Tire Cold Retreading Method

Abstract

A method for the cold retreading of a tyre (1) comprising the following steps: —a removal step, during which the old, worn tread is removed from the tyre in order to expose an equatorial surface (2) of a casing (3) of the tyre (1); —a deposition step, during which a cushion (4) and a pre-cured tread strip (6) provided with a tread pattern are deposited around the equatorial surface (2) of the casing (3); and—a curing step, during which the cushion (4) arranged between the casing (3) and the pre-cured tread strip (6) is cured. The retreading method also comprises a conductive interposition step, during which a conductive adhesive compound (5) is deposited between said cushion (4) and said pre-cured tread strip (6) and/or between said cushion (4) and said casing (3). The conductive adhesive compound (5) comprises at least one conductive material in a quantity ranging from 5 to 20% by weight and chosen among graphene, graphite and a carbon black having a surface area which is greater than or equal to 300 m.sup.2/gr. The curing step comprises a connection operation, during which said conductive adhesive (5) compound is connected either to a heat source (S) or to a power source (S) so as to transmit the heat to the cushion (4).

Claims

1-7. (canceled)

8. A method for a cold retreading of a tire, the method comprising the steps of: removing a tread from the tire in order to expose an equatorial surface of a casing of the tire; depositing a cushion and a pre-cured tread strip with a tread pattern around the equatorial surface of the casing; interposing a conductive adhesive compound between the cushion and the pre-cured tread strip and/or between the cushion and the casing, the conductive adhesive compound comprising at least one conductive material in a quantity ranging from 5% to 20% by weight and chosen from among graphene, graphite, and carbon black having a surface area that is greater than or equal to 300 m.sup.2/gr; and curing the cushion arranged between the casing and the pre-cured tread strip, during which the conductive adhesive compound is connected to a heat source or a power source to transmit heat to the cushion.

9. The method of claim 8, wherein the conductive adhesive compound further comprises an organic solvent.

10. The method of claim 9, wherein the organic solvent comprises n-heptane.

11. The method of claim 8, further comprising: prior to the curing step, depositing a filler in a fluid state on the pre-cured tread strip to form a filler coating that covers the pre-cured tread strip.

12. The method of claim 11, further comprising: during the curing step, applying a radial pressure on the pre-cured tread strip by pressing, from an outside of the tire, against the filler coating.

13. The method of claim 12, further comprising: following the curing step, removing the filler from the pre-cured tread strip.

14. The method of claim 12, wherein applying the radial pressure on the pre-cured tread strip comprises pressing a plurality of pressing bodies of a curing mold against the filler coating.

15. The method of claim 14, wherein each of the plurality of pressing bodies comprises a circular sector and the plurality of pressing bodies form a ring around the tire.

16. The method of claim 11, wherein the filler comprises a material that shrinks when dry.

17. The method of claim 16, wherein the shrinking material comprises clay.

18. The method of claim 8, wherein the cushion comprises raw rubber.

19. The method of claim 8, wherein the conductive adhesive compound forms a strip, the strip having one or more free ends, the one or more free ends configured to connect the conductive adhesive compound either to the heat source or the power source to transmit heat to the cushion.

20. The method of claim 8, wherein the conductive adhesive compound further comprise at least one of natural rubber, butylphenol-acetone, zinc oxide (ZnO), sulphur, or N-Tert-Butyl-2-benzothiazolesulfenamide (TBBS), and combinations thereof.

21. The method of claim 8, wherein the step of curing further comprises curing the cushion arranged between the casing and the pre-cured tread strip at a temperature from 100° C. to 125° C.

22. The method of claim 8, wherein the step of curing further comprises curing the cushion arranged between the casing and the pre-cured tread strip at a pressure from 4 bar to 6 bar.

23. A tire which is retreaded via the cold retreading method of claim 8.

24. A method for a cold retreading of a tire, the method comprising the steps of: removing a tread from the tire in order to expose an equatorial surface of a casing of the tire; depositing a cushion and a pre-cured tread strip provided with a tread pattern around the equatorial surface of the casing; interposing a conductive adhesive compound between the cushion and the pre-cured tread strip and/or between the cushion and the casing; connecting the conductive adhesive compound either to a heat source or a power source to transmit heat to the cushion; depositing a filler in a fluid state on the pre-cured tread strip to form a filler coating that covers the pre-cured tread strip; applying a radial pressure on the pre-cured tread strip by pressing, from an outside of the tire, against the filler coating; curing the cushion arranged between the casing and the pre-cured tread strip; and removing the filler from the pre-cured tread strip.

25. The method of claim 24, wherein the conductive adhesive compound comprises: at least one conductive material in a quantity ranging from 5% to 20% by weight and chosen among graphene, graphite, and carbon black having a surface area that is greater than or equal to 300 m.sup.2/gr.

