ELECTRICAL FEEDTHROUGH GLASS-METAL ELECTRODES
20210280934 · 2021-09-09
Assignee
Inventors
Cpc classification
H01M50/536
ELECTRICITY
Y02T10/70
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02E60/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M2220/20
ELECTRICITY
International classification
Abstract
An electrical device, having a feedthrough through a housing part which has a material thickness T of the housing of the device and is made of metal. The metal being iron, iron alloys, iron-nickel alloys, iron-nickel-cobalt alloys, KOVAR, steel, high-grade steel, aluminum, aluminum alloys, AlSiC, magnesium, magnesium alloys, titanium or titanium alloys. The housing part having at least one opening, wherein the opening receives a contact element, being a conductor consisting of a conductive material in a glass or glass ceramic material. The housing part has a collar in the region of the opening and thus forms an inner wall of the feedthrough opening having a height H, which is greater than material thickness T, wherein glazing length EL of the glass or glass ceramic material preferably corresponds to height H.
Claims
1. An electrical device, comprising: a housing part; a feedthrough extending through the housing part, the housing part having a material thickness T and is made of metal, the metal being iron, iron alloys, iron-nickel alloys, iron-nickel-cobalt alloys, KOVAR, steel, stainless steel, high-grade steel, aluminum, aluminum alloys, AlSiC, magnesium, magnesium alloys, titanium or titanium alloys, wherein the housing part has at least one opening, wherein the opening receives a contact element consisting of a conductive material in a glass or glass ceramic material, the housing part having a collar in the region of the opening, the collar forms an inner wall of the feedthrough at the opening, the inner wall having a height H which is greater than the material thickness T, wherein a glazing length EL of the glass or the glass ceramic material corresponds to the height H.
2. The electrical device of claim 1, wherein the collar is an upward bulging reshaped collar, the housing part and the collar being a single piece.
3. The electrical device of claim 1, wherein there is a transitional region between the collar and the housing part, the transitional region being rounded on at least one side, the at least one side including the top side, the transitional region being rounded with a radius R.
4. The electrical device of claim 1, wherein material thickness T of the housing part is in a range of 0.02 mm to 1 mm, or in a range of 0.1 mm to 0.3 mm and glazing length EL of the inner wall is in a range of 0.3 mm to 1 mm, a range of 0.4 mm to 0.7 mm, or the glazing length EL is 0.6 mm.
5. The electrical device of claim 1, wherein the housing part has a first thermal coefficient of expansion α.sub.1, the glass and/or glass ceramic material has a second thermal coefficient of expansion α.sub.2 and the contact element, has a third thermal coefficient of expansion α.sub.3 and the thermal coefficients of expansion α.sub.1, α.sub.2 and/or α.sub.3 vary by 2*10.sup.−6 l/K at most, by no more than 1*10.sup.−6 l/K, they are substantially the same, and/or are in the range of 3 to 7*10.sup.−6 l/K, in the range of 4.5 to 5.5*10.sup.−6 l/K or in the range of 9*10.sup.−6 l/K to 11*10.sup.−6 l/K.
6. The electrical device of claim 1, further comprising an insulating element arranged on the glass or the glass ceramic material, the insulating element consisting of a plastic material, a glass or glass ceramic material, the insulating element covering a front face of the collar, a plane of the surface of the collar is located below a plane of the surface of the contact element or a surface of the insulating element is located in one plane with the surface of the contact element.
7. The electrical device of claim 1 wherein the contact element is a cap-shaped element having a thickness in the range of 0.1 mm to 0.3 mm.
8. The electrical device of claim 1, wherein the feedthrough includes a connecting conductor being a tongue which is connected electrically and/or mechanically with the contact element, the contact element being a pin-shaped conductor or a cap-shaped element.
9. The electrical device of claim 8, wherein the contact element is round, with a diameter, the diameter being in a range of 1.5 mm to 5.0 mm, or the diameter is in a range of 2.0 mm to 4.00 mm.
10. The electrical device of claim 1, wherein the electrical device is an electrical storage device having a total height not exceeding 5 mm, not exceeding 4 mm, not exceeding 3 mm, in a range of 1 mm to 5 mm, or in a range of 1 mm to 3 mm.
11. The electrical device, of claim 10, wherein the electrical storage device has a housing which is connected via a flange with the feedthrough, the flange being a flexible flange.
