COOLING ELEMENTS AND COOLING ASSEMBLIES COMPRISING SAME

Abstract

A cooling element for cooling a body, comprising a heat conduction layer coterminous with a proximal side of the cooling element, a heat retardant layer coterminous with a distal side of the cooling element, and a heat sink volume disposed between the heat conduction and heat retardant layers, extending from a proximal boundary with the heat conduction layer to a distal boundary with the heat retardant layer. The heat sink volume comprises a porous material including a first substance; and the heat conduction layer comprises a porous material including a second substance. The first and second substances have thermal properties such that the first substance will solidify at a first temperature, the second substance being in the liquid state at the first temperature. The heat retardant layer has a lower mean thermal conductivity than the heat conduction layer.

Claims

1. A cooling element, comprising a heat conduction layer coterminous with a proximal side of the cooling element, a heat retardant layer coterminous with a distal side of the cooling element, and a heat sink volume disposed between the heat conduction and heat retardant layers, extending from a proximal boundary with the heat conduction layer to a distal boundary with the heat retardant layer; in which the heat sink volume comprises a porous material including a first substance; the heat conduction layer comprises a porous material including a second substance; the first and second substances having thermal properties such that the first substance will solidify at a first temperature less than 20° C., the second substance being in the liquid state at the first temperature; and the heat retardant layer has a lower mean thermal conductivity than the heat conduction layer; configured such that when the proximal side of the cooling element contacts a surface of the body as in use, the heat conduction layer will conduct heat from the body and into the heat sink volume more rapidly than heat is conducted through the heat retardant layer and into the heat sink volume, from the distal side of the cooling element.

2. The cooling element as claimed in claim 1, wherein the cooling element is sufficiently flexible to be capable of curving in any of a range of arcs, in response to being placed against a curved surface of a body to be cooled.

3. The cooling element of claim 1, in which the heat sink volume comprises a plurality of heat sink elements.

4. The cooling element of claim 1, in which the porous material of the heat sink volume comprises a biodegradable and/or compostable material.

5. The cooling element of claim 1, in which the porous material of the heat conduction layer, and the porous material of the heat sink volume, and the heat retardant layer comprise a biodegradable and/or compostable material.

6. The cooling element of claim 1, in which the heat retardant layer comprises a biodegradable and/or compostable material.

7. (canceled)

8. The cooling element of claim 1, in which the porous material of the heat conduction layer, and/or the porous material of the heat sink volume, and/or the heat retardant layer comprise a biodegradable and/or compostable material and the biodegradable and/or compostable material comprises at least one of paper, cardboard, hemp fibers, bamboo fibers, or wood-pulp material.

9. The cooling element of claim 1, in which the volume of the second substance is less than the volume of the first substance.

10. The cooling element of claim 1, in which the heat retardant layer is free of any liquid phase up to 50° C.

11. The cooling element of claim 1, in which the first substance comprises water.

12. The cooling element of claim 1, in which the second substance comprises an aqueous solution.

13. The cooling element of claim 1, in which the second substance comprise a solution of sodium chloride in water.

14. The cooling element of claim 1, in which the mean thickness of the heat conduction layer is 0.5-3 mm.

15. The cooling element of claim 1, in which the mean thickness of the heat retardant layer is 1-15 mm.

16. The cooling element of claim 1, in which the pores of the porous material of the heat conduction layer are filled with the second substance; or partly filled and include air voids.

17. A cooling assembly for cooling a body comprising: one or more cooling element as claimed in claim 1, and a container for containing the body and the cooling element.

18. The cooling assembly as claimed in claim 17, comprising a plurality of cooling elements.

19. The cooling assembly of claim 18, in which the container is configured for accommodating more than one body.

20. A method of cooling a body, the method comprising: providing a cooling assembly as claimed in claim 1; reducing the temperature of the heat sink volume to less than the first temperature; arranging the cooling element between the body and a surface of the container, the body being housed within the container; the proximal side of the cooling element being in contact with the body.

21. The method of claim 20, further comprising: providing a cooling element such that the heat capacity of the heat sink volume is sufficiently great to reduce the temperature of the body by at least 5° C., from an initial temperature of around 20° C. to 40° C.

