Reusable display addressable with incident light
11287718 · 2022-03-29
Assignee
Inventors
Cpc classification
G02F1/0126
PHYSICS
International classification
G02F1/133
PHYSICS
G02F1/1335
PHYSICS
Abstract
A reflective color display that can be addressed from the front (viewing surface side) of the display with a light source, such as a projector, LED, or laser. The display comprises (in order) a color filter array, a transparent electrode, an electro-optic medium, a photoconductive material, and a rear electrode. The color displays of the invention are useful for large format color signage, such as billboards and wayfinding.
Claims
1. A method for updating a reflective image, comprising: providing a display including, in this order, from top to bottom: a color filter array, a transparent electrode, an electro-optic medium, a photoconductive material, and a rear electrode; supplying a first electrical potential between the transparent electrode and the rear electrode; and exposing the display, through the color filter array, to a source of patterned light while the first electrical potential is supplied, thereby resulting in an updated reflective image being visible from the top of the display when the first electrical potential is not supplied.
2. The method of claim 1, further comprising supplying a second electrical potential to remove the reflective image.
3. The method of claim 1, wherein the source of patterned light comprises a projector.
4. The method of claim 1, wherein the electrical potential is a time-dependent wave form.
5. The method of claim 1, wherein the electro-optic medium comprises an electrophoretic material comprising a plurality of electrically charged particles disposed in a fluid and capable of moving through the fluid under the influence of an electric field.
6. The method of claim 5, wherein the electrically charged particles are white and black.
7. The method of claim 1, wherein the color filter array comprises red, green, and blue elements.
8. The method of claim 7, wherein the red, green, and blue elements are smaller than 1 mm.sup.2 in area.
9. The method of claim 7, wherein the red, green, and blue elements are greater than 1 mm.sup.2 in area.
10. The method of claim 1, wherein the photoconductive material comprises photoconductive polymers, dye-aggregate photoreceptors, or pigment-based photoconductors.
11. The method of claim 1, wherein the photoconductive material comprises 2,4,7-trinitro-9-fluorine complexed with poly(N-vinylcarbazole).
12. A system for providing a reflective image, comprising: a display including, in this order from top to bottom, wherein the reflective image is viewed from the top: a color filter array, a transparent electrode, an electro-optic medium, and a photoconductive material; an electrode configured to provide an electrical potential suitable for addressing a portion of the display with light; and an illumination source configured to illuminate the top of the display, through the color filter array, with light to address the display.
13. The system of claim 12, wherein the illumination source produces light outside of the visible spectrum.
14. The system of claim 12, further comprising a light filter that passes visible light.
15. The system of claim 12, wherein the electro-optic medium comprises an electrophoretic material comprising a plurality of electrically charged particles disposed in a fluid and capable of moving through the fluid under the influence of an electric field.
Description
BRIEF DESCRIPTION OF DRAWINGS
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DETAILED DESCRIPTION
(16) As indicated above, the present invention provides a reusable display medium for providing messaging and advertising in large formats. Specifically, the invention includes displays comprising a color filter array (CFA), a transparent electrode, an electro-optic medium, a photoconductive material, and a rear electrode. In some embodiments, the displays can be incorporated into large format displays such as posters or billboards. In some embodiments, the displays incorporate reflective, rather than emissive, electro-optic media. Reflective media are particularly well-suited for high-background lighting environments, such as outdoor advertising, because emissive electro-optic media must supply light in excess of the ambient light to be viewed from far away. The disclosed displays are also more energy efficient than state-of-the-art reusable displays because the displays only require small amounts of energy for refreshing the content, after which they operate substantially without additional energy.
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(18) The transparent and rear electrodes 120 and 110, respectively, are biased with an electrical potential that is supplied by a source of electrical potential 220 using electrical connections 210. The electrical potential supplied by the source 220 may be essentially DC, or it may be time-dependent. Typically, the electrical connection 210 between the source 220 and the electrodes 110 and 120 is interruptible, e.g., with a switch 230. Typically, the switch 230 is controlled electronically, so that the correctly-biased electrical potential can be applied to the electrodes as needed. In some instances, the source 220 is coupled to a controller (not shown) that can be programmed to modify the time and the magnitude of the electrical potential. For example, the controller can be used to apply a time dependent waveform to the electrodes, of the type disclosed in the patents and applications described in the Background. In some embodiments, the controller will include a central processing unit, memory, and instructions for controlling the time and magnitude of an electrical potential applied between the electrodes 110 and 120
(19) Exposing the photoconductive layer 12 to light reduces its impedance, permitting the electric field between electrodes 110 and 120 to address the electro-optic medium 14. Photoconductive materials useful as the photoconductive layer 12 of display 200 include organic photoconductive polymers, dye-aggregate photoreceptors, and pigment-based photoconductors. Photoconductive materials for use in displays 200 of the invention are preferably organic photoconductive polymers. An example of an organic photoconductive polymer is 2,4,7-trinitro-9-fluorenone complexed with poly(N-vinylcarbazole). For pigment-based photoconductors, the pigment particles themselves may be photoconductive, so that the photoactive and optically active components are the same.
