PLASTIC CONVERSION FEED SYSTEM
20220065535 · 2022-03-03
Inventors
- Jay Schabel (Chagrin Falls, OH, US)
- George W. Strekal (Conneaut, OH, US)
- Richard A. Schwarz (Akron, OH)
- Mehmet A. Gencer (Brecksville, OH, US)
- Richard K. Peterson (Huntertown, IN, US)
- Cassten Everidge (Hudson, IN, US)
- Laura Christine STRONG (Fort Wayne, IN, US)
Cpc classification
B01J4/001
PERFORMING OPERATIONS; TRANSPORTING
B01J2204/002
PERFORMING OPERATIONS; TRANSPORTING
F27D3/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01J2204/007
PERFORMING OPERATIONS; TRANSPORTING
F27D13/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27D2003/0071
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02P20/143
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
F27D3/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01J4/00
PERFORMING OPERATIONS; TRANSPORTING
B01J6/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A plastic conversion feeding system serves to transport a feedstock through different processing units or stations to a vessel wherein chemical and/or physical reactions occur to produce suitable, useful end products. Various processing units include a homogenizer for breaking up said feedstock, a size reduction device for reducing the feedstock to particles and densifying the same, a heating and/or blending device for heating said feedstock, and a feed conduit connecting said heating and blending device to said vessel. The feedstock conversion unit vessel through various cracking, reforming, condensation, recombination, and recracking operations, produces a mixture of useful gases and condensable gases.
Claims
1. A plastic conversion feed system for transporting a feedstock to a reactor vessel, comprising: a homogenizer capable of breaking up said feedstock comprising plastic material or a hydrocarbonaceous material, or any combination thereof; a pelletizer capable of reducing the size and densifying said homogenized feedstock; and an extruder, said extruder capable of forming a continuous mass of feedstock that is fed to said reactor vessel.
2. The plastic conversion feed system of claim 1, including a shredder, said shredder capable of reducing the size of said feedstock.
3. The plastic conversion feed system of claim 2, including a heater and feeder system for heating said pelletized feedstock, said heater and feeder capable of transferring said feedstock to said extruder.
4. The plastic conversion feed system of claim 3, including a conduit that extends from said extruder to said reactor vessel.
5. The plastic conversion feed system of claim 4, including a plug of said feedstock that is located around said conduit at the entrance to said reactor vessel.
6. The plastic conversion feed system of claim 3, wherein said feedstock egressing from said extruder is a flowable, non-melted material
7. A process for transporting a feedstock to a reactor vessel comprising: breaking up said feedstock in a homogenizer, said feedstock comprising a plastic, a hydrocarbonaceous material, or any combination thereof; a pelletizer, said pelletizer reducing the size of said feedstock; an extruder, and a feed conduit operatively connecting said extruder to said reactor, and extruding said feedstock into said reactor.
8. The process of claim 7, including, a heater, said heater heating said pelletized feedstock to a temperature of from about 200° F. to about 500° F.
9. The process of claim 7, including forming a plug of said feedstock located around said conduit at the entrance to said reactor vessel.
10. A plastic conversion feed system for transporting a feedstock to a reactor vessel, comprising: a size reduction device capable of reducing the size of and densifying said feedstock comprising a plastic, or a hydrocarbonaceous material, or any combination thereof; a heating device capable of heating and transferring said reduced sized feedstock to an extruder, said extruder having an output axis; and a conduit connecting said extruder to said vessel and capable of feeding said feedstock to said vessel, and said conduit optionally having an output axis of up to about a 5° radius angle with respect to said extruder device output axis.
11. The plastic conversion feed system of claim 10, wherein said size reduction device comprises a shredder, or a pelletizer, or both, and wherein said heating device comprises a feeder.
12. The plastic conversion feed system of claim 11, wherein said reactor vessel is a pyrolytic reactor.
13. The plastic conversion feed system of claim 11, wherein said size reducing is said pelletizer, and wherein said pelletizer is capable of densifying said feedstock to greater than about 15 pounds/cubic foot.
14. The plastic conversion feed system of claim 10, wherein said heating device is said extruder,
15. A process for transporting a feedstock to a reactor vessel comprising the steps of: reducing the size of said feedstock in a size reduction device, said feedstock comprising a plastic, or a hydrocarbonaceous material, or any combination thereof; heating and blending said reduced size feedstock; and transferring said reduced size feedstock to a feed conduit, wherein said feed conduit is connected to said vessel, and feeding said conduit containing reduced size feedstock to said vessel.