Description

[0041] Non-limiting example arrangements of chiller devices will be described with reference to the accompanying drawings, of which

[0042] FIG. 1 shows a schematic exploded view of a portion of an example cooling element, as well as a perspective view of a portion of the cooling element, assembled as for use;

[0043] FIG. 2A shows a perspective view of an example cooling element, viewed from the proximal side; and FIG. 2B shows a perspective view from the distal side of the cooling element;

[0044] FIG. 3A shows a perspective top view of an example cooling assembly, without beverages present; and FIG. 3B shows a perspective view of the example container assembly containing two drink cans;

[0045] FIG. 4A shows a schematic top view of an example cooling assembly, with two drinks cans present; FIG. 4B shows a schematic perspective view of an example cooling element wrapped against a drink can as in use; and FIG. 4C shows a perspective top view of the example cooling assembly, containing two drinks cans; and

[0046] FIG. 5A-5E shows various views of various component parts of an example cooling assembly: FIG. 5A shows a perspective view of a portion of an example cooling element, from the distal side; FIG. 5B shows a schematic top view of an example bottle cooler assembly, with a bottle present; FIG. 5C shows a perspective view of the cooling assembly, containing a wine bottle; FIG. 5D shows a perspective view of the container assembly with the bottle present, in which the two example cooling elements are being removed from, or inserted into, the container; and FIG. 5E shows a perspective view of an example bottle container in a compact condition for storage or transportation.

[0047] With reference to FIG. 1-FIG. 5E, example cooling elements 100 may comprise a heat conduction layer 130, a plurality of elongate heat sink bars 120, and a heat retardant layer 110 (which may also be referred to as a thermal insulation layer). With particular reference to FIG. 1, the heat conduction layer 130 may consist essentially of a thin (for example, 1-2 mm thick), substantially flat sheet of paper impregnated with a water-based solution (for example saline solution), a proximal (inner) side 130-i of which is intended to contact a body to be cooled (for example a bottle or can containing a beverage, not shown). The heat sink bars 120 may consist essentially of paper, or cardboard material, or other porous biodegradable (and/or compostable) material, impregnated with water, which water may be frozen or partially frozen when in use, or which water may be liquid water when in storage or transportation. In this particular example arrangement, each heat sink bar 120 has a substantially flat proximal (inner) side 120-i, which will contact a distal (outer) side 130-o of the heat conduction layer 130 when assembled, and an opposite distal (outer) side 120-o, which includes a flat surface area extending along the length of the heat sink bar 120. The distal (outer) sides 120-o of the heat sink bars 120 will contact a (proximal) inner side 110-i of the thermal barrier layer 110 when assembled for use. The thermal barrier layer 110 may be a substantially water-free (or dry) sheet of paper or cardboard, having a corrugated form that is configured to accommodate the plurality of heat sink bars 120.

[0048] When the cooling element 100 is assembled as in use, its distal (outermost) side will be at least partly defined by the distal (outer) side 110-o of the thermal barrier layer 110, and its proximal (innermost) side will be defined by the proximal (inner) side 130-i of the heat conduction layer 130. In some examples, the innermost side of the cooling element 100 will contact a drinks container, such as a drink can or bottle (or other chilled product, in general) that is intended to be cooled (or to remain cooled), and the outermost side may be held by a user. The poor thermal conductivity of the heat retardant layer 110, relative to the thermal conductivity of the heat conduction layer 130, will reduce the flux of heat from the ambient environment, including from the user's hand, to the heat sink bars 120, which may make it comfortable for the user to hold the chilled drink container, and reduce the rate at which the heat sink bars 120 heat towards the ambient temperature. In general, the longer the heat sink bars 120 can be maintained below the ambient temperature, the longer the cooling assembly 100 can function to chill the drink container (and consequently any beverage contained inside it).

[0049] The heat conduction layer 130 may comprise a porous matrix, such as fibrous material; for example, the porous matrix may comprise fibrous material such as paper or cardboard, which includes pores between the fibres. The pores may be at least partly filled with an aqueous solution of sodium chloride (NaCl). In some examples, the pores may include air bubbles, or unfilled voids, which may reduce the rate at which heat can be transported from the drink container to the heat sink bars 120, and which may be desired for reducing the rate of cooling of the drink container (or other body) and extending the period over which the drink container is maintained at temperatures below the ambient temperature. It is envisaged that that the volume of unfilled pores (that is, unfilled with aqueous solution), and the volume of saline solution within the pores can be varied according the desired heat transport behaviour of the heat conduction layer 130 in use, depending on the kind of drink in a drink container, or the circumstances of use, for example.