26. The method of claim 24, wherein the conductive adhesive compound comprises: an organic solvent; and at least one of natural rubber, butylphenol-acetone, zinc oxide (ZnO), sulphur, or N-Tert-Butyl-2-benzothiazolesulfenamide (TBBS), and combinations thereof.

27. The method of claim 24, wherein the conductive adhesive compound forms a strip, the strip having one or more free ends, the one or more free ends configured to connect the conductive adhesive compound either to the heat source or the power source so as to transmit heat to the cushion.

Description

[0026] Hereinafter there is a description of an embodiment of the invention, by mere way of explanatory and non-limiting example, with reference to the accompanying drawings, wherein:

[0027] FIG. 1 is a schematic view of a tire, in which the old, worn tread was mechanically removed, thus exposing an equatorial surface of a respective casing;

[0028] FIG. 2 is a schematic view of the wrapping of a cushion around a casing of a tire to be retreaded;

[0029] FIG. 3 is a schematic view of the deposition of a conductive adhesive compound on a cushion;

[0030] FIG. 4 is a schematic view of the wrapping of a pre-cured tread strip around the cushion with the interposition of the conductive adhesive compound;

[0031] FIG. 5 is a schematic view of the application of a filler on the previously wrapped pre-cured tread strip;

[0032] FIG. 6 is a schematic view of a compression during the curing of a retreaded tire;

[0033] FIG. 7 is a schematic view of a removal of a filler from the pre-cured tread strip after curing.

[0034] In FIG. 1, number 1 indicates, as a whole, a tire, in which the old, worn tread was mechanically removed, thus exposing an equatorial surface 2 of a respective casing 3.

[0035] The procedure with which the old, used tread is removed is known and, since it is not relevant for the invention, it will not be discussed any further.

[0036] FIG. 2 shows a deposition step, during which a cushion 4 is wrapped on the equatorial surface 2 of the casing 3. As a person skilled in the art knows, the cushion is an intermediate strip of raw rubber, which fulfils a bonding function between the casing of the used tire and the new, previously cured tread strip.

[0037] FIG. 3 shows a conductive interposition step, during which a conductive adhesive compound 5 is deposited on the exposed surface of the cushion 4. According to FIG. 3, the conductive adhesive compound was not deposited on the entire exposed surface of the cushion 4, but it was deposited in the form of a strip along a broken line, which extends on the exposed surface of the cushion 4 as much as possible. In particular, in this specific example, the conductive adhesive compound is based on n-heptane, where graphite was dissolved in a quantity amounting to 15% by weight.

[0038] By way of example, Table I shows the phr composition of the conductive adhesive compound with an indication of the weight percentages only in relation to the solvent and the conductive material.

TABLE-US-00001 TABLE I % by weight of n-heptane 30 Natural rubber 100 Resin: butylphenol-acetone 20 Carbon black 10 ZnO 1 Sulphur 1 TBBS 1 % by weight of conductive compound* 15 *The conductive material is chosen among graphite, graphene and carbon black having a surface area which is greater than or equal to 300 m.sup.2/gr.

[0039] Experiments have shown that the quantity of conductive material (chosen among graphite, graphene and carbon black having a surface area which is greater than or equal to 300 m2/gr), in order to be effective for the purposes of the invention, must be comprised in the conductive adhesive compound in a quantity ranging from 5 to 20% by weight.

[0040] The strip of the conductive adhesive compound 5 has two free ends 5a, which are useful to create an electrical or thermal contact, as described more in detail below.

[0041] Contrary to what described above in the embodiment, the conductive adhesive compound 5 can be arranged between the cushion 4 and the equatorial surface 2 of the casing 3; or it can be arranged both between the cushion 4 and the equatorial surface 2 of the casing 3 and between the cushion 4 and the new pre-cured tread strip.

[0042] Contrary to what described above in the embodiment, the conductive adhesive compound can be deposited according to a different conformation, provided that it extends with continuity on the surface of the cushion and has a portion arranged so as to be connected to a power source or to a heat source.

[0043] FIG. 4 shows another operation of the deposition step, during which a pre-cured tread strip 6 is wrapped on the cushion 4 on which the conductive adhesive compound 5 was previously deposited. It should be pointed out that the pre-cured tread strip 6, since it has already been cured in a suitable mold, has a defined tread pattern.

[0044] FIG. 5 shows a coating step, during which, after the wrapping of the pre-cured tread strip 6 and before subjecting the tire 1 to a curing step, a filler 7 in the fluid state is deposited on the pre-cured tread strip 6. The filler 7 completely fills the pattern of the tread (namely, it penetrates the grooves of the tread pattern) and forms a coating which covers the pre-cured tread strip 6. In other words, the filler 7 creates a “negative” of the pre-cured tread strip 6.

