Organic electroluminescent device

Abstract

An organic electroluminescent device adopts a TADF material as a first host material (6) of a green light unit (302) to sensitize a green phosphorescent material serving as a first guest material (7). A portion of triplet excitons are converted into singlet excitons through inverse gap crossing, and thus decrease of the triplet exciton concentration results in narrowing of the recombination region, thereby preventing the triplet excitons from diffusing into a blue light layer (4) to emit light, so as to realize a green light spectrum containing no blue light component. And because an energy level difference between red light and blue light is relatively large, carriers in a red light unit cannot be easily transferred to the blue light layer, and therefore it is not easy for a blue light component to appear in a red light spectrum. Accordingly, the light-emitting spectrums of red/green subpixels in the organic electroluminescent device with a shared blue light layer do not contain blue light, thereby effectively broaden the range of applicable combinations of luminescent materials and improving the display performance of the device. Moreover, a hole-blocking layer is not required, and thus the structure of the device is effectively simplified, and the operation voltage is lowered; in the meantime, the process difficulty is reduced, and the product yield is increased, thereby reducing the production cost.

Claims

1. An organic electroluminescent device, comprising a first electrode, a first light-emitting layer, a second light-emitting layer and a second electrode stacked upon a substrate; wherein the first light-emitting layer comprises red light units, green light units and blue light units, which are arranged in the same layer, the second light-emitting layer is a blue light layer, the green light unit comprises a host material doped with a guest material, wherein the host material at least includes a Thermal Activation Delayed Fluorescence (TADF) material having a structure selected from the following formulas (1-90) to (1-100): ##STR00030## ##STR00031## ##STR00032## ##STR00033##

2. The organic electroluminescent device according to claim 1, the blue light unit in the first light-emitting layer is formed by a part of the second light-emitting layer extending into the first light-emitting layer.

3. The organic electroluminescent device according to claim 1, the red light unit comprises phosphorescent material; the blue light unit comprises fluorescent material; and the blue light layer comprises fluorescent material.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) In order to make the content of the present invention easier to be understood clearly, hereinafter, the present invention is further described in detail according to specific embodiments of the present invention with reference to the accompanying drawings, wherein,

(2) FIG. 1 is a structural schematic diagram of an organic electroluminescent device of the present invention;

(3) FIG. 2 is a mechanism diagram of the organic electroluminescent device of the present invention.

(4) The reference numerals in the Drawings represent: 1—substrate, 2—first electrode, 3—first light—emitting layer, 4—second light—emitting layer, 5—second electrode, 6—host material, 7—guest material, 301—red light unit, 302—green light unit, 303—blue light unit.

DETAILED DESCRIPTION OF EMBODIMENTS

(5) In order to make the objective, technical scheme and advantages of the present invention clearer, detailed description of embodiments of the present invention is further given below, with reference to the accompanying drawings.

(6) The present invention can be implemented in many different forms and should not be interpreted to be limited to the embodiments described herein. On the contrary, by providing these embodiments, the present disclosure is made complete and thorough, and the inventive concept of the present invention is sufficiently conveyed to those skilled in the art, wherein the present invention is only defined by the claims. In the accompanying drawings, for the sake of clarity, dimensions and relative sizes of layers and areas might be exaggerated.

Embodiment 1

(7) This embodiment provides an organic electroluminescent device, as shown in FIG. 1, comprising a first electrode 2, a first light-emitting layer 3, a second light-emitting layer 4 and a second electrode 5 stacked upon a substrate 1, wherein the first light-emitting layer 3 comprises red light units 301, green light units 302 and blue light units 303, which are arranged in the same layer, and the second light-emitting layer 4 is a blue light layer. In this embodiment, preferably, the blue light unit 303 in the first light-emitting layer 3 is formed by a part of the second light-emitting layer 4 extending into the first light-emitting layer 3, that is to say, the blue light unit 303 has the same material as that of the second light-emitting layer 4.

(8) As an alternative embodiment of the present invention, the material of the blue light unit 303 may also be different from that of the second light-emitting layer 4, which can also achieve the purpose of the present invention and is also within the protection scope of the present invention.

(9) As a preferred embodiment of the present invention, in the organic electroluminescent device, there are also functional layers such as a hole injection layer, a hole transport layer, an electron injection layer, an electron transport layer arranged between the first electrode 2 and the second electrode 5.

