METAL - HALIDE OXYANION BATTERY ELECTRODE CHEMISTRY

Abstract

A metal-halo oxyanion electrode and battery including the metal-halo oxyanion electrode is described.

Claims

1. An electrode comprising a halogen oxyanion salt and a conductive material.

2. The electrode of claim 1, wherein the halogen is chlorine, bromine or iodine.

3. The electrode of claim 1, wherein the halogen is iodine.

4. The electrode of claim 1, wherein the halogen oxyanion salt is an alkali metal salt.

5. The electrode of claim 4, wherein the alkali metal salt is a lithium salt, a sodium salt or a potassium salt.

6. The electrode of claim 1, wherein the halogen oxyanion salt is a lithium iodate, a sodium iodate or a potassium iodate.

7. The electrode of claim 1, wherein the halogen oxyanion salt is formed by oxidation of a metal hydroxide salt in the presence of a halogen or halide.

8. The electrode of claim 1, wherein the conductive material is a conductive carbon material.

9. The electrode of claim 1, wherein the conductive carbon material includes carbon black, graphene, carbon nanotubes, or graphite.

10. The electrode of claim 1, wherein the halogen oxyanion is lithium iodate.

11. A battery comprising: a metal electrode; a halogen oxyanion electrode; and a separator between the metal electrode and the halogen oxyanion electrode.

12. The battery of claim 11, wherein the halogen oxyanion electrode includes a halogen oxyanion salt and a conductive material.

13. The battery of claim 11, wherein the halogen is chlorine, bromine or iodine.

14. The battery of claim 11, wherein the halogen is iodine.

15. The battery of claim 11, wherein the halogen oxyanion salt is an alkali metal salt.

16. The battery of claim 15, wherein the alkali metal salt is a lithium salt, a sodium salt or a potassium salt.

17. The battery of claim 11, wherein the halogen oxyanion salt is a lithium iodate, a sodium iodate or a potassium iodate.

18. The battery of claim 11, wherein the halogen oxyanion salt is formed by oxidation of a metal hydroxide salt in the presence of a halogen or halide.

19. The battery of claim 11, wherein the conductive material is a conductive carbon material.

20. The battery of claim 19, wherein the conductive carbon material includes carbon black, graphene, carbon nanotubes, or graphite.

21. The battery of claim 11, wherein the halogen oxyanion electrode further comprises a binder.

22. The battery of claim 11, wherein the halogen oxyanion is lithium iodate.

23. The battery of claim 11, wherein the metal electrode includes an alkali metal or metal ion negative electrode.

24. The battery of claim 23, wherein the alkali metal includes lithium, sodium or potassium.

25. A method of generating electricity, comprising: creating an electronic connection to a battery of claim 11.

26. The electrode of claim 8, wherein the metal electrode includes an alkali metal or metal ion negative electrode.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0015] FIG. 1A is a schematic depiction of an alkali metal halogen oxide electrochemical system.

[0016] FIG. 1B is a graph depicting cyclic voltammograms of solutions of 0.5M LiTFSI+10 mM LiI collected at 100 mVps under argon environment in each of the considered solvents with a Pt working electrode, either Li metal (DME, DMSO) or lithium titanium oxide (DMA) counter electrode and Ag/Ag.sup.+ reference electrode. Currents were normalized based on the maximum current observed. Potentials were converted to a Me.sub.10Fc scale based on its half-wave potential measured at the end of the experiment by adding 2 mM Me.sub.10Fc to the electrolyte (as detailed in FIG. 18).

[0017] FIG. 2 is a set of graphs depicting (panel a) Color changes when solutions of 50 mM I.sub.3.sup.− (0.2 M LiI+50 mM 12) are added to 0.1 M synthetic Li.sub.2O.sub.2 (panel b) UV-vis spectra of the liquid phase before and after the reaction with Li.sub.2O.sub.2 confirm the consumption of I.sub.3.sup.− in DMSO, but that I.sub.3.sup.− remains in DME (panel c) The change in concentration of I.sub.3.sup.− when adding a 50 mM I.sub.3.sup.− solution to a two times excess of synthetic Li.sub.2O.sub.2 (left axis, black filled symbols). I.sub.3.sup.− concentrations were determined through UV-Vis Spectroscopy. Full consumption of I.sub.3.sup.− was found in DMA, DMSO and Me-Im with differences in the plot stemming from different initial concentrations. Error bars were estimated based on the accuracy of the mass balance used during preparation of diluted samples of +/−0.5 mg. Calibration curves for each solvent can be found in FIG. 12-14. The difference between the I.sub.3.sup.−/I.sup.− and Li.sup.+, O.sub.2/Li.sub.2O.sub.2 redox potentials (right axis, open grey symbols).

[0018] FIG. 3 is a graph depicting gas chromatography of the gaseous products during the reaction between 50 mM I.sub.3.sup.− (0.2 M LiI+50 mM 12) and synthetic Li.sub.2O.sub.2. (panel a) the change in O.sub.2 concentration in the Argon carrier gas stream at 2, 22, 42 and 62 minutes following the injection of the I.sub.3.sup.− solution; (panel b) The GC sensor outputs for each of the four measurements. N.sub.2 and O.sub.2 signals were calibrated using a 2500 ppm O.sub.2+17000 ppm N.sub.2 in Argon gas mixture. The absence of N.sub.2 indicates O.sub.2 came from the reaction and not a leak in the cell.

[0019] FIG. 4 is a graph depicting a voltage profile and corresponding O.sub.2 (filled symbols) and CO.sub.2 (open symbols) evolution during charge at 0.1 mA/cm.sup.2 in 0.5 M LiTFSI in G2 (panel a, panel c) or DMSO (panel b, panel d), both with 0.1 M LiI (lighter colors) and with an additional 0.1 M LiTFSI (darker colors) to keep the overall [Li.sup.+] constant. Cells constructed with a Li metal counter electrode and a solid Li-conducting separator to prevent shuttling of oxidized iodide species from the positive electrode to the Li metal electrode where they can be chemically reduced and diffuse back to the positive electrode. See, for example, Burke, C. M. et al. Implications of 4e.sup.− Oxygen Reduction via Iodide Redox Mediation in Li—O.sub.2 Batteries. ACS Energy Lett 1, 747-756 (2016), which is incorporated by reference in its entirety. Potentials referenced against lithium metal counter electrode. Cells were first discharged for 20 hours at 0.05 mA/cm.sup.2 under O.sub.2 environment, and then the cell headspace was evacuated and purged with Argon gas five times. The added 0.1 M LiI could provide a theoretical maximum of 33 mM I.sub.3.sup.− and 50 mM I.sub.2, accounting for a maximum of 0.25 mAhr/cm.sup.2 of capacity.

[0020] FIG. 5A is a set of drawings showing a graph depicting (panel a) The change in concentration of I.sub.3.sup.− when adding a 50 mM I.sub.3.sup.− (0.2 M LiI+50 mM I.sub.2) solution to a two times excess of LiOH (left axis, black filled symbols). I.sub.3.sup.− concentrations were determined through UV-Vis Spectroscopy. Full consumption of I.sub.3.sup.− was found in DMA, DMSO and Me-Im with differences in the plot stemming from different initial concentrations. Error bars were estimated based on the accuracy of the mass balance used during preparation of diluted samples of +/−0.5 mg. Calibration curves for each solvent can be found in FIGS. 12-14. The difference between the I.sub.3.sup.−/I.sup.− and Li.sup.+,O.sub.2,H.sub.2O/LiOH redox potentials (right axis, open grey symbols) and Li.sup.+,IO.sub.3.sup.−,H.sub.2O/LiOH,I.sup.− redox potentials (right axis, filled grey symbols); (panel b) The change in concentration of 12 when adding a 50 mM I.sub.2 solution to a two times excess of LiOH (left axis, black filled symbols). The difference between the I.sub.2/I.sub.3.sup.− and Li.sup.+, O.sub.2, H.sub.2O/LiOH redox potentials (right axis, open grey symbols) and Li.sup.+,IO.sub.3.sup.−, H.sub.2O/LiOH, I.sup.− redox potentials (right axis, filled grey symbols; (panel c) Raman spectra of the solid participate which was separated and washed after reacting an excess of 12 with LiOH in DMSO and three reference spectra (LiIO.sub.3, LiOH and LiOH—H.sub.2O). The solid precipitate has only peaks consistent with LiIO.sub.3 and no erroneous peaks; measurement is representative of three separate locations in the solid.

[0021] FIG. 5B is a set of drawings showing a graph (panel a) showing the consumption of I.sub.3.sup.− when adding 200 μmol of commercial LiOH to 1 mL of 50 mM I.sub.3.sup.− solution (50 μmol I.sub.3.sup.−, LiOH:I.sub.3.sup.−=4:1)) (left axis, black filled symbols) measured after 48 hours. I.sub.3.sup.− concentrations were determine through UV-Vis Spectroscopy. Full consumption of I.sub.3.sup.− was found in DMA, DMSO and Me-Im with differences in the plot stemming from different initial concentrations. Error bars were estimated based on the accuracy of the mass balance used during preparation of diluted samples of +/−0.5 mg. Calibration curves for each solvent can be found in FIGS. 12-14. The difference between the I.sub.3.sup.−/I.sup.− and Li.sup.+,O.sub.2,H.sub.2O/LiOH redox potentials (right axis, open grey symbols) and Li.sup.+,IO.sub.3.sup.−,H.sub.2O/LiOH,I.sup.− redox potentials (right axis, open black symbols). Panel b shows the consumption of 12 when adding 200 μmol of commercial LiOH to 1 mL of 50 mM I.sub.2 solution (50 μmol 12, LiOH:I.sub.3.sup.−=4:1)) (left axis, black filled symbols) measured after 48 hours. The difference between the I.sub.2/I.sub.3.sup.− and Li.sup.+,O.sub.2,H.sub.2O/LiOH redox potentials (right axis, open grey symbols) and Li.sup.+,IO.sub.3.sup.−,H.sub.2O/LiOH,I.sup.− redox potentials (right axis, open black symbols). Panel c shows Raman spectra of the solid participate which was separated and washed after reacting an excess of I.sub.2 with LiOH in DMSO and three reference spectra (LiIO.sub.3, LiOH and LiOH—H.sub.2O). The solid precipitate has only peaks consistent with LiIO.sub.3 and no erroneous peaks; measurement is representative of three separate locations in the solid.

[0022] FIG. 6 is a graph depicting (panel a).sup.1H NMR spectrum of pure DMSO, DMSO after exposure to LiOH, and DMSO after the reaction between 50 mM I.sub.2/I.sub.3.sup.− and 0.2 M commercial LiOH. After the reactions between I.sub.2/I.sub.3.sup.− and LiOH, two new peaks appear; one at ˜2.95 ppm (based on the DMSO peak being assigned to 2.5 ppm) corresponding to DMSO.sub.2 and one at ˜3.3 ppm corresponding to H.sub.2O. All .sup.1H NMR samples were prepared by mixing 0.5 mL of the sample+0.1 mL of DMSO-D6 (for NMR locking)+10 μL of 1,4-dioxane internal reference (for quantification) and (panel b) full quantification of detected liquid and solid products after reactions between I.sub.2/I.sub.3.sup.− and LiOH. LiIO.sub.3 was quantified using iodometric titration, DMSO.sub.2 and H.sub.2O were quantified using .sup.1H NMR with an internal standard of 1,4-dioxane.

[0023] FIG. 7 is a graph depicting voltage profile and corresponding O.sub.2 (filled symbols) and CO.sub.2 (open symbols) evolution during charge of LiOH preloaded electrodes at 0.1 mA/cm2 in 0.5 M LiTFSI in G2 (panel a, panel c) or DMSO (panel b, panel d), both with 0.1 M LiI (lighter colors) and with an additional 0.1 M LiTFSI (darker colors) to keep the overall [Li+] constant. Cells constructed with a Li metal counter electrode and a solid Li-conducting separator to prevent shuttling of oxidized iodide species from the positive electrode to the Li metal electrode where they can be chemically reduced and diffuse back to the positive electrode. See, for example, Burke, C. M. et al. Implications of 4e.sup.− Oxygen Reduction via Iodide Redox Mediation in Li—O.sub.2 Batteries. ACS Energy Lett. 1, 747-756 (2016), which is incorporated by reference in its entirety. Potentials referenced against lithium metal counter electrode. The added 0.1 M LiI could provide a theoretical maximum of 33 mM I.sub.3.sup.− and 50 mM I.sub.2, accounting for a maximum of 0.25 mAhr/cm.sup.2 of capacity.

[0024] FIG. 8 is a drawing depicting a battery.

[0025] FIG. 9 is a graph depicting Raman spectroscopy of commercial Li.sub.2O.sub.2, anhydrous LiOH after additional drying at 170° C. under vacuum for 24 hrs, LiOH—H.sub.2O and LiIO.sub.3.

[0026] FIG. 10 is a graph depicting cyclic voltammograms of solutions of 0.5M LiTFSI+10 mM LiI collected at 100 mVps under argon environment in each of the considered solvents with a Pt working electrode, either Li metal (G4, DME, DMSO) or lithium titanium oxide (pyridine, DMA, Me-Im) counter electrode and Ag/Ag.sup.+ reference electrode. Currents were normalized based on the maximum current observed. Potentials were converted to a Me.sub.10Fc scale based on its half-wave potential measured at the end of the experiment by adding 2 mM Me.sub.10Fc to the electrolyte (as per FIG. 18).

[0027] FIG. 11 is a graph depicting calibration curves relating UV-vis absorbance at (panel a) 364 nm and (panel b) 293 nm to the concentration of I.sub.3.sup.− in prepared DME solutions.

[0028] FIG. 12 is a graph depicting calibration curves relating UV-vis absorbance at 366 nm and 297 nm to the concentration of I.sub.3.sup.− in prepared DMSO solutions.

[0029] FIG. 13 is a graph depicting calibration curves relating UV-vis absorbance at 367 nm and 296 nm to the concentration of I.sub.3.sup.− in prepared G4 solutions.

[0030] FIG. 14 is a graph depicting a calibration curve relating UV-vis absorbance at 368 nm to the concentration of I.sub.3.sup.− in prepared pyridine solution.

[0031] FIG. 15 is a graph depicting UV-vis absorbance of pure solvents, with I.sub.3.sup.− peaks marked. The solvent's inherent absorbance interferes with the observation of 293 nm I.sub.3.sup.− peak in pyridine and Me-Im.

[0032] FIG. 16 is a graph depicting XRD reference spectra of commercial Li.sub.2O.sub.2, LiOH, LiOH—H.sub.2O, LiI, LiIO.sub.3 and DMSO.sub.2.

[0033] FIG. 17 is a photograph depicting observed corrosion of 316 stainless steel current collector following cycling of a cell with 0.1M LiI in DMSO.

[0034] FIG. 18 is a graph depicting details on how the Ag.sup.+/Ag reference electrode scale was converted to a Me.sub.10Fc scale. All measurements were made on the potentiostat against the Ag.sup.+/Ag reference electrode. The Me.sub.10Fc half-wave potential was obtained by adding 2 mM Me.sub.10Fc to the electrolyte at the end of the experiment and measuring its CV at 100 mVps. The half-wave potential of Me.sub.10Fc was determined based on taking the average potential of the anodic and cathodic peaks. The position of this Me.sub.10Fc potential on the Ag.sup.+/Ag scale was then used to determine the positions of other redox transitions on the Me.sub.10Fc scale.

[0035] FIG. 19 is a graph depicting possible correlations between solvent DN and measured half-wave potentials for I.sup.−/I.sub.3.sup.− (squares), I.sub.3.sup.−/I.sub.2 (Xs) and Li/Li.sup.+ (open circles).

[0036] FIG. 20 is a graph depicting possible correlations between solvent AN and measured half-wave potentials for I.sup.−/I.sub.3.sup.− (squares), I.sub.3.sup.−/I.sub.2 (Xs) and Li/Li.sup.+ (open circles).

[0037] FIG. 21 is a graph depicting possible correlations between solvent dielectric constant and measured half-wave potentials for I.sup.−/I.sub.3.sup.− (squares), I.sub.3.sup.−/I.sub.2 (Xs) and Li/Li.sup.+ (open circles).

[0038] FIG. 22 is a graph depicting: (panel a) color changes when solutions of 50 mM I.sub.3.sup.− are added to 0.1 M synthetic Li.sub.2O.sub.2; (panel b) UV-vis spectra of the liquid phase before and after the reaction with Li.sub.2O.sub.2 confirm the consumption of I.sub.3.sup.−; and (panel c) the concentrations of I.sub.3.sup.− before and after adding the solution to a two times excess of Li.sub.2O.sub.2. I.sub.3.sup.− concentrations were determined through UV-Vis Spectroscopy. Error bars were estimated based on the accuracy of the mass balance used during preparation of diluted samples of +/−0.5 mg. Calibration curves for each solvent can be found in FIG. 11-14.

[0039] FIG. 23 is a graph depicting full, unscaled adsorption spectra of the liquid phase retrieved after the reaction between I.sub.3.sup.− and Li.sub.2O.sub.2 in DMA, DMSO and Me-Im.

[0040] FIG. 24 is a graph depicting Raman spectra of commercial Li.sub.2O.sub.2 and LiTFSI for reference, as well as the solid recovered after the reaction between synthesized Li.sub.2O.sub.2 and I.sub.3.sup.− in G4, DME, Pyridine, DMA, DMSO and Me-Im.

