Aerosol device based on a calcium salt, on a fixing polymer, on a surfactant and on water

Abstract

The invention relates to an aerosol device which contains a composition comprising: (i) one or more water-insoluble calcium salts, (ii) one or more fixing polymers, (iii) one or more surfactants, (iv) water, and (v) less than 20% by weight, relative to the total weight of the composition, of one or more propellants. It also relates to a process for shaping the hair and/or retaining the hairstyle, using the aerosol device of the invention.

Claims

1. An aerosol device which contains a composition, said composition comprising: (i) calcium carbonate, (ii) at least one fixing polymer chosen from AMP-acrylatestallyl methacrylate copolymer, vinyllactam homopolymers, vinyllactam copolymers, vinylamine/vinylformamide copolymers, polyquaternium-4, or mixtures thereof, (iii) at least one surfactant chosen from anionic, cationic, non-ionic, amphoteric, or zwitterionic surfactants, or mixtures thereof, (iv) water, and (v) at least one propellant, present in an amount of less than about 20% by weight, relative to the total weight of the composition, wherein the weight ratio of the total amount of the at least one fixing polymer to the total amount of the at least one surfactant ranges from 0.5 to 8.

2. The aerosol device according to claim 1, wherein the calcium carbonate is in the form of a powder comprising particles which have a mean diameter ranging from about 2 μm to about 50 μm.

3. The aerosol device according to claim 1, wherein the calcium carbonate is present in an amount ranging from about 0.1% to about 15% by weight, relative to the total weight of the composition.

4. The aerosol device according to claim 1, wherein the at least one fixing polymer is present in an amount ranging from about 0.1% to about 15% by weight, relative to the total weight of the composition.

5. The aerosol device according to claim 1, wherein the at least one surfactant is chosen from (C.sub.6-C.sub.24)alkyl sulfates; (C.sub.6-C.sub.24)alkyl ether sulfates comprising from 2 to 50 ethylene oxide units; polyethoxylated C.sub.8-C.sub.18 alcohols, the number of ethylene oxide groups ranging from 2 to 50; vegetable oils, which are optionally hydrogenated; polyethoxylated vegetable oils; (C.sub.8-C.sub.20)alkylbetaines; (C.sub.8-C.sub.20)alkylamido(C.sub.1-C.sub.6)alkylbetaines; (C.sub.8-C.sub.29)alkyl amphodiacetates; cetyltrimethylammonium salts; or mixtures thereof.

6. The aerosol device according to claim 1, wherein the at least one surfactant is present in an amount ranging from about 0.05% to about 10% by weight, relative to the total weight of the composition.

7. The aerosol device according to claim 1, wherein the at least one propellant is chosen from dimethyl ether; 1,1-difluoroethane; C.sub.3-C.sub.5 alkanes; or mixtures thereof.

8. The aerosol device according to claim 1, wherein the at least one propellant is present in an amount of less than about 15% by weight, relative to the total weight of the composition.

9. The aerosol device according to claim 1, wherein the water is present in an amount of more than about 5% by weight, relative to the total weight of the composition.

10. The aerosol device according to claim 1, wherein the composition further comprises at least one thickening polymer.

11. The aerosol device according to claim 10, wherein the at least one thickening polymer is chosen from polysaccharides, scleroglucan gums, or mixtures thereof.

12. The aerosol device according to claim 1, further comprising at least one additive chosen from silicone derivatives in soluble forms, silicone derivatives in dispersed forms, silicone derivatives in micro-dispersed forms; solvents; clays; silica; plasticizers; anti-agglomerating agents; protective screening agents; acids; bases; nacres; flakes; fragrances; permanent dyes; temporary dyes; treating active agents, or mixtures thereof.

13. A method for shaping the hair and/or retaining the hairstyle, the method comprising: applying, to dry or wet hair, a composition sprayed from an aerosol device, the composition comprising: (i) calcium carbonate, (ii) at least one fixing polymer chosen from AMP-acrylates/allyl methacrylate copolymer, vinyllactam homopolymers, vinyllactam copolymers, vinylamine/vinylformamide copolymers, polyquaternium-4, or mixtures thereof, (iii) at least one surfactant chosen from anionic, cationic, non-ionic, amphoteric, or zwitterionic surfactants, or mixtures thereof, (iv) water, and (v) at least one propellant, present in an amount of less than about 20% by weight, relative to the total weight of the composition, wherein the weight ratio of the total amount of the at least one fixing polymer to the total amount of the at least one surfactant ranges from 0.5 to 8; and optionally rinsing the composition from the hair after an optional leave-on time and/or after optional drying.

Description

EXAMPLES

(1) In the examples that follow, all the amounts are indicated as weight percentage of product as active materials relative to the total weight of the composition.

