Cosmetic composition having increased skin contact and makeup persistence and method of manufacturing same

Abstract

Disclosed are a cosmetic composition having increased skin contact and makeup persistence and a method of manufacturing the same. The method includes: forming a powder continuous phase by rapidly mixing a powder and a film-forming agent; and obtaining a cosmetic composition in which a surface of the powder is compounded with the film-forming agent by heating the powder continuous phase for a predetermined time. In an embodiment, the cosmetic composition is manufactured by the method. In an embodiment, the cosmetic composition includes 5 wt % to 30 wt % of a powder, 0.1 wt % to 10 wt % of a film-forming agent, 10 wt % to 30 wt % of a silicone oil, and 0.1 wt % to 10 wt % of a spherical powder.

Claims

1. A method of manufacturing a cosmetic composition having increased skin contact and makeup persistence, comprising: forming a powder continuous phase by mixing a powder and a film-forming agent; and obtaining a cosmetic composition in which a surface of the powder is compounded with the film-forming agent by heating the powder continuous phase for a predetermined time, wherein the forming the powder continuous phase comprises: forming a first powder continuous phase activated with a weakly acidic region by placing 90 wt % to 99.5 wt % of the powder in a reactor, followed by addition with a powder activation solvent with stirring at 300 rpm to 700 rpm; and forming a second powder continuous phase by adding the first powder continuous phase with 0.5 wt % to 10 wt % of the film-forming agent with stirring at 200 rpm to 400 rpm.

2. The method of claim 1, further comprising homogenizing the cosmetic composition through pulverization and filtration.

3. The method of claim 1, wherein the obtaining the cosmetic composition comprises performing heating at a reaction temperature of 60° C. to 120° C. for 0.5 hr to 24 hr.

4. The method of claim 2, wherein the homogenizing comprises performing pulverization using a pulverizer of 3HP or more and filtration with 20 to 100 mesh.

5. The method of claim 1, wherein the powder is at least one selected from the group consisting of talc, kaolin, mica, sericite, nylon-12, methyl methacrylate crosspolymer, polymethyl methacrylate, boron nitride, alumina, titanium dioxide, zinc oxide, iron oxide, silica, pearl, organic dye, lake pigment, organic pigment and mixtures thereof.

6. The method of claim 1, wherein the film-forming agent is at least one selected from the group consisting of acrylate/dimethicone copolymer, acrylate/stearyl acrylate/dimethicone methacrylate copolymer, acrylate/ethylhexyl acrylate/dimethicone methacrylate copolymer, trimethylsiloxysilicate/dimethiconol crosspolymer, and mixtures thereof.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a flowchart showing a process of manufacturing a cosmetic composition having increased skin contact and makeup persistence according to an embodiment of the present invention;

(2) FIGS. 2A and 2B are images before and after adhesion testing of the cosmetic composition having increased skin contact and makeup persistence of Example 1 of the present invention using a coating adhesion test tape;

(3) FIGS. 3A and 3B are images before and after adhesion testing of the cosmetic composition having increased skin contact and makeup persistence of Example 2 of the present invention using a coating adhesion test tape; and

(4) FIGS. 4A and 4B are images before and after adhesion testing of the cosmetic composition having increased skin contact and makeup persistence of Comparative Example 1 of the present invention using a coating adhesion test tape.

DETAILED DESCRIPTION

(5) Hereinafter, a detailed description will be given of preferred embodiments of the present invention with reference to the appended drawings. However, the present invention is not limited to the embodiments described herein but may be embodied in other forms. Rather, the embodiments introduced herein are provided so that the disclosure may be made thorough and complete and so as to fully convey the spirit of the present invention to those skilled in the art. Throughout the specification, like reference numerals refer to like elements.

(6) FIG. 1 is a flowchart showing a process of preparing a cosmetic composition having increased skin contact and makeup persistence according to an embodiment of the present invention, FIGS. 2A and 2B are images before and after adhesion testing of the cosmetic composition having increased skin contact and makeup persistence of Example 1 of the present invention using a coating adhesion test tape, FIGS. 3A and 3B are images before and after adhesion testing of the cosmetic composition having increased skin contact and makeup persistence of Example 2 of the present invention using a coating adhesion test tape, and FIGS. 4A and 4B are images before and after adhesion testing of the cosmetic composition having increased skin contact and makeup persistence of Comparative Example 1 of the present invention using a coating adhesion test tape.