[0041] FIG. 25 is a graph depicting details of GC experiments measuring the O.sub.2 generation due to the reaction between I.sub.3.sup.− and Li.sub.2O.sub.2 in DMSO.

[0042] FIG. 26 is a graph depicting the concentration of I.sub.2 present before and after the reaction between I.sub.2 and Li.sub.2O.sub.2 in DME, DMA and DMSO.

[0043] FIG. 27 is a graph depicting measured extent of reaction determined by UV-Vis of solutions of I.sub.2 in DME with different starting concentrations of LiI with both commercial Li.sub.2O.sub.2 and Li.sub.2O.sub.2 formed through disproportionation. Calculated values based on the reaction stopping when only I.sub.3.sup.− remains are shown as dashed gray lines.

[0044] FIG. 28 is a graph depicting Raman of solutions of mixtures of I.sub.2 and LiI in DME taken before and after reaction with Li.sub.2O.sub.2.

[0045] FIG. 29 is a graph depicting .sup.1H NMR spectra of pure solvent as well as the liquid phase recovered following the reaction with Li.sub.2O.sub.2 and LiOH. All .sup.1H NMR samples were prepared by mixing 0.5 mL of the sample+0.1 mL of DMSO-D6 (for NMR locking)+10 μL of MeCN internal reference (for quantification).

[0046] FIG. 30 is a graph depicting reference .sup.1H NMR spectra of commercial dimethyl sulfone (DMSO.sub.2) added to DMSO-D6 with contaminate water.

[0047] FIG. 31 is a graph depicting .sup.1HNMR spectra showing the change in proton exchange dynamics of Me-Im after creating a solution with 50 mM I.sub.2 and 0.2M LiI.

[0048] FIG. 32 is a graph depicting iodination of Me-Im led to loss of the I.sub.3.sup.− peak in UV-vis.

[0049] FIG. 33 is a graph depicting XRD of electrodes discharged in 0.1M LiI+0.5M LiTFSI solutions in G2 and DMSO. G2 electrode was discharged for 20 hours at 0.05 mA/cm.sup.2 which corresponded to its total capacity before sudden death, DMSO electrode was discharged for 40 hours at 0.05 mA/cm.sup.2 to allow more easy identification of the discharge product.

[0050] FIG. 34 is a graph depicting I.sub.3.sup.− concentration of solutions of 50 mM I.sub.3.sup.− (0.2 M LiI+50 mM I.sub.2) in a range of solvents before and after reaction with 0.2 M LiOH.

[0051] FIG. 35 is a graph depicting UV-vis spectra of solutions of I.sub.3.sup.− in DME (left) and DMSO (right) before and after reaction with 0.2 M LiOH, confirming the consumption of I.sub.3.sup.− in DMSO, but that I.sub.3.sup.− remains in DME.

[0052] FIG. 36 is a graph depicting Raman spectra of LiOH and LiOH—H.sub.2O powder compared with the solid recovered after the reaction between I.sub.3.sup.− and a two times excess of LiOH in G4, DME, pyridine, DMA, DMSO and Me-Im.

[0053] FIG. 37 is a graph depicting GC measurements during the reaction between LiOH and I.sub.3.sup.− in DMSO show no detectable quantity of O.sub.2 generated.

[0054] FIG. 38 is a graph depicting XRD of solid recovered after the reaction between LiOH and a two times excess of I.sub.3.sup.− in DMSO.

[0055] FIG. 39 is a graph depicting Raman spectra collected before and during the reaction between I.sub.3.sup.− and LiOH in DMSO. Measurements were taken by directly measuring the solution phase of a 50 mM I.sub.3.sup.− DMSO solution in a vial either with (red) or without (blue) LiOH present (during the initial stages of the reaction.

[0056] FIG. 40 is a graph depicting XRD patterns of preloaded electrodes following charging in G2 and DMSO compared with references for LiOH, LiOH—H.sub.2O and LiIO.sub.3. Electrodes show only peaks present on XRD taken on the pristine carbon paper (CP) and LiOH.

[0057] FIG. 41 is a graph depicting (panel a) Calculated thermodynamics of the oxidation of Li.sub.2O.sub.2(black) and LiOH(blue) to O.sub.2 (solid) and LiIO.sub.3 (dotted). These values are overlayed with the measured half-wave potentials of the I.sup.−/I.sub.3.sup.− and I.sub.3.sup.−/I.sub.2 redox couples in DME, DMA and DMSO. (panel b) Predicted selectivity towards O.sub.2 and LiIO.sub.3 formation based on the minimum O—O distance in the crystal lattice.

[0058] FIG. 42 is a graph depicting DEMS from cells with and without KO.sub.2 in between glass fiber separators in 0.1M KI in G2. I.sub.3.sup.−/I.sub.2 is formed at the positive carbon paper electrode can diffuse towards the negative electrode where it can be chemically reduced by the K metal plated onto the Cu film creating shuttling between the electrodes as has been shown previously. If KO.sub.2 is present between the separators (electronically isolated from both electrodes), it can also be oxidized by the I.sub.3.sup.−/I.sub.2 in the electrolyte and give off O.sub.2 gas and enhance capacity.

[0059] FIG. 43 is a graph depicting solid phase after the reaction between Li.sub.2O and I.sub.3.sup.− in DMSO shows clear evidence of LiIO.sub.3 through Raman (top) and XRD (bottom).

[0060] FIG. 44 is a graph depicting comparison of the color of 12 solutions in hexane (left) and DME (right). The purple color indicates the absence of I.sub.3.sup.− and therefore no Solvent-I.sup.+ complexes.

[0061] FIG. 45 is a graph depicting the liquid phase (left) and solid phase (right) following the reaction between hexane and commercial Li.sub.2O.sub.2.

[0062] FIG. 46 is a graph depicting Raman spectra of the solid recovered after the reaction between Li.sub.2O.sub.2 and I.sub.2 in hexane. Peaks are consistent with Li.sub.2O.sub.2 and solid LiI.sub.3 (which may have a slightly shifted peak compared with I.sub.3.sup.− in solution.

[0063] FIG. 47 is a graph depicting Raman spectra of the solution recovered after the reaction between I.sub.2 and LiOH in DME compared to reference spectra for solutions of I.sub.3.sup.− and I.sub.2 in DME. Spectra show on I.sub.3.sup.− remains after the reaction.

[0064] FIG. 48 is a graph depicting Raman spectra of LiOH synthesized via the disproportionation of KO.sub.2 in a two times excess of LiTFSI in MeCN with added water. Spectra indicates the anhydrous phase of LiOH was formed.

[0065] FIG. 49 is an image of vials following the reaction between 200 μmol of synthetic LiOH and 1 mL of 50 mM I.sub.3.sup.− solution (50 μmol I.sub.3.sup.−, LiOH:I.sub.3.sup.−=4:1)) after 96 hours. Similar to the commercial LiOH, the DMSO solution became colorless after ˜1 hour, the DMA solution became colorless after ˜96 hours and the DME solution did not change color.

[0066] FIG. 50 is a graph depicting XRD and SEM of the commercial LiIO.sub.3 used to construct LiIO.sub.3 battery electrodes.

[0067] FIG. 51 is a drawing depicting a schematic of cell used to test discharge process.

[0068] FIG. 52 is a graph depicting sample discharge profile (discharged at C/40) of composite electrodes constructed with commercial LiIO.sub.3, carbon and a PvDF binder.

[0069] FIG. 53 is a graph depicting sample discharge profile (discharged at 0.1 mA/cm2) of electrodes prepared by drop casting LiIO.sub.3 and Vulcan carbon onto carbon paper substrate.

[0070] FIG. 54 is a graph depicting Raman spectra on electrodes after discharge show the clear formation of anhydrous LiOH.

[0071] FIG. 55 is a graph depicting XRD on electrodes after discharge show the clear formation of anhydrous LiOH.

[0072] FIG. 56 is a micrograph depicting SEM of a pristine composite electrode made from LiIO.sub.3, carbon and PvDF binder.

[0073] FIG. 57 is a micrograph depicting SEM of a discharged composite electrode made from LiIO.sub.3 shows clear morphological changes.

[0074] FIG. 58 is a graph depicting discharge profile (bottom) and results of titrations to quantify the amount of formed LiOH and LiIO.sub.3 (top) for cells discharged in different solvents with O.sup.0V % added H.sub.2O.

[0075] FIG. 59 is a. graph depicting (left) XRD and (right) Raman characterization on the discharged electrodes demonstrate the consumption of LiIO.sub.3 and formation of LiOH on discharge

[0076] FIG. 60 is a graph depicting discharge profile (bottom) and results of titrations to quantify the amount of formed LiOH and LiIO.sub.3 (top) for cells discharged in DME with different amounts of added H.sub.2O.

[0077] FIG. 61 is a graph depicting (left) XRD and (right) Raman characterization on the discharged electrodes demonstrate the consumption of LiIO.sub.3 and formation of LiOH on discharge.

[0078] FIG. 62 is a set of micrographs depicting SEM images of pristine (left) and discharged (right) electrodes demonstrate substantial morphological changes during discharge, consistent with dissolution of reactants and precipitation of reaction products.

[0079] FIG. 63 is a graph depicting solubilities of LiOH and LiIO.sub.3 measured with inductively coupled plasma (ICP) indicate solubility in the mM region with added H.sub.2O in the electrolyte. Viscodensity measurements indicate high viscosity and a linear relationship between the volume of added water and its resulting concentration in the mixed electrolyte.

[0080] FIG. 64 is a graph depicting overpotentials during discharge are consistent with mass transport limitations as evidenced by the linear relationship between overpotential and log(viscosity/LiIO.sub.3 solubility).

[0081] FIG. 65 is a graph depicting discharge process is proposed to go through a three step process of 1) dissolution of LiIO.sub.3 2) electrochemical reduction of IO.sub.3.sup.− to OH.sup.− and 3) precipitation of LiOH.

DETAILED DESCRIPTION

[0082] Lithium oxygen batteries (a potential alternate positive electrode chemistry) work by reacting oxygen in its gaseous form with lithium ions to form lithium peroxide on discharge and then reforming oxygen gas and lithium ions on charge. The lithium oxygen approach can be thought of as the opposite approach to lithium ion as the entire solid structure of lithium peroxide formed on discharge is decomposed into ions and gaseous oxygen on charge. While this approach leads to a significantly higher theoretical energy density, it poses significant challenges such as the reactivity of reaction intermediate and the challenges associated with such an extreme state change between the discharged and charged forms.

[0083] The positive electrode chemistry developed herein takes an intermediate approach to those of lithium ion and lithium oxygen batteries. During discharge (reaction 1), solid lithium iodate reacts with water in the electrolyte to form solid lithium hydroxide. On charge, the process is reversed (reaction 2 and 3) and lithium iodate is regenerated. This is achieved by exploiting the fact that the soluble lithium iodide forms on discharge acts as a soluble redox mediator, allowing the process to happen in solution. Since the solid structure is different between the charged and discharged states, the fundamental concern of structural stability in both the lithiated and delithiated states is potentially circumvented. Additionally, since the phase transition is not as extreme as lithium oxygen batteries, some of these challenges may also be mitigated.

Discharge:

[0084]
LiHO.sub.3+3H.sub.2O+5Li.sup.++6e.sup.−.fwdarw.I.sup.−+6LiOH  (1)

Charge:

[0085]
2I.sup.−.fwdarw.I.sub.2+2e.sup.−  (2)

6LiOH+3I.sub.2.fwdarw.5Li.sup.++5I.sup.−+3H.sub.2O+LiO.sub.3  (3)

[0086] FIG. 8 schematically illustrates a rechargeable battery 1, which includes anode 2, cathode 3, electrolyte 4, anode collector 5, and cathode collector 6. The battery can include a housing including an electrolyte (not shown). The battery can be a lithium battery, for example, a lithium-halogen oxyanion battery.

[0087] The electrolyte can include an aprotic solvent. The aprotic solvent can be 1,2-dimethoxyethane (DME), pyridine, DMA, Me-Im, G2 or G4. The electrolyte can include a salt, such as, both lithium bis(trifluromethane sulfonyl)-imide (LiTFSI) or lithium iodide (LiI).

[0088] The halogen oxyanion electrode, or positive electrode, can be a mixture of a halogen oxyanion salt and a conductive material. The conductive material can include carbon black, graphene, carbon nanotubes, or graphite. A binder, such as a polymer, can be applied hold the components of the electrode together, for example, a poly(carboxylic acid), poly(carboxylic acid), poly(acrylic acid) (PAA), poly-(methacrylic acid) (PMAA), poly(ethylene oxide) (PEO), poly(vinyl alcohol), or poly(vinylpyrrolidone).

[0089] The active material of the electrode is the halogen oxyanion salt. The halogen oxyanion salt can be a lithium salt, a sodium salt or a potassium salt. The halogen oxyanion salt can be a chlorate salt, a bromate salt or an iodate salt. Alternatively, the halogen oxyanion salt can be formed during a charging cycle by reaction of a metal hydroxide and a metal halide salt, for example, lithium hydroxide in the presence of lithium iodide.

[0090] The negative electrode can include lithium, sodium or potassium. In specific examples, the metal electrode can include lithium metal or a lithium compound, such as a lithium metal oxide (e.g., a lithium cobalt oxide or a lithium manganese oxide), lithiated graphite or silicon, or other metal ion complex. The term “battery” as used herein includes primary and secondary (rechargeable) batteries.

[0091] The separators that directly contact on the electrode can include porous organic polymers or porous glass separators. The separator permits ionic conduction but not electrical conduction between the electrodes.

[0092] In one implementation of this chemistry, an electrode resembling a conventional lithium ion composite electrode (active material+carbon+binder) is made using either lithium iodate or lithium hydroxide as the active material (depending on if the battery is assembled in its charged or discharged state). This chemistry is found to be highly sensitive to the electrolyte composition. In initial studies, an electrolyte based on 1,2-dimethoxyethane (DME) with both lithium bis(trifluromethane sulfonyl)-imide (LiTFSI) and lithium iodide (LiI) salts as well as added water (5-10 weight percent) has been used. The combined effect of a weakly interacting aprotic solvent (DME) and strong water-iodide interactions has been found to enhance the protonation of water (necessary for improving the discharge process (reaction 1)). The charge process has already been identified as a parasitic process on charging on lithium hydroxide based battery chemistries with lithium iodide present. It is unclear whether this occurs based on forming iodine (I.sub.2) as shown in reaction 2, or whether a triiodide (I.sub.3.sup.−) or pentaiodide (I.sub.5.sup.−) intermediate is instead formed.

[0093] A cell based on this chemistry would need sufficient electrode porosity to allow water and iodide to reach all active material in the positive electrode, however, since both discharged and charged states are either solid/insoluble in the electrolyte, or soluble in the electrolyte, an open, gas positive electrode (such as those used in lithium oxygen batteries) is not needed—improving volumetric energy density. The cell would likely have to be kept free of molecular oxygen to avoid parasitic reactions. This positive electrode could be paired with any negative electrode which is based on lithium ions (lithiated graphite/silicon, lithium metal, etc). Some protection of the negative electrode from water in the electrolyte is likely necessary.

[0094] While the above chemistry is based on lithium and iodide oxyanions, similar chemistries may be possible based on substituting lithium for other alkali metals such as sodium and potassium or substituting iodine for other halides such as bromine, chlorine or fluorine.

Calculated Theoretical Gravimetric Energy Density (Positive Electrode Active Material Only)

[0095]

TABLE-US-00001 Lithium ion (LCO)  875-1000 Whr/kg Lithium oxygen 3250-3450 Whr/kg Lithium iodate/hydroxide 1550-1750 Whr/kg

[0096] Lithium iodide (LiI) has been extensively studied as a soluble redox mediator in Li—O.sub.2 batteries in order to catalyze the charging process. Despite some promising initial results, serious ambiguities exist in the literature regarding the reactivity between oxidized iodide species (I.sub.3.sup.−/I.sub.2) and the products formed during discharge (Li.sub.2O.sub.2/LiOH). In this work, we systematically examined the solvent-dependence of the oxidizing power of I.sub.3.sup.−/I.sup.− and I.sub.2/I.sub.3.sup.− towards Li.sub.2O.sub.2/LiOH through the use of ex-situ chemical reactions where the liquid reaction products were examined using UV-vis spectroscopy and .sup.1H NMR, the solid reaction products were studied by Raman spectroscopy and XRD and the gaseous products were assessed using gas chromatography. In addition, the role of I.sup.− on the charging of Li—O.sub.2 batteries and LiOH pre-loaded cells was examined using DEMS, where the amount of oxygen release was quantified. Stronger solvation of Li.sup.+ and I.sup.− ions can lead to an increase in the oxidizing power of I.sub.3.sup.−, which allowed I.sub.3.sup.− to oxidize Li.sub.2O.sub.2/LiOH in stronger solvents, such as DMA, DMSO and Me-Im, whereas in weaker solvents (G4, DME), the more oxidizing I.sub.2 was needed before a reaction could occur. It was observed that Li.sub.2O.sub.2 was oxidized to O.sub.2, whereas LiOH was oxidized to an IO.sup.− intermediate, which could either disproportionate to LiIO.sub.3 or attack solvent molecules. Based on observed reactions with KO.sub.2/Li.sub.2O, we propose that while LiIO.sub.3 formation is thermodynamically favored, O.sub.2 gas evolution dominates in the oxidation of Li.sub.2O.sub.2 due to a kinetic barrier to O—O bond dissociation in the formation of LiIO.sub.3.