Example 1

(2) The following compositions according to the invention were prepared from the compounds indicated in the table below.

(3) TABLE-US-00001 Composition A B C D E F Calcium carbonate.sup.(1) 5   2   1   1   0.8 3   Polyvinylcaprolactam.sup.(2) 1.2 2   — — — — Vinylpyrrolidone/vinyl acetate — — — 6   — — copolymer.sup.(3) Polyquaternium-4.sup.(4) — — 2   — — — Vinylamine/vinylformamide — — — — 7.7 — copolymer.sup.(5) AMP-acrylates/allyl — — — — — 7.5 methacrylate copolymer.sup.(6) Hydroxyethylcellulose.sup.(7) — 0.1 — —  0.15 — Scleroglucan gum.sup.(8) 0.4 — — 0.3 —  0.22 Polyoxyethylenated (PEG-40) 0.8 0.5 0.7 0.6 0.7 0.6 and hydrogenated castor oil Cetyltrimethylammonium — —  0.05  0.06  0.08 — chloride Laureth-4 1   — 0.5 — 0.2 0.4 Cocamidopropyl betaine — — — 0.2 — — Sodium lauryl sulfate —  0.35 — — —  0.07 Propylene glycol — 3   — — 2   — Fragrance 0.3 0.3 0.3 0.3 0.3 0.3 Preservative 0.3 0.3 0.3 0.3 0.3 0.3 Ethanol — — — 3   — — Isobutane/Butane/Propane.sup.(9) 10   4.5 5   4.5 5   6   Dimethyl ether — — — 1.5 — — 1,1-Difluoroethane.sup.(10) — 1.5 — — — — Water qs 100    100    100    100    100    100    .sup.(1)Sold under the trade name OMYACARE S 60-AV by the company Omya, .sup.(2)Sold under the trade name LUVISKOL PLUS by the company BASF, .sup.(3)Sold under the trade name LUVISKOL VA 64 W by the company BASF, .sup.(4)Sold under the trade name CELQUAT LOR by the company Akzo Nobel, .sup.(5)Sold under the trade name LUVIQUAT 9030 by the company BASF, .sup.(6)Sold under the trade name FIXATE G-100L PR POLYMER by the company Lubrizol, .sup.(7)Sold under the trade name NATROSOL 250 HHR PC by the company Ashland, .sup.(8)Sold under the trade name AMIGEL by the company Alban Muller, .sup.(9)Sold under the trade name PROPEL 45 by the company Repsol, .sup.(10)Sold under the trade name DYMEL 152 A by the company DuPont.

(4) Each composition was then introduced into an aerosol device which comprises a 210 ml aluminium can equipped with a foam-propelling device comprising a valve, in particular a P14180 Precision valve, and a foam diffuser, in particular a DMPR190 Precision diffuser, the valve and the diffuser being sold by the company Valve Precision. The compositions are applied in the form of mousses to a head of hair.

(5) After application of the mousse, it is noted that the fibres are given volume, texturization and body while a natural appearance of the head of hair is maintained, without any helmet effect.

Example 2

(6) A composition of a commercial product (composition H) was compared to a composition according to the invention (composition G).

(7) TABLE-US-00002 Composition G H (Invention) (comparative) Calcium carbonate.sup.(1) 5.23 — Polyquaternium-4 .sup.(2) 1.43 1.41 Scleroglucan gum.sup.(3) 0.29 — Polyoxyethylenated (PEG-40) and 0.86 0.85 hydrogenated castor oil Cetyltrimethylammonium chloride 0.05 0.05 Laureth-4 0.38 0.38 Fragrance 0.29 0.19 Phenoxyethanol 0.67 0.47 Preservative qs qs Propylene glycol 2.38 2.35 Isobutane/Butane/Propane .sup.(4) 5 6 Water qs 100 100 .sup.(1)Sold under the trade name OMYACARE S 60-AV by the company Omya, .sup.(2) Sold under the trade name CELQUAT LOR by the company Akzo Nobel, .sup.(3)Sold under the trade name AMIGEL by the company Alban Muller, .sup.(4) Sold under the trade name PROPEL 45 by the company Repsol.

(8) Each composition was then introduced into an aerosol device which comprises a 210 ml aluminium can equipped with a foam-propelling device comprising a valve, in particular a P14180 Precision valve, and a foam diffuser, in particular a DMPR190 Precision diffuser, the valve and the diffuser being sold by the company Valve Precision.

(9) 2 g of each of the mousses was applied to wet locks per half head. This application is carried out on 6 heads for each of the compositions.

(10) The qualities of use on application and the cosmetic properties conferred on the hair after blow-drying were then evaluated. It emerges therefrom: that, on application, greater texturization is obtained with composition G according to the invention, and that, after blow-drying, the hair treated with composition G according to the invention exhibits greater texturization and greater mass.