16. The process of claim 15, wherein said size reduction device comprises a pelletizer.
17. The process of claim 16, wherein said reduced size of said feedstock has a density of greater than about 25 pounds/cubic foot.
18. The process of claim 16, wherein said feed conduit has an output radial axis that can vary up to about 5° with respect to the axis of said extruder.
19. The process of claim 15, including a hopper system, said hopper system comprising an upper hopper and a lower hopper, feeding said feedstock to said upper hopper, and subsequently feeding said feedstock in said upper hopper to said lower hopper.
20. The process of claim 15, wherein said conduit is flexible and is heated.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0015] The foregoing and other features of the present invention will become apparent to those skilled in the art to which the present disclosure relates upon reading the following description with reference to the accompanying drawings, in which:
[0016]
[0017]
[0018]
[0019]
[0020]
[0021]
DETAILED DESCRIPTION OF THE INVENTION
[0022] Feedstock Conversion Unit (FCU)
[0023] Vessel 300 of the present invention can generally be any vessel, known to the art or to the literature wherein physical and/or chemical reactions can occur, and desirably is substantially free of air and oxygen. That is, the total amount of oxygen based upon the total internal volume of the vessel is less than about 3 volume percent, desirably less than about 2 volume percent, and preferably less than about 1 volume percent, and more preferably it is totally free of any air or oxygen. Hence, reactor vessels such as pyrolytic vessels can be utilized. The vessel can generally have multiple heating units, multiple reaction stages, multiple product gas exhaust vents, and the like, or any combination thereof. Optionally, but preferably, vessel 300 contains an outer shroud 360 having a plurality of inner walls 365 that extend from the shroud to the vessel exterior wall and forms heated channels for hot gases to heat the vessel. A preferred vessel that is schematically shown in
[0024] Feedstock conversion feed system 400 contains different processing units or stations. The feedstock material is generally a plastic, or hydrocarbonaceous material 405, or any combination thereof, that is fed to particle size reduction device 420 by hopper system 410. The hopper system comprises an upper, large hopper 412 that receives large amounts of feedstock and upon receiving an electronic signal from lower and smaller hopper 414 that it is low on feedstock, opens an orifice device such as bottom valve 413 and transfers feedstock (e.g. fills) to lower hopper 414. Lower hopper 414 has an orifice such as a lower valve 415 therein that can transfer, convey or deliver at a constant rate or a steady state amount of waste material into size reduction device 420. In a manner well known to the art and to the literature, the lower hopper feed valve can be programmed to increase or decrease the amount of waste feedstock admitted to size reduction device 420 in order to stabilize, and generally equalize the flow of subsequently reduced size solid feedstock or semi-molten or molten feedstock into FCU vessel 300.
[0025] A desirable aspect of vessel 300 is to generally produce petroleum gas products. Preferable plastic waste feedstock items include waste polymers, as in the form of sheets, wrappers, packaging, furniture, plastic housings, containers, waste plastics, and the like, and are utilized that essentially contain only hydrogen and carbon atoms such as polyethylene, high density polyethylene, low density polyethylene, linear low density polyethylene, polypropylene, polystyrene, and the like. Other suitable commercial polymers include polyesters, polycarbonates, polymethyl methacrylates, nylons, polybutylene, acrylonitrile-butadiene-styrene (ABS) copolymers, polyurethanes, polyethers, poly(oxides), poly(sulfides), polyarylates, polyetherketones, polyetherimides, polysulfones, polyvinyl alcohols; and polymers formed by polymerization of dienes, vinyl esters, acrylates, acrylonitrile, methacrylates, methacrylonitrile, diacids, diols, or lactones, or any combination thereof. Still other polymers include block copolymers of the preceding, and alloys thereof. Polymer materials can also include thermoset polymers such as, for example, epoxy resins, phenolic resins, melamine resins, alkyd resins, vinyl ester resins, crosslinked polyester resins, crosslinked polyurethanes; and also crosslinked elastomers, including but not limited to, polyisoprene, polybutadiene, polystyrene-butadiene, polystyrene-isoprene, polyethylene-propylene, ethylene-propylene-diene, and the like, and blends thereof.
[0026] Hydrocarbonaceous material generally includes compounds that have, of course, primarily only carbon and hydrogen atoms such as various bitumens including bitumen tailings as from a mine, various heavy fractions of a fractionating column that include various heavy oils, greases, semi-asphalt compounds, and the like, that by the present invention, are reduced to lighter components, and are mostly various types of hydrocarbon containing gases.
