YANKEE ADHESIVE COMPOSITIONS AND METHODS OF USING THESE COMPOSITIONS

Abstract

The invention relates to a method of transferring a tissue web with residual moisture to a Yankee cylinder and final removal of the dried tissue web from the Yankee cylinder using a doctor blade and collecting the dried web on a reel-up machine forming a tissue reel. The invention also relates to the Yankee adhesive composition per se. The method involves preparation of a water solution of a Yankee adhesive composition with less than 10% final solids content to be applied on the surface of the Yankee cylinder ahead of transferring the tissue web with residual moisture to the Yankee cylinder. The inventive method applies an aqueous PVOH solution with a very high molecular weight polyvinyl alcohol as a part of the solid content of the Yankee adhesive in an amount ranging from 20-65% of the final solids content of the Yankee adhesive. The aqueous PVOH solution with the very high molecular weight polyvinyl alcohol establish a viscosity ranging from 90 cP to 300 cP.

Claims

1-20. (canceled)

21. A method of transferring a tissue web (W) with residual moisture to a Yankee cylinder (CR) and final removal of the dried tissue web from the Yankee cylinder using a doctor blade, and collecting the dried web on a reel-up machine forming a tissue reel, the method comprising: (a) preparing a water solution of a Yankee adhesive with less than 10% final solids content to be applied on the surface of the Yankee cylinder ahead of transferring the tissue web with residual moisture to the Yankee cylinder; and (b) adding an aqueous PVOH solution with a very high molecular weight polyvinyl alcohol into the solution of the Yankee adhesive in an amount ranging from 25-65% of the final solids content of the Yankee adhesive, wherein the aqueous PVOH solution is reaching a resulting viscosity ranging from 90 mPa-s to 300 mPa-s.

22. The method according to claim 21, wherein the aqueous PVOH solution is heated to a temperature in the range 80-100° C. during storage of the aqueous PVOH solution.

23. The method according to claim 22, wherein the heated aqueous PVOH solution is cooled down to a temperature in the range 40-65° C. before adding the aqueous PVOH solution into the solution of the Yankee adhesive.

24. The method according to claim 21, wherein a pre-made aqueous PVOH solution is added into the water solution of the Yankee adhesive.

25. The method according to claim 21, wherein a release agent is mixed into the aqueous PVOH solution in an amount ranging from 10-40% of the final solids content of the Yankee adhesive.

26. The method according to claim 21, wherein an additional creping adhesive agent is mixed into the aqueous PVOH solution in an amount ranging from 15-45% of the final solids content of the Yankee adhesive.

27. The method according to claim 26, wherein the additional creping adhesive agent is a thermosetting or non-thermosetting adhesive resins selected from a group of creping adhesive agents including poly(aminoamide)-epihalohydrin polymer (PAE) resins; other polyvinyl alcohol (PVOH) resins, epichlorohydrin, PEI resins, PVAM resins, Polyamine resins and PVP resins.

28. The method according to claim 27, wherein the weight ratio between the PVOH and PAE resin is in the range 1:1 to 2.5:1.

29. The method according to claim 21, wherein the aqueous PVOH solution is mixed on site by adding PVOH powder into a flow of water using a mixer, heating the aqueous PVOH solution to about 80-130° C. and storing the aqueous PVOH solution during a minimum time period of 45-200 minutes, and before feeding the aqueous PVOH solution onto the Yankee cylinder cooling the aqueous PVOH solution to a lower temperature in the range 40-65° C.

30. The method according to claim 21, wherein additional additives are added to the aqueous PVOH solution using additional mixers for mixing these additional additives.

31. The method according to claim 30, wherein each additive is mixed into the aqueous PVOH solution, using a dedicated mixer for each additive.

32. The method according to claim 31, wherein the aqueous PVOH solution is passing several mixers for different additives before being applied onto the surface of the Yankee cylinder as the final Yankee adhesive (YA).

33. The method according to claim 25, wherein the release agent is mixed into the aqueous PVOH solution after a storage time of the aqueous PVOH solution and within 5 minutes from application of the final Yankee adhesive(YA) onto the Yankee surface.

34. The method according to claim 26, wherein the additional creping adhesive agent is mixed into the aqueous PVOH solution after a storage time of the aqueous PVOH solution and within 5 minutes from application of the final Yankee adhesive (YA) onto the Yankee surface.

35. The method according to claim 21, wherein the tissue web is partially dried to a consistency of at least 35% prior to transferring the tissue web with residual moisture to the Yankee cylinder.

36. The method according to claim 35, wherein the tissue web is dried to a consistency of at least 90% upon final removal of the dried tissue web from the Yankee cylinder.

