Processes for producing superalloys and superalloys obtained by the processes

Abstract

A method of producing a metal superalloy may include: providing a charge of metal materials; melting the charge of metal materials in an electric-arc furnace to obtain a first melt of the charge of metal materials; performing Argon Oxygen Decarburization (A.O.D.) treatment on the first melt to obtain a decarburized and refined first melt; solidifying the decarburized and refined first melt to obtain first ingots; melting the first ingots in a Vacuum Induction Degassing and Pouring (V.I.D.P.) furnace to obtain a second melt; solidifying the second melt to obtain second ingots; melting the second ingots in a Vacuum Arc Remelting (V.A.R.) furnace to obtain a third melt; and solidifying the third melt to obtain the metal superalloy. The charge of metal materials may have a weight greater than or equal to forty tons and less than or equal to sixty tons.

Claims

1. A method of producing a metal superalloy, the method comprising: providing a charge of metal materials; melting the charge of metal materials in an electric-arc furnace to obtain a first melt of the charge of metal materials; performing Argon Oxygen Decarburization (A.O.D.) treatment on the first melt to obtain a decarburized and refined first melt; solidifying the decarburized and refined first melt to obtain first ingots; melting the first ingots in a Vacuum Induction Degassing and Pouring (V.I.D.P.) furnace to obtain a second melt; solidifying the second melt to obtain second ingots; melting the second ingots in a Vacuum Arc Remelting (V.A.R.) furnace to obtain a third melt; and solidifying the third melt to obtain the metal superalloy; wherein the charge of metal materials has a weight greater than or equal to forty tons and less than or equal to sixty tons, and wherein the decarburized and refined first melt is obtained by performing the A.O.D. treatment on the first melt while the first melt is in a molten state as a result of the melting of the charge of metal materials in the electric-arc furnace.

2. The method of claim 1, wherein the melted first ingots in the V.I.D.P. furnace have a weight greater than or equal to ten tons and less than or equal to twenty tons.

3. The method of claim 1, wherein the solidifying of the second melt to obtain the second ingots comprises casting the second melt into molds.

4. The method of claim 1, wherein the solidifying of the decarburized and refined first melt to obtain the first ingots comprises cooling the decarburized and refined first melt after casting the decarburized and refined first melt into first ingot molds, and wherein the solidifying of the second melt to obtain the second ingots comprises cooling the second melt after casting the second melt into second ingot molds.

5. The method of claim 4, wherein the first ingot molds have a shape such that the first ingots have a cylindrical shape, and wherein the second ingot molds have a shape such that the second ingots have the cylindrical shape.

6. The method of claim 1, wherein the metal superalloy is an iron-based or nickel-based alloy that comprises variable amounts of Chromium, Cobalt, Niobium, Titanium, and/or other elements.

7. The method of claim 1, wherein after solidifying the third melt to obtain the metal superalloy, the metal superalloy undergoes thermomechanical processing that comprises press forging.

8. The method of claim 7, wherein after solidifying the third melt to obtain the metal superalloy and the thermomechanical processing that comprises the press forging, the metal superalloy, when thicknesses of less than 250-300 millimeters (mm) are required, undergoes further thermomechanical processing comprising: radial four-die forging using a hydraulic RUMX machine; and continuous radial deformation forging in a rolling plant.

9. The method of claim 1, wherein the metal superalloy has less than 5 parts per million (ppm) of Sulfur.

10. The method of claim 1, wherein the metal superalloy has less than 1 part per million (ppm) of Bismuth.

11. The method of claim 1, wherein the metal superalloy has less than 1 part per million (ppm) of Selenium.

Description

BRIEF DESCRIPTION OF THE FIGURES

(1) Further features and advantages of the present description will appear more clearly from the illustrative, non-limiting description of a preferred, non-exclusive embodiment of a method of producing superalloys, as well as superalloys obtained with the method as shown in the accompanying FIG. 1, which shows a flowchart of the production of a superalloy according to the present invention.

DETAILED DESCRIPTION

(2) Even when this is not expressly stated, the individual features as described with reference to the particular embodiments shall be intended as auxiliary to and/or interchangeable with other features described with reference to other exemplary embodiments.

(3) Referring to the accompanying FIGURE, numeral 1 designates the method of producing a metal superalloy 10, i.e. a metal alloy that is mainly composed of Iron and Nickel with the addition of variable amounts of Chromium, Cobalt, Titanium and other elements.

(4) In particular, the method 1 is a triple-melt method including, as further explained below, a triple-melt process for melting and remelting a charge of base material 2.

