Method and device for laser micromachining
11059129 · 2021-07-13
Assignee
Inventors
- François Courvoisier (Cussey sur l'Ognon, FR)
- Pierre-Ambroise Lacourt (Besançon, FR)
- Arnaud Couairon (Gif sur Yvette, FR)
Cpc classification
B23K26/40
PERFORMING OPERATIONS; TRANSPORTING
B23K2103/50
PERFORMING OPERATIONS; TRANSPORTING
B23K26/389
PERFORMING OPERATIONS; TRANSPORTING
B23K26/388
PERFORMING OPERATIONS; TRANSPORTING
International classification
B23K26/388
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The invention, according to an aspect thereof, relates to a device (60) for laser micromachining a sample made of a given material, which includes a focusing module enabling a nondiffracting beam to be generated from a given incident beam, said nondiffracting beam being focused along a focusing cylinder that is oriented generally along the optical axis of the focusing module, means (601) for transmitting at least one first light pulse (11) suitable for generating, after said focusing module focuses in the sample, a plasma of free charges by multiphotonic absorption in a volume of the sample located on the side surface of said focusing cylinder.
Claims
1. A laser micromachining device for drilling holes in a sample made of a given material, comprising: a laser source configured to generate an incident beam comprising at least one light pulse; and a spatial conditioning optical system having an optical axis and configured to generate and focus, from the incident beam, a non-diffracting beam of Bessel-Vortex type, the focused non-diffracting beam having a property of maintaining a constant profile along the optical axis, and having a shape of a hollow cylinder of given dimensions oriented along the optical axis, wherein the focused non-diffracting beam is a focusing cylinder wherein the spatial conditioning optical system is configured to adapt a size and a position of the focused non-diffracting beam in the sample, and wherein the laser source is designed to generate, after the focusing in the sample, a plasma of free charges by multi-photonic absorption in a volume of the sample situated on the lateral surface of said focusing cylinder, said plasma generates a hole formation.
2. The device as claimed in claim 1, in which the at least one light pulse has a duration of less than 100 picoseconds.
3. The device as claimed in claim 1, in which said laser source allows the emission of a first light pulse or of a train of first light pulses of given optical power, higher than a first optical power threshold, said first optical power threshold being sufficient for causing a modification of one or more physico-chemical properties of the material at the location of formation of the plasma.
4. The device as claimed in claim 3, in which said optical power is higher than a second optical power threshold sufficient for causing an ablation of the material at the location of formation of the plasma.
5. The device as claimed in claim 1, in which the laser source allows the emission of at least a second electromagnetic wave designed to be spatially superposed at the location of formation of the plasma.
6. The device as claimed in claim 5, in which said laser source comprises a single laser source, and wherein a first and at least a second light pulse are conditioned in a time-domain to be generated starting from a light wave emitted by said laser source.
7. The device as claimed in claim 1, in which the optical system allows a beam to be generated having an annular distribution of an intensity in a space of spatial frequencies and a phase in the space of the spatial frequencies of the type Φ(k.sub.r,θ)=Nθ, where (k.sub.r,θ) are the cylindrical coordinates and N is a relative non-zero integer.
8. The device as claimed in claim 1, in which the optical system allows, after focusing in said sample, a plurality of focusing cylinders to be formed simultaneously.
9. The device as claimed in claim 1, wherein the laser source is configured to condition a polarization of light pulses.
10. The device as claimed in claim 1, wherein the focusing cylinder is configured to evacuate the material contained inside the focusing cylinder.
11. A method for drilling holes in a sample made of a material having a given transparency band by laser micromachining, comprising: emitting an incident beam comprising at least one light pulse with a spectral band included within the transparency band of said material; and spatial conditioning said first pulse for generating, after focusing in said sample, a non-diffracting beam of Bessel-Vortex type, the focused non-diffracting beam having a property of maintaining a constant profile along an optical axis, and having a shape of a hollow cylinder of given dimensions oriented along the optical axis, the focused non-diffracting beam being a focusing cylinder, wherein light intensity of said non-diffracting beam allows a plasma of free charges to be generated by multi-photonic absorption within a volume of the sample situated on the lateral surface of said focusing cylinder, said plasma generates a hole formation.
12. The method as claimed in claim 11, further comprising emitting a first light pulse or of a train of light pulses with an optical power sufficient to cause a modification of one or more physico-chemical properties of the material at the location of formation of the plasma.
13. The method as claimed in claim 12, in which said optical power is sufficient for causing an ablation of the material at the location of formation of the plasma.
14. The method as claimed in claim 11, further comprising: emitting at least a second electromagnetic wave with a spectral band included within the transparency band of said material, spatially superposed at the location of formation of the plasma so as to generate a heating up of said material by absorption by the free charges of the plasma.
