ROLL OF CLEANING FABRIC AND RELATED APPARATUS AND METHODS
20210292687 · 2021-09-23
Inventors
Cpc classification
B41P2235/24
PERFORMING OPERATIONS; TRANSPORTING
C11D3/30
CHEMISTRY; METALLURGY
C11D1/523
CHEMISTRY; METALLURGY
B41F35/00
PERFORMING OPERATIONS; TRANSPORTING
International classification
B41F35/00
PERFORMING OPERATIONS; TRANSPORTING
C11D1/52
CHEMISTRY; METALLURGY
C11D3/30
CHEMISTRY; METALLURGY
Abstract
A roll of cleaning fabric is used for cleaning printing cylinders of a printing system. The cleaning fabric (13) is impregnated with a cleaning composition containing an organic solvent and a cellulose solubilizer. The roll may be wound around a core (14) and inserted in a removable sealing bag (15) configured to seal around the roll (12) of cleaning fabric (13) in order to prevent the cleaning composition from evaporating before use.
Claims
1. A roll of cleaning fabric for cleaning printing cylinders of a printing system, said cleaning fabric being impregnated with a cleaning composition, wherein said cleaning composition comprises an organic solvent and a cellulose solubilizer.
2. The roll according to claim 1, wherein said cleaning composition comprises less than 10 wt % of water.
3. The roll according to claim 2, wherein said cleaning composition comprises less than 2 wt % of water.
4. The roll according to claim 1, wherein the cellulose solubilizer comprises an ethanol amine moiety.
5. The roll according to claim 4, wherein said ethanol amine moiety is an ethanolamide.
6. The roll according to claim 5, wherein said ethanolamide is coconut diethanolamide.
7. The roll according to claim 4, wherein said cellulose solubilizer comprising said ethanol amine moiety is an ethanolamine.
8. The roll according to claim 7, wherein said ethanolamine is triethanolamine.
9. The roll according to claim 1, wherein the cellulose solubilizer is a glycol ether.
10. The roll according to claim 1, wherein the cellulose solubilizer is a C.sub.2-C.sub.6 alkane diol.
11. The roll according to claim 10, wherein the C.sub.2-C.sub.6 alkane diol is ethylene glycol.
12. The roll according to claim 1, wherein the cellulose solubilizer is a hydrophilic tenside.
13. The roll according to claim 12, wherein the hydrophilic tenside is one of a super-wetting agent, an amphoteric betaine, an anionic organic sulphate and an amine oxide.
14. The roll according to claim 1, wherein the content of the cellulose solubilizer in the cleaning composition is between 0.05 and 20 wt %.
15. The roll according to claim 1, wherein the content of the organic solvent is between 80 and 99.9 wt %.
16. The roll according claim 1, wherein said cleaning fabric (13) is wrapped around a core (14) to form said roll (12).
17. The roll according claim 1, wherein the roll (12) is inserted in a removable sealing bag (15) configured to seal around said roll (12) of cleaning fabric (13) in order to prevent said cleaning composition from evaporating before use.
18. The roll according to claim 17, wherein said roll (12) of cleaning fabric (13) is vacuum packed in said sealing bag (15).
19.-28. (canceled)
29. The roll according to claim 14, wherein the content of the cellulose solubilizer in the cleaning composition is between 0.1 and 5 wt %.
30. The roll according to claim 15, wherein the content of the organic solvent is between 95 and 99.9 wt %.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0049] Embodiments of the invention will be described in the following; references being made to the appended diagrammatic drawings, which illustrate non-limiting examples of how the inventive concept can be reduced into practice.
[0050]
[0051]
[0052]
[0053]
[0054]
[0055]
DETAILED DESCRIPTION
[0056] With reference to
[0057] The set of inking rollers 5 is associated with an ink source 8 which provides the inking rollers 5 with ink. The set of damping rollers 6 is associated with a damping source, in this case a water bath 9, which provides the damping rollers 6 with water. The printing system 1 further comprises a cleaning machine or cleaning cassette 10 which houses a cleaning device or roll 12 with a cleaning fabric 13, also referred to as a cleaning cloth.
[0058] In
[0059]
[0060]
[0061]
[0062]
[0063] The printing work and cleaning of the printing system 1 will now be explained more in detail. With reference to
[0064] Depending on type and use, the printing system 1 needs to be cleaned more or less often in order to maintain a sufficient printing quality. Commonly in prior art printing systems, the cleaning process starts by spraying a liquid, most often water, which dissolves cellulose in the form of paper debris and other water soluble impurities which have adhered to the printing cylinders. Once the water soluble contaminants such as paper residues and the like have been removed, the cleaning cassette 10 can perform its cleaning. The cleaning composition which has impregnated the cleaning fabric 13 removes, inter alia, ink residues from the printing cylinders 2, 3, 4, 5.
