Fitout articles and articles of equipment for kitchens or laboratories with a display device

11136262 · 2021-10-05

Assignee

Inventors

Cpc classification

International classification

Abstract

A fitout article or article of equipment for a kitchen or laboratory is provided. The article has a display device, a separating element, and a covering. The covering is on an interior side of the separating element and has a cutout at the separating element. The separating element has a light transmittance of at least 5% and at most 70%. The covering has light transmittance of at most 7% and a colour locus in the CIELAB colour space with coordinates L* of 20 to 40, a* of −6 to 6 and b* of −6 to 6, and the colour locus of D65 standard illuminant light, after passing through the substrate, is within a white region W1 determined in the chromaticity diagram CIExyY-2° by the coordinates: TABLE-US-00001 White region W1 x Y 0.27 0.21 0.22 0.25 0.32 0.37 0.45 0.45 0.47 0.34 0.36 0.29.

Claims

1. A fitout article or article of equipment for a kitchen or laboratory, comprising: an interior; a separating element dividing the interior from an exterior, the separating element having a light transmittance of at least 5% and of at most 70%; a display device in the interior such that light emitted by the display device passes through the separating element to the exterior; and a covering on a side of the separating element facing the interior, the covering has a cutout that overlaps with the separating element, the covering has a light transmittance of at most 7%, wherein the separating element comprises a glass or glass ceramic substrate having a coefficient of thermal expansion of −6×10−6/K to 6×10−6/K in a temperature range between 20° C. and 300° C., wherein the covering has a colour locus in the CIELAB colour space with coordinates L* of 20 to 40, a* of −6 to 6 and b* of −6 to 6, measured in reflectance with D65 standard illuminant light against a black trap in transmission through the glass or glass ceramic substrate, wherein the fitout article or article of equipment has a colour locus of D65 standard illuminant light, after passing through the glass or glass ceramic substrate in a region of the cutout, is within a white region W1 determined in a chromaticity diagram CIExyY-2° by coordinates: TABLE-US-00017 White region W1 x y 0.27 0.21 0.22 0.25 0.32 0.37 0.45 0.45 0.47 0.34 0.36 0.29.

2. The fitout article or article of equipment of claim 1, wherein the fitout article or article of equipment does not include a black-body compensation filter.

3. The fitout article or article of equipment of claim 1, wherein the light transmittance of the covering is at most 1%.

4. The fitout article or article of equipment of claim 1, wherein the separating element in the region of the cutout has a transmission at a wavelength of 1600 nm of at least 30%.

5. The fitout article or article of equipment of claim 1, wherein the separating element in the region of the cutout has a transmission at at least a wavelength in the range between 850 nm and 1000 nm of at least 3%.

6. The fitout article or article of equipment of claim 1, wherein the separating element in the region of the cutout has a transmission at at least a wavelength in the range between 3.25 μm and 4.25 μm of at least 10%.

7. The fitout article or article of equipment of claim 1, wherein the glass or glass ceramic substrate is a glass ceramic substrate, the coefficient of thermal expansion of the glass ceramic substrate is between 20 and 300° C. of −2.5 to 2.5×10−6/K.

8. The fitout article or article of equipment of claim 1, wherein the glass or glass ceramic substrate is a glass substrate, the coefficient of thermal expansion of the glass substrate between 20 and 300° C. is 3.5 to 6×10−6/K, the glass substrate having a glass transition temperature of 500 to 650° C.

9. The fitout article or article of equipment of claim 1, wherein the light transmittance of the separating element is at least 9% and of at most 55%.

10. The fitout article or article of equipment of claim 1, wherein the colour locus in the CIELAB colour space of the covering has the coordinates of 22≤L*≤35, with −4≤a*≤4, and with −4≤b*≤4.

11. The fitout article or article of equipment of claim 1, further comprising a coating on the separating element, wherein the coating comprises a material system selected from a group consisting of: spinels, cermets, carbides, and carbonitrides.