[0050] While wishing not to be bound by a particular theory, the temperature at which a saline solution will freeze (at a given pressure) will generally decrease as the dissolved salt content increases towards the saturation point. The freezing point of pure water is 0° C. at one atmosphere of pressure, and the freezing point of saline solution having a NaCl content can be reduced by about 1-2° C. The impregnation of saline solution in the heat conduction layer 130 is understood to promote the transport of heat from the drink container, or other body to be cooled. In use, the heat conduction layer 130 may be wrapped at least partly around, and against, a drink container (or other body) to be cooled. The saline solution should remain substantially unfrozen in use, heated by the heat being transported from the body, and may form a wetting contact with a surface of the drink container. Heat can diffuse from the body into the saline solution forming a good thermal contact with it, through the saline solution impregnated within the pores of the porous matrix of the heat conduction layer 130, and into the heat sink 120 (some saline solution may infiltrate into the heat sink elements to some extent).

[0051] The heat sink bars 120 may comprise a porous matrix, such as fibrous material; for example, the porous matrix may comprise fibrous material such as paper or cardboard, which includes pores between the fibres. The pores may be impregnated with substantially pure water between the fibres. The water may be frozen or partly frozen, in use. In other examples, the pores may contain saline solution, or some other aqueous solution, or emulsion; or the pores may contain a gel, or substantially non-aqueous medium. The porous matrix material of the heat sink bars 120, and/or the material with which the porous material is impregnated may be selected to enhance the ability of the heat sink bars 120 (or other configuration) to retain their shape as the ice melts, or the other impregnation medium liquifies, in use. The combined water content of the plurality of heat sink bars 120 may be of the order of 10 g, or 100 g; for example, the water content may be about 50 g to about 500 g. The shape of the heat sink volume may be configured according to the shape of the container, or other body, to be cooled; and/or the shape of the heat sink volume may be configured to be suitable for wrapping against surfaces having any of a range of shapes, such as curvatures. In the example illustrated in FIG. 1, the heat sink volume is in the form of a plurality of bars, such that the relative disposition of neighbouring bars can be varied depending on the shape the drink container to be cooled. In certain other examples, the heat sink volume 120 may comprise a single pre-shaped body, or a flexible sheet. In various examples, the matrix material comprised in the heat sink bars 120 may be substantially the same, or different, kind of material that is comprised in the heat conduction layer 130.

[0052] The thermal barrier sheet 110 may contain any of a wide range of materials that have a sufficiently low thermal conductivity, such that the risk of a user's hand becoming uncomfortably cold when they are holding the cooling element 100 in use; and/or such that the heat sink means 120 remains frozen for a sufficiently long period. In the example illustrated in FIG. 1, the thermal barrier sheet 110 is formed of a thin sheet of paper or cardboard that is corrugated to conform the shapes of the outer sides 120-o of the heat sink bars 120. In various examples, the type of material comprised in the thermal barrier layer 110 may be substantially the same, or different from, the porous matrix material comprised in the heat sink bars 120, and/or the matrix material comprised in the heat conduction layer 130.

[0053] With reference to FIG. 2A and FIG. 2B, an example cooling element 100 may comprise a heat conduction layer 110, a plurality of heat sink bars 120 and a thermal barrier layer 130. These layers may be attached to each other by means of adhesive material, and may have the features and characteristics as described with reference to FIG. 1.

[0054] With reference to FIGS. 3A and 3B, and FIGS. 4A-4C, example cooling assemblies may comprise a carrier 200 for containing and carrying one or two (or more than two) drink cans 300, and a pair of cooling elements 100A, 100B. The carrier 200 may formed of cardboard and have a pair of ears that include through-holes as handles, to facilitate a user carrying the carrier 200, and drink cans 300 contained by it. While the carriers 200 in each of the examples have somewhat different configurations, both comprise a containment volume of sufficient size to accommodate two drink cans (for example, 330 ml capacity drink cans) and the pair of cooling elements 100A, 100A. Each of the cooling elements 100A, 100B may be as described with reference to FIG. 1, and be capable of being formed into a semi-circular arc, such that the substantially flat proximal (inner) side 130-i of the heat conduction layer 130 can wrap about halfway around the cylindrical side of a drink can 300. This is facilitated by the heat sink volume 120 being in the form of separate heat sink bars, and the thermal barrier layer 110 being corrugated to accommodate the heat sink bars 120. In the illustrated example arrangements, each of the cooling elements 100A, 100B can be inserted between a respective drink can 300 and a respective end of the carrier 200, each having substantially the same semi-circular shape as the cylindrical side of the drink can 300. Prior to use, the cooling elements 100A, 100B will have been treated in a refrigerator or freezer to freeze the water or other medium impregnated into the porous matrix comprised in the heat sink bars 120. Each treated cooling element 100A, 100B can be inserted into the carrier 200, between a drink can 300 and a respective end of the containment volume of the carrier 200.

