METHOD OF PRODUCING HOT-DIP METAL COATED STEEL STRIP AND CONTINUOUS HOT-DIP METAL COATING LINE
20210310109 · 2021-10-07
Assignee
Inventors
- Yu TERASAKI (Chiyoda-ku, Tokyo, JP)
- Hideyuki TAKAHASHI (Chiyoda-ku, Tokyo, JP)
- Takumi KOYAMA (Chiyoda-ku, Tokyo, JP)
- Yoshihiko KAKU (Chiyoda-ku, Tokyo, JP)
Cpc classification
C23C2/00344
CHEMISTRY; METALLURGY
C23C2/0038
CHEMISTRY; METALLURGY
International classification
C23C2/00
CHEMISTRY; METALLURGY
Abstract
Provided is a method of producing a hot-dip metal coated steel strip with which a hot-dip metal coated steel strip of high quality can be produced by sufficiently suppressing edge overcoating. The method comprises spraying gas from a pair of gas wiping nozzles 20A and 20B onto a steel strip S while being pulled up from a molten metal bath 14, to adjust a coating weight of molten metal on both sides of the steel strip S, wherein a pair of baffle plates 40 and 42 are respectively placed outside of both transverse edges of the steel strip, and a height B of a lower end of each of the pair of baffle plates 40 and 42 with respect to a bath surface of the molten metal bath is set to +50 mm or less, where an upper side in a vertical direction is positive.
Claims
1. A method of producing a hot-dip metal coated steel strip, the method comprising: continuously immersing a steel strip into a molten metal bath; and spraying, onto the steel strip while being pulled up from the molten metal bath, gas from respective slit-like gas jet orifices of a pair of gas wiping nozzles arranged so that the steel strip is situated therebetween, to adjust a coating weight of molten metal on both sides of the steel strip to thereby continuously produce a hot-dip metal coated steel strip, the gas jet orifices each being wider than the steel strip in a transverse direction of the steel strip, wherein a pair of baffle plates are respectively placed outside of both transverse edges of the steel strip in a state in which both sides of each of the pair of baffle plates partially face the respective gas jet orifices of the pair of gas wiping nozzles, and a height B of a lower end of each of the pair of baffle plates with respect to a bath surface of the molten metal bath is set to +50 mm or less, where an upper side in a vertical direction is positive.
2. The method of producing a hot-dip metal coated steel strip according to claim 1, wherein the height B is set to −10 mm or more.
3. The method of producing a hot-dip metal coated steel strip according to claim 1, wherein the pair of gas wiping nozzles are each placed to point downward with respect to a horizontal plane so that an angle θ between the gas jet orifice and the horizontal plane is 10° or more and 75° or less.
4. The method of producing a hot-dip metal coated steel strip according to claim 1, wherein a chemical composition of the molten metal contains Al: 1.0 mass % to 10 mass %, Mg: 0.2 mass % to 1 mass %, and Ni: 0 mass % to 0.1 mass %, with a balance being Zn and inevitable impurities.
5. A continuous hot-dip metal coating line, comprising: a coating tank configured to contain molten metal and form a molten metal bath; a pair of gas wiping nozzles arranged so that a steel strip being continuously pulled up from the molten metal bath is situated therebetween, having respective slit-like gas jet orifices that are each wider than the steel strip in a transverse direction of the steel strip, and configured to spray gas from the respective gas jet orifices onto the steel strip to adjust a coating weight on both sides of the steel strip; and a pair of baffle plates respectively arranged outside of both transverse edges of the steel strip in a state in which both sides of each of the pair of baffle plates partially face the respective gas jet orifices of the pair of gas wiping nozzles, wherein a height B of a lower end of each of the pair of baffle plates with respect to a bath surface of the molten metal bath is +50 mm or less, where an upper side in a vertical direction is positive.
6. The continuous hot-dip metal coating line according to claim 5, wherein the height B is −10 mm or more.
7. The continuous hot-dip metal coating line according to claim 5, wherein the pair of gas wiping nozzles are each placed to point downward with respect to a horizontal plane so that an angle θ between the gas jet orifice and the horizontal plane is 10° or more and 75° or less.
