METHOD OF FABRICATING A FIBRE-OPTIC PRESSURE AND TEMPERATURE SENSOR
20210299782 · 2021-09-30
Assignee
Inventors
- Adrien DESJARDINS (London, GB)
- Malcolm Finlay (London, GB)
- Charles Alexander MOSSE (London, GB)
- Ioannis Papakonstantinou (London, GB)
- Radhika PODUVAL (London, GB)
Cpc classification
B23K9/0026
PERFORMING OPERATIONS; TRANSPORTING
G01K11/3206
PHYSICS
B29D11/00769
PERFORMING OPERATIONS; TRANSPORTING
B23K26/0006
PERFORMING OPERATIONS; TRANSPORTING
G02B5/284
PHYSICS
International classification
B23K26/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method for making a housing that defines a cavity for a pressure sensor, the method comprising: providing a bulk of material that will form the housing; focusing a radiation beam on internal portions of the bulk of material so as to modify the internal portions, thereby defining the housing's shape, wherein upstream of the focus of the radiation beam other portions of the bulk material remain unmodified; and discarding either the modified portions or the unmodified portions of the bulk material so as to form the cavity.
Claims
1. A method for making a housing that defines a cavity for a fibre optic pressure sensor, the method comprising: providing a bulk of material that will form the housing; focusing a radiation beam on internal portions of the bulk of material so as to modify the internal portions, thereby defining the housing's shape, wherein upstream of the focus of the radiation beam other portions of the bulk material remain unmodified; and discarding either the modified portions or the unmodified portions of the bulk material so as to form the cavity.
2. The method of claim 1, wherein the focusing step comprises modifying the etching rate of the material where the radiation is focused, and the discarding comprises etching or developing away the modified or unmodified material.
3-8. (canceled)
9. The method of claim 1, comprising sealing the cavity after the discarding step.
10. The method of claim 1, wherein the housing supports a diaphragm adjacent to the cavity that deflects with changes in pressure external to the sensor, wherein after the focusing step and before the discarding step, a portion of the diaphragm is deposited onto a region of the bulk of material that will be discarded to form the cavity, such that said portion of the diaphragm remains adjacent to the cavity after the discarding step.
11. (canceled)
12. The method of claim 10, in which the diaphragm comprises a reflective surface.
13-18. (canceled)
19. The method of claim 1, wherein the housing's shape is defined such that it comprises an integrally formed optical element that extends across a cross-section of the cavity.
20. The method of claim 19, wherein the optical element is one of a spacer, a lens, a diffraction grating and a beam splitter.
21. The method of claim 20, wherein the optical element is a beam splitter and there are two diaphragm surfaces for receiving radiation respectively along two paths downstream of the beam splitter.
22. The method of claim 1, wherein the housing's shape is defined to comprise an optical fibre-receiving hole adjacent one end of the cavity.
23. The method of claim 1, wherein the housing comprises a ridge separating the cavity and an optical fibre-receiving hole.
24. (canceled)
25. The method of claim 1, wherein the housing's shape is defines a plurality of cavities arranged for receiving radiation from a corresponding plurality of cores of a multi-core optical fibre.
26. (canceled)
27. The method of claim 1, wherein the material is a glass material.
28. The method of claim 1, wherein the material is a light-sensitive polymeric material.
29.-30. (canceled)
31. A method for making a pressure sensor, the method comprising: making a housing that defines a cavity for the pressure sensor by the method of claim 1 and applying a barrier layer surrounding the housing after attachment to the optical fibre.
32. The method of claim 31, comprising attaching the housing to one end of an optical fibre such that the cavity is adjacent to the end of the optical fibre.
33. (canceled)
34. A housing that defines a cavity for a pressure sensor, the housing comprising: a fibre-receiving hole adjacent one end of the cavity; and a diaphragm surface at the opposite end of the cavity, wherein the cross-sectional area of the cavity increases from the end adjacent to the fibre-receiving hole towards the diaphragm surface.
35. (canceled)
36. The housing of claim 34, wherein the housing comprises a beam splitter extending across the cavity and there are two diaphragm surfaces for receiving radiation respectively along two paths downstream of the beam splitter.
37. The housing of claim 34, wherein the housing comprises a plurality of cavities arranged for receiving radiation from a corresponding plurality of cores of a multi-core optical fibre.