12. The electrical device of claim 11, wherein the flange of the electrical storage device provides a free space F between a raised or lowered region, and a glazing, the flange having a connecting region.
13. The electrical storage device of claim 12, wherein the flexible flange has a tip.
14. The electrical storage device of claim 13, wherein the flange is weakened in the region of the tip.
15. The electrical storage device of claim 14, wherein the tip of the flange has a thickness in the range of 0.05 to 0.2, or a thickness of 0.15 mm.
16. The electrical storage device of claim 11, wherein the flexible flange is connected with a battery housing by welding, laser welding or soldering.
17. The electrical storage device of claim 16, wherein the flange is connected with the battery housing, the connection being substantially gas impermeable having an He leakage rate of less than 1.Math.10.sup.−8 mbar l/sec.
18. The electrical storage device of claim 12 wherein the feedthrough has a plane of a housing region on a surface facing away from a housing interior outside of the feedthrough opening above or below, with an offset to a plane formed by a surface of the conductor facing away from the housing interior and that the inorganic material, in particular the glass or glass ceramic material covers at least one area of a partial surface of a housing component.
19. The electrical storage device of claim 18, wherein the offset measures no more than 1 mm, no more than 0.7 mm, or is in a range of 0.1 mm to 1 mm.
20. The electrical storage device of claim 19, wherein the partial surface of the housing component that is covered by the inorganic material has a wall thickness, the wall thickness being less than 1 mm, less than 0.7 mm, less than 0.5 mm, less than 0.3 mm, less than 0.2 mm, less than 0.1 mm, in a range of 0.02 mm to 1 mm, or in a range of 0.02 mm to 0.1 mm.
21. The electrical storage device of claim 20, wherein a wall of the raised or lowered housing component includes recesses, embossing, fluting or openings.
22. The electrical storage device of claim 21, wherein the opening has a diameter and the diameter of the raised or lowered region decreases or increases in a progression of the raised or lowered region.
23. The electrical storage device of claim 22, wherein the inorganic material, the glass or the glass ceramic material has pores in its volume area, the pores being bubble-shaped pores.
24. The electrical storage device of claim 23, wherein a share of the pores in the volume of the glass or the glass ceramic material is in a range of 10 volume-% to 45 volume-%, or 18 volume-% to 42 volume-%.
25. The electrical storage device of claim 24, wherein the glass or the glass ceramic material forms a glass-metal bond with the end face of the raised or lowered region of the housing region, the bond being free of pores at least in the outside circumferential region of the raised or lowered region.
26. The electrical storage device of claim 25, wherein the surface of the glass or the glass ceramic material is positioned on the surface facing away from the interior of the housing in a plane with the surface of the conductor.
27. The electrical storage device of claim 26, wherein the contact element in the form of a metal pin, a contact pin, or a cap-shaped element includes an indentation.
28. The electrical storage device of claim 27, wherein the raised or lowered region progresses in such a way that a constriction is created.
29. The electrical storage device of claim 29, wherein the raised or lowered region has a glazing length L.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0102] The above-mentioned and other features and advantages of this invention, and the manner of attaining them, will become more apparent and the invention will be better understood by reference to the following description of embodiments of the invention taken in conjunction with the accompanying drawings, wherein:
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[0123] Corresponding reference characters indicate corresponding parts throughout the several views. The exemplifications set out herein illustrate embodiments of the invention and such exemplifications are not to be construed as limiting the scope of the invention in any manner.
DETAILED DESCRIPTION OF THE INVENTION
[0124] Referring now to the drawings, and more particularly to
[0125] The substantially circular opening with an edge has a diameter which is identified with D2 in
[0126] Like the opening, cap-shaped element 3 in this embodiment is also essentially round and has a diameter D1. As shown in
[0127] Thin side walls 10 of cap-shaped element 3 whose thickness is coordinated with the thickness of cover 1—preferably a thickness in the range of 0.1 to 0.3 mm—have the advantage that, in contrast to solid pins, they can absorb mechanical transverse loads which occur under thermal stresses. Thus, in contrast to a solid pin the comparatively thin metal yields under transverse loads, especially advantageously in a flexibly resilient manner, whereas a solid pin presses onto the glass where it can result in damage. Another reduction in the load upon the glass is preferably achieved in that all components, namely the housing part with the opening, the glass material and the cap-shaped element 3 have substantially the same thermal coefficient of expansion, namely in the range of 3 to 7*10.sup.−6 l/K.