[0065] Cleaning processes known in the art involve two separate steps. The first water washing step, where water is sprayed onto the blanket cylinder, can be time consuming and inefficient. Moreover, the spray devices and water tubes leading water to the spray device clog easily. Clogging in the spray devices and the tubes supplying the spray devices with water occurs due to contamination by paper residues, lime in the water, ink residues and other debris. These contaminating particles penetrates the spray openings of the devices and may also clog the internal cavities of the water tubes.
[0066] According to the present disclosure when cleaning the printing system 1, there is no need for a pre-washing step of spraying the blanket cylinder 3 with water with a spray device 17a, 17b to remove paper residues and other water soluble debris, since paper residues are dissolved by the cleaning composition of the present disclosure.
[0067] The cleaning composition of the present disclosure comprises at least one organic solvent to dilute and/or dissolve ink residues and at least one cellulose solubilizer configured to dissolve cellulosic material such as paper debris from the cylinders 2, 3, 4, 5. The water spray step is thus no longer needed, meaning that the spray device 17a, 17b can be omitted. The cellulosic solubilizer aims to dissolve cellulosic paper debris which is water soluble. However, if water is added to the cleaning composition, the water will evaporate and the cleaning composition will lose its ability to dissolve water soluble impurities. Replacing the water spray step with the addition of water in the cleaning composition is hence not an option. Instead, the cellulosic solubilizer should be a low volatile organic compound (low VOC). The possible groups of compounds presented below from which the cellulosic solubilizer can be selected are all low VOCs.
[0068] The concentration of the cellulosic solubilizer in the cleaning composition is between 0.05 to 20 wt %, preferably between 0.06 and 15 wt %, more preferably between 0.075 to 10 wt % and most preferably between 0.1 and 5 wt %. The concentration of the cellulosic solubilizer has to be balanced against the concentration of the organic solvent(s). If the concentration of the cellulosic solubilizer is higher than 20 wt %, the ink solubility of the cleaning composition is decreased. If the concentration of the solubilizer is too low, i.e. lower than 0.05 wt %, the cleaning composition will not dissolve and remove paper residues in a favourable way.
[0069] The cellulosic solubilizer may be any compound selected from the group consisting of compounds comprising an ethanol amine moiety, glycol ethers, C.sub.2-C.sub.6 alkane diols, hydrophilic tensides, super-wetting agents, or a combination of such compounds.
[0070] Preferable hydrophilic tensides are so called super-wetting agents, such as an amphoteric betaine, an anionic organic sulphate or an amine oxide. These super-wetting agents are powerful wetting agents, meaning that a low concentration is enough to effectively dissolve cellulosic material. The concentration of the super-wetting agent in the cleaning composition may be as low as 0.1 wt %. Other hydrophilic tensides may also be used in the cleaning composition as the cellulosic solubilizer.
[0071] The C.sub.2-C.sub.6 alkane diol may be for instance propylene glycol, tetramethylene diol (butane-1,4-diol) or ethylene glycol. Preferably the C.sub.2-C.sub.6 alkane diol is ethylene glycol.
[0072] Examples of glycol ethers which may be used as the cellulosic solubilizer are for instance ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monoisopropyl ether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, ethylene glycol monobenzyl ether, propylene glycol methyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol mono-n-butyl ether, dipropyleneglycol methyl ether, phenoxyethanol, pentaethylene glycol monododecyl ether and alkylene polyglycol ether.
[0073] The ethanol amine moiety is herein defined as a —(N(CH.sub.2CH.sub.2OH))— moiety and as shown in Formula I.
##STR00003##
[0074] The compound comprising an ethanol amine moiety may be for instance an alkanolamine or alkanolamide, preferably an ethanolamine or ethanolamide, most preferred triethanolamine or coconut diethanolamide.
[0075] It is appreciated that a combination of the different cellulose solubilizers presented herein can be used in the cleaning composition according to the present disclosure.
[0076] The organic solvent component of the cleaning composition may be for instance distillates (petroleum, hydrotreated light) D100, isooctyl laurate, 2-ethyl hexyl laurate, a propylene glycol oligomer, an unsaturated fatty acid, an ester, such as a fatty acid ester, preferably a saturated fatty acid alkyl ester, a plasticizer, a petroleum-based solvent such as naphthene or paraffin, or a combination thereof, or any other organic solvent dissolving ink residues.
