PROCESS FOR MAKING A COMPOSITE LINER FOR COLD CHAMBER DIE CASTING APPLICATION

Abstract

A process of forming a low cost, erosion, oxidation, and wear resistant composite liner or insert that can be installed into a shot chamber in a die casting machine is provided. The process utilizes a self-healing erosive wear resistant coating on a liner of refractory metal to serve as the working surfaces of a shot chamber. The refractory liner is bonded to a low cost material so that the liner can be made extremely thin. Such a composite liner is expected to have an improved service life for die casting of corrosive metals and alloys.

Claims

1. A method for forming an oxidation, erosion, and wear resistant composite liner or insert that can be installed into a shot chamber in a die casting machine, the method comprising the steps of: preparing a liner made of refractory metallic materials with melting temperatures higher than 1600° C.; and coating at least the working surface of the liner with a thin layer of protective coating.

2. A method of claim 1, wherein the refractory metallic material is a refractory metal or its alloy that includes but is not limited to niobium, molybdenum, rhenium, tantalum, titanium, tungsten.

3. A method of claim 1, wherein the said coating on the liner is a metalized coating such as aluminum, nickel, silver, tin, or zinc alloy coating using plating, hot dipping, cementation-packing, laser-printing, thermal spring, arc surface alloying, or other techniques.

4. A method of claim 1, wherein the said coating on the liner is an oxidation resistant coating conventionally used for protecting a refractory metal from oxidation.

5. A method of claim 1, wherein the coating on the liner is a carbide, nitride, silicide, oxide, or TiAlN type of coating that can be applied using a hot dipping, cementation-packing, physical vapor deposition or a chemical vapor deposition process.

6. A method of claim 1, wherein the thickness of the coating is in the range of about 1 to 100 micrometers, preferably in the range of about 1 to 10 micro meters.

7. A method for forming a low cost and erosion resistant composite liner or insert that can be installed into a shot chamber in a die casting machine, the method comprising the steps of: preparing a thin inner layer of refractory metallic materials; preparing a thick outer layer of metallic materials; and bonding the inner layer strongly with the outer layer to form a composite liner or insert.

8. A method of claim 7, wherein the refractory metallic material is niobium, molybdenum, rhenium, tantalum, titanium, tungsten metal, or its alloy.

9. A method of claim 7, wherein the thickness of the thin inner layer is in the range of about 0.5 to 10 millimeters, preferably in the range of about 1 to 5 millimeters.

10. A method of claim 7, wherein the metallic material for the outer layer includes but is not limited to steel, cast iron, or a copper alloy.

11. A method of claim 7, wherein the bonding method includes but is not limited to conventional cast-on bonding, diffusion bonding, explosive bonding, hydroforming bonding, roll bonding, powder metallurgy bonding, sintering, or solder bonding.

12. A method for forming a low cost, erosion, corrosion, and wear resistant composite liner or insert for a shot chamber in a die casting machine, the method comprising the steps of: preparing a thin inner layer of refractory metallic materials; preparing a thick outer layer of metallic materials; bonding the inner layer strongly with the outer layer to form a composite liner or insert; and coating at least the working surface of the liner with a layer of coating.

13. A method of claim 12, wherein the refractory metallic material is niobium, molybdenum, rhenium, tantalum, titanium, tungsten metal, or its alloy.

14. A method of claim 12, wherein the thickness of the thin inner layer is in the range of about 0.5 to 10 millimeters, preferably in the range of about 1 to 5 millimeters.

15. A method of claim 12, wherein the metallic material for the outer layer includes but is not limited to steel, cast iron, or a copper alloy.

16. A method of claim 12, wherein the bonding method includes but is not limited to conventional cast-on bonding, diffusion bonding, explosive bonding, hydroforming bonding, roll bonding, powder metallurgy bonding, sintering, or solder bonding.

17. A method of claim 12, wherein the said coating on the liner is a metalized coating such as aluminum, nickel, silver, tin, or zinc alloy coating using plating, hot dipping, cementation-packing, laser-printing, thermal spring, arc surface alloying, or other techniques.

18. A method of claim 12, wherein the said coating on the liner is an oxidation resistant coating conventionally used for protecting a refractory metal from oxidation.

19. A method of claim 12, wherein the coating on the liner is a carbide, nitride, oxide, silicide, or TiAlN type of coating that can be applied using a hot dipping, cementation-packing, physical vapor deposition or a chemical vapor deposition process.

20. A method of claim 12, wherein the thickness of the coating is in the range of about 1 to 100 micrometers, preferably in the range of about 1 to 10 micro meters.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0017] FIG. 1 schematically represents composite shot sleeves used in the cold-chamber die casting process.

