2)
(3)
(4)
(5)
DETAILED DESCRIPTION OF THE INVENTION
(6) The invention provides containers, kits, and methods for pressurizing a liquid, e.g., by reducing headspace above the liquid or reducing accessible volume within a container.
(7) Containers of the invention are advantageous because they allow sufficient space for complete in situ gas evolution inside a sealed container. This allows for the maximum production of a gas, e.g., H.sub.2 from a solid composition, e.g., an effervescent tablet. The containers of the invention are further advantageous in that they allow for the pressurization of a liquid with the gas, allowing for supersaturation of the liquid. The containers can also be designed to maintain pressure inside while liquid is dispensed, e.g., via drinking, to maintain a substantially constant concentration of gas during use.
(8) By having a container with an adjustable headspace, supersaturated levels of a gas, e.g., H.sub.2, can be achieved. These levels are considerably higher than can be achieved by addition of gas to an open container. Pressurized containers are able to retain dissolved gases for longer periods while also allowing for easier transport and shipping. Additionally, a container with minimal headspace is also advantageous in reducing the growth of aerobic microbial agents, enhancing the safety of dissolved gas containing beverage products.
(9) Containers
(10) In general, containers of the invention have at least one chamber for receiving a liquid and a gas that may be evolved inside the container. The containers also allow for a reduction in the accessible volume of a chamber to pressurize a liquid, typically by forcing gas in a headspace into the liquid. These functions may be carried out by a variety of configurations, e.g., as described herein.
(11) A container of the invention includes a housing having a hollow chamber with a first end and a second end. The first and second ends define a longitudinal axis extending therebetween. Containers of the invention include a moveable section that is configured to move within the container, e.g., either along the longitudinal axis or substantially perpendicular to it, to reduce the accessible volume of the hollow chamber. An example of a container with a moveable section that translates along the longitudinal axis is shown in
(12) Containers of the invention can have the first end and/or second end sealed by a releasable cover, or an end may be permanently sealed. Covers for a container can be attached using standard mating features, including friction fit, screw threads, clamps, bayonet fitting, and grooves. Covers can be made of any suitable material, including, but not limited to, metals, polymers, glass, or a combination thereof such that the combination of the material and mating features are sufficient to maintain pressure upon sealing the container. Additionally, the covers may be configured to control the motion of a moveable section of the container by acting as an attachment location. Alternatively, the motion control for a moveable section may be integrated into the exterior of the container.
(13) In certain embodiments of the invention, such as that shown in
(14) In any of the various embodiments, the container may contain a pressure relief system to prevent over-pressurizing the container. The pressure relief system may be a valve, such as a relief valve, safety valve, or rupture disk configured to rupture at a pre-determined pressure. Other pressure relief systems are known in the art. In some cases, a container of the invention may include a mechanism for monitoring the pressure within the sealed container, such as a pressure gauge, e.g., a mechanical pressure gauge, e.g., a Bourdon gauge.
(15) Valves useful for controlling flow between sub-chambers in the present invention include one-way valves (i.e., gas or fluid can only move through the valve in a single direction and not in the reverse direction). The valves can be operated manually, electronically, or can be chosen to open when a threshold pressure is reached, then close when the pressure falls below the threshold value. Exemplary one-way valves for the invention include, but are not limited to, ball valves, diaphragm valves, swing valves, and solenoid valves.
(16) Containers of the invention may have a liquid passageway that is fluidically connected to the hollow chamber to remove liquid from the container. The liquid passageway may be integrated into the exterior of the container, such as the container shown in
(17) Containers of the invention may be lined, e.g., with a material other than that used in the housing. For example, the walls of a chamber may, in full or in part, be made of a flexible material, e.g., a plastic, that allows for deformation to reduce the accessible volume.