38. A pressure sensor comprising the housing of claim 34.
39. (canceled)
40. Use of the pressure sensor of claim 38 for at least one of: obtaining a pressure measurement inside a blood vessel; obtaining an intracranial pressure; and monitoring pressure in an oil well.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0013] Various implementations of the invention will now be described in detail by way of example only with reference to the following drawings:
[0014]
[0015]
DETAILED DESCRIPTION
[0016] Described herein are methods for fabricating fibre-optic sensors to measure pressure and temperature. As an example of their usage, these sensors may be used to obtain pressure measurements inside a blood vessel to guide stent placement, or to measure intracranial pressure. In general, the described fabrication methods are particularly suited to applications where small sensor dimensions are of utmost importance, for instance in monitoring physiological parameters to facilitate clinical diagnosis and therapy, and to monitor pressure in oil and gas wells.
[0017] A sensor fabricated by the described methods typically has a diaphragm adjacent to a sealed gas cavity that deforms with changes in external pressure. The extent of the deformation depends on several factors such as the diaphragm thickness, the diaphragm geometry, and the mechanical properties of the diaphragm material. For instance, reducing the thickness and elastic modulus of the diaphragm tends to increase diaphragm deformation.
[0018] The sensor diaphragm is illuminated by interrogation light provided by the optical fibre; deformations result in changes to the reflection properties of interrogation light (for instance, its wavelength-dependent reflectivity), which are detected by an external console. The sensor typically comprises an optical cavity that brackets the sealed gas cavity. This optical cavity can include a high-finesse Fabry-Perot optical cavity, in which there are two mirrors with high optical reflectivity (typically greater than 70%), or a low-finesse cavity in which there are two or more reflective surfaces with low optical reflectivity (typically less than 10%), or a combination thereof. Methods for interrogating low- and high-finesse Fabry-Perot cavities, for instance with broadband or wavelength-swept interrogation light sources, and for processing detected changes to the reflectivity of interrogation light to measurements of external pressure, are known to the art.
[0019] A first class of the described fabrication methods involves creating a gas cavity with femtosecond laser-assisted etching of a transparent material. This transparent material may be a glass such as quartz silica glass or borosilicate glass, or it may be crystals such as sapphire and yttrium aluminium garnet (YAG). Pulsed laser light, with pulse durations typically less than 1000 fs and greater than 1 fs, is tightly focused to a transparent first material (typically with a microscope objective). At the focus, the high photon flux results in highly localised modifications to the first material and importantly, these modified regions can be etched away significantly more quickly than the regions that have not undergone modification. The etching process can result in a cavity that can subsequently be sealed to gas and fluids. With this method, a diaphragm can be created with un-modified regions of the first material. In a preferred embodiment, this first material is fused silica, which is not photosensitive. The glass may also be a photosensitive glass such as Foturan; in this case, etching can be followed by post-thermal treatment to increase surface smoothness.
[0020] A diaphragm can also be created with a second material that is deposited onto a modified region of the first material, prior to etching. This deposition process can be performed with methods known to the art including chemical vapour deposition (CVD), atomic layer deposition (ALD), and physical vapour deposition (PVD). The etching step removes the modified region of the first material, leaving behind the diaphragm. A key advantage of this class of fabrication methods is that glass and other transparent non-polymeric materials that have low water and gas permeation, high structural rigidity, and low thermal expansion coefficients (relative to some polymers) can be used for sensor construction.
[0021] Femtosecond laser modification allows for extrinsic structures to have a wide range of geometries and thereby to optimise the sensors for different applications. For instance, the extrinsic glass structures can have a narrow aperture to secure the fibre, and a widening of the cross-sectional diameter toward the distal end of the sensor, where the diaphragm is positioned. This arrangement could allow for the diaphragm to be significantly larger than the diameter of the optical fibre, for instance.
[0022] Femtosecond laser modification enables precise fabrication of optical elements to provide sensor functionality that extends beyond pressure sensing. For instance, it can be used to create lenses within or proximal to the optical cavity to focus interrogation light and thereby to increase the confinement of interrogation light. It can also be used to create structures such as optical windows that can be used to obtain temperature measurements, for instance with low-coherence interferometric phase resolved detection. It can be combined with femtosecond laser drilling.
[0023] Femtosecond laser modification may be performed more than once to fabricate the sensor. For instance, it may be formed once to define a first geometry for the extrinsic structure, which can include a region for a diaphragm that is recessed from the distal end, or which is curved; following etching, femtosecond laser modification may be performed again, which may be followed by deposition of the second material for diaphragm formation, and second etching step to remove modified material adjacent to the diaphragm.
