COMPOSITION COMPRISING AT LEAST TWO DIFFERENT ANIONIC SURFACTANTS, NON-IONIC AND AMPHOTERIC SURFACTANTS, AND CATIONIC OR AMPHOTERIC POLYMERS

Abstract

The present invention relates to a cosmetic composition comprising anionic surfactants of polyoxyalkylenated alkyl(amido)ether carboxylic acid type, additional non-sulfated anionic surfactants, non-ionic and amphoteric surfactants and cationic or amphoteric polymers. The invention also relates to a process for the cosmetic treatment of keratin materials, in particular for washing and/or conditioning the hair, using such a composition, and also to a use employing said composition.

Claims

1.-17. (canceled)

18. A cosmetic composition comprising: (i) at least one anionic surfactant chosen from polyoxyalkylenated alkyl(amido)ether carboxylic acids or salts thereof; (ii) at least one non-sulfated anionic surfactant other than the at least one anionic surfactant chosen from polyoxyalkylenated alkyl(amido)ether carboxylic acids or salts thereof (i); (iii) at least one nonionic surfactant chosen from alkyl(poly)glycosides; (iv) at least one amphoteric surfactant; and (v) at least one polymer chosen from amphoteric polymers and cationic polymers.

19. The composition of claim 18, wherein the polyoxyalkylenated alkyl(amido)ether carboxylic acids are chosen from compounds of formula (1):
R.sub.1—(OC.sub.2H.sub.4).sub.n—OCH.sub.2COOA  (1) wherein in formula (1): R1 is chosen from a linear or branched C6-C24 alkyl or alkenyl radical, a (C8-C9)alkylphenyl radical, or a radical R2CONH—CH2-CH2-, wherein R2 is chosen from a linear or branched C9-C21 alkyl or alkenyl radical; n is an integer or decimal number ranging from 2 to 24; and A is chosen from H, ammonium, Na, K, Li, Mg, Ca, a monoethanolamine residue, or a triethanolamine residue.

20. The composition of claim 18, wherein the at least one anionic surfactant chosen from the polyoxyalkylenated alkyl(amido)ether carboxylic acids or salts thereof is present in a total amount ranging from 0.1% to 30% by weight, relative to the total weight of the composition.

21. The composition of claim 18, wherein the at least one non-sulfated anionic surfactant (ii) is chosen, alone or as a mixture, from: C6-C24 olefin sulfonates; C6-C24 alkylsulfosuccinates; C6-C24 alkyl ether sulfosuccinates; (C6-C24)acylisethionates; C6-C24 acylsarcosinates; C6-C24 acylglutamates; or C6-C24 acylglycinates; optionally in the form of alkali metal, alkaline-earth metal, ammonium salts, or amino alcohol salts.

22. The composition of claim 18, wherein the at least one non-sulfated anionic surfactant (ii) is present in a total amount ranging from 3% to 20% by weight, relative to the total weight of the composition.

23. The composition of claim 18, wherein the alkyl(poly)glycosides are represented by the formula: R1O—(R2O)t-(G)v, wherein: R1 is chosen from a linear or branched alkyl or alkenyl radical including 6 to 24 carbon atoms, or an alkylphenyl radical, of which the linear or branched alkyl radical includes 6 to 24 carbon atoms; R2 represents an alkylene radical including 2 to 4 carbon atoms; G represents a sugar unit including 5 to 6 carbon atoms; t denotes a value ranging from 0 to 10; and v denotes a value ranging from 1 to 15.

24. The composition of claim 18, wherein the at least one nonionic surfactant is present in a total amount ranging from 0.1% to 15% by weight, relative to the total weight of the composition.