8. The continuous hot-dip metal coating line according to claim 6, wherein the pair of gas wiping nozzles are each placed to point downward with respect to a horizontal plane so that an angle θ between the gas jet orifice and the horizontal plane is 10° or more and 75° or less.
9. The method of producing a hot-dip metal coated steel strip according to claim 2, wherein the pair of gas wiping nozzles are each placed to point downward with respect to a horizontal plane so that an angle θ between the gas jet orifice and the horizontal plane is 10° or more and 75° or less.
10. The method of producing a hot-dip metal coated steel strip according to claim 2, wherein a chemical composition of the molten metal contains Al: 1.0 mass % to 10 mass %, Mg: 0.2 mass % to 1 mass %, and Ni: 0 mass % to 0.1 mass %, with a balance being Zn and inevitable impurities.
11. The method of producing a hot-dip metal coated steel strip according to claim 3, wherein a chemical composition of the molten metal contains Al: 1.0 mass % to 10 mass %, Mg: 0.2 mass % to 1 mass %, and Ni: 0 mass % to 0.1 mass %, with a balance being Zn and inevitable impurities.
12. The method of producing a hot-dip metal coated steel strip according to claim 9, wherein a chemical composition of the molten metal contains Al: 1.0 mass % to 10 mass %, Mg: 0.2 mass % to 1 mass %, and Ni: 0 mass % to 0.1 mass %, with a balance being Zn and inevitable impurities.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0020] In the accompanying drawings:
[0021]
[0022]
[0023]
[0024]
[0025]
[0026]
[0027]
[0028]
[0029]
[0030]
DETAILED DESCRIPTION
[0031] A method of producing a hot-dip metal coated steel strip and a continuous hot-dip metal coating line (hereafter also simply referred to as “coating line”) 100 according to one of the disclosed embodiments will be described below, with reference to
[0032] With reference to
[0033] The pair of gas wiping nozzles (hereafter also simply referred to as “nozzles”) 20A and 20B face each other with the steel strip S therebetween, above the coating tank 12. With reference to
[0034] As illustrated in
[0035] As illustrated in
[0036] In the method of producing a hot-dip metal coated steel strip according to this embodiment, the steel strip S is continuously immersed into the molten metal bath 14, and gas is sprayed onto the steel strip S while being pulled up from the molten metal bath 14 from the pair of gas wiping nozzles 20A and 20B arranged so that the steel strip S is situated therebetween to adjust the coating weight of the molten metal on both sides of the steel strip S, thus continuously producing a hot-dip metal coated steel strip.
[0037] With reference to
[0038] The shape of each of the baffle plates 40 and 42 is not limited, but is preferably rectangular as illustrated in
[0039] With reference to
[0040] Particularly under high coating weight and low gas pressure conditions of a target coating thickness of 120 g/m.sup.2 or more and a header pressure P of 30 kPa or less, the edge portion of the steel strip surface tends to lift top dross (a mass of zinc floating on the pot bath surface), so that edge overcoating tends to worsen. The effect of suppressing edge overcoating according to the present disclosure is particularly remarkable under such conditions. Here, the header pressure P is preferably 1 kPa or more.
[0041] The height B is preferably −10 mm or more. This can reduce the possibility that the baffle plates come into contact with the support rolls 18 in the molten metal bath or the baffle plates hinder flow of dross in the bath and increase dross defects.
[0042] In an operation example, the height of the bath surface slightly changes during operation. Specifically, as a result of the steel strip taking the molten zinc out, the height of the bath surface decreases gradually. Once the height of the bath surface has decreased by approximately several mm, an ingot of the bath composition is gradually added during operation to restore the original bath surface height. The bath surface height can be constantly monitored by a laser displacement meter. Since the method of producing a hot-dip metal coated steel strip according to this embodiment achieves the effect of suppressing edge overcoating by performing wiping in a state in which the height B is +50 mm or less, it is preferable to constantly maintain the state in which the height B is +50 mm or less during operation, but the present disclosure is not limited to such and includes cases where the height B temporarily exceeds +50 mm during operation. It is to be noted that the continuous hot-dip metal coating line according to this embodiment is configured to perform control so as to constantly maintain the state in which the height B is +50 mm or less during operation.
