Elementary module for a fuel cell
11158869 · 2021-10-26
Assignee
Inventors
- Vincent Faucheux (Lans en Vercors, FR)
- Olivier Blanchot (Sassenage, FR)
- Philippe Capron (Virieu Sur Bourbre, FR)
- Jessica Thery (Saint Jean de Moirans, FR)
Cpc classification
H01M8/0297
ELECTRICITY
Y02E60/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M8/0258
ELECTRICITY
International classification
H01M8/0297
ELECTRICITY
H01M8/0271
ELECTRICITY
H01M8/0258
ELECTRICITY
Abstract
An elementary module including an oxidation unit for generating electrons by oxidizing a fuel with an oxidant, an anode and cathode sandwiching an electrolytic membrane, an anode block including a fuel transporter support for transporting an anode feed flow containing the fuel to an anode chamber and an anode electron collector attached to the fuel transporter support, a cathode block including an oxidant transporter support for transporting a cathode feed flow containing the oxidant to a cathode chamber and a cathode electron collector attached to the oxidant transporter support, the elementary module defining the anode chamber, respectively, the cathode chamber, between the oxidation unit and the fuel transporter support, respectively, the oxidant transporter support, the anode electron collector, respectively, the cathode electron collector and the oxidation unit being attached by bonding and electrically connected by means of an anode conductive bridge, respectively, a cathode conductive bridge, containing an electrically conductive adhesive.
Claims
1. An elementary module of a fuel cell, the elementary module including: an oxidation unit configured to generate electrons by means of the oxidation of a fuel with an oxidant the oxidation unit including an anode and a cathode sandwiching an electrolytic membrane, an anode block including a fuel transporter support suitable for transporting an anode feed flow containing the fuel to an anode chamber, and an anode electron collector attached to the fuel transporter support, a cathode block including an oxidant transporter support suitable for transporting a cathode feed flow containing the oxidant to a cathode chamber, and a cathode electron collector attached to the oxidant transporter support, the elementary module being configured so as to define the anode chamber between the oxidation unit and the fuel transporter support, and the cathode chamber between the oxidation unit and the oxidant transporter support, the anode electron collector and the oxidation unit being both attached by bonding and electrically connected to each other by means of an anode conductive bridge containing an electrically conductive adhesive and the cathode electron collector and the oxidation unit being both attached by bonding and electrically connected to each other by means of a cathode conductive bridge containing the electrically conductive adhesive.
2. The elementary module as claimed in claim 1, in which the oxidation unit includes an anode collecting layer, placed on the face of the anode opposite the face that is facing the electrolytic membrane, and/or a cathode collecting layer, placed on the face of the cathode opposite the face that is facing the electrolytic membrane.
3. The elementary module as claimed in claim 1, in which: the anode conductive bridge is attached by bonding to the anode and/or to the anode collecting layer and/or to the electrolytic membrane, and/or the cathode conductive bridge is attached by bonding to the cathode and/or to the cathode collecting layer and/or to the electrolytic membrane.
4. The elementary module as claimed in claim 1, in which the anode conductive bridge and/or the cathode conductive bridge partially, or even entirely, cover the anode electron collector and/or the cathode electron collector, respectively.
5. The elementary module as claimed in claim 1, in which: the anode electron collector and/or the cathode electron collector are at least partially in the form of strips spaced apart from each other and/or the anode conductive bridge and/or the cathode conductive bridge are in the form of studs or strips.
6. The elementary module as claimed in claim 1, the elementary module extending in a longitudinal plane, in which: the ratio R of the area S.sub.A of the projection of the anode electron collector to the area S of the projection of the fuel transporter support is between 0.01 and 0.50, and/or the ratio R′ of the area S′.sub.A of the projection of the cathode electron collector to the area S′ of the projection of the fuel transporter support is between 0.01 and 0.50, said projections being made on the longitudinal plane, and in a transverse direction with respect to said longitudinal plane.
7. The elementary module as claimed in claim 1, in which the anode conductive bridge is sandwiched between the oxidation unit and the anode electron collector and/or the cathode conductive bridge is sandwiched between the oxidation unit and the cathode electron collector.
8. The elementary module as claimed in claim 1, including: an anode insulating bridge sandwiched between the oxidation unit and the anode collector and/or a cathode insulating bridge sandwiched between the oxidation unit and the cathode electron collector, the anode insulating bridge formed from at least one electrically insulating material and the cathode insulating bridge formed from at least one electrically insulating material.
