METHOD FOR IMPROVING EFFICIENCY OF ANAEROBIC FERMENTATION IN MEDIUM TEMPERATURE-HIGH TEMPERATURE TRANSITION ZONE
20230392171 · 2023-12-07
Assignee
Inventors
- Yuezhong LI (Changzhou, CN)
- Changda CAI (Changzhou, CN)
- Yabin GONG (Changzhou, CN)
- Ouru ZHAN (Changzhou, CN)
- Qian Li (Changzhou, CN)
Cpc classification
International classification
C12M1/02
CHEMISTRY; METALLURGY
Abstract
A method for improving efficiency of anaerobic fermentation in a medium temperature-high temperature transition zone includes: After being subjected to heat exchange through a front heat exchanger, hydrolyzed slurry is pumped to a bottom of an anaerobic tank. A temperature of the slurry is controlled at 45±0.2° C. A central agitator is turned on after feeding is completed, to slowly gently stir the slurry in the anaerobic tank, and the central agitator is turned off after the slurry is uniformly mixed. In an operating state, making medium-temperature anaerobic flora and high-temperature anaerobic flora in methanogenic bacteria in the anaerobic sludge overlap at the fermentation temperature and be fully mixed with and in contact with the slurry, to continuously treat and convert organic substances in the slurry when the slurry is under an anaerobic fermentation condition in a medium temperature-high temperature transition zone.
Claims
1. A method for improving efficiency of anaerobic fermentation in a medium temperature-high temperature transition zone, comprising the following steps: (1) performing an heat exchange on a hydrolyzed slurry through a front heat exchanger, and then pumping a resulting hydrolyzed slurry into a bottom of an anaerobic tank uniformly from a plurality of water distribution pipes at the bottom of the anaerobic tank, wherein a temperature of the resulting hydrolyzed slurry after the heat exchange performed through the front heat exchanger is 45±0.2° C., a thermal insulation layer and a warming device are arranged on a wall of the anaerobic tank, and an intermittently-operating central agitator with upper blades and lower blades is arranged inside the anaerobic tank; wherein a slurry before hydrolysis is one of a food waste slurry, a vinasse slurry, a cow manure slurry, and a stalk slurry; (2) in an initial state, turning on the intermittently-operating central agitator after a feeding is completed, to slowly gently stir the resulting hydrolyzed slurry in the anaerobic tank, wherein a rotational speed of the intermittently-operating central agitator ranges from 12 to 15 r/min, and turning off the intermittently-operating central agitator after uniformly mixing an upper-layer slurry, a middle-layer slurry, and a lower-layer slurry in the anaerobic tank, wherein a first concentration of an anaerobic sludge in the anaerobic tank in the initial state is 5 to 15 g/l; and (3) in an operating state when a pH value of the resulting hydrolyzed slurry in the anaerobic tank ranges from 6.8 to 7.8, and a second concentration of the anaerobic sludge in the anaerobic tank ranges from 20 to 30 g/l, controlling the warming device, a biogas slurry reflux pump, and the intermittently-operating central agitator of the anaerobic tank through an automatic control system, to control a fermentation temperature of the resulting hydrolyzed slurry at 44±1° C., making a medium-temperature anaerobic flora and a high-temperature anaerobic flora of methanogenic bacteria in the anaerobic sludge overlap at the fermentation temperature and be fully mixed with and in contact with the resulting hydrolyzed slurry, to continuously treat and convert organic substances in the resulting hydrolyzed slurry when the resulting hydrolyzed slurry is under an anaerobic fermentation condition in the medium temperature-high temperature transition zone; wherein temperature sensors for monitoring temperatures of layers of the resulting hydrolyzed slurry and performing a multi-point temperature measurement are arranged on the anaerobic tank; when the temperature sensors detect a temperature difference between two measurement points at a same layer is greater than 2° C. or a temperature difference between two layers is greater than 2° C. the automatic control system automatically turns on the warming device, the intermittently-operating central agitator, and the biogas slurry, reflux pump, to heat the upper-laver slurry, the middle-layer slurry, and the lower-layer slurry through the warming device and to reflux a first upper-layer biogas slurry to a first lower layer through the biogas slurry reflux pump, wherein a reflux ratio of the first upper-layer biogas slurry to the resulting hydrolyzed slurry ranges from 2:1 to 6:1, and the intermittently-operating central agitator slowly gently stirs the resulting hydrolyzed slurry; wherein the rotational speed of the intermittently-operating central agitator ranges from 12 to 15 r/min; and when the temperature sensors detect the temperature difference between the two measurement points at the same layer is less than 1° C. or the temperature difference between the two layers is less than 1° C., the automatic control system controls the warming device and the biogas slurry reflux pump to stop working and the intermittently-operating central agitator lags to stop working.
