Multi-parameter enhancement of membrane bioreactor process efficiency by biomass selection and selective biomass wasting
11117821 · 2021-09-14
Assignee
Inventors
Cpc classification
Y02W10/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C02F2203/004
CHEMISTRY; METALLURGY
C02F9/00
CHEMISTRY; METALLURGY
C02F3/1221
CHEMISTRY; METALLURGY
C02F2209/105
CHEMISTRY; METALLURGY
C02F1/001
CHEMISTRY; METALLURGY
International classification
C02F9/00
CHEMISTRY; METALLURGY
Abstract
The present invention relates to a process and device for selectively removal of deflocculated sludge below a pre-selected size from a sludge mixed liquor. The invention resides in the concept of removing from the sludge mixed liquor deflocculated sludge. The removal is preferably carried out by a two-step separation providing a fraction comprising sludge flocs, substantially freed from deflocculated sludge, and a fraction containing mostly deflocculated sludge. The fraction comprising sludge flocs is returned into the sludge mixed liquor, while the fraction containing mostly deflocculated sludge is removed from the system.
Claims
1. A process for selective removal of deflocculated sludge below a pre-selected size from a sludge mixed liquor, the process comprising: a first separation separating at least a fraction of said sludge mixed liquor into fractions comprising: a first fraction comprising sludge flocs, and a second fraction comprising deflocculated sludge; wherein the first and the second fractions are provided by separating said sludge mixed liquor extracted from a first tank; a second separation separating at least a fraction of the second fraction into fractions comprising: a third fraction comprising a lower amount of deflocculated sludge, and a fourth fraction comprising a higher amount of the deflocculated sludge contained in the second fraction; feeding the first fraction and the third fraction into a second tank: wherein the process further comprises feeding the first fraction and the third fraction contained in the second tank into said sludge mixed liquor in the first tank; the combination of the first fraction and the third fraction in the second tank having a higher content of sludge flocs than said sludge mixed liquor in the first tank.
2. The process according to claim 1, wherein the process further comprises: filtering mixed liquor in the second tank to provide a filtrate comprising substantially no sludge flocs.
3. The process according to claim 1, wherein the first separation is selected from one or more or a combination of: a gravity-based separation in which the first fraction is provided by settling or sedimentation, a cyclone based separation, and/or a cross flow filter with openings selected in the range between 5-30 micron.
4. The process according to claim 1, wherein the second separation is selected from one or more of: a cake filtration, wherein a filter cake is provided by sludge flocs, a sock filter filtration, a membrane filter, a granular media filter, a mesh type band filter or a disc filter.
5. The process according to claim 1, wherein the separating of the at least a fraction of said sludge mixed liquor as the first separation is into two fractions: the first fraction containing sludge flocs, and the second fraction containing deflocculated sludge.
6. The process according to claim 1, wherein the separating of the second fraction as the second separation is into two fractions: the third fraction, and the fourth fraction.
7. The process according to claim 1, wherein said pre-selected size is 15 micron, 10 micron, or 5 micron.
8. The process according to claim 1, wherein the process further comprises gas sparging by introducing a gas or atmospheric air into said sludge mixed liquor.
9. The process according to claim 1, wherein the sludge mixed liquor is contained in the first tank, and wherein: the first and the second fractions are provided by extracting and separating the sludge mixed liquor from the first tank, the first fraction and the third fraction are fed into said first tank, thereby selectively removing deflocculated sludge from the sludge mixed liquor contained in the first tank.
10. The process according to claim 1, wherein the process further comprises filtering sludge mixed liquor contained in the second tank to provide a filtrate containing a lower amount of sludge flocs.
11. The process according to claim 10, wherein the the filtering is carried out by a microporous membrane filter having a pore size of between 10 micron and 0.1 micron, or an ultrafiltration membrane having a pore size between 0.1 micron and 0.001 micron.
12. The process according to claim 1, wherein the fourth fraction is fed to a storage capacity, or a biogas production facility, or is dewatered and disposed of.