[0128] Preferred materials for cap 3 are KOVAR, nickel-iron-cobalt alloys but also iron, iron alloys, iron-nickel alloys, iron-nickel-cobalt alloys, titanium, titanium alloys, steel, stainless steel, high-grade steel, magnesium, magnesium alloys, aluminum, aluminum alloys, or AlSiC.
[0129] Also clearly shown in
[0130] It is especially preferred if contacting of a conductor occurs in the interior of the housing with cap 3 via tongues, which are two-dimensionally connected in particular with cap 3 in the region of the hollow space of cap 3. Contacting by means of tongues has the advantage over contacting by means of a pin, in that the contact areas are larger, along with which there is a lesser contact resistance. The connection with tongues can furthermore be permanently more resistant to shear stresses.
[0131] In the illustrated embodiment cap 3 is preferably round with a diameter D1. Diameter D1 of cap 3 is in the range of, for example 1.5 mm to 5 mm, and preferably between 2.0 mm and 4.0 mm. Exemplary diameter D2 of the opening is substantially larger and is in the range of between 8 mm and 4.0 mm, in particular around 5 mm. Glazing length H of the inventive cap 3 in the opening is preferably between 0.4 mm and 1 mm, preferably 0.6 mm. All stated dimensions are exemplary and do not represent a limitation.
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[0133] Also shown in
[0134] The material thickness in the region of stamping 50 is greatly reduced and is preferably in the μm range, depending on the requirements regarding at what pressure a pressure release is to occur. Exemplary material strengths, that is the thicknesses of the metal 40 in the region of stamping 50 are in the range of 10 μm to 50 μm as used in this embodiment, however, without restriction thereto. The material thicknesses in the region of stamping 50 are thus the remaining material thicknesses.
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[0139] Insulating material 200 consisting in particular of plastic or glass or ceramic is arranged on glass or glass ceramic material 2 and covers in particular the front face of collar 100 or respectively of the drawn-up region. The collar is thus electrically insulated from the conductor 3. The plane of the surface of collar 100 is preferably located below the plane of the surface of contact element 3 or respectively conductor 3. It is especially preferred if the surface of insulating element 200 is located in one plane with the surface of the contact element or respectively the conductor, in this case cap-shaped element 3.
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[0142] Instead of solid conductor 400 a cap-shaped element, as shown in
[0143] The flange is hereby reduced in its thickness, in other words made thinner and has then better elasticity in particular for laser welding, which again provides better impermeability.
[0144] An arrangement is shown in
[0145] In particular, any tensile or compressive stress, which occurs, for example with laser welding, is avoided due to the flexibility of flange 310. Thus, tensile and compressive tensions can be deflected from the welded cap to the ring. Same components as in
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[0147] In contrast to a solid plate as used in the current state of the art which, based on its thickness provides the necessary glazing length, an especially thin and thus compact housing part with a feedthrough opening having a sufficient glazing length EL or H of preferably 0.3 mm to 1 mm, preferably approximately 0.6 mm is provided with the inventive arrangement with a relatively thin housing component and raised or lowered regions which are for example created by reshaping. The diameter of opening 1005 is between 2 mm and 5 mm, in particular 2.5 mm to 4 mm.
[0148] In addition, also illustrated in the drawing is metal pin 1010 which is inserted in feedthrough opening 1005 and which, in the current example is in the embodiment of a solid pin. Instead of solid metal pin 1010, the conductor may also consist of a cap-shaped element (not illustrated). The cap-shaped element compared to the solid metal pin has the advantage that it is also manufactured from a comparatively thin metal which yields in the event of a transverse load, especially advantageously in a flexibly resilient manner, whereas, in contrast a solid metal pin presses on the glass where it can cause damage.
[0149] The invention provides that the conductor, in particular metal pin 1010 is glazed into the feedthrough opening which is created by the raised or lowered region 1003 of the metal, preferably in an inorganic material, in particular in a glass or a glass ceramic material. The glass or glass ceramic material of the glazing is identified with reference number 1020 in the current example. According to the present invention it is provided that the inorganic material, in particular the glass or glass ceramic material covers a partial area of the housing component outside wall 1004, which supports the glazing. This protruding section of the glass that covers the housing component or respectively the battery cover is identified in the current example with reference number 1050. The fact that the glazing covers end 1052 of the raised region with a glass or glass ceramic material ensures that metal pin 1010 is electrically insulated from the housing component that is also made of metal. Instead of the glass material protruding over the edge of the raised region, an insulation can also be provided by a separate insulating material, as shown in
[0150] The glass that is used is a swelling glass with a share of bubbles or pores in the glass. This applies especially to the volume range. The share of bubbles or respectively a pore share is preferably 18 to 42 weight percent. To create the bubbles or respectively pores 1101, gas is added to the glass, which is outgassed again during melting and results in pores 1101. The glass ceramic material is alumoborate glass with the following main components: Al.sub.2O.sub.3, B.sub.2O.sub.3, BaO and SiO.sub.2. The coefficient of expansion of the glass material is in the range α.sub.glass of 9.0 to 9.5*10.sup.−6/K.
