A WATER FILTRATION DEVICE

Abstract

A filter to remove contaminants from potable water. The filter comprises a plurality of porous layers 15,16 forming a fluid path for the water to pass sequentially from the first layer 16 through the layers to the final layer. The first layer 16 is formed of a ceramic and/or sintered material and includes a virucide. Said first layer 16 is distinguishable from an adjacent second layer 15, wherein at least one of the first and second layers 16, 15 comprises a dye material.

Claims

1. A filter to remove contaminants from potable water, the filter comprising a plurality of porous layers forming a fluid path for the water to pass sequentially from the first layer through the layers to the final layer, wherein the first layer is formed of a ceramic and/or sintered material and includes a virucide and further that said first layer is distinguishable from an adjacent second layer, wherein one or both of the first and second layers comprises a dye material.

2. A filter as claimed in claim 1, wherein the filter is a tubular filter candle, a flat sheet, disc or sphere.

3. A filter as claimed in claim 2, wherein the second layer is also formed of a ceramics material.

4. A filter as claimed in claim 3, wherein the second layer includes a bactericide.

5. A filter as claimed in claim 1, wherein the first and second ceramic/sintered layers have a mean pore size of from 0.6 to 1.1 μm, preferably 0.7-1.0 μm.

6. A filter as claimed in claim 1, wherein the mean pore size of the first layer is equal or greater than that of the second layer.

7. A filter as claimed in claim 1, wherein a third layer is formed of carbon.

8. A filter as claimed in claim 7, wherein the third layer is in the form of a hollow cylinder, open at both ends.

9. A filter as claimed in claim 1, wherein the virucide is the virucide “Biocoat”™.

10. A filter as claimed in claim 1, wherein the layers are formed into a cylindrical filter body.

11. A filter as claimed in claim 10, wherein the cylindrical filter layers are housed at a first end in a first end-cap.

12. A filter as claimed in claim 11, wherein the first end-cap includes one or more channels defined by channel walls.

13. A filter as claimed in claim 12, wherein cylindrical filter layers are housed at a second end by a second end-cap.

14. A filter as claimed in claim 13, wherein a second end-cap including one or more channel, defined by channel walls.

15. A filter as claimed in claim 14, wherein a resilient layer is provided between the carbon layer arid the second end-cap.

16. A filter as claimed in claim 1, wherein the material of the first and second ceramic layers interpenetrate each other.

17. A filter as claimed in claim 1, further comprising an outlet adjacent the final layer, wherein water passing through the final layer exits the filter through the outlet.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0022] The invention is illustrated with respect to the accompanying drawings which show, by way of example only, two embodiments of the filter. In the drawings:

[0023] FIG. 1 illustrates diagrammatically a filter candle in accordance with a first embodiment of the invention;

[0024] FIG. 1a illustrates diagrammatically a filter candle in accordance with a second embodiment of the invention;

[0025] FIG. 2 is a perspective view of the first embodiment of the invention;

[0026] FIG. 3 is a perspective view of a third embodiment of the invention;

[0027] FIG. 4 is a longitudinal section through the filter candle of FIG. 2;

[0028] FIG. 5 is a longitudinal section through the filter candle of FIG. 3;

[0029] FIG. 6 is a perspective view of the filter candle of FIG. 3;

[0030] FIG. 7 is a longitudinal section through the filter candle of FIG. 6;

[0031] FIG. 8 is a section through the inner and outer ceramic layers;

[0032] FIG. 9 is an electron micrograph of the site marked ‘X’ in FIG. 8; and

[0033] FIGS. 10 and 11 illustrate use of a filter candle in accordance with an embodiment of the invention.

DETAILED DESCRIPTION OF THE INVENTION

[0034] The requirement to filter chemicals along with viruses and small organisms from water being supplied for domestic usage is becoming increasingly important. Although in most first world countries the domestic water supply is supposed to comply with defined legal standards concerning materials dissolved or suspended therein, such standards are not always met, either on a temporary basis (due to malfunction of a cleaning system) or also because of systemic deficiencies in a purification plant due to lack of competence or lack of effective public oversight of the process. In non-first world countries, the risk of drinking unsuitable water is even greater. Many people choose therefore to install their own purification systems, at the point of drawing off the water from the mains supply. This provides them with greater control over the water they drink, but increases the maintenance they personally need to undertake.

