ONE-STEP INTEGRALLY-FORMED BAMBOO SLEEPER AND PREPARATION METHOD THEREOF

Abstract

The present invention discloses a one-step integrally-formed bamboo sleeper. For the one-step integrally-formed bamboo sleeper, a bamboo unit is used as a raw material, to be dried and modified at the temperature of 110-180° C., and then subject to adhesive dipping, adhesive throwing, solidification, dopamine solution treatment, anti-mildew and/or anti-corrosion and/or anti-insect treatment, and fastening, to obtain the one-step integrally-formed bamboo sleeper with a density of 0.9-1.5 g/cm.sup.3. The present invention further provides a preparation method for the foregoing bamboo sleeper. The bamboo sleeper prepared in the present invention has a suitable elastic modulus, and applicable for ballasted tracks of railways and urban rail transit systems.

Claims

1. A one-step integrally-formed bamboo sleeper, obtained by using a bamboo unit as a raw material, dried and modified at the temperature of 110-180° C., undergone adhesive dipping, adhesive throwing, curing, dopamine solution treatment, and anti-mildew and/or anti-corrosion and/or anti-insect treatment, and then fastened, and a density of the one-step integrally-formed bamboo sleeper is 0.9-1.5 g/cm.sup.3.

2. A preparation method of a one-step integrally-formed bamboo sleeper, including the following steps: step 1) drying and modifying the pretreated bamboo unit by using water vapor with a superheat degree of 10-80° C., until a water content of the bamboo unit is 8-20%, to obtain a dried and modified bamboo unit; step 2) dipping the dried and modified bamboo unit obtained in the step 1) in an adhesive to perform adhesive dipping, adhesive throwing, draining, and drying, until the water content of the bamboo unit is 10%-16%, to obtain a blank; step 3) curing and solidifying the blank in the step 2), to obtain a bamboo sleeper billet; step 4) coating a dopamine solution on a surface of the bamboo sleeper billet in the step 3), and then performing anti-mildew and/or anti-corrosion and/or anti-insect treatment, to obtain a bamboo sleeper; and step 5) fastening the bamboo sleepers in the step 4) by using a fastener, to obtain a one-step integrally-formed bamboo sleeper.

3. The method of claim 2, wherein the step 3) specifically includes: assembling the blanks in the step 2) to obtain a slab, and simultaneously pressing and heating upper and lower parts of the slab to cure and solidify it, to obtain the bamboo sleeper billet, where the pressure in the center of the slab is 15-30 MPa, and the temperature is 120-160° C.

4. The method of claim 3, wherein a thickness of the slab is D, and a pressing time is t, where, t=D×30, a unit oft is s, and a unit of D is mm.

5. The method of claim 2, wherein the step 3) specifically includes: after placing the blanks in the step 2) in a cold compacting mold for compacting to a predetermined target thickness, fastening the cold compacting mold and the blanks and then placing the fastened cold compacting mold and blanks in a device or a drying kiln filled with heat conduction oil for curing and solidifying, and then cooling, to obtain the bamboo sleeper billet; the temperature for curing is 120-160° C., and the time is 1-9 h.

6. The method of claim 5, wherein the medium in the drying kiln is wet air, flue gas, or superheated water vapor.

7. The method of claim 5, wherein when the cured and solidified blanks are cooled to be at a temperature 20-40° C. higher than the indoor temperature, the cold compacting mold is removed to obtain the bamboo sleeper billet.

8. The method of claim 2, wherein the step 3) specifically includes: curing the blanks in the step 2) by a high-frequency assisted hot pressing, to obtain the bamboo sleeper billet, where in the high-frequency assisted hot pressing, a power supply input voltage is 380 V, a DC output voltage is 4-7 kV, an oscillation frequency is 6.5-7.3 MHz, a pressure is greater than 20 MPa, and a temperature is 120-140° C.

