YANKEE DRIER AND METHOD FOR MANUFACTURING A YANKEE DRIER
20220081835 · 2022-03-17
Assignee
Inventors
- Francesco Simoncini (San Lorenzo a Vaccoli, IT)
- Giulia Masia (Fornacette, IT)
- Gaetano Passanisi (Capannori, IT)
- Luca GHELLI (Torino, IT)
- Leonardo Micheli (Bagni di Lucca, IT)
- Jacopo Bibbiani (Pisa, IT)
- Alessandro Piccinocchi (Pisa, IT)
- Stefano Marenco (Pinerolo, IT)
Cpc classification
International classification
Abstract
A Yankee drier including a cylindrical mantle to which two end heads are connected, on each of which a corresponding pin is arranged, wherein the cylindrical mantle has an external surface and an internal surface, and wherein the internal surface of the mantle in cooperation with the lateral heads delimits an internal chamber of the Yankee drier in which steam can be introduced. The internal surface of the mantle is at least partially provided with a surface protective coating, the surface protective coating protecting the internal surface of the mantle from corrosive and/or abrasive agents contained in the steam introduced into said chamber.
Claims
1-16. (canceled)
17. A steel Yankee drier comprising: a cylindrical mantle to which two end heads are connected, on each of which a corresponding pin is arranged, wherein the cylindrical mantle has an external surface and an internal surface, and wherein the internal surface of the mantle in cooperation with the end heads delimits an internal chamber of the Yankee drier in which steam can be introduced, wherein the internal surface of the mantle is at least partially provided with a surface protective coating, the surface protective coating protecting the internal surface of the mantle from corrosive and/or abrasive agents contained in the steam introduced into said chamber.
18. The Yankee drier according to claim 17, further comprising one or more of: the surface protective coating has a degree of porosity defined by a percentage quantity of air or impurities in the volume unit of the protective coating itself lower than 10%; the surface protective coating resists to variations in length of the substrate constituted by the internal surface of the mantle in excess of 1%, without being cracked or detached; the protective surface coating has a thermal conductivity coefficient higher than 3 w/m*K; the surface protective coating has a thickness of less than 200 microns; the surface protective coating causes an increase in the thermal resistance of the substrate on which it is applied not more than 10%, with respect to the thermal resistance of the substrate without the surface protective coating; the surface protective coating has a hardness, measured at room temperature of 25° C., greater than 350 HV.
19. The Yankee drier according to claim 17, further comprising a metallic coating or has metallic elements dissolved in a non-metallic matrix, such that it has a high coefficient of thermal conductivity.
20. The Yankee drier according to claim 17, wherein the surface protective coating consists of a Ni—P alloy.
21. The Yankee drier according to claim 17, wherein the internal surface of the mantle is provided with circumferential grooves and the surface protective coating is applied on the circumferential grooves.
22. The Yankee drier according to claim 17, wherein the internal surface of the mantle is smooth.
23. A method for manufacturing a steel Yankee drier comprising a cylindrical mantle to which two end heads are connected, on each of which a corresponding pin is arranged, wherein the cylindrical mantle has an external surface and an internal surface, and wherein the internal surface of the mantle in cooperation with the end heads delimits an internal chamber of the Yankee drier in which steam can be introduced, wherein a surface protective coating is at least partially formed on the internal surface of the mantle by introducing a predetermined amount of a nickel bath in a volume delimited in a radial direction by the internal surface of the mantle, followed by a permanence of the bath in said volume for a predetermined time, the surface protective coating protecting the internal surface of the mantle from corrosive and/or abrasive agents contained in the steam introduced into said chamber.
24. The method according to claim 23, wherein said volume is subjected to rotation around a longitudinal axis of the mantle during the formation of the surface protective coating.
25. The method according to claim 24, wherein said rotation is continuous or intermittent.
26. The method according to claim 23, wherein the nickel bath comprises NiSO4 and NaH2 PO2 and determines the formation of the surface protective coating in accordance with the following reaction: H2PO2−+Ni2++H2O.fwdarw.Ni+2H++H2PO3−.
27. The method according to claim 23, wherein the nickel bath is at a temperature comprised between 60° C. and 90° C.
28. The method according to claim 23, wherein the nickel bath is preheated outside the mantle (15) before being inserted in the latter.