[0018] FIG. 2A is a schematic side view of a layout of a prior art on a design of a composite shot sleeve.

[0019] FIG. 2B is a schematic side view of a layout of a prior art on a design of a composite shot sleeve.

[0020] FIG. 3 shows photographs of Nb alloy tubes suffering from mass loss in an oxidation environment.

[0021] FIG. 4 is a schematic view of a layout of one embodiment of the present invention.

[0022] FIG. 5 is a schematic view of a layout of one embodiment of the present invention.

[0023] FIG. 6 is a schematic view of a layout of one embodiment of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

[0024] Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. All publications, patent applications, patents, and other references mentioned herein are incorporated by reference in their entirety.

[0025] The primary function of a shot sleeve is to receive and hold the molten metal after pouring [3]. The shot sleeve also provides a pressure chamber to contain the molten metal during injection and intensification. The quality of die castings depends on many factors including the ability of the shot sleeve to convey the molten metal into the die cavity. It is essential that the inside of the shot sleeve be smooth, round, straight and uniform to allow the appropriate velocities and pressure rise times required for precise die filling and intensification [3, 13]. The shot sleeve is exposed to extremely severe conditions as during operation the molten metal above 660° C. impacts the inside wall of the shot chamber, the sleeve temperatures can approach the temperature of the molten metal, the plunger can reach velocity of 6 m/s or more, and metal pressures can be as high as 25,000 psi [14]. Consequently, shot sleeves normally fail due to erosion under the pour hole, wear and scoring on the internal surface, and thermal fatigue producing small cracks. Erosion failure is one of the major reasons for a shorter life of a shot sleeve especially when the sleeve is used for the die casting of low iron aluminum alloys. Composite shot sleeves are designed to separate the section of the inner layer of a sleeve containing the pour hole to the main body of the sleeve, allowing just that section to be replaced when severe erosion under the pour hole occurs. The goal for most die casters is to maximize the life of their sleeves while controlling costs.

[0026] FIG. 1 illustrates two types of composite shot sleeve used in the die casting industry: one with a short insert or liner and the other with a long liner which covers the entire length of the internal surface of a shot sleeve. The term “liner” or “insert” here refer both the short and long one shown in FIG. 1.

[0027] FIGS. 2A and 2B are vertical sections of these two types of composite shot sleeve. The small hole 14 on the top of a shot sleeve is the pour hole. Molten metal is poured through the pour hole 14 and impacts the bottom inside wall of the shot chamber opposite the pour hole at the impingement site 20. A composite shot sleeve consists of two parts: an outer layer 10 and an inner layer 12. The inner layer 12 can be a short insert or liner forming the internal surface of the sleeve near the pour hole 14 or a liner covering the entire internal surface of the sleeve. The insert or the liner 12 can be made of similar or dissimilar material to the outer layer of the sleeve. The insert or liner 12 is installed in the outer layer 10 with a tight interface 16 with a small tolerance.

[0028] U.S. Pat. No. 3,786,552 to Saito et al. and U.S. Pat. No. 9,114,455 to Donahue et al. disclose the use of refractory metals as the materials for the liner 12, but these prior arts for the fabrication of composite shot sleeves have issues with the costs of sleeve fabrication and the service life of the sleeves.

[0029] Refractory metals usually have a poor oxidation resistance [3-4]. FIG. 3 illustrates niobium tubes used for melting aluminum alloys in the temperature range of 650 to 750° C. The left side tube is a new one and the right side one is the used one. A significant amount of niobium metal is lost due to the formation of niobium oxide scales which spall off the tube because the oxides have much smaller thermal coefficients than the metal. Two niobium lined composite shot sleeves were made according to U.S. Pat. No. 9,114,455 to Donahue et al. One shot sleeve was used for over 6,000 cycles which lasted longer than the H13 shot sleeves. However, a dent was formed on the inside surface of the shot sleeve opposite the pour hole where the molten metal impinged the internal surface of the shot sleeve. Erosion did not appear to happen at this area, so the mass loss was due to oxidation.

[0030] The present invention describes new ideas in the manufacturing of the liner or insert for a cold-chamber die casting shot sleeve shown in FIGS. 2A and 2B. Instead of a liner 12 composed of a single metal, either steel or refractory metal as disclosed in prior art, a composite liner with a multiple layered structure is described. Each layer in the composite liner contains materials designed to serve unique purposes such as extending the service life and/or reducing the production costs of the liner in a shot sleeve for cold-chamber die casting operations.

