Hair dyeing composition comprising an oxidation dye, a scleroglucan gum and an associative cellulose polymer

Abstract

The disclosure relates to a composition for dyeing keratin fibers, in particular human keratin fibers such as hair, comprising one or more oxidation dyes, one or more scleroglucan gums in a total weight content greater than or equal to 0.5% relative to the total weight of the composition, and one or more associative polymers comprising at least one fatty chain having 8 to 30 carbon atoms, preferably non-ionic. The disclosure also relates to a method for dyeing keratin fibers using said composition and to a multi-compartment device suitable for implementing said composition.

Claims

1. A composition for dyeing keratin fibers, comprising: at least one oxidation base; at least one coupler; at least one scleroglucan gum present in a total amount of greater than or equal to 0.5% by weight, relative to the total weight of the composition; and at least one associative cellulose-based polymer comprising at least one fatty chain including from 8 to 30 carbon atoms.

2. The composition of claim 1, wherein the at least one scleroglucan gum is present in an amount ranging from 0.5% to 10% by weight, relative to the total weight of composition.

3. The composition of claim 1, wherein the at least one oxidation base is chosen from para-phenylenediamines, bis(phenyl)alkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases, salts thereof, or mixtures thereof.

4. The composition of claim 1, wherein the at least one coupler is chosen from meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene-based couplers, heterocyclic couplers, salts thereof, or mixtures thereof.

5. The composition of claim 1, wherein the at least one associative cellulose-based polymer is present in a total amount ranging from 0.01% to 10% by weight, relative to the total weight of the composition.

6. The composition of claim 1, wherein the at least one associative cellulose-based polymer is present in a total amount ranging from 0.1% to 2% by weight, relative to the total weight of the composition.

7. The composition of claim 1, wherein the at least one associative cellulose-based polymer is nonionic.

8. The composition of claim 7, wherein the at least one associative cellulose-based polymer that is nonionic is chosen from celluloses modified with groups including at least one fatty chain.

9. The composition of claim 1, wherein the at least one associative cellulose-based polymer is chosen from celluloses modified with groups including at least one fatty chain.

10. The composition of claim 1, wherein the at least one associative cellulose-based polymer is chosen from: hydroxyethylcelluloses modified with groups including at least one fatty chain chosen from alkyl groups, arylalkyl groups, alkylaryl groups, or mixtures thereof; hydroxyethylcelluloses modified with polyalkylene glycol alkyl phenol ether groups; or mixtures thereof.

11. The composition of claim 1, wherein the at least one associative cellulose-based polymer is chosen from cetylhydroxyethylcellulose, polyethylene glycol (15) ether of nonyl phenol, or a mixture thereof.

12. The composition of claim 1, further comprising at least one carboxylic acid, a salt thereof, a solvate thereof, or a mixture thereof.

13. The composition of claim 12, wherein the at least one carboxylic acid is chosen from oxalic acid, malonic acid, rnalic acid, glutaric acid, citraconic acid, citric acid, maleic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, or a mixture thereof.

14. The composition of claim 1, further comprising at least one non-oxyalkylenated, non-polyglycerolated fatty alcohol.

15. The composition of claim 1, further comprising at least one alkaline agent, wherein the at least one alkaline agent is present in a total amount ranging from 1% to 20% by weight, relative to the total weight of the composition.

16. The composition of claim 15, wherein the at least one alkaline agent is chosen from aqueous ammonia, alkali metal or alkaline-earth metal metasilicates, alkanolamines, amino acids, or mixtures thereof.

17. The composition of claim 1, further comprising at least one cationic polymer chosen from: (1) dialkyldiallylammonium homopolymers; and/or (2) cationic polymers that are constituted of repeating units corresponding to the formula (IV): ##STR00005## wherein in formula (IV), R.sub.1, R.sub.2, R.sub.3, and R.sub.4, which may be identical or different, are chosen from an alkyl or hydroxyalkyl radical containing from 1 to 4 carbon atoms, n and p are integers ranging from 2 to 20, and X- is an anion derived from a mineral or organic acid.

18. The composition of claim 17, wherein in formula (IV), R.sub.1, R.sub.2, R.sub.3, and R.sub.4 represent a methyl radical, n=3, p=6, and X=Cl.

19. The composition of claim 1, further comprising at least one chemical oxidizing agent chosen from hydrogen peroxide and/or one or more systems for generating hydrogen peroxide.