13. The process according to claim 1, further comprising treating waste water to provide said sludge mixed liquor.
14. A device for selective removal of deflocculated sludge below a pre-selected size from a sludge mixed liquor, the device comprising: a first tank configured to contain a sludge mixed liquor; a first separator fluidically connected to an interior of the first tank for receiving said sludge mixed liquor from the first tank and being configured for separating the received mixed liquor into fractions including: a first fraction containing sludge flocs, and a second fraction containing deflocculated sludge; a second separator fluidically connected with the first separator for receiving at least a fraction of the second fraction and being configured for separating said second fraction into fractions including: a third fraction comprising a lower amount of deflocculated sludge, and a fourth fraction comprising a higher amount of deflocculated sludge contained in the second fraction; a second tank configured to contain at least a fraction of the first fraction and at least a fraction of the third fraction; wherein the first separator is fluidically connected to the second tank to feed the first fraction into the second tank, the second separator is fluidically connected to the second tank to feed the third fraction into said second tank, and the second tank is fluidically connected to the first tank to feed at least a fraction of the sludge mixed liquor contained in the second tank to the first tank, said fraction of sludge mixed liquor having a higher content of sludge flocs than the content of sludge flocs in the first tank.
15. The device according to claim 14, wherein the device further comprises: a filter configured to filter mixed liquor contained in the second tank to provide a filtrate containing substantially no sludge flocs.
16. The device according to claim 14, wherein the first separator is selected from one of: a gravity separator in which the first fraction is provided by settling or sedimentation, a cyclone separator, and/or a cross flow filter with openings selected in the range between 5-30 micron.
17. The device according to claim 14, wherein the second separator is selected from one of: a cake filter, wherein the cake filter is provided by sludge flocs being deposited on a filtration cake support being a porous member allowing liquid to flow through and arresting deflocculated sludge, a sock filter filtration, a membrane filter, a granular media filter, a mesh type band filter or a disc filter.
18. The device according to claim 14, wherein the first separator is configured to separate the received sludge mixed liquor into two fractions: the first fraction comprising sludge flocs, and the second fraction comprising deflocculated sludge.
19. The device according to claim 14, wherein the second separator is configured to separate the second fraction into two fractions: the third fraction, and the fourth fraction.
20. The device according to claim 14, wherein said pre-selected size is 15 micron, 10 micron, or 5 micron.
21. The device according to claim 14, wherein the device further comprises a gas sparer for introducing a gas or atmospheric air into the first tank so as to supply said sludge mixed liquor with said gas or atmospheric air.
22. The device according to claim 14, wherein a filter filters: sludge mixed liquor contained in the second tank.
23. The device according to claim 22, wherein the filter is a microporous membrane filter having a pores size of between 10 micron and 0.1 micron and/or an ultrafiltration membrane having a pore size between 0.1 micron and 0.001 micron.
24. The device according to claim 14, wherein the second separator is fluidically connected to feed the fourth fraction into a storage capacity, or a biogas production facility, or is dewatered and disposed of.
25. The device according to claim 14, further comprising an inlet to the first tank for feeding waste water into said first tank.
Description
BRIEF DESCRIPTION OF THE FIGURES
(1) The present invention and in particular preferred embodiments thereof will now be described in more detail with reference to the accompanying figures. The FIGS. show ways of implementing the present invention and are not to be construed as being limiting to other possible embodiments falling within the scope of the attached claim set.
(2)
(3)
DETAILED DESCRIPTION OF AN EMBODIMENT
(4) The present invention aims inter alia at providing technology capable of addressing some, most or even all the issues related to the presence of a membrane in the biological sludge system and adding new degrees of freedom to process control.
(5) Once concept of the invention, is to selectively remove the deflocculated material from MBR mixed liquor by separation of small particles (deflocculated cells, floc debris) from large particles (flocs and floc aggregates), and further solid/liquid separation of that fraction and ultimate removal of reject matter from the system. In addition, selective wasting of deflocculated material rather than general mixed liquor is seen to create a new degree of freedom in system control, by decoupling sludge age from MLSS concentration and sludge wasting. This extra control handle would be especially valuable to MBR systems run with short sludge age and low MLSS concentrations, enabling higher abundances of slow-growing microorganisms to thrive in such systems regardless of the apparently short sludge age or low MLSS concentration.