[0151] The preferred materials for the housing component as well as for the conductor in the embodiment of a metal pin are iron, an iron alloy, an iron-nickel alloy, an iron-nickel-cobalt alloy, Kovar, steel, stainless steel, high-grade steel, aluminum, an aluminum alloy, AlSiC, magnesium, a magnesium alloy, titanium or a titanium alloy. It is especially preferred if the material of the housing component, as well as of the conductor, is a high-grade steel, in particular an alloyed high-grade steel according to EN 10020, preferably a high-grade steel containing chromium, in particular a high-grade steel selected from the group of ferritic high-grade steels and/or hardened high-grade steels. It is especially preferred if AISI446 or AISI430 are used as the ferritic high-grade steel materials. The metal pins used as the conductor are made of a ferritic high-grade steel and can be furnished with a nickel and/or gold cover, so that easy contacting is provided. The chromium content of the ferritic high-grade steels is in the range of 10 weight percent chromium to 30 weight percent chromium. The thermal coefficient of expansion is preferably in the range of 9.0 to 10.0 ppm/K, for example for high-grade steel AISI443 at 9.9*10.sup.−6/K.
[0152] Based on the thin component thickness of the component housing, it is preferred that the feedthrough is not a compression seal with different coefficients of expansion for the pin material, the glass material and the housing material, but that the coefficients of expansion are substantially the same and that the feedthrough is a matched feedthrough. This means that α.sub.glass α.sub.pin α.sub.housing show a difference in their coefficients of expansion which is maximally 2 ppm/K, preferably maximally 1 ppm/K. Based on the coefficient of expansion for the pin material α.sub.pin of 9.9 ppm/K or respectively 9.9*10.sup.−6/K for ferritic high-grade steel AISI443 it is advantageous if the alumoborate glass has a coefficient of expansion of 9.1 ppm/K or respectively 9.1*10.sup.−6/K. The thin housing material is selected in regard to the coefficient of expansion to be approximately the same as that of the glass and material of the conductor. The material of the housing component is preferably also a ferritic high-grade steel, for example AISI443. However, the material of the housing is in no way restricted thereto. Other materials as specified in the application are also possible if the coefficient of expansion does not differ greatly from that of the glass and conductor material.
[0153] As illustrated in
[0154] To improve adhesion for the glass material in feedthrough opening 1005 provision can be made that the material, in particular the metal that provides the inside wall of the feedthrough opening includes recesses and/or openings, as illustrated in
[0155] An additional improvement in the adhesion can be achieved if the conductor, in particular the metal pin, preferably the contact pin, but also the cap-shaped element has an indentation which is not illustrated in the current example. Whereas the glass has a share of 18-42% of pores in the feedthrough opening, the glass or glass ceramic material is largely pore-free at the faces 1052 of the raised or lowered region which identified with 1003. The glass or glass ceramic material which has pores 1101 in the volume region thus forms a pore-free unbroken surface in its surface area, in particular a glass or glass ceramic skin which coats the housing component in particular on the boundary surface to the air.
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[0163] An embodiment is shown in
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[0165] On the basis of the compact feedthrough, the height of the entire micro-battery is at most 5 mm, preferably at most 3 mm, in particular it is in the range of 1 mm to 5 mm. The dimensions in the region of the feedthrough with the flexible flange according to
[0166] The feedthrough according to the invention is used for housings for electrical storage devices, in particular batteries of capacitors. On the basis of the very flat inventive feedthrough for an electrical storage device an electrical storage device can be provided having a total height of at most 5 mm, in particular at most 4 mm, preferably at most 3 mm, in particular in the range of 1 mm to 5 mm, preferably 1 mm to 3 mm.
[0167] Thus, a very flat feedthrough is specified for the first time, which allows for very compact components with electrical storage devices, in particular batteries or capacitors.