(7) With reference to FIGS. 1, 2A and 2B to 4A and 4B, the method of manufacturing the cosmetic composition having increased skin contact and makeup persistence according to an embodiment of the present invention may include forming a powder continuous phase by rapidly mixing a powder and a film-forming agent (S10), obtaining a cosmetic composition in which the surface of the powder is compounded with the film-forming agent by heating the powder continuous phase for a predetermined time (S20), and homogenizing the cosmetic composition through pulverization and filtration (S30).

(8) According to the present invention, at least one powder is surface-treated with a modified silicone film-forming agent, thereby obtaining a powder coating composition having superior skin contact and makeup persistence.

(9) The cosmetic composition of the present invention is able to increase skin contact and makeup persistence of a powder for use in, for example, a BB cream, foundation, makeup base, primer, concealer, sun cream, lipstick, lip gloss, tint, powder, blush, eyeshadow, eyeliner, mascara, or the like.

(10) Specifically, a powder such as a white pigment, a color pigment, a pearl pigment, an extender, etc. is coated with a particularly polymerized modified silicone film-forming agent, thereby increasing skin contact and ultimately makeup persistence.

(11) Thereby, problems with a conventional powder, in which makeup persistence is lowered and the effect thereof does not last long, due to coating with fatty acid, ester or pure silicone oil, may be overcome.

(12) Specifically, a powder and a film-forming agent are rapidly mixed, thus forming a powder continuous phase (S10). Here, the forming the powder continuous phase (S10) may be conducted by rapidly mixing 90 wt % to 99.5 wt % of the powder with 0.5 wt % to 10 wt % of the film-forming agent.

(13) The forming the powder continuous phase (S10) may include forming a first powder continuous phase activated with a weakly acidic region by placing 90 wt % to 99.5 wt % of the powder relative to 1 kg of the total amount in a reactor, followed by addition with a powder activation solvent with stirring at 300 rpm to 700 rpm (S10-1), and forming a second powder continuous phase by adding the first powder continuous phase with 0.5 wt % to 10 wt % of the film-forming agent with stirring at 200 rpm to 400 rpm (S10-2).

(14) Specifically, the powder is placed in an amount of 90 wt % to 99.5 wt % relative to 1 kg of the total amount in the reactor, and added with the powder activation solvent with stirring at 300 rpm to 700 rpm, thus forming a first powder continuous phase activated with a weakly acidic region (S10-1).

(15) Then, the first powder continuous phase surface-activated with cations is slowly added with 0.5 wt % to 10 wt % of a modified silicone film-forming agent with stirring at 200 rpm to 400 rpm, thus forming a second powder continuous phase (S10-2).

(16) Here, if the amount of the modified silicone film-forming agent is less than 0.1 wt %, skin contact and makeup persistence may become insignificant. On the other hand, if the amount of the modified silicone film-forming agent exceeds 10 wt %, power dispersibility and use sensation may decrease. Hence, it is preferred that the amount of the film-forming agent that is added fall within the above range.

(17) Thereafter, the powder continuous phase is heated for a predetermined time, thus obtaining a cosmetic composition in which the powder surface is compounded with the film-forming agent (S20). Here, the obtaining the cosmetic composition may be performed under heating conditions of a reaction temperature of 60° C. to 120° C. for 0.5 hr to 24 hr.

(18) Thereafter, the cosmetic composition is pulverized and filtered and thus homogenized (S30). Here, the homogenization step (S30) may be performed through pulverization using a pulverizer of 3HP or more and filtration with 20 to 100 mesh.

(19) In the present invention, the powder may include at least one selected from the group consisting of talc, kaolin, mica, sericite, nylon-12, methyl methacrylate crosspolymer, polymethyl methacrylate, boron nitride, alumina, titanium dioxide, zinc oxide, iron oxide, silica, pearl, organic dye, lake pigment, organic pigment and mixtures thereof.