25. The composition of claim 18, wherein the at least one amphoteric surfactant is chosen from: (C.sub.8-C.sub.20)alkylbetaines; (C.sub.8-C.sub.20)alkylsulfobetaines; (C.sub.8-C.sub.20)alkylamido(C.sub.3-C.sub.8)alkylbetaines; (C.sub.8-C.sub.20)alkylamido(C.sub.6-C.sub.8)alkylsulfobetaines; or compounds having formulae (II) or (III) below:
R.sub.a—CONHCH.sub.2CH.sub.2—N.sup.+(R.sub.b)(R.sub.c)—CH.sub.2COO.sup.−, M.sup.+, X.sup.−  (II) wherein in formula (II): R.sub.a is chosen from a C.sub.10 to C.sub.30 alkyl or alkenyl group derived from an acid R.sub.aCOOH, a heptyl group, a nonyl group, or an undecyl group; R.sub.b is chosen from a β-hydroxyethyl group; and R.sub.c is chosen from a carboxymethyl group; M.sup.+ represents a cationic counterion derived from an alkali metal, an alkaline-earth metal, an ammonium ion, or an ion derived from an organic amine; and X.sup.− represents an organic or mineral anionic counterion; or alternatively M.sup.+ and X.sup.− are absent;
R.sub.a′—CONHCH.sub.2CH.sub.2—N(B)(B′)  (III) wherein in formula (III): B is chosen from the group —CH.sub.2CH.sub.2OX′; B′ is chosen from the group —(CH.sub.2).sub.zY′, wherein z=1 or 2; X′ is chosen from the group —CH.sub.2COOH, —CH.sub.2—COOZ′, —CH.sub.2CH.sub.2COOH, CH.sub.2CH.sub.2—COOZ′, or a hydrogen atom; Y′ is chosen from the group —COOH, —COOZ′, —CH.sub.2CH(OH)SO.sub.3H, or CH.sub.2CH(OH)SO.sub.3—Z′; Z′ represents a cationic counterion derived from an alkali metal, an alkaline-earth metal, an ammonium ion, or an ion derived from an organic amine; R.sub.a′ represents a C.sub.10 to C.sub.30 alkyl or alkenyl group of an acid R.sub.a′—COOH, an alkyl group or its iso form, or an unsaturated C.sub.17 group; compounds of formula (IV): R.sub.a″—NHCH(Y″)—(CH2)nCONH(CH2)n′-N(Rd)(Re) wherein in formula (IV): Y″ is chosen from —COOH, —COOZ″, —CH.sub.2—CH(OH)SO.sub.3H, or CH.sub.2CH(OH)SO.sub.3—Z″; R.sub.d and R.sub.e, independently of each other, represent a C.sub.1 to C.sub.4 alkyl or hydroxyalkyl radical; Z″ represents a cationic counterion derived from an alkali metal or alkaline-earth metal, an ammonium ion, or an ion derived from an organic amine; R.sub.a″ represents a C.sub.10 to C.sub.30 alkyl or alkenyl group of an acid R.sub.a″—COOH; and n and n′, independently of each other, denote an integer ranging from 1 to 3.

26. The composition of claim 18, wherein the at least one amphoteric surfactant is present in a total amount ranging from 3% to 20% by weight, relative to the total weight of the composition.

27. The composition of claim 18, wherein the weight ratio of the total amount of the at least one amphoteric surfactant (iv) to the total amount of the at least one non-sulfated anionic surfactant (ii) other than the at least one anionic surfactant (i) chosen from polyoxyalkylenated alkyl(amido)ether carboxylic acids or salts thereof is greater than or equal to 0.5.

28. The composition of claim 18, wherein the cationic charge density of the at least one polymer chosen from amphoteric polymers and cationic polymers is less than or equal to 4 meq/g.