(10) Specifically, in this embodiment, ITO (indium tin oxide) is adopted as an anode; HATCN is adopted as a hole injection layer; TCTA is adopted as a hole transport layer; the green light unit 302 adopts the TADF molecule of formula (1-103) as a host material (GH-1), and adopts Tr(ppy).sub.3 as a guest material (with a doping percentage of 10 wt %); the host material and guest material of the second light-emitting layer 4 are respectively BH-1 and BD-1 (with a doping percentage of 5 wt %); Bphen is adopted as an electron transport layer; LiF is adopted as an electron injection layer; Al is adopted as a cathode.

(11) The green light unit structure is as follows: ITO/HAT-CN(7 nm)/NPB(50 nm)/TCTA(10 nm)/GH-1: 10% Ir(ppy).sub.3(30 nm)/BH-1: 5% BD-1 (25 nm)/Bphen(30 nm)/LiF(0.7 nm)/Al(150 nm). The green light unit 302 comprises a host material doped with a guest material, wherein the host material is a Thermal Activation Delayed Fluorescence (TADF) material having an energy level difference ΔE.sub.ST that is less than 0.15 eV between triplet state and singlet state (ΔE.sub.ST of (1-103) is 0.1 eV).

(12) In the red light unit structure, except that the red light unit 301 is different from the green light unit 302, the other layers are the same. The red light host material of the red light unit 301 adopts a red light dye and Ir(piq).sub.3.

(13) The red light unit structure is as follows: ITO/HAT-CN(7 nm)/NPB(50 nm)/TCTA(10 nm)/CBP: 5% Ir(piq).sub.3(30 nm)/BH-1: 5% BD-1(25 nm)/Bphen(30 nm)/LiF(0.7 nm)/Al(150 nm).

Embodiment 2

(14) This embodiment provides an organic electroluminescent device with the same device structure as that of Embodiment 1, and the difference is that the host material of the red light unit 301 is the Thermal Activation Delayed Fluorescence material of formula (1-1) and the host material of the green light unit 302 is the Thermal Activation Delayed Fluorescence material of formula (1-2).

Embodiment 3

(15) This embodiment provides an organic electroluminescent device with the same device structure as that of Embodiment 1, and the difference is that the host material of the green light unit 302 is the Thermal Activation Delayed Fluorescence material of formula (1-11).

Embodiment 4

(16) This embodiment provides an organic electroluminescent device with the same device structure as that of Embodiment 1, and the difference is that the host material of the green light unit 302 is the Thermal Activation Delayed Fluorescence material of formula (1-19).

Embodiment 5

(17) This embodiment provides an organic electroluminescent device with the same device structure as that of Embodiment 1, and the difference is that the host material of the green light unit 302 is the Thermal Activation Delayed Fluorescence material of formula (1-23).

Embodiment 6

(18) This embodiment provides an organic electroluminescent device with the same device structure as that of Embodiment 1, and the difference is that the host material of the green light unit 302 is the Thermal Activation Delayed Fluorescence material of formula (1-26).

Embodiment 7

(19) This embodiment provides an organic electroluminescent device with the same device structure as that of Embodiment 1, and the difference is that the host material of the green light unit 302 is the Thermal Activation Delayed Fluorescence material of formula (1-50).

Embodiment 8

(20) This embodiment provides an organic electroluminescent device with the same device structure as that of Embodiment 1, and the difference is that the host material of the green light unit 302 is the Thermal Activation Delayed Fluorescence material of formula (1-54).

Embodiment 9

(21) This embodiment provides an organic electroluminescent device with the same device structure as that of Embodiment 1, and the difference is that the host material of the green light unit 302 is the Thermal Activation Delayed Fluorescence material of formula (1-66).

Embodiment 10

(22) This embodiment provides an organic electroluminescent device with the same device structure as that of Embodiment 1, and the difference is that the host material of the green light unit 302 is the Thermal Activation Delayed Fluorescence material of formula (1-90).

Comparison Example 1

(23) As compared to Embodiment 1, the difference is the host material of the green light unit. In this comparison example, the green light unit adopts CBP as a green light host material, and the specific structure is as follows:

(24) ITO/HAT-CN(7 nm)/NPB(50 nm)/TCTA(10 nm)/CBP: 10% Ir(ppy).sub.3(30 nm)/BH-1: 5% BD-1(25 nm)/Bphen(30 nm)/LiF(0.7 nm)/Al(150 nm).