(20) The film-forming agent may include at least one selected from the group consisting of modified silicones, such as acrylate/dimethicone copolymer, acrylate/stearyl acrylate/dimethicone methacrylate copolymer, acrylate/ethylhexyl acrylate/dimethicone methacrylate copolymer, trimethylsiloxysilicate/dimethiconol crosspolymer and mixtures thereof.

(21) The actual component ratio of a cosmetic composition manufactured by the above method and the manufacturing process thereof are described in detail below.

(22) According to an embodiment of the present invention, the cosmetic composition having increased skin contact and makeup persistence may include 5 wt % to 30 wt % of a powder, 0.1 wt % to 10 wt % of a film-forming agent, 10 wt % to 30 wt % of a silicone oil and 0.1 wt % to 10 wt % of a spherical powder.

(23) Specific examples and comparative examples of the cosmetic composition are shown in Table 1 below.

(24) TABLE-US-00001 TABLE 1 Example Example Comparative 1 2 Example 1 Phase Component (wt %) (wt %) (wt %) Pigment 1. Titanium dioxide 9.7 19.4 9.7 (A) (Powder) 2. Trimethylsiloxysilicate/ 0.3 0.6 dimethiconol crosspolymer (Film-forming agent) 3. Triethoxycaprylylsilane 0.3 (Coating agent) 4. Iron oxide (Pigment) 2 2 2 Oil part 5. Cyclopentasiloxane 20 20 20 (B) (Silicone oil) 6. Quaternium-18 0.95 0.95 0.95 Bentonite (Thickener) 7. Silica 0.5 0.5 0.5 (Spherical powder) 8. PEG-10 dimethicone 3 3 3 (Emulsifier) Aqueous 9. Disodium EDTA 0.05 0.05 0.05 part (C) (Sequestering agent) 10. Sodium chloride 1.5 1.5 1.5 (Emulsion stabilizer) 11. Butylene glycol 5 5 5 (Moisturizer) 12. Potassium sorbate 0.11 0.11 0.11 (Preservative) 13. Sodium benzoate 0.22 0.22 0.22 (Preservative) 14. Purified water 56.57 46.57 56.57 Additive 15. Perfume 0.1 0.1 0.1 (D)

(25) The cosmetic composition having increased skin contact and makeup persistence according to an embodiment of the present invention was manufactured using components in the amounts shown in Table 1. The specific manufacturing process thereof is described below.

(26) Specifically, a pigment (A) including component 1 to component 4 shown in Table 1 was placed in a Henschel mixer and pulverized and mixed at 800 rpm to 1,000 rpm at room temperature for 5 min to afford a mixture. The mixture and an oil part (B) including component 5 to component 8 shown in Table 1 were placed in a stirring vacuum emulsification bath, warmed to 70° C. to 80° C. with stirring, and uniformly mixed with stirring at 1,500 rpm to 2,600 rpm for 5 min to 10 min using a homo mixer. Here, the powder was sufficiently stirred before introduction into the vacuum emulsification bath.

(27) An aqueous part (C) was placed in an aqueous dissolution bath enabling temperature adjustment and stirring, and was uniformly mixed with stirring at a temperature of 60° C. to 70° C. Then, the aqueous part of the aqueous dissolution bath was added to the oil part of the vacuum emulsification bath, mixed with stirring at 1,500 rpm to 3,600 rpm for 5 min to 8 min using a homo mixer, and then cooled to 40° C. to 45° C.

(28) Thereafter, an additive (D) was added at about 40° C. to 45° C. and uniformly mixed with stirring. Moreover, mixing was performed with stirring at 1,500 rpm to 3,600 rpm for 2 min to 3 min using a homo mixer at 30° C. to 35° C. in the vacuum emulsification bath. After stirring, cooling to 30° C. to 35° C. was performed, finally obtaining BB cream.

