Method for producing optoelectric semiconductor components, and optoelectronic semiconductor component

11127877 · 2021-09-21

Assignee

Inventors

Cpc classification

International classification

Abstract

The application concerns a method of manufacturing optoelectronic semiconductor components (1) comprising the following steps: A) Growing a semiconductor layer sequence (3) for generating radiation onto a growth substrate (2), B) Structuring the semiconductor layer sequence (3) into emitter strands (11) so that the semiconductor layer sequence (3) is removed in gaps (12) between adjacent emitter strands (11), C) Applying a passivation layer (4), the semiconductor layer sequence (3) at waveguide contacts (51) remote from the growth substrate (2) and the gaps (12) remaining at least partially free, D) Producing at least one metal layer (50), which extends from the waveguide contacts (51) into the gaps (12), E) Replacing the growth substrate (2) with a carrier (6), F) Making vias (53) in the carrier (6) so that the metal layer (50) and underside contacts (52) of the semiconductor layer sequence (3) facing the carrier (6) are electrically contacted, and removing the carrier (6) between at least some of the emitter strands (11) and between emitter units (13) following one another along the emitter strands (11), and G) Breaking the semiconductor layer sequence (3) between the emitter units (13), so that facets (31) are formed.

Claims

1. A method of manufacturing optoelectronic semiconductor components comprising the steps: A) growing a semiconductor layer sequence for generating radiation onto a growth substrate, B) structuring the semiconductor layer sequence into emitter strands so that the semiconductor layer sequence is removed in gaps between adjacent emitter strands, C) applying a passivation layer, the semiconductor layer sequence at waveguide contacts remote from the growth substrate and the gaps remaining at least partially free, D) producing at least one metal layer, which extends from the waveguide contacts into the gaps, E) replacing the growth substrate with a carrier, F) making vias in the carrier so that the metal layer and underside contacts of the semiconductor layer sequence facing the carrier are electrically contacted, and removing the carrier between at least some of the emitter strands and between emitter units following one another along the emitter strands, and G) breaking the semiconductor layer sequence between the emitter units, so that facets are formed.

2. The method according to claim 1, wherein the semiconductor components are edge-emitting lasers the passivation layer is applied directly to the semiconductor layer sequence and the metal layer is applied directly to the passivation layer, and the metal layer reproduces the side surfaces of the emitter strands.

3. The method according to claim 1, in which at least a part of the facets is configured for radiation extraction from the finished semiconductor components, wherein the facets after step G) project beyond the associated carrier by at least 2 μm and by at most 50 μm.

4. The method according to claim 1, in which, before step C), strip waveguides are produced at a side of the growth substrate remote from the semiconductor layer sequence, the strip waveguides being configured for one-dimensional radiation guiding in a direction parallel to the emitter strands, wherein the waveguide contacts are each located at the associated strip waveguide.

5. The method according to claim 1, in which a side of the semiconductor layer sequence remote from the growth substrate is planar in a region of a current feeding width of an active zone of the semiconductor layer sequence, so that the finished semiconductor components are gain-guided lasers.

6. The method according to claim 1, where between steps D) and E) a filling layer is produced which fills the gaps so that a side of the filling layer remote from the growth substrate is planar, and subsequently an auxiliary carrier is attached to the filling layer.

7. The method according to claim 1 one of the previous claims, in which an etch stop layer is produced between the semiconductor layer sequence and the growth substrate before or with step A), wherein the etch stop layer is removed from the gaps in step B) and remaining residues of the etch stop layer are removed in step E) between detaching the growth substrate and attaching the carrier.

8. The method according to claim 7, wherein, after removing the residues of the etch stop layer and before attaching the carrier at least one contact layer is produced on each of the underside contacts, and the contact layers are covered with a planarization layer.

9. The method according to claim 8, wherein the carrier is directly and areally attached to the planarization layer by direct bonding and subsequently the auxiliary carrier is removed.

10. The method according to claim 1, in which the metal layer extends on either side of the emitter strands from the respective waveguide contacts into the adjacent gaps, so that the emitter strands are symmetrically surrounded by the metal layer in the region of the semiconductor layer sequence as seen in cross-section.

11. The method according to claim 1, in which exactly two of the vias are created per emitter unit in the direction perpendicular to the emitter strands.