9. The method of claim 2, wherein the anti-mildew and/or anti-corrosion and/or anti-insect treatment in the step 4) specifically includes: coating the dopamine solution on a surface of the bamboo sleeper billet and drying, coating a titanyl sulfate solution, drying, and then coating a silver nitrate solution, and drying, to obtain the bamboo sleeper.

10. The method of claim 2, wherein the pretreating in the step 1) specifically includes: removing an outer green part and an inner yellow part from the bamboo unit, steaming and softening, and then washing and grinding, to obtain the pretreated bamboo unit.

11. The method of claim 3, wherein the anti-mildew and/or anti-corrosion and/or anti-insect treatment in the step 4) specifically includes: coating the dopamine solution on a surface of the bamboo sleeper billet and drying, coating a titanyl sulfate solution, drying, and then coating a silver nitrate solution, and drying, to obtain the bamboo sleeper.

12. The method of claim 4, wherein the anti-mildew and/or anti-corrosion and/or anti-insect treatment in the step 4) specifically includes: coating the dopamine solution on a surface of the bamboo sleeper billet and drying, coating a titanyl sulfate solution, drying, and then coating a silver nitrate solution, and drying, to obtain the bamboo sleeper.

13. The method of claim 5, wherein the anti-mildew and/or anti-corrosion and/or anti-insect treatment in the step 4) specifically includes: coating the dopamine solution on a surface of the bamboo sleeper billet and drying, coating a titanyl sulfate solution, drying, and then coating a silver nitrate solution, and drying, to obtain the bamboo sleeper.

14. The method of claim 6, wherein the anti-mildew and/or anti-corrosion and/or anti-insect treatment in the step 4) specifically includes: coating the dopamine solution on a surface of the bamboo sleeper billet and drying, coating a titanyl sulfate solution, drying, and then coating a silver nitrate solution, and drying, to obtain the bamboo sleeper.

15. The method of claim 7, wherein the anti-mildew and/or anti-corrosion and/or anti-insect treatment in the step 4) specifically includes: coating the dopamine solution on a surface of the bamboo sleeper billet and drying, coating a titanyl sulfate solution, drying, and then coating a silver nitrate solution, and drying, to obtain the bamboo sleeper.

16. The method of claim 8, wherein the anti-mildew and/or anti-corrosion and/or anti-insect treatment in the step 4) specifically includes: coating the dopamine solution on a surface of the bamboo sleeper billet and drying, coating a titanyl sulfate solution, drying, and then coating a silver nitrate solution, and drying, to obtain the bamboo sleeper.

17. The method of claim 3, wherein the pretreating in the step 1) specifically includes: removing an outer green part and an inner yellow part from the bamboo unit, steaming and softening, and then washing and grinding, to obtain the pretreated bamboo unit.

18. The method of claim 4, wherein the pretreating in the step 1) specifically includes: removing an outer green part and an inner yellow part from the bamboo unit, steaming and softening, and then washing and grinding, to obtain the pretreated bamboo unit.

19. The method of claim 5, wherein the pretreating in the step 1) specifically includes: removing an outer green part and an inner yellow part from the bamboo unit, steaming and softening, and then washing and grinding, to obtain the pretreated bamboo unit.

20. The method of claim 6, wherein the pretreating in the step 1) specifically includes: removing an outer green part and an inner yellow part from the bamboo unit, steaming and softening, and then washing and grinding, to obtain the pretreated bamboo unit.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0037] FIG. 1 is a schematic flowchart of a process of Example 1 of the present invention.

[0038] FIG. 2 is a schematic structural diagram of a one-step integrally-formed bamboo sleeper of Example 1 of the present invention.

[0039] FIG. 3 is a test result diagram of the one-step integrally-formed bamboo sleeper of Example 1 of the present invention.

DESCRIPTION OF THE EMBODIMENTS

[0040] The following will describe the present invention in detail in combination with the specification and the specific embodiments. Unless otherwise specified, the following materials and instruments are commercially available.

[0041] Example 1 (by using a bamboo sleeper with a length of 1800 mm, a width of 200 mm, and a thickness of 140 mm as an example)

[0042] As shown in FIG. 1, the preparation method of the one-step integrally-formed bamboo sleeper in this example specifically has the following steps.