[0077] The plasticizer decreases the swelling of the rubber sheet 3′. A preferred plasticizer is diisononyl phthalate (DINP), which also improves the cleaning performance of the cleaning composition and reduces the amount of chemical residues on the blanket cylinder 3 after washing.
[0078] The propylene glycol oligomer may for instance be tri(propylene glycol) propyl ether, tri(propylene glycol) methyl ether, tri(propylene glycol) butyl ether, propylene glycol propyl ether, tripropylene glycol, propylene glycol diacetate, ethylene glycol monophenyl ether, di(propylene glycol) propyl ether, di(propylene glycol) methyl ether, di(propylene glycol) dimethyl ether, or di(propylene glycol) butyl ether.
[0079] The fatty acid may for instance be myristoleic acid, vaccenic acid, elaidic acid, linoelaidic acid, linoleic acid, palmitoleic acid, sapienic acid, oleic acid, arachidonic acid, eicosapentaenoic acid, erucic acid or docosahexaenoic acid.
[0080] The organic solvents used in the cleaning composition are low VOCs to avoid unwanted evaporation of the solvents.
[0081] The concentration of the organic solvent is in the cleaning composition is between 80 and 99.05 wt %, preferably between 85 and 99.04 wt %, more preferably between 90 and 99.025 wt % and most preferably between 95 and 99.9 wt %.
[0082] Other possible compounds comprised in the cleaning liquid with different properties may be e.g. aliphatic hydrocarbons for cleaning power, vegetable esters for cleaning power and reduction of evaporation, corrosion inhibitors for preventing corrosion and emulsifiers for emulsification with water.
[0083] In one embodiment, the cleaning composition comprises an unsaturated fatty acid, a propylene glycol oligomer and a cellulosic solubilizer, preferably coconut diethanolamide.
[0084] In a further embodiment, the cleaning composition comprises distillates (petroleum, hydrotreated light) D100, isooctyl laurate, 2-ethyl hexyl laurate and a cellulosic solubilizer, preferably coconut diethanolamide.
[0085] In another embodiment, the cleaning composition comprises an ester, preferably a saturated fatty acid alkyl ester, a plasticizer, preferably diisononyl phthalate (DINP), and a cellulosic solubilizer, preferably coconut diethanolamide. Preferred weight concentrations of the ester, the plasticizer and the cellulosic solubilizer in this embodiment is 30 to 50 wt % of the ester, 40 to 60 wt % of the plasticizer and 1 to 5 wt % of the cellulosic solubilizer. Most preferably, the cleaning composition comprises about 40 wt % of the ester, about 57 wt % of the plasticizer DINP and about 3 wt % of the coconut diethanolamide.
[0086] In still a further embodiment, the cleaning composition comprises a petroleum-based solvent such as naphthene or paraffin and a cellulosic solubilizer, preferably coconut diethanolamide.
[0087] The cleaning composition further comprises less than 2 wt % of water, such as less than 1 wt % of water or such as less than 0.5 wt % of water. A higher content of water than 2 wt % will cause the cleaning composition to evaporate and will dilute the concentration of the cellulosic solubilizer and the organic solvent, which affects the ability of the cleaning composition to dissolve ink and paper debris from the rubber sheet 3′.
[0088] The content of the organic solvent and the cellulosic solubilizer in the cleaning composition according to the present disclosure is 98 wt % or more.
[0089] Pre-packed cleaning rolls of basic structure are known in the art per se and are described for instance in the publication U.S. Pat. No. 5,368,157A.
[0090] According to the present disclosure, the cleaning fabric 13 is a liquid or solvent absorbable material, such as a non-woven material, and is adapted to be impregnated or soaked with the cleaning composition of the present disclosure before starting a cleaning process. Preferably, the cleaning fabric 13 is impregnated or soaked with the cleaning liquid of the present disclosure before being packed and stored or transported, i.e. it can be impregnated or soaked long before it is to be used in a cleaning process. Further, the cleaning fabric 13 can be impregnated or soaked either before or after being wrapped around the core 14.
[0091] The cleaning roll 12 shown in
[0092] Before the cleaning process begins, the cleaning roll 12 is taken out of its package or bag 15, as shown in
[0093] The cleaning cassette 10 is then moved from an idle position, in which the cleaning fabric 13 is not in contact with the rubber sheet 3′ of the cylinder 3, to an active position in contact with said rubber sheet 3′ of the cylinder 3. The cleaning cassette 10 may also be brought into contact with other cylinders of the printing system, such as the impression cylinder 2. The cylinders 2, 3, 4, 5, 6 are rotated in the opposite direction of that when using the printing system for printing. The cleaning composition will thus be transferred from the cleaning fabric 13 onto the rubber sheet 3′ of the cylinder 3 and further onto the remaining cylinders 2, 4, 5, 6 of the printing system 1.