[0168] In addition, a feedthrough or respectively an electrical device is provided, in particular a storage device which is characterized by greater stability in regard to mechanical and/or pressure related transverse loads. The inventive feedthrough moreover has the advantage that it can be produced efficiently, that it offers an increased inside housing volume and thus greater battery or capacitor capacities and at the same time contributes to weight reduction due to reduced material use.
[0169] In addition the feedthrough can be designed in such a manner that the cap provides a safety function, in particular in regard to the battery or capacitor internal pressure.
[0170] In an alternative embodiment of the invention a feedthrough for a housing component or respectively a housing component is provided which includes a flange and which is characterized in that the feedthrough, or respectively the housing component can be tightly sealed with the housing, for example a storage device and it absorbs tensile and compressive stresses.
[0171] The invention comprises aspects which are recorded in the following propositions, which are part of the description, but which are not claims
Propositions
[0172] 1. Feedthrough, in particular through a housing part (1) of a housing, in particular a storage device, preferably a battery or a capacitor, consisting of metal, in particular iron, iron alloys, iron-nickel alloys, iron-nickel-cobalt alloys, KOVAR, steel, stainless steel, high-grade steel, aluminum, an aluminum alloy, AlSiC, magnesium, a magnesium alloy, titanium or a titanium alloy, wherein the housing part has at least one opening, wherein the opening receives a conductive material in a glass or glass ceramic material (2), characterized in that [0173] the conductive material is a cap-shaped element (3), in particular having a thickness or wall strength in the range of 0.1 mm to 0.3 mm.
[0174] 2. Feedthrough according to proposition 1, [0175] characterized in that [0176] cap-shaped element (3) comprises side walls (10), preferably thin side walls, and/or a hollow space in the cap.
[0177] 3. Feedthrough according to one of the propositions 1 to 2, [0178] characterized in that [0179] cap-shaped element (3) is a drawn component.
[0180] 4. Feedthrough according to one of the propositions 1 to 3, [0181] characterized in that [0182] in addition the feedthrough comprises a conductor, in particular in the embodiment of a tongue which is connected electrically and/or mechanically with cap-shaped element (3), preferably inside cap-shaped element (3), preferably inside the hollow space of the cap.
[0183] 5. Feedthrough according to proposition 3, [0184] characterized in that [0185] in the hollow space the cap of cap-shaped element (3) sensor devices, in particular temperature and/or pressure gauges are arranged.
[0186] 6. Feedthrough according to one of the propositions 1 to 5, [0187] characterized in that [0188] cap-shaped element (3) includes at least one region with locally reduced thickness, in particular a base stamping (50), in particular having a thickness in the range of 10 μm to 50 μm, acting as a safety release in the event of a pressure overload.
[0189] 7. Feedthrough according to one of the propositions 1 to 6, [0190] characterized in that [0191] the side wall of cap-shaped element (3) is designed conically.
[0192] 8. Feedthrough according to one of the propositions 1 to 7, [0193] characterized in that [0194] cap-shaped element (3) is preferably round, with a diameter, wherein the diameter is in particular a diameter in the range of 1.5 mm to 5.0 mm, in particular 2.0 mm to 4.00 mm.
[0195] 9. Feedthrough according to one of the propositions 1 to 8, [0196] characterized in that [0197] housing (1) has a first coefficient of expansion α.sub.1, the glass [0198] or glass ceramic material (2) has a second coefficient of expansion α.sub.2 and cap-shaped element (3) has a third coefficient of expansion α.sub.3 and [0199] thermal coefficients of expansions α.sub.1, α.sub.2, α.sub.3 are substantially the same and are preferably in the range of 3 to 7*10.sup.−6 l/K, preferably 4.5 to 5.5*10.sup.−6 l/K.
[0200] 10. A housing, in particular a housing for an electrical storage device, in particular a battery or capacitor having a feedthrough according to one of the propositions 1 to 9.
[0201] 11. A storage device, in particular a battery or capacitor with a housing or housing part according to proposition 10.
[0202] 12. A feedthrough, in particular through a housing part (1001) of a housing, in particular of a housing, in particular a storage device, preferably a battery or a capacitor, made of metal, in particular iron, iron alloy, iron-nickel alloy, iron-nickel-cobalt alloy, KOVAR, steel, stainless steel, high-grade steel, aluminum, an aluminum alloy, AlSiC, magnesium, a magnesium alloy, titanium or a titanium alloy, wherein the housing part has at least one opening, wherein the opening receives a conductive material, preferably a conductor in a glass or glass ceramic material, [0203] characterized in that [0204] the housing part is drawn upward so that the opening is formed with a drawn-up edge (100, 300, 1003).