[0043] The height of the upper end of each of the baffle plates 40 and 42 is not limited, as long as it is higher than the position of the gas jet orifice 28. From the viewpoint of reliably preventing direct collision of the gas, the height of the upper end of each of the baffle plates 40 and 42 is preferably 10 mm or more higher than the gap center position of the gas jet orifice 28. From the viewpoint of avoiding providing the baffle plates in unnecessary areas, the height of the upper end of each of the baffle plates 40 and 42 is preferably 300 mm or less higher than the gap center position of the gas jet orifice 28.
[0044] With reference to
[0045] The material of the baffle plates is not limited. In this embodiment, since the baffle plates are close to the bath surface, top dross or splashes (splashes of molten zinc) may adhere to the baffle plates and alloy with the baffle plates and stick thereto. Moreover, in the case where the baffle plates are immersed in the bath, not only the foregoing alloying but also thermal deformation needs to be taken into consideration. From this viewpoint, examples of the material of the baffle plates include iron plates to which a boron nitride-based spray repellent to zinc has been applied, and SUS316L that is hard to react with zinc. Further, ceramic such as alumina, silicon nitride, or silicon carbide is desirable because both alloying and thermal deformation can be suppressed.
[0046] With reference to
[0047] With reference to
[0048] With reference to
[0049] The gas sprayed from the gas wiping nozzle is not limited, and may be, for example, air. The gas may be inert gas. By using inert gas, oxidation of the molten metal on the steel strip surface can be prevented, so that viscosity unevenness of the molten metal can be further suppressed. The inert gas may contain, but is not limited to, one or more selected from the group consisting of nitrogen, argon, helium, and carbon dioxide.
[0050] In this embodiment, the chemical composition of the molten metal preferably contains Al: 1.0 mass % to 10 mass %, Mg: 0.2 mass % to 1 mass %, and Ni: 0 mass % to 0.1 mass %, with the balance being Zn and inevitable impurities. It has been recognized that the molten metal having such Mg content is easily oxidizable and the amount of top dross increases, and as a result edge overcoating tends to occur. Hence, in the case where the molten metal has the foregoing chemical composition, the effect of suppressing edge overcoating according to the present disclosure is remarkable. In the case where the chemical composition of the molten metal is 5 mass % Al—Zn and in the case where the chemical composition of the molten metal is 55 mass % Al—Zn, too, the effect of suppressing edge overcoating according to the present disclosure can be achieved.
[0051] A hot-dip metal coated steel strip produced by the production method and the coating line according to the present disclosure is, for example, a hot-dip galvanized steel sheet. Examples of the hot-dip galvanized steel sheet include a galvanized steel sheet (GI) obtained without alloying treatment after hot-dip galvanizing treatment and a galvannealed steel sheet (GA) obtained by performing alloying treatment after hot-dip galvanizing treatment.
EXAMPLES
Example 1
[0052] A hot-dip galvanized steel strip production test was conducted in a hot-dip galvanized steel strip production line. The coating line illustrated in
[0053] As a method of supplying gas to each gas wiping nozzle, a method of supplying, to the nozzle header, gas pressurized to a predetermined pressure by a compressor was employed. The gas type was air, and the wiping gas temperature was 100° C. A steel strip with a thickness of 1.2 mm and a width of 1000 mm was passed through the line at a predetermined steel strip speed L to produce a hot-dip galvanized steel strip.