2. (canceled)
3. (canceled)
4. The method for improving efficiency of anaerobic fermentation in the medium temperature-high temperature transition zone according to claim 1, wherein the hydrolyzed slurry is a food waste slurry after oil extraction and hydrolysis, a carbon-nitrogen ratio of the food waste slurry ranges from 13:1 to 15:1, and a TS concentration of the food waste slurry ranges from 10% to 20% by a mass percentage; and when a COD of the food waste slurry ranges from 120000 to 180000 mg/l, the automatic control system automatically turns on the intermittently-operating central agitator and the biogas slurry reflux pump to reflux a second upper-layer biogas slurry to a second lower layer of the anaerobic tank through the biogas slurry reflux pump, wherein a reflux ratio of the second upper-layer biogas slurry to the food waste slurry ranges from 4.0:1 to 6.0:1, to dilute the food waste slurry and make the COD of the food waste slurry entering into the anaerobic tank lower than 30000 mg/l.
5. The method for improving efficiency of anaerobic fermentation in the medium temperature-high temperature transition zone according to claim 1, wherein the hydrolyzed slurry is a vinasse slurry after hydrolysis, a carbon-nitrogen ratio of the vinasse slurry ranges from 13:1 to 15:1, and a TS concentration of the vinasse slurry ranges from 6% to 8% by a mass percentage; and when a COD of the vinasse slurry ranges from 60000 to 80000 mg/l, the automatic control system automatically turns on the intermittently-operating central agitator and the biogas slurry reflux pump to reflux a third upper-layer biogas slurry to a third lower layer of the anaerobic tank through the biogas slurry reflux pump, wherein a reflux ratio of the third upper-layer biogas slurry to the vinasse slurry ranges from 2.0:1 to 3.0:1, to dilute the vinasse slurry and make the COD of the vinasse slurry entering the anaerobic tank lower than 30000 mg/l.
6. The method for improving efficiency of anaerobic fermentation in the medium temperature-high temperature transition zone according to claim 1, wherein the hydrolyzed slurry is a cow manure slurry after hydrolysis and staying-end-the-for at least 24 hours, and a TS concentration of the cow manure slurry ranges from 8% to 10% by a mass percentage.
7. The method for improving efficiency of anaerobic fermentation in the medium temperature-high temperature transition zone according to claim 1, wherein the hydrolyzed slurry is a stalk slurry after hydrolysis and staying for at least 2 to 3 days.
8. (canceled)
9. (canceled)
10. (canceled)
11. (canceled)
12. (canceled)
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0010] Embodiments of the present invention are further described below with reference to the accompanying drawings.
[0011]
[0012]
[0013]
[0014]
[0015]
[0016]
[0017]
[0018]
[0019]
[0020] 1—front heat exchanger, 2—anaerobic tank, 3—biogas slurry reflux pump, 4—biogas slurry reflux pipe, 5—central agitator, 6—water distribution pipe, 7—sludge-water separator, 8—temperature sensor, 9—sludge reflux pump, 10—hydrolysis tank, 11—silage pit.
DETAILED DESCRIPTION OF THE EMBODIMENTS
[0021] The present invention provides a method for improving efficiency of anaerobic fermentation in a medium temperature-high temperature transition zone, including the following steps: [0022] (1) Perform heat exchange on hydrolyzed slurry through a front heat exchanger 1, as shown in
[0023] As shown in
[0026] In the present invention, the methanogenic medium-temperature anaerobic flora in anaerobic sludge include Methanobacillus formate, Methaniella zoe, Methanobacillus elvesii, Brachyceus rumenis, Methanobacillus bruceti, Methanobacillus vinnefii, Helicobacter heinne, Ococcus pasteurii, Methanobacillus mereson, Methanobacillus subground, Methanobacillus swamp, rumen polyethylene, Methanophilus, and Methanophila. Moreover, the high-temperature anaerobic flora include Methanobacillus thermophilus, Methanobacillus thermoforme, Methanobacillus Vornie, Methanobacillus thermoautotroph, Methanobacillus thermopoly. Because all of these anaerobic bacteria, for example, Methanobacillus formate, Methaniella zoe, Methanobacillus elvesii, Methanophilus, and Methanophila in medium-temperature anaerobic bacteria, can rapidly grow under a fermentation condition of 44±1° C., advantages of medium-temperature flora are fully revealed. In addition, in the transition zone, high-temperature anaerobic bacteria also start to reproduce and function. Medium-temperature anaerobic flora and high-temperature anaerobic flora overlap in this transition zone, so that a best coordination effect can be produced, and fermentation efficiency can be significantly improved.