[0097] In general, lithium-oxygen batteries offer considerably higher gravimetric energy density than commercial Li-ion batteries (up to three times). Despite this promise, rechargeable nonaqueous Li—O.sub.2 batteries suffer from considerable fundamental issues relating to cycle life, parasitic reactions and poor round trip efficiency. Some of the most significant issues stem from the poor kinetics of Li.sub.2O.sub.2 oxidation on charge, which leads to high overpotential and considerable parasitic reactions. Soluble redox mediators, such as LiI, have been proposed as a potential solution to this problem, however, despite a number of promising initial results, there exists considerable discrepancy in the literature regarding the oxidizing power of I.sub.3.sup.−/I.sub.2 (the oxidized species formed during charge) against both Li.sub.2O.sub.2 and LiOH (potential discharge products of the Li—O.sub.2 chemistry), as well as the product formed by their oxidation. Some studies have suggested that I.sub.3.sup.− can oxidize Li.sub.2O.sub.2/LiOH, while others suggest the more oxidizing I.sub.2 is needed to react with Li.sub.2O.sub.2/LiOH and others still have claimed that LiOH is inactive in the presence of I.sub.3.sup.−/I.sub.2. There are studies that claim LiOH is oxidized reversibly to O.sub.2, whereas others claim it is irreversibly oxidized to LiIO.sub.3. In this study, we use detailed quantifications, a wide range of characterization techniques and cells constructed with a solid Li-conducting separator to eliminate shuttling in order to resolve these ambiguities. We show that the oxidizing power of I.sub.3.sup.− is solvent-dependent and can oxidize Li.sub.2O.sub.2/LiOH in stronger solvents (DMA, DMSO and Me-Im), but the more oxidizing I.sub.2 is required in weaker solvents like DME and G4. Furthermore, we show that Li.sub.2O.sub.2 is oxidized to O.sub.2, whereas LiOH is irreversibly oxidized to IO.sup.− which can either disproportionate to form LiIO.sub.3 or attack solvent molecules.

[0098] There has been considerable interest in nonaqueous Li—O.sub.2 batteries in the past decade due to their high theoretical gravimetric energy density (potentially up to 3 times that of commercial lithium ion batteries). See, for example, Aurbach, D., McCloskey, B. D., Nazar, L. F. & Bruce, P. G. Advances in understanding mechanisms underpinning lithium-air batteries. Nat. Energy 1, 16128 (2016); Bruce, P. G., Freunberger, S. A., Hardwick, L. J. & Tarascon, J.-M. Li—O2 and Li—S batteries with high energy storage. Nat. Mater. 11, 19-29 (2011); and Kwabi, D. G. et al. Materials challenges in rechargeable lithium-air batteries. MRS Bull. 39, 443-452 (2014), each of which is incorporated by reference in its entirety. This large theoretical improvement in gravimetric energy density stems from the fundamentally different reactions of the Li—O.sub.2 battery chemistry, which relies on reducing gaseous oxygen to form solid lithium peroxide (2Li+O.sub.2═Li.sub.2O.sub.2, E.sup.0=2.96 V.sub.Li) or lithium oxide (2Li.sup.+O.sub.2═Li.sub.2O, E.sup.0=2.91 V.sub.Li). Previous work shows that the discharge of nonaqueous Li—O.sub.2 batteries can produce Li.sub.2O.sub.2 with low overpotential, the morphology of which is dependent on the solvent, counter anion and potential/rate. See, for example, Lu, Y.-C. et al. Lithium-oxygen batteries: bridging mechanistic understanding and battery performance. Energy Environ. Sci. 6, 750 (2013); Viswanathan, V. et al. Li—O.sub.2 Kinetic Overpotentials: Tafel Plots from Experiment and First-Principles Theory. J. Phys. Chem. Lett. 4, 556-560 (2013); Kwabi, D. G. et al. Experimental and Computational Analysis of the Solvent-Dependent O.sub.2/Li.sup.+—O.sub.2.sup.− Redox Couple: Standard Potentials, Coupling Strength, and Implications for Lithium-Oxygen Batteries. Angew. Chem. Int. Ed. 55, 3129-3134 (2016); Johnson, L. et al. The role of LiO2 solubility in O2 reduction in aprotic solvents and its consequences for Li—O.sub.2 batteries. Nat. Chem. 6, 1091-1099 (2014); Sharon, D. et al. Mechanistic Role of Li.sup.+ Dissociation Level in Aprotic Li—O.sub.2 Battery. ACS Appl. Mater. Interfaces 8, 5300-5307 (2016); Burke, C. M., Pande, V., Khetan, A., Viswanathan, V. & McCloskey, B. D. Enhancing electrochemical intermediate solvation through electrolyte anion selection to increase nonaqueous Li—O.sub.2 battery capacity. Proc. Natl. Acad. Sci. 112, 9293-9298 (2015); Kwabi, D. G. et al. Controlling Solution-Mediated Reaction Mechanisms of Oxygen Reduction Using Potential and Solvent for Aprotic Lithium-Oxygen Batteries. J. Phys. Chem. Lett. 7, 1204-1212 (2016); and Mitchell, R. R., Gallant, B. M., Shao-Hom, Y. & Thompson, C. V. Mechanisms of Morphological Evolution of Li.sub.2O.sub.2 Particles during Electrochemical Growth. J. Phys. Chem. Lett. 4, 1060-1064 (2013), each of which is incorporated by reference in its entirety. Unfortunately, charging rechargeable Li—O.sub.2 batteries with nonaqeuous electrolytes requires a high overpotential to liberate molecular oxygen and this reaction is considerably more irreversible at high potentials as shown by McCloskey et al., leading to poor round-trip efficiency and cycle life resulting from parasitic side reactions. See, for example, McCloskey, B. D. et al. Combining Accurate O.sub.2 and Li.sub.2O.sub.2 Assays to Separate Discharge and Charge Stability Limitations in Nonaqueous Li—O.sub.2 Batteries. J. Phys. Chem. Lett. 4, 2989-2993 (2013); Aurbach, D., McCloskey, B. D., Nazar, L. F. & Bruce, P. G. Advances in understanding mechanisms underpinning lithium-air batteries. Nat. Energy 1, 16128 (2016); Bruce, P. G., Freunberger, S. A., Hardwick, L. J. & Tarascon, J.-M. Li—O.sub.2 and Li—S batteries with high energy storage. Nat. Mater. 11, 19-29 (2011); and Kwabi, D. G. et al. Materials challenges in rechargeable lithium-air batteries. MRS Bull. 39, 443-452 (2014), each of which is incorporated by reference in its entirety. Therefore, considerable efforts have been placed on attempting to catalyze the charging process in Li—O.sub.2 batteries. See, for example, Lim, H.-D. et al. Rational design of redox mediators for advanced Li—O.sub.2 batteries. Nat. Energy 1, 16066 (2016); Lim, H.-D. et al. Superior Rechargeability and Efficiency of Lithium-Oxygen Batteries: Hierarchical Air Electrode Architecture Combined with a Soluble Catalyst. Angew. Chem. Int. Ed. 53, 3926-3931 (2014); Liu, T. et al. Cycling Li—O.sub.2 batteries via LiOH formation and decomposition. Science 350, 530-533 (2015); Bergner, B. J., Schurmann, A., Peppler, K., Garsuch, A. & Janek, J. TEMPO: A Mobile Catalyst for Rechargeable Li—O.sub.2 Batteries. J. Am. Chem. Soc. 136, 15054-15064 (2014); Kwak, W.-J. et al. Li—O.sub.2 cells with LiBr as an electrolyte and a redox mediator. Energy Env. Sci 9, 2334-2345 (2016); Kwak, W.-J. et al. Understanding the behavior of Li-oxygen cells containing LiI. J Mater Chem A 3, 8855-8864 (2015); Chen, Y., Freunberger, S. A., Peng, Z., Fontaine, O. & Bruce, P. G. Charging a Li—O.sub.2 battery using a redox mediator. Nat. Chem. 5, 489-494 (2013); Sun, D. et al. A Solution-Phase Bifunctional Catalyst for Lithium-Oxygen Batteries. J. Am. Chem. Soc. 136, 8941-8946 (2014); Feng, N., He, P. & Zhou, H. Enabling Catalytic Oxidation of Li.sub.2O.sub.2 at the Liquid-Solid Interface: The Evolution of an Aprotic Li—O.sub.2 Battery. ChemSusChem 8, 600-602 (2015); Kundu, D., Black, R., Adams, B. & Nazar, L. F. A Highly Active Low Voltage Redox Mediator for Enhanced Rechargeability of Lithium-Oxygen Batteries. ACS Cent. Sci. 1, 510-515 (2015); Torres, W. R., Herrera, S. E., Tesio, A. Y., Pozo, M. del & Calvo, E. J. Soluble TTF catalyst for the oxidation of cathode products in Li—Oxygen battery: A chemical scavenger. Electrochimica Acta 182, 1118-1123 (2015); Wu, S., Tang, J., Li, F., Liu, X. & Zhou, H. Low charge overpotentials in lithium-oxygen batteries based on tetraglyme electrolytes with a limited amount of water. Chem Commun 51, 16860-16863 (2015); Zhu, Y. G. et al. Dual redox catalysts for oxygen reduction and evolution reactions: towards a redox flow Li—O.sub.2 battery. Chem Commun 51, 9451-9454 (2015); Pande, V. & Viswanathan, V. Criteria and Considerations for the Selection of Redox Mediators in Nonaqueous Li—O.sub.2 Batteries. ACS Energy Lett. 2, 60-63 (2016); Yao, K. P. C. et al. Utilization of Cobalt Bis(terpyridine) Metal Complex as Soluble Redox Mediator in Li—O.sub.2 Batteries. J. Phys. Chem. C 120, 16290-16297 (2016); Zeng, X. et al. Enhanced Li—O 2 battery performance, using graphene-like nori-derived carbon as the cathode and adding LiI in the electrolyte as a promoter. Electrochimica Acta 200, 231-238 (2016); Zhang, W. et al. Promoting Li2O2 oxidation via solvent-assisted redox shuttle process for low overpotential Li—O 2 battery. Nano Energy 30, 43-51 (2016); and Zhang, T., Liao, K., He, P. & Zhou, H. A self-defense redox mediator for efficient lithium-O.sub.2 batteries. Energy Env. Sci 9, 1024-1030 (2016), each of which is incorporated by reference in its entirety.

[0099] While solid-state catalysts have been employed to reduce the overpotential during charge, including metal oxides, modified carbon and metals/metal alloys, these catalysts rely on good electrical contact between Li.sub.2O.sub.2 and the catalyst throughout the entire charging process and do not suppress side reactions during charging. See, for example, Xu, J.-J. et al. Synthesis of Perovskite-Based Porous La.sub.0.75Sr.sub.0.25MnO.sub.3 Nanotubes as a Highly Efficient Electrocatalyst for Rechargeable Lithium-Oxygen Batteries. Angew. Chem. Int. Ed. 52, 3887-3890 (2013); Yao, K. P. C. et al. Solid-state activation of Li.sub.2O.sub.2 oxidation kinetics and implications for Li—O.sub.2 batteries. Energy Environ. Sci. 8, 2417-2426 (2015); Yin, Y.-B., Xu, J.-J., Liu, Q.-C. & Zhang, X.-B. Macroporous Interconnected Hollow Carbon Nanofibers Inspired by Golden-Toad Eggs toward a Binder-Free, High-Rate, and Flexible Electrode. Adv. Mater. 28, 7494-7500 (2016); Li, L. & Manthiram, A. O- and N-Doped Carbon Nanowebs as Metal-Free Catalysts for Hybrid Li-Air Batteries. Adv. Energy Mater. 4, 1301795 (2014); Shui, J. et al. Nitrogen-Doped Holey Graphene for High-Performance Rechargeable Li—O.sub.2 Batteries. ACS Energy Lett. 1, 260-265 (2016); Xu, J.-J., Wang, Z.-L., Xu, D., Zhang, L.-L. & Zhang, X.-B. Tailoring deposition and morphology of discharge products towards high-rate and long-life lithium-oxygen batteries. Nat. Commun. 4, (2013); Kwon, H.-M. et al. Effect of Anion in Glyme-based Electrolyte for Li—O.sub.2 Batteries: Stability/Solubility of Discharge Intermediate. Chem. Lett. 46, 573-576 (2017); and Wong, R. A. et al. Critically Examining the Role of Nanocatalysts in Li—O.sub.2 Batteries: Viability toward Suppression of Recharge Overpotential, Rechargeability, and Cyclability. ACS Energy Lett. 3, 592-597 (2018), each of which is incorporated by reference in its entirety. An alternative approach is the use of soluble redox mediators to promote electron transfer to the surface of the electronically insulating Li.sub.2O.sub.2, where the redox mediator is first electrochemically oxidized at the electrode surface and then the oxidized form of the redox mediator chemically oxidizes Li.sub.2O.sub.2 to form Li.sup.+ ions and molecular oxygen and regenerate the reduced form of the redox mediator. See, for example, Radin, M. D. & Siegel, D. J. Charge transport in lithium peroxide: relevance for rechargeable metal-air batteries. Energy Environ. Sci. 6, 2370 (2013), which is incorporated by reference in its entirety. Many organic molecules like TEMPO, TDPA and TTF as well as inorganics like LiI and LiBr have been proposed as redox mediators. Lithium iodide (LiI) has received considerable attention owing to a number of studies suggesting high cycling performance.sup.14,15. See, for example, Lim, H.-D. et al. Superior Rechargeability and Efficiency of Lithium-Oxygen Batteries: Hierarchical Air Electrode Architecture Combined with a Soluble Catalyst. Angew. Chem. Int. Ed. 53, 3926-3931 (2014); Liu, T. et al. Cycling Li—O.sub.2 batteries via LiOH formation and decomposition. Science 350, 530-533 (2015); Bergner, B. J., Schurmann, A., Peppler, K., Garsuch, A. & Janek, J. TEMPO: A Mobile Catalyst for Rechargeable Li—O.sub.2 Batteries. J. Am. Chem. Soc. 136, 15054-15064 (2014); Kwak, W.-J. et al. Li—O.sub.2 cells with LiBr as an electrolyte and a redox mediator. Energy Env. Sci 9, 2334-2345 (2016); Kwak, W.-J. et al. Understanding the behavior of Li-oxygen cells containing LiI. J Mater Chem A 3, 8855-8864 (2015); Bergner, B. J. et al. Understanding the fundamentals of redox mediators in Li—O.sub.2 batteries: a case study on nitroxides. Phys. Chem. Chem. Phys. 17, 31769-31779 (2015);

[0100] Bergner, B. J. et al. How To Improve Capacity and Cycling Stability for Next Generation Li—O.sub.2 Batteries: Approach with a Solid Electrolyte and Elevated Redox Mediator Concentrations. ACS Appl. Mater. Interfaces 8, 7756-7765 (2016); Lee, D. J., Lee, H., Kim, Y.-J., Park, J.-K. & Kim, H.-T. Sustainable Redox Mediation for Lithium-Oxygen Batteries by a Composite Protective Layer on the Lithium-Metal Anode. Adv. Mater. 28, 857-863 (2016); Kundu, D., Black, R., Adams, B. & Nazar, L. F. A Highly Active Low Voltage Redox Mediator for Enhanced Rechargeability of Lithium-Oxygen Batteries. ACS Cent. Sci. 1, 510-515 (2015); and Torres, W. R., Herrera, S. E., Tesio, A. Y., Pozo, M. del & Calvo, E. J. Soluble TTF catalyst for the oxidation of cathode products in Li—Oxygen battery: A chemical scavenger. Electrochimica Acta 182, 1118-1123 (2015), each of which is incorporated by reference in its entirety. Lim et al. have suggested stable cycling with low overpotential over 900 cycles using LiI as a soluble redox mediator in a tetraglyme (G4) electrolyte with a CNT fibril electrode. In addition, Liu et al. have claimed to achieve 2000 cycles using LiI in a 1,2-dimethoxyethane (DME)-based electrolyte containing ˜5 v % H.sub.2O with a reduced graphene oxide electrode and LiOH as the dominant discharge product. See, for example, Lim, H.-D. et al. Superior Rechargeability and Efficiency of Lithium-Oxygen Batteries: Hierarchical Air Electrode Architecture Combined with a Soluble Catalyst. Angew. Chem. Int. Ed. 53, 3926-3931 (2014); and Liu, T. et al. Cycling Li—O.sub.2 batteries via LiOH formation and decomposition. Science 350, 530-533 (2015), each of which is incorporated by reference in its entirety. However, ambiguities exist in the influence of LiI on both the discharge and charge processes. See, for example, Kwak, W.-J. et al. Understanding the behavior of Li-oxygen cells containing LiI. J Mater Chem A 3, 8855-8864 (2015); Burke, C. M. et al. Implications of 4e.sup.− Oxygen Reduction via Iodide Redox Mediation in Li—O.sub.2 Batteries. ACS Energy Lett. 1, 747-756 (2016); Tulodziecki, M. et al. The role of iodide in the formation of lithium hydroxide in lithium-oxygen batteries. Energy Env. Sci (2017), Qiao, Y. et al. Unraveling the Complex Role of Iodide Additives in Li—O.sub.2 Batteries. ACS Energy Lett. 1869-1878 (2017); and Li, Y. et al. Li—O.sub.2 Cell with LiI (3-hydroxypropionitrile).sub.2 as a Redox Mediator: Insight into the Working Mechanism of I.sup.− during Charge in Anhydrous Systems. J. Phys. Chem. Lett. 4218-4225 (2017), each of which is incorporated by reference in its entirety.