[0094] The cellulosic solubilizer comprised in the cleaning composition impregnated in the cleaning fabric 13 will hence dissolve and remove paper residues and other water soluble impurities, for instance calcium carbonate. Thus, there is no need to spray the rubber sheet 3′ with water before cleaning the system 1 with the cleaning cassette 10 and the spray bars 17a, 17b can be omitted.
[0095] Other components in the cleaning composition such as the organic solvent(s) will dissolve and remove for instance ink residues on the cylinders 2, 3, 4, 5.
[0096] Once the cleaning process has finished, the printing system 1 will rotate the cylinders 2, 3, 4, 5 and damping rollers 6 in the printing direction. This is the opposite direction of that used during the washing procedure. The damping rollers 6 will transfer water from the water bath 9 to the printing cylinders 2, 3, 4, 5 and the cleaning composition which has been used to clean the printing cylinders 2, 3, 4, 5 will be diluted and eventually removed from the printing system 1.
[0097] The pre-packed roll 12 comprising the cleaning composition of the present disclosure can be used in already functioning printing systems 1 which uses a cleaning cassette 10 as described and which has a spray device 17a, 17b installed. The spray device 17a, 17b can simply be switched off or closed, and the new pre-packed roll 12 can be installed on the mounting means 11 will replace the spray step of the washing process.
[0098] In an embodiment (not shown), the cleaning composition may be sprayed onto a dry cleaning fabric before the cleaning process is started. The cleaning process can then be performed as described above without the need for a water spray step to dissolve the paper residues on the blanket cylinder.
[0099] In yet another embodiment (not shown), the cleaning composition may be sprayed directly onto the blanket cylinder. The cleaning process can then be performed as described above without the need for a water spray step to dissolve the paper residues on the blanket cylinder.
EXPERIMENTS
[0100] The inventor has surprisingly found that the addition of a cellulose solubilizer to a cleaning composition is an effective substitute to the commonly used first washing step of spraying water on to the rubber sheets 3′ of the printing cylinder 3. The cellulosic solubilizer is selected from the group consisting of a hydrophilic tenside, a super-wettability agent, a C.sub.2-C.sub.6 alkane diol, a glycol ether, a compound comprising an ethanol amine moiety or a combination thereof. An exemplary cleaning composition comprising a cellulosic solubilizer is listed in table 1a.
[0101] The new cleaning compositions comprising the cellulose solubilizer meet the requirements of a cleaning composition which is illustrated by the experiments presented in the following. Favourable properties of a cleaning composition are ink solubility, low swelling of the rubber sheet 3′ when in contact with the cleaning composition, and the dissolution of cellulosic paper residues from the rubber sheet 3′. The results are presented below in tables 2 and 3 and shown in
Example 1
[0102] The three organic solvents destillates D100, isooctyl laurate and 2-ethyl hexyl laurate make up the cleaning composition A (CC.sub.A) shown in Table 1 below.
[0103] An example of a cleaning composition according to an embodiment is presented below in Table 1a. The exemplary cleaning composition according to an embodiment of the present disclosure comprises three organic solvents (destillates D100, isooctyl laurate, 2-ethyl hexyl laurate) and a cellulosic solubilizer (coconut diethanol amide).
[0104] The concentration of the three organic solvents is when summarized 95 wt %. The cellulosic solubilizer (CS) in the presented embodiment is coconut diethanolamide. The concentration of the coconut diethanolamide is 5 wt %.
TABLE-US-00001 TABLE 1 the composition of the cleaning composition A (CC.sub.A) Chemical ingredient Concentration (wt %) CC.sub.A Distillates (petroleum, hydrotreated light) 75 D100 Isooctyl laurate/2-Ethyl hexyl laurate 25
TABLE-US-00002 TABLE 1a the composition of a cleaning composition according to an embodiment of the present disclosure comprising the three organic solvents from CC.sub.A and a cellulosic solubilizer (CS). Concentration Chemical ingredient Effect (wt %) CC.sub.A Distillates (petroleum, Solvent - dissolves ink 75 hydrotreated light) residues D100 Isooctyl laurate Solvent - dissolves ink 10 residues 2-Ethyl hexyl laurate Solvent - dissolves ink 10 residues CS Coconut Cellulosic solubilizer - 5 diethanolamide dissolves paper residues
Experiment 1—Swellability of the Rubber Sheet 3′
[0105] When using cleaning compositions in a printing system, one of the requirements of the cleaning composition is that it should not cause the rubber sheet 3′ on the blanket cylinder 3 to swell. If the rubber sheet 3′ swells too much, the pressure between the rubber sheet 3′, on the blanket cylinder 3, and the impression cylinder 2 becomes too high, which results in e.g. poor quality of the prints.