12. The fitout article or article of equipment of claim 1, wherein the glass or glass ceramic substrate comprises a material selected from a group consisting of: 0.003-0.5% by weight of MoO3, less than 0.2% by weight of Nd2O3, less than 0.015% by weight of V2O5, and any combinations thereof.

13. The fitout article or article of equipment of claim 1, further comprising a difference between a percentage grey value in the region of the cutout when the display device is off and a percentage grey value in the region without the cutout, wherein the difference is less than 5.0%.

14. The fitout article or article of equipment of claim 1, wherein the separating element in the region of the cutout has a haze of at most 5%.

15. The fitout article or article of equipment of claim 1, wherein the separating element in the region of the cutout has a clarity of at least 90%.

16. The fitout article or article of equipment of claim 1, wherein the display device is a display selected from a group consisting of: an LCD display, an OLED display, and a video projector.

17. The fitout article or article of equipment of claim 1, wherein the fitout article or article of equipment is configured for a use selected from a group consisting of: a cooking table, a laboratory table, a kitchen cabinet, a kitchen appliance, a cooking appliance, a baking oven, a microwave device, a refrigerator, a grill, a steam cooker, a toaster, and an extractor hood.

18. The fitout article or article of equipment of claim 1, wherein the separating element is configured for a use selected from a group consisting of: a table surface, a cooking table surface, a laboratory table surface, a kitchen working surface, a cooktop, a baking oven door, a microwave oven door, an item of furniture, a part of a front of a door, and a part of a drawer.

19. The fitout article or article of equipment of claim 1, wherein the covering is selected from a group consisting of: a coating, a self-supporting carrier material, a sheet, a film of glass, a glass ceramic, a plastic material, an insulation material, and any combination thereof.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1a shows a chromaticity diagram of the CIExyY colour space.

(2) FIG. 1b shows an enlarged detail from FIG. 1a.

(3) FIG. 2 is a schematic diagram of an embodiment of a fitout article or article of equipment of the disclosure in cross section.

DETAILED DESCRIPTION

(4) FIG. 1a and FIG. 1b show chromaticity diagrams of the CIExyY colour space with 2° standard observer (CIExyY-2°). FIG. 1b shows an enlarged detail of the overall region of the chromaticity diagram shown in FIG. 1a.

(5) The figures depict the black-body curve as a dotted line, the two white regions W1 and W2 as dashed lines, the colour coordinates of the examples that are listed in the tables and are suitable for use in an article of the invention as black squares, and examples from the prior art as black crosses.

(6) Every point on the black-body curve corresponds to the colour locus of the light emitted by a black-body radiator at a defined temperature, called the colour temperature. This curve is of particular relevance to human perception since the sun likewise corresponds to a black-body radiator and hence the colour of sunlight is on the black-body curve. According to the position of the sun, the colour locus moves between cooler and warmer colour loci; a colour temperature of 20 000 K corresponds to a clear sky and a temperature of 3500 K to evening sunlight shortly before the commencement of dusk. Colour loci at or close to the black-body curve are therefore perceived as white and particularly natural.

(7) The prior art described consists partly of the glass ceramic types specified in WO 2012076414 A1 and partly of commercially available glass ceramics from SCHOTT AG and Eurokera. These examples from the prior art are all outside the white region W1. As known from WO 2012076414 A1, the white region W1 can be covered by these glass ceramics only through the use of additional, complex compensation filters. However, the inventive examples cover this region even without such a filter. All the colour loci shown relate to a material thickness of 4 mm.

(8) The examples adopted from Tables 2, 4, 5, 6 and 7 are all within the white region W1. Among these, all examples that contain less than 0.01% by weight of V2O5 in the glass ceramic, i.e. including the coating examples from Table 5 that have been applied to V2O5-free glass ceramics, are also within the white region W2. In addition, the V2O5-free glass ceramics from Tables 2 and 4 are also within the white region W3 (not shown).