37. Yankee adhesive composition comprising: a water solution containing at least 90% per weight of water and up to 10% by weight of solids; and a part of the solids content containing a very high molecular weight polyvinyl alcohol (PVOH) in an amount ranging from 25-65% of the solids and added into the Yankee adhesive composition as an aqueous PVOH solution, which aqueous PVOH solution has a viscosity ranging from 90 mPa-s to 300 mPa-s.

38. Yankee adhesive composition according to claim 37, comprising further a part of the solids content containing a release agent in an amount ranging from 10-40% of the solids content.

39. Yankee adhesive composition according to claim 38, comprising further a part of the solids content containing an additional creping adhesive agent in an amount ranging from 15-35% of the solids content.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0051] The invention is described in detail with reference to following figures in which:

[0052] FIG. 1 is a schematic layout of a part of a tissue machine wherein a tissue web is fed, transferred to the surface of a Yankee cylinder and finally taking off the dried web and collecting the web on a paper reel;

[0053] FIG. 2a is a schematic layout of a Yankee adhesive application system in a first embodiment;

[0054] FIG. 2b is a schematic layout of a Yankee adhesive application system in a second embodiment;

[0055] FIG. 2c is a schematic layout of a Yankee adhesive application system in a third embodiment;

[0056] FIG. 2d is a schematic layout of a Yankee adhesive application system in a fourth embodiment; and

[0057] FIG. 3 is an alternative embodiment of a retention vessel used to prepare and store the Yankee adhesive composition.

DETAILED DESCRIPTION

[0058] As to definitions of web consistency is weight percent used, meaning that a 35% web consistency comprises 65% water per weight, and 35% bone dry pulp (including fillers, brightening agents etc).

[0059] As to definitions of Yankee adhesive compositions is a composition including 90% water and 10% total solids comprising 90% water per weight and the total solids comprising in total 10% solids per weight.

[0060] “Wet-tack” refers generally to the ability of an adhesive coating on a Yankee drying cylinder to adhere a wet web to the Yankee before additional drying on the Yankee cylinder.

[0061] Polyvinyl alcohol resins, hereinafter referred to as PVOH, may be manufactured using differing processes and obtaining differing degree of polymerization. However, the degree of polymerization is not clearly related to obtainable viscosity in an aqueous solution as some PVOH with higher degree of polymerization could result in lower obtainable viscosity in an aqueous solution than another PVOH with lower degree of polymerization. The same applies for choosing molecular weight as a definition on the PVOH used. The important feature is the viscosity that may be obtained when mixing the PVOH in an aqueous solution.

[0062] Besides the content of PVOH, additional resins and release agents could also modifiers be added, said modifiers preventing the adhesive film from hardening. Modifiers include quaternary ammonium complexes, polyethylene glycols, phosphate salts, ethylene glycol propylene glycol, polyethylene glycol, oligosaccharides etc.

[0063] In FIG. 1 is shown schematically the final part of a tissue machine, where a tissue web W is transferred in a transfer position TP to a Yankee Cylinder CR, often referred to as creping roll. The tissue web W is conveyed to the transfer position on any appropriate felt F and the web is transferred to the surface of the Yankee CR in a transfer nip between a roll 1 and the Yankee Cylinder CR.

[0064] As indicated here is the web more or less flat, see encircled figure C1, but may have obtained some structured surface from the felt F before the transfer position. A first order of crepe may or may not be induced on the web during the transfer, see encircled figure C2, by a decrease of speed in the Yankee VS the preceding felt F.

[0065] The Yankee is a cylinder heated internally by steam at high pressure, resulting in a drastic reduction of water in the web. The web is exposed for drying during the passage over the angle α. The web is thereafter removed from the Yankee cylinder in a take-off position TO using a doctor blade 10. The doctor blade may induce a final order of crepe in the web, see encircled figure C3.

[0066] After takeoff the web is led to a conventional reeling drum 11b forming a paper reel 11c. The reeling drum 11b is driven by a supporting cylinder 11a.

[0067] As shown in FIG. 1 is a Yankee adhesive YA applied on the surface of the Yankee ahead of the transfer position TP. The amount of Yankee adhesive applied may be controlled by a valve V, which may be a manually controlled valve set at any appropriate feed rate or be controlled in a close loop by a control Unit CPU depending upon the measured thickness of Yankee adhesives after application.

[0068] The thickness of the Yankee adhesive may be measured by any state-of-the-art non-contact measuring means 15.

[0069] In FIGS. 2a-2d are shown 4 different principal layouts of the Yankee adhesive application system.