[0054] The edge overcoating ratio R on both sides of the produced hot-dip galvanized steel strip was measured and evaluated according to the following procedure. The total target coating weight CW (g/m.sup.2) on both sides for each sample is indicated in Table 1. For the galvanized steel strip produced for each sample, the total actual coating weight CWc (g/m.sup.2) on both sides in a steel sheet center portion and the total actual coating weight CWe (g/m.sup.2) on both sides in a steel sheet edge portion were measured. The results are indicated in Table 1. The measurement of each of CWc and CWe was performed on one part of each of both sides in accordance with JIS G3302. The edge overcoating ratio R was calculated as (CWe/CWc−1)×100(%). The results are indicated in Table 1. Table 1 also indicates, for each coating type, the edge overcoating improving ratio relative to the edge overcoating ratio in the case where no baffle plates were used. For coating type B, the edge overcoating improving ratio in each of Nos. 9 to 13 and 18 to 23 is relative to No. 8, and the edge overcoating improving ratio in each of Nos. 15 to 17 is relative to No. 14. Each sample having an edge overcoating improving ratio of 50% or more was evaluated as pass, and each sample having an edge overcoating improving ratio of less than 50% was evaluated as fail.
TABLE-US-00001 TABLE 1 Height B of lower Dis- Actual Actual end of tance coating coating baffle d weight weight plate between CWc CWe Edge with nozzle in in Edge over- respect Gas tip Target steel steel over- coating to Nozzle pres- and strip coating sheet sheet coating im- Coat-- Molten bath bath angle sure steel speed weight center edge ratio proving ing composition [%] surface θ P strip L CW portion portion R ratio No. Category type Al Mg Ni Si Zn [mm] [°] [kPa] [mm] [m/min] [g/m.sup.2] [g/m.sup.2] [g/m.sup.2] [%] [%] 1 Comparative A 0.2 0 0 0 Bal- No 0 25 13 90 120 118 182 54 — Example ance baffle plates 2 Compamtive 200 0 25 13 90 120 120 162 35 35 Example 3 Compamtive 70 0 25 13 90 120 121 158 31 44 Example 4 Example 50 0 25 13 90 120 122 142 16 70 5 Example 25 0 25 13 90 120 119 135 13 75 6 Example 0 0 25 13 90 120 120 132 10 82 7 Example 0 30 28 13 90 120 120 124 3 94 8 Comparative B 4.5 0.5 0.05 0 Bal- No 0 5.5 17 55 270 272 561 106 — Example ance baffle plates 9 Comparative 200 0 5.5 17 50 270 270 493 83 22 Example 10 Comparative 70 0 5.5 17 50 270 270 487 80 24 Example 11 Example 50 0 5.5 17 50 270 271 384 42 61 12 Example 25 0 5.5 17 50 270 270 350 30 72 13 Example 0 0 5.5 17 50 270 268 316 18 83 14 Comparative No 0 22 13 90 120 123 220 79 — Example baffle plates 15 Example 50 0 22 13 90 120 120 144 20 75 16 Example 25 0 22 13 90 120 121 140 16 80 17 Example 0 0 22 13 90 120 120 131 9 88 18 Example 0 10 5.5 17 50 275 274 315 15 86 19 Example 0 15 5.5 17 50 280 279 307 10 91 20 Example 0 30 5.5 17 50 290 292 318 9 92 21 Example 0 50 5.5 17 50 310 310 342 10 90 22 Example 0 75 5.5 17 50 320 322 359 11 89 23 Example 0 30 8 17 50 270 270 284 5 95 24 Comparative C 5 0 0 0 Bal- No 0 14 14 80 180 180 309 72 — Example ance baffle plates 25 Comparative 200 0 14 14 80 180 179 272 52 28 Example 26 Comparative 70 0 14 14 80 180 178 266 49 31 Example 27 Example 50 0 14 14 80 180 178 226 27 62 28 Example 25 0 14 14 80 180 180 216 20 72 29 Example 0 0 14 14 80 180 181 207 14 80 30 Example 0 30 16 14 80 180 180 185 3 96 31 Comparative D 55 0 0 1.6 Bal- No 0 8 14 70 200 203 323 59 — Example ance baffle plates 32 Comparative 200 0 8 14 70 200 201 287 43 28 Example 33 Comparative 70 0 8 14 70 200 198 280 41 30 Example 34 Example 50 0 