(18) Moveable Section
(19) The containers of the invention employ a moveable section for reducing the accessible volume of the chambers(s) of the containers. The moveable section may be configured to translate, e.g., along or perpendicular to the longitudinal axis to reduce the accessible volume of the chamber. The moveable section may be a wall of a chamber or part of a wall of a chamber. Alternatively, the moveable section can compress one or more walls of the container (either reversibly or irreversibly) to reduce the accessible volume. The moveable section may be shaped to contour to either the longitudinal dimension of the container or the latitudinal dimension of the container. The reduction has the effect of forcing gas in the headspace of the container back into the aqueous liquid within the container. Containers may have a moveable section such as the container shown in
(20) In certain embodiments, the position of the moveable section may be releasably fixed within the housing (i.e., the moveable section cannot move once secured), such that it can resist motion from the force of gases pushing back on the moveable section. Examples of mechanisms to secure the position of the moveable section include, but are not limited to, screw, tension-based collets, clamps, or combinations thereof. When the moveable section is a bladder, the moveable section may be secured by a valve. Other mechanisms for securing the position of the moveable section are known in the art.
(21) An exemplary moveable section that forms a mechanical seal within a container is a gasket. Gaskets can be formed into the shape of the container and can be made of any suitable material, including but not limited to, cork, silicone, natural or synthetic rubber, neoprene, polytetrafluoroethylene (PTFE, e.g., TEFLON™), and nitrile. Other gasket materials are known in the art. Alternatively, the moveable section may be made from one material, e.g., the same material as the container, but have its outer perimeter include a gasket material as defined herein.
(22) The moveable section may include a bladder, e.g., toroidal, cylindrical, or one-sided, or other flexible structure. For example, when the chamber includes a flexible portion, a bladder can be inflated, e.g., by mouth or using a pump, to press into the flexible portion and reduce the accessible volume. In another example, the moveable section mechanically constrains a flexible chamber or portion thereof. This mechanical constraint can occur by hand press, an iris, or similar mechanism. A mechanically constrained moveable section can be designed to be deformed into a specific configuration by pressing into it. For example, the moveable section can be segmented in a manner such that it changes shape in response to an applied pressure. Alternatively, the accessible volume of a flexible chamber can be reduced by applying reduced pressure to the inside of the chamber, e.g., by suction of the liquid contents by a user.
(23) The invention also provides containers including a lid and a bottom portion. The bottom portion includes a bottom and side walls, and the lid contains the mechanisms for increasing and relieving pressure, e.g., as shown in
(24) Motion Controls
(25) In order for the accessible volume of the container to be reduced, a moveable section must be operatively connected to an actuator for applying sufficient force to move the moveable section. In certain embodiments, a moveable section may be translated, expanded, or reshaped using any type of force, e.g. mechanical, electrical, pneumatic, or hydraulic. For example, a moveable section may be attached to a shaft which can be linearly translated within the container by the user, e.g., either manually or using a motor. For example, as shown in
(26) In some embodiments, the container has a translatable moveable section for reducing the volume of the container. The translation of the moveable section may be controlled by the motion control as described herein. Additionally or alternatively, the moveable section may be resiliently connected by a material that is capable of providing a restoring force (i.e., when compressed, the material returns to its equilibrium position by providing an equivalent force in the opposite direction of the externally applied force), or the container or moveable section may be connected to a resilient member or a resilient member may otherwise be disposed between the moveable section and the container. This externally applied force may result from the expansion of gas within the container. An example of a container with a moveable section having both a motion control and a resilient member is shown in
(27) Accessible volume reduction may by motion external or internal to the chamber. For example, a motion control may physically press a moveable section into a chamber or may pull a moveable section from inside the chamber. Similarly, bladders or other flexible moveable sections can be moved by an increase or decrease of pressure.
(28) Insert
(29) The invention provides an insert for housing an aqueous liquid-soluble solid composition which produces a gas while dissolving, e.g., a powder. An example of an insert is shown in
(30) A liquid permeable membrane material is configured to allow aqueous liquids and evolved gases to escape while having sufficiently small pores for retaining solid compositions. Liquid permeable membrane materials useful for the invention include, but are not limited to, metal meshes, natural paper fibers (e.g., cellulose or lignin), fabrics (e.g., cotton or linen), polymers (e.g., polyester, PTFE, or polyamide), or combinations thereof. Other liquid permeable membrane materials are known in the art. The membrane material may be substantially non-degradable. Alternatively, the membrane material may be degradable with varying kinetics in order to control the evolution of gas from a solid composition. Inserts with liquid permeable membranes may further include seals, e.g., foils, covering the membranes that are removable prior to use.