(6) Removal of deflocculated matter from MBR mixed liquor may not only combat membrane fouling better than flux enhancers (no ‘sticky’ matter to potentially plug membrane pores will be introduced into the system), but will assure comprehensive optimization of many aspects of MBR functioning: improve biomass cake formation characteristics, leading to higher fluxes and lower pressure drops on the membrane decrease the demand for membrane air sparging or crossflow decrease the dead fraction of MLSS, improving the process rates and system capacity with respect to BOD removal and potentially opening a way to design more compact systems improve aeration efficiency by increasing the alpha factor for oxygen transfer decouple the true sludge age from sludge wasting and MLSS concentration, leading to improving the biomass composition by enabling slow growing organisms like nitrifiers, denitrifiers and PAO to build up to significantly higher abundancies (especially important to systems run with short sludge age)
(7) Given that the dead fraction of MBR mixed liquor is often around 20%, and that anti-fouling costs in MBRs can reach up to 50% of their OPEX, at least a 20-30% reduction of the overall OPEX can be expected with the proposed technology.
(8) The selective removal of deflocculated matter can be achieved in a compact, stand-alone sub-system performing a two-step procedure. In the first step, the mixed liquor would be separated into large and small particles e.g. by gravity-based or filter-based approaches. The ‘heavy’ fraction, containing well-flocculated sludge, would then be returned to the process tank, or membrane tank if present. In the second step, the ‘light’ fraction containing the deflocculated material would be subjected to more rigorous solid/liquid separation, where water would be returned to the process and solids would constitute the waste sludge. This way the waste sludge of the MBR system would by partly or entirely made up of the unproductive sludge fraction, helping to realize the abovementioned advantages.
(9) There is a number of possible specific approaches to separating the large sludge aggregates from small debris, such as those included high-rate clarification, cyclone centrifugation and cross-flow assisted coarse filtration. All these approaches have been shown to work in our experiments and carry out the required functions
(10) In the following, various aspects and embodiments of the invention will be presented with reference to the accompanying figures.
(11)
(12) As illustrated in
(13) The separation in
(14) However, the process can also be implemented by arranging the first separation device 2 inside the tank 15, and can use other physical principles than screening, such as gravity separation and forced gravity separation (centrifugation, cyclones etc.)
(15) The process also comprise a second separation 6 separating at least a fraction of the second fraction 5 into fractions including a third fraction 7 containing a less amount of, such as substantially no, deflocculated sludge, and a fourth fraction 8 containing a higher amount, such as substantially all of the deflocculated sludge contained in the second fraction. Also this second separation 6 may be—alternatively to arranging the second separator 6 outside the tank 15—performed inside the tank 15 by arranging the second separator 6 inside the tank 15. Separators 2 and 6 can also be integrated into a single device performing both separation functions.
(16) In the embodiments shown in
(17) The process further comprises feeding the first fraction 4 and the third fraction 7 into said sludge mixed liquor 1.
(18) Hereby, the “selective nature” of the invention can be realised, since the first fraction 4 contains sludge flocs and the third fraction 7 contains substantially no deflocculated slugde, and such matter is substantially contained in the fourth fraction 8 which is not introduced into the sludge mixed liquor, the separations 2, 6 form a selectively removal of deflocculated sludge from the sludge mixed liquor. Thus, the first fraction 4 may be seen as containing improved quality sludge and the third fraction may be seen as containing water, which may be termed clarified supernatant.
(19) It is noted that the fourth fraction 8 may be a liquid fraction containing the deflocculated flocs or may be a deposition of deflocculated flocs inside the second separator 6 which deposition is removed occasionally, thereby removed from the separator 6.
(20) As illustrated, the process further comprise filtering the mixed liquor 1 contained inside the tank 15. Such a filtering is designed to provide a filtrate 11 containing substantial no sludge flocs. In preferred embodiments, the filtering is preferably a membrane filtration.
(21) Different choices for providing the first separation exist, and it is envisaged that a first separation 2 selected from one or more of: a gravity-based separation in which the first fraction is provided by settling or sedimentation, a cyclone based separation, and/or a cross flow filter with opening selected in the range between 5-30 micron provides a useful separation.