(29) As described above, the powder in an embodiment of the present invention may be a planar powder, the amount of which may be, based on the total weight of the composition, 5 wt % to 30 wt %, preferably 5 wt % to 25 wt %, and more preferably 5 wt % to 20 wt %. If the amount of the powder is less than 5 wt %, the persistence may decrease. On the other hand, if the amount thereof exceeds 30 wt %, payoff may decrease. Hence, it is preferred that the wt % amount of the powder that is added be determined within the above range.

(30) In the present invention, the amount of the film-forming agent is preferably 0.1 wt % to 10 wt %. If the amount thereof is less than 0.1 wt %, the persistence may decrease. On the other hand, if the amount thereof exceeds 10 wt %, payoff may decrease. Hence, it is preferred that the amount of the film-forming agent that is added be determined within the above range.

(31) In the present invention, the amount of the silicone oil may be 10 wt % to 30 wt %, preferably 10 wt % to 25 wt %, and more preferably 12 wt % to 20 wt %. If the amount of the silicone oil is less than 10 wt %, the relative amount of the powder may increase and dry and transfer effects may decrease. On the other hand, if the amount thereof exceeds 30 wt %, persistence may decrease. Hence, it is preferred that the amount of the silicone oil that is added be determined within the above range.

(32) Here, the silicone oil that is added may include at least one selected from the group consisting of cyclopentasiloxane, cyclohexasiloxane, dimethicone, phenyl trimethicone, capryl dimethicone, diphenyl dimethicone and mixtures thereof.

(33) The amount of the spherical powder may be, based on the total weight of the composition, 0.1 wt % to 10 wt %, and preferably 0.1 wt % to 5 wt %. If the amount of the spherical powder is less than 0.1 wt %, payoff may decrease. On the other hand, if the amount thereof exceeds 10 wt %, skin contact may decrease. Hence, it is preferred that the amount of the spherical powder that is added be determined within the above range.

(34) Here, the spherical powder may include at least one selected from the group consisting of silica, polyurethane, polymethyl methacrylate, nylon, silicone resin powder and mixtures thereof.

(35) As described above, the cosmetic composition manufactured above is homogenized through pulverization and filtration (S30). The reason why the homogenization process (S30) is performed is that the powder has an oxygen system in its basic structure and aggregates with electrostatic attraction, making it possible to achieve high quality with more uniform particles after filtration.

(36) A sensory evaluation of 10 persons for the skin contact was performed using the cosmetic composition having increased skin contact and makeup persistence of each of Examples 1 and 2 and Comparative Example 1. The higher the score, the better the skin contact, and the scores are higher in the order of Example 2, Example 1, and Comparative Example 1, from which the skin contact was evaluated to improve with an increase in the amount of the film-forming agent.

(37) TABLE-US-00002 * Contact sensory test <5 out of 5>

(38) TABLE-US-00003 TABLE 2 Comparative Subject Example 1 Example 2 Example 1 1 4.2 4.5 3.8 2 4.1 4.3 3.6 3 3.6 3.8 4.3 4 3.8 4.4 4 5 4.2 3.8 3.9 6 3.9 4.4 4 7 4.4 4.6 3.6 8 3.8 3.7 4 9 4 3.8 3.3 10 4.2 4.4 3.6 Average 4.02 4.17 3.81

(39) Moreover, a sensory evaluation of 10 persons for the transfer was performed with Examples 1 and 2 and Comparative Example 1. The lower the score, the lower the transfer, and the scores are lower in the order of Example 2, Example 1, and Comparative Example 1, from which the transfer was evaluated to be decreased with an increase in the amount of the film-forming agent.

(40) TABLE-US-00004 * Transfer sensory test <5 out of 5>

(41) TABLE-US-00005 TABLE 3 Comparative Subject Example 1 Example 2 Example 1 1 3.6 3 3.4 2 3.4 3.6 4 3 3.6 3.3 4 4 4 3.2 3 5 3.4 3.8 4.2 6 3.6 3.4 4 7 3.3 3 3.9 8 3.5 2.8 3.6 9 3.3 3 3.6 10 3.2 2.8 3.4 Average 3.49 3.19 3.71

(42) 0.02 g of each sample was applied on a substrate 50 mm×50 mm in size, dried for 20 min, and then subjected to an adhesion test using a 3M 610 coating adhesion test tape.

