Thermal spray material

Abstract

Provided is a thermal spray material capable of, when used in a thermal spray operation for repairing a furnace wall of an industrial furnace or for other purposes, maintaining good post-repetition bondability with respect to a target surface to thereby prevent peel-off of a resulting thermally sprayed deposit, and improving initial ignitability while suppressing dust-generating property. The thermal spray material comprised a basic compound comprising at least one of a Ca component and an Mg component, a metal Si powder, and a silica-based or alumina-silica based powder. A content rate of a fraction constituting the basic compound and having a particle size of 0.15 mm or less is 30 mass % or more with respect to 100 mass % of the basic compound, and a content rate of a fraction constituting the metal Si powder and having a particle size of 20 μm or less is from 10 mass % to 25 mass % with respect to 100 mass % of the thermal spray material. Further, (the content rate (mass %) of the fraction constituting the metal Si powder and having a particle size of 20 μm or less, with respect to 100 mass % of the thermal spray material)/(a content rate (mass %) of the fraction constituting the basic compound and having a particle size of 0.15 mm or less, with respect to 100 mass % of the thermal spray material) is from 0.8 to 10, and a content rate of a fraction constituting the metal Si powder and having a particle size of 10 μm or less is 60 mass % or more with respect to 100 mass % of the metal Si powder.

Claims

1. A thermal spray material capable of being sprayed onto a target surface using oxygen or oxygen-containing gas as a carrier gas and melt-adhered to the target surface by means of heat generated based on combustion of a metal Si powder, the thermal spray material containing: a basic compound comprising at least one of a Ca component and an Mg component, in an amount of 4.5 mass % to 20 mass %; a metal Si powder in an amount of 15 mass % to 30 mass %; and one or more refractory powders selected from the group consisting of silica-based powders and alumina-silica based powders, in an amount of 50 mass % to 86 mass %; wherein: a content rate of a fraction constituting the basic compound and having a particle size of 0.15 mm or less is 30 mass % or more with respect to 100 mass % of the basic compound; a content rate of a fraction constituting the metal Si powder and having a particle size of 20 μm or less is from 15 mass % to 25 mass % with respect to 100 mass % of the thermal spray material; (the content rate (mass %) of the fraction constituting the metal Si powder and having a particle size of 20 μm or less, with respect to 100 mass % of the thermal spray material)/(a content rate (mass %) of the fraction constituting the basic compound and having a particle size of 0.15 mm or less, with respect to 100 mass % of the thermal spray material) is from 0.8 to 10; and a content rate of a fraction constituting the metal Si powder and having a particle size of 10 μm or less is 60 mass % or more with respect to 100 mass % of the metal Si powder, and wherein the content rate of the fraction constituting the basic compound and having a particle size of 0.15 mm or less is from 4 mass % to 16 mass % with respect to 100 mass % of the thermal spray material.

2. The thermal spray material as recited in claim 1, wherein (the content rate (mass %) of the fraction constituting the metal Si powder and having a particle size of 20 μm or less, with respect to 100 mass % of the thermal spray material)/(the content rate (mass %) of the fraction constituting the basic compound and having a particle size of 0.15 mm or less, with respect to 100 mass % of the thermal spray material) is from 1 to 3.6.

Description

DESCRIPTION OF EMBODIMENTS

(1) A thermal spray material of the present invention contains: a basic compound comprising at least one of a Ca component and an Mg component, in an amount of 2 mass % to 25 mass % (this basic compound will hereinafter be referred to simply as “the specified basic compound”); a metal Si powder in an amount of 10 mass % to 30 mass %; and one or more refractory powders selected from the group consisting of silica-based powders and alumina-silica based powders, in an amount of 50 mass % to 86 mass %.