(31) The insert may be made of any suitable material which resists degradation in aqueous fluids. Example materials used to make the insert include, but are not limited to, metals, polymers (e.g., PET), glass, or a combination thereof. Other suitable materials are known in the art.
(32) Methods of Use
(33) The invention features methods for pressurizing an aqueous liquid held within a container with a gas also present in the container. In particular, the invention provides a method for reducing the headspace of a liquid within the container using a system of one or more moveable sections within the container upon the dissolution of a gas-evolving solid composition.
(34) An exemplary use for the containers of the invention is for producing a supersaturated solution of molecular hydrogen (H.sub.2) within a consumable beverage. H.sub.2 can be produced in an aqueous solution through the dissolution of a solid composition as is known in the art, for example, in U.S. Pat. No. 9,144,581, which is incorporated herein for reference. H.sub.2 is poorly soluble in aqueous liquids, having a solubility of 0.8 mM, equating to 1.8 ppm at room temperature. Furthermore, when stored in a container, dissolved H.sub.2 will escape the liquid through any headspace within the container.
(35) In one embodiment of the invention, a container of the invention is filled with an aqueous liquid and a solid composition which produces a gas, e.g., H.sub.2. The composition may be an effervescent tablet, such as those previously described in the art referenced herein, or, optionally, can be a loose powder to be contained within an insert described herein. As the solid composition dissolves and H.sub.2 is evolved, the H.sub.2 fills the headspace above the liquid in the container. The accessible volume of the container is reduced by applying a suitable force to translate one or more moveable sections in the container towards the liquid, thereby forcing evolved H.sub.2 gas into the liquid and supersaturating it.
EXAMPLES
Example 1
(36)
(37) The moveable section is connected to the shaft such that the position of the moveable section can be changed along the longitudinal axis of the container and shaft. Furthermore, the moveable section is separated from the end of the container by a resilient member that is able to compress upon application of an applied force, e.g., pressure increase due to evolving gas within a closed system.
(38) The container in
Example 2
(39)
(40) The lower sub-chamber of the container in
Example 3
(41)
(42) The container in
(43) As liquid is drawn from the container, the headspace increases, thereby allowing evolved gas to escape the liquid. To prevent this, the motion control system is configured to translate the moveable section further down the container, allowing the liquid to be re-pressurized with gas and thereby maximizing the concentration of gas within the aqueous liquid.
Example 4
(44)
(45) The liquid permeable membranes are configured such that aqueous liquids can pass through them to contact the solid composition within the insert, facilitating complete dissolution. The liquid permeable membranes are also gas permeable such that all evolved gas from the solid composition can escape into the aqueous liquid.
(46)
Example 5
(47)
(48) To operate the container, the plunger is inserted into the inner sub-chamber. Liquid, e.g., water, is added via the sealable access port. Air can be purged from the inner sub-chamber by pulling out the plunger with the two-way valve open, and then pushing in the plunger with the two-way valve closed. A gas-evolving composition can then be placed in the retention structure, and the sealable access port is closed. With the two-way valve open, gas evolves, and the increase in pressure forces the plunger out of the inner sub-chamber.
(49) Once the gas-evolving composition has ceased producing gas, the two-way valve is closed, and the plunger is pushed down, forcing the contents of the inner sub-chamber into the outer sub-chamber and increasing the pressure inside the container. The increased pressure allows the gas to supersaturate the liquid in the outer sub-chamber. Once supersaturated, pressure is released, either by opening the sealable access port or by opening a separate pressure relief valve. At this point, the liquid can be consumed.
(50) Other embodiments are in the claims.