[0070] In FIG. 2a is a first basic system layout disclosed wherein only PVOH is added as an aqueous solution into the Yankee adhesive YA. The Yankee adhesive application system comprises a first supply boom 14 with several nozzles 14n arranged over the entire width of the Yankee cylinder, or minimum over a part width W.sub.W that carries the web. Preferably may each nozzle 14n be controlled individually by a unique driver signal 14c, which in response to a single measuring head in the measuring means 15 may adjust application rate of the Yankee adhesive in the narrow strip of the web width. The supply boom 14 is pressurized with a pump P1 feeding Yankee adhesives from a storage container 20 as well as from a return flow from the supply boom 14. As indicated here may the supply boom be subject to a continuous flow of Yankee adhesive, such that a part of the Yankee adhesives fed to the supply boom is returned to the pump P1. The circulation rate back to the pump P1 may be 20-80% of the volume of Yankee adhesive feed to the supply boom. In the first basic system layout is new Yankee adhesives added in a PVOH preparation system Prep in a separate feed flow replacing the volumes fed out via the nozzles 14n. As it is an aqueous solution is clean water Aq added, possibly via a heater that heats the water to about 80-100° C. at the most during initial mixing with fresh PVOH. But in this first embodiment is the heater located after a mixer. Somewhat higher temperature may be established after initial mixing with colder water, to about 130° C. at the most, but then the storage container needs to be designed as a pressure vessel which add cost. Heating during initial mixing with fresh PVOH to 80-130° C. improve further mixing of very high molecular weight polyvinyl alcohol and allowing the molecular chains to untangle from each other, as well as causing a swelling of the PVOH. Depending on type of PVOH may a maximum temperature be at hand where the excessive heating may cut the length of the molecular chains (which must be prevented).

[0071] Thereafter is the aqueous solution with very high molecular weight polyvinyl alcohol PVOH.sub.UHMW fed to a storage container 20. As the molecular chains of the very high molecular weight polyvinyl alcohol are very long, and it takes time to untangle the chains from each other it is important that the heated aqueous solution with PVOH is stored for a longer time in order to obtain best effect. The storage container may thus be divided in several compartments establishing a longer storage time for the entire volume of the PVOH solution. In FIG. 2a is the fresh mixture of the aqueous PVOH solution, having had no storage time, fed into the bottom of a first compartment. Addition into the bottom suppress formation of PVOH as a layer in the bottom. First after having had the retention time in all compartments may the Yankee coating YA be fed out from the bottom of a final compartment. The temperature of the aqueous PVOH solution fed out from the storage container 20 is here about 80-130° C. and needs to be reduced before being fed to the boom 14, and hence is a cooler Co used to lower the temperature down to about 40-65° C. This kind of preparation system Prep is preferably used in tissue machines with high production rate, where consumption of PVOH become high, allowing use of fresh PVOH to be mixed on site instead of buying already mixed aqueous solution, which latter option is more expensive. However, the Prep system may alternatively be replaced by a pump P2 sucking already mixed aqueous solution of PVOH from barrels or tanks.

[0072] In FIG. 2b is a second basic system layout disclosed. The difference here is that a number of additives are mixed into the recirculation loop of the boom 14. Each additive may be added in a dedicated mixer as shown here, preferably using a static mixer. The additives may include at least an additional creping adhesive agent such as PAE/ADH, and a release agent RA, and a plasticizer. The order of mixing these additional additives into the recirculation is preferably done in view of how easy each additive is to be evenly mixed into the recirculation. As to the very high molecular weight PVOH mixed into water in the preparation system, this additive will be subjected to the mixer in the preparation system, and then also be subjected to additional remixing in each following mixers for additional additives. Gentle repeat mixing in static mixers will improve a thorough mixing of the very high molecular weight PVOH.

[0073] In FIG. 2c is a third basic system layout disclosed. The difference here is that all additives are mixed in the preparation system Prep before entering the recirculation flow. In this embodiment is the most difficult additive to be mixed, the very high 10 molecular weight PVOH, added first in a dedicated mixer, thereafter heated, and subsequently follows mixing of complementary additives in a sequence of dedicated mixers before being fed to a storage container 20. Before being pumped into the recirculation is the new Yankee adhesive cooled in a cooler Co.

[0074] In FIG. 2d is a fourth basic system layout disclosed, but here without a recirculation flow from the boom back to the feed flow to the boom. The very high molecular weight PVOH is first mixed into a feed flow of water Aq and passed on to a container 20 with integrated heating. After sufficient storage time is the aqueous solution of PVOH fed via a cooler Co to a first mixing station for an additional additive, in this case additional creping adhesive agent such as PAE/ADH. Thereafter may a release agent RA, phosphate and a plasticizer be added in a sequence of dedicated mixers. The final Yankee additive mixed in this way and fed to the boom may also pass a filtering system with at least 2 filters F in parallel, that may prevent larger particles to pass to the boom where the nozzles may become blocked. Using parallel filters enables back flushing and cleaning of one filter at the time while still being able to feed Yankee additive trough the filter that still is in a filtering mode.