[0106] The test is performed by taking a portion of the rubber material used for the rubber sheet in the printing system and placing it on a flat surface (not shown). The thickness of the rubber material is approximately 2 mm. A hollow beaker with no bottom is placed standing on top of the rubber sheet material and filled with the cleaning composition which is to be tested (not shown). The cleaning composition is left in the beaker at a specified temperature (here 40° C.) during a predetermined amount of time (here 24 h). The thickness of the rubber sheet material is measured outside the beaker and acts as a reference height. The height of the area of the rubber sheet material which has been in contact with the cleaning composition is also measured. Finally, the difference between the two heights are calculated as a percentage of the reference height.
[0107] The test results for the cleaning composition CC.sub.A according to table 1, and for the a cleaning composition according to the embodiment of Table 1a are presented below in Table 2. The test results for another cleaning composition CC.sub.B and CC.sub.B with the addition of a cellulosic solubilizer (coconut diethanolamide) are also presented below in Table 2. The cleaning composition CC.sub.B comprises an unsaturated fatty acid and a propylene glycol oligomer.
[0108] The cleaning compositions remained in contact with the rubber sheet material for 24 hours at 40° C. First, the cleaning compositions CC.sub.A and CC.sub.B were tested without the addition of a cellulosic solubilizer. The swellability of the rubber sheet material then corresponded to 1.42 and 1.97 respectively, as can be seen from Table 2. After the addition of 5% of coconut diethanolamide to CC.sub.A the swellability increased only slightly to 1.59% and after the addition of 5% of coconut diethanolamide to CC.sub.B the swellability increased to 2.59%. Both these values (1.59 and 2.59) are below the threshold value for an approved swellability of the rubber sheet material.
TABLE-US-00003 TABLE 2 the test results from the swelling test. Swelling test rubber blanket (24 h, 40° C.) % increased height CC.sub.A 1.42 CC.sub.A + 5% coconut diethanolamide 1.59 CC.sub.B 1.97 CC.sub.B + 5% coconut diethanolamide 2.59
Experiment 2—Ink Solubility
[0109] The addition of the water substitute should not decrease the ink solubility of the cleaning composition. If the ink solubility decreases, there is a risk that the cleaning composition will not be able to remove the ink residues from the printing cylinders efficiently during the cleaning process.
[0110] The result from the ink solubility test is shown in
[0111] When performing the test, a substrate covered with red ink is lowered into the beaker containing a cleaning composition. The substrate is then lifted out of the beaker and transferred to a paper towel 18. The solubility is visually evaluated by observing the amount of ink on the substrate that has been dissolved by the cleaning composition.
[0112] In
[0113] To the right in
Experiment 3—Paper Residue Wash Test
[0114] To evaluate the dissolution of paper residues from the rubber sheet material, a paper residue and ink wash test was performed.
[0115] An unwashed rubber sheet blanket 19 of the same type used as the rubber sheet 3′, covered with ink and paper residues, was placed on a flat surface. Cleaning compositions with different concentrations of a cellulosic solubilizer (coconut diethanolamide and triethanolamine) were applied on different cloths C1, C2, C3, C4, C5 which were subsequently placed into contact with the dirty rubber sheet blanket 19. The cloths C1, C2, C3, C4, C5 were then manually dragged over the surface five times.
[0116] The result shown in
TABLE-US-00004 TABLE 3 the table presents the five tests performed in the paper residue wash test. Wash test Cellulosic solubilizer Concentration (wt %) WT1 Coconut diethanolamide 5 WT2 Control (no water substitute used) — WT3 Triethanolamine 5 WT4 Coconut diethanolamide 10 WT5 Coconut diethanolamide 1
[0117] The result indicates that a concentration of the cellulosic solubilizer of 5 wt % gave the best result. The results from test WT1 and WT3 shows a darker cloth (C1 and C3 respectively) after the repeated wash of the rubber sheet 19 and hence, they have dissolved more ink and paper residues than the other cloths. The control test WT2 has the cloth C2 with the least dark colour and has hence dissolved least ink and paper residues of all cloths C1, C2, C3, C4, C5. Thus, a cleaning composition according to the present disclosure performs better in a wash test.
[0118] Finally, although the inventive concept has been described above with reference to specific embodiments, it is not intended to be limited to the specific form set forth herein. Rather, the invention is limited only by the accompanying claims and other embodiments than the specific above are equally possible within the scope of these appended claims.