[0027] The various above-noted polymer feedstocks often include fillers, pigments, flame retardants, clay, and the like. Generally, the amount thereof is about 2% to about 25% by weight, or desirably about 3% to about 20% by weight, or preferably about 3% to about 15% by weight, or most preferably less than about 7% by weight, all based on the total weight of the one or more polymer feedstocks. Such compounds generally are not chemically or physically reacted but are emitted from vessel 300 as through vessel discharge channel 330, often as solid inert residues.
[0028] In a preferred embodiment, the above different types of feedstock compositions often comprise from about 40% to about 90%, desirably from about 50% to about 85%, and preferably from about 70% to about 80% by weight, of polymers of polyethylenes, polypropylenes and polystyrenes. Any remaining polymers can be, but are not limited to, polyurethane, nylon, PET, and polyvinylchloride, as well as any of the remaining above-noted polymers.
[0029] Processing size reduction device 420 comprises one or more shredders 422 and/or one or more pelletizers 424, While they can be in any order, preferably the feedstock is shredded first and then subsequently pelletized as shown in
[0030] The reduced sized waste feed, in the form of feed stream 430, as on conveyor 435 is fed to another processing unit, heating and blending device 440. Device 440 comprises one or more feeding units and/or one or more extruders. The feeder and/or extruders can be in any order with preferably a feeder being first with subsequently a single downstream extruder as shown in
[0031] Another favorable aspect of utilizing an extruder is that densification of the feed stream there from (egress) can be readily increased to its fully dense state that generally is greater than about 25 pounds per cubic food and desirably from about 30 to about 38 pounds per cubic foot. Such increased density further eliminates and generally ensures minimum intrusion of air into any FCU vessel 300 via the feedstock.
[0032] Another important aspect of the present invention is the utilization of a processing unit that is feed conduit 500 that extends from extruder 444 into said vessel 300 and transfers said feedstock from the extruder into the vessel, and can be made out of any conventional type of metal such as stainless steel, cast iron, or carbon steel. This device is generally a flexible conduit or pipe having a smooth interior that connects the output of feeder 442 and/or extruder 444 to FCU vessel 300 and ensures that a steady rate and smooth flow of feedstock, or semi-molten, and/or molten feedstock waste material is fed into the vessel, regardless of the vessel input location, e.g., height, distance, lateral location, etc., with respect to the feeder and/or extruder outlet. Feed conduit output or axis 452 that can be exactly aligned with or is capable of generally moving in a moderate radial direction with regard to extruder output axis 448. That is, optionally it can move vertically, i.e., up or down, or sideways, i.e. left or right, or any combination thereof within about a radial angle of up to about 5° with respect to the output axis 448 of the extruder and desirably within an angle of about 3° or less. Axis 452 of conduit 500 can be perpendicular to the ingress face of the feed conduit. Optionally, the entire conduit can be located within a flexible tube to permit angular movement of the feed into the vessel. Such movement readily permits the shredded or pelletized or semi-molten or molten waste feed stream from extruder 444 to be transferred to ingress 310 of vessel 300 in a smooth, consistent, steady stream, and even flow rate. This is an important aspect because the vessel can then run at a steady reaction state of pyrolyzation, cracking, reforming, etc., whereby an efficient output of the various constituents of the shredded or pelletized flowable waste are generally converted to a gas such as a petroleum gas, and the like, as noted above. The length of conduit 500 can vary such as from about 24 to about 240 inches, and more desirable is from about 36 to about 120 inches. The length is adjusted to allow for plant layout considerations, but also to ensure adequate length for development of a vapor seal with the feedstock being fed into the reactor.
[0033] A detailed view of a preferred conduit 500 is shown in
[0034] Another advantage of conduit 500 is that it is flexible, meaning that the feed conduit axis 452 of conduit 500 can generally be substantially aligned with the horizontal axis 448 of extruder 444 at one end, and at the other end is generally substantially aligned parallel with the input axis 305 of the ingress of vessel 300 as when it is at a slightly different location, e.g. vertically, horizontally, etc.
[0035] Conduit 500 can be supported as by any conventional scaffold or other support device or alternatively, it can be suspended from an overhead truss system and the like. Feed transfer pipe or conduit 500 can be capable of feeding 2500-7500 lb/hr of material into the vessel.