[0101] LiI addition in the electrolyte can change the dominant discharge product from Li.sub.2O.sub.2 to LiOH, LiOH.H.sub.2O or LiOOH.H.sub.2O by decreasing the pK.sub.a of water in the electrolyte. See, for example, Liu, T. et al. Cycling Li—O.sub.2 batteries via LiOH formation and decomposition. Science 350, 530-533 (2015); Kwak, W.-J. et al. Understanding the behavior of Li-oxygen cells containing LiI. J Mater Chem A 3, 8855-8864 (2015); Burke, C. M. et al. Implications of 4e.sup.− Oxygen Reduction via Iodide Redox Mediation in Li—O.sub.2 Batteries. ACS Energy Lett. 1, 747-756 (2016); Tulodziecki, M. et al. The role of iodide in the formation of lithium hydroxide in lithium-oxygen batteries. Energy Env. Sci (2017); and iao, Y. et al. Unraveling the Complex Role of Iodide Additives in Li—O.sub.2 Batteries. ACS Energy Lett. 1869-1878 (2017); and Zhu, Y. G. et al. Proton enhanced dynamic battery chemistry for aprotic lithium-oxygen batteries. Nat. Commun. 8, 14308 (2017), each of which is incorporated by reference in its entirety. Adding water to DME-based electrolytes up to 5000 ppm still results in Li.sub.2O.sub.2 on discharge when no LiI is present. On the other, while the discharge of a Li—O.sub.2 battery forms Li.sub.2O.sub.2 in LiI-containing DME-based electrolytes without added water, the dominant discharge product can become LiOH (H.sub.2O>˜500 ppm) or LiOOH (H.sub.2O>˜5 v %) instead of Li.sub.2O.sub.2 with water addition in the electrolytes. See, for example, Burke, C. M. et al. Implications of 4e.sup.− Oxygen Reduction via Iodide Redox Mediation in Li—O.sub.2 Batteries. ACS Energy Lett. 1, 747-756 (2016); Tulodziecki, M. et al. The role of iodide in the formation of lithium hydroxide in lithium-oxygen batteries. Energy Env. Sci (2017); Qiao, Y. et al. Unraveling the Complex Role of Iodide Additives in Li—O2 Batteries. ACS Energy Lett. 1869-1878 (2017); Li, Y. et al. Li—O.sub.2 Cell with LiI (3-hydroxypropionitrile).sub.2 as a Redox Mediator: Insight into the Working Mechanism of I.sup.− during Charge in Anhydrous Systems. J. Phys. Chem. Lett. 4218-4225 (2017); Zhu, Y. G. et al. Proton enhanced dynamic battery chemistry for aprotic lithium-oxygen batteries. Nat. Commun. 8, 14308 (2017); and Kwabi, D. G. et al. The effect of water on discharge product growth and chemistry in Li—O.sub.2 batteries. Phys Chem Chem Phys 18, 24944-24953 (2016), each of which is incorporated by reference in its entirety. Specifically, at low H.sub.2O:LiI ratios (lower than 5), LiOH instead of Li.sub.2O.sub.2 has been observed, which is accompanied by the oxidation of iodide to triiodide, while at high H.sub.2O:LiI ratios, a mixture of Li.sub.2O.sub.2, LiOOH—H.sub.2O and LiOH—H.sub.2O has been observed with no triiodide detected.sup.44. The formation of LiOH and relevant products upon discharge is promoted by the lowered deprotonation energy of water due to the stronger solvation of water molecules by organic solvent molecules such as MeCN (Kwabi et al.) and the interactions between water molecules and anions such as I.sup.−. See, for example, Tulodziecki, M. et al. The role of iodide in the formation of lithium hydroxide in lithium-oxygen batteries. Energy Env. Sci (2017); and Kwabi, D. G. et al. The effect of water on discharge product growth and chemistry in Li—O.sub.2 batteries. Phys Chem Chem Phys 18, 24944-24953 (2016), each of which is incorporated by reference in its entirety. These studies have shown that the major proton source for the formation of LiOH/LiOH—H.sub.2O/LiOOH—H.sub.2O is added water and not the decomposition of solvents such as DME, which is supported by a subsequent computational work showing water as a more energetically favorable proton source for the formation of LiOH than DME. On the other hand, Qiao et al. and Kwak et al. have suggested iodide-catalyzed decomposition of G4 to promote the formation of LiOH based on the observation of greater LiOH with increasing amounts of LiI added to the electrolyte. This apparent discrepancy can be explained by the addition of water associated with the LiI used (Qiao et al. with dried LiI having >98%, Sigma Aldrich under vacuum at 80° C. overnight and Kwak et al. with anhydrous LiI, Sigma-Aldrich with no mention of drying).

[0102] I.sub.2 (which is more oxidizing than I.sub.3.sup.−) is required to oxidize Li.sub.2O.sub.2 and generate molecular O.sub.2 in anhydrous DME and G4. Ambiguities exist in what oxidized iodide species can oxidize Li.sub.2O.sub.2 and LiOH and what oxidation products, such as O.sub.2, are formed. For example, Qiao et al. have reported that I.sub.3.sup.− can oxidize peroxide-like species (in part Li.sub.2O.sub.2) to form O.sub.2 with water addition up to 30 v % in G4. See, for example, Qiao, Y. et al. Unraveling the Complex Role of Iodide Additives in Li—O.sub.2 Batteries. ACS Energy Lett. 1869-1878 (2017), which is incorporated by reference in its entirety. On the other hand, Zhu et al. discuss that the oxidation of Li.sub.2O.sub.2 requires the formation of I.sub.2 while LiOOH—H.sub.2O formed in diglyme (G2) and DMSO with 9.1 v % water can be oxidized to form O.sub.2 by I.sub.3.sup.−. See, for example, Zhu, Y. G. et al. Proton enhanced dynamic battery chemistry for aprotic lithium-oxygen batteries. Nat. Commun. 8, 14308 (2017), which is incorporated by reference in its entirety. Moreover, Liu et al.sup.15 have suggested that I.sub.3.sup.− can oxidize LiOH formed in DME and G4 with the addition of ˜5 v % water to generate O.sub.2. In addition, Zhu et al. have suggested that LiOH was oxidized to O2 by 12. See, for example, Zhu, Y. G. et al. Proton enhanced dynamic battery chemistry for aprotic lithium-oxygen batteries. Nat. Commun. 8, 14308 (2017), which is incorporated by reference in its entirety. However, the concept of LiOH oxidation to O.sub.2 by I.sub.3.sup.− is rebutted by Viswanathan et al. arguing the oxidation of LiOH by I.sub.3.sup.− as thermodynamically uphill in DME and Shen et al. suggesting that observed charge capacity is from iodine redox and inactive LiOH is accumulated. See, for example, Viswanathan, V. et al. Comment on ‘Cycling Li—O.sub.2 batteries via LiOH formation and decomposition’. Science 352, 667-667 (2016); and Shen, Y., Zhang, W., Chou, S.-L. & Dou, S.-X. Comment on ‘Cycling Li—O2 batteries via LiOH formation and decomposition’. Science 352, 667-667 (2016), each of which has been incorporated by reference in its entirety. Furthermore, Qiao et al. argued that LiOH was inactive in the presence of I.sub.3.sup.− and I.sub.2, and Burke et al. have proposed that LiOH is oxidized irreversibly to lithium iodate (LiIO.sub.3) by I.sub.2 in DME, which is in agreement with Liu et al. noting LiIO.sub.3 formation from LiOH formed in a 3 wt % water/DME solution. See, for example, Burke, C. M. et al. Implications of 4e.sup.− Oxygen Reduction via Iodide Redox Mediation in Li—O.sub.2 Batteries. ACS Energy Lett. 1, 747-756 (2016); Qiao, Y. et al. Unraveling the Complex Role of Iodide Additives in Li—O.sub.2 Batteries. ACS Energy Lett. 1869-1878 (2017); and Liu, T. et al. Response to Comment on “Cycling Li—O.sub.2 batteries via LiOH formation and decomposition”. Science 352, 667-667 (2016),

[0103] The discrepancies found for the oxidation of Li.sub.2O.sub.2 and LiOH by I.sub.3.sup.−/I.sub.2 in previous work may result from several factors. First, some previous claims of O.sub.2 evolution have not been supported by quantification of reaction products to ensure the amount of oxygen detected as the dominant path of the reaction but not from cell leakage or H.sub.2O.sub.2 contamination of the solvents. Second, the oxidizing power of I.sub.3.sup.− and I.sub.2 against Li.sub.2O.sub.2 or LiOH can be solvent-dependent. Generally speaking, I.sup.− ions go through two distinct redox transitions during oxidation in aprotic electrolytes, having first iodide anions (I.sup.−) oxidized to form triiodide (I.sub.3.sup.−) and I.sub.3.sup.− oxidized to form iodine (I.sub.2), where the potentials of the I.sup.−/I.sub.3.sup.− and I.sub.3.sup.−/I.sub.2 redox transitions can be significantly influenced by solvent. While it has been previously suggested that changes in these redox potentials may be important for the performance of LiI as a redox mediator in Li—O.sub.2 batteries, this effect has not been studied systematically. This concept is supported by a very recent study, where Nakanishi et al..sup.54 have shown that the thermodynamic shifts in the iodide redox on a lithium scale due to the effect of solvent and lithium concentration can change the oxidizing power of I.sub.3.sup.− against Li.sub.2O.sub.2 in 1 M and 2.8 M LiTFSI electrolytes in DMSO and G4 with 0.1 M LiI. See, for example, Nakanishi, A. et al. Electrolyte Composition in Li/O.sub.2 Batteries with LiI Redox Mediators: Solvation Effects on Redox Potentials and Implications for Redox Shuttling. J. Phys. Chem. C (2018), which is incorporated by reference in its entirety.

[0104] The role of LiI on the charging process of Li—O.sub.2 batteries can be examined by systematically studying the solvent-dependent oxidizing power of I.sub.3.sup.−/I.sup.− and I.sub.2/I.sub.3.sup.− towards Li.sub.2O.sub.2 and LiOH. The oxidizing power of I.sub.3.sup.−/I.sup.− and I.sub.2/I.sub.3.sup.− towards Li.sub.2O.sub.2 and LiOH was examined chemically by examining the consumption of I.sub.3.sup.− upon addition of synthetic Li.sub.2O.sub.2 (from disproportionation), where the liquid reaction product was examined using UV-vis spectroscopy and .sup.1H NMR, the solid reaction products were studied by Raman spectroscopy and XRD and the gaseous products were assessed using gas chromatography. In addition, the role of I.sup.− on the charging of Li—O.sub.2 batteries and LiOH-pre-loaded cells was examined using DEMS, where the amount of oxygen release was quantified. It is shown here that I.sub.3.sup.−/I.sup.− potentials increase with greater solvent AN, suggesting stronger solvation of I.sup.− while I.sub.2/I.sub.3.sup.− redox potentials are largely solvent independent. Therefore, stronger solvation of Li.sup.+ and I.sup.− ions in solvents such as DMA, DMSO and Me-Im can increase the oxidizing power of I.sub.3.sup.−/I.sup.−, allowing I.sub.3.sup.− to effectively oxidize Li.sub.2O.sub.2 to generate O.sub.2, which was supported by chemical and electrochemical experiments. On the other hand, in solvents where both I.sup.− and Li.sup.+ are weakly solvated such as glymes, I.sub.3.sup.−/I.sup.− redox potentials are not high enough to oxidize Li.sub.2O.sub.2 and the more oxidizing I.sub.2 is required for the oxidation of Li.sub.2O.sub.2 to O2 to proceed. The oxidation of LiOH by I.sub.3.sup.− was also found to be solvent dependent, where no reaction was observed in G4, DME and pyridine while the reaction proceeded to completion in DMA, DMSO and Me-Im where the I.sub.3.sup.−/I.sup.− redox potential was above ˜3.1 V.sub.Li. It is shown here that the reaction between LiOH and oxidized iodide species produced water and a hypoiodite (IO.sup.−) intermediate, which could either disproportionate to form LiIO.sub.3 or attack solvent molecules and result in decomposition products such as dimethyl sulfone (DMSO.sub.2). From GC of ex-situ reactions and DEMS during the charging of pre-loaded LiOH electrodes, no O.sub.2 gas evolution was observed during the reaction between LiOH and oxidized iodide species. The selectivity between O.sub.2 and the thermodynamically preferred LiIO.sub.3 can be governed by a kinetic barrier relating to O—O bond dissociation and this kinetic barrier prevents IO.sup.− formation, allowing for the evolution of gaseous O.sub.2 when oxidizing Li.sub.2O.sub.2, which was supported by reactions between oxidized iodide species and KO.sub.2/Li.sub.2O.

Experimental

I. Chemicals

[0105] High purity dimethyl sulfoxide (“DMSO”, Sigma Aldrich, anhydrous, >99.9%), diethylene glycol dimethyl ether (“G2”, Sigma Aldrich, anhydrous, 99.5%), N,N-dimethylacetamide (“DMA”, Sigma Aldrich, anhydrous, 99.8%), 1-methylimidazole (“Me-Im”, Sigma Aldrich, 99%), pyridine (Sigma Aldrich, anhydrous, 99.8%) and tetraethylene glycol dimethyl ether (Sigma Aldrich, >99%) were purchased and dried over molecular sieves for at least a week before use. 1,2-dimethoxyethane (DME) was purchased from Acros and was degassed and dried using a Glass Contour Solvent Purification System built by SGWater USA, LLC. Lithium bis(trifluoromethanesulfonyl)imide (“LiTFSI”, 99.99% extra dry grade from Solvay) was used as received. High purity LiI (ultra dry, 99.999% pure), I.sub.2 (99.9985% pure), Li.sub.2O.sub.2 (90%), Li.sub.2O (99.5%) and decamethylferrocene (“Me.sub.10Fc”, 99%) chemicals were ordered from Alfa Aesar and were used as received. LiOH (anhydrous, 99.995%) was purchased from Alfa Aesar and was further dried under vacuum for 24 hrs at 170° C. to ensure only the anhydrous phase remained (see FIG. 9). KO.sub.2 (99% pure) powder was purchased from Sigma Aldrich and was used as received.

[0106] All chemicals were stored in an argon-filled glovebox (MBraun, USA) with H.sub.2O and O.sub.2 content of <0.1 ppm. Electrolytes were prepared by dissolution of a desired amount of salts in the solvent with molarity determined by the volume of solvent added. The total H.sub.2O content in the solvents and electrolytes was checked using a C20 compact Karl Fisher coulometer from Mettler Toledo and for the dry solvent it was <20 ppm for ˜2 g of sample. A 20 wt % solution of LiTFSI in DME was found to have a slightly higher water content of 21 ppm (compared with 3.0 ppm for the pure DME solvent). Solutions of 0.2 M LiI in all solvents were clear, indicating the absence of H.sub.2O.sub.2 contamination, which can be of particular concern in glymes.

[0107] Due to the low purity of commercially available Li.sub.2O.sub.2 (90%), for most experiments, Li.sub.2O.sub.2 was first synthesized through the well-known disproportionation reaction between KO.sub.2 and Li-containing salt.sup.4:

2LiTFSI+2KO.sub.2.fwdarw.2KTFSI+Li.sub.2O.sub.2+O.sub.2  (1)

[0108] In all experiments, a two times excess of LiTFSI was used, the reaction occurred in the solvent being studied and the reaction was allowed to proceed for one hour with stirring to ensure complete production of Li.sub.2O.sub.2. The resulting solution of unconsumed LiTFSI and produced KTFSI as well as the precipitated Li.sub.2O.sub.2 was used directly without additional processing/washing. The presence of LiTFSI/KTFSI was assumed to have a negligible influence on subsequent reactions.

II. Redox Potential Measurements of I.sub.3.sup.−/I.sup.− and I.sub.2/I.sub.3.sup.− Redox Couples Using Cyclic Voltammograms

[0109] Cyclic voltammograms (CVs) were collected of solutions of 0.5M LiTFSI+10 mM LiI collected at 100 mVps under argon environment in each of the considered solvents. Electrolytes were prepared in an Argon-filled glove box (MBraun, <0.1 ppm H.sub.2O, <0.1 ppm O.sub.2) and transferred to a second Argon-filled glovebox directly through a shared antechamber (MBraun, <0.1 ppm H.sub.2O, <0.10% O.sub.2). The electrolyte was bubbled with Argon for at least 30 minutes prior to beginning electrochemistry. Due to the volatility of DME, for the DME experiment, the argon was first saturated with DME vapor by bubbling the Argon through pure DME prior to going to the electrolyte. The working macroelectrode was platinum and either a Li metal (G4, DME, DMSO) or lithium titanium oxide (pyridine, DMA, Me-Im) counter electrode was used. A fritted Ag/Ag.sup.+ reference electrode (0.1M TBAClO.sub.4+10 mM AgNO.sub.3 in MeCN) was used and following collection of CVs, 2 mM Me.sub.10Fc was added to the solution and CVs were collected to determine the Me.sub.10Fc half-wave potential. Li.sup.+/Li potentials were determined in G4, DME, DMA and DMSO using a piece of Li metal. See Table 2.