12. The method according to claim 1, in which three of the vias are created per emitter unit in the direction perpendicular to the emitter strands, the via for the underside contacts being located in each case centrally between the two vias for the waveguide contacts.

13. The method according to claim 1, in which only one via is provided per emitter unit in the direction parallel to the emitter strands for each bottom contact and for each waveguide contact.

14. The method according to claim 1, in which several of the vias are provided per emitter unit in the direction parallel to the emitter strands for each bottom contact and/or for each waveguide contact.

15. The method according to claim 14, wherein along the emitter strands per emitter unit the metal layer and/or the waveguide contacts are divided into a plurality of subregions which are electrically controllable independently of one another.

16. The method according to claim 1, in which the metal layer extends along the emitter strands to at least 90% along the emitter units each.

17. The method according to claim 1, in which the semiconductor layer sequence is based on InAlGaAs, the growth substrate is a GaAs substrate and the carrier is a silicon substrate.

18. The method according to claim 1, in which several of the emitter units are electrically connected in series in a direction perpendicular to the emitter strands, wherein only between emitter units connected in series the carrier remains between adjacent emitter strands in step F).

19. A surface-mountable optoelectronic semiconductor component comprising: a carrier having a plurality of electrical vias therein, a semiconductor layer sequence on the carrier with an active zone for generating radiation, a passivation layer which completely covers side surfaces of the semiconductor layer sequence and which leaves a waveguide contact remote from the carrier at least partially free, at least one metal layer extending from the waveguide contact to the carrier, wherein the vias electrically contact the metal layer and an underside contact of the semiconductor layer sequence facing the carrier, a facet of the semiconductor layer sequence for radiation extraction projects beyond the carrier, and the metal layer reproduces the side surfaces so that an average distance between the metal layer and the semiconductor layer sequence is at most 1 μm.

Description

(1) In the Figures:

(2) FIGS. 1A to 1I show schematic sectional views of method steps of a method described here,

(3) FIG. 1J show a schematic sectional view of a via for optoelectronic semiconductor components described here,

(4) FIG. 1K show a schematic sectional view of a method step of a method described here,

(5) FIG. 1L shows a schematic top view and two corresponding sectional views of a method step of a method described here,

(6) FIG. 1M shows a schematic top view of a method step of a method described here,

(7) FIG. 1N shows a schematic sectional view of a method step of a method described here,

(8) FIG. 2 shows a schematic sectional view of a variation of a manufacturing method,

(9) FIG. 3 shows a schematic sectional view of an exemplary embodiment of an optoelectronic semiconductor component described here,

(10) FIG. 4 shows a schematic sectional view of a variation of a semiconductor component,

(11) FIGS. 5 to 8 show schematic sectional views of exemplary embodiments of optoelectronic semiconductor components described here, and

(12) FIG. 9 shows schematic top views of exemplary embodiments of optoelectronic semiconductor components described here.

(13) In FIG. 1 an exemplary embodiment of a manufacturing method for optoelectronic semiconductor components 1 is illustrated.

(14) A growth substrate 2 is provided as shown in FIG. 1A. The growth substrate 2 is a GaAs substrate, for instance.

(15) Optionally, an etch stop layer 22 is provided on the growth substrate 2. For example, the etch stop layer 22 is made of AlGaAs with an aluminum content of 30%.

(16) A semiconductor layer sequence 3 is epitaxially grown on the etch stop layer 22. The semiconductor layer sequence 3 comprises an active zone 33 and is based on the AlInGaAs material system, for example.

(17) Optionally, several strip waveguides 35 are produced by etching on a side of the semiconductor layer sequence 3 that is remote from the growth substrate 2. The strip waveguides 35 extend in the direction perpendicular to the drawing plane in FIG. 1A, as well as resonator axes defined by the strip waveguides 35.

(18) In the method step of FIG. 1B, the semiconductor layer sequence 3 is structured into emitter strands 11 extending perpendicular to the drawing plane. Each of the emitter strands 11 preferably has one of the strip waveguides 35. Gaps 12 are formed between adjacent emitter strands 11, in which the growth substrate 2 or, in contrast to FIG. 1B, the etch stop layer 22 is exposed.