[0036] In summary, advantages of the above plastic conversion feed stock 405 of
[0037] Vessel 300 desirably exists, that is, axis 305 thereof, optionally can be set at a slight upward slope or angle from a reference point of level ground (not a slope, hill, or any upward or downward grade of land) on which the vessel rests, i.e., at about 0° to about 10°, desirably from about 1° to about 5°, and preferably from about 1.5° to about 4°. Thus, when desired, complete pyrolyzation of the feedstock mass 460 can be achieved before any unreacted feedstock waste mass reaches the upper end or egress 320 of the vessel as shown in
[0038] Beach head point 350 is located on the vessel bottom upstream from the vessel ingress or opening 310 at a distance where the height of the vessel bottom is generally equal to the initial vertical height of the feedstock mass injected into the vessel. Point 350 should be approximately at least about 2%, desirably at least about 5%, and preferably at least about 10% of the distance from the vessel upper egress or discharge channel 330, based on the total length of the vessel.
[0039] The yield of gaseous product produced by the present invention is very high and is at least about 70 wt. %, desirably at least about 80 wt. %, and preferably at least about 85 wt. % or 90 wt. % of the feedstock admitted to the vessel. The remaining material is generally classified as a solid inert residue, that is dry, and often contains fillers and other inert material and is ejected from the upper or egress end 320 of vessel 300 through discharge channel 330.
[0040] A desired reaction vessel is set forth in
[0041] Pyrolization occurs during transfer of the mass 460 along the vessel as in
Modified Embodiment
[0042] According to another embodiment of the present invention, a modified feed system 600 that is schematically set forth in
[0043] The recyclable materials received for pyrolyzation as from numerous sources such as food and grocery stores, drug stores, home improvement stores, mixed waste, city collection plants, as well as industrial sources generally contain a variety of materials some of which are not desirable for use in a pyrolytic reactor. Thus, as set forth in
[0044] Inasmuch as the one or more manual assortment areas will not have a constant influx of particular types of material, the amounts of feedstock from the individual manual assortment areas will vary and thus desirably needs to be regulated with respect to amount of the feedstock and type thereof to achieve a generally similar input of different type of plastics, as well as hydrocarbonaceous material. For example, if too many polyolefins such as polyethylene or polypropylene are contained in a first manual assorted feedstock, the amount of other or different polymers such as polystyrene, polyurethanes, polyesters, nylons, and the like, from another feedstock can be added thereto to generally maintain a similar overall input of the various different polymers, and hydrocarbonaceous material to homogenizer 610. This procedure is generally manually accomplished by taking different assortment area feedstock rich in one type of material and adding it to a feedstock low in said type of material.
[0045] The above-noted feedstocks are fed to hopper system 410 that is described hereinabove and hereby fully incorporated by reference. The hopper system can comprise the above noted upper and lower hoppers that preferably in this embodiment, are of the same size and generally convey or deliver the pyrolytic feedstock in a fairly constant or steady flow rate in order to stabilize, and equalize the flow of said feedstock to homogenizer 610. Also, the top hopper is important because it allows one to measure mass feed, and improves controllability of the process (pellets can be stored and replenished somewhat independently of the pyrolizer demand).
[0046] The purpose of homogenizer 610 is to break-up said feed stock and to ensure that generally a similar amount of specific feedstock materials are delivered to pyrolytic reactor 300 so that the output of various products from the pyrolizer such as various petroleum gas products that comprise naphtha, various distillates such as gasoline and the like, as well as various gas-oil compounds such as heavy gas and wax, diesel fuel , and the like are produced at a fairly constant rate by said pyrolytic reactor. The homogenized material flows into the pyrolytic reactor and thus ensure that a smooth production of the various noted end products will be produced and that the efficiency of the pyrolytic reactor is thus maximized reducing the various feed operations to ensure smooth running of the pyrolytic reactor, such as desired temperatures in each of the heating sections of the reactor, a generally desired flow rate of various end products from the product exhaust channels 380 of the reactor, and fairly constant heat input by the various heaters 370 of the reactor, and the like.
[0047] The homogenizer generally contains a rotating “breaker” shaft is designed to accept and mix the feedstock as from different assortment areas, so as to achieve a similar overall distribution of various polymers, etc., as noted above, without plugging the equipment or stopping the process. A common challenge of rotating equipment when exposed to film that exists in the feedstock is wrapping of the film around the rotating shaft, which increases energy requirements, or stops and or damages the equipment. The geometry of the breaker shaft is such that film does not easily wrap, that is it is free of low relief knobs and overhanging geometries that can catch film. Additionally, the bearings are free, i.e. guarded from film ingress. Optionally, a blade can be used to continuously cut film off the shaft, and/or the shaft can be reversible to “unload” wrapped film. In another system, a moving rake keeps the feed stream depth level. Such types of rotating equipment are known to the art and to the literature.