[0024] The optical fibre may have microfabricated components connected to it before it is bonded to a microfabricated extrinsic structure. These components can include polymer domes and glass components microfabricated with femtosecond laser modification. The use of polymers with high linear expansion coefficients, such as polydimethylsiloxane, within the sensor can be useful to achieve measurements of temperature changes with high sensitivity.
[0025] A second class of the described sensor fabrication methods involves defining the geometry of an extrinsic structure with a sealed gas cavity using a positive or negative photoresist, in which a light-sensitive material is modified using non-linear optical absorption with a focused beam, wherein upstream of the focus of the radiation beam, other portions of this material remain unmodified. This includes mechanisms known to the art, such as multi-photon absorption, ultralow one photon absorption, stimulated emission depleted direct laser writing, saturable absorption, reverse saturable absorption, among others. Two-photon excitation, a sub-class of multi-photon absorption is prominent among these and typically involves a beam that is tightly focused and has a short pulse durations (typically femtosecond-scale), in which two incident photons (each typically in the infrared range) of comparably lower photon energy than needed for one photon absorption are absorbed in one quantum event. The material is substantially transparent at wavelengths of individual incident photons, and absorbing in the wavelength range corresponding to the total energy of two incident photons. Two-photon absorption is a non-linear process that scales with the square of the incident light intensity, thereby photoresist modification occurs only in a very tightly-confined region within the material around the focal point of the incident beam. Due to the requirement of high flux of incident photons, this two-photon absorption process occurs in very tightly-confined regions within the material (typically sub-micron in dimensions). This technique allows for printing at sub-micron resolution, which also makes it suitable to directly create textured diaphragm surfaces for further functionalisation to form plasmonic sensors for instance. Multi-photon, and one-photon based non-linear absorption processes are possible too and known to the art.
[0026] With a negative photoresist, non-linear absorption leads to curing of the material; by varying the location of the focus of excitation light within the material and tracing predefined trajectories with algorithms known to the art, confined curing over ultrasmall voxels can be controlled in three dimensions. Following optically curing using non-linear absorption, un-cured material is rinsed out (for instance, using materials known to the art such as PGMEA or SU-8 developer), leaving behind a structure that can be used to fabricate an extrinsic sensing element. After rinsing, further processing steps can include exposure to UV light (for instance with a UV oven) and/or post-baking (e.g. at 120° C. for 90 minutes) to enhance crosslinking density and improve material properties (for instance, to increase material stiffness or enhance surface smoothness). With a positive photoresist, non-linear excitation of a material is used to modify regions of a material in 3D and subsequently these optically modified regions are washed away (for instance, using solutions such as Novo developer 591S, PGMEA, and AR 300-XX). Two-photon microfabrication of external structures are typically guided by software that automatically varies the location of excitation light based on provided designs. Photoresist materials known to the art include SU-8, IP-S, IP-Dip, Ormocere, AZ 125nXT (negative photoresists), AZ MIR 701, AZ 9260, AZ 40XT (positive photoresists), amongst others. The photoresist can comprise metallic nanoparticles, and heating can be performed to remove polymeric components, as disclosed in Vyatskikh et al. Nat. Communications (2018)9: 593.
[0027] The extrinsic structure fabricated with a nonlinear optical lithography process (for instance, two-photon absorption) can be bonded to an optical fibre using a flowable adhesive such as UV-curable epoxies such as Norland 81, cyanoacrylates, ceramic adhesives, heat curing epoxies, positive photoresists, or polymer material used for the microfabrication itself The geometry of the structure and its cavity can be arranged such that bonding of the extrinsic structure to the optical fibre results in gas sealing of the cavity. Alternatively, the extrinsic structure may include one or more vent holes to allow for material washout and these vent holes may be subsequently sealed.
[0028] Before or after bonding of the extrinsic structure to the optical fibre, a mirror coating (metallic or polymeric) may be applied to the inner or outer surface of the diaphragm to increase its reflectivity to interrogation light and thereby to improve the signal-to-noise ratio of the sensor signal. In a preferred embodiment, this mirror is formed by evaporation of metals such as gold. Subsequently, a protective coating may be applied to a part of the distal end of the sensor (for instance to prevent water ingress into a flowable adhesive) or to the entire distal end of the sensor (for instance with a conformal coating such as parylene).
[0029] The optical fibre is typically single-mode with a silica core, with a distal end that is cleaved at normal incidence. Alternatively, it can be a double clad fibre to allow for interrogation light to propagate in the core and for additional light used for effecting other types of sensing functionality can be delivered in the multimode inner cladding. Alternatively, it could be a single-mode fibre with an air core or a multimode or multi-core fibre or a polymer fibre.