(20) Surprisingly, the inventors have found that it is possible to address a display of the invention with incident light from the display side, even though the photoconductive layer, which interacts with the incident light, is on the opposite side of the electro-optic medium from the incident light. As mentioned previously, the displays disclosed in U.S. Pat. No. 6,704,133 also included a photoconductive layer opposed from the viewing surface. However, the displays of U.S. Pat. No. 6,704,133 were intended to be addressed from the backside specifically because it was believed that the incident light would not traverse the electro-optic medium. The inventors have found that with the addition of a biasing voltage it is possible to address the photoconductive layer through the electro-optic layer, for example, an electrophoretic medium comprising charged particles in a fluid.
(21) Examples of other photoconductive materials from which the photoconductive layer 12 may be formed include inorganic and organic photoconductive materials, layered photoconductive materials having inorganic or organic compositions, and composite layered devices containing photoconductive materials in a polymer matrix. Exemplary photoconductive materials include, for example, an inorganic photoconductive composition or an organic photoconductive composition dispersed in a resinous binder material such as, for example, a poly(hydroxyether) material. One example of a composite layered device is a dispersion of zinc oxide particles in a polymer matrix. Useful polymer matrices include those that are incapable of transporting for any significant distance injected charge carriers generated by the photoconductive material. Such useful polymer matrices include, but are not limited to, polystyrene resins, silicone resins, acrylic and methacrylic ester polymers, polymerized ester derivatives of acrylic acids, α-acrylic acids and α-methacrylic acids, chlorinated rubber, vinyl polymers and copolymers, and cellulose esters.
(22) Other known photoconductive materials which may be useful in the present invention include hydrogenated amorphous silicon, cadmium selenide, gallium arsenide, trigonal selenium, amorphous selenium, doped amorphous selenium substances, halogen doped amorphous selenium substances, amorphous selenium alloys, doped amorphous selenium alloys, including selenium arsenic, selenium tellurium, selenium arsenic antimony, halogen doped selenium alloys, wherein the dopant is a material such as chlorine, iodine, bromine, sodium or fluorine, cadmium sulfide, an alkali metal, and the like. Selenium alloys that may be used may comprise, for example, selenium-tellurium-arsenic; in one embodiment a halogen doped selenium arsenic alloy is employed. Other inorganic photoconductive materials may include, for example, cadmium sulfoselenide, cadmium selenide, and cadmium sulfide. The organic photoconductive composition may include, for example, a metal free phthalocyanine, a metal phthalocyanine, a charge transfer complex material, a squarilium dye, and a vanadyl phthalocyanine. Generally, these photoconductive materials are deposited on a suitable substrate, such as a glass, plastic, or polyester substrate.
(23) The photoconductive layer 12 is preferably formed from a material having an absorption activity that is substantially matched to the visible spectrum, however, it is possible to tune the photoconductive layer 12 so that it responds to light outside of the visible spectrum, e.g., infrared or ultraviolet light. The wavelength sensitivity of the photoconductor is dependent on the composition of the charge generator. For example, if the charge generator is primarily selenium alloys, the photoconductive material is most sensitive to blue light near the 400 nm wavelength range. Alternatively, if the charge generator is mainly phthalocyanine pigments, the photoconductive material is most sensitive to red light near the 700 nm wavelength range.
(24) The photoconductive layer 12 is typically spread onto rear electrode 110 as a paste or dispersion, however, the photoconductive layer may be partially dissolved in a solvent so that it can be sprayed onto the rear electrode 110. In some embodiments, the photoconductive layer is deposited as a pattern of islands, e.g., using an inkjet printer, so that the photoconductive materials are very localized, and do not allow neighboring elements of the CFA 150 to experience electric fields sufficient to address the electro-optic medium 14 between the electrodes.