[0035] There are many systems of varying effectiveness, available for carrying this out, such as the use of magnetic fields disposed about a pipe, beads to remove unwanted salts etc. The present invention contemplates a different system involving a filter, a non-limiting example of which is often referred to as a candle, and which is figuratively illustrated in FIG. 1. Alternative shapes of filter, such as flat sheets or discoid or spherical filters, are also contemplated.

[0036] FIG. 1 is an exploded view of a filter candle 10, which Figure shows the main component parts. The assembled candle 10 is shown in FIG. 2 and is designed and placed within the water stream such that the water flows from the outside of the candle 10, passing through the different layers discussed below, before exiting through the outlet 11 as shown by arrow A. The different layers are structured and assembled together that the water has to pass through each before it can exit. In this manner therefore, all the water is treated by each layer, ensuring that unwanted constituents are removed.

[0037] In broad outline therefore, the candle 10 comprises a central, generally cylindrical filter element 12 formed of carbon banded to a first end-cap 13 in a fluid tight manner along a first edge, with the hollow core of the element 12 being fluidly connected to the outlet 11 of the end-cap 13. Surrounding the element 12 is an inner ceramic/sintered layer 15, which is also bonded at one end to the first end-cap 13 in a fluid-tight manner. An outer ceramic/sintered piece comprising an outer ceramic/sintered sacrificial layer 16 surrounding the inner layer 15 which optionally may surround, where applicable, either a further working or structural layer, is again bonded at one end, in a fluid-tight manner to the first end-cap 13. In general terms the element 12 acts to filter out microorganisms as well as soluble chemicals from the water supply such as heavy metals, organic chemicals, pesticides and herbicides, pharmaceuticals etc. The inner ceramic/sintered layer 15 comprises either a separate bespoke ceramic or sintered material which acts to filter out microorganisms and/or a specific chemical or group of chemicals or acts purely as a structural agent to support the outer two layers.

[0038] The inner ceramic/sintered layer 15 has a pore size which is sufficiently small to prevent bacteria and viruses and particles of a similar size from passing therethrough. The outer ceramic layer 16 has a pore size equal to or greater than those present in the inner ceramic layer 15, which are sufficiently small to prevent the passage of viruses.

[0039] It can be seen therefore that the three layers, including the carbon layer 12, will combine together to remove most unwanted impurities from the water.

[0040] In the embodiment of FIG. 2, the end 20 of the candle 10, distal to the first end-cap 13 is formed of the ceramic materials of the inner and outer ceramic/sintered layers, 15, 16 and is co-extensive therewith to close off the end of the candle 10.

[0041] In more detail, the inner and outer ceramic layers 15, 16 are porous in nature, having a mean pore size as measured by mercury porosity, of from 0.6 to 1.1 μm, preferably 0.7-1.0 μm. The mean pore size of the outer ceramic layer 16 is preferably equal or greater than that of the inner ceramic layer 15. The proportion of lower size to higher size pores needs to be controlled as pores of smaller size are more easily blocked and also resist more strongly flow of water through the pores.

[0042] As exemplified thicknesses of the inner and the outer ceramic layers 15, 16, under normal operation of a candle and a water pressure of 2.4 bar (240 kPa) to give a flow rate of 2.5 l/min, then the inner ceramic layer is from 4.6 mm in thickness and preferably 4.5-5.5 mm and further preferably 4.9-5.1 mm. The outer ceramic layer 16 is usually thinner than the inner ceramic layer 15 for the reasons stated above with a thickness of 4 mm, preferably 3.5 mm, further preferably <3.0 mm.

[0043] To improve the virucidal properties of the inner and outer ceramic layers 15 and 16, a biocide such as a virucide is included within the ceramic material of the outer ceramic/sintered layer 16. An example of a suitable biocide is Biocoat™. An advantage of there being a filter element 12 formed of carbon is that the use of a biocide can be confined to the ceramic component to minimise the risk that the biocide might seep more easily into the water being purified.

[0044] Additionally, the outer ceramic layer 16 is provided with a feature which enables the outer ceramic layer 16 to be readily visually distinguished from the inner ceramic layer 15.