20. A method for dyeing keratin fibers, comprising: applying to the keratin fibers a dye composition (A) and an oxidizing composition (B); wherein the dye composition (A) comprises: at least one oxidation base; at least one coupler; at least one scleroglucan gum present in a total amount of greater than or equal to 0.5% by weight, relative to the total weight of the dye composition (A); and at least one associative cellulose-based polymer comprising at least one fatty chain including from B to 30 carbon atoms; wherein the oxidizing composition (B) comprises at least one chemical oxidizing agent; and wherein the oxidizing composition (B) is extemporaneously mixed with the dye composition (A) just before being applied to the keratin fibers, or alternatively, the dye composition (A) and the oxidizing composition (B) are applied sequentially to the keratin fibers without intermediate rinsing.

Description

EXAMPLE 1

(1) The following dye compositions were prepared from the following ingredients in the proportions indicated in grams of active material:

(2) TABLE-US-00001 Composition Comparative Comparative Comparative A1 composition composition composition (according C1 outside C2 outside C3 outside to the the invention the invention the invention invention) Ammonium hydroxide 2.47 2.47 2.47 2.47 Ethanolamine 4 4 4 4 EDTA 0.2 0.2 0.2 0.2 Sodium sulfite 0.5 0.5 0.5 0.5 Oxidation dyes 1.401 1.401 1.401 1.401 Fragance qs qs qs qs Hexadimethrine chloride 0.3 0.3 0.3 0.3 Polyquaternium-6 0.4 0.4 0.4 0.4 Cetylhydroxyethylcellulose 0.2 0.2 0.2 0.2 Xanthan gum 1 — — — Algin — — 1 — Sclerotium gum — — — 1 Hydroxypropylcellulose — 1 — — Water qs 100 qs 100 qs 100 qs 100 Glycerol 10 10 10 10 Cetrimonium chloride 0.25 0.25 0.25 0.25 Caprylyl/capryl glucoside 0.6 0.6 0.6 0.6 Ascorbic acid 0.4 0.4 0.4 0.4
Visual Evaluation of the Stability of the Compositions
The stability of the dye compositions was evaluated by observing the compositions at T0 (immediately after preparation of the composition) and then after 2 months of storage at 45° C.

(3) TABLE-US-00002 Composition Composition C1 Composition C2 Composition C3 A1 Observation Liquid texture Liquid texture Liquid texture Translucent gel at T0 at Non- Non- Non- Homogeneous room homogeneous homogeneous homogeneous (no phase temperature (phase (phase (phase separation) (25° C.) separation) separation) separation) Observation Liquid texture Liquid texture Liquid texture Translucent gel after 2 Non- Non- Non- Homogeneous months at homogeneous homogeneous homogeneous (no phase 45° C. (phase (phase (phase separation) separation) separation) separation)

(4) It is observed that composition A1 according to the invention is homogeneous and forms a translucent gel at T0. After 2 months at 45°, composition A1 according to the invention is stable; it is homogeneous and translucent. Comparative compositions C1, C2 and C3 in which the scleroglucan gum was replaced weight-for-weight with another thickener of polysaccharide type are unstable. Specifically, they are not homogeneous; phase separation of these compositions is observed as early as T0.

EXAMPLE 2

(5) The following compositions were prepared from the following ingredients in the proportions indicated in grams:

(6) TABLE-US-00003 Comparative Composition A2 Composition according to the C4 outside invention the invention Ammonium hydroxide 2.47 2.47 Ethanolamine 4.47 4.47 EDTA 0.2 0.2 Sodium sulfite 0.5 0.5 Toluene-2,5-diamine 0.4 0.4 2-Methyl-5- 0.264 0.264 hydroxyethylaminophenol 4-Amino-2-hydroxytoluene 1.304 1.304 Hydroxyethoxyaminopyrazolopyridine 1.76 1.76 HCl p-Aminophenol 0.128 0.128 Fragance qs qs Cetylhydroxyethylcellulose 0.2 0.4 Sclerotium gum 0.6 0.4 Water qs 100 qs 100 Glycerol 10 10 Cocoyl betaine 0.15 0.15 Caprylyl/capryl glucoside 0.6 0.6 Ascorbic acid 0.4 0.4
Visual Evaluation of the Stability of the Compositions
The stability of the dye compositions was evaluated by observing the compositions at T0 (immediately after preparation of the composition) and then after 2 months of storage at room temperature (25° C.), and after 2 months of storage at 45° C.