(22) The gravity-based separation may be provided by a using a container of sufficient volumetric size to allow settling or sedimentation of matter having a density making the matter sink towards the bottom—that is typically sludge mixed liquor, and/or sludge flocs—and arranging an outlet at the bottom for extracting the first fraction 4 and an outlet at an upper end for extracting second fraction 5 deflocculated flocs and fine particles.
(23) The cyclone based separation may be provided by an ordinary hydro-cyclone where the first fraction 4 is taken out at the lower end of the hydro-cyclone and the second fraction 5 is taken out at the upper end of the hydro-cyclone at the centre of the hydro-cyclone.
(24) The cross flow filter separation may be provided by leading the fraction of sludge mixed liquor passed a filter element in a flow direction being parallel to the surface of the filter element and providing a positive pressure difference across the filter element to provide a flow though the filter element.
(25) The different types for the first separation 2 mentioned above may also be combined, such as arranged in series.
(26) Different choices for providing the second separation 6 exist, and it is envisaged that a second separation 6 selected from one or more of: a cake filtration, where a filter cake is provided by sludge flocs, a sock filter filtration, a membrane filter, a granular media filter, such as sand filter, a mesh type band filter or disc filter.
(27) The cake filtration option is found to be particular useful separating deflocculated flocs out from the second fraction 5. Such a cake filtration is based on formation of a filtration cake on a filtration cake support, such as a screen with opening, wherein the filtration cake is made by depositing sludge flocs. While such flocs may be harvested from the tank 15, it is found to be advantageous to use the first fraction 4 as a source of sludge flocs, since deflocculated flocs are substantially removed from this fraction. When the filtration cake is formed, the sludge flocs—typically be a fluid flow—are directed towards the surface of filtration cake support. A flow is at the same time established through the filtration cake support, whereby sludge flocs deposit on the surface of the filtration cake support. The filtering characteristics can be designed by the thickness of the filtration cake and by compressing the filtration cake deposited on the filtration cake support; such a compression can suitably be provided by increasing the pressure across the deposited sludge flocs for a pre-defined time period so as to compress the filtration cake to obtain a more dense structure. After the formation of the filtration cake, the filtration cake can be used as filter to separate the second fraction 5 into the third fraction 7 and the fourth fraction 8 would remain inside the filtration cake and be removed together with it.
(28) A sock filtering can be embodied by an ordinary sock filter into which the second fraction is fed. The filtering is typically provided by an outside-in filtration where the second fraction is filtered through filter material of the sock so as to provide the third fraction at the inside of the sock—or reversed in an inside-out configuration.
(29) Membrane filter, granular media filter, such as sand filter, a mesh type band filter or disc filter, may also be embodied by ordinary filters of the named type. The different types for the second separation 6 mentioned above may also be combined, such as arranged in series.
(30) In a specific preferred embodiment of the process the first separation 2 separates the at least a fraction 3 of said sludge mixed liquor 1 into two fractions: the first fraction 4 containing sludge flocs, and the second fraction 5 containing deflocculated sludge. Thereby (with reference to
(31) In a specific preferred embodiment of the process the second separation 6 separates the second fraction 5 into two fractions: the third fraction 7, and the fourth fraction 8. Thereby (with reference to
(32) In a process according to the present invention, the pre-selected size for the deflocculated sludge is below 15 micron, such as below 10 micron, preferably below 5 micron. This means that particles having size smaller than this is considered to be finer particles. By size is typically meant that the particles can pass through a porous material having a pores size up to 15 micron, such as 10 micron, preferably 5 micron. However, size may not be the only parameter useful to define first and second fractions, as speed of settling could be another one.
(33) As illustrated in
(34) Reference is made to
(35) Since in the embodiment shown in
(36) Further, in
(37) Reference is made to
(38) The filtering 12 of the sludge mixed liquor 1 to provide a filtrate 11 containing a less amount of such as substantially no sludge flocs, filters: the sludge mixed liquor contained in the second tank 15b in embodiments where the tank 15 is divided into two or more tanks 15a, 15b. If more than two tanks 15 are provided, the filtering is provided in the most downstream tank; the sludge mixed liquor contained in the tank 15 in embodiments wherein the tank is non-divided (as also referred to herein as a non-divided void).