[0045] As the candle 20 is used it will require cleaning from time to time on the outside, using an abrasive cleaner. This cleaning is carried out to remove contaminant particulate material which becomes caught in the outer pores and thus prevents flow of liquid through the outer ceramic layer 16 and also provides surface area and nutrients to support microbial growth, which is obviously undesirable. As such, each time the contaminant is removed a layer of the outer ceramic layer 16 is also abraded and over time the thickness of the outer ceramic layer 16 becomes reduced. Enabling the layers 15, 16 to be visually distinguished allows a ready check to be carried out as to whether the candle needs to be replaced.

[0046] FIGS. 6 and 7 illustrate a second embodiment of a filter candle 70. This embodiment has the advantage of providing a higher surface area of a porous nature. The candle 70 is generally cylindrical having an end-cap 71, including outer and inner walls 72, 73 to frictionally engage the ends of the inner and outer ceramic layers 15, 16. This embodiment of candle 70 can be of larger dimensions than those of the first embodiments.

[0047] Further end-cap 81, similarly to the end-cap 13 of the first embodiment, has outer and inner retaining walls 82, 83 to form a channel 84 which retains the inner and outer ceramic layers 15, 16 of the candle 70. End cap 81 is further provided with an outlet 86 through which filtered liquid exits the candle 70.

[0048] FIGS. 3 and 5 illustrate a third embodiment of a filter candle 30. The candle 30 is generally cylindrical having an end-cap 31, including outer and inner walls 32, 33 to frictionally engage the ends of the inner and outer ceramic layers 15, 16. This embodiment of candle 30 can be of larger dimensions than those of the first embodiment.

[0049] Further end-cap 34, similarly to the end-cap 13 of the first embodiment, has outer and inner retaining walls 35, 36 to form a channel 37 which retains the inner and outer ceramic layers 15, 16 of the candle 30. End cap 34 is further provided with a threaded outlet 38 through which filtered liquid exits the candle 30.

[0050] A dye is be incorporated into one or both layers, 15, 16 to distinguish them. Several additional alternatives are also available to allow the layers 15, 16 to be distinguished. To reduce costs, then only one of the layers 15, 16 is dyed. Once the outer ceramic layer 16 has been worn away, the inner ceramic layer 15 will show through, since it is a different colour, to provide the required indication that a new filter is needed. The outer ceramic layer 16 will need changing after a number of cleaning cycles. Alternatively, a layer 15, 16 can be dyed to given a patterned configuration, either by altering the structure of a layer and/or including pigmentation.

[0051] The inner ceramic layer and outer ceramic layer 15, 16 are preferably held in contiguous relationship to aid water transfer between the two layers.

[0052] Further preferably, the two layers interpenetrate each other, which can be achieved for example by forcing the two layers together whilst their engaging surfaces are still wet, thus giving an indistinct boundary layer once the water is removed. Alternatively or additionally, the inner ceramic layer and outer ceramic layer 15, 16 can be formed together using a multi-stage, variable pressure, high pressure casting process. The advantage of the interpenetration is that there is then a reduced tendency for the inner ceramic layer and outer ceramic layer 15, 16 to crack or split, something which would lead to failure of the filtration unit. The interpenetration can be seen from FIGS. 8 and 9. FIG. 8 shows a section through a ceramic wall material, and the distinguishing colours of the inner ceramic layer 15 and outer ceramic layer 16 can be seen. A marker ‘X’ 60, indicates the position at which the electron micrograph of FIG. 9 (x310) is taken, on the line joining the two layers 15, 16. It can be seen that there are no features to readily define a ‘border’ between the layers 15, 16, other than the colour difference (not shown in FIG. 9), and that they are intermixed.

[0053] The inner ceramic layer 15 and the element cylinder 12 are optionally held in spaced relationship to each other. Without being bound to theory, it is believed that a gap helps the water to flow out more evenly given the irregular structure of the inner ceramic layer 15 and the central element.

[0054] The compositions of the ceramic materials from which the inner ceramic layer 15 and the outer ceramic layer 16 can be formed are set out below in Tables 1 and 2.