(2) As the specified basic compound, a magnesia-based powder or a calcia-based powder is typically used. Specific examples of the magnesia-based powder include one or more selected from the group consisting of a magnesia powder, a magnesia-calcia powder, an MgO—Al.sub.2O.sub.3 based spinel powder, and a magnesia-calcia-silica powder. Specific examples of the calcia-based powder include one or more selected from the group consisting of a calcia powder, a magnesia-calcia powder and a calcia-silica powder. These may be in the form of a sintered powder or may be in the form of a fused powder. Preferably, the magnesia-based powder has an MgO content of 25 mass % or more, and the calcia-based powder has a CaO content of greater than 75 mass %. It is also possible to use, as the specified basic compound, calcium hydrate, magnesium hydrate, calcium carbonate, magnesium carbonate, and magnesium sulfate.

(3) The specified basic compound is prepared such that a content rate thereof is set to be from 2 mass % to 25 mass %. If the content rate is less than 2 mass %, stability of continuous combustion cannot be ensured when a temperature of the target surface is low, so that an obtained thermal spray material becomes inferior in the adherability and the post-repetition bondability. If the content rate is greater than 25 mass %, a content rate of the metal Si powder or the silica-based powder is reduced accordingly so that properties of the metal Si powder or the silica-based powder are impaired. Preferably, the content rate of the specified basic compound is set to be from 4.5 mass % to 20 mass %.

(4) In terms of particle size distribution, the specified basic compound is prepared such that a content rate of a fraction constituting the specified basic compound and having a particle size of 0.15 mm or less is 30 mass % or more, with respect of the entire basic compound. If the content rate of the fraction having a particle size of 0.15 mm or less is less than 30 mass %, an amount of MgO or CaO remaining in a thermally sprayed deposit is increased, so that an obtained thermal spray material becomes inferior in the post-repetition bondability.

(5) As the metal Si powder, it is possible to use a type which is commonly used as a refractory raw material. Specifically, the metal Si powder is prepared such that a fraction constituting the metal Si powder and having a particle size of 20 μm or less is contained in an amount of 10 mass % to 25 mass % with respect to 100 mass % of the thermal spray material. If the content rate of the fraction constituting the metal Si powder and having a particle size of 20 μm or less is less than 10 mass %, an obtained thermal spray material becomes inferior in a combustion-based heat generation (exothermic) property and in the adherability, the post-repetition bondability, and the strength of a thermally sprayed deposit. On the other hand, if the content rate is greater than 25 mass %, an amount of metal Si remaining in a thermally sprayed deposit is increased, so that an obtained thermal spray material becomes inferior in the post-repetition bondability. Moreover, if the content rate of the fraction constituting the metal Si powder and having a particle size of 20 μm or less is greater than 25%, dust generation from the metal Si powder becomes prominent during a thermal spray operation, thereby leading to deterioration in work environment.

(6) The metal Si powder may comprise a fraction having a particle size other than 20 μm or less as in the above fraction. The metal Si powder is prepared such that a content rate thereof is set to be from 10 mass to 30 mass with respect to the entire thermal spray material. If the content rate is less than 10 mass, an obtained thermal spray material becomes inferior in the adherability, the post-repetition bondability, and strength of a thermally sprayed structure, as with the above case. On the other hand, if the content rate of the metal Si powder is greater than 30 mass % with respect to the entire thermal spray material, dust generation from the metal Si powder becomes prominent during a thermal spray operation, thereby leading to deterioration iii work environment, as with the above case.

(7) In terms of particle size distribution, the metal Si powder is prepared such that a content rate of a fraction constituting the metal Si powder and having a particle size of 10 μm or less is 60 mass % or more, with respect to the entire metal Si powder. If the contend rate is less than 60 mass %, it is unable to ensure sufficient initial ignitability. Moreover, if the content rate is less than 60 mass %, an amount of a fraction constituting the metal Si powder and having a particle size of greater than 10 μm is increased, and thus an amount of an uncombusted or unreached part of the metal Si powder is increased, so that the unreached metal Si powder can float in air, causing an increase in dust generation.

(8) Specific examples of the silica-based powder to be used in the present invention include a silica sand powder, a natural quartz powder, a molten silica (silica glass) powder, a silica stone powder, and a refractory powder consisting primarily of the above components. Specific examples of the alumina-silica based powder include agalmatolite, chamotte, clay, flint clay, andalusite, sillimanite, kyanite, and mullite.