[0043] (1) A 4-year raw moso bamboo was selected and cut into sections each with a length of 1900 mm±10 mm, to obtain a bamboo cylinder section.

[0044] (2) The bamboo cylinder section was cleaved, from which an outer green part and a yellow inner part were 100% removed, then placed in an ammonia liquid with a pH value of 8.5 for steaming for 30 min, washed, and then mechanically ground to form a filamentous bamboo unit.

[0045] (3) The filamentous bamboo unit was dried by a dry bulb at 150° C. and by superheat water vapor at of 30° C., until a water content of the filamentous bamboo unit was approximately 13%, to obtain a dried and modified filamentous bamboo unit. High-temperature hydrothermal modification treatment can kill microorganisms and insect pests, and can also decompose carbohydrate substances such as starch in bamboo. The decrease in the mechanical strength caused by high temperature can be ameliorated by polydopamine treatment in the subsequent process, and the polydopamine did not affect the subsequent gluing and can prevent water from entering the filamentous bamboo unit.

[0046] (4) The dried and modified filamentous bamboo unit was dipped in a phenolic resin solution with a solid content of 25%, and was then subject to ultrasonic pulse assisted normal-pressure treatment for 20 min, adhesive throwing, draining, and then drying, until the water content of the filamentous bamboo unit was controlled to 15%, to obtain a blank.

[0047] In other examples, the adhesive dipping may be a treatment for 10-20 min at a pressure of 0.2-0.8 MPa, which can also achieve the same or similar technical effect.

[0048] (5) The blanks were paved and assembled in a prefabricated mold, and the phenolic resin adhesive in the filamentous bamboo unit was solidified by high-frequency assisted hot pressing, to obtain a one-step integrally-formed bamboo sleeper billet.

[0049] In this example, parameters of the high-frequency assisted process were: a power supply input voltage of 380 V, a DC output voltage of 6 kV, and an oscillation frequency of 6.9 Mhz. Parameters of the hot pressing process were: a pressure of 20 MPa, a temperature of 130° C., and a hot pressing time of 4200 s.

[0050] In other examples, the high-frequency assisted process may also be replaced with a bidirectional pressure-bidirectional heating molding technology, a room temperature cold pressing mold locking-high-temperature curing and solidifying technology, or a high-frequency assisted one-way high-temperature hot pressing technology, so that the adhesive can be fully cured and the filamentous bamboo units can be tightly connected together.

[0051] (6) The bamboo sleeper billet was mechanically processed, and then coated, in a manner of spraying, by a 0.05 mg/ml dopamine solution (a Tris buffer liquid was added in advance to adjust the pH of the dopamine solution to be 8) three times, where each time before spraying, it was requited to wait for the last coating to be fully dried, and a self-made Ag/TiO.sub.2-doped multifunctional treatment liquid was coated on the surface of the bamboo sleeper billet three times, to obtain a bamboo sleeper undergone anti-mildew treatment. The specific steps were as follows.

[0052] (6.1) The bamboo sleeper billet was mechanically processed, repeatedly coated by a 0.05 mg/mL dopamine solution of which a pH value was adjusted to 8 by a Tris buffer solution, where each time it was required to wait for the coating layer to be dried to be an extent of non-stick in hand, and then dried at 70° C. for 40 min, to obtain a bamboo sleeper billet covered by a polydopamine membrane.

[0053] (6.2) A surface of the bamboo sleeper billet covered by the polydopamine membrane was coated by a 0.01 mol/L titanyl sulfate solution and then coated by an ammonia liquid (in other examples, a sodium hydroxide solution can be used); and the mixed liquids were coated and a pH test paper was used to measure a pH value of the surface of the bamboo sleeper billet, until the pH value was 9; and when the coating layer was non-stick in hand, the bamboo sleeper billet was dried at 70° C. for 60 min, to obtain a bamboo sleeper billet loaded with TiO.sub.2.