8 14 70 200 198 247 25 58 35 Example 25 0 8 14 70 200 200 236 18 70 36 Example 0 0 8 14 70 200 199 221 11 81 37 Example 0 30 10 14 70 200 199 206 4 94 38 Comparative E 5 0.9 0 0 Bal- No 0 6 16 60 240 240 467 95 — Example ance baffle plates 39 Comparative 200 0 6 16 60 240 241 404 68 28 Example 40 Comparative 70 0 6 16 60 240 238 392 65 32 Example 41 Example 50 0 6 16 60 240 239 306 28 70 42 Example 25 0 6 16 60 240 240 292 22 77 43 Example 0 0 6 16 60 240 241 278 15 84 44 Example 0 30 9 16 60 240 239 269 13 87 45 Comparative F 4.9 0.6 0.09 0 Bal- No 0 4.5 25 45 350 350 668 91 — Example ance baffle plates 46 Comparative 200 0 4.5 25 45 350 347 603 74 19 Example 47 Comparative 70 0 4.5 25 45 350 348 588 69 24 Example 48 Example 50 0 4.5 25 45 350 352 453 29 68 49 Example 25 0 4.5 25 45 350 348 412 18 80 50 Example 0 0 4.5 25 45 350 351 401 14 84 51 Example 0 30 8 25 45 350 350 366 5 95
[0055] As is clear from Table 1, in the case where the height B of the lower end of the baffle plate with respect to the bath surface was 50 mm or less, the edge overcoating ratio R was low and the edge overcoating improving ratio was 50% or more, and a coated steel sheet of good quality was able to be produced. In the case where the height B of the lower end of the baffle plate with respect to the bath surface was outside the range according to the present disclosure, on the other hand, the edge overcoating ratio R was high and the edge overcoating improving ratio was less than 50%. Particularly in coating types B, E, and F, the effect in the case of limiting the height B of the lower end of the baffle plate with respect to the bath surface to be within the range according to the present disclosure was remarkable.
Example 2
[0056] A hot-dip galvanized steel strip production test was conducted using the coating line illustrated in
[0057] Gas wiping nozzles with a nozzle gap of 1.2 mm were used. The composition of the molten bath contained Al: 0.2 mass %, with the balance being zinc. The nozzle angle θ was 0°, the wiping gas pressure (header pressure) P was 8 kPa, the distance d between the nozzle tip and the steel strip was 10 mm, and the steel strip speed L was 50 m/min. The upper end of the baffle plate was 70 mm higher than the gap center position of the gas jet orifice. The nozzle height H from the bath surface was 200 mm. The material of the baffle plate was silicon nitride, the thickness of the baffle plate was 3 mm, and the distance E between the transverse edge of the steel strip and the baffle plate was 5 mm.
[0058] The edge overcoating ratio R was measured in the same way as in Example 1.
[0059] As is clear from
INDUSTRIAL APPLICABILITY
[0060] It is possible to provide a method of producing a hot-dip metal coated steel strip and a continuous hot-dip metal coating line that can produce a hot-dip metal coated steel strip of high quality by sufficiently suppressing edge overcoating.
REFERENCE SIGNS LIST
[0061] 100 continuous hot-dip metal coating line [0062] 10 snout [0063] 12 coating tank [0064] 14 molten metal bath [0065] 16 sink roll [0066] 18 support roll [0067] 20A gas wiping nozzle [0068] 20B gas wiping nozzle [0069] 22 nozzle header [0070] 24 upper nozzle member [0071] 26 lower nozzle member [0072] 28 gas jet orifice [0073] 40 baffle plate [0074] 42 baffle plate [0075] S steel strip [0076] B height of lower end of baffle plate with respect to bath surface [0077] θ angle between gas jet orifice and horizontal plane [0078] d distance between nozzle tip and steel strip [0079] H nozzle height [0080] E distance between transverse edge of steel strip and baffle plate