(25) Electro-optic media 14 for use in displays 200 of the invention may include any display media that is bistable. The definition of a bistable depends on the application for the display 200. A slowly-decaying optical state can be effectively bistable if the optical state is substantially unchanged over the required viewing time. For example, in a display which is updated every few minutes, a display image which is stable for hours or days is effectively bistable for that application. In this invention, the term bistable also indicates a display with an optical state sufficiently long-lived as to be effectively bistable for the application in mind. In practice, some electro-optic displays are capable of achieving multiple gray states, and are stable not only in their extreme black and white optical states, but also in their intermediate gray states. Such displays may be described as “multi-stable”.
(26) Examples of electro-optic media 14 suitable for use include rotating bichromal spheres or cylinders, retroreflective liquids of differing dielectric constants (i.e., suspended liquid displays). In one embodiment, the electro-optic medium 14 is an encapsulated medium comprising electrophoretic particles, such as the electro-optic medium described in the patents and applications discussed above. In some other embodiments, the electro-optic material is dispersed within one or more wells defined by a polymer matrix. The wells may be formed by, for example, embossing, etching, punching, slitting stretching, stamping, extruding and injection molding the shape of the matrix onto the polymer material.
(27) In preferred embodiments, the electro-optic medium 14 is a particle-based electrophoretic medium, in which a plurality of charged particles will move through a fluid under the influence of an electric field. This medium is particularly-well suited for displays 200 of the invention because the medium can be addressed by DC voltages and draws very little current. As such, the conductive leads and electrodes used to deliver the voltage to electrophoretic particle-based ink displays can be of relatively high resistivity, and/or flexible.
(28) In some embodiments, either or both of the electrodes 110, 120 may be replaced by an alternative mechanism applying an electric field to the electro-optic medium 14. For example, electrostatic charge may be deposited to one side of the electro-optic medium 14, one side of the photoconductive layer 12, or both the electro-optic medium 14 and the photoconductive layer 12. In other embodiments, the display 200 may be created without the rear electrode 110, and the electro-optic medium can be prepared for “writing” with an illuminated pattern by movable electrodes (not coupled to the medium) that deliver an electrical potential to the electro-optic medium 14 and/or the photoconductive layer 12. In still other embodiments, a stylus-type addressing apparatus may be used to apply electrostatic charge to one side of the electro-optic medium 14 or the photoconductive layer 12.
(29) As shown in
(30) The colored sub-pixels of the CFA 150 can be arranged in a variety of patterns to achieve the desired mixture of colors and/or color saturation.
(31) As shown in
(32) In some embodiments, the color intensity can vary across a lateral dimension of the pixel such that one area of the pixel is densely colored and another portion of the pixel is substantially colorless, with other regions containing intermediate color intensities. Such a variation in color density can be achieved using a variety of methods. For example, such a pattern could be developed by using a colored material which develops (or loses) its color upon exposure to radiation, and selectively scanning the pixel using a radiation source. A similar effect can be achieved by patterning the colored material to form spatially dense dots (or other suitable shapes) toward the middle region of the pixel and spatially sparse dots near the edges of the pixel.
(33) Aside from varying the variety of sub-pixel colors and the arrangement of the sub-pixels, the relative areas of each colored sub-pixel may be varied. For example, if a common background color is to be used, e.g., blue, a larger number of blue sub-pixels may be included in the CFA 150, e.g., as compared to the number of red sub-pixels. Alternatively, shades of intermediate colors (e.g., purple) can be skewed toward one sub-pixel color (e.g., red) by altering the relative amounts of one sub-pixel versus the others.
(34) The CFA 150 and the patterns of colored sub-pixels described herein can be achieved using any suitable manufacturing process. For example, in some embodiments, photolithography (e.g., using a colored material comprising a photoresist) can be used to produce the desired distribution of colored material within the sub-pixel. Other exemplary processes that can be used to produce patterned colored materials include, but are not limited to, ink jet printing and thermal transfer printing.
(35) In a display 200 of the invention, light passes through the CFA 150 at all times, regardless of the state of the underlying electro-optic layer. The transparent electrode 120, beneath the CFA 150, allows most light that passes through the CFA 150 to pass on to the electro-optic medium 14. While most of the incident light reaching the electro-optic medium 14 will be reflected or absorbed, depending upon the state of the medium, some amount of the incident light will pass through the electro-optic medium and strike the photoconductive layer 12, When the light reaches the photoconductive layer 12, the resistance of the photoconductive layer 12 in this region is lowered. Accordingly, in these regions the electrical potential across the electro-optic medium 14 will now be sufficient to address the electro-optic medium 14, causing a change in state, e.g., from black to white.