29. The composition of claim 18, wherein the at least one polymer chosen from amphoteric polymers and cationic polymers are chosen from: (1) homopolymers or copolymers derived from acrylic or methacrylic esters, or amides, and including at least one of the units having the following formulae: ##STR00012## wherein: R3, which may be identical or different, represents a hydrogen atom or a CH3 radical; A, which may be identical or different, is chosen from a linear or branched divalent alkyl group of 1 to 6 carbon atoms, or a hydroxyalkyl group of 1 to 4 carbon atoms; R4, R5 and R6, which may be identical or different, is chosen from an alkyl group containing from 1 to 18 carbon atoms or a benzyl radical; R1 and R2, which may be identical or different, is chosen from a hydrogen atom or an alkyl group containing from 1 to 6 carbon atoms; X denotes an anion derived from a mineral or organic acid; (2) cationic polysaccharides; cationic derivatives of cassia gum; or cationic associative celluloses; (3) polymers constituted of piperazinyl units, and of divalent alkylene or hydroxyalkylene radicals containing linear or branched chains, optionally interrupted with an oxygen atom, sulfur atom, nitrogen atom, or aromatic or heterocyclic rings, and the oxidation and/or quaternization products of these polymers; (4) water-soluble polyaminoamides; (5) polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents; (6) polymers obtained by reacting a polyalkylene polyamine including two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids containing from 3 to 8 carbon atoms; (7) cyclopolymers of alkyldiallylamine or of dialkyldiallylammonium, which may be homopolymers or copolymers, including, as main constituent of the chain, units corresponding to formula (I) or (II): ##STR00013## wherein in formulae (I) and (II), k and t are equal to 0 or 1, the sum k+t being equal to 1; R12 denotes a hydrogen atom or a methyl radical; R10 and R11, independently of each other, are chosen from a C1-C6 alkyl group, a C1-C5 hydroxyalkyl group, or a C1-C4 amidoalkyl group; or alternatively, R10 and R11 are chosen from, together with the nitrogen atom to which they are attached, a heterocyclic group; and Y.sup.− is an anion; (8) quaternary diammonium polymers comprising repeating units of formula: ##STR00014## wherein in formula (III): R13, R14, R15, and R16, which may be identical or different, are chosen from aliphatic, alicyclic, or arylaliphatic radicals comprising from 1 to 20 carbon atoms, or from C1-C12 hydroxyalkyl aliphatic radicals; alternatively, R13, R14, R15, and R16, together or separately, form, with the nitrogen atoms to which they are attached, heterocycles optionally comprising a second non-nitrogen heteroatom; or alternatively, R13, R14, R15, and R16 is chosen from a linear or branched C1-C6 alkyl radical substituted with a nitrile, ester, acyl, amide, —CO—O—R17-D group, or —CO—NH—R17-D group, wherein R17 is an alkylene and D is a quaternary ammonium group; A1 and B1 are chosen from linear or branched, saturated or unsaturated, or divalent polymethylene groups comprising from 2 to 20 carbon atoms, which may contain, linked to, or intercalated in the main chain, at least one aromatic ring, at least one oxygen or sulfur atom, or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide, or ester groups; and X.sup.− denotes an anion derived from a mineral or organic acid; wherein A1, R13, and R15 can form, with the two nitrogen atoms to which they are attached, a piperazine ring; wherein, if A1 is chosen from a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B1 can also be chosen from a group (CH2)n-CO-D-OC—(CH2)p- with n and p, which may be identical or different, being integers ranging from 2 to 20, wherein D is chosen from: a) a glycol residue of formula —O—Z—O—, wherein Z is chosen from a linear or branched hydrocarbon-based radical, or a group corresponding to one of the following formulae: —(CH2CH2O)x-CH2CH2- and —[CH2CH(CH3)O]y-CH2CH(CH3)-, wherein x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization, or any number from 1 to 4, representing an average degree of polymerization; b) a bis-secondary diamine residue; c) a bis-primary diamine residue of formula —NH—Y—NH—, in which Y denotes a linear or branched hydrocarbon-based radical, or alternatively, the divalent radical —CH2-CH2-S—S—CH2-CH2-; or d) an ureylene group of formula —NH—CO—NH—; (9) polyquaternary ammonium polymers comprising units of formula (V): ##STR00015## wherein in formula (V): R18, R19, R20 and R21, which may be identical or different, are chosen from a hydrogen atom, a methyl, ethyl, propyl, β-hydroxyethyl, β-hydroxypropyl, or —CH2CH2(OCH2CH2)pOH radical, wherein p is equal to 0, or to an integer between 1 and 6, with the proviso that R18, R19, R20 and R21 do not simultaneously represent a hydrogen atom; r and s, which may be identical or different, are integers between 1 and 6; q is equal to 0 or to an integer between 1 and 34; X− denotes an anion; and A denotes a divalent dihalide radical or —CH2-CH2-O—CH2-CH2-; (10) quaternary polymers of vinylpyrrolidone and of vinylimidazole; (11) polyamines; (12) polymers including in their structure: (a) at least one unit corresponding to formula (A) below: ##STR00016## (b) optionally at least one unit corresponding to formula (B) below: ##STR00017## (13) amphoteric polymers comprising a repetition of: (i) at least one unit derived from a (meth)acrylamide-type monomer; (ii) at least one unit derived from a (meth)acrylamidoalkyltrialkylammonium-type monomer; and (iii) at least one unit derived from a (meth)acrylic acid-type acid monomer.

30. The composition of claim 29, wherein the cationic polysaccharides comprise associative or nonassociative cationic celluloses or galactomannan gums.

31. The composition of claim 29, wherein the cationic derivatives of cassia gum comprise quaternary ammonium groups.

32. The composition of claim 29, wherein the cationic associative celluloses comprise quaternized celluloses modified with groups including at least one fatty chain; wherein the at least one fatty chain includes at least 8 carbon atoms.