[0027] In the present invention, to keep the fermentation temperature stable and reliable during operation, temperature sensors 8 for monitoring temperatures of layers of slurry and performing multi-point temperature measurement are arranged on the anaerobic tank 2. A plurality of measurement points are respectively arranged at the upper layer, the middle layer, and the lower layer, so that the temperature sensors 8 can monitor slurry temperature at different positions of respectively layers in time. When it is detected that a temperature difference between any two measurement points at a same layer is greater than 2° C. or a temperature difference between any two layers is greater than 2° C., the automatic control system automatically turns on the warming device, the central agitator 5, and the biogas slurry reflux pump 3. The automatic control system may be an existing control system, and heat the upper-layer, middle-layer, and lower-layer slurry through the warming device. The biogas slurry reflux pump 3 refluxes upper-layer biogas slurry to a lower layer. A reflux ratio of the biogas slurry to the slurry ranges from 2:1 to 6:1. For example, a reflux ratio of the biogas slurry to the slurry ranges from 3:1 to 5:1 or the like. The central agitator 5 slowly gently stirs the slurry, to ensure that the fermentation temperature in the anaerobic tank 2 is stabilized at the anaerobic fermentation temperature of 44±1° C., and make the slurry come into full contact with strains. When it is detected that a temperature difference between any two measurement points at a same layer is less than 1° C. or a temperature difference between any two layers is less than 1° C., the automatic control system automatically controls the warming device and the biogas slurry reflux pump 3 to stop working and the central agitator 5 lag to stop working, to implement stable operation of the devices, to enable the anaerobic reactor to achieve a higher operating load, a higher organic substance removal rate, and a capacity gas yield rate.
Example 1
[0028] As shown in
[0029] In an initial state, the central agitator 5 was turned on after feeding was completed, to slowly gently stir the slurry in the anaerobic tank 2 at 13±0.5 r/min, and the central agitator 5 was turned off after uniformly mixing upper-layer, middle-layer, and lower-layer slurry in the anaerobic tank 2, to make the slurry come into full contact with the anaerobic sludge. The stirring time may be 2±0.1 h. A concentration of anaerobic sludge in the anaerobic tank 2 in the initial state was 10 to 14 g/l.
[0030] During operation, the pH value of the slurry in the anaerobic tank 2 ranged from 7 to 7.5, the concentration of the sludge ranged from 24 to 28 g/l, the TS concentration of the slurry ranged from 3% to 4%, and the fermentation temperature of the slurry was controlled at 43° C., 44° C., and 45° C. respectively for anaerobic reaction. When the COD of the food waste slurry material ranged from 120000 to 180000 mg/l, the automatic control system automatically turned on the central agitator 5 and the biogas slurry reflux pump 3, refluxed upper-layer biogas slurry through the biogas slurry reflux pipe 4 and the water distribution pipe 6 to the lower layer of the anaerobic tank 2 by using the biogas slurry reflux pump 3. A reflux ratio of the biogas slurry to the food waste slurry ranged from 3.5:1 to 5.5:1, to dilute the slurry and make the COD of the food waste slurry entering into the tank lower than 30000 mg/l. After the feeding was completed, the biogas slurry reflux pump 3 was turned off, and the central agitator 5 lagged to be turned off. The central agitator 5 may be turned off 1 h later.
[0031] After the fermentation temperature of the slurry in the anaerobic tank 2 increased due to environmental factors, when it was detected that a temperature difference between any two measurement points at a same layer was greater than 2° C. or a temperature difference between any two layers was greater than 2° C., the automatic control system automatically turned on the warming device, the central agitator 5, and the biogas slurry reflux pump 3. The central agitator 5 slowly and gently stirred at 13 to 14 r/min. The biogas slurry reflux pump 3 refluxed biogas slurry and fresh food waste slurry according to a ratio of 3.5:1 to 5.5:1, to make the fresh material come into full and uniform contact with the anaerobic sludge. When it was detected that a temperature difference between any two measurement points at a same layer was less than 1° C. or a temperature difference between any two layers was less than 1° C., the automatic control system controls the warming device and the biogas slurry reflux pump 3 to stop working and the central agitator 5 lag to stop working. The temperature in the tank was controlled within a specified range, and organic substances in the food waste slurry were continuously treated and converted into methane, carbon dioxide, and water. The biogas was collected through an exhaust pipe. The effluent after sludge-water separation was collected for post-treatment, and discharged or partially reused after meeting standards.