[0048] Subsequently, homogenized feed stream 615 is fed by any general transfer device such as conveyor belt 625 to the next unit operation that desirably is shredder 442. As noted above, shredder 442 basically is utilized to reduce the size of feedstock 405 and to break up clumps of feedstock. Such shredders, if they have a rotating shaft, rotate at a slow rate but has high torque to prevent feedstock film from clogging the system. Various shredders are known to the literature and to the art and include machines that are made by VECO and the like. Such shredders require low amounts of energy and promote a constant flow of feedstock so that it is easier to pelletize the same in the next unit operations step.
[0049] Down line from shredder 422 is pelletizer 424. As noted above, the primary purpose of the pelletizer is to reduce the size of feedstock 405 into smaller particles. Pelletizer 424 also densifies the feedstock generally in the form of briquettes and/or cubes having size of from about a half inch to about 3 or 4 inches and preferably from about 1 to 2 inches in size. Standard compacting or densifying machines can be utilized to produce the briquettes and/or cubes such as those made by machines made by MUNCH.
[0050] The next unit operation is the transfer the pellets to heater and feeder 640 wherein the noted briquettes and/or cubes, etc., is generally heated to temperatures of from about 50° F. or about 100° F. to about 400° F. or about 500° F., desirably from about 150° F. to about 300° F., and preferably from about 200° F. to about 250° F. These low temperatures are desired so that feedstock 460 can be easily transferred and then processed in an extruder without causing undo strain on the extruder apparatus. However, too much heat applied to the pelletized feedstock can cause high strain to the extruder apparatus and hence heating temperatures of about 500° F. or higher and especially 500° F. or higher are avoided. The heating and feeding apparatus can be a standard rotary kiln dryer and the like that are well known to the art and to the literature.
[0051] Subsequently, the next unit operation of the feed system is the utilization of extruder 444, the general purpose of which is to heat and densify the noted feedstock as in the form of briquettes or cubes to form a continuous mass or stream of feedstock that is egressed from the extruder into pyrolytic reactor 300 wherein it can be converted through cracking, recombination, and the like into various types of petroleum gases as noted above. An advantage of the process according to
[0052] The amount of solid or softened feedstock material fed through extruder 650 into feed conduit 500 can range from about 25 to about 50 pounds per cubic foot and desirably from about 30 to about 45 pounds per cubic foot.
[0053] Feed conduit 500 is utilized to feed the solid or semi-solid feedstock from the extruder into pyrolytic reactor 300. Accordingly, the above description of the same is hereby fully incorporated by reference with regard to all aspects thereof unless otherwise, a different description is set forth herein. However, it is noted that the radial angle of the output axis of the feeder, that is output axis 652 of extruder can vary over a range up to about 10° and generally from about 1° to 7° and most preferably from about 1° to about 3°.
[0054] In order to achieve a consistent vapor seal, the compaction of flowing material can be adjusted by changing the cross sectional geometry of the feed pipe, or lengthening/shortening the feed pipe. One means of accomplishing this is by adding ports in the side of the feed tube where rod(s) can be inserted an adjustable depth into the flow of material, thereby increasing resistance to flow and increasing compaction of material in the feed pipe, which creates a tighter seal. The rods need to be robust enough to avoid deformation in the flow, and there needs to be a seal between the inside of the feed tube and the ambient environment. This seal can be any commonly used, such as a packing gland or mechanical seal designs. Common thread patterns are generally not sufficient to achieve a vapor seal while allowing for adjustability, but can be sealed with multiple fasteners such as nuts with or without gaskets.
[0055] More specifically, the present invention relates to the utilization of adjustaplug 660 as shown in
[0056] Another feature of the present invention is that feed stream 615 upon leaving conduit 500 encounters very high temperatures within the initial portion of pyrolytic reactor 300 that causes the same to liquify and results in a natural formation of plug 655 that generally forms at the egress of feed conduit 500 as shown in
[0057] While in accordance with the patent statues, the best mode and preferred embodiment have been set forth, the scope of the invention is not limited thereto, but rather by the scope of the attached claims.