(39) It may in general be preferred to perform the filtering at a position being most downstream to the position at which waste water is introduced.
(40) The filtering 12 is preferably carried out by use of a microporous membrane filter, being is a microfiltration typically having a pores size of between 10 micron and 0.1 micron, or an ultrafiltration membrane typically having a pore size between 0.1 micron and 0.001 micron.
(41) The fourth fraction 8 may contain biological material which may be of use e.g. as a fertilizer, a source for biogas production or it may be considered as of no use. Accordingly, the fourth fraction 8 may be disposed by being fed to a storage capacity, a biogas production facility, or may be dewatered and disposed of in general.
(42) The waste water is in general considered be treated when in contact with the sludge mixed liquor and a process according to the invention may therefore be seen as waste water treatment process which provide said sludge mixed liquor.
(43) Reference is in the following made to
(44)
(45) In the following, the wording “fluidic connected” is used in a couple of instances and is typically used inter alia to refer to a flow passage (such as inlet or outlet), a pipe, a tube and the like. One or more valves may be introduced to control the flow through the fluidic connection.
(46) Further, configured for is used to reference inter alia the various devices disclosed herein.
(47) The device has a first separator 2 fluidic connected to the interior of tank 15 for receiving said sludge mixed liquor 1 from the tank 15. In the embodiment of the
(48) The first separator 2 being configured for separating the received mixed liquor into fractions including: a first fraction 4 containing sludge flocs, and a second fraction 5 containing deflocculated sludge.
(49) The device also has a second separator 6 fluidic connected with first separator 2 for receiving at least a fraction of the second fraction 5. In the embodiment of
(50) Further, the first separator 2 is fluidic connected to the tank 15 by a pipe to feed the first fraction 4 into the tank 15, and the second separator 6 is fluidic connected to the tank 15 by a pipe to feed the third fraction 7 into said tank 15.
(51) Although the embodiment of
(52) As illustrated in
(53) The first separator 2 may be is selected from one of (or a combination thereof): a gravity separator in which the first fraction is provided by settling or sedimentation, a cyclone separator, and/or a cross flow filter with openings selected in the range between 5-30 micron as also disclosed in connection with the process aspect of the invention (see above).
(54) The second separator 6 may be selected from one of (or a combination thereof): a cake filter, where a filter cake is provided by sludge flocs being deposited on a filtration cake support being a porous member allowing liquid to flow through and arresting deflocculated sludge, a sock filter filtration, a membrane filter, a granular media filter, such as sand filter, a mesh type band filter or disc filter
(55) as also disclosed in connection with the process aspect of the invention (see above).
(56) The filtration cake support is typically defined by a material having penetrations, such as a net with meshes, wherein the pore diameter of the penetrations is preferably in the range of 1 micron to 100 micron. The filtration cake support is preferably a net made from metal, such as stainless steel, or polymers.
(57) As disclosed herein, the first separator 2 may be configured for separating the received sludge mixed liquor 1 into two fractions the first fraction 4 containing sludge flocs, and the second fraction 5 containing deflocculated sludge. This means that all of the slugde mixed liquor 1 received from the tank is separated in such two fractions only. Similarly, the second separator 6 may be configured for separating the second fraction 5 into two fractions only, namely the third fraction 7, and the fourth fraction 8.
(58) As illustrated in
(59) As will be disclosed below in connection with
(60) Similarly, a stirrer may be arranged in the tank 15 or in each of the tanks 15a and 15b.
(61) Reference is made to
(62) The first separator 2 is fluidic connected by a pipe to the second tank 15 to feed the first fraction 4 into the second tank 15b, and to the second separator 6 to feed the second fraction into the second separator 6. In the embodiment shown in
(63) The second separator 6 is fluidic connected by a pipe to the second tank 15b to feed the third fraction 7 into the second tank 15b.