(9) FIG. 2 contains a schematic illustration of an article of the invention in cross section. The fitout article or article of equipment (1) shown for a kitchen or laboratory comprises a display device (2) and a separating element (3) that divides sections of an interior (4) of the article (1) from an exterior (5). The display device (2) is disposed in the interior (4) of the article (1) such that the light emitted by the display device (2) passes through a section of the separating element (3) and is perceptible by a user in the exterior (5) of the article (1). In the embodiment shown, the separating element (3) consists of a glass or glass ceramic substrate having a coefficient of thermal expansion CTE of −6×10−6/K to 6×10−6/K in the temperature range between 20° C. and 300° C. A covering means (6) disposed on the side of the separating element (3) facing the interior (4) of the article (1) has a light transmittance of at most 7% and has a cutout (8) in the region of the display device (2). The separating element (3) in the region of this cutout (8) has a light transmittance of at least 5% and of at most 70%. The covering means (6) has a colour locus in the CIELAB colour space having the coordinates L* of 20 to 40, a* of −6 to 6 and b* of −6 to 6. The colour locus of the D65 standard illuminant light after passing through the glass or glass ceramic substrate of the separating element (3) in the region of the cutout (8) of the covering means (6) is within the white region W1.

(10) Fitout articles or articles of equipment of the invention for kitchens or laboratories may also contain a multitude of further components in their interior in addition to the display device.

(11) The articles may, for example, have one or more heating elements for heating an article, for example a pan, in the exterior or even in the interior of the article. These may especially be radiative heating elements, induction heating elements, gas heating elements or microwave generators.

(12) The articles may have further display devices and other lighting elements such as point, linear or areal light sources. These include, for example, LEDs, optical fibres and OLEDs. These light sources can emit in a particular colour, especially white, red, green and/or blue, or else variable colours. Between these display devices or lighting elements and the separating element, it is also possible for additional colour filters to be provided, for example in order to be able to utilize a white LED for production of a coloured lighting effect with a defined colour locus and high colour saturation.

(13) Further display devices that may be provided may be either segment displays or graphic displays. The segment displays may especially be designed as coloured 7-segment displays. The graphic displays are preferably TFT displays, for example LCDs or OLED displays.

(14) Lighting elements may especially also be disposed in the hot region in the vicinity of heating elements. In this case, especially for the production of white lighting effects in the exterior of the article, it is advantageous that no temperature-sensitive black-body compensation filters are required.

(15) In a preferred embodiment, in addition to a lighting element, one or more scattering or diffuser layers may be provided. Preferably, such layers are used in combination with at least one covering layer between substrate and lighting element and with at least one cutout in the covering layer. Scattering and diffuser layers can especially be used to produce a homogeneous lighting effect of linear and areal lighting elements.

(16) Scattering and diffuser layers may optionally also be executed in coloured form. Coloured scattering and diffuser layers may simultaneously function as diffuser and as optical filter.

(17) Such scattering or diffuser layers may have a thickness of 1 to 15 μm, for example. They may contain non-coloured scattering particles, for example of TiO2, SiO2, Al2O3, ZrO2 or other metal oxides. The average size of such particles may be less than 1 μm. Preferably, the scattering or diffuser layers have high homogeneity of the luminance produced, low granularity and high brightness. This results in a perception of a very homogeneously lit area which is very pleasing to the user.

(18) The articles may have cooling aggregates, for example Peltier elements, in thermal contact with the separating element in order to produce a cooling surface, for example for cooling of foods or chemicals, on the exterior-facing side of the separating element.

(19) The article may have various sensors, for example capacitative touch sensors for control or infrared sensors for gesture control or for measurement of the temperature of hot articles in the exterior, for example hot pans. In addition, the article may have microphones and cameras, for example for voice control or user recognition and authentication. This may be particularly advantageous in laboratories, for example, if the article may be used only by correspondingly trained personnel. Such sensors may have been printed, pressed, bonded or adhesive-bonded, or arranged in some other way, on the inside of the separating element. This is particularly true of touch sensors.