[0205] 13. Feedthrough according to proposition 12, [0206] characterized in that [0207] drawn-up edge (100, 300, 1003) provides a glazing length (EL)
[0208] 14. Feedthrough according to one of the propositions 12 to 13, [0209] characterized in that [0210] the housing part has a thickness, and the thickness is in the range of 0.1 mm to 0.3 mm.
[0211] 15. Feedthrough according to one of the propositions 12 to 14, [0212] characterized in that [0213] glazing length EL is 0.3 mm to 1 mm.
[0214] 16. Feedthrough according to one of the propositions 12 to 14, [0215] characterized in that [0216] the conductor is a solid conductor, preferably a pin, in particular a solid pin.
[0217] 17. Feedthrough according to one of the propositions 12 to 16, [0218] characterized in that [0219] the conductor consists of a metal, in particular iron, an iron alloy, an iron-nickel alloy, an iron-nickel-cobalt alloy, KOVAR, titanium, a titanium alloy, steel, stainless steel, high-grade steel, aluminum, an aluminum alloy, AlSiC, magnesium and a magnesium alloy.
[0220] 18. Feedthrough according to one of the propositions 12 to 17, [0221] characterized in that [0222] housing component (2, 1002) has a first coefficient of expansion α.sub.housing, conductor (5, 1005), in particular the metal pin, preferably the contact pin has a second coefficient of expansion α.sub.pin and the glass or glass ceramic material (20) has a third coefficient of expansion α.sub.glass and that the difference of first, second and third coefficient of expansion is 2 ppm/K maximum, preferably 1 ppm/K maximum.
[0223] 19. Feedthrough according to one of the propositions 12 to 18, [0224] characterized in that [0225] the first, second and third coefficients of expansion (α.sub.pin, α.sub.glass, α.sub.housing) is in the range of 9 ppm/K to 11 ppm/K.
[0226] 20. Feedthrough according to one of the propositions 12 to 19, [0227] characterized in that [0228] the wall of the drawn-up edge comprises recesses, in particular embossing, fluting or openings.
[0229] 21. Feedthrough according to one of the propositions 12 to 20, [0230] characterized in that [0231] the housing component with raised edge (100, 300, 1003) includes a flange, in particular a flexible flange, or connects to a flexible flange (1110).
[0232] 22. Feedthrough according to one of the propositions 12 to 21, [0233] characterized in that [0234] flexible flange (1110) includes a connecting region (1180) for connecting the flange to a housing part, in particular a battery housing part.
[0235] 23. Housing, in particular a housing for an electrical storage device, in particular a battery or capacitor with a feedthrough according one of the propositions 12 to 22.
[0236] 24. Storage device, in particular a battery or capacitor, with a housing or housing part according to proposition 23.
[0237] 25. Storage device, in particular electrical storage device according to proposition 24, [0238] characterized in that [0239] the electrical storage device has a total height not exceeding 5 mm, in particular not exceeding 4 mm, preferably not exceeding 3 mm, in particular in the range of 1 mm to 5 mm, preferably 1 mm to 3 mm.
[0240] 26. Electrical storage device according to one of the propositions 24 to 25, [0241] characterized in that [0242] the electrical storage device includes a contact device (1400), in particular a contact flag.
[0243] 27. Electrical storage device according to one of the propositions 24 to 26, [0244] characterized in that [0245] the electrical storage device has a housing which is connected via a flange (1110), in particular a flexible flange with the feedthrough according to one of the propositions 21 to 22.
[0246] 28. Electrical storage device according to proposition 27, [0247] characterized in that [0248] flange (1110), in particular the flexible flange is connected with the battery housing by means of welding, in particular laser welding or soldering.
[0249] 29. Electrical storage device according to proposition 28, [0250] characterized in that [0251] flange (1110) is connected with the battery housing in such a way, the connection is substantially gas impermeable, and that the He leakage rate is preferably less than 1.Math.10.sup.−8 mbar l/s at 1 bar pressure difference.