TABLE-US-00002 TABLE 2 Estimated half-wave potentials of I.sup.−/I.sub.3.sup.− and I.sub.3.sup.−/I.sub.2 vs Me.sub.10Fc Solvent I.sup.−/I.sub.3.sup.− vs Me.sub.10Fc I.sub.3.sup.−/I.sub.2 vs Me.sub.10Fc TEGDME 0.003 0.653 DME 0.018 0.632 Pyridine 0.286 0.496 DMA 0.069 0.648 DMSO 0.228 0.629 Me-Im 0.299 0.748

[0110] In addition to the two expected peaks associated with the I.sup.−/I.sub.3.sup.− and I.sub.3.sup.−/I.sub.2 redox transitions, both pyridine and Me-Im exhibit additional redox features (FIG. 10). Pyridine is known to in literature to form stable complexes with oxidized forms of iodide as well as adsorb strongly on platinum surfaces. One can therefore attribute the small peak at ˜−0.35V vs Me.sub.10Fc to an adsorption/desorption process (total charge passed ˜1.2×10.sup.−7 C) and the additional features in the I.sub.3.sup.−/I.sup.− and I.sub.2/I.sub.3.sup.− redox peaks to the formation of iodine-solvent complexes. Given the similarities in structure between Me-Im and pyridine, we suggest that similar iodine-solvent complexes are also possible in Me-Im and would account for the additional feature observed in the anodic sweep of the Me-Im CV. Since neither pyridine nor Me-Im are likely solvent candidates for lithium oxygen batteries due to instability issues, the precise origin and implications of these additional redox features in the presented CVs was not investigated further.

III. Using I.sup.−/I.sup.− and I.sub.3.sup.−/I.sub.2 for Chemical Li.sub.2O.sub.2 and LiOH Oxidation

[0111] In an argon-filled glovebox (MBraun, O.sub.2, H.sub.2O<0.1 ppm), solutions of I.sub.3.sup.− (0.2M LiI+50 mM I.sub.2) and I.sub.2 (50 mM I.sub.2) were first prepared in each solvent and allowed to fully dissolve under stirring. For studies of Li.sub.2O.sub.2, a two times excess of Li.sub.2O.sub.2 was first synthesized through disproportionation using 1 mL of the solvent to be studied and the reaction was allowed to proceed under stirring for ˜1 hour. For studies of LiOH, a two times excess of LiOH powder was added to 1 mL of solvent and allowed to reach equilibrium under stirring for ˜1 hour. Next, 1 mL of the I.sub.3.sup.−/I.sub.2 solution was added to the vial with Li.sub.2O.sub.2/LiOH and 1 mL of solvent. The reaction was allowed to take place under stirring for 24 hours, following which, the solid product was allowed to settle for 1 hour and the liquid and solid phases were separated. This ex-situ, chemical analog approach has been used extensively previously and has been very effective at isolating a chemical reaction to enable its independent study.

IV. Physical Characterization of Reaction Liquids, Solids and Gases

[0112] UV-Vis was performed using a Perkin Elmer Lambda 1050 UV/VIS/NIR Spectrophotometer. The pure solvent (e.g. G4, DME, etc.) was used as the blank solution, except in assessments of the pure solvent absorbance where no blank was used. Solutions were prepared in an Argon glovebox and sealed in a quartz cuvette used for data collection, preventing air exposure. Due to high molar absorptivity of I.sub.3.sup.−, the solutions with I.sub.3.sup.− were diluted in pure solvent so that the intensity of I.sub.3.sup.− absorption signals (at ˜293 nm and ˜364 nm) were within the calibration range (FIG. 12-14). The concentrations of triiodide were calculated based on the absorption intensity at the wavelength of the peak absorbance of the calibration curves. In the case where both peaks were distinguishable above the solvent's inherent absorbance (FIG. 15), the average of the concentration determined by both peaks was used. The absorption spectra in the figures are rescaled (arbitrary units) in order to visualize the difference in I.sub.3.sup.− concentration for different solutions. Thus, a high concentration of I.sub.3.sup.− corresponds to high absorption at wavelengths 293 nm and 364 nm and vice versa. The scale factors and the calculation of I.sub.3.sup.− concentrations are summarized in Table 1. Dilutions were calculated based on a mass balance of the added solvent and I.sub.3.sup.− solution. Error bars for the diluted samples were estimated based on an error of +/−0.5 mg in each weight measurement (+/−0.1 mg from the accuracy of the balance with additional error incurred due to a small amount of evaporation). In the case of determining the concentration of I.sub.2 in solution, the solution was first mixed with a ˜4 times excess of LiI to chemically form I.sub.3.sup.− in solution through the association of I.sub.2 and I.sup.−. The resulting I.sub.3.sup.− concentration was then determined using the as described above.

TABLE-US-00003 TABLE 1 UV-vis scaling factors applied in manuscript figures Scale in FIG. Data Dilutions FIG. 22 G4 D1 - 51.61 mg into 1983.49 mg pure G4 1 before D2 - 43.98 mg into 2967.27 mg pure G4 22 G4 D1 - 50.48 mg into 1991.72 mg pure G4 1 after D2 - 49.75 mg into 2976.53 mg pure G4 22 DME D1 - 43.71 mg into 1751.37 mg pure DME 0.955 before D2 - 41.1 mg into 2614.28 mg pure DME 22 DME D1 - 90.79 mg into 1750.39 mg pure DME 0.671 after D2 - 69.02 mg into 2611.43 mg pure DME 22 Pyridine D1 - 49.3 mg into 1953.19 mg pure Pyridine 1.254 before D2 - 46.18 mg into 2930.22 mg pure Pyridine 22 Pyridine D1 - 49.26 mg into 1960.9 mg pure Pyridine 0.762 after D2 - 44.68 mg into 2932.65 mg pure Pyridine 22 DMA Starting I.sub.3.sup.− concentration from mass balance 2.34 before 22 DMA 0.4 mL into 2.6 mL pure DMA 0.00417 after (scaled to reflect deviation from usual dilution) 22 DMSO Starting I.sub.3.sup.− concentration from mass balance 0.641 before 22 DMSO 0.4 mL into 2.6 mL pure DMSO 0.00417 after (scaled to reflect deviation from usual dilution) 22 Me-Im Starting I.sub.3.sup.− concentration from mass balance 1.468 before 22 Me-Im 0.4 mL into 2.6 mL pure Me-Im 0.00417 after (scaled to reflect deviation from usual dilution)

[0113] Iodometric titration was performed with a prepared 5 mM thiosulfate solution (anhydrous 99.99% Sigma-Aldrich, stored in desiccator) using a 50 mL burette (Class A, graduation 0.10 mL, tolerance ±0.05 mL from VWR) and starch indicator (1% w/v of Amylodextrin) in aqueous solution (18.2 MΩ.Math.cm, Millipore). The thiosulfate solution was first standardized with a KIO.sub.3 (99.995% pure from Sigma Aldrich) solution of a known concentration in three separate probes. 10 mL of KOI.sub.3 solution was added to Erlenmeyer flask (250 ml), to which ˜100 mg of KI (Bioultra >99.5% TA from Sigma Aldrich) and 2 mL of 6 M H.sub.2SO.sub.4 was added. The obtained I.sub.3.sup.− solution was immediately titrated with thiosulfate solution. Just before the end-point, indicated by a light straw-like color, the starch solution was added, resulting in a change of color to a dark red/brown (this color change is due to branched Amylodextrin rather than blue when using straight chain amylose). The thiosulfate solution was prepared fresh the same day as the titration experiment. Titrations to determine LiIO.sub.3 formed through reactions in I.sub.3.sup.− were performed by allowing the reaction to reach completion (indicated by the complete consumption of I.sub.3.sup.− based on the solution becoming colorless). The entirety of the solid and liquid phases were then transferred to an Erlenmeyer flask (rinsing the reaction vial three times with DI H.sub.2O) and then titrated as per above.

[0114] Raman spectroscopy was performed on a LabRAM HR800 microscope (Horiba Jobin Yvon) using an external 20 mW He:Ne 633 nm laser (Horiba, Jobin Yvon) and, focused with a 50× long working distance objective and a 10-0.3 neutral density filter. A silicon substrate was used to calibrate the Raman shift. An air-tight cell was used for powders, and all samples preparation was done in an argon-filled glovebox. Liquid samples were tightly sealed in a 3 mL vial and assessed using a 10× working length. Reference spectra of Li.sub.2O.sub.2, LiOH, LiOH—H.sub.2O and LiIO.sub.3 are available in FIG. 9.

[0115] XRD of discharged products and powders was performed on a Rigaku Smartlab diffractometer in Bragg-Brentano geometry. A domed air tight XRD cell holder from Panalytical was used to prevent exposing the electrodes to ambient atmosphere. Reference spectra for LiOH, LiOH—H.sub.2O, Li.sub.2O.sub.2, LiI, DMSO.sub.2 and LiIO.sub.3 are available in FIG. 16.

[0116] .sup.1H NMR was performed on a Bruker AVANCE and Bruker AVANCE III-400 MHz nuclear magnetic resonance (NMR) spectrometers. Samples were prepared by mixing 0.5 mL of the sample+0.1 mL of DMSO-D6 (for NMR locking)+10 μL of internal reference (either MeCN (Acetonitrile anhydrous, 99.8%, Sigma-Aldrich dried over molecular sieves) or 1,4-dioxane (anhydrous, 99.8%, Sigma-Aldrich, dried over molecular sieves) chosen to avoid overlap with peaks of interest).

[0117] Gas chromatography (GC) was performed using Argon (5.0, Praxair) as a carrier gas flowing at ˜12 sccm, through a glass cell. Cell was purged with Ar for 1 hour, during the last 15 minutes of which, a background spectrum was taken. The reaction compartment contained 15 mL of DMSO with either Li.sub.2O.sub.2 formed from disproportionation or commercial LiOH suspended in solution with active stirring. 2 mL of I.sub.3.sup.− solution (0.2 M LiI+50 mM I.sub.2 in DMSO) was injected using a syringe which was sealed onto a port of the glass reaction cell prior to purging without exposure to the ambient. 1 mL of gas sample was injected into a gas chromatograph (GC, SRI 8610C in the Multi-Gas #3 configuration). Samples were injected after 2, 22, 42 and 62 minutes of reaction. GC was calibrated using a 2500 ppm O.sub.2+17000 ppm N.sub.2 in Argon gas mixture.

V. Li—O.SUB.2 .Cell Assembly and Tests

[0118] Li—O.sub.2 cells consisted of a lithium metal negative electrode (Chemetall, Germany, 15 mm in diameter) and a carbon paper with gas diffusion layer positive electrode (FuelCellsEtc, F2GDL, LOT: TST008, 12.5 mm diameter). The carbon paper was dried for 24 hours at 90° C. under vacuum and transferred to a glove box (H.sub.2O<0.1 ppm, O.sub.2<0.1 ppm, Mbraun, USA) without exposure to ambient air. Glass fiber (Whatman, GF-A/GF-F, 17 mm diameter) was dried at 150° C. under vacuum overnight and was transferred to the glove box without exposure to the ambient. Lithium-ion conducting glass-ceramic electrolyte (19 mm diameter, 150 μm thick, LICGC, Ohara Corp) was dried at 80° C. under vacuum overnight. Cells were constructed by placing a single piece of glass fiber separator on top of the lithium, adding 120 μL of liquid electrolyte, followed by the lithium-ion conducting glass-ceramic electrolyte, another piece of glass fiber separator, another 120 μL of liquid electrolyte and finally the carbon paper positive electrode. No 316 stainless steel current collector was used to avoid a reaction which was observed between the 316 stainless steel and iodine formed during charge in some cells (see FIG. 16). The origin of this corrosion is not fully understood and is worthy of further investigation as it poses challenges for the practical implementation of LiI as a redox mediator, however, adequate performance over a single charging cycle was acquired by simply avoiding the use of the current collector and restricting the electrolyte contact with the 316 stainless steel spring as much as possible. For cells not analyzed using DEMS, following assembly, cells were transferred to a connected second argon glove box (Mbrau.sub.2n, USA, H.sub.2O<0.1 ppm, O.sub.2<1%) without exposure to air and pressurized with dry O.sub.2 (Airgas, 99.999% pure, H.sub.2O/CO/CO.sub.2<0.5 ppm) to 25 psi (gauge) to ensure that an adequate amount of O2 was available. The oxygen pressure in the cell was measured using a pressure gauge during the experiments to confirm proper cell sealing. Electrochemical tests were conducted using a Biologic VMP3.

[0119] LiOH preloaded electrodes were prepared by drop casting a slurry (70% wt Vulcan Carbon, 20% wt LiOH, 10% wt PTFE) onto neat carbon paper (Toray TGP-H-60, 12.5 mm diameter). The vulcan carbon (VC), PTFE and carbon paper were dried at 80° C. under vacuum for 24 hours and transferred to a glovebox (Mbraun, USA, H.sub.2O<0.1 ppm, O.sub.2<1%) without exposure to the ambient. The LiOH and VC were ground into a homogenous mixture using a mortar and pestle then added to a suspension of PTFE in DME. After allowing the mixture to stir for 1 hour, the slurry was drop cast 50 μL at a time until the desired mass loading was achieved. Individual 12.5 mm pieces of carbon paper were weighed before and after drop casting to determine the amount of mixture deposited. Typical loadings of the VC/LiOH/PTFE mixture were 3.9-5.0 mg per electrode (1.267 cm.sup.2). Electrodes were additionally dried under vacuum for ˜15 minutes to remove residual DME.

VI. Differential Electrochemical Mass Spectroscopy of Cells During Charging

[0120] A custom-made DEMS setup based on a design by McCloskey et al., which has been reported previously, was used for assessing gas evolution during the charging process. O.sub.2, CO, CO.sub.2, H.sub.2 and H.sub.2O evolution during charge was quantified at 20 minute intervals using a mass spectrometer coupled with pressure monitoring. Details of DEMS and cell technical construction are available online. Argon (Airgas, 99.999% pure, O.sub.2, H.sub.2O, CO.sub.2<1 ppm) was used as a carrier gas. In all cells, no detectable quantities of CO, H.sub.2 and H.sub.2O were detected, so these values are omitted from all plots. Cells were prepared as described above. Li—O.sub.2 cells were first discharged under O.sub.2 environment for 20 hours at 0.05 mA/cm.sup.2. The cell environment was then changed to Argon by evacuating the cell and refilling it with Argon five times and charged at 0.1 mA/cm.sup.2 to a cut-off voltage of 4.5 V.sub.Li. LiOH− preloaded electrodes were charged under argon environment at 0.1 mA/cm.sup.2 to a cut-off voltage of 4.5 V.sub.Li.

Results and Discussion

[0121] VII. Solvent-Dependent Potential of I.sub.3.sup.−/I.sup.−

[0122] The redox potential of I.sub.3.sup.−/I.sup.− was shown to shift positively against the solvent-insensitive reference potential of decamethylferrocene (Me.sub.10Fc) from DME, DMA and DMSO while that of I.sub.3.sup.−/I.sub.2 remained nearly constant, as shown in FIG. 1B. The reduction and oxidation peaks of the I.sub.3.sup.−/I.sup.− (centered between 0.02 and 0.23 V.sub.Me10Fc) and I.sub.3.sup.−/I.sub.2 (centered at ˜0.64 V.sub.Me10Fc) couples were observed in cyclic voltammograms (CVs), from which the redox potential of I.sub.3.sup.−/I.sup.− was obtained by averaging the reduction and oxidation peak centers (FIG. 1, FIG. 10). These measurements were collected using a Pt macroelectrode as the working electrode and Ag.sup.+/Ag as the reference electrode in solvents containing 10 mM LiI with 0.5 M LiTFSI under an argon environment, where the Ag.sup.+/Ag reference electrode potential scale was converted to that of Me.sub.10Fc following previous work.sup.−6 (FIG. 18) for each solvent. The shifts in the potential of the I.sub.3.sup.−/I.sup.− redox were plotted against reported Guttmann acceptor number (AN), Guttmann donor number (DN) and dielectric constant for these solvents (FIGS. 19-21). Here the positive shift in the potential of I.sub.3.sup.−/I.sup.− can be attributed to increasing thermodynamic stability of the I.sup.− ion through solvation via higher Guttmann acceptor number (AN), dielectric constant and possibly through the formation of ion pairs with Li.sup.+47. Solvation effects can more significantly influence I.sup.− ions as there are three I.sup.− ions for each I.sub.3.sup.− and the larger I.sub.3.sup.− ions (which are more charge diffuse) might interact with the solvent less. Following the same argument, the solvent-insensitive redox potential of I.sub.2/I.sub.3.sup.− can be attributed to the weak solvation of I.sub.3.sup.− and I.sub.2 in the considered solvents.