(9) In the present invention, one or more refractory powders selected from the group consisting of the above silica-based powders and alumina-silica based powders are contained in an amount of 50 mass % to 86 mass % with respect to 100 mass % of the thermal spray material. If the content rate is less than 50 mass %, an obtained thermal spray material becomes inferior in volume stability of a thermally sprayed deposit, thereby causing deterioration in the post-repetition bondability. On the other hand, if the content rate is greater than 86 mass %, rebound loss during a thermal spray operation is increased, thereby causing deterioration in the adherability.

(10) From a viewpoint of meltability, the particle size of each of the silica-based powders and the alumina-silica, based powders is preferably 2 mm or less. As long as the particle size falls within 2 mm, there is not much difference in terms of the meltability, even when the particle size is limited to 1.5 mm or less or 1 mm or less. More preferably, in a particle size distribution of each of the silica-based powders and the alumina-silica based powders, a content rate of a fraction having a particle size of 0.3 mm or less is adjusted to be from 0 mass % to 15 mass %.

(11) In the thermal spray material of the present invention, “(the content rate (mass %) of the fraction constituting the metal Si powder and having a particle size of 20 μm or less, with respect to 100 mass % of the thermal spray material)/(a content rate (mass %) of the fraction constituting the specified basic compound and having a particle size of 0.15 mm or less, with respect to 100 mass % of the thermal spray material)” (this ratio will hereinafter be referred to as “fine powder ratio”) is adjusted to be from 0.8 to 10. If the fine powder ratio is less than 0.8, the content rate of the fraction constituting the specified basic compound and having a particle size of 0.15 mm or less is excessively increased with respect to the content rate of the fraction constituting the metal Si powder and having a particle size of 20 μm or less, so that an amount of MgO or CaO remaining in a thermally sprayed deposit is increased, so that an obtained thermal spray material becomes inferior in the post-repetition bondability. On the other hand, if the fine powder ratio is greater than 10, the content rate of the fraction constituting the specified basic compound and having a particle size of 0.15 mm or less is excessively reduced with respect to the content rate of the fraction constituting the metal Si powder and having a particle size of 20 μm or less, so that, even when the metal Si powder is combusted and formed as SiO.sub.2, the reaction between the SiO.sub.2 and MgO or CaO in the fine particle fraction of the specified basic compound is not efficiently performed, because an amount of the fine particle fraction of the specified basic compound is excessively small. Thus, an amount of heat generated during a thermal spray operation becomes insufficient, so that an amount of metal Si remaining in a thermally sprayed deposit is increased, thereby causing deterioration in the post-repetition bondability. Moreover, if the fine powder ratio is greater than 10, an amount of the metal Si powder is excessively large, thereby causing worsening of the dust-generating property. Preferably, the fine powder ratio is set to be from 1 to 3.6.

(12) In the thermal spray material of the present invention, a refractory raw material powder other than those described above and other raw material may be used in combination, without impairing an advantageous effect of the present invention. Examples of the other raw material include cements, steelmaking slag and blast furnace slag. For example, these raw materials may be combined within 10 mass %.

EXAMPLES

(13) Table 1 presents Inventive Examples, and Table 2 presents Comparative Examples. Table 1 and Table 2 additionally present evaluation results of the Examples. In Tables 1 and 2, a silica stone powder, chamotte, a magnesia powder, a calcia powder, and a magnesia-calcia powder are used, respectively, as the silica-based powder, the alumina-silica based powder, the magnesia-based powder, the calcia-based powder, and the magnesia-calcia based powder.