(43) FIGS. 2A and 2B are images before and after the adhesion test of the cosmetic composition having increased skin contact and makeup persistence of Example 1 using a coating adhesion test tape, FIGS. 3A and 3B are images before and after the adhesion test of the cosmetic composition having increased skin contact and makeup persistence of Example 2 using a coating adhesion test tape, and FIGS. 4A and 4B are images before and after the adhesion test of the cosmetic composition having increased skin contact and makeup persistence of Comparative Example 1 using a coating adhesion test tape.

(44) When viewed with the naked eye, most of the sample remained for Example 2, followed sequentially by Example 1 and Comparative Example 1, and the sample was found to have better adhesion in Examples than in Comparative Example.

(45) The cosmetic composition having increased skin contact and makeup persistence according to an embodiment of the present invention may further include at least one active principle.

(46) Specifically, the active principle may include at least one selected from the group consisting of natural extract, oil, moisturizer, whitening agent, anti-wrinkling agent, acne reliever, atopy reliever, sunscreen, hair growth promoter, vitamin and derivatives thereof, amino acid, polypeptide, anti-inflammatory agent, female hormone agent, keratolytic agent, disinfecting agent, placenta, allantoin, yeast extract, collagen, elastin, DHA, EPA, ceramide, perfume and mixtures thereof.

(47) In the active principle, the oil may include at least one selected from the group consisting of fat and oil, wax, hydrocarbon oil, fatty acid ester oil, alcohol oil, butter, silicone oil, ester oil and mixtures thereof.

(48) Specifically, the fat and oil may include at least one selected from the group consisting of macadamia nut oil, olive oil, jojoba oil, almond oil, apricot seed oil, green tea oil, meadowfoam oil, sunflower oil, argan oil, camellia oil, avocado oil, soybean oil, grape seed oil, castor oil, rice bran oil and mixtures thereof.

(49) The wax may include at least one selected from the group consisting of carnauba wax, candelilla wax, jojoba oil, beeswax, lanolin, soybean wax, rice wax, silicone wax and mixtures thereof.

(50) The hydrocarbon oil may include at least one selected from the group consisting of liquid paraffin, paraffin, Vaseline, ceresin, microcrystalline wax, squalane and mixtures thereof.

(51) The fatty acid ester oil may include at least one selected from the group consisting of lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid and mixtures thereof, and the alcohol oil may include at least one selected from the group consisting of cetyl alcohol, stearyl alcohol, isostearyl alcohol, 2-octyldodecyl, 2-ethylhexanecetyl, diisostearyl malate and mixtures thereof.

(52) The butter may include at least one selected from the group consisting of shea butter, soy butter, mango butter and mixtures thereof.

(53) The silicone oil may include at least one selected from the group consisting of dimethicones, cyclomethicones, silicone polymers and mixtures thereof.

(54) The ester oil may include at least one selected from the group consisting of cetyl ethyl hexanoate, diglyceryl triisostearate, capric/caprylic triglyceride, glyceryl tri-2-ethylhexanoate, isononyl isononanoate, ethylhexyl isononanoate, ethylhexyl palmitate, isostearyl isostearate, neopentyl glycol dicaprate, neopentyl glycol diethylhexanoate, octyldodecyl myristate, pentaerythrityl tetraethylhexanoate, pentaerythrityl tetraisostearate, isotridecyl isononanoate, trimethylolpropane triisostearate, squalane and mixtures thereof.

(55) In the active principle, the moisturizer may include at least one selected from the group consisting of sodium lactate, hydroproline, sodium 2-phytolipo-5-carbonate, hyaluronic acid, sodium hyaluronate, ceramide, phytosterol, cholesterol, sitosterol and mixtures thereof.

(56) In the active principle, the sunscreen may include at least one selected from the group consisting of benzophenone derivatives, para-aminobenzoic acid derivatives, methoxy cinnamic acid derivatives, salicylic acid derivatives and mixtures thereof.