33. The composition of claim 29, wherein the water-soluble polyaminoamides are prepared by polycondensation of an acidic compound with a polyamine; wherein the water-soluble polyaminoamides is able to be crosslinked with an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-alkyl halide, or alternatively with an oligomer resulting from the reaction of a difunctional compound which is reactive with a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-alkyl halide, an epihalohydrin, a diepoxide, or a bis-unsaturated derivative; wherein a crosslinking agent is used when preparing the water-soluble polyaminoamides in proportions ranging from 0.025 to 0.35 mol per amine group of the polyaminoamide; and wherein the water-soluble polyaminoamides can be alkylated, or, if they include at least one tertiary amine function, the water-soluble polyaminoamides can be quaternized.

34. The composition of claim 18, wherein the at least one polymer chosen from amphoteric polymers and cationic polymers are chosen from: cationic polysaccharides; homopolymers or copolymers of dimethyldiallylammonium salts; or amphoteric polymers comprising: from 30 mol % to 70 mol % of units derived from a monomer of (meth)acrylamide type (i), from 10 mol % to 60 mol % of units derived from a monomer of (meth)acrylamidoalkyltrialkylammonium type (ii), and from 1 mol % to 20 mol % of units derived from a monomer of (meth)acrylic acid type (iii).

35. The composition of claim 18, wherein at least one polymer chosen from amphoteric polymers and cationic polymers is present in a total amount ranging from 0.01% to 5% by weight, relative to the total weight of the composition.

36. The composition of claim 18, further comprising water present in a total amount ranging from 50% to 95% by weight, relative to the total weight of the composition.

37. A method of treating keratin materials comprising: applying to the keratin materials an effective amount of a composition comprising: (i) at least one anionic surfactant chosen from polyoxyalkylenated alkyl(amido)ether carboxylic acids or salts thereof; (ii) at least one non-sulfated anionic surfactant other than the polyoxyalkylenated alkyl(amido)ether carboxylic acids or salts thereof (i); (iii) at least one nonionic surfactant chosen from alkyl(poly)glycosides; (iv) at least one amphoteric surfactant; and (v) at least one polymer chosen from amphoteric polymers and cationic polymers; optionally, subsequently rinsing the keratin materials after the composition is left on the keratin materials for a desired period of time; and optionally drying the keratin materials after rinsing the keratin materials.

Description

EXAMPLE 1

[0258] The cosmetic compositions (A) and (B) according to the invention and the comparative composition are prepared from the ingredients shown in the table below, the amounts of which are expressed as weight percentages of active material (AM).

TABLE-US-00001 Compositions (% AM) A B comparative Laureth-5 carboxylic acid 2.0 2.0 6.0 Sodium C14-C16 olefin sulfonate 7.0 7.0 — Cocamidopropyl betaine 6.4 7.0 7.0 Caprylyl/capryl glucoside 1.5 1.5 — Cassia hydroxypropyltrimonium 0.3 0.3 — chloride Polyquaternium-7 0.1 — — Polyquaternium-53 —  0.25 0.25 Polyquaternium-6 — — 0.5 Laureth-12 — — 4 Laureth-4 — — 1 Sodium laureth sulfate — — 7 NaCl 1.2 1.3 1.8 Preserving agents qs qs qs pH agent qs pH qs pH qs pH 4.7 ± 0.3 4.7 ± 0.3 4.7 ± 0.3 Water qs 100 qs 100 qs 100

[0259] The compositions according to the invention may be used as shampoos.

[0260] It is found that compositions A and B according to the invention give the head of hair good properties in terms of disentangling, a smooth feel and visual smoothness, suppleness and coating of the fiber.

EXAMPLE 2

[0261] The cosmetic compositions C and D according to the invention are prepared from the ingredients shown in the table below, the amounts of which are expressed as weight percentages of active material (AM).

TABLE-US-00002 Compositions (% AM) C D Laureth-5 carboxylic acid 2.0 2.0 Sodium C14-C16 olefin sulfonate 7.0 7.0 Cocamidopropyl betaine 6.4 6.4 Caprylyl/capryl glucoside 1.5 1.5 Polyquaternium-67 0.3 0.2 Plant oils (coconut, soybean) —  0.03 NaCl 1.2 1.3 Preserving agents qs qs pH agent qs pH qs pH 4.7 ± 0.3 5.1 ± 0.3 Water qs 100 qs 100

[0262] The compositions according to the invention may be used as shampoos.

[0263] It is found that these compositions give the head of hair good properties in terms of disentangling, a smooth feel and visual smoothness, suppleness and coating of the fiber.