(19) A height H1 of the semiconductor layer sequence 3 together with the etch stop layer 22 is about 3 μm. For example, a height H2 of strip waveguide 35 is 0.5 μm. The active zone 33 can be located below the strip waveguide 35. In particular, a thickness of the etch stop layer 22 is at least 100 nm and/or at most 1000 nm.

(20) A distance D1 between adjacent emitter strands 11 is preferably at least 20 μm and/or at most 100 μm, for example around 50 μm, and is thus comparatively large. A width D2 of emitter strands 11 is preferably at least 100 μm.

(21) FIG. 1C illustrates that a passivation layer 4 is produced. The passivation layer 4 is made of silicon dioxide, for example, and has a thickness of between 100 nm and 500 nm in particular. The comparatively thin passivation layer 4 leaves the growth substrate 2 free in the gaps 12 in places. The strip waveguide 35 is also free of the passivation layer 4, so that a waveguide contact 51 is formed there on a semiconductor contact layer.

(22) As shown in FIG. 1D, metal layers 50 are produced, which are located on the passivation layer 4 and on the waveguide contacts 51. The left side of FIG. 1D shows that several metal layers 50a, 50b, 50c are present. The metal layer 50a is restricted to the waveguide contact 51. The metal layer 50a, for example, is a platinum layer. The remaining metal layers 50b, 50c are congruent with each other from the strip waveguide 35 up to the gaps 12. The metal layers 50b, 50c are for example made of titanium, platinum, palladium or gold. In contrast, in FIG. 1D, right-hand side, there is only a single metal layer 50. The configuration in the left half of FIG. 1D is preferred.

(23) To avoid electrical short circuits, the metal layer 50 does not extend continuously over the emitter strands 11. A distance D4 between the metal layers 50 of adjacent emitter strands 11 is preferably at least 2 μm or 5 μm and/or at most 20 μm or 10 μm. A width D3, within which the metal layer 50 is in contact with the growth substrate 2, is preferably at least 10 μm and/or at most 40 μm. A thickness of the metal layers 50a, 50b, 50c together or of the metal layer 50 is for example at least 0.3 μm and/or at most 5 μm.

(24) In the step of FIG. 1E a filler layer 70 is produced, for example from silicon dioxide. A planarization is achieved via the filling layer 70. A height H3, with which the filling layer 70 protrudes above the metal layer 50, is preferably at least 0.2 μm or 0.5 μm and/or at most 2 μm or 1 μm.

(25) For example, direct bonding is used to areally apply an auxiliary carrier 71, especially made of silicon, to the filling layer 70.

(26) In FIG. 1F the growth substrate 2 is removed. The growth substrate 2 is preferably removed by grinding and wet chemical etching, with etch stop layer 22 preferably stopping etching. After removing the growth substrate 2, the etch stop layer 22 can also be removed. Alternatively, the etch stop layer 22 can remain on the remaining semiconductor layer sequence 3.

(27) In this way, one bottom contact 52 is formed opposite each waveguide contact 51. The passivation layer 4 can overhang the underside contacts 52 in the direction away from the waveguide contacts 51.

(28) In the step of FIG. 1G, a contact layer 54 is created at each underside contact 52. The contact layer 54 can be a single layer, see the left side in FIG. 1G, or, preferably, a stack of layers, see the right side in FIG. 1G. The contact layer 54 is preferably a metallic layer or stack of metallic layers.

(29) Subsequently, a planarization layer 73 is applied, which covers the contact layer 54 as well as the passivation layer 4 and also the metal layer 50 completely and in planar manner. The planarization layer 73 is electrically insulating and made of silicon dioxide, for example.

(30) A carrier 6 is then applied, see FIG. 1H. The carrier 6 is preferably attached to the planarization layer 73 by direct bonding. Carrier 6 is preferably a doped or undoped silicon carrier. After an optional thinning process, the carrier 6 has a thickness between 60 μm and 250 μm, for example.

(31) According to FIG. 1I, several electrical vias 53 are created through the carrier 6. Via the vias 53 the metal layer 50 and thus the waveguide contacts 51 are electrically contacted. On the other hand, the contact layers 54 are electrically connected to the underside contacts 52. The vias 53 also form electrical contact areas 55 for external electrical contacting.

(32) The auxiliary carrier may already have been removed in the step of FIG. 1I or, in contrast to the illustration, may still be present.