(14) TABLE-US-00001 TABLE 1 Inven- Inven- Inven- Inven- Inven- Inven- Inven- Inven- Inven- tive tive tive tive tive tive tive tive tive Exam- Exam- Exam- Exam- Exam- Exam- Exam- Exam- Exam- ple 1 ple 2 ple 3 ple 4 ple 5 ple 6 ple 7 ple 8 ple 9 Thermal Silica-based powder 2 mm or less 65 50 86 75.5 65 55 60 57 70 Spray Alumina-silica based powder 2 mm or less Material Basic Magnesia-based powder 0.5 mm- 5 5 5 5 5 3 7 Compound 0.15 mm Magnesia-based powder 0.15 mm- 10 17 2 4.5 15 20 10 10 3 0 mm Calcia-based powder 0.5 mm- 0.15 mm Calcia-based powder 0.15 mm- 0 mm Magnesia-calcia based powder 0.5 mm-0.15 mm Magnesia-calcia based powder 0.15 mm-0 mm Metal Metal Si powder(45-20 μm) 8 2 4 8 Si Metal Sii powder(20 μm or less) 20 20 10 16 15 20 25 22 20 powder 10 μm or less; 85 mass % Ignition promoter iron powder Content rate of a basic compoung fraction 67 77 100 100 75 80 67 77 30 having particle size of 0.15 mm or less, with respect to 100 mass % of the basic compound Fine powder ratio (metal Si powder fraction 2.0 1.2 5.0 3.6 1.0 1.0 2.5 2.2 6.7 having particle suze of 20 μm or less/basic compound having a oarticle size of 0.15 mm or less) Content rate of metal Si power fraction 85 60.7 70.8 68 85 85 85 62.3 85 having a particle size of 10 μm or less, with respect to 100 mass % of the metal Si powder Evalu- Post-repetition bondability ⊚ ◯ ◯ ⊚ ⊚ Δ ◯ Δ ◯ ation Si remaining in thermally sprayed deposit 4 9 10 8 7 8 10 10 8 (mass %) Initial ignitability ⊚ ⊚ ⊚ ⊚ ⊚ ⊚ ⊚ ⊚ ⊚ Dust-generation performance ⊚ Δ ◯ ⊚ ⊚ ⊚ ⊚ ◯ ⊚ Complehensive evaluation ⊚ Δ ◯ ⊚ ⊚ Δ ◯ Δ ◯ Inven- Inven- Inven- Inven- Inven- Inven- Inven- tive tive tive tive tive tive tive Exam- Exam- Exam- Exam- Exam- Exam- Exam- ple 10 ple 11 ple 12 ple 13 ple 14 ple 15 ple 16 Thermal Silica-based powder 2 mm or less 70 68 72.5 63.6 65 65 Spray Alumina-silica based powder 2 mm or less 65 Material Basic Magnesia-based powder 0.5 mm- 6 4 5 5 Compound 0.15 mm Magnesia-based powder 0.15 mm- 4 16 2.5 10 10 0 mm Calcia-based powder 0.5 mm- 5 0.15 mm Calcia-based powder 0.15 mm- 10 0 mm Magnesia-calcia based powder 5 0.5 mm-0.15 mm Magnesia-calcia based powder 10 0.15 mm-0 mm Metal Metal Si powder(45-20 μm) 6.3 Si Metal Sii powder(20 μm or less) 20 12 25 15.1 20 20 20 powder 10 μm or less; 85 mass % Ignition promoter iron powder Content rate of a basic compoung fraction 40 80 100 67 67 67 67 having particle size of 0.15 mm or less, with respect to 100 mass % of the basic compound Fine powder ratio (metal Si powder fraction 5.0 0.8 10.0 1.5 2.0 2.0 2.0 having particle suze of 20 μm or less/basic compound having a oarticle size of 0.15 mm or less) Content rate of metal Si power fraction 85 85 85 60 85 85 85 having a particle size of 10 μm or less, with respect to 100 mass % of the metal Si powder Evalu- Post-repetition bondability ⊚ Δ Δ Δ ⊚ ⊚ ⊚ ation Si remaining in thermally sprayed deposit 6 8 10 10 3 4 4 (mass %) Initial ignitability ⊚ ⊚ ⊚ ◯ ⊚ ⊚ ⊚ Dust-generation performance ⊚ ◯ Δ Δ ⊚ ⊚ ⊚ Complehensive evaluation ⊚ Δ Δ Δ ⊚ ⊚ ⊚