9. The elementary module as claimed in claim 1, in which the electrically conductive adhesive has anisotropic electrical conductivity.
10. The elementary module as claimed in claim 1, in which the electrically conductive adhesive is formed from a polymer resin in which are dispersed carbon particles or metal particles.
11. The elementary module as claimed in claim 10, in which the particles consist of a metal chosen from silver, gold and mixtures thereof, or are formed from a metal core covered with a carbon coating or a metal coating.
12. The elementary module as claimed in claim 1, in which the oxidation unit and the fuel transporter support are both attached by bonding to each other and electrically insulated from each other by means of an anode leakproofing bridge containing a fuel-leaktight electrically insulating adhesive, the anode leakproofing bridge being configured so that the anode feed flow transported to the anode chamber flows essentially directly from the fuel transporter support to the anode.
13. The elementary module as claimed in claim 1, including a plurality of electrolysis units sharing the same electrolytic membrane.
14. A fuel cell including an elementary module as claimed in claim 1 or a plurality of elementary modules stacked on top of each other in a stacking direction, each elementary module being as claimed in claim 1.
15. The fuel cell as claimed in claim 14, being free of means for compressing the plurality of elementary modules.
Description
BRIEF DESCRIPTION OF THF DRAWINGS
(1) Other features and advantages of the invention will also emerge on reading the detailed description that follows and from the attached drawing, in which:
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DETAILED DESCRIPTION
(12) In the various figures, identical references are used to denote identical or similar members.
(13) The elementary module 5 of
(14) A cathode electron collector 40, in the form of a strip projecting in a transverse direction T relative to the longitudinal plane, is attached to the oxidant transporter support, thus defining with the oxidant transporter support a cathode block 45. It is attached to the cathode by means of a cathode conductive bridge 50 formed from an electrically conductive adhesive. The cathode conductive bridge extends in the transverse direction between two opposite faces 55 and 60, one of them 55 being in contact with the cathode electron collector, the other 60 being in contact with the cathode. Thus, the oxidation unit and the cathode block are attached to each other by bonding and electrically connected.
(15) Moreover, the oxidant transporter support, the cathode electron collector, the cathode conductive bridge and the cathode define a cathode chamber 65. Thus, during functioning, the cathode feed flow, for example generated by a fan and transported in a cathode feed channel, as will be described hereinbelow, passes through the porous oxidant transporter support, as indicated by the arrow O to penetrate into the cathode chamber and come into contact with the cathode so as to ensure the oxidation reaction of the fuel. The cathode electrons resulting from the oxidation reaction which are formed at the cathode may be collected and then, as indicated by the arrow Ec, may then be transferred by means of the cathode collector bridge to the cathode electron collector.
(16) An anode electron collector 70, in the form of a strip projecting in the transverse direction, is attached to the fuel transporter support 35, thus defining with the fuel transporter support an anode block 75. The anode electron collector is attached to the anode by means of an anode conductive bridge 80 formed from an electrically conductive adhesive. The anode conductive bridge extends in the transverse direction between two opposite faces 85 and 90, one of them 90 being in contact with the anode electron collector, the other 85 being in contact with the anode. Thus, the oxidation unit and the anode block are attached to each other by bonding. In addition, the anode electrons resulting from the oxidation reaction of the fuel, which are formed at the anode, may be collected and then, as indicated by the arrow Ea, may then be transferred by means of the anode conductive bridge to the anode electron collector.
(17) In this way, the attachments by bonding of the anode and cathode blocks by means of the respective anode and cathode conductive bridges to the oxidation unit ensure the mechanical strength of the elementary module, without it being necessary to insert permanent compression means for this purpose.
(18) Moreover, an anode leakproofing bridge 100, formed from a fuel-leaktight electrically insulating adhesive seal, is sandwiched between the anode block and the fuel transporter support and holds them a distance from each other, defining an anode chamber 105 extending in a plane parallel to the longitudinal plane. The anode leakproofing bridge forms a leakproofing seal extending between the faces facing the anode and the fuel transporter support, in a transverse direction relative to the longitudinal plane. The anode leakproofing bridge surrounds said anode chamber in a plane parallel to the longitudinal plane. Besides its leakproofing function described hereinbelow, it reinforces the mechanical strength of the elementary module, by adding an additional attachment between the anode block and the oxidation unit. During functioning, the attachment of the oxidation unit by means of the anode leakproofing bridge and the anode conductive bridge allows the elementary module to withstand the fuel pressure in the anode chamber, which is above atmospheric pressure.