[0031] In a preferred embodiment, the present invention relates to a method for forming an oxidation, erosion, and wear resistant composite liner in a shot sleeve for cold-chamber die casting applications. FIG. 4 depicts the composite liner. The internal surface of the refractory metal liner or the insert 12 is coated with a layer of self-healing coating 22. The oxidation and wear resistance of the shot sleeve are provided by the self-healing coating 22 on the internal surface of a refractory metallic alloy liner 12. The erosion resistance of the shot sleeve is provided by compounds formed between the cast material, i.e. aluminum alloy, and the refractory metal in the liner 12 after the coating fails. The term “self-healing coating” is defined as a coating that, if damaged, can be repaired in-situ by chemical reactions between the bulk liner materials and the molten alloy processed in the shot chamber, forming similar or dissimilar compounds to that of the original coating on the damaged sites. The purpose of using an initial coating on the refractory metal liner is to protect the liner from oxidation during its fabrication process before the liner is in contact with liquid metal. The initial coating can be damaged by the molten metal in the shot chamber with the liner. However, as long as the damaged site can be filled or replaced immediately by newly formed materials due to the chemical reaction between the molten metal and the materials on the surface of the liner, a protective layer of coating is formed on the surface of the liner. By such a definition of the self-healing coating, any coating that is suitable for protecting refractory metals from oxidation may be used as the initial coating on the refractory liner. Such a coating includes but is not limited to silicide and nitride coatings, hot dipping and plating of various metals and alloys such as aluminum alloy, tin, silver, nickel, and zinc alloy, laser printing of metals and alloys, arc surface alloying, spray forming of metals and alloys, and PDV and CVD of various compounds.

[0032] For a liner made of niobium, tungsten, molybdenum, titanium, and their alloys, an aluminizing coating is one of the preferred surface coatings [15-16]. This is because aluminizing produces a metallurgical bond between the refractory metal liner and aluminides. The bond consists of line compounds at the interface between a refractory metal and molten aluminum. These line compounds have high melting temperatures and thus are resistant to erosion and soldering by molten aluminum [5]. As a line compound, its composition falls within a very narrow range as diffusion of elements across this compound becomes difficult because composition difference is the driving force for elemental diffusion and erosion is a diffusion-controlled process. Furthermore, the line compound usually has a high hardness which is good in resisting wear in the shot chamber by the plunger. Niobium, for instance, reacts with molten aluminum and forms a line compound, NbAl.sub.3. The melting temperature of this compound is 1760° C., much higher than the melting temperature of aluminum (660° C.). Aluminum at the external surface of the compound is resistant to oxidation at elevated temperatures. This line compound, if damaged on the liner surface, can be replaced in-situ with newly formed line compounds in the next cycle of die casting when the liner is in contact with molten metal. Aluminum metal can be deposited on niobium alloys (or molybdenum and its alloys) using hot dipping, chemical vapor deposition, laser printing, fused salt processes, and physical vapor deposition. Aluminum deposited on the refractory metal can then be heat treated to improve the formation of aluminides.

[0033] The composite liner described in FIG. 4 can be installed in a shot sleeve either as a short insert to cover just the internal surface of the shot sleeve near the pour hole 14 or the entire internal surface of the shot sleeve as illustrated in FIGS. 1, 2A, and 2B.

[0034] Another issue with the use of a composite shot sleeve designed described by U.S. Pat. No. 9,114,455 to Donahue et al. is the costs associated with the use a thick refractory liner. Conventional methods for fabricating a composite shot sleeve with a refractory metal liner involve using a rough chamber of wrought H13 steel, machining to expand portion of its internal diameter, and inserting the liner tightly into the shot sleeve with a small tolerance. The liner has to be thick enough to reduce thermal distortion during its service. Refractory metals are expensive, so the use of a thick refractory metal increases the costs of the shot chamber substantially. A shot sleeve with a thin niobium liner was built and tested [8-9] in order to reduce costs. After this shot sleeve was used for around 300 shots or cycles, the liner was pushed towards the dies/molds due to its plastic deformation, leaving a gap at the ram end. Such a gap decreases the service life of the ram. It is also a safety concern. Obviously, a much thicker niobium liner is needed. Tungsten liners used in the die casting industry are usually much thicker than 12 millimeters. The costs of refractory metals are a few hundred times of that of H13 steel. A composite shot sleeve design that is capable of reducing the use of refractory metal is extremely beneficial.