[0054] (6.3) The bamboo sleeper billet loaded with TiO.sub.2 was coated by a 0.001 mol/L silver nitrate solution three times, and after the coating layer was non-stick in hand, dried at 80° C. until a water content of the bamboo sleeper billet loaded with TiO.sub.2 was approximately 10%, to obtain a bamboo sleeper undergone anti-mildew treatment.

[0055] (7) The bamboo sleeper undergone anti-mildew treatment was locked and fastened by two stainless steel ferrules with a thickness of 2 mm and a width of 50 mm, where an edge of each of the steel ferrules at the left and right ends of the bamboo sleeper had a distance of 230 mm with each corresponding end portion of the bamboo sleeper, to obtain a one-step integrally-formed bamboo sleeper. In order to prevent fiber separation caused by repeated load applying or overloading of the bamboo sleeper during use, stainless steel ferrules or fasteners made of other materials were used for locking and fastening.

[0056] In this example, the bamboo was subject to multiple coupled techniques such as high-temperature hydrothermal drying modification multi-effect treatment, gluing, Ag/TiO.sub.2-doped protection for a surface, locking and fastening, to produce a one-step integrally-formed bamboo sleeper, as shown in the FIG. 2. The specific process flow was as follows.

[0057] Original bamboo cutting.fwdarw.cleaving.fwdarw.removing an outer green part and an inner yellow part.fwdarw.basic liquid assisted steaming and softening.fwdarw.washing.fwdarw.grinding and scattering.fwdarw.high-temperature hydrothermal drying multi-effect treatment.fwdarw.phenolic resin dipping.fwdarw.drying.fwdarw.billet paving and assembling.fwdarw.high-frequency assisted hot pressing.fwdarw.mechanical processing.fwdarw.polydopamine-Ag/TiO.sub.2-doped treatment.fwdarw.steel ferrule fastening.fwdarw.bamboo sleeper.

[0058] Tests of the density, UV resistance, water absorption thickness expansion rate, anti-skid performance, bending elastic modulus and horizontal shear strength of the manufactured bamboo sleeper billet were carried out in laboratory, as shown in the FIG. 3, which indicated that the bamboo sleeper manufactured in this example met the requirements of high-value and green sleepers in track construction.

Example 2

[0059] This example is substantially the same as Example 1, with the only difference in that: the high-frequency assisted high-temperature hot pressing process is replaced with a bidirectional pressure-bidirectional heating molding technology, and the specific steps were as follows:

[0060] assembling blanks, to obtain a slab, and placing the slab on a pad to simultaneously press and heat upper and lower parts of the slab for 70 min, to cure and solidify the slab, to obtain a bamboo sleeper billet, where a center of the slab had a pressure of 20 Mpa and a temperature of 130° C.

Example 3

[0061] This example is substantially the same as Example 1, with the only difference in that: the high-frequency assisted high-temperature hot pressing process is replaced with a room temperature cold pressing mold locking-high-temperature curing and solidifying technology, and the specific steps were as follows:

[0062] placing a blank in a cold pressing mold, compacting the blank in the mold by a cold pressing machine, to compact the blank to 140 mm; then locking the mold and the blank; feeding the mold loaded with the blank fed together to a drying kiln at a high temperature of 130° C. for successively 5 h, to enable the slab to be fully cured and solidified; and after the solidification, gradually cooling the mold and the slab in an indoor environment, and when the slab was at a temperature 40° C. higher than the indoor temperature, removing the mold, where the bamboo sleeper slab is cured and solidified, to obtain the bamboo sleeper billet.

[0063] Although the present invention has been disclosed in preferred embodiments above, it is not intended to limit the present invention. Any person skilled in the art may make many possible variants and modifications to the present invention without departing from the scope of the present invention by using the foregoing disclosed technical content, or modify it to equivalent embodiments of equivalent variants. Therefore, any simple amendments, equivalent variants, and modifications made to the foregoing embodiments according to the technical essence of the present invention without departing from the content of the technical solution of the present invention should fall within the scope of protection of the technical solution of the present invention.