(20) The article may have various interfaces for communication, for example WLAN, Bluetooth or NFC modules or infrared interfaces. By means of such interfaces, the article can be connected, for example, either to the Internet or to other articles in its vicinity, for example pans with a corresponding interface or other electronic devices. More particularly, for control and communication, it can be connected to a mobile electronic device, such as a mobile phone or a tablet.

(21) The article may contain a device for wireless energy transmission from articles in the exterior, especially by means of induction coils and in accordance with the Qi standard.

(22) The separating element may have coatings on the exterior-facing side, for example anti-scratch layers, anti-reflection layers, anti-glare layers, decorative layers, easily cleanable layers or infrared-reflecting layers, provided that these do not alter the essential optical properties of the separating element.

(23) The separating element may have cutouts, for example recesses for sinks or down-draft fume hoods or bushings for pipelines.

(24) Likewise optionally, the separating element may have edge elaboration, for example a facet or a pencil finish.

(25) All these constituents may be present individually or in combination.

(26) TABLE-US-00010 TABLE 1 COMPOSITION AND PROPERTIES OF THE CRYSTALLIZABLE BASE GLASS 1 WITH BASE COMPOSITION. % by Glass No. wt. 1 Composition Li.sub.2O 3.80 Na.sub.2O 0.60 K.sub.2O 0.25 MgO 0.29 CaO 0.40 SrO 0.02 BaO 2.23 ZnO 1.53 Al.sub.2O.sub.3 20.9 SiO.sub.2 65.0 TiO.sub.2 3.10 ZrO.sub.2 1.38 P.sub.2O.sub.5 0.09 SnO.sub.2 0.25 As.sub.2O.sub.3 0 MnO.sub.2 0.025 H.sub.2O - content (β-OH) mm.sup.−1 0.39 Properties in glass form Transformation temperature ° C. 662 Tg 10.sup.2 temperature ° C. 1742 Working temperature V.sub.A ° C. 1306 UDL temperature ° C. 1260