(15) TABLE-US-00002 TABLE 2 Copparative Copparative Copparative Copparative Copparative Copparative Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Thermal Silica-based powder 2 mm or less 55 78.5 50 58 90 60 Spray Alumina-silica based powder 2 mm or less Material Basic Magnesia-based powder 0.5 mm- 25 Compound 0.15 mm Magnesia-based powder 0.15 mm- 30 1.5 15 15 5 5 0 mm Calcia-based powder 0.5 mm- 0.15 mm Calcia-based powder 0.15 mm- 0 mm Magnesia-calcia based powder 0.5 mm-0.15 mm Magnesia-calcia based powder 0.15 mm-0 mm Metal Metal Si powder(45-20 μm) 5 10 Si Metal Sii powder(20 μm or less) 15 15 25 27 5 10 powder 10 μm or less; 85 mass % Ignition promoter iron powder Content rate of a basic compoung fraction 100 100 100 100 100 17 having a particle size of 0.15 mm or less, with respect to 100 mass % of the basic compound Fine powder ratio (metal Si powder fraction 0.5 10.0 1.7 1.8 1.0 2.0 having particle suze of 20 μm or less/basic compound having a oarticle size of 0.15 mm or less) Content rate of metal Si power fraction #REF! #REF! #REF! #REF! #REF! #REF! having a particle size of 10 μm or less, with respect to 100 mass % of the metal Si powder Evalu- Post-repetition bondability X X X X X X ation Si remaining in thermally sprayed deposit 13 14 15 12 18 15 (mass %) Initial ignitability ⊚ ◯ ◯ ⊚ ◯ ◯ Dust-generation performance ◯ Δ X X X Δ Complehensive evaluation X X X X X X Copparative Copparative Copparative Copparative Copparative Example 7 Example 8 Example 9 Example 10 Example 11 Thermal Silica-based powder 2 mm or less 60 55 62 85 65 Spray Alumina-silica based powder 2 mm or less Material Basic Magnesia-based powder 0.5 mm- 5 18 10 5 Compound 0.15 mm Magnesia-based powder 0.15 mm- 25 2 10 15 10 0 mm Calcia-based powder 0.5 mm- 0.15 mm Calcia-based powder 0.15 mm- 0 mm Magnesia-calcia based powder 0.5 mm-0.15 mm Magnesia-calcia based powder 0.15 mm-0 mm Metal Metal Si powder(45-20 μm) 8 Si Metal Sii powder(20 μm or less) 10 25 10 20 powder 10 μm or less; 85 mass % 15 Ignition promoter iron powder 0.5 Content rate of a basic compoung fraction 83 10 50 100 67 having a particle size of 0.15 mm or less, with respect to 100 mass % of the basic compound Fine powder ratio (metal Si powder fraction 0.4 12.5 1.0 1.0 2.0 having particle suze of 20 μm or less/basic compound having a oarticle size of 0.15 mm or less) Content rate of metal Si power fraction #REF! #REF! #REF! 23.1 85 having a particle size of 10 μm or less, with respect to 100 mass % of the metal Si powder Evalu- Post-repetition bondability X X ◯ ◯ X ation Si remaining in thermally sprayed deposit 10 14 10 8 9 (mass %) Initial ignitability ◯ ◯ X X ⊚ Dust-generation performance ◯ X X X X Complehensive evaluation X X X X X

(16) In a thermal spray apparatus used in an operation of thermally spraying each thermal spray material in the Examples, a nitrogen gas as an inert gas was introduced in a material tank to cope with a risk of combustion of the thermal spray material in the material tank due to backfire from a nozzle tip or the like. The thermal spray material was fed through a table feeder installed at a bottom of the tank, and conveyed by oxygen. In this process, although the inert gas from an inside of the material tank is mixed into the oxygen, it does not hinder ignition and combustion of the thermal spray material because an amount of the mixed inert gas is insignificant.