(36) Referring again to
(37) The function of the display 200 is illustrated in
(38) For the sub-pixels that are white (transparent), the projected light will strike the photoconductive layer 12 regardless of the color, causing the electro-optic medium 14 to change to white or intermediate gray, depending upon design of the display and the specific needs of the application. Because there is no color associated with these sub-pixels, the subpixels will, thereafter, reflect white or gray light. For the sub-pixels that are colored, but do not match the color of the projected light, little to no light will pass through the CFA 150 and the electro-optic medium 14 to reach the photoconductive layer 12. In this instance, the electro-optic medium 14 will remain in its initial state, typically black. In instances where the light is partially transmitted by the colored sub-pixel, the end result will be a gray level in the underlying electro-optic medium, as shown in
(39) As discussed above, the invention uses an electro-optic medium 14 with an initial black state, and the display 200 is illuminated with a positive color (true color) image. However, it is understood that the invention can be practiced by starting with an electro-optic medium 14 in a white state and projecting a negative (reverse color) image on the display. Furthermore, the color saturation of the projected image can be modified, as needed, to obtain an image with the correct hues. For example, it may be desired that a billboard display a logo with a particular shade of blue. Illuminating the display 200 with the desired shade of blue may not result in a matching shade because of the presence of the red and green sub-pixels. However, with the use of an RGB LCD projector, it is straightforward to adjust the color levels in the projected image so that the final displayed image matches the desired shade of blue. In other embodiments, a test pattern may be used to adjust the color levels in the projector so that the final projected image results in a retained image with the desired colors.
(40) Time-dependent electrical potentials (waveforms) for preparing a display 200 for writing, and for writing the display, are shown in
(41) Once the display has been cleared (“wiped”), the polarity of the potential is reversed, as shown in
(42) In an alternate embodiment, shown in
(43) The electro-optic medium 14 is not limited to only white and black, however. For example, the initial “write” state might be a gray level between white and black. Furthermore, pixels receiving full intensity exposure during the write phase (i.e., a white sub-pixel of the CFA or a colored sub-pixel illuminated with a matching color) may be driven to a gray level, rather than white, by decreasing the voltage between the electrodes, 110 and 120, or by modifying the displayed image to intentionally decrease the light intensity of the projected image. (When a digital projector, e.g., an LCD projector, is used to write the image, it is straightforward to adjust the color balance and intensity to produce the desired final image.) In other embodiments, a “finish” voltage waveform may be used to adjust the state of the electro-optic medium 14 after an image has been written. A finish waveform may, for example, drive the entire electro-optic medium more toward the white or the black state, depending upon the needs of the final image.
(44) The displays of the invention are well suited for large format displays that will be changed regularly. For example, a billboard, illustrated in
(45) In addition to using a projected image, it is also possible to address a display 200 of the invention using an illuminating instrument, such as a light pen or a laser.
(46) Advanced applications of the displays of the invention can be used in other environments where temporary or personalized information is needed in a large format. In the embodiment shown in
(47) The displays 200 of the invention may be part of a display system. For example, the display system may include a display of the type described in
(48) Hybrid systems incorporating the principles of the invention are also possible, as illustrated in
(49) While displays of the invention are intended to display images for long periods of time with little to no energy input, the looped displays, described above, can be used to refresh content on the same time scale as emissive displays, e.g., large format LEI) displays. Displays of the invention can display two different images in less than one hour, e.g., in less than 10 minutes, e.g., in less than five minutes, e.g., in less than two minutes. Furthermore, the refresh periods can be staggered, depending upon the use of the display. For example, a transportation schedule may be refreshed every five minutes with an advertisement that lasts for 30 seconds, whereupon the transportation schedule is returned for another five minute period.
(50) From the foregoing, it will be seen that the present invention can provide a reusable large-format display medium that requires little energy to maintain an image. Additionally, because the displays of the invention are lightweight and flexible, they can be used in a variety of temporary environments, i.e., they can be disassembled, moved, etc. with ease. In some embodiments, the displays may be simply rolled up like a poster and carted away. Finally, because digital photography and graphic arts are ubiquitous, there is no barrier to using the displays of the invention outside of providing a suitable illumination device coupled to a computer, for example an LCD projector.
(51) It will be apparent to those skilled in the art that numerous changes and modifications can be made in the specific embodiments of the invention described above without departing from the scope of the invention. Accordingly, the whole of the foregoing description is to be interpreted in an illustrative and not in a (imitative sense.