(27) TABLE-US-00011 TABLE 2 DOPANTS AND PROPERTIES OF THE INVENTIVE GLASS CERAMICS AND COMPARATIVE EXAMPLES 1 AND 2 Example No. 1 2 3 4 5 6 7 Glass No. 1 1 2 3 4 4 5 Base glass 1 1 1 1 1 1 1 Dopants (% by wt.) Fe.sub.2O.sub.3 0.090 0.090 0.120 0.088 0.086 0.086 0.090 V.sub.2O.sub.5 0.023 0.023 0.010 MoO.sub.3 0.057 0.078 0.013 0.013 0.057 Cr.sub.2O.sub.3 CeO.sub.2 WO.sub.3 Addition to batch Ceramization # 1 2 1 1 1 3 1 Properties in ceramized form Transmission, thickness 4 mm, D65 standard light, 2°  470 nm % 1.2 0.7 2.9 13.3 41.6 33.5 16.7  630 nm % 9.9 6.6 12.6 17.2 58.1 43.7 21.7  950 nm % 73.0 71.9 66.5 60.8 75.5 73.0 62.1 1600 nm % 76.4 76.3 70.9 74.8 77.1 76.3 75.1 3700 nm % 52.0 51.1 50.0 52.2 52.4 56.1 51.0 Colour coordinates (CIE) in transmission x 0.502 0.517 0.447 0.337 0.344 0.340 0.337 y 0.367 0.358 0.365 0.334 0.357 0.355 0.339 Brightness Y % 3.6 2.2 5.8 13.6 50.1 38.2 17.6 Colour 0.193 0.207 0.139 0.025 0.042 0.038 0.026 distance d Colour coordinates (CIELAB) in reflectance L* 25.19 24.99 25.74 26.52 29.79 25.66 a* 0.28 0.04 0.39 0.16 0.16 0.15 b* −0.66 −0.78 0.80 −0.80 −2.12 -0.9 c* 0.72 0.78 0.89 0.82 2.13 0.91 ΔE 4.26 0.68 5.58 19.55 |G.sub.1-G.sub.2| % 0.2 1.6 0.1 Flatness nm 8.4 10.0 4.4 1.4 1.4 1.3 1.3 transmission 630/ 630/ 630/ 630/ 630/ 630/ 630/ (wavelength 470 470 470 529 470 470 524 max./min.) Scatter, thickness 4 mm, D65 standard light, 2° Visual 1 1 1 1 1 3 1 assessment Haze % 0.8 0.5 1.5 1.5 1.7 10.7 1.3 Thermal expansion CTE α.sub.20/300 10.sup.−6/ −0.26 −0.29 −0.24 K CTE α.sub.20/700 10.sup.−6/ 0.13 0.17 0.70 0.16 K X-ray diffraction Main crystal HQMC HQMC HQMC HQMC HQMC KMC HQMC phase DOPANTS AND PROPERTIES OF INVENTIVE GLASS CERAMICS. Example No. 8 9 10 11 Glass No. 6 6 7 8 Base glass 1 1 1 1 Dopants (% by wt.) Fe.sub.2O.sub.3 0.062 0.062 0.061 0.062 V.sub.2O.sub.5 MoO.sub.3 0.015 0.015 0.019 0.014 CoO Cr.sub.2O.sub.3 Nd.sub.2O.sub.3 0.042 NiO Addition to batch 0.1% sugar without nitrate Ceramization # 1 2 1 1 Properties in ceramized form Transmission, thickness 4 mm, D65 standard light, 2°  470 nm % 42.6 43.4 22.2 42.8  630 nm % 53.4 52.7 21.2 54.2  950 nm % 76.4 75.9 57.4 76.5 1600 nm % 80.8 80.4 78.1 80.8 3700 nm % 53.6 53.4 50.5 53.2 Colour coordinates (CIE) in transmission x 0.335 0.332 0.311 0.334 y 0.348 0.345 0.326 0.348 Brightness Y % 47.6 47.4 20.4 47.8 Colour distance d 0.029 0.025 0.003 0.029 Colour coordinates (CIELAB) in reflectance L* 28.13 28.42 25.84 a* 0.32 0.30 −0.05 b* 0.15 0.31 −1.27 c* 0.35 0.43 1.27 ΔE 22.43 23.22 5.33 |G.sub.1-G.sub.2| 3.0 0.3 Flatness nm 1.3 1.2 1.1 1.3 transmission 630/470 630/470 470/572 630/470 (wavelength at max./min.) Scatter, thickness 4 mm, D65 standard light, 2° Visual assessment 1 1 1 1 Haze % 1.9 1.6 2.7 Thermal expansion CTE α.sub.20/300 10.sup.−6/ −0.24 −0.28 −0.24 −0.21 K CTE α.sub.20/700 10.sup.−6/ 0.16 0.09 0.14 0.16 K X-ray diffraction Main crystal HQMC HQMC HQMC HQMC phase