29. The method according to claim 23, wherein, during its permanence in said volume, the nickel bath is subjected to mixing.
30. The method according to claim 23, wherein the volume delimited radially by the mantle (15) is a volume which is axially delimited by caps temporarily applied to the mantle or by the heads of the Yankee drier.
31. The method according to claim 23, wherein the mantle is put into rotation around its own axis longitudinally by of rollers which transmit a rotary motion to the mantle by acting externally to the latter.
32. The method according to claim 23, wherein the mantle is made of steel and the heads are welded or bolted to the mantle.
Description
[0027] These and further advantages and characteristics of the present invention will be more and better understood by the skilled in the art thanks to the following description and the attached drawings, provided by way of example but not to be considered in a limiting sense, in which:
[0028]
[0029]
[0030]
[0031]
[0032]
[0033]
[0034] The Yankee drier shown in
[0035] The steam passes from the tubular inner chamber (3) to the annular external chamber (4), delimited by the internal surface (1) of the mantle (15) and the external surface of the tie rod (12), through holes (5) provided on the surface of the latter.
[0036] In operation, the paper (7) adheres to the external surface (11) of the mantle (15). The paper covers the most part of the mantle surface along the width of the latter, leaving uncovered only the connection areas between the end heads (13, 14) and the mantle (15). The part of the steel mantle comprised between the internal surface (1) and the paper (7) is the part through which takes place the most part of thermal exchange originating from the heat introduced through the steam. The heat transmission causes the steam to condensate. The condensate (C), due to centrifugal force, tends to accumulate on the radially outermost parts of the internal surface (1) of the mantle (15).
[0037] Typically, the Yankee driers have circumferential grooves (8) formed on the internal surface of the mantle (15). Said grooves have a dual function: to increase the heat exchange surface increasing the thermal efficiency of the system and collecting the condensate that concentrates on the bottom of the same grooves. The condensate extraction system (not shown) is typically composed of a series of tubes placed with their respective ends at a predetermined distance from the bottom of the grooves (8). The steam is generally introduced in a larger amount in relation to the amount strictly required, such that not all the steam is subjected to condensation and a certain amount of steam is used as a carrier for removal of the condensate. Therefore, through the tubes of the condensate extraction system is removed thanks to the excess of steam.
[0038] In
[0039] The present invention also applies to Yankee driers made in a different way like, for example, Yankee driers made as shown in
[0040]
[0041] A further configuration is shown in
[0042]
[0043] In the drawings, the protective coating (9) is generally represented by a thicker line.
[0044] The following description provides a possible way of applying the protective coating and involves the so-called high phosphorus nickel plating. Compared to other techniques for forming protective coatings on metal bodies, it provides the following advantages: [0045] it is possible to realize a metal protective coating having a higher thermal conductivity compared to spraying or metallization; [0046] high phosphorus nickel plating implies a high adhesion to surfaces of different nature; [0047] nickel is typically a highly ductile metal suitable, therefore, to tolerate high deformations without being damaged; [0048] high phosphorus nickel plating allows deposition of protective coatings having a very low thickness (a few micrometers). The high thermal conductivity, however, allows the formation of thicker protective coatings (typically within 100 micrometers) without negatively affecting the thermal exchanges; [0049] It is possible to obtain a high surface hardness (higher than 350 HV measured at room temperature) which implies a higher resistance to the possible erosion due to the entrainment of hard particles by the flows of the condensate extracted from the drier.
[0050] Nickel plating is an auto-catalytic process allowing the deposition of a Nickel-Phosphorus alloy layer on a metal substrate.
[0051] The nickel is used in solution in solution in the form of salts thereof (NiSO.sub.4) and then precipitates thanks to its chemical reduction. The reducing agent is identifiable in the hypophosphite ion (H.sub.2PO.sub.2) present in the nickel bath as sodium hypophosphite (NaH.sub.2PO.sub.2). The speed at which the alloy is deposited and the phosphorus content depend on the amount of phosphite and hypophosphite in the nickel bath.