Comparison Example 2

(25) As compared to Embodiment 1, the difference is there is no blue light layer covering upon the red, green light units. The specific red light unit structure and green light unit structure are as follows:

(26) green light unit structure: ITO/HATCN(7 nm)/NPB(50 nm)/TCTA(10 nm)/GH-1: 10% Ir(ppy).sub.3(30 nm)/Bphen(30 nm)/LiF(0.7 nm)/Al(150 nm);

(27) red light unit structure: ITO/HAT-CN(7 nm)/NPB(50 nm)/TCTA(10 nm)/CBP:5% Ir(piq).sub.3(30 nm)/Bphen(30 nm)/LiF(0.7 nm)/Al(150 nm).

(28) The structural formulas of the organic materials adopted in the embodiments and comparison examples are as follows:

(29) TABLE-US-00001 Abbreviation structural formula HAT-CN 0 NPB TCTA CBP Ir(piq)3 Ir(ppy)3 Bphen GH-1 BH-1 (AND) BD-1

Test Example

(30) Tests are carried out on the organic electroluminescent devices of the above-mentioned Embodiments 1-10 and comparison examples, and the test results are listed in the table below:

(31) TABLE-US-00002 Current Brightness Voltage efficiency Serial Number (cd/m.sup.2) (V) (cd/A) x (V) y (V) Embodiment 1 1000.00 3.5 52 0.32 0.62 Green light Comparison 1000.00 3.7 20 0.23 0.44 example 1 Green light Comparison 1000.00 3.2 45 0.31 0.62 example 2 Green light Embodiment 1 1000.00 4.7 15 0.66 0.33 Red light Comparison 1000.00 4.4 14 0.66 0.33 example 2 Red light Embodiment 2 1000.00 3.6 50 0.32 0.61 Green light Embodiment 2 1000.00 4.7 17 0.66 0.33 Red light Embodiment 3 1000.00 3.6 49 0.32 0.61 Green light Embodiment 4 1000.00 3.7 49 0.32 0.62 Green light Embodiment 5 1000.00 3.6 51 0.32 0.62 Green light Embodiment 6 1000.00 3.5 50 0.32 0.62 Green light Embodiment 7 1000.00 3.5 46 0.32 0.61 Green light Embodiment 8 1000.00 3.6 47 0.32 0.61 Green light Embodiment 9 1000.00 3.6 47 0.32 0.62 Green light Embodiment 10 1000.00 3.5 49 0.32 0.61 Green light

(32) Thus it can be seen that, the green light spectrum and red light spectrum of the organic electroluminescent devices in Embodiments 1-10 do not contain blue light.

(33) As can be seen from the green light tests on Embodiment 1 and Comparison example 1, using a non-TADF green-light host material in the green light unit 302 would cause a blue light component to appear in the green light spectrum; on the other hand, introducing a TADF green-light host material can narrow the carrier recombination region, so that the green light spectrum does not contain a blue light component.

(34) As can be seen from the green light tests on Embodiment 1 and Comparison example 2, adding a blue light layer upon the green light unit 302 that has a TADF green-light host material would not influence the current efficiency or chroma of the green light unit itself, and no blue light component would appear in the green light spectrum. Introducing a blue light layer would slightly increase the operation voltage of the green light unit.

(35) As can be seen from the red light tests on Embodiment 1 and Comparison example 2, adding a blue light layer upon the red light unit 301 would not influence the current efficiency or chroma of the red light unit 301 itself, and no blue light component would appear in the red light spectrum. Introducing a blue light layer would slightly increase the operation voltage of the red light unit.

(36) As can be seen from the red light tests on Embodiment 2 and Comparison example 2, the red light unit 301 adopts a Thermal Activation Delayed Fluorescence material as its host material, and adding a blue light layer upon the red light unit 301 would not influence the chroma of the red light unit 301 itself, while the operation voltage of the red light unit is slightly increased. When the red light unit 301 adopts a Thermal Activation Delayed Fluorescence material as its host material, the red light-emitting efficiency is increased to a certain extent.

(37) Apparently, the aforementioned embodiments are merely examples illustrated for clearly describing the present invention, rather than limiting the implementation ways thereof. For a person skilled in the art, various changes and modifications in other different forms can be made on the basis of the aforementioned description. It is unnecessary and impossible to exhaustively list all the implementation ways herein. However, any obvious changes or modifications derived from the aforementioned description are intended to be embraced within the protection scope of the present invention.