(19) Moreover, the elementary module includes a reservoir 108, defining an internal volume 110, including a filling orifice 115 for feeding the reservoir with fuel. The fuel transporter support moreover defines a wall 118 separating the anode chamber from the internal volume of the reservoir.
(20) During functioning, a compressor can inject a fuel flow into the internal volume of the reservoir via the filling orifice, in which the fuel is thus stored. The anode feed flow containing the fuel then passes through the fuel transporter support, which is porous, and penetrates into the anode chamber where it flows, in a transverse direction relative to the longitudinal direction, until it comes into contact with the anode, as indicated by the arrow C. The anode leakproofing bridge limits the flow of the fuel flow in the chamber in any direction contained in the longitudinal plane, as indicated by the arrows L.sub.1 and L.sub.2, and thus reduces the leaks of fuel out of the anode chamber.
(21) The elementary module of
(22) The anode and cathode collecting layers improve the collection of the anode and cathode electrons generated remotely from the anode and cathode electron collectors, respectively.
(23) In order for the fuel and the oxidant to be able to come into contact with the anode and the cathode, respectively, the electron collecting layers may partially cover said faces of the anode and cathode and, for example, may be fuel-leaktight or oxidant-leaktight, respectively. In this variant, the fuel and the oxidant may come into contact with the anode and the cathode, respectively, in the zones of said faces of the anodes and cathodes that are not covered with the anode and cathode collecting layers, respectively. The anode and cathode collecting layers may also be in the form of a film that is porous with respect to the fuel and to the oxidant, respectively, and which covers, for example entirely, said faces of the anode and cathode, respectively.
(24) In the example of
(25) Moreover, to further reinforce the mechanical strength of the elementary module, the elementary module of
(26) Although this is not illustrated, the elementary module of
(27) The elementary module of
(28) In the variant in which the mechanical connection between the anode, respectively, the cathode and the electrolytic membrane is weak, the mechanical strength of the elementary module is improved, the connections of the anode and cathode blocks, respectively, by means of the anode and cathode conductive bridges, respectively, with the oxidation unit being made directly with the electrolytic membrane.
(29) The anode conductive bridge 80, respectively, the cathode conductive bridge 50 has a relief 165, respectively, 170 projecting longitudinally and being placed in contact with the anode collecting layer, respectively, with the cathode collecting layer. The relief of the anode conductive bridge, respectively, of the cathode conductive bridge places the anode, respectively, the cathode in electrical contact with the anode electron collector, respectively, with the cathode electron collector.
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(32) The fuel cell of
(33) The fuel cell also has a second hollow tube 210 placed such that the elementary module 5 is sandwiched between the first 185 and second 210 hollow tubes. The second hollow tube has a wall in common with the reservoir. It defines a cooling channel 212 having an inlet aperture 215 configured for the inlet of a cooling flow R including a heat transfer fluid such as air, placed facing a fan 220 configured to generate and distribute said cooling flow to said inlet aperture.
(34) When it flows in the cooling channel as indicated according to the arrow R, the elementary module exchanges heat generated by the exothermic oxidation reaction by convection on the wall 225 common to the module and to the second hollow tube. The cooling flow thus heated flows to an outlet aperture 230 placed opposite the inlet aperture, via which it is evacuated from the fuel cell.
(35) As may be seen in
(36) Moreover, in the example of
(37) In a variant not shown, and notably when the cell is intended for generating an electric current within a limited operating temperature range, the cell may be free of means as described, for example, in
(38) The fuel cell 250 of
(39) Each elementary module of the plurality is identical to that illustrated in
(40) The fuel cell is configured such that each pair of two consecutive elementary modules of the stack is such that said two elementary modules, for example 5a and 5b, are arranged head to tail relative to each other in the stacking direction.
(41) The modules of the stack are electrically connected by means of an electrical circuit, not shown, connecting an anode electron collector of one elementary module to a cathode electron collector of an adjacent elementary module.
(42) In the stack of
(43) Moreover, two consecutive elementary modules whose anode blocks, for example 75b and 75c, are placed facing each other and are separated by a cooling channel 260 extending in a transverse plane relative to the stacking direction. Thus, by means of a single cooling channel, the two elementary modules 5b and 5c are cooled by convective exchange with the cooling flow R flowing in the channel.