[0052] The process described above is represented by the flowing equation:
H.sub.2PO.sub.2+Ni.sub.2—H.sub.2O-->Ni+2H+H.sub.2PO.sub.3−
[0053] The thickness of the Ni—P alloy deposited according to this technique is very uniform on all points of the surface to be coated and depends on the time of contact with the bath. By this process it is generally possible to treat pieces having a relatively complex geometry, realizing a protective coating having a uniform thickness over the entire surface of the treated pieces. A further advantage of the nickel plating is that the protective coating is sufficiently hard and resistant to corrosion in relation to its application to the manufacturing of Yankee driers.
[0054] The metallurgical properties of the deposited protective coating are function of the phosphorous content. According to the phosphorous content three categories can be defined: [0055] low phosphorous content alloys (P comprised between 2% and 4%); [0056] medium phosphorous content alloys (P comprised between 5% and 11%); [0057] high phosphorous content alloys (P comprised between 11% and 14%);
[0058] A high phosphorous content alloys is preferred for realizing a protective coating by chemical nickel plating in accordance with the present invention: such a protective coating will exhibit, in fact, higher corrosion resistance and ductility that are suitable for this specific application.
[0059] Typically, chemical nickel coating is implemented by immersing the component to be coated in a chemical bath having a given chemical composition, at a predetermined temperature and a given degree of turbulence.
[0060] In accordance with the present invention, there is a need to coat only the internal surface of the Yankee drier. Yankee driers are extremely larger than components normally subjected to chemical nickel plating. To this end, it is useful to consider that the most compact Yankee driers have a minimum diameter of 2-3 m and a width of 3 m; larger Yankee driers can have a diameter exceeding 6-7 m and a width higher than 6 m. Since Yankee driers are pressure vessels subjected to fatiguing stress, the thickness of the structural parts is high, therefore their weight can easily exceed tens of tons (the bigger Yankee drier can have a weight of more than 150 tons). Nickel plating by immersion of objects having such a size would be a very complex operation because it would require the immersion of the Yankee drier, or at least the mantle, in a enormous tank completely filled with a nickel bath. Such an approach would involve a number of drawbacks that would reduce its convenience. In fact, the tank would have to be of such dimension to contain the Yankee drier, special supports for supporting the Yankee drier inside the Yankee drier would be required, and a large amount of nickel bath would be required for at completely covering the Yankee drier or partially covering the latter providing means for ensuring the contact of the bath with all surfaces to be coated.
[0061] The purpose of the protective coating according to the present invention is the protection of internal surfaces of the Yankee drier, i.e. surfaces coming into contact with steam and forming condensate, while the coating of other surfaces of the Yankee drier, where the absence of condensate eliminates the risk of oxidation and corrosion, is not required.
[0062] The complete immersion of the Yankee drier in the nickel bath, as normally occurs for smaller components, would inevitably lead to the coating of all surfaces in contact with the bath, including those surfaces for which a protective coating is not required. In the context of the present invention, this would imply unnecessary additional costs since the formation of protective coating implies consumption of nickel and phosphorus contained in the nickel bath. In addition, some of the surfaces coated by the protective coating following a total immersion of the Yankee drier in the nickel bath should be brought back to their non-coated state. This further process step would concern, in particular, the external surfaces of the Yankee drier that must be metallized and, in particular, the surfaces that delimit welds to be made in the subsequent manufacturing step. For example, if the mantle is immersed in the nickel bath before connecting the end heads to the mantle and a welded connection between these parts is required, the surfaces provided for the subsequent welds should be further machined to eliminate the nickel-phosphorus coating, due to the presence of phosphorus that, once dissolved in the welding substances normally used, would cause unacceptable welding defects and impurities. In addition, the chemical reaction producing the formation of the protective coating requires heating of the nickel bath at a given minimum temperature. Indicatively, the reaction activates when the nickel bath temperature is above 60° C. A large amount of nickel bath would require heating means capable of transmitting large quantities of heat, with large energy loss, in order to reach the required temperature in a reasonable time. Moreover, a large tank for immersing the mantle in the nickel bath would have large containment surfaces and, therefore, would imply large thermal losses and additional heat for maintaining the required temperature over the time needed for completing the coating process.