[0123] Such positive shifts in the potential of I.sub.3.sup.−/I.sup.− increases its oxidizing power towards Li.sub.2O.sub.2 (or the thermodynamic driving force to oxidize Li.sub.2O.sub.2) to evolve O.sub.2 (Li.sub.2O.sub.2=>2Li++O.sub.2+2e.sup.−), with a trend of G4<DME<Pyridine<DMA<DMSO<Me-Im. Considering that the Li.sup.+/Li potential decreases from DME, DMA to DMSO on the Me.sub.10Fc scale due to stronger lithium solvation with high Guttmann donor number (DN) and high dielectric constant (the Born model), and that the free energy of O2 and Li.sub.2O.sub.2 are solvent independent, the redox potential of Li.sup.+,O.sub.2/Li.sub.2O.sub.2 would follow the same trend as the Li.sup.+/Li potential, decreasing from 0.00 V.sub.Me10Fc in DME to −0.11 V.sub.Me10Fc in DMA and −0.31 V.sub.Me10Fc in DMSO. Therefore, as the potential of I.sub.3.sup.−/I.sup.− shifts to higher values from DME, DMA to DMSO and that of Li.sup.+,O.sub.2/Li.sub.2O.sub.2 moves to lower values on the Me.sub.10Fc scale, the oxidative power of I.sub.3.sup.−/I.sup.− towards Li.sub.2O.sub.2 oxidation increases, from −0.04 eV in DME, to −0.36 eV in DMA and −1.08 eV in DMSO. Using the linear free energy relationship that links thermodynamics and kinetics, one would expect that the kinetics of I.sub.3.sup.− against Li.sub.2O.sub.2 oxidation would significantly increase from DME, DMA to DMSO.

VIII. Solvent-Dependent Oxidizing Power of I.sub.3.sup.−/I.sup.− and I.sub.2/I.sub.3.sup.− Towards Li.sub.2O.sub.2

[0124] The solvent-dependent oxidizing power of I.sub.3/I.sup.− towards Li.sub.2O.sub.2 was examined by adding Li.sub.2O.sub.2 (0.1 M, Li.sub.2O.sub.2:I.sub.3.sup.−=2:1) to 50 mM I.sub.3.sup.− (50 mM of I.sub.2+0.2 M of LiI) in different solvents. The brown-colored solution became clear in DMA (<24 hours), DMSO (˜1 minute) and Me-Im (˜10 seconds), as shown in FIG. 2, panel a. On the other hand, the brown color became less pronounced for pyridine while no visible color change was found for DME and G4 after 24 hours. The color change observed for DMA, DMSO and Me-Im can be attributed to the reduction of I.sub.3.sup.− (dark brown) to I.sup.− (colorless). This hypothesis is supported by UV-vis spectroscopy of the liquid phase decanted from the reaction mixture after 24 hours, where characteristic peaks for I.sub.3.sup.− at 293 nm and 364 nm disappeared for DMA, DMSO and Me-Im while those for DME, G4 and pyridine remained, as shown in FIG. 2, panel b and FIGS. 22 and 23. The concentration changes of I.sub.3.sup.− during the reaction (24 hours) quantified using the absorbance of I.sub.3.sup.− solutions with known concentration (as detailed in FIGS. 12-14 increased with greater redox potentials of I.sub.3.sup.−/I.sup.− from G4, DME, pyridine to DMA (DMSO or Me-im) in FIG. 2, panel c. All the I.sub.3.sup.− was consumed in DMA, DMSO and Me-im and Raman spectra of the solid recovered after the reaction between Li.sub.2O.sub.2 and I.sub.3.sup.− revealed Li.sub.2O.sub.2 remained after the reaction as Li.sub.2O.sub.2 was 2 times over stoichiometric (FIG. 24). This trend is in agreement with the greater kinetics of Li.sub.2O.sub.2 oxidation by I.sub.3/I.sup.− with higher potentials in solvents such as DMA and DMSO which renders a higher thermodynamic driving force relative to Li.sup.+,O.sub.2/Li.sub.2O.sub.2(FIG. 1). Further support for Li.sub.2O.sub.2 oxidation by I.sub.3.sup.− in DMSO came from oxygen evolution as detected by gas chromatography (GC) accompanied with color changes of the solution after addition of Li.sub.2O.sub.2. GC measurements of oxygen evolution from solutions of DMSO (FIG. 3, FIG. 25) show that the amount of oxygen detected was comparable to that expected for oxidation of I.sub.3.sup.− by I.sub.3.sup.−+Li.sub.2O.sub.2.fwdarw.2Li.sup.++3I.sup.−+O.sub.2. Therefore, having solvents not only with higher AN to increase the potential of I.sub.3.sup.−/I.sup.− but also with higher DN to lower the potential of Li,O.sub.2/Li.sub.2O.sub.2 in solvents such as DMA and DMSO promotes the oxidizing power of I.sub.3.sup.−/I.sup.− towards Li.sub.2O.sub.2 as opposed to solvents like G4 and DME.

[0125] I.sub.3.sup.− in DME can oxidize Li.sub.2O.sub.2 in small part considering experimental uncertainty while previous studies showing that I.sub.3.sup.− cannot oxidize Li.sub.2O.sub.2.sup.43,45-47 in DME. The more oxidizing I.sub.2 could fully oxidize synthetic Li.sub.2O.sub.2 in DMA and DMSO and I.sub.2 in DME reacted until all I.sub.2 was reduced to I.sub.3.sup.− via I.sub.2+Li.sub.2O.sub.2.fwdarw.2Li.sup.++2I.sup.−+O.sub.2 and I.sub.2+I.sup.−<I.sub.3.sup.− (FIG. 26). Reactions between commercial Li.sub.2O.sub.2 and I.sub.3.sup.−/I.sub.2 in DME proceeded to a lesser extent than synthetic Li.sub.2O.sub.2 as shown in FIG. 27. I.sub.3.sup.− in DME did not react at all with commercial Li.sub.2O.sub.2, whereas solutions of I.sub.2 (50 mM I.sub.2) and I.sub.5.sup.− (50 mM I.sub.2+25 mM LiI) proceeded until all higher order polyiodide species were reduced to I.sub.3.sup.−. Raman on the solution phase after the reaction revealed that only I.sub.3.sup.− species remained (FIG. 28). We attribute this difference in oxidizing power of polyiodide species against commercial and synthetic Li.sub.2O.sub.2 to the oxygen-rich, defective surface of Li.sub.2O.sub.2 formed through disproportionation which has been reported previously and is anticipated to be more readily oxidized than bulk Li.sub.2O.sub.2. A discussion of higher-order polyiodide species (such as I.sub.5.sup.− and I.sub.7) is presented below.

[0126] No solvent decomposition was detected for G4, DME and DMA while decomposed species from pyridine, DMSO and Me-Im were found in presence of Li.sub.2O.sub.2 and/or I.sub.3.sup.−. .sup.1H NMR measurements of the solution phase decanted from the reaction mixture after 24 hours was used to detect protonated species produced after the addition of synthetic Li.sub.2O.sub.2. No changes were observed in G4, DME and DMA (FIG. 29, indicating no detectable solvent decomposition. On the other hand, a small peak at ˜2.95 ppm appeared for DMSO, which can be attributed to the presence of ˜6 mM dimethyl sulfone (DMSO.sub.2) (FIG. 30). This observation is in agreement with previous work showing that DMSO is chemically unstable in the presence of Li.sub.2O.sub.2-like and LiO.sub.2 species. In addition, changes were found for the .sup.1H NMR peaks of Me-Im at ˜7.1 ppm and ˜7.7 ppm, splitting into two peaks and shifting downfield, respectively (FIG. 31), As comparable changes were found when a solution of I.sub.3.sup.− was prepared in Me-Im (without addition of Li.sub.2O.sub.2), we attribute this to changes in Me-Im proton exchange dynamics caused by the introduction of a Brønsted base (I.sup.−/I.sub.3.sup.−). Interactions between iodide species and Me-Im are known to be strong and lead to the iodination of Me-Im, which is supported by observed color-fading of I.sub.3.sup.− solutions of Me-Im over time, which was most pronounced in diluted samples for UV-Vis analysis (FIG. 32). Considering that the short duration of Li.sub.2O.sub.2 oxidation (<10 seconds) and long iodination reaction time (>weeks for a 50 mM solution without Li.sub.2O.sub.2) to render colorless solutions, the oxidation of Li.sub.2O.sub.2 by I.sub.3.sup.− to form I.sup.− dominates.

[0127] Discharging and charging of a Li—O.sub.2 battery with and without LiI as a redox mediator was performed, where the added I.sup.− was electrochemically oxidized to I.sub.3.sup.− and/or I.sub.2 during charge. DEMS cells were assembled using 0.5 M LiTFSI in diglyme (G2) or DMSO, with and without 0.1 M LiI, where added 0.1 M LiI could provide a theoretical maximum of 33 mM I.sub.3.sup.− and 50 mM I.sub.2, accounting for a maximum of 0.25 mAhr/cm.sup.2 of capacity. G2 was selected as an analogous solvent to DME with a lower vapor pressure, but lower viscosity than G4. Cells were first discharged at 0.05 mA/cm.sup.2.sub.geo for 20 hours to yield 1 mAhr/cm.sup.2 in capacity and only Li.sub.2O.sub.2 was detected by XRD (FIG. 33). While the addition of 0.1 M LiI did not lead to significant changes the discharge voltage, it markedly reduced the charging potential in both solvents. The entire charging voltage profile for G2 was sloped and the reduction of charging voltage can be attributed to electrochemical oxidation of I.sup.− to I.sub.3.sup.− (>2.98 V.sub.Li) and I3.sup.− to I2 (>3.59 V.sub.Li), with minute oxidation of Li.sub.2O.sub.2 by I.sub.3.sup.−. This hypothesis is supported by the DEMS measurements in G2, which showed no greater oxygen evolution rate with addition of I.sup.− upon charge, as shown in FIG. 4, panel c. On the other hand, the charging voltage profile with DMSO exhibited a plateau below the oxidation potential of I.sub.3.sup.− to I.sub.2 (3.90 V.sub.Li), which was accompanied with a significantly enhanced (˜two times) rate of oxygen evolution during charging relative to that without I.sup.−. The result confirmed that having the I.sub.3.sup.−/I.sup.− redox potential equal to or lower than Li.sup.+,O.sub.2/Li.sub.2O.sub.2 in solvents such as G2 and DME was unable to promote the oxidation of Li.sub.2O.sub.2 while those with greater potentials than that of Li.sup.+,O.sub.2/Li.sub.2O.sub.2 in solvents such as DMSO can facilitate Li.sub.2O.sub.2 oxidation kinetics to evolve O.sub.2 and lower charging overpotential of Li—O.sub.2 batteries.

IX. Solvent-Dependent Oxidizing Power of I.sub.3.sup.−/I.sup.− and I.sub.2/I.sub.3.sup.− Towards LiOH

[0128] The solvent-dependent oxidizing power of I.sub.3.sup.−/I.sup.− towards LiOH was examined by adding LiOH (2 times excess) to 50 mM I.sub.3.sup.− (50 mM of I.sub.2+0.2 M of LiI) in different solvents. The presence of water and I.sup.− can lead to the formation of LiOH on discharge, where water is consumed in this reaction. Thus we examine how oxidized iodide species can promote the oxidation of LiOH, beginning from anhydrous conditions. The brown-colored solution became clear in DMA (˜48 hours) and DMSO (<1 hour) (Me-Im with ˜10 minutes). On the other hand, no clearly visible color change was found for pyridine, DME and G4 after 48 hours. The color change observed for DMA, DMSO and Me-Im can be attributed to the reduction of I.sub.3.sup.− (dark brown) to I.sup.− (colorless). This hypothesis is supported by UV-vis spectroscopy of the liquid phase decanted from the reaction mixture after 48 hours, where characteristic peaks for I.sub.3.sup.− at 293 nm and 364 nm disappeared for DMA, DMSO and Me-Im while those for DME, G4 and pyridine remained, as shown in FIG. 5, panel a and FIG. 34 and FIG. 35. The concentration changes of I.sub.3.sup.− during the reaction (48 hours) was quantified using the absorbance of I.sub.3.sup.− solutions with known concentration (as detailed in FIGS. 12-14) increased with greater redox potentials of I.sub.3.sup.−/I.sup.− from G4, DME, pyridine to DMA (DMSO or Me-im) in FIG. 4, panel a. All the I.sub.3.sup.− was consumed in DMA, DMSO and Me-im while nearly no I.sub.3.sup.− was consumed in G4, DME and Pyridine. Raman spectra of the solid recovered after the reaction between LiOH and I.sub.3.sup.− revealed only LiOH as expected from LiOH being 2 times overstoichiometric (FIG. 36). Similarly, the addition of LiOH to the more oxidizing I.sub.2 in DMA and DMSO led to complete consumption of I.sub.2 while the consumption of I.sub.2 stopped when the reaction had proceeded to a point when all I.sub.2 would be expected to be converted to I.sub.3.sup.− in DME, as shown in FIG. 5, panel b.

[0129] Unfortunately, the consumption of I.sub.3.sup.− by reacting with LiOH in solvents such as DMSO did not yield oxygen evolution as shown from GC measurements after the addition of LiOH (FIG. 37). To assess reaction products generated during the reaction between I.sub.3.sup.− and LiOH, the reaction between an excess of I.sub.3.sup.− (2 times) and LiOH in DMSO was allowed to carry out for more than one week. Raman (FIG. 5, panel c) and XRD (FIG. 38) revealed LiIO.sub.3 without LiOH and LiOH—H.sub.2O. The formation of LiIO.sub.3 can come from the following reaction: 3I.sub.3.sup.−+6LiOH.fwdarw.8I.sup.−+5Li.sup.++3H.sub.2O+LiIO.sub.3. The reaction between I.sub.3.sup.− and LiOH (I.sub.3.sup.−+2LiOH.fwdarw.2I.sup.−+2Li.sup.++H.sub.2O+IO.sup.−) has been well studied in aqueous systems as well as the disproportionation of hypoiodite (IO.sup.−) to IO.sub.3.sup.−71-73 (3IO.sup.−.fwdarw.2I.sup.−+IO.sub.3.sup.−). In-situ Raman spectroscopy revealed a vibration at 430 cm.sup.−1 previously attributed to IO.sup.−74 (FIG. 39), which provided support to the proposed mechanism involving IO.sup.−. The formation of LiIO.sub.3 is also supported by previous observations by Burke et al..sup.43 based on charging of a cell with LiI in DME with LiOH formed during discharge. The trend in FIG. 5, panel a can be attributed to the greater kinetics of LiOH oxidation by I.sub.3.sup.−/I.sup.− with higher potentials in solvents such as DMA and DMSO to render higher thermodynamic driving force relative to Li.sup.+,IO.sub.3.sup.−,H.sub.2O/LiOH,I.sup.− (FIG. 5, panel a).

[0130] .sup.1H NMR analysis and iodometric titration of the solution phase before and after reaction with 50 mM I.sub.3.sup.−/I.sub.2 further confirmed the proposed reaction mechanism for the formation of LiIO.sub.3. A H.sub.2O peak became visible following the addition of LiOH to DMA (FIG. 27), DMSO (FIG. 6, panel a, FIG. 27) and Me-Im (FIG. 27) with 50 mM I.sub.3.sup.− for 48 hours. No H.sub.2O was detected in the liquid solution from mixing DMSO (without oxidized iodide species) with LiOH for 48 hours while an H.sub.2O peak at 3.36 and 3.30 ppm was detected after reacting LiOH with 50 mM I.sub.3.sup.− and 50 mM I.sub.2 in DMSO, respectively. The upfield shift of H.sub.2O found for I.sub.2 compared to I.sub.3.sup.− can be attributed to the larger quantity of LiI in the I.sub.3.sup.− solution as shown previously for .sup.1H NMR chemical shift of H.sub.2O induced by interaction with I.sup.− in DME.sup.44. In contrast, no H.sub.2O and other changes were observed in the .sup.1H NMR spectra of G4 and DME (FIG. 27) following the reaction between Li.sub.2O.sub.2 and I.sub.3.sup.− while pyridine showed the emergence of some small peaks (FIG. 27) which we attribute to solvent decomposition. The concentration of H.sub.2O was quantified (±5 mM) using an internal MeCN reference, where ˜80 mM was found in DMA and ˜60 mM was found in DMSO and Me-Im. The amount of water detected was greater than that (50 mM) expected from the proposed reaction, 3I.sub.3.sup.−+6LiOH.fwdarw.8I.sup.−+5Li.sup.++3H.sub.2O+LiHO.sub.3, where the difference might be attributed to solvent decomposition. DMSO.sub.2 at 2.95 ppm of ˜18 mM was found for DMSO and the peak changes of Me-Im (FIG. 27, FIG. 29) can be attribute to the previously discussed interactions with I.sup.−/I.sub.3.sup.−70. The amount of the iodate species detected with iodometric titration (8.2 mM and 6.4 mM for reactions with I.sub.3.sup.− and I.sub.2 in DMSO, respectively) was close to that (16.7 mM) expected for 3I.sub.3.sup.−+6LiOH.fwdarw.8I.sup.−+5Li.sup.++3H.sub.2O+LiHO.sub.3, as shown in FIG. 6, panel b. The difference can be attributed to the decomposition of DMSO by IO.sup.− via IO.sup.−+(CH.sub.3).sub.2SO.fwdarw.I.sup.−+(CH.sub.3).sub.2SO.sub.2, having 18.5 mM and 24.9 mM DMSO.sub.2 (18.5/24.9 mM IO.sup.− consumed) in this decomposition reaction for reactions with I.sub.3.sup.− and I.sub.2, respectively. A similar oxidation of DMSO to DMSO.sub.2 was reported by Liu et al. in the ruthenium-catalyzed oxidation of LiOH. Therefore, combined spectroscopic data from .sup.1H NMR, Raman, GC and iodometric titration show that the oxidation of LiOH by oxidized iodide species such as I.sub.3.sup.− leads to the formation of an IO.sup.− intermediate, which can disproportionate to form LiIO.sub.3 as the major product and attack solvent molecules to form species such as DMSO.sub.2. This reaction mechanism does not lead to the formation of O.sub.2 gas as some have reported previously.