(17) In each Example, 3 kg of the thermal spray material was sprayed onto a target surface under a condition that a powder supply speed was 50 kg/h; and a distance between the target surface and the nozzle tip was from 50 to 70 mm.

(18) As the post-repetition bondability, bondability between a thermally sprayed deposit and a brick (target surface) was measured after subjecting the thermally sprayed deposit to a repetitive cycle of temperature rising-lowering cycles between 300° C. and 1000° C., 100 times. In this evaluation, a thermal spray material having better post-repetition bondability was evaluated as a higher one of the following four ranks: ⊚ (Excellent), ∘ (Good), Δ (Acceptable) and x (NG). Specifically, when a thermally sprayed deposit was breakingly detached together with the brick as a result of an operation of detaching the deposit by hammering, the thermal spray material was evaluated as ⊚ (Excellent); when no defect in bonding was observed from external appearance, and the thermally sprayed deposit was peeled off from a bonding interface as a result of the operation of detaching the deposit by hammering, the thermal spray material was evaluated as ∘ (Good); when a partially detached portion was observed from the external appearance, the thermal spray material was evaluated as Δ (Acceptable); and when a defect in bonding was significantly observed from the external appearance, the thermal spray material was evaluated as x (NG).

(19) Further, an amount of metal Si remaining in a thermally sprayed deposit bonded to a target surface was evaluated by quantitative analysis.

(20) As to the initial ignitability when ignition was visually confirmed within 5 seconds after start of thermal spray with respect to a target surface, the thermal spray material was evaluated as ⊚ (Excellent); when ignition was visually confirmed in the range of 5 seconds to 10 seconds, the thermal spray material was evaluated as ∘ (Good); when ignition was visually confirmed in the range of 10 seconds to 15 seconds, the thermal spray material was evaluated as Δ (Acceptable); and when ignition was visually confirmed at a time of greater than 15 seconds, or no ignition was confirmed, the thermal spray material was evaluated as x (NG).

(21) As to evaluation on the dust-generation property, when almost no dust generation occurred, and visibility was good, the thermal spray material was evaluated as ⊚ (Excellent); when dust generation slightly occurred, but visibility was good, the thermal spray material was evaluated as ∘ (Good); when dust generation occurred to cause slight deterioration in visibility, but it did not cause difficulty in continuing the thermal spray operation, the thermal spray material was evaluated as Δ (Acceptable); and when dust generation occurred to cause deterioration in visibility and thus difficulty in continuing the thermal spray operation, the thermal spray material was evaluated as x (NG).

(22) Then, as to comprehensive evaluation, when all of the evaluations on the post-repetition bondability, the initial ignitability and the dust generating property were ⊚ (Excellent), and the amount of Si remaining in the thermally sprayed deposit was 10 mass % or less, the thermal spray material was evaluated as ⊚ (Excellent); when the worst evaluation among all of the evaluations was ∘ (Good), and the amount of Si remaining in the thermally sprayed deposit was 10 mass % or less, the thermal spray material was evaluated as ∘ (Good); when the worst evaluation among all of the evaluations was Δ (Acceptable), and the amount of Si remaining in the thermally sprayed deposit was 10 mass % or less, the thermal spray material was evaluated as Δ (Acceptable); and when the worst evaluation among all of the evaluations was x (NG), or the amount of Si remaining in the thermally sprayed deposit was 10 mass % or more, the thermal spray material was evaluated as x (NG).

(23) Each of Inventive Examples 1 to 16 falling within the scope of the present invention was evaluated as Δ or better in the comprehensive evaluation.

(24) In Comparative Example 1 as an example where the content of the magnesia-based powder is excessive, an unreacted part of the magnesia-based power largely remained in a thermally sprayed deposit, and the post-repetition bondability was evaluated as x (NG). The unreacted magnesia-based powder absorbs heat from the metal Si powder without generating heat. Thus, a reactivity of the metal Si powder was deteriorated, and the amount of Si remaining in the thermally sprayed deposit was increased to 10 mass % or more.