[0063] Thus, in summary, the technique normally adopted in industrial chemical nickel-plating processes would imply great technological/engineering difficulties to obtain the coating of a large component like a Yankee drier. Furthermore, excessive amounts of nickel and phosphorus would be used for coating surfaces that do not require coating. Further economic inefficiencies would derive from the thermal energy required to heat an unnecessarily large nickel bath.
[0064] The example described below provides a method for using a chemical nickel-plating technique optimized for the internal surfaces of a Yankee drier.
[0065] The concept on which the following example is based is that the protective coating is not provided by immersing a Yankee drier in a nickel bath but it is provided by using the internal surface of the Yankee drier as a container for the nickel bath.
[0066] According to the preferred embodiment of a method for forming a protective coating as shown in
[0067] Once the caps (12, 13) are mounted, the nickel bath can be introduced in the mantle.
[0068] The nickel bath is composed of a mixture of nickel salts and sodium hypophosphite. The nickel bath may also comprise: [0069] additives acting as complexing agents blocking a part of the Nickel ions and slowing down the precipitation of byproducts of the reaction such as organic hydroxy acids; [0070] stabilizers that prevent the decomposition of the nickel bath like slats of heavy metals or cyclic compounds; [0071] accelerators that increase the deposition rate, like dicarboxylic aliphatic acids; [0072] wetting agents that favor the wettability of the surfaces to be coated and facilitate the detachment of hydrogen bubbles, like mixtures of cationic and anionic surfactants.
[0073] The nickel bath (24) will not completely fill the volume inside the cylindrical mantle
[0074] The amount of nickel bath initially introduced in the mantle and laterally contained by caps (12) and (13) is such that the upper level (23) of the nickel bath is preferably above the chord (29) of the lowermost sector (in the drawing, the sector 19), formed on the circumference (27) defined by the bottoms of grooves (8) formed in the mantle. The level (23) can also preferably be above the chord (30) of sector (19) formed on the circumference (26) defined by the radially innermost part of the grooves (8). In this way, when the mantle will be rotated to expose another sector (for example, sector 20) to the nickel bath, there will be a superimposition of the protective coating formed in the first step to the protective coating formed in the subsequent step. Therefore, it will be possible to completely coat the internal surface of the mantle that will be in contact with the condensate when the Yankee drier will be in operation.
[0075] The preferably circular openings (17, 18) formed in the caps (12, 13) are such that they always remain above the level (23) of the nickel bath, even after a complete rotation of the mantle around its longitudinal axis.
[0076] Once introduced in the mantle, the nickel bath must be brought to a temperature suitable for the desired deposition (typically, a temperature comprised between 60° C. and 95° C.). During this phase, the mantle is stationary. For heating the nickel bath, it is possible to make use of both heating means placed externally to the mantle and heating means immersed in the nickel bath. For example, it is possible to make use of radiant lamps placed externally around the mantle so as to selectively or simultaneously heating the sectors mentioned above. In this case, the lamps can be uniformly distributed to uniform the temperature of the outer surface of the mantle subjected to heating and avoid areas that are heated more than others. Alternatively, or in addition, it is possible to make use of heating means totally or partially immersed in the nickel bath. For example, immersed electric heating resistors can be used.
[0077] To speed up the activation of the chemical deposition process, the nickel bath can be pre-heated before introducing it into the mantle.
[0078] Preferably, the nickel bath is recirculated inside the mantle for two reasons: a limited turbulence of the nickel bath facilitates removal of hydrogen micro-bubbles that tend to adhere to the treated surface. A second reason is that the content of nickel, phosphorus and other substances contained in the bath progressively decrease while the reaction takes place and the protective coating is formed. If the nickel bath is not mixed, some parts of the latter could have a non-uniform concentration due, for example, to a (even if limited) an uneven distribution of the temperature.
[0079] The mixing and turbulence in the nickel bath can be obtained in different ways. A preferred embodiment, schematically represented in
[0080] Another embodiment can foresee a heater (33) placed at any point of the recirculation system, preferably downstream of the filter (preferably an electrical heating resistor). This heater can cooperate with, or substitute the, heating system for heating the nickel bath disclosed above.