(5) The method 1 comprises a first step 3 in which the aforementioned charge of materials 2 is provided in an amount ranging from forty to sixty tons, preferably of fifty tons.

(6) This first step 3 includes melting the aforementioned charge of materials in an electric-arc furnace to obtain a first melt 3A.

(7) The electric-arc furnace is a conventional furnace and will not be further described.

(8) Once the first melt 3A of the entire charge of materials 2 has been obtained by means of the electric-arc furnace 3, the same melt, in a liquid state, undergoes an A.O.D. (Argon Oxygen Decarburization) treatment 4, which is known in the art and will not be further described.

(9) In other words, the first melt 3A molten by the electric furnace 3 undergoes the A.O.D. treatment 4 to obtain a refined first melt 4A.

(10) According to an advantageous aspect of the present method, the treatment A.O.D. treatment 4 is carried out on the first melt 3A when the first melt 3A is still in the liquid state.

(11) Namely, the A.O.D. treatment 4 can provide a decarburized and refined melt 4A with minimized impurities such as S, Pb and Sn and extremely high deoxidation.

(12) It shall be noted that the first melt 4A has the same amount as the charge of materials 2 introduced into the electric furnace 3, that is if the charge of materials 2 is fifty tons then also the first melt 4A. will be fifty tons.

(13) During the A.O.D. treatment 4, the liquid mass of the first melt 3A is subjected to vigorous stirring due to gases (argon, nitrogen and oxygen in varying proportions depending on the stage of the A.O.D. treatment) blown during treatment, which imparts high homogeneity to the first melt 4A.

(14) The A.O.D. treatment 4 is followed by a step of solidification 5 of the first melt 4A.

(15) In one aspect the solidification step 5 comprises a step in which the melt is cast into ingot molds and later cooled to obtain ingots 5A, preferably having a cylindrical shape.

(16) Then, the ingots 5A undergo melting in a V.I.D.P. (Vacuum Induction Degassing and Pouring) furnace 6 to obtain a second melt 6A.

(17) At the end of the treatment in the V.I.D.P furnace 6, the second melt 6A undergoes a step of solidification 7, still in the V.I.D.P furnace.

(18) In one aspect the solidification step 7 comprises a step in which the melt is cast into ingot molds and later cooled to obtain ingots 7A, preferably having a cylindrical shape.

(19) The ingots 7A as obtained from the solidification step 7 undergo melting in a V.A.R. (Vacuum Arc Remelting) furnace 8 to obtain a third melt 8A.

(20) Once melting in the V.A.R. furnace 8 is completed, the third melt 8A undergoes a step of solidification 9 in the V.A.R. furnace to obtain the metal superalloy 10.

(21) The superalloy 10 obtained by the triple-melt 4, 6 and 8 later undergoes homogenization, thermomechanical processing and thermal treatment in prior art plants and with prior art equipment.

(22) Namely, after the solidification step 9, the superalloy 10 undergoes thermomechanical processing, which comprises a press forging step, preferably with a hydraulic press.

(23) If a thickness of less than 250-300 mm is desired, after the solidification step and the press forging step, the superalloy 10 undergoes additional thermomechanical processing which comprises a radial four-die forging step using a hydraulic RUMX machine, and a continuous radial deformation forging step in a rolling plant, preferably of hydraulic type.

(24) This superalloy 10 has a high chemical homogeneity and uniform mechanical, thermal and corrosion-resistance properties, as required for their use.

(25) The superalloy 10 obtained with the method 1 is found to have high chemical homogeneity, a very high degree of desulfurization with less than 5 ppm residual sulfur, an equally high degree of deoxidation and Bi and Se impurity levels of less than 1 ppm.

(26) This is believed to result from the fact that the initial charge 2 ranging from forty to sixty tons establishes the chemico-physical conditions required for an effective A.O.D. Treatment 4, leading to a high impurity elimination degree. In addition, the A.O.D. treatment after the first melt 3A is carried out with a high turbulence of the molten mass generated by blowing process gases, which results in a high homogeneity of chemical process reactions, and hence of the chemical composition of the molten alloy.

(27) According to a variant embodiment of the method of the invention, the charge that leaves the A.O.D. treatment 4, for the subsequent V.I.D.P. and V.A.R. melting steps 6, 8, may be divided into multiple portions depending on the required supply of the alloy 10, thereby ensuring highly homogeneous supplies of the material even after some time.

(28) Those skilled in the art will obviously appreciate that a number of changes and variants as described above may be made to fulfill particular requirements, without departure from the scope of the invention, as defined in the following claims.