(28) TABLE-US-00012 TABLE 3 COMPOSITIONS AND PROPERTIES OF CRYSTALLIZABLE GLASSES AND COMPARATIVE GLASS NO. 9 % by Glass No. wt. 9 10 11 12 Composition Li.sub.2O 3.83 3.83 3.79 3.31 Na.sub.2O 0.57 0.61 0.60 0.37 K.sub.2O 0.21 0.27 0.26 0.36 MgO 0.19 0.30 0.29 0.56 CaO 0.36 0.43 0.43 0.58 SrO 0.02 0.02 BaO 2.41 2.21 2.23 1.62 ZnO 1.41 1.49 1.47 1.92 Al.sub.2O.sub.3 20.2 20.9 21.0 21.4 SiO.sub.2 65.8 64.8 65.0 64.8 TiO.sub.2 3.02 3.14 3.05 3.20 ZrO.sub.2 1.39 1.40 1.40 1.35 P.sub.2O.sub.5 0.11 0.10 0.10 0.04 SnO.sub.2 0.30 0.24 As.sub.2O.sub.3 0.28 0.15 Fe.sub.2O.sub.3 0.090 0.062 0.061 0.0990 V.sub.2O.sub.5 0.016 MoO.sub.3 0.150 0.150 0.1600 MnO.sub.2 0.021 0.025 0.025 CoO 0.027 Addition to batch % by 0.2% wt. sugar without nitrate Properties in glass form Transformation ° C. 675 temperature Tg 10.sup.2 temperature ° C. 1733 Working temperature V.sub.A ° C. 1300 UDL temperature ° C. 1275 COMPOSITIONS AND PROPERTIES OF CRYSTALLIZABLE GLASSES % by Glass No. wt. 13 14 15 Composition Li.sub.2O 4.13 3.22 3.73 Na.sub.2O 0.64 0.78 0.78 K.sub.2O 0.29 0.20 0.58 MgO 0.24 0.81 0.20 CaO 0.52 0.21 0.21 SrO 0.02 BaO 2.05 2.42 2.41 ZnO 1.16 0.93 Al.sub.2O.sub.3 21.7 19.8 20.0 SiO.sub.2 65.8 66.9 66.4 TiO.sub.2 3.58 2.68 2.83 ZrO.sub.2 0.64 1.44 1.40 P.sub.2O.sub.5 0.03 SnO.sub.2 0.25 0.20 0.39 As.sub.2O.sub.3 Fe.sub.2O.sub.3 0.065 0.110 0.033 V.sub.2O.sub.5 MoO.sub.3 0.026 0.043 0.045 MnO.sub.2 CoO Addition to batch Sugar 0.2% without nitrate Properties in glass form Transformation ° C. 685 680 674 temperature Tg 10.sup.2 temperature ° C. 1774 1770 1770 Working temperature V.sub.A ° C. 1327 1331 1331 UDL temperature ° C. 1255 1260

(29) TABLE-US-00013 TABLE 4 PROPERTIES OF INVENTIVE GLASS CERAMICS AND COMPARATIVE GLASS CERAMIC OF EXAMPLE 12 Example No. 12 13 14 15 16 Glass No. 9 10 11 12 12 Ceramization # 2 1 1 1 2 Properties in ceramized form Transmission, thickness 4 mm  470 nm % 1.9 43.4 39.4 5.8 5.2  630 nm % 10.8 57.1 52.3 8.3 7.0  950 nm % 72.0 82.2 83.1 53.4 50.9 1600 nm % 67.5 82.9 82.8 69.1 68.1 3700 nm % 49.4 53.6 52.0 46.3 46.4 Colour coordinates (CIE) in transmission x 0.476 0.342 0.342 0.344 0.338 y 0.322 0.355 0.351 0.325 0.320 Y % 3.5 48.7 43.7 5.9 5.0 Colour distance d 0.163 0.024 0.037 0.032 0.027 Colour coordinates (CIELAB) in reflectance L* 29.38 a* 0.46 b* 0.78 c* 0.91 ΔE 31.01 Flatness nm 8.0 1.3 1.3 1.6 1.6 transmission 630/504 630/470 630/470 630/527 630/536 (wavelength at max./min.) Scatter, thickness 4 mm, D65 standard light, 2° Visual assessment 1 1 1 1 1 Haze % 2.0 1.4 0.6 3.4 Thermal expansion [10.sup.−6/K] CTE α.sub.20/300 −0.40 −0.24 −0.27 0.05 0.00 CTE α.sub.20/700 −0.03 0.16 0.12 0.34 0.27 X-ray diffraction Main crystal phase HQMC HQMC HQMC HQMC HQMC PROPERTIES OF INVENTIVE GLASS CERAMICS Example No. 17 18 19 Glass No. 13 14 15 Ceramization # 1 2 2 Properties in ceramized form Transmission, thickness 4 mm, D65 standard light, 2°  470 nm % 12.1 33.2 12.5  630 nm % 27.4 46.1 10.8  950 nm % 54.0 71.6 51.8 1600 nm % 72.1 72.3 82.7 3700 nm % 49.9 46.1 47.0 Colour coordinates (CIE) in transmission x 0.389 0.342 0.302 y 0.385 0.348 0.313 Y % 19.6 38.5 10.3 Colour distance d 0.095 0.035 0.019 Flatness nm 2.3 1.4 1.3 transmission 630/470 630/470 470/575 (wavelength at max./min.) Scatter, thickness 4 mm, D65 standard light, 2° Visual assessment 2 1 1 Haze % 1.1 1.1 Thermal expansion CTE α.sub.20/300 10.sup.−6/ −0.37 0.32 −0.14 K CTE α.sub.20/700 10.sup.−6/ 0.01 0.59 0.26 K X-ray diffraction Main crystal HQMC HQMC HQMC phase