[0081] A cover (36) can be placed above the nickel bath, preferably not rigidly connected with the mantle so as to allow the latter to rotate without having to reposition the cover (36) at each rotation of the mantle. The purpose of said cover is to hinder the dispersion of vapors produced by the reaction: the nickel bath, even if not brought to the boiling point, can be brought o relatively high temperatures (preferably up to 95° C.) such that a high evaporation is expected, due also to recirculation and turbulence mentioned above. The presence of a cover allows the condensation of part of the vapors and its re-introduction (for example, by dripping) into the nickel bath. In this way, at least two advantages are obtained: the nickel bath consumption is reduced such that reintegration of demineralized water in the nickel bath is also reduced, and thermal losses are limited, thus reducing the thermal power required for reaching the desired temperature and its control during the process.
[0082] Preferably, said cover is as large as possible to increase its efficiency. Ideally, the maximum efficiency is achieved by completely covering the nickel bath.
[0083] As said above, the cover (36) is preferably stationary also during rotation of the mantle. Therefore, preferably, the cover is supported by a structure constrained to a part external to the mantle, for example supported by abeam (37) passing through the openings (17, 18) of the caps (12, 13) and supported by columns (38, 39) bearing on the ground externally to the mantle. The cover can be connected to the beam (37) by means of cables or tie rods (40).
[0084] Preferably, said cover is made of a thermally insulating material or it is coated with a thermally insulating material. Preferably, said cover can be provided with coverable openings allowing visual inspection of the nickel bath or collection of samples to be analyzed.
[0085] Once the nickel bath has been brought to a temperature higher than the reaction triggering temperature, the Ni—P coating deposits on the treated surfaces. The deposition rate will also depend on the temperature of the nickel bath (a higher temperature will imply a higher deposition rate).
[0086] Preferably, the mantle is kept stationary for a time sufficient to allow the deposition of the protective coating having the desired thickness. During the reaction process, it will be possible to manually or automatically add substances containing nickel and/or phosphorus to avoid excessive variations of the nickel bath composition with respect to the starting composition, variations due to the progressive deposition of nickel and phosphorus. Other substances can be added to the nickel bath (for example, pH regulators) in order to keep the acidity of the solution within the limits required for the reaction.
[0087] Once the surface of the mantle corresponding to the first of the above-mentioned sectors has been exposed to the reaction for the predetermined time required for the deposition of the protective coating having the desired thickness, the mantle is rotated about its longitudinal axis through rollers (10) and (11). The rotation of the mantle, indicated by the arrow “R” in
[0088] As said above, the level (23) of the nickel bath is such that, preferably, there is an overlapping of the protective coating at the ends of the surfaces exposed to the nickel bath in order to avoid uncoated areas in the mantle inner surface to be coated.
[0089] Preferably, the surface of the mantle corresponding to the sector (20) is pre-heated before being brought into contact with the nickel bath, the pre-heating bringing said surface at a temperature lower than, or equal to, the temperature of the nickel bath such that, when there is the contact of the surface with the nickel bath, the temperature of the latter is not excessively or quickly reduced given the high thermal conductivity of the mantle. An excessive or too quick decreasing of the bath temperature (indicatively, a temperature decrease of 10° C. occurring during said rotation) could slow down or interrupt the reaction providing the deposition of the protective coating that, as a consequence, could be defective or it could have a thickness lower than the desired thickness.
[0090] The step disclosed above is repeated as many times as the number of sector subdivisions. Therefore, at the end of the process, the entire internal surface of the mantle exposed to the nickel bath will be coated by a protective coating having a substantially uniform thickness with the exception of said overlapping zones where the protective coating will have a higher thickness. According the example disclosed above, said operation is executed four times, i.e. for each of said sectors (19, 20, 21, 22).
[0091] In some other embodiments, the mantle can be attached to the end heads (13, 14), as shown in
[0092] According to an alternative implementation of the process, the mantle can be rotated about its axis also during the reaction, i.e. during the deposition of the protective coating. In this way, overlapping zones of protective coating are avoided. In this case, the protective coating is formed by superimposed layers formed along the internal cylindrical surface of the mantle. The number of the superimposed layers will be equal to the number of complete rotations of the mantle.
[0093] In practice the execution details may vary with regard to the elements described and illustrated, without thereby departing from the adopted solution and therefore remaining within the limits of the protection granted by this patent in accordance with the appended claims.