[0075] The basic systems layouts of FIGS. 2a-2c all include a return line YARET from the boom 14 back to the storage container or the pump P1, but this return line may be omitted in systems with large consumption of the Yankee adhesive (i.e. for larger tissue machines), like the system shown in FIG. 2d. But the return line adds several advantages as it adds a stirring effect in the storage container 20 at re-introduction and increases the total averaged residence time of the Yankee adhesives as well as subject the aqueous solution for repeated mixing.

[0076] In FIG. 3 is an alternative storage container 20 shown. This is a design with four chambers in series, needing only 3 partition walls. The fresh aqueous solution with water and PVOH is fed to the bottom of a first right hand side chamber in the storage container 20. This inflow in the bottom suppress sedimentation of PVOH in this chamber. From the first chamber the aqueous solution overflows to a second and third chamber having an inlet in the bottom of the return flow YA.sub.RET. And first when the aqueous solution has passed the first three chambers it overflows to a final fourth chamber on the left-hand side. As shown here may also a number of motor driven agitators be arranged, having stirring members that breaks up any flocs formed on the upper liquid surface.

Tests

[0077] The Yankee Adhesive that was ran had a total add-on of: 15-35 mg/m2, and contained [0078] Crepetrol 9750: 20-65% [0079] Crepetrol 874 and Rezosol CS-3290: 10-40% [0080] Kuraray KP200-88 KX: 25-65%

[0081] The findings from the tests shows that Yankee coating will work with PAE, non-PAE resins, thermosetting (crosslinking) and non-thermosetting resins (fully-crosslinked) as Yankee adhesive are mainly becoming active and providing adhesion at crepe blade and less at the Yankee transfer nip unlike PVOH. Non-PAE resin includes GPAM resins, PVAM and derivatives from these, CPAM, APAM, interpenetrating networks (IPNs) used directly into coating system or into the wet-end of the paper machine. The Yankee coating package will work whether a phosphate additive is used or not in the Yankee coating (MAP, DAP, TKPP and other kind of polyphosphate).

[0082] Effect of Kuraray KP200-88 KX (very high MW PVOH) was enhanced when used in combination with

[0083] CS-3290 Yankee modifier. The viscosity of Kuraray KP200-88 KX obtained in a 4% aqueous solution at ° C. would lie in the range 175.0-225.0 cP.

[0084] Kuraray KP200-88 KX was compared with Selvol 523 and Selvol 540.

[0085] Selvol 523, classified as medium MW PVOH by Sekisui, obtained a viscosity in a 4% aqueous solution

[0086] at 20° C. that lies in the range 23.0-23.7 cP and this at a hydrolysis level of 87.0-89.0%.

[0087] Selvol 540, classified as high MW PVOH by Sekisui, obtained a viscosity in a 4% aqueous solution at

[0088] 20° C. that lies in the range 45-55 cP. and this at a hydrolysis level of 87.0-89.0%. Selvol 350 is also an alternative but could obtain a viscosity in the range 60-72 cP.

[0089] Viscosity range for Kuraray product KP200-88 KX tested is close to 4 times higher than standard

[0090] Selvol 540. Kuraray refers KP200-88 KX as premium PVOH grade/product. The hydrolysis level of

[0091] KP200-88 KX lies in the range 87.0-89.0%, i.e. the same as for Selvol 523/540, and this shows that

[0092] the hydrolysis level per se do not clearly indicate what kind of viscosity may be obtained.

[0093] The Rezosol CS-3290 is modifier chemistry supplied by Solenis LLC. It also worked with Crepetrol 874 (surfactant based modifier). It can work with other modifiers such imidazoline quaternary amine based Yankee modifiers and suit applications using oil based release (mineral or vegetal oil release).

[0094] This can be implemented in a wide range of total add-on, i.e. in the range: 1-150 mg/m.sup.2 and over a wide range of ratios for each of the component as conditions may vary quite a lot from one machine to another machine depending on, furnish, moisture conditions, etc.

[0095] This should be wide enough to cover tissue manufacturing processes such as Through air-drying (TAD), NTT, QRT, Single or double recrepe (SRC or DRC), Advanced Molding Tissue System (ATMOS) as well as conventional light dry-crepe assets (LDC)