[0252] 30. Feedthrough (1001) through a housing component (1002), preferably an annular housing component with a feedthrough opening (1005) of an electrical storage device, preferably a battery or a capacitor, with at least one conductor (1010), in particular a metal pin, preferably a contact pin, in particular preferably a cap-shaped element which, by means of an inorganic material, in particular a glass or glass ceramic material (1020) is insulated in the housing feedthrough opening (1005), preferably electrically insulated from the housing component, [0253] characterized in that [0254] a plane (1110) of the housing region is arranged on the surface facing away from the housing interior outside the feedthrough opening above or below, with an offset (V) to a plane (1100) which is formed by the surface of the conductor facing away from the housing interior and that the inorganic material, in particular the glass or glass ceramic material (1020) covers at least one area of a partial surface of housing component (1052).
[0255] 31. Feedthrough according to proposition 30, [0256] Characterized in that [0257] offset (V) measures no more than 1 mm, preferably no more than 0.7 mm, and is in particular in the range of 0.1 mm to 1 mm.
[0258] 32. Feedthrough according to one of the proposition 30 or 31, [0259] characterized in that [0260] housing component (1002) has a first coefficient of expansion α.sub.housing, conductor (1005), in particular the metal pin, preferably the contact pin has a second coefficient of expansion α.sub.pin and the glass or glass ceramic material (1020) has a third coefficient of expansion α.sub.glass and that the difference of first, second and third coefficient of expansion is 2 ppm/K maximum, preferably 1 ppm/K maximum.
[0261] 33. Feedthrough according to one of the propositions 30 to 32, [0262] characterized in that [0263] the first, second and third coefficients of expansion (α.sub.pin, α.sub.glass, α.sub.housing) is in the range of 9 ppm/K to 11 ppm/K.
[0264] 34. Feedthrough according to one of the proposition 30 to 33, [0265] characterized in that [0266] the partial surface of housing component (1052) that is covered by the inorganic material, in particular the glass or glass ceramic material (1020) has a wall thickness wherein the wall thickness is less than 1 mm, preferably less than 0.7 mm, in particular less than 0.5 mm, especially preferably less than 0.3 mm, in particular less than 0.2 mm, particularly preferably less than 0.1 mm. preferably in the range of 0.02 mm to 1 mm, in particular in the range of 0.02 mm to 0.1 mm.
[0267] 35. Feedthrough according to one of the proposition 30 to 34, [0268] characterized in that [0269] housing component (1002) and/or metal pin (1005) consist of one of the following materials: [0270] iron, [0271] an iron alloy, [0272] an iron-nickel alloy, [0273] an iron-nickel-cobalt alloy, [0274] Kovar, [0275] steel, [0276] stainless steel, [0277] high-grade steel, [0278] ferritic high-grade steel, [0279] austenitic high-grade steel, [0280] Duplex high-grade steel [0281] aluminum [0282] an aluminum alloy, [0283] AlSiC, [0284] magnesium, [0285] a magnesium alloy, [0286] titanium, [0287] a titanium alloy.
[0288] 36. Feedthrough according to one of the proposition 30 to 35, [0289] characterized in that [0290] housing component (1002) includes a raised or lowered region (1003) in the region of the feedthrough opening, in such a manner that a wall (1004) is created in the region of the feedthrough opening.
[0291] 37. Feedthrough according to one of the proposition 30 to 36, [0292] characterized in that [0293] that the housing component outside raised or lowered region (1003) has a first plane (1060) and the raised or lowered region is located in a second plane (1070) and the first plane, and the first plane is angled toward the second plane, in particular vertically angled.
[0294] 38. Feedthrough according to one of the proposition 30 to 37, [0295] characterized in that [0296] the glass or glass ceramic material covers an end face (1052) of the raised or lowered region.
[0297] 39. Feedthrough according to one of the proposition 30 to 38, [0298] characterized in that [0299] wall (1004) of the raised or lowered housing component comprises recesses (1200, 1202, 1204) in particular embossing, fluting or openings.
[0300] 40. Feedthrough according to proposition 39, [0301] characterized in that [0302] the opening has a diameter and the diameter of the raised or lowered region decreases or increased in the progression of the raised or lowered region.
[0303] 41. Feedthrough according to one of the proposition 30 to 40, [0304] characterized in that [0305] the inorganic material, in particular the glass or glass ceramic material has pores (1101) in its volume area, in particular bubble-shaped pores (1101).
[0306] 42. Feedthrough according to proposition 41, [0307] characterized in that [0308] the share of pores (1101) in the volume of the inorganic glass or glass ceramic material is in the range of 10 volume-% to 45 volume-%, preferably 18 volume-% to 42 volume-%.