15. The method as claimed in claim 11, applied to the micro-drilling of a sample made of a given material for the formation of at least one through-hole, comprising: controlling the diameter of the through-hole by the control of the spatial conditioning parameters of the at least one light pulse; and controlling the relative position of the sample and the focused non-diffracting beam.
16. The method as claimed in claim 15, further comprising: evacuating the material contained inside the focusing cylinder in order to form said through-hole.
17. The method as claimed in claim 11 applied to the cleaving of a sample, further comprising: displacing the focused non-diffracting beam along a cleaving plane.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Other advantages and features of the invention will become apparent upon reading the description, illustrated by the following figures:
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DETAILED DESCRIPTION
(13)
(14) According to this example, the micromachining method comprises an emission 101 of a beam by a pulsed laser source, and the focusing of the beam onto a sample 10 to be drilled, after a time-domain conditioning step 102 (optional), a spatial conditioning step 103 and a polarization conditioning step 104 (optional) which will be described in more detail hereinbelow. The scanning of the beam and the translation/rotation (symbolized by the arrows 106) of the sample can allow a relative movement between the beam and the sample in order to carry out several drillings sequentially on the same sample. According to one variant, as will be described in more detail hereinafter, the component to be drilled may be prepared prior to the drilling operation (step 105) and a step for cleaning the component after drilling (step 107) may also be carried out in order to eliminate the ablated material.
(15) The spatial conditioning 103 of the incident beam allows a non-diffracting beam to be formed after focusing, thus foaming a focusing cylinder in the sample, in other words a beam having the property of maintaining a constant profile along the axis of propagation on a focusing cylinder of given dimensions, hence the description “non-diffracting”. Such a beam exhibits a maximum of light intensity on the surface of the focusing cylinder.
(16) A non-diffracting beam according to the present description, generally speaking, has an annular intensity distribution in the domain of the spatial frequencies with an intensity maximum for a non-zero spatial frequency k.sub.r0 and a negligible intensity, typically less than or equal to a twentieth of the maximum intensity, for spatial frequencies in the range around the spatial frequency zero, for example between k.sub.r=0 and k.sub.r=k.sub.r0/5. It furthermore exhibits a spectral or spatial phase of the type Φ(r, θ)=Nθ, where (r, θ) are the cylindrical coordinates, and N, a relative non-zero integer, called topological charge of the vortex.
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or a more peaked distribution, as is illustrated in
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(20) In the example illustrated in
(21) According to one variant, a single spatial conditioning element will be able to be used for applying the annular conditioning and the vortex conditioning.
(22) Bessel-Vortex beams possess several special features used to advantage in the device and the method according to the present description.
(23) The non-linear propagation in the material of non-diffracting beams, and notably beams of the Bessel-Vortex type, is quasi-stationary. This means that, even at high intensity, these beams are subject to very little deformation in the spatial and time domains. This is in strong contrast to the propagation of Gaussian beams, which are deformed at high intensity owing to the Kerr effect (self-focusing) and to the interaction with the plasma of free electrons generated by the laser pulse in the material.
(24) Advantageously, the applicants have shown that an excellent stationarity of beams of the Bessel-Vortex type is obtained for a sufficiently large conical angle, preferably greater than around 10°.
(25) Lastly, variants of the beams of the Bessel-Vortex type may be formed by applying a slight additional deformation to the wavefront. For example, the diameter of the central ‘dark’ region may decrease or increase along the propagation, while at the same time maintaining the property of non-linear quasi-stationarity of the beam, as is illustrated in
(26) Thanks to the spatial conditioning of the pulses implemented in the present description, it is thus possible, with very high light intensities (for example using femtosecond pulses), to cause a nano-explosion within the material by means of a single laser pulse, and to generate a cylindrical hollow. The material is thus only vaporized on the lateral surface of the cylinder. The material remaining inside this cylinder may be evacuated by the force of gravity or by using other methods, for example by an ultrasound cleaning.
(27) It is also possible to work under the ablation threshold; the material then undergoes a modification of its physical and/or chemical properties due to the laser pulse, then a step for selective chemical attack (for example by the hydrofluoric acid or potassium hydroxide for the case of silica glasses) allows the ablation per se to be generated.
(28) Thus, the drilling of channels with dimensions of the order of a few tens of micrometers in diameter over a few tens of micrometers in depth is achievable by means of a single laser pulse, which renders the technique extremely attractive in terms of speed of execution.
(29) According to one variant shown in
(30) The time-domain conditioning of the incident beam in the form of two pulses with suitable durations and wavelength thus allows an excitation at low energy to be carried out and the non-linear effects during the propagation in the material to be minimized accordingly, then the density of energy necessary for the heating up of the material to be deposited for causing it damage or its ablation by virtue of the second pulse of longer duration.