[0030] The microfabricated extrinsic structures are typically detached from the flat substrate and integrated with the optical fibre. The integration can be performed manually under an optical microscope using a three-axis stage for alignment or automatically using appropriate autofocussing and alignment instrumentation. The elements can be securely integrated by using adhesive materials for instance Norland 81, cyanoacrylates, heat curing epoxies, or even positive photoresists or the starting polymer material used for the microfabrication itself Following complete integration of the optical fibre to the sensor element or printed sensor sub-structure, addition of further design elements can be performed over the initially-integrated optical fibre structure.
[0031] In a preferred embodiment, the microfabricated sensor comprises a polymer dome that is insensitive to external pressure changes and sensitive to changes in ambient temperature, and transparent to the interrogation wavelength. This dome is arranged symmetrically with respect to the optical fibre axis and proximal to the diaphragm. Reflections of interrogation light from the polymer dome and from the diaphragm are resolved with phase-resolved low coherence interferometry based on differences in the phases of the interferogram frequency components. With this embodiment, measured changes in dimension of the polymer dome are used to obtain measurements of temperature changes; measured deformations of the diaphragm are used to obtain measurements of pressure changes. The polymer dome can comprise through-holes to allow for removal of the etchant. The polymer dome and the diaphragm can both be fabricated with a single material using multi-photon printing microfabrication, although the polymer and diaphragm can also be fabricated with different materials.
[0032] It can be advantageous to guide interrogation light within the extrinsic structure by lensing it or by redirecting it to different locations. One advantage of a lens is that it can collimate or focus the interrogation light to reduce beam walk-off. Additionally, it the beam exiting the optical fibre core (single mode optical fibre in this instance) is prone to divergence. Partially reflective surfaces, which can be achieved using angled structures fabricated with non-linear polymerisation, can redirect portions of the interrogation light at different diaphragms that are oriented differently with respect to each other. Said angled structures can also be curved and can have partially reflective coatings applied. Design optimisation of these elements can be performed using optical design software known to the art.
[0033] It can be useful to increase the optical reflectivity within the extrinsic structure, for instance to increase the intensity of interrogation light back-coupled into the fibre and to optically isolate the sensor from its environment. In preferred embodiments, reflective coatings are applied to the inner or outer surfaces of the diaphragm. These coatings can be applied with methods such as metal sputtering, evaporation, PVD, CVD, ALD, among others.
[0034] The sensing functionality of the distal diaphragm could be extended beyond pressure and temperature by including nanostructuring along with functional coatings. For instance, a functional metallic coating in conjunction with nanostructuring the outer/distal surface of the diaphragm (away from the confined cavity) could be used to design a plasmonic sensor. Design optimisation for the geometry and materials used for the plasmonic sensing can be achieved through optical simulation methods such as finite difference time domain, finite element methods, ray tracing, rigorous coupled wave analysis, among others.
[0035] The present invention makes use of the advancement of optical microfabrication techniques. With these techniques, three-dimensional structures can be created using materials that are modified in three dimensions with focused light beams. By moving the position of the focus relative to a material, structures with complex three-dimensional geometries can be fabricated. In one example, femotosecond (fs) laser-assisted micromachining is used to modify the material, due to non-linear interactions between the light and the material that are enabled with the brief pulse durations and tight spatial confinement of the beam. These modifications can include nanocracks and disordered nanostructures, as reported [Appl. Phys. A 84, 47-61 (2006)]. Subsequently the modified regions are etched away, resulting in a structure fabricated through subtractive microfabrication. In another example, two-photon excitation is used to cure a light-sensitive resin material at specific locations; subsequently, non-illuminated/uncured regions are washed away in the developer solvent, whereby the resulting structure is realised through additive microfabrication.
[0036] In a preferred embodiment illustrated in
[0037] With this class of fabrication methods, the first material can be within the optical fibre itself, as illustrated in
[0038]
[0039]
[0040]
[0041]
[0042]
[0043]
[0044] The figures and previous description relate to preferred features by way of illustration only. It should be noted that from the following discussion, alternative features of the structures and methods disclosed herein will be readily recognized as viable alternatives. The equipment described above is by way of example only, and it will be appreciated that it may be modified in several different ways while remaining within the scope of the present invention. In particular, preferred features that are described with reference to different Figures can be combined together in the same embodiment, unless it is clear that these features are exclusive alternatives to each other.