[0032] It can be seen from
Example 2
[0033] The slurry of the present invention was hydrolyzed vinasse slurry. Because vinasse was brewing waste mash distilled at a high temperature of 90° C., as shown in
[0034] During operation, the pH value of the slurry in the anaerobic tank 2 ranged from 7.2 to 7.6, the concentration of the sludge ranged from 25 to 30 g/l, the TS concentration of the slurry ranged from 3% to 4%, and the fermentation temperature of the slurry was controlled at 43° C., 44° C., and 45° C. respectively for anaerobic reaction. When the COD of the vinasse slurry material ranged from 60000 to 180000 mg/l, the automatic control system automatically turned on the central agitator 5 and the biogas slurry reflux pump 3. The central agitator 5 stirred at 13 r/min to 14 r/min. The biogas slurry reflux pump 3 refluxed upper-layer biogas slurry to the lower layer of the anaerobic tank 2. A reflux ratio of the biogas slurry to the food waste slurry ranged from 2.0:1 to 3.0:1. The reflux ratio of 2.5:1 may be used, to dilute the slurry and make the COD of the slurry entering into the tank lower than 30000 mg/l. After the feeding was completed, the biogas slurry reflux pump 3 was turned off. The central agitator 5 was turned off 1 h later. For specific temperature control, reference may be made to Example 1, but the reflux ratios were different. Organic substances in the food waste slurry were continuously treated and converted into methane, carbon dioxide, and water at specified fermentation temperatures. The biogas was collected through an exhaust pipe. The effluent after sludge-water separation was collected for post-treatment, and discharged or partially reused after meeting standards.
[0035]
Example 3
[0036] The slurry of the present invention was hydrolyzed cow manure slurry that stayed for at least 24 hours, and a TS concentration ranged from 8% to 10% by mass percentage. As shown in
[0037] In an initial state, the central agitator 5 was turned on after feeding was completed, to slowly gently stir the slurry in the anaerobic tank 2 at 13.5 r/min to 14.5 r/min, where the stirring time may be 2±0.2 h. The central agitator 5 was turned off, to uniformly mix upper-layer, middle-layer, and lower-layer slurry in the anaerobic tank 2, to make the slurry come into full contact with the anaerobic sludge. A concentration of anaerobic sludge in the anaerobic tank 2 in the initial state was 8 to 12 g/l.
[0038] During operation, the pH value of the slurry in the anaerobic tank 2 ranged from 6.8 to 7.5, the concentration of the sludge ranged from 20 to 25 g/l, the TS concentration of the slurry ranged from 5% to 6%, and the fermentation temperature of the slurry was controlled at 43° C., 44° C., and 45° C. respectively for anaerobic reaction. After the fermentation temperature of the slurry in the anaerobic tank 2 increased due to environmental factors, when it was detected that a temperature difference between any two measurement points at a same layer was greater than 2° C. or a temperature difference between any two layers was greater than 2° C., the automatic control system automatically turned on the warming device, the central agitator 5, and the biogas slurry reflux pump 3. A reflux ratio of the biogas slurry and the slurry ranged from 2:1 to 6:1, to make the fresh material come into full and uniform contact with the anaerobic sludge. When it was detected that a temperature difference between any two measurement points at a same layer was less than 1° C. or a temperature difference between any two layers was less than 1° C., the automatic control system controls the warming device and the biogas slurry reflux pump 3 to stop working and the central agitator 5 lag to stop working. The temperature in the tank was controlled within a specified range, and organic substances in the cow manure slurry were continuously treated and converted into methane, carbon dioxide, and water. The biogas was collected through an exhaust pipe. The effluent after sludge-water separation was collected for post-treatment, and discharged or partially reused after meeting standards.
[0039]
Example 4
[0040] The slurry of the present invention was hydrolyzed stalk slurry that stayed for at least 48 hours. The stalks may be corn stalks, dry wheat stalks, dry straws and weeds, and the like. As shown in
[0041] In an initial state, the central agitator 5 was turned on after feeding was completed, to slowly gently stir the slurry in the anaerobic tank 2 at 14 r/min, where the stirring time may be 2±0.2 h. The central agitator 5 was turned off, to uniformly mix upper-layer, middle-layer, and lower-layer slurry in the anaerobic tank 2, to make the slurry come into full contact with the anaerobic sludge. A concentration of anaerobic sludge in the anaerobic tank in the initial state was 8 g/l.
[0042] During operation, the pH value of the slurry in the anaerobic tank was 7, the concentration of the sludge was 22 g/l, the TS concentration of the slurry ranged from 5% to 6%, and the fermentation temperature of the slurry was controlled at 43° C., 44° C., and 45° C. respectively for anaerobic reaction. For specific temperature control, reference may be made to Example 3. Organic substances in the stalk slurry were continuously treated and converted into methane, carbon dioxide, and water at specified fermentation temperatures. The biogas was collected through an exhaust pipe. The effluent after sludge-water separation was collected for post-treatment, and discharged or partially reused after meeting standards.
[0043]