(31) As an alternative to the use of a single laser source and of a time-domain conditioning module, two separate laser sources may be used for generating the first and second pulses. Furthermore, the deposition of energy can be carried out by means of an electromagnetic wave which is not a light wave, for example a wave of the microwave or terahertz wave type, as long as the spectral band of the electromagnetic wave is included within the range of transparency of the material and can be absorbed by the free charges of the plasma formed by the first pulse. Alternatively, the deposition of energy may be effected by a train of short rapid pulses.
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(33) The device 60 comprises, in this example, a laser source 601 adapted to the emission of ultra-short first pulses, denoted I.sub.1. Optionally, a time-domain conditioning module 602 can allow first and second light pulses to be generated, as has been previously described and will be detailed in the following.
(34) The device furthermore comprises a focusing module 603 for the spatial conditioning of the pulses in the sample, allowing, starting from a given incident beam, a non-diffracting beam 310 to be generated in the sample according to a focusing cylinder. The non-diffracting beam is for example of the Bessel-vortex type. The focusing cylinder is generally oriented along an optical axis of the focusing module. In the case of two light pulses formed by the time-domain conditioning module, the two pulses advantageously pass through the same module 603, which allows the spatial superposition of the pulses in the sample to be facilitated.
(35) In the example in
(36) As previously explained, the spatial conditioning of the beam comprises two aspects. On the one hand, it aims to create an annular intensity distribution in the domain of the spatial frequencies, and on the other hand, to apply a phase of the vortex type to the beam(s). These two conditioning functions may be carried out independently or conjointly by the same optical element.
(37) The optical elements allowing the conditioning of the vortex type to be carried out are for example a phase hologram in reflection or in transmission mode, an intensity hologram (in particular binary) in reflection or in transmission mode, a spatial phase modulator, a glass plate in which a distribution of anisotropy is photo-inscribed (see for example M. Beresna et al. “Polarization sensitive elements fabricated by femtosecond laser nanostructuring of glass”, Optical Material Express Vol. 1 N° 4 (2011)).
(38) In order to form an annular intensity distribution, the elements described hereinabove can all be used for applying a spatial phase of the type Φ(r)=βr (in cylindrical coordinates). For the same purpose, it is furthermore possible to use an axicon, or a mirror with a hole in its center. Advantageously, a single spatial conditioning element will be used for applying the annular conditioning and the vortex conditioning.
(39) Furthermore, it is advantageous to be able to form these beams, with identical or slightly different characteristics, in parallel. This may be achieved by virtue of matrices of holographic structures, or of matrices of micro-axicons in particular.
(40) According to one variant, the device 60 may furthermore comprise a module for conditioning the polarization of the non-diffracting beam. In particular, circular polarization allows uniform damage to be obtained irrespective of the point of the beam. Benefits in terms of ionization efficiency may also be gained from a radial or ortho-radial polarization.
(41) The imaging system is for example a system of the “telescopic” or “4f” type, in order not to introduce any quadratic phase distortion, and comprises for example an optical element 604 and a microscope lens 609. In the example in
(42) In the example in
(43) According to one variant, the spatial conditioning may comprise amplitude modulation allowing the intensity of the beams on the axis of propagation to be adjusted, in particular so as to render it as uniform as possible. This amplitude modulation may be achieved either by a specific modulation system of the focusing module, for example a matrix of mirrors or a phase modulator, or it may be integrated into the existing modulation system when such a modulation system is already used to form the non-diffracting beam. In this case, a part of the energy may be diverted toward a diffraction order that will be spatially filtered, for example by means of the spatial filter 611 described in
(44) In order to reduce the time for moving between one ablation site and another, it may be advantageous to use a displacement system for the laser beam, such as a system of the galvanometrical mirrors type 608 or a system of rotating plates with non-parallel faces.
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(46) Each of the devices 70.sub.A and 70.sub.B comprises a laser source 701 and a time-domain conditioning module 702 allowing said first and second light pulses I.sub.1 and I.sub.2 to be generated. The device furthermore comprises a focusing module 703 for the spatial conditioning of the beam allowing the generation, starting from a given incident beam, of a non-diffracting beam 310, for example of the Bessel-vortex type, such as has been previously described. For example, the focusing module comprises an optical system 712 designed to generate the non-diffracting beam and an optical block 709, comprising a telescope, for the beam reduction and a set of mirrors for the deflection and the scanning. In the examples in
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(49) As an alternative to the devices 70.sub.A and 70.sub.B shown in
(50) According to one variant, the duration and the energy of the second pulse are adjusted so as not to produce any effect if the second pulse alone is applied in the material. In this case, the synchronization of the pulses is a more flexible parameter. The second pulse may be sent before the first pulse. The energy deposited in the material is then proportional to the time difference between the end of the second pulse and the start of the first pulse. In particular, this approach allows the constraints on the precision of the synchronization to be reduced when the duration of the second pulse is long compared with that of the first pulse.