[0131] The proposed oxidation mechanism of LiOH in the presence of oxidized iodide species is supported by galvanostatic charging and DEMS measurements (FIG. 7) of preloaded LiOH electrodes with a solid Li-conducting separator to eliminate shuttling, charged in 0.5 M LiTFSI G2 (FIG. 7, panel a, panel c) and DMSO (FIG. 7 panel b, panel d) with and without 0.1 M LiI addition (in cases where no LiI was added, an additional 0.1 M LiTFSI was added to fix the total Li.sup.+ concentration at 0.6 M). Of significance, there was no observable oxygen generation in either G2 or DMSO, which supports the proposed oxidation of LiOH by oxidized iodide species to form lithium iodate. The majority of the charging plateau took place above the I.sub.3.sup.−/I.sub.2 redox transition in G2 (comparable to that in DME), indicating that I.sub.3.sup.− could not oxidize LiOH in glymes but I.sub.2 could (FIG. 5, panel a, panel b). On the other hand, significant capacity was noted below the I.sub.3.sup.−/I.sub.2 redox transition in DMSO, corresponding to the formation of LiIO.sub.3 from I.sub.3.sup.−. XRD of the electrodes after charging (FIG. 40) indicated that not all LiOH was removed, which is consistent with the calculated charging capacity based on the mass of deposited LiOH (7.3 and 5.2 mAhr/cm.sup.2 for G2 and DMSO, respectively). However, the observed capacity is significantly larger than the maximum calculated capacity based on the oxidation of LiI (˜0.25 mAhr/cm.sup.2), indicating consumption of LiOH during charge. We postulate the incomplete oxidation of LiOH in-situ may relate to either slow kinetics of oxidation of LiOH by iodide species (shown to be much slower than the oxidation of Li.sub.2O.sub.2 in ex-situ experiments) and/or the passivation of the LiOH surface by insoluble LiIO.sub.3. Leftover LiOH after charging is consistent with the observations of Qiao et al., however, using ex-situ reactions and a solid Li-conducting separator to eliminate shuttling, we are able to demonstrate that LiOH is still active during the charging process and not inactive as suggested by Qiao et al.

[0132] The reaction of Li.sub.2O.sub.2 by oxidized iodide species leads to O.sub.2 gas evolution whereas LiOH is oxidized to IO.sup.−, which can then either disproportionate to form LiIO.sub.3 or attack solvent molecules. We estimated the free energy of formation for LiIO.sub.3 by combining the computed enthalpy of LiIO.sub.3 formation from Huang et al. with approximated entropy estimated from KIO.sub.3, where full derivation is available in the Supporting Information. The formation of LiIO.sub.3 from Li.sub.2O.sub.2 and LiOH was found thermodynamically at 2.21 and 2.97 V.sub.Li, respectively as shown in FIG. 41. The oxidation of Li.sub.2O.sub.2 to O.sub.2 in the presence of oxidized iodide species is anticipated to occur when the polyiodide equilibrium potential is higher than 2.96 V.sub.Li. Similarly, LiOH is expected to be oxidized to O.sub.2 by polyiodide species with redox potentials above 3.35 V.sub.Li. The estimated thermodynamics predicting oxidation of LiOH to LiIO.sub.3 at voltages greater than ˜3 V.sub.Li is in good agreement with measured values in this work. Since I.sub.3.sup.− is unable to oxidize LiOH in DME, but is able to oxidize LiOH in DMA, we would anticipate the formation of LiIO.sub.3 from LiOH to occur in the range of 2.98-3.14 V.sub.Li. Since LiIO.sub.3 is thermodynamically favorable to form from both Li.sub.2O.sub.2 and LiOH, it is proposed that the evolution of O.sub.2 without the formation of LiIO.sub.3 upon oxidation of Li.sub.2O.sub.2 by oxidized iodide species can be attributed to slow kinetics of O—O dissociation needed to form IO.sup.− and subsequently LiIO.sub.3. Further support to this hypothesis came from the experiments with KO.sub.2 and Li.sub.2O. The oxidation of KO.sub.2 by I.sub.3.sup.− in G2 was found to readily evolve O.sub.2 using DEMS, and have a color change from brown to colorless in the ex situ chemical reaction (FIG. 42) while the chemical reactions between Li.sub.2O and I.sub.3.sup.− in DMSO led to LiIO.sub.3 (FIG. 43).

[0133] The formation of LiIO.sub.3 from the oxidation of LiOH by I.sub.3.sup.−/I.sub.2 indicates a significant incompatibility between LiI as a redox mediator for Li—O.sub.2 batteries and any water present in the electrolyte. As previous demonstrated, the presence of LiI in DME-based electrolytes decreases the deprotonation energy of water, leading to the formation of LiOH (even with H.sub.2O content <40 ppm). In this work, we have demonstrated that the oxidation of LiOH leads to the formation of LiIO.sub.3, and not the reversible formation of O.sub.2, as well as the regeneration of water. Therefore, with cycling in the presence of any water (even contaminate levels of water), through the action of consuming water to form LiOH on discharge and oxidizing it to LiIO.sub.3 and reforming water on charge, LiI will be converted to LiIO.sub.3, leading to the irreversible loss of the redox mediator. The full implication of this reaction on the cycle life of cells with LiI as a redox mediator is beyond the scope of this work, but this work highlights a significant issue that needs to be addressed in order for LiI to be practically implemented as a redox mediator in a Li—O.sub.2 battery.

[0134] The role of LiI on the charging process of Li—O.sub.2 batteries was examined by systemically studying the solvent-dependent oxidizing power of I.sub.3.sup.−/I.sup.− and I.sub.2/I.sub.3.sup.− towards Li.sub.2O.sub.2 and LiOH. The oxidizing power of I.sub.3.sup.−/I.sup.− and I.sub.2/I.sub.3.sup.− towards Li.sub.2O.sub.2 and LiOH was examined chemically by examining the consumption of I.sub.3.sup.− upon addition of synthetic Li.sub.2O.sub.2, where the liquid reaction product was examined using UV-vis spectroscopy and .sup.1H NMR, the solid reaction products were studied by Raman spectroscopy and XRD and the gaseous products were assessed using gas chromatography. In addition, the role of I.sup.− on the charging of Li—O.sub.2 batteries and LiOH pre-loaded cells was examined using DEMS, where the amount of oxygen generated was quantified. We have shown that I.sub.3.sup.−/I.sup.− shifts towards higher potentials in solvents with higher dielectric constant and AN, suggesting stronger solvation of I.sup.− ions, whereas the I.sub.2/I.sub.3.sup.− potential was observed to be largely solvent independent in the considered solvents. This strong solvation of I.sup.− ions, coupled with a strong solvation of Li.sup.+ ions in solvents like DMA, DMSO and Me-Im was found to increase the oxidizing power of I.sub.3.sup.−/I.sup.−, allowing I.sub.3.sup.− to effectively oxidize Li.sub.2O.sub.2 to generate O2, which was supported by chemical and electrochemical experiments. In solvents with weaker solvation of I.sup.− and Li.sup.+ (such as DME and G4), the more oxidizing I.sub.2/I.sub.3.sup.− redox couple was needed before Li.sub.2O.sub.2 could be fully oxidized to O.sub.2. The oxidation of LiOH by I.sub.3.sup.− was also found to be solvent dependent, where no reaction was observed in G4, DME and pyridine while the reaction proceeded to completion in DMA, DMSO and Me-Im where the I.sub.3.sup.−/I.sup.− redox potential was above ˜3.1 VW. No O.sub.2 was detected from the oxidation of LiOH by I.sub.3.sup.− using gas chromatography and the charging of pre-loaded LiOH electrodes in DEMS, but instead, the oxidation of LiOH was found to produce water and a hypoiodite (IO.sup.−) intermediate, which could either disproportionate to form LiIO.sub.3 or attack solvent molecules and result in decomposition products such as dimethyl sulfone (DMSO.sub.2). The selectivity between O.sub.2 and the thermodynamically preferred LiIO.sub.3 can be governed by a kinetic barrier relating to O—O bond dissociation and this kinetic barrier prevents IO.sup.− formation, allowing for the evolution of gaseous O.sub.2 when oxidizing Li.sub.2O.sub.2, which was supported by reactions between oxidized iodide species and KO.sub.2/Li.sub.2O. This work highlights a significant incompatibility between LiI as a redox mediator for Li—O.sub.2 batteries and even trace amounts of water in the electrolyte, which may lead to the consumption of the LiI redox mediator to form LiIO.sub.3 with cycling.

[0135] Demonstrating the Charging Reaction of the Proposed Chemistry

[0136] The reaction between I.sub.3.sup.− and LiOH was found to be solvent-dependent, with I.sub.3.sup.− being fully consumed in DMA, DMSO and Me-Im but little to no reaction occurring in G4, DME and pyridine. The solvent-dependent oxidizing power of I.sub.3.sup.−/I.sup.− towards LiOH was examined by adding commercial LiOH (0.2 μmol, LiOH:I.sub.3.sup.−=4:1) to 1 mL of 50 mM I.sub.3.sup.− (50 mM of I.sub.2+0.2 M of LiI, I.sup.−:I.sub.2=4:1) in different solvents. The brown-colored solution became clear in DMA (˜48 hours), DMSO (˜1 hour) and Me-Im (˜10 minutes). This color change could be attributed to the reduction of I.sub.3.sup.− (dark brown) to I.sup.− (colorless) as revealed by UV-vis spectroscopy of the liquid phase decanted from the reaction mixture after 48 hours (FIG. 5B, panel a, FIG. 35). On the other hand, no color change was found for pyridine, DME and G4 after 48 hours as evidenced by the characteristic peaks for I.sub.3.sup.− at 293 nm and 364 nm remaining after the reaction with LiOH (FIG. 5B, panel a, FIG. 35). The consumption of I.sub.3.sup.− after the reaction for 48 hours was quantified using the absorbance of I.sub.3.sup.− with known concentrations (FIGS. 11-14). All the I.sub.3.sup.− was consumed in DMA, DMSO and Me-Im while nearly no I.sub.3.sup.− was consumed in G4, DME and Pyridine, as shown in FIG. 1A. Similarly, as shown in FIG. 1B, the addition of LiOH to the more oxidizing I.sub.2 in DMA and DMSO led to complete consumption of I.sub.2 while in DME, the reaction stopped after only I.sub.3.sup.− remained (FIGS. 5B, panel b, FIG. 47), resulting from the previously discussed association between I.sup.− generated by the reaction and the remaining I.sub.2 via I.sub.2+I.sup.−.Math.I.sub.3.sup.−. Anhydrous LiOH synthesized via the disproportionation of KO.sub.2 in a two times excess of LiTFSI in MeCN with added water (FIG. 48) was found to exhibit similar reactivity to commercial anhydrous LiOH in the presence of I.sub.3.sup.−, with a brown-colored 50 mM I.sub.3.sup.− solution becoming clear in DMA (˜96 hours) and DMSO (˜4 hour), but no visible color change in DME after 96 hours (FIG. 49).

[0137] The reaction between I.sub.3.sup.− and anhydrous LiOH in solvents such as DMSO did not yield oxygen evolution as shown from GC measurements with commercial LiOH (FIG. 37). As expected due to the excess of LiOH (LiOH:I.sub.3.sup.−=4:1), Raman spectra of the solid recovered after the reaction between LiOH and I.sub.3.sup.− in all solvents revealed anhydrous LiOH as the dominant phase remaining after the reaction (FIG. 36). To further probe potential solid reaction products between I.sub.3.sup.− and LiOH, the I.sub.3.sup.− excess reaction with commercial anhydrous LiOH (LiOH:I.sub.3.sup.−=1:1) in DMSO was performed for more than one week. Raman (FIG. 5B, panel C) and XRD (FIG. 38) of the solid recovered revealed LiIO.sub.3 only without LiOH remaining. The presence of LiIO.sub.3 has been previously reported by Burke et al., Implications of 4e.sup.− Oxygen Reduction via Iodide Redox Mediation in Li—O.sub.2 Batteries. ACS Energy Letters 2016; 1:747-56, which is incorporated by reference in its entirety. upon charging of cells having LiOH formed during discharge with LiI in DME. The formation of LiIO.sub.3 can come from the following reaction: 3I.sub.3.sup.−+6LiOH.fwdarw.8I.sup.−+5Li.sup.++3H.sub.2O+LiIO.sub.3, which can include the reaction between I.sub.3.sup.− and LiOH to generate hypoiodite (I.sub.3.sup.−+2LiOH.fwdarw.2I.sup.−+2Li.sup.++H.sub.2O+IO.sup.−) and the disproportionation of hypoiodite (IO.sup.−) to iodate IO.sub.3.sup.− (3IO.sup.−.fwdarw.2I.sup.−+IO.sub.3.sup.−). See, Gerritsen C M, Gazda M, Margerum D W. Non-metal redox kinetics: hypobromite and hypoiodite reactions with cyanide and the hydrolysis of cyanogen halides. Inorganic Chemistry 1993; 32:5739-5748, Lengyel I, Epstein I R, Kustin K. Kinetics of iodine hydrolysis. Inorganic Chemistry 1993; 32:5880-5882; and Xie Y, McDonald M R, Margerum D W. Mechanism of the Reaction between Iodate and Iodide Ions in Acid Solutions (Dushman Reaction). Inorganic Chemistry 1999; 38:3938-40, each of which is incorporated by reference in its entirety. The presence of IO.sup.− is supported by the presence of a vibration at 430 cm.sup.−1 previously attributed to IO.sup.− (FIG. 39) by in-situ Raman spectroscopy of a solution of commercial anhydrous LiOH with I.sub.3.sup.− in DMSO. See, Wren J C, Paquette J, Sunder S, Ford B L. Iodine chemistry in the +1 oxidation state. II. A Raman and uv-visible spectroscopic study of the disproportionation of hypoiodite in basic solutions. Canadian Journal of Chemistry 1986; 64:2284-96, which is incorporated by reference in its entirety. The thermodynamic driving force to form LiIO.sub.3 from LiOH (3I.sub.3.sup.−+6LiOH.fwdarw.8I.sup.−+5Li.sup.++3H.sub.2O+LiIO.sub.3) is much greater than that for oxygen evolution (2I.sub.3.sup.−+4LiOH.fwdarw..sub.6I.sup.−+4Li.sup.++2H.sub.2O+O.sub.2), and increases with greater redox potentials of I.sub.3.sup.−/I.sup.− on the Li.sup.+/Li scale from G4/DME, to DMA, to DMSO, to Me-Im (FIG. 10, FIG. 18). Of particular significance is the case of DMA, where full consumption of I.sub.3.sup.− was observed and the reaction to form LiIO.sub.3 is predicted to be spontaneous (E.sub.rxn=−ΔG.sub.rxn/6F=+0.17V) whereas the reaction to form O.sub.2 is not (E.sub.rxn=−ΔG.sub.rxn/4F=−0.21V), which further supports the preference for LiIO.sub.3 formation instead of O.sub.2 evolution. Similar trends were found for I.sub.2/I.sub.3.sup.− where increased thermodynamic driving force correlated with increased consumption of I.sub.2 in DME, DMA and DMSO (FIG. 5B, panel b).