(44) In this way, the fuel cell 250 of
(45) As regards the generation of the cathode feed flows and of the cooling flows, the fuel cell of
(46) Moreover, the fuel cell illustrated in
(47) In this way, by means of a single cathode feed probe, the flow rate of the cathode feed flows of the plurality of cathode feed channels of the cell can be easily regulated.
(48) The fuel cell of
(49) In this way, by means of a single cooling probe, the flow rate of the cooling flows of the plurality of cooling channels of the cell can be easily regulated.
(50) The fuel cell also includes a sensor 300 placed in an elementary module to measure, for example, the internal resistance of the elementary module. The sensor is connected to the units for controlling the cathode feed fan and cooling fan which are also each configured to regulate the flow rates of the cathode feed flow and the cooling flow as a function of the internal resistance measurement of the elementary module.
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(52) The elementary modules of the fuel cell are placed head to tail in pairs as in the example of
(53) The fuel cell of
(54) In the example of
(55) Thus, although each cathode feed channel and each cooling channel have apertures on the four side faces 280a-d of the cell, interactions with harmful consequences for the functioning of the fuel cell, between cathode feed flows and cooling flows, are limited.
(56) The fuel cell of
(57) For example, to obtain the cell illustrated in
(58) In this way, the cathode feed flows and cooling flows flow in perpendicular directions and do not interfere with each other.
(59) In the example of
(60) Moreover, the stack of
(61) The fuel cell of
(62) Finally, none of the elementary modules described in
Example
(63) A fuel cell, a photograph of which is shown in
(64) Each elementary module weighs 8 g and is capable of generating an electric power of 8 W. Two consecutive elementary modules are placed head to tail in the stacking direction and are spaced 1.2 mm apart, by means of a spacer formed by foam bars, the opposite faces of which, each in contact with one of said two consecutive modules, are covered with adhesive. The stack is in the form of a right slab, with a length of 117 mm, a width of 74 mm and a thickness of 45 mm.
(65) The fuel cell has a volume of 0.4 liter and a mass of less than 150 g. It is capable of generating an electric power of 100 W and has a power density per unit mass of 0.67 W.Math.g.sup.−1. It is moreover suitable for generating electrical energy over a temperature range of between −20° C. and 50° C.
(66) The fuel cell has an internal resistance of 175 mΩ.Math.cm.sup.2, similar to that of a cell of the prior art including end clamping plates and having a lower power density per unit mass for the same generated power. This internal resistance value indicates that the collection of electrons and the electrical connection of the elementary modules is of good quality.
(67) Moreover, the pressure resistance measurements indicate that the fuel cell can withstand a maximum dihydrogen pressure of 3 bar in the anode chamber of each elementary module. In addition, as regards the leaktightness of the anode chamber, the measurements of leaktightness by infiltration of helium indicate that the rate of leakage is low, less than 0.1 cm.sup.3/min
(68) For comparative purposes, the performance qualities of the present fuel cell may be compared with a fuel cell formed from a stack of modules compressed by end plates, sold by the company Horizon FC. This cell functions within a lower temperature range of between 0° C. and 40° C. and is capable of generating a power of 200 W. However, it has a mass of 470 g and thus a low power density per unit mass equal to 0.42 W.Math.g.sup.−1 compared with the fuel cell of the invention.
(69) Needless to say, the invention is not limited to the embodiments and examples described above.
(70) For example, notably in the variant in which the cathode feed channel and/or the cooling channel have bent shapes, for example a coil or a plurality of parallel tubes, the cell may include a compressor, a distribution channel being connected to the compressor, the compressor being configured to distribute a cathode feed flow and/or a cooling flow at the inlet of the cathode feed channel and/or of the cooling channel, respectively.
(71) Moreover, preferably, the cooling flow may include a heat transfer fluid other than air, for example a liquid, for example water or an oil.
(72) Moreover, the fuel is not limited to dihydrogen. It may also be an alkane chosen, for example, from methane, propane, butane and mixtures thereof, or an alcohol in vapor form chosen, for example, from ethanol, methanol and mixtures thereof. The oxidant is not limited to dioxygen. It may also be a gas including dioxygen, for example air, or a mixture constituted of dioxygen and dinitrogen.
(73) Finally, the terms “comprising a”, “containing a” and “including a” are understood as equivalently meaning, respectively, “comprising at least one”, “containing at least one” and “including at least one”.