[0035] In another preferred embodiment, the present invention relates to a method for forming an erosion composite liner or insert in a shot sleeve for cold-chamber die casting applications. The idea is illustrated in FIG. 5. The composite liner consists of a thin inner layer of refractory metal 12 strongly bonded to a thick outer layer 24 of a low cost metal. The refractory metal includes but is not limited to either niobium, molybdenum, titanium, tungsten metal or its alloy. The low-cost metal for the outer layer 24 of the composite liner/insert includes but is not limited to steel, cast iron, or a copper alloy. The inner layer 12 and the outer layer 24 materials are strongly bonded at their interface 26 using a bonding method that includes but is not limited to cast-on bonding [17], diffusion bonding, explosive bonding, hydroforming bonding, rolling bonding, sintering, or solder bonding. The refractory metal in the inner layer 12 of the composite liner provides erosion resistance. The low-cost material in the outer layer 24 provides the required strength and stiffness for the composite liner or an enhanced thermal diffusivity to assist thermal management of the shot sleeve. The strong bond, ideally a metallurgical bond, ensures that the thin inner layer 12 is strongly held by the outer layer material 24 to minimize thermal distortion of the composite liner. Such a composite liner is a cost effective replacement of the thick refractory metal liner while still maintaining excellent erosion resistance to molten aluminum in the shot sleeve. The composite liner can be installed in a shot sleeve either as a short insert to cover just the internal surface of the shot sleeve near the pour hole 14 or the entire internal surface of the shot sleeve as illustrated in FIGS. 1, 2A, and 2B.

[0036] Yet in another preferred embodiment, the present invention relates to a method for forming an oxidation, erosion, and wear resistant composite liner in a shot sleeve for cold-chamber die casting applications. The idea is illustrated in FIG. 6. The bulk of the liner/insert is made using low cost materials such as steels as the outer layer 24. A thin layer 12 of refractory metal is strongly bonded at the interface 26 between the thin layer 12 and the thick layer 24. The refractory metal includes but is not limited to either niobium, molybdenum, titanium, tungsten metal or its alloy. The low-cost metal for the outer layer 24 of the composite liner/insert includes but is not limited to steel, cast iron, or copper alloy. The inner layer 12 and the outer layer 24 materials are strongly bonded at their interface 26 using a bonding method that includes but is not limited to cast-on bonding [17], diffusion bonding, explosive bonding, hydroforming bonding, rolling bonding, sintering, or solder bonding. The refractory metal in the inner layer 12 of the composite liner provides erosion resistance. The low-cost material in the outer layer 24 provides the strength and stiffness for the composite liner. The strong bond, ideally a metallurgical bond, ensures that the thin inner layer 12 is strongly held by the outer layer material 24 to minimize thermal distortion of the composite liner. The refractory metal layer 12 is coated with a layer of self-healing coating 22. As discussed above, the oxidation and wear resistance of the shot sleeve are provided by the self-healing coating 22 on the internal surface of a refractory metallic alloy liner 12. The erosion resistance of the shot sleeve is provided by compounds formed between the cast material, i.e. aluminum alloy, and the refractory metal in the liner 12 after the coating fails. The term “self-healing coating” is also defined as a coating that, if damaged, can be repaired in-situ by chemical reactions between the bulk liner materials and the molten alloy processed in the shot chamber, forming similar or dissimilar compounds to that of the original coating on the damaged sites. The purpose of using an initial coating on the refractory metal liner is to protect the liner from oxidation during its fabrication process before the liner is in contact with liquid metal. The initial coating can be damaged by the molten metal in the shot chamber with the liner. However, as long as the damaged site can be filled or replaced immediately by newly formed materials due to the chemical reaction between the molten metal and the materials on the surface of the liner, a protective layer of coating is formed on the surface of the liner. By such a definition of the self-healing coating, any coating that is suitable for protecting refractory metals from oxidation may be used as the initial coating on the refractory liner. Such a coating includes but is not limited to silicide and nitride coatings, hot dipping and plating of various metals and alloys such as aluminum alloy, tin, silver, nickel, and zinc alloy, laser printing of metals and alloys, arc surface alloying, spray forming of metals and alloys, and PDV and CVD of various compounds. Such a composite liner shown in FIG. 6 is a cost effective replacement of thick refractory metal liner while still maintaining excellent erosion resistance to molten aluminum and increasing the wear resistance to the ram in the shot sleeve. The composite liner can be installed in a shot sleeve either as a short insert to cover just the internal surface of the shot sleeve near the pour hole 14 or the entire internal surface of the shot sleeve as illustrated in FIGS. 1, 2A, and 2B.

[0037] While the invention has been described in connection with specific embodiments thereof, it will be understood that the inventive methodology is capable of further modifications. This patent application is intended to cover any variations, uses, or adaptations of the invention following, in general, the principles of the invention and including such departures from the present disclosure as come within known or customary practice within the art to which the invention pertains and as may be applied to the essential features herein before set forth and as follows in scope of the appended claims.

REFERENCES

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