(64) Thus, by the arrangement of the first and the second separator in a configuration where sludge mixed liquor 1 is taken from the first tank 15a, freed from deflocculated flocs and introduced into the second tank 15b, the quality of the sludge mixed liquor 1 is improved, which improved sludge mixed liquor is introduced into the second tank 15b. The content of the second tank 15b is furthermore filtered by the filter 12 e.g. to extract the filtrate, i.e. the effluent of the MBR system.
(65) To make, further, use of improved sludge mixed liquor, the second tank 15b is fluidic connected, by a pipe for return of sludge mixed liquor 17 to the first tank 15a in order to feed at least a fraction of the sludge mixed liquor contained in the second tank 15b to the first tank 15a. Due to inter alia the filtering by filter 12, the fraction of sludge mixed liquor returned to the first tank typically has a higher content of sludge flocs compared to the content of sludge flocs in the first tank 15a.
(66) In the embodiment of
(67) The first separator 2 is also fluidic connected by a pipe to the non-divided void 18 to feed the first fraction 4 into the said non-divided void 18 and fluidic connected to the second separator 6 to feed the second fraction into the second separator 6 (as noted above, the first and the second separators 2, 6 are built in to a single unit in
(68) Further the second separator 6 is fluidic connected by a pipe to the non-divided void 18 to feed the third fraction 7 into the non-divided void 18.
(69) It is noted that also in this embodiment, one or both separators 2, 6 may be arranged inside the tank 15, that is inside the non-divided void 18.
(70) The filter 12 is typically arranged so that it filters: the sludge mixed liquor contained in the second tank 15b in embodiments having two or more tanks as illustrated in
(71) Again, the filter 12 may be arranged inside the tank 15 or outside the tank, and be fluidic connected to the relevant region of the tank 15 by suitable fluid connection such as pipes.
(72) A suitable filter 12 is found to be a microporous membrane filter, such as a microfiltration typically having a pores size of between 10 micron and 0.1 micron, and/or an ultrafiltration membrane typically having a pore size between 0.1 micron and 0.001 micron.
(73) As illustrated in
(74) Further, the device as illustrated in
(75) As disclosed herein a number of fractions, generally referenced below as fluid fractions, are produced. Although the process may be embodied as a batch process, it is generally preferred to operate the process as a continuous process in which waste water is continuously delivered to the tank 15. The fluid streams are selected so that:
Waste water infeed 10=Filtrate 11+Fourth Stream 8
Stream 3=First Stream 4+Third Stream 7+Fourth Stream 8
(76) However, since the fluid flow pattern inside the tank and in the separators are difficult to estimate precisely it may be necessary to project a running-in-phase where valve and pump settings are tuned to provide the desired result. This may even be necessary during normal operation of the process and device since the waste water may change composition on a regular basis calling for a different setting of the various control devices. In general, the device according to this invention takes over the function of wasting sludge from the system, so the speed of running the separators, and the resulting speed of removing solids with fraction/stream 8 needs to be adjusted to sludge production rate of the system (MLSS increase rate).
(77) Pumps and/or valves are typically provided in devices according to the invention to move the fluid around and in between the various components of the device.
(78) Although the present invention has been described in connection with the specified embodiments, it should not be construed as being in any way limited to the presented examples. The scope of the present invention is set out by the accompanying claim set. In the context of the claims, the terms “comprising” or “comprises” do not exclude other possible elements or steps. Also, the mentioning of references such as “a” or “an” etc. should not be construed as excluding a plurality. The use of reference signs in the claims with respect to elements indicated in the figures shall also not be construed as limiting the scope of the invention. Furthermore, individual features mentioned in different claims, may possibly be advantageously combined, and the mentioning of these features in different claims does not exclude that a combination of features is not possible and advantageous.
LIST OF REFERENCE SYMBOLS USED
(79) 1 sludge mixed liquor 2 Separating/separator 3 Fraction of sludge mixed liquor 4 First fraction containing flocculated sludge 5 Second fraction containing deflocculated sludge 6 Second separation 7 Third fraction 8 Fourth fraction 10 Waste water 11 Filtrate 12 Filtering/Filter 16 Tank (MBR) 16 Gas sparger 17 Return sludge mixed liquor 18 Non-divided void 19 Dividing wall