(33) FIG. 1J illustrates an example of one of the vias 53 in more detail. Electrical insulation 56 is present in particular as a cylinder jacket, for example made of silicon dioxide. A thickness of the insulation 76, for example, is between 10 nm and 500 nm, preferably around 100 nm. Inside the insulation 76, a first seed layer 77 is produced, for example by sputtering or CVD (chemical vapor deposition). The first seed layer 77 is for example made of tungsten, tantalum, titanium, titanium nitride, tantalum nitride, copper or titanium tungsten nitride.

(34) Starting from the first seed layer 77, a filling 78 is produced, for example by electroplating or CVD. The filling 78 can fill the area within the insulation 76 completely or only partially, especially in the form of a cylinder jacket. The filling 78 is for example made of tungsten, copper or nickel.

(35) Correspondingly, a second seed layer 79 is produced perpendicular to it, to which the electrical contact surfaces 55 are applied. The finished semiconductor component 1 is electrically contactable externally via the contact surfaces 55.

(36) FIG. 1K illustrates that an expansion film 8 is applied to the filling layer 70.

(37) FIG. 1L illustrates a top view of contact pads 55 and, marked by arrows and dashed lines, two corresponding sectional views. The support 6 is removed along grid lines. This defines individual emitter units 13. For each emitter unit 13, for example, there are two of the contact areas 55.

(38) Thus, the emitter strands 11, which are separated from the gaps 12, are each divided into several of the emitter units 13 in the longitudinal direction. The emitter strands 11 as shown in FIG. 1L still run continuously from left to right, as do the gaps 12, i.e. parallel to the resonator axes 37 of the semiconductor components 1. This means that the semiconductor layer sequence 3 is not yet subdivided in the area of the emitter strands 11 as shown in FIG. 1L. This can be seen in the sectional view in FIG. 1L at the top right. The sectional view in FIG. 1L top left shows that the carrier 6 is divided between adjacent emitter strings 11 in the area of the gaps 12. This creates a large number of, for example, rectangular subregions of carrier 6, one subregion for each semiconductor component 1.

(39) Subsequently, a singulation into the semiconductor components 1 takes place via breaking, so that the emitter strands 11 are divided into the emitter units 13. Furthermore, expansion takes place via the expansion foil 8, see FIG. 1M.

(40) Breaking is explained in FIG. 1N in more detail. Along the emitter strands 11, a tool such as a breaking blade 85 is placed between the subareas of the carrier 6 for the emitter units 13 which are still connected, thus creating facets 31 by means of breaking.

(41) Because the carrier 6 was previously removed in the area of the facets 31, the semiconductor layer sequence 3 at the facets 31 protrudes above the respective associated carrier 6. A projection E, for example, is about 5 μm. Preferably, the metal layer 50 and the contact layers 54 not shown in FIG. 1N are also set back from the facets 51, for example by at least 1 μm or 2 μm and/or by at most 10 μm or 3 μm. In addition, the contact surfaces 55 do not extend as far as the facets 31.

(42) A variation is shown in FIG. 2. As shown in FIG. 2, breaking is done with tool 85 when the growth substrate 2 and metallizations 65 are still present. This means that during the method, as illustrated in connection with FIG. 2, the growth substrate 2 and the metallizations 65 must also be broken up. This means increased effort and leads to a risk of the greatest scrap when creating the facets.

(43) FIG. 3 illustrates a finished semiconductor component 1 in mounted condition on a mounting platform 9. The semiconductor component 1 is surface-mountable and connected without bonding wires.

(44) In contrast, a bond wire 91 is required for the variation of FIG. 4 in order to achieve the electrical contact on the mounting platform 9.

(45) In the exemplary embodiment of FIG. 5, several of the emitter units 13 are monolithically integrated in the filling layer and on the continuous carrier 6. The semiconductor component 1 thus comprises several of the emitter units 13. The individual emitter units 13 can be contacted electrically independently of one another via the vias 53 and the contact areas 55. Between adjacent emitter units 11 are the gaps 12, which are filled with the filling material 70.

(46) In contrast, in FIG. 6, several of the semiconductor components 1, as shown in FIG. 3, are individually and in a space saving manner mounted on the mounting platform 9.