(51) According to one variant, the nano-machining device according to the invention comprises an electronically-controlled shutter allowing one or more pulses to be selected from amongst the train of pulses emitted by the laser(s). The shutter may be mechanical or optical. In the latter case, it could for example be a Pockels cell followed by a polarizer.
(52) Alternatively, the time-domain conditioning comprises the generation of a train of pulses, the first of the pulses, ultra-short, allowing the generation in the sample of the plasma of free charges on the focusing cylinder obtained by multi-photonic absorption by virtue of the focusing module and the subsequent pulses allowing the deposition of the energy. The duration of the first pulse is for example less than 10 ps. The second pulses can be longer or shorter but each of low intensity. Thus, it is possible to use a train of ultra-short second pulses for the deposition of the energy and the generation of the heating of the material by absorption by the free charges of the plasma, typically with a duration of less than 10 ps, for example with a duration of less than the lifetime of the plasma of free charges in the material (i.e. around 100 fs in glass). The pulses are brought closer together, for example the time difference between the pulses is less than 10 ps. The intensity of said pulses is sufficiently low to avoid the beam de-stabilization by a non-linear effect of the Kerr type. On the other hand, the intensity may be sufficient for contributing to the generation of free charges and amplifying the plasma density. The generation of a train of pulses may be obtained by the means described with reference to
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(56) According to one variant, in order to limit the deposition of debris after ablation or in order to allow an adaptation of linear index and/or of non-linear index so as to reduce the deformation of the beam upon crossing the air/glass interface, the component may be “prepared” prior to the drilling operation, for example by deposition on the surface or surfaces of the component to be drilled of a layer of polymer which will be able to be removed after drilling by chemical cleaning.
(57) The drilling operation is preferably carried out in the open air, or, according to one variant, in water or in a liquid medium for either limiting the deposition of debris after ablation or implementing the above-mentioned index adaptation, or else, in multi-pulse ablation mode, for allowing a progressive drilling on the back face.
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(61) The component to be formed is for example illustrated in
(62) It is also possible to evacuate the cylinder 22 using a jet of air or of liquid, or via a de-pressurization exerted on one face of the component to be drilled. Alternatively, it is possible to evacuate the cylinder 22 by means of a cleaning process in an ultrasound bath or using chemical attack, chosen as a function of the material to be ablated. For example, for fused silica or glasses, it may be advantageous to eliminate the cylinder of remaining material 22 by a chemical attack with hydrofluoric acid (HF) or by a chemical attack with potassium hydroxide (KOH), which could be combined with a cleaning process as mentioned in the previous points.
(63) As far as the drilling itself is concerned (
(64) According to a first variant illustrated in
(65) In the case of a thick sample, in other words thicker than the diffraction length of the Bessel-Vortex beam, several variants are possible. According to a first example, the component is moved longitudinally along the axis of the focusing cylinder. According to a second example, illustrated by
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(67) Other variants are envisioned for the micro-drilling.
(68) For example, the component to be drilled may advantageously undergo, between two laser shots, one rotation about the axis of the beam, in such a manner as to spread out the damage induced uniformly.
(69) In order to implement several drillings on the same component, it is possible to translate the component between each site or to perform the ablation of several sites at the same time by virtue of a device allowing Bessel-Vortex beams to be generated in parallel. This solution may advantageously be obtained by means of holograms known as ‘multiplex holograms’.
(70) For the formation for example of holes with large diameters (typically larger than a few tens of microns), several laser shots may be carried out on the same site of the component to be drilled, but using slightly different parameters for the Bessel-Vortex beams, in order to generate damaged areas on concentric cylinders with different diameters. These beams with different parameters may be formed either with different means for producing the beam or by varying the parameters between each illumination or each sequence of illuminations of several sites.
(71) In the case of drilling holes of large diameter, it is also possible to use a “milling” process. In this case, the method comprises for example the displacement of a focusing cylinder around the region to be hollowed out.
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(73) A sample 10 is illuminated for example by means of a beam of the Bessel-Vortex type 310 such as previously described, and the sample is displaced with respect to the beam in such a manner as to create a modification of the physico-chemical properties of the material within volumes 120.sub.i, 120.sub.j, 120.sub.k, 120.sub.l, situated on the lateral surface of the focusing cylinder (
(74) Although described via a certain number of detailed exemplary embodiments, the method and the device for laser micromachining according to the invention comprise various variants, modifications and improvements which will be apparent and obvious to those skilled in the art, it being understood that these various variants, modifications and improvements form part of the scope of the invention, such as defined by the claims that follow.