[0045] In particular, the filler 7 is applied on the pre-cured tread strip 6 so as to completely cover it and, hence, have, on the outside, a flat equatorial surface (namely, a flat surface, i.e. without recesses and grooves). In other words, the filler 7 is used to form a coating that “levels off” the pre-cured tread strip 6, thus offering, towards the outside, a flat equatorial surface (namely, a smooth surface without recesses and grooves).

[0046] In the embodiment shown in FIG. 5, the filler 7 is applied on the pre-cured tread strip 6 by means of an applying device 8 after the pre-cured tread strip 6 has been wrapped around the casing 3 (namely, when the pre-cured tread strip 6 has an annular shape).

[0047] According to a preferred embodiment, the filler 7 can be made of clay, which has the advantage of being easy to be found, not very expensive and recyclable for further retreading operations or in general. Furthermore, the natural shrinking of the clay when dry also allows the filler 7 to be easily removed from the pattern of the tread.

[0048] FIG. 6 shows a curing and compression step, during which the tire 1 is housed inside a curing mold 9, which consists of a plurality of pressing bodies 10, which are each shaped like a circular sector and form, all together, a ring designed to contain, on the inside, the tire 1.

[0049] According to the figure, the two ends 5a of the conductive adhesive compound 5 are connected to a heat or power source, which is schematically shown and indicated with S. In case S is a power source, due to Joule effect, the conductive adhesive compound 5 heats up and the heat is transferred to the cushion 4, causing the curing thereof.

[0050] In this way, heat can be transferred only to the portion (cushion) of the tire 1 that is involved in the curing process. This possibility offers the great advantage of not having to subject the entire tire to a heating process, with the consequence both that already cured parts of the tire do not risk being deteriorated and that the curing step is quicker.

[0051] Since the conductive adhesive compound 5 also has heat conductive properties, an alternative to what described above lies in connecting the conductive adhesive compound 5 to a heat source. In this case, S indicates a heat source instead of a power source.

[0052] Each pressing body 10 is radially moved (hence, is radially pushed against the tire 1) by an actuator 11 (for example a pneumatic or hydraulic cylinder). According to a preferred embodiment, the actuators 11 are designed to apply on the pressing body 10 a radial pressure towards the centre (namely, a radial pressure compressing the tire 1) with an adjusted force, which is determined in such a way that, during the curing process, the tire 1 (namely, the pre-cured tread strip 6 which is part of the tire 1) is radially compresses with a desired pressure; by way of example, the actuators 11 could use, in order to radially push the pressing bodies 10, a pneumatic or hydraulic system with an adjusted pressure or they could use a completely mechanical system provided with adjusted springs.

[0053] During the curing process, the tire 1 is kept at ambient pressure and a radial pressure is mechanically applied to the pre-cured tread strip 6 by means of the pressing bodies 10 of the curing mold 9 and with the interposition of the filler 7. In other words, the pressing bodies 10 of the curing mold 9 press against the filler 7, which has, on the outside, a smooth surface (hence, the pressure exerted by the pressing bodies 10 is distributed in a uniform manner on the entire filler 7); the filler 7 transmits the pressure exerted by the pressing bodies 10 in a uniform manner to the entire pre-cured tread strip 6, since the filler 7 is homogeneously distributed on the entire pre-cured tread strip 6 (namely, even in all the grooves of the tread pattern). As a consequence, the filler 7 acts like a “distributor” of the pressure exerted by the pressing bodies 10 on the entire pre-cured tread strip 6, since it is a coating that reproduces in negative the shape of the pre-cured tread strip 6.

[0054] FIG. 7 shows a removal step, during which, after the curing step, the filler 7 is removed from the pre-cured tread strip 6 by means of a suitable device, which is schematically shown and indicated with 12, and with this operation the tire 1 retreading process ends.

[0055] To sum up, the cold retreading method according to the invention makes sure that the curing step is carried out without using autoclaves and by subjecting the sole cushion to heating. This leads to the important advantage of having a quicker and safer curing (avoiding the safety problems caused by the use of autoclaves) and of preventing, to a significant extent, the already cured parts of the tire from having to undergo a heating process, which could jeopardize them. These results are obtained thanks to the presence of a conductive adhesive compound arranged between the cushion and the pre-cured tread strip and/or between the cushion and the casing.

[0056] Furthermore, the fact that the pre-cured tread strip is covered with the filler prevents manufacturers from having to use vacuum envelops, thus avoiding the complicated tire dressing/undressing operations and the risks of breaking of the envelops.