(25) In Comparative Example 2 as an example where the content of the magnesia-based powder is insufficient, a reaction between SiO.sub.2 and the magnesia-based powder was insufficient, and the post-repetition bondability was evaluated as x (NG). Moreover, due to the insufficiency of the magnesia-based powder, the amount of Si remaining in the thermally sprayed deposit was increased to 10 mass % or more.

(26) Comparative Example 3 is an example where the content of the metal Si powder in the thermal spray material is excessive, and Comparative Example 4 is an example where the content of the fraction constituting the metal Si powder and having a particle size of 20 μm or less is excessive. In both of Comparative Examples 3 and 4, the post-repetition bondability was evaluated as x (NG), and the amount of Si remaining in the thermally sprayed deposit was increased to 10 mass % or more. Moreover, the dust generating property was also evaluated as x (NG).

(27) In Comparative Example 5 as an example where the content of the metal Si powder is insufficient, the post-repetition bondability was evaluated as x (NG). Moreover, due to inferiority in the post-repetition bondability, an amount of a thermally sprayed deposit adhered to the target surface becomes excessively small, so that the amount of Si remaining in the small amount of thermally sprayed deposit was increased to 10 mass % or more.

(28) In Comparative Example 6 as an example where the content of the fraction constituting the magnesia-based powder and having a particle size of 0.15 mm or less is insufficient, an unreacted part of the magnesia-based power largely remained in a thermally sprayed deposit, and the post-repetition bondability was evaluated as x (NG). Moreover, as with Comparative Example 1, the unreacted magnesia-based powder absorbs heat, so that the amount of Si remaining in the thermally sprayed deposit was increased to 10 mass % or more.

(29) In Comparative Example 7 as an example where the fine powder ratio is less than. 0.8, the post-repetition bondability was evaluated as x (NG). In Comparative Example 8 as an example where the fine powder ratio is greater than 10, the post-repetition bondability was evaluated as x (NG), and the amount of Si remaining in the thermally sprayed deposit was increased to 10 mass % or more.

(30) In Comparative Example 9 as an example where the content rate of the fraction constituting the metal Si powder and having a particle size of 10 μm or less, with respect to 100 mass % of the metal Si powder, is insufficient, the initial ignitability was evaluated as x (NG). Moreover, an amount of a fraction constituting the metal Si powder and having a particle size of greater than 10 μm is increased, and thus an amount of an unreacted part of the metal Si powder is increased, so that the unreached metal Si powder floated in air, causing an increase in dust generation. As a result, the dust generating property was evaluated as x (NG).

(31) Comparative Example 10 is also an example where the content rate of the fraction constituting the metal Si powder and having a particle size of 10 μm or less, with respect to 100 mass % of the metal Si powder, is insufficient. A difference from Comparative Example 9 is as follows: In Comparative Example, a fraction constituting the metal Si powder and having a particle size of greater than 20 μm to 45 μm is contained in an amount of 8 mass %, and thereby the content rate of the fraction constituting the metal Si powder and having a particle size of 10 μm or less becomes less than 60 mass %, whereas, in Comparative Example 10, although the entire metal Si powder has a particle size of 20 μm or less, the metal Si powder having a particle size of 20 μm or less comprises a fraction having a particle size of 10 μm or less, in an amount of only 30 mass %, and thereby the content rate of the fraction constituting the metal Si powder and having a particle size of 10 μm or less becomes less than 60 mass %. In Comparative Example 10, the initial ignitability was evaluated as x (NG), and the unreached metal Si powder floated in air, causing an increase in dust generation. As a result, the dust generating property was evaluated as x (NG), as with Comparative Example 9.

(32) In Comparative Example 11 as an example where an iron powder was added as an ignition promoter, according to the aforementioned Patent Document 3, a low-melting-point substance was formed by the iron powder, and an expansion characteristic was largely changed due to the low-melting-point substance, so that the post-repetition bondability was evaluated as x (NG). Moreover, due to an oxidation reaction of the iron powder, reddish brown dust was generated, so that the dust generating property was also evaluated as x (NG).