(30) TABLE-US-00014 TABLE 5 EXAMPLES OF SUITABLE COATINGS AND COMPARATIVE EXAMPLE ON TRANSPARENT NON-COLOURED GLASS CERAMICS OF THE CERAN ® CLEARTRANS TYPE. No. B1 B2 B3 Type Spinel Spinel + compensation Cermet layer Material CoFeMnCr CoFeMnCr + SiOxNy MoSiOx Mo — — 32 Si — — 68 Colour blue black black Colour coordinates (CIExyY) in transmission x 0.39 0.387 0.368 y 0.39 0.378 0.374 Y % 37.6 33.2 32.8 Colour coordinates (CIELAB) in reflectance L* 29.79 30.48 27.1 a* 1.86 −0.75 0.4 b* −17.95 0.57 1.2 c 18.05 0.94 1.26 Spectral transmittance  950 nm % 59.4 67.1 65.3 1600 nm % 63.3 63.2 83.4 3750 nm % 43.6 43.5 47.3 Haze % 0.11 0.28 0.22 Other properties R MΩ/□ >20 >20 >20 Thickness nm 200 + 45

(31) TABLE-US-00015 TABLE 6 FURTHER EXAMPLES OF SUITABLE COATINGS ON TRANSPARENT NON-COLOURED GLASS CERAMICS. No. B4 B5 B6 Type Cermet Cermet Cermet Material MoSiOx MoSiOx MoSiOx Mo 32 22 32 Si 68 78 68 Colour black black black Colour coordinates (CIELAB) in reflectance L* 27.1 27.2 26.9 a* 0.4 −0.8 0.6 b* 1.2 1.4 1 Colour coordinates (CIExyY) in transmission x 0.368 0.37 0.37 y 0.374 0.37 0.37 Y % 32.8 29.5 32.0 Transmission  470 nm % 20.2 21.8  630 nm % 38.4 41.3  950 nm % 65.3 59.8 65.1 1600 nm % 83.4 80.2 82.2 3750 nm % 47.3 47 46.9 Haze % 0.22 0.2 0.2 Other properties R MΩ/□ >20 >20 >20

(32) TABLE-US-00016 TABLE 7 FURTHER EXAMPLES OF SUITABLE COATINGS ON TRANSPARENT NON-COLOURED GLASS CERAMICS No. B7 B8 B9 Type Cermet Cermet Cermet Material MoSiOx MoSiOx MoSiOx Mo 32 32 32 Si 68 68 68 Colour black black black Colour coordinates (CIELAB) in reflectance L* 26.4 27.1 27.8 a* 2.0 1.0 −2.8 b* −1.8 −2.4 1.2 Colour coordinates (CIExyY) in transmission x 0.38 0.37 0.37 y 0.39 0.38 0.38 Y % 35.5 36.7 34.4 Transmission  470 nm % 22.7 23.7 24.1  630 nm % 45.8 45.8 44.2  950 nm % 54.9 65.1 66.1 1600 nm % 79.9 81.3 80.4 3750 nm % 47.8 47.8 47.5 Haze % 0.3 0.3 0.3 Other properties R MΩ/□ >20 >20 >20