(7) TABLE-US-00004 Composition A2 according to the Comparative invention composition C4 Observation at T0 Homogeneous (no phase Homogeneous (no phase (immediately after separation) separation) preparation) Texture: Smooth gel Texture: Smooth gel Observation after 2 Homogeneous (no phase Phase separation: months at 25° C. separation) Gel with presence Texture: Smooth gel of leached liquid Observation after 2 Smooth homogeneous Phase separation: months at 45° C. gel texture (no phase Gel with presence separation) of leached liquid
It is observed that composition A2 according to the invention which comprises a content of scleroglucan gum of greater than or equal to 0.5% by weight relative to the total weight of the composition is stable at room temperature and also at 45° for two months, unlike comparative composition C4 which comprises a content of scleroglucan gum of 0.4% by weight, relative to the weight of the composition. Compositions A2 and C4 comprise the same total content of thickener(s) (0.8%). Comparative composition C4 is therefore unstable.

EXAMPLE 3

(8) The following composition was prepared from the following ingredients in the following proportions indicated in grams:

(9) TABLE-US-00005 Composition A3 according to the invention Ammonium hydroxide 1.23 Arginine 3 Ethanolamine 5 EDTA 0.2 Sodium sulfite 0.5 Citric acid 3.3 Sodium metasilicate 2 Toluene-2,5-diamine 0.16 4-Amino-2-hydroxytoluene 0.92 5-Amino-6-chloro-o-cresol 0.2 1-Hydroxyethyl 4,5-diaminopyrazole 1.44 sulfate p-Aminophenol 0.12 Fragance qs Polyquaternium-11 1.84 Hexadimethrine chloride 1.2 Polyquaternium-6 0.8 Cetylhydroxyethylcellulose 0.2 Sclerotium gum 1 Water qs 100 Glycerol 10 Cetrimonium chloride 0.25 Caprylyl/capryl glucoside 0.6 Ascorbic acid 0.4
Visual Evaluation of the Stability of the Compositions
The stability of the dye composition was evaluated by observing it at T0 and then after 48 hours at room temperature (25° C.) and then after two months of storage at 45° C.

(10) TABLE-US-00006 Composition A3 Observation at T0 (immediately Translucent gel after preparation) at room Homogeneous (no phase temperature (25° C.) separation) Observation after 2 months at Translucent gel 45° C. Homogeneous (no phase separation)

(11) It is observed that composition A3 according to the invention is homogeneous and forms a translucent gel at T0. After two months at 45°, composition A3 according to the invention is stable and in the form of a homogeneous, translucent gel.

EXAMPLE 4

(12) Composition A3 of example 3 was mixed with one times its weight of 20-volumes oxidizing agent (6 g % H.sub.2O.sub.2 AM). The mixture thus obtained was applied to locks of natural hair containing 90% white hairs.

(13) The “mixture/lock” bath ratio is, respectively, 10/1 (g/g).

(14) The leave-on time is 30 minutes, on a hotplate set at 27° C. On conclusion of the leave-on time, the locks are rinsed and then dried under a drying hood at 40° C.

(15) The color of the locks was evaluated in the CIE L*a*b* system, using a Datacolor Spectraflash SF600X spectrocolorimeter.

(16) Intense coloring of the keratin fibers is obtained (L*=24.95).

EXAMPLE 5

(17) The following composition according to the invention is prepared, which comprises oxidation dyes in the composition below

(18) TABLE-US-00007 Concentration (g/%) p-Phenylenediamine 0.224 Resorcinol 0.5 Cetylhydroxyethylcellulose 0.2 Hydroxypropylbis(N-hydroxyethyl-p- 0.0454 phenylenediamine) HCl Ammonium hydroxide 2.5 Ethanolamine 4 Polyquaternium-6 1.5 Sclerotium gum 1 Ascorbic acid 0.4 Glycerol 10 m-Aminophenol 0.04 EDTA 0.2 2-Methylresorcinol 0.1 2,4-Diaminophenoxyethanol HCl 0.118 Isopropyl alcohol 0.41 Cetearyl alcohol 6 Hexadimethrine chloride 3 Behentrimonium chloride 2.0 Aqua qs 100
This composition is mixed with an oxidizing agent containing hydrogen peroxide under the conditions described previously.
A composition that is stable over time, which does not undergo phase separation and which affords an intense coloring on keratin fibers is thus obtained.