(47) FIG. 7 illustrates that the emitter units 13 are electrically connected in series via contact pads 55b, which extend between adjacent emitter units 13. Anode contacts and cathode contacts are formed by the edge contact areas 55a, 55c.

(48) In contrast, an electrical parallel connection can be achieved, for example, by ensuring that the metal layer 50 extends continuously over all emitter areas 13 and that the vias 53, 55 are designed accordingly.

(49) In the previous exemplary embodiments, only one of the vias 53 is present along the emitter strands 11 per emitter unit 13, see also FIG. 1N. Furthermore, in the transverse direction, perpendicular to the emitter strings 11, there is also only one via 53 each for the underside contact 52 and the waveguide contact 51, so that as shown in FIG. 6 there are exactly two vias per emitter unit 13 in the transverse direction. This configuration is not mandatory. For example, there may be two vias per emitter unit 13 in the transverse direction for the metal layer 50, see FIG. 8A. The outer vias 53 and the metal layer 50 are preferably arranged symmetrically to the semiconductor layer sequence 3 with the strip waveguide 35.

(50) In the previous exemplary embodiments, semiconductor component 1 is an edge-emitting ridge waveguide laser in each case. This is not absolutely necessary, see FIG. 8B. Thus the semiconductor component 1 can also be designed as a weekly guided laser without ridge waveguide.

(51) The type of contacting shown in connection with FIGS. 8A and 8B can also be used accordingly in all other exemplary embodiments.

(52) FIG. 9 illustrates various configurations for the vias 53 and the electrical contact areas 55. These configurations can be used in the same way for the exemplary embodiments in FIGS. 1 to 8.

(53) As shown in FIG. 9A, there are several vias 53 along the resonator axes 37, i.e. along the emitter strands 11 and perpendicular to the facets 31. This applies to both contact areas 55.

(54) In contrast, see FIG. 9B, the vias 53 are not approximately circular when viewed from above, but are elongated. In this case, for example, exactly one of the vias 53 is present per contact area 55, but it extends along the resonator axis 37 over the majority of the contact areas 55.

(55) In FIG. 9C the contact area 55 for the waveguide contact 51 is divided into several subregions 56. The metal layer, not shown in FIG. 9C, can also be divided accordingly. For example, one of the vias 53 is present for each subregion 56. This allows the semiconductor layer sequence 3 along the resonator axis 37 to be controlled independently of each other in the subregions 56.

(56) FIG. 9D illustrates a configuration of the contact areas 55 in particular for the case that there are several connections for the metal layer 50 in transverse direction, compare FIG. 8A or FIG. 8B. For example, the contact area 55 for the two outer vias 53 for the waveguide contact 51 is U-shaped or, in contrast to the illustration in FIG. 9D, is also frame-shaped. The inner contact area 55, for example for the underside contact 52, can be rectangular.

(57) Unless otherwise indicated, the components shown in the figures follow each other, preferably in the order indicated. Layers not touching each other in the figures are preferably spaced apart. As far as lines are drawn parallel to each other, the corresponding areas are preferably also parallel to each other. Likewise, unless otherwise indicated, the relative positions of the drawn components to each other are correctly shown in the figures.

(58) The invention described here is not restricted to the description based on the exemplary embodiments. Rather, the invention encompasses any new feature and also any combination of features, which in particular comprises any combination of features in the claims, even if this feature or this combination itself is not explicitly specified in the claims or exemplary embodiments.

(59) This patent application claims the priority of the German patent application 10 2017 130 131.3, the disclosure content of which is hereby incorporated by reference.

LIST OF REFERENCES

(60) 1 optoelectronic semiconductor component 11 emitter strand 12 gap 13 emitter unit 2 growth substrate 22 etch stop layer 3 semiconductor layer sequence 30 side surface of the semiconductor layer sequence 31 facet 33 active zone 35 strip waveguide 37 resonator axis 4 passivation layer 50 metal layer 51 waveguide contact 52 underside contact 53 via 54 contact layer 55 electrical contact area 56 subregion 65 metallization 6 carrier 70 Filling layer 71 auxiliary carriers 73 planarization layer 74 electrical insulation layer 76 electrical insulation 77 first seed layer 78 filling 79 second seed layer 8 expansion foil 85 breaking blade 9 mounting platform 91 bond wire D width E protrusion H height