[0138] Quantifications through .sup.1H NMR analysis of the solution phase and iodometric titration after reaction with 50 mM I.sub.3.sup.−/I.sub.2 further confirmed the proposed reaction mechanism for the formation of LiIO.sub.3. A H.sub.2O peak became visible following the addition of LiOH to DMA (FIG. 30), DMSO (FIG. 6, panel a, FIG. 16) and Me-Im (FIG. 29) with 50 mM I.sub.3.sup.− for 48 hours. No H.sub.2O was detected in the liquid phase from mixing DMSO (without oxidized iodide species) with LiOH while an H.sub.2O peak at 3.36 and 3.30 ppm was detected after reacting LiOH with 50 mM I.sub.3.sup.− and 50 mM I.sub.2 in DMSO, respectively (FIG. 6, panel a). The upfield shift of H.sub.2O found for 12 compared to I.sub.3.sup.− can be attributed to the larger quantity of I.sup.− in the solution following the reaction with I.sub.3.sup.−, as shown previously for changes in the .sup.1H NMR chemical shift of H.sub.2O induced by interactions with I.sup.− in DME. See, for example, Tulodziecki M, Leverick G M, Amanchukwu C V, Katayama Y, Kwabi D G, Barde F, et al. The role of iodide in the formation of lithium hydroxide in lithium-oxygen batteries. Energy Environ Sci 2017; 10:1828-42, which is incorporated by reference in its entirety. In contrast, no H.sub.2O or other changes were observed in the .sup.1H NMR spectra of G4 and DME (FIG. 29) following the reaction between LiOH and I.sub.3.sup.− while pyridine showed the emergence of some small peaks (FIG. 29) which we attribute to solvent decomposition. In addition to the formation of H.sub.2O, reactions between LiOH and I.sub.3.sup.−/I.sub.2 in DMSO resulted in DMSO.sub.2 (˜2.95 ppm, FIG. 30) with quantity of 18 μmol and 25 μmol for reactions with I.sub.3.sup.− and I.sub.2, respectively (FIG. 6, panel a and panel b) while Me-Im experienced peak changes (FIG. 29) which can be attributed to the previously discussed interactions with I.sup.−/I.sub.3.sup.−. See, for example, Schutte L, Kluit P P, Havinga E. The substitution reaction of histidine and some other imidazole derivatives with iodine. Tetrahedron 1966; 22:295-306, which is incorporated by reference in its entirety. The amount of iodate species detected with iodometric titration (8.2 μmol and 6.4 μmol for reactions with I.sub.3.sup.− and I.sub.2 in DMSO, respectively) was close to that expected (16.7 μmol) for 3I.sub.3.sup.−+6LiOH.fwdarw.8I.sup.−+5Li.sup.++3H.sub.2O+LiIO.sub.3, as shown in FIG. 6, panel b. The difference can be attributed to the decomposition of DMSO by a IO.sup.− intermediate via IO.sup.−+(CH.sub.3).sub.2SO.fwdarw.I.sup.−+(CH.sub.3).sub.2SO.sub.2 which accounts for 18.5/24.9 μmol of IO.sup.− consumed in reactions with I.sub.3.sup.− and I.sub.2, respectively, which otherwise could have disproportionated to form LiIO.sub.3. A similar oxidation of DMSO to DMSO.sub.2 from intermediates of LiOH oxidation was reported by Liu et al. in a ruthenium-catalyzed Li—O.sub.2 battery system. See, for example, Liu T, Liu Z, Kim G, Frith J T, Garcia-Araez N, Grey C. Understanding LiOH Chemistry in a Ruthenium Catalyzed Li—O2 Battery. Angewandte Chemie International Edition 2017; 56:16057-62, which is incorporated by reference in its entirety. Therefore, combined spectroscopic data from .sup.1H NMR, Raman, GC and iodometric titration show that the reaction between LiOH and oxidized iodide species such as I.sub.3.sup.− leads to the formation of an IO.sup.− intermediate, which can disproportionate to form LiIO.sub.3 as the major product and attack solvent molecules to form species such as DMSO.sub.2. This reaction mechanism does not lead to the formation of O2 gas as some have reported previously. See, for example, Liu T, Leskes M, Yu W, Moore A J, Zhou L, Bayley P M, et al. Cycling Li—O.sub.2 batteries via LiOH formation and decomposition. Science 2015; 350:530-3; and Zhu Y G, Liu Q, Rong Y, Chen H, Yang J, Jia C, et al. Proton enhanced dynamic battery chemistry for aprotic lithium-oxygen batteries. Nature Communications 2017; 8:14308, each of which is incorporated by reference in its entirety.

[0139] Without being bound to any specific theory, the proposed reaction mechanism of LiOH in the presence of oxidized iodide species is supported by galvanostatic charging and DEMS measurements (FIG. 7) of pre-loaded commercial, anhydrous LiOH electrodes with a solid Li-conducting separator to eliminate shuttling, charged in 0.5 M LiTFSI G2 (FIG. 7, panel a and panel c) and DMSO (FIG. 7, panel B and panel D) with and without 0.1 M LiI addition (in cases where no LiI was added, an additional 0.1 M LiTFSI was added to fix the total Li.sup.+ concentration at 0.6 M). Of significance, there was no observable oxygen generation in either G2 or DMSO, which supports the proposed reaction with LiOH by oxidized iodide species to form LiIO.sub.3. The majority of the charging plateau took place above the I.sub.3.sup.−/I.sub.2 redox transition in G2 (comparable to DME/G4), indicating that I.sub.3.sup.− could not react with LiOH in glymes but I.sub.2 could, which is consistent with ex-situ chemical reactions (FIG. 5B, panel a and panel b). On the other hand, significant capacity was noted below the I.sub.3.sup.−/I.sub.2 redox transition in DMSO, corresponding to the formation of LiIO.sub.3 from I.sub.3.sup.−. XRD of the electrodes after charging (FIG. 40) indicated that not all LiOH was removed, which is consistent with the calculated charging capacity based on the mass of deposited LiOH (7.3 and 5.2 mAhr/cm.sup.2 for G2 and DMSO, respectively) being considerably higher than the achieved charging capacity (1.0 and 1.6 mAhr/cm.sup.2 for G2 and DMSO, respectively). However, the observed capacity is significantly larger than the maximum calculated capacity based on the oxidation of LiI (˜0.25 mAhr/cm.sup.2), indicating consumption of LiOH during charge. We postulate the incomplete oxidation of LiOH in-situ may relate to either slow kinetics of reaction with LiOH by oxidized iodide species and/or the passivation of the LiOH surface by insoluble LiIO.sub.3. Leftover LiOH after charging is consistent with the observations of Qiao et al., however, using ex-situ reactions and a solid Li-conducting separator to eliminate shuttling, we are able to demonstrate that LiOH is still active during the charging process and not inactive as suggested by Qiao et al. See, for example, Qiao Y, Wu S, Sun Y, Guo S, Yi J, He P, et al. Unraveling the Complex Role of Iodide Additives in Li—O.sub.2 Batteries. ACS Energy Letters 2017; 2:1869-78, which is incorporated by reference in its entirety.

[0140] Demonstrating the Discharge Process

[0141] Electrodes were prepared using commercially available LiIO.sub.3 from Sigma-Aldrich which was received and maintained in an α crystal structure (FIG. 50). After grinding by hand, the particle size obtained was 10-200 um (FIG. 50). Cells were constructed using a lithium iron phosphate (LFP) counter electrode and potentials were converted to a Li scale using the LFP potential of 3.45V.sub.Li. O'hara glass was using as a solid li-ion conducting membrane to prevent shuttling of iodide species between the electrodes (FIG. 51). Discharges were performed using both composite electrodes (FIG. 52) and drop cast electrodes (FIG. 53). Composite electrodes were prepared by grinding LiIO.sub.3 with carbon (SuperP and/or Vulcan carbon (VC)) and a polymer binder (PvDF) (FIG. 52) and deposited onto aluminum foil using a solvent (such as dimethoxymethane or NMP). Other electrodes were prepared by drop casting a slurry of LiIO.sub.3 and Vulcan carbon with a PTFE binder onto a carbon paper substrate (Toray 60). Electrodes were discharged under Argon environment in an electrolyte consisting of 5-10 w % H.sub.2O in 1,2-dimethoxyethane or acetonitrile. 0.5M LiTFSI was added as a conducting salt with an additional 0.1M LiI added to some electrolytes. Discharge profiles consisted of a sloped voltage profile from 2.2-2.7V vs Li (FIG. 52, FIG. 53). Electrodes recovered following discharge were analyzed using Raman (FIG. 54) and XRD (FIG. 55) and show the clear formation of anhydrous LiOH during the discharge process. Additional SEM images of pristine electrodes (FIG. 56) and discharged electrodes (FIG. 57) demonstrate clear morphological differences following discharge.

[0142] Additional work was carried out to understand the role of the electrolyte and water content on the discharge process. Discharges were carried out using drop cast LiIO.sub.3 electrodes in 1,2-dimethoxyethane (DME), acetonitrile (MeCN) and 1,4-dioxane (DOL), all with added 10 v % H.sub.2O. Discharge capacity and voltage increased from DOL, to DME, to MeCN, reaching the full anticipated discharge capacity of 880 mAhr/g.sub.LiIO3 (FIG. 58). Both XRD and Raman were performed on the discharged electrodes and support the anticipated removal of LiIO.sub.3 and formation of LiOH (FIG. 59). Acid base titrations were performed to quantify the amount of LiOH formed during discharged by adding 5 mL DI water to a 20 mL vial container either the discharged electrode or separator and allowing all LiOH to dissolve for 30 minutes. Titration was performed using 10 mM HCl and a phenolphthalein indicator. Immediately following the acid-base titration, ˜50 mg KI and 0.5 mL 5M H.sub.2SO.sub.4 was added to the vial and an iodometric titration was performed using 10 mM Na.sub.2S.sub.2O.sub.3 solution, adding a 1 w %/V starch solution near the end point. The iodometric titration results enabled the quantification of the remaining LiIO.sub.3 after the discharge process. The consumption of LiIO.sub.3 and formation of LiOH during the discharge process in the different solvents supports the proposed 6e.sup.− reduction of LiIO.sub.3 to LiOH (FIG. 58). Similar discharges were performed in DME with 1 v %, 5 v %, 10 v % and 20 v % H.sub.2O added (FIG. 60). Titrations (FIG. 60) and XRD/Raman characterization (FIG. 61) again support the proposed discharge mechanism.

[0143] Substantial morphological changes in the electrode were observed with SEM (FIG. 62), suggesting that LiIO.sub.3 and/or LiOH may be soluble in the electrolyte. In order to assess the solubility of LiIO.sub.3 and LiOH in the electrolytes, mixtures of DME, DOL and MeCN with added water were allowed to saturate with LiOH or LiIO.sub.3 under stirring for 3 days. The resulting mixtures were centrifuged and the decanted liquid was assessed using an inductively couple plasma technique to quantify the amount of dissolved lithium (FIG. 63). It was observed that upon the addition of water at 10 v % and 20 v %, both LiOH and LiIO.sub.3 could be solubilized up to ˜10 mM. The high overpotential during the discharge process are believed to stem from mass transport limitations. This hypothesis is supported by a linear trend between the overpotential on discharged (where the thermodynamic potential is 2.97V vs Li.sup.+/Li) and the logarithm of viscosity divided by the solubility of LiIO.sub.3 in the electrode (FIG. 64). Overall, the titration, SEM and discharge profile results are all consistent with a mechanism which starts with dissolution of LiIO.sub.3, then a 6e.sup.− reduction of IO.sub.3.sup.− to OH.sup.− and I.sup.−, followed by precipitation of LiOH onto the electrode surface and separator (FIG. 65).

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Derivation of the Role of Solvation Energy on Li.sub.2O.sub.2 Oxidation by I.sub.3.sup.−: For the reaction:

Li.sub.2O.sub.2+I.sub.3.sup.−.fwdarw.2Li.sup.++3I.sup.−+O.sub.2

[0221] Using the same approach as Kwabi et al.sup.2:

ΔG.sub.rxn=2Δ.sub.fG.sup.0.sub.Li.sub.++Δ.sub.fG.sup.0.sub.O.sub.2+3Δ.sub.fG.sup.0.sub.I.sub.−−Δ.sub.fG.sup.0.sub.Li.sub.2.sub.O.sub.2−Δ.sub.fG.sub.I.sub.3.sub.−+2ΔG.sub.Li.sub.+.sup.solv+ΔG.sub.O.sub.2.sup.solv+3ΔG.sub.I.sub.−.sup.solv−ΔG.sub.I.sub.3.sub.−.sup.solv

Assuming ΔG.sup.0.sub.O.sub.2.sup.solv≈0 and collecting all formation energy terms as Δ.sub.fG.sup.0.sub.rxn:

ΔG.sub.rxn=Δ.sub.fG.sup.0.sub.rxn+2ΔG.sub.Li.sub.+.sup.solv+3ΔG.sub.I.sub.−.sup.solv−ΔG.sub.I.sub.3.sub.−.sup.solv

Approximation of LiIO.SUB.3 .Formation Energy

[0222] From Huang et al.sup.3, the following reaction:

LiI+3/2O.sub.2.fwdarw.LiIO.sub.3

[0223] Has a reaction enthalpy of −3.0 eV. From Lide.sup.4, the S.sup.0 of KIO.sub.3 is 1.57 meV/° K and the Δ.sub.fG.sup.0 of LiI is −2.80 eV. Based on approximating the S° of LiIO.sub.3 to be the same as KIO.sub.3, at 298.15° K, the Δ.sub.fG.sup.0 of LiIO.sub.3 is calculated to be −5.05 eV.

Discussion of Polyiodide Species

[0224] While shifts in thermodynamics caused by changes in Li.sup.+ and I.sup.− solvation energy provide a clear explanation as to why the ability of I.sub.3.sup.− species to chemically oxidize Li.sub.2O.sub.2 can change with solvent, the dissociation of I.sub.3.sup.− into I.sub.2 species given by equilibrium (5), is also solvent dependent.sup.5 and must also be considered.

[0225] In addition to this equilibrium, there also exists higher order polyiodide species such as pentaiodide (I.sub.5.sup.−) and heptaiodide (I.sub.7.sup.−) that exist in other equilibriums caused by the association of I.sub.2 to I.sub.x.sup.− (x=1, 3, 5).sup.6-8:

I.sub.5.sup.−I.sub.2+I.sub.3.sup.−  (1)

I.sub.7.sup.−I.sub.2+I.sub.5.sup.−

[0226] To further complicate matters, iodine-solvent complexes can also cause the dissociation of I.sub.2 into I.sup.− and I.sup.+ leading to further still equilibria to consider.sup.9:

I.sub.2Solvent.Math.I.sup.++I.sup.−  (3)

where the I.sup.− formed from this dissociation would then associate with another I.sub.2 to form I.sub.3.sup.− via reaction (5). The existence of these chemical equilibria considerably complicates the interpretation of reactions involving oxidized forms of iodide, as a large number of different species can be present in the solution at any given time. This begs the question; which polyiodide species are responsible for the observed oxidation of Li.sub.2O.sub.2?

[0227] In order to examine the possible role of highly oxidizing I.sup.+ species, the reaction between Li.sub.2O.sub.2 and 12 in hexane (a solvent which does not support the formation of Solvent-I.sup.+ complexes as indicated by its purple color in FIG. 44) was conducted. After reacting with commercial Li.sub.2O.sub.2, the originally purple 50 mM I.sub.2 hexane solution became clear and an orange/brown solid remained (FIG. 45). Raman spectroscopy on this solid reveals Li.sub.2O.sub.2, in addition to peaks consistent with LiI.sub.3 (FIG. 46). While stable triiodide salts can be formed with larger cations, such as Cesium.sup.10, such complexes are not typically stable with Li.sup.+. However, due to hexane's very low solubility for most salts.sup.11, the I.sub.3.sup.− remaining after the reaction of I.sub.2 with Li.sub.2O.sub.2 is likely more stable as a solid precipitate than in solution. Over time, this precipitate was found to lose its color, which would be consistent with the sublimation of I.sub.2 gas and formation of LiI. Since I.sub.2 is able to react with Li.sub.2O.sub.2 in hexane, we can conclude that the formation of I.sup.+ is not necessary for the oxidation of Li.sub.2O.sub.2.

[0228] The equilibria between I.sub.2, I.sub.3.sup.− and higher order polyiodide species cannot be untangled as effectively as there isn't an equivalent model solvent which eliminates these equilibria. Experiments were performed using solutions of 50 mM 12, I.sub.5.sup.− (50 mM I.sub.2+25 mM LiI) and I.sub.3.sup.− (50 mM I.sub.2+0.2M LiI) in DME and both commercial Li.sub.2O.sub.2 and Li.sub.2O.sub.2 formed through disproportionation (see FIG. 27). In all cases, the reaction with commercial Li.sub.2O.sub.2 was observed to stop once the reaction proceeded enough such that the solution contained 50 mM I.sub.x (within experimental error). Raman spectra on the solution before and after the reaction (FIG. 28) indicated that while initially, the dominant species were I.sub.2, I.sub.5.sup.− and I.sub.3.sup.−, respectively, following the reaction, only the signal from I.sub.3.sup.− was visible in all solutions. Despite these results which suggest that some polyiodide species, like I.sub.5.sup.−, may be reactive with Li.sub.2O.sub.2, we note that these experiments do not clarify whether the reaction proceeds directly from I.sub.5.sup.−, or whether I.sub.5.sup.− first dissociates to I.sub.2 via reaction (1) and then the formed I.sub.2 reacts with Li.sub.2O.sub.2. In fact, the dissociation equilibria responsible for the formation of a more oxidizing and less oxidizing species (for example I.sub.3.sup.− dissociates to the more oxidizing I.sub.2 and I.sup.−), are actually unequivocally linked to the oxidizing power of the associated complex. Considering I.sub.3.sup.−, we recall from above that the increased solvation energy of I.sup.− ions increases the potential of the I.sup.−/I.sub.3.sup.− redox transition vs Me.sub.10Fc. However, the dissociation of I.sub.3.sup.− into I.sub.2 and I.sup.− will also be promoted by stronger solvation of I.sup.−. Furthermore, since this dissociation is in equilibrium, the thermodynamic driving force for the oxidation of Li.sub.2O.sub.2 by either I.sub.3.sup.− or the I.sub.2 formed from dissociation will be identical due to Nemstian shifts associated with the I.sub.2, I.sub.3.sup.− and I.sup.− concentrations present in this equilibrium. We therefore suggest that the distinction between the various polyiodide species which exist in all of the existing equilibria in solution is only relevant in discussion of reaction kinetics (and even here may not prove important unless the dissociation step is rate limiting) and that whether a reaction will occur or not is governed simply by the thermodynamic driving force for the reaction between Li.sub.2O.sub.2 and any of the polyiodide species which are in equilibria, which can be effectively understood with the framework presented above.

REFERENCES (EACH OF THE FOLLOWING REFERENCES IS INCORPORATED BY REFERENCE IN ITS ENTIRETY)

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[0241] Other embodiments are within the scope of the following claims.