[0309] 43. Feedthrough according to one of the proposition 30 to 42, [0310] characterized in that [0311] glass or glass ceramic material (1020) forms a glass-metal bond with end face (1052) of the raised or lowered region of the housing region, said bond being free of pores at least in the outside circumferential region of the lowered region.
[0312] 44. Feedthrough according to one of the proposition 30 to 43, [0313] characterized in that [0314] the surface of the glass or glass ceramic material (1020) is positioned on the surface facing away from the interior of the housing, in a plane with the surface of the conductor.
[0315] 45. Feedthrough according to one of the proposition 30 to 44, [0316] characterized in that [0317] the conductor (1005), in particular the metal pin, preferably the contact pin, in particular the cap-shaped element includes an indentation.
[0318] 46. Feedthrough according to one of the proposition 30 to 45, [0319] characterized in that [0320] raised or lowered region (1003) progresses in a such a way that a constriction is created.
[0321] 47. Feedthrough according to one of the proposition 30 to 46, [0322] characterized in that [0323] the raised or lowered region provides a glazing length L.
[0324] 48. Feedthrough according to one of the proposition 30 to 47, [0325] characterized in that [0326] the raised or lowered region includes a flexible flange or connects to a flexible flange.
[0327] 49. Feedthrough according to proposition 48, [0328] characterized in that [0329] the flexible flange includes a connection region to connect the flange to a housing part, in particular to a battery housing part.
[0330] 50. Electrical storage device, in particular a battery or capacitor, in particular a micro-battery, comprising at least one feedthrough according to one of the propositions 30 to 49.
[0331] 51. Electrical storage device according to proposition 50, [0332] characterized in that [0333] the electrical storage device has a total height not exceeding 5 mm, in particular not exceeding 4 mm, preferably not exceeding 3 mm, in particular in the range of 1 mm to 5 mm, preferably 1 mm to 3 mm.
[0334] 52. Electrical storage device according to one of the propositions 50 to 51, [0335] characterized in that [0336] the electrical storage device includes a contact device (1400), in particular a contact flag.
[0337] 53. Electrical storage device according to one of the propositions 50 to 52, [0338] characterized in that [0339] contact device (1400), in particular the contact flag, is electrically connected [0340] with the conductor, in particular with metal pin (1010), and is electrically insulated from the housing via the inorganic material, in particular the glass or glass ceramic material which covers a partial surface of the housing component.
[0341] 54. Electrical storage device according to proposition 53, [0342] characterizes in that [0343] that the thickness of the glass or glass ceramic material between the contact device, in particular contact flag (1400) and the partial surface of the housing component is in the region of 0.1 mm to 1.0 mm, in particular 0.1 mm to 0.7 mm.
[0344] 55. Electrical storage device according to one of the propositions 50 to 54, [0345] characterized in that [0346] the electrical storage device has a housing which is connected via a flange, in particular a flexible flange with the feedthrough according to one of the propositions 30 to 49.
[0347] 56. Electrical storage device according to proposition 55, [0348] characterizes in that [0349] the flange, in particular the flexible flange is connected with the battery housing by means of welding, in particular laser welding or soldering.
[0350] 57. Electrical storage device according to proposition 56, [0351] characterizes in that [0352] the flange is connected with the battery housing in such a way, the connection is substantially gas impermeable, and that the He leakage rate is preferably less than 1.Math.10.sup.−8 mbar l/s at 1 bar pressure difference.
[0353] 58. Electrical storage device according to one of the propositions 50 to 57, [0354] characterized in that [0355] the material of the storage device—at least for the housing region which is in contact with the inorganic material, in particular the glass or glass ceramic material—is a metal, in particular iron, an iron alloy, an iron-nickel alloy, an iron-nickel-cobalt alloy, Kovar, steel, stainless steel, high-grade steel, ferritic high-grade steel, aluminum, an aluminum alloy, AlSiC, magnesium, a magnesium alloy, titanium or a titanium alloy.
[0356] While this invention has been described with respect to at least one embodiment, the present invention can be further modified within the spirit and scope of this disclosure. This application is therefore intended to cover any variations, uses, or adaptations of the invention using its general principles. Further, this application is intended to cover such departures from the present disclosure as come within known or customary practice in the art to which this invention pertains and which fall within the limits of the appended claims.