(57) In the active principle, the whitening agent may include at least one selected from the group consisting of arbutin and arbutin derivatives, kojic acid, vitamin C and vitamin C derivatives, and mixtures thereof.

(58) In the active principle, the hair growth promoter may include at least one of a blood circulation promoter and a topical stimulant. Here, the blood circulation promoter may include at least one selected from the group consisting of moonshine weed extract, cepharanthine, vitamin E and derivatives thereof, gamma-oryzanol, proteoglycan and mixtures thereof.

(59) Also, the topical stimulant in the hair growth promoter may include at least one selected from the group consisting of pepper tincture, ginger tincture, cantharis tincture, nicotinic acid benzyl ester and mixtures thereof.

(60) In the active principle, the vitamin and derivatives thereof are not particularly limited, but may include at least one selected from the group consisting of vitamin A and derivatives thereof, vitamin B1, B2, B6, E and derivatives thereof, vitamin D, H, K, pantothenic acid and derivatives thereof, biotin, panthenol and mixtures thereof.

(61) In the active principle, the amino acid may include at least one selected from the group consisting of cystine, cysteine, methionine, serine, leucine, tryptophan, amino acid extract, EGF (Epidermal Growth Factor), IGF (Insulin-like Growth Factor), FGF (Fibroblast Growth Factor), kappa-peptide and mixtures thereof.

(62) In the active principle, the anti-inflammatory agent may include at least one selected from the group consisting of beta-glycyrrhizic acid, glycyrrhizic acid derivatives, aprene, aminocaproic acid, hydrocortisone, beta-glucan, licorice and mixtures thereof.

(63) In the active principle, the acne treatment agent may include at least one selected from the group consisting of estradiol, estrogen, ethinyl estradiol, triclosan, azelaic acid and mixtures thereof.

(64) In the active principle, the disinfecting agent may include at least one selected from the group consisting of benzalkonium chloride, benzethonium chloride, halocarbon and mixtures thereof.

(65) In the active principle, the female hormone agent may be estrogen, and the estrogen may be at least one of estradiol, ethinyl estradiol, and isoflavone, which is a phytoestrogen.

(66) In the active principle, the keratolytic agent may include at least one selected from the group consisting of sulfur, salicylic acid, AHA, BHA, resorcin and mixtures thereof.

(67) In the active principle, the natural extract may include extracts of animals and plants, marine animals and plants or seaweed, or components obtained therefrom (functional ingredients having effects such as moisturizing, hydrating, pore-tightening, trouble reduction, whitening, elasticity restoration, wrinkle prevention, etc.).

(68) Specifically, the natural extract may include at least one selected from the group consisting of Hamamelis japonica, Lamium album, Mucuna, Pinus, licorice, aloe, chamomile, rosehip, hinokitiol, horse chestnut, beta-carotene, ginseng extract, Luffa aegyptiaca, cucumber, layer extract, brown seaweed extract, Dioscorea polystachya, birch sap and mixtures thereof.

(69) Also, the natural extract may include at least one selected from the group consisting of Ascophyllum nodosum extract, Iceland Alps glacier water, deep sea microorganisms, Antarctic microorganisms, Mourera fluviatilis extract, Arctic yeast, Arctic brown algae, sea parsley (Dulse), Picea abies (Nidiformis) extract and mixtures thereof.

(70) In the cosmetic composition having increased skin contact and makeup persistence and the method of manufacturing the same according to embodiments of the present invention, skin contact and makeup persistence can be increased due to the use of a formulation surface-treated with a modified silicone film-forming agent, and moreover, powder dispersibility can be improved, thus making it possible to provide a superior use sensation to a user and to maintain high-quality makeup for a long time by overcoming problems in which the makeup effect does not last long.

(71) Although the preferred embodiments of the present invention have been disclosed for illustrative purposes, those skilled in the art will appreciate that various modifications, additions and substitutions are possible without departing from the scope and spirit of the invention as disclosed in the accompanying claims. Therefore, all modifications and the like basically including the elements in the claims of the present invention should be considered to be included in the technical scope of the present invention.