TABLE-US-00001 TABLE 1 Constituents of inner ceramic layer Constituents Amounts (% w/w) Diatomaceous earth 27-31 Silver powder 0.01-0.02 Ball clay  3.7-6.10 Dispex (RTM) 0.005-0.009 Quartz 1.00-1.5  Water 68.28-61.37 Total 100%

TABLE-US-00002 TABLE 2 Constituents of outer ceramic layer Constituents Amounts (% w/w) Diatomaceous earth 26.00-29.00 Biocoat (RTM) 0.04-0.06 Blue stain 4.00-6.00 Ball clay 3.50-5.90 Dispex (RTM) 0.0050-0.0090 Quartz 0.910-1.4  Water 65.55-57.63 Total 100%

[0055] In the above, Dispex® is a polyacrylate polymer, typically based on the monomer ammonium acrylate.

[0056] Utilising the above arrangement, then the following reductions in harmful materials have been achieved for 4000 l feed of water.

TABLE-US-00003 TABLE 3 Reduction in microorganism contaminant Contaminant Reduction (%) at 3000 litres Klebsiella terrigena >99.9999 Cryptosporidium spp. >99.9 Rotavirus spp. >99.9

TABLE-US-00004 TABLE 4 Reduction in contaminant heavy metals Influent Challenge Reduction Metal contaminant (μg/l) (%) Aluminium 3185.0 >99.9 Arsenic (5+) 50.2 93.8 Cadmium 30.2 >99.9 Chromium 30.4 >99.7 Copper 3059.0 99.3 Lead 152.0 >99.9 Mercury 6.1 >99.9 Thallium 6.0 >99.9

TABLE-US-00005 TABLE 5 Reduction in inorganic contaminant Influent Challenge Reduction Inorganic contaminant (μg/l) (%) Chlorine (free) 2150 >99.9 Chloramine 3100 >99.9 Chloride 820000 96.6 Nitrate 27000 95.6 Nitrite 3000 >99.9

TABLE-US-00006 TABLE 6 Reduction in volatile and semi-volatile organic contaminant Volatile and semi-volatile Influent Challenge Reduction organic contaminant (μg/l) (%) Vinylchloride 43.23 >99.8 Carbon tetrachloride 88.50 >99.9 Benzene 80.50 >99.9 1,1-trichloroethane 84.8 >99.9 Toluene 78.30 >99.9 Styrene 150.00 >99.9 2-chlorotoluene 10.08 >99.9 2,3-dichlorobenzene 80.20 >99.9 Naphthalene 160.20 >99.9 Ethylene dibromide (EDB) 44.80 >99.9 Bromoacetonitrile 22.00 >99.9 anthracene 49.8 >99.9 Fluorene 47.9 >99.9 Hexachlorobenzene 50.2 >99.9 Phenol 50.9 >99.9 Nitrobenzene 48.3 >99.9 4-nitrotoluene 47.5 >99.9 Diethylphthalate 49.2 >99.9 Pyrene 49.7 >99.9

TABLE-US-00007 TABLE 7 Reduction in pesticide and herbicide contaminant Pesticide/herbicide Influent Challenge Reduction contaminant (μg/l) (%) Chlorothalonil 51.2 >99.9 chloropyrifos 50.6 >99.9 2,4-D 50.1 >99.9 Glyphosphate 804.2 >99.9 p,p-DDT 60.5 >99.9 Dichlorvos 52.3 >99.9 Aldrin 46.8 >99.9

TABLE-US-00008 TABLE 8 Reduction in pharmaceutical contaminant Influent Challenge Reduction Pharmaceutical contaminant (μg/l) (%) Ibuprofen 0.45 >99.9 Caffeine 1.82 >98.9 Testosterone 1.44 >99.9 Progesterone 2.08 >99.9 Trimethoprim 2.20 >99.9 Acetaminophen 2.42 >99.2 Diclofenac Sodium 1.90 >99.9 Carbamazepine 1.43 >99.9

[0057] In use therefore, a device in accordance with the above described embodiments is inserted between a mains supply and a user. For example, FIGS. 10 and 11 illustrate a means of utilising the invention. Here, a device 90 is shown, which in use is housed within the casing 91. The casing 91 is connected to the tap 92 by a specially adapted connector 93 and a flexible tube 94. The device 90 is inserted into an aperture (not illustrated) within the casing 91. The aperture is fluidly connected to the outlet 95.