[0055] In the particular example shown in FIGS. 3A and 3B, each of the heat sink bars 120 includes a plurality of elongate cavities extending from one end of the heat sink bar 120 to the other. The presence of the cavities may have the aspect of reducing the amount of material within the cooling elements, and/or of achieving a desired cooling rate response.

[0056] In the particular example shown in FIGS. 4A-4C, each of the heat sink bars 120 has four substantially flat longitudinal sides that extend between opposite ends, in which inner and outer sides are substantially parallel to each other, and connected to each other by tapered, non-parallel sides.

[0057] With reference to FIG. 5A-5E, an example cooling assembly may comprise a carrier 200 for containing and carrying a bottle 300, such as a wine bottle, and a pair of cooling elements 100A, 100B. The carrier 200 may formed of cardboard and have a pair of ears that include through-holes, to form handles and facilitate a user carrying the carrier, and potentially a wine bottle contained by it. In the illustrated example, the carrier 200 may comprise a containment volume of sufficient size to accommodate the bottle 300 (for example, a 750 ml capacity bottle) and the pair of inserts 100A, 100A. Each of the cooling elements 100A, 100B may be as described with reference to FIGS. 1-4C, and be capable of formed into a semi-circular arc, such that the substantially flat inner side of the heat conduction layer 130 can wrap about halfway around the cylindrical side of a bottle 300. The heat sink bars 120 may have four substantially flat longitudinal sides that extend between opposite ends, each being substantially square, rectangular, or tapered when viewed in lateral cross-section (that is, in a plane perpendicular to the longitudinal axis of the heat-sink bar 120). As shown in FIG. 5D, each of the two cooling elements 100A, 100B can be inserted between opposite sides of the bottle 300 and a respective side of the carrier 200, each having substantially the same semi-circular shape as the cylindrical side of the bottle 300.

[0058] Prior to use, the cardboard carrier 200 may be provided in compact form as shown in FIG. 5E, since it may be more efficient to pack and store the carrier 200 in a flat, folded form. A user may open the carrier 200 and place a bottle 300 (or in general some other body to be cooled) into the containment volume. The carrier 200 should be configured such that the containment volume is sufficiently wide to accommodate the bottle as well as at least a pair of cooling elements 100A, 100B between respective sides of the bottle 300 and the wall of the containment volume. Each cooling element 100A, 100B can be prepared by impregnating the porous matrix with water, and then placing them in a refrigerator at a temperature below the freezing point of water for a sufficiently long period for substantially all the water to freeze. If the saline solution impregnated into the heat conduction layer 130 also freezes, then it is expected to melt before the water in the heat sink bars 120, owing to the lower freezing point of the saline solution, especially when the conduction layer 130 is placed in contact with the bottle 300 in use. The cooling element 100A, 100B can be bent into an arcuate form to match the curvature of the side of the bottle 300, and inserted between respective sides of the bottle 300 and the wall of the containment volume of the carrier 200, such that the proximal (inner) side 130-i of the heat conduction layer 130 is in contact with the respective side of the bottle 300. In the illustrated example, the heat sink volume 120 is in the form of a plurality of bars (six bars 120 in each cooling element 100, in this example) arranged substantially parallel to each other and connected by the heat conduction layer 130 on the proximal (inner) side 120-i and by the thermal barrier layer 110 on the distal (outer) side 120-o. This arrangement can allow the cooling element 100A, 100B to be bent sufficiently to match the curvature of the bottle 300, even when the heat sink bars 120 are frozen solid. In some examples, wine contained within the bottle 300 may be cooled from about 24° C. to about 15° C. in approximately 15 minutes.

[0059] The method of using the cooling assemblies for drink cans described with reference to FIGS. 3A-4C will be substantially the same as described with reference to FIGS. 5A-5E in connection with a wine bottle. The cardboard carriers 200 can be configured such that the same cooling elements 100A, 100B can be used in combination with a variety of drink containers, including cans and bottles; and the example cooling elements 100A, 100B may be bent into a range of curvatures, for use with various drink containers. For example, the cooling elements 100A, 100B may be used with a range of drink cans and bottles.

[0060] Certain example cooling elements may contain a relatively low content of water, and may have the aspect of promoting a sustainable environment and minimising the consumption of clean water, particularly in geographical regions in which water is relatively scarce. In various examples, it may be desirable for the amount of water, or other impregnated medium, contained within the heat sink, and/or within the heat conduction layer, to be relatively low, or to be minimised. In some examples, each cooling element may contain less than about 130 millilitres (ml) of water.

[0061] Certain example cooling elements may have a relatively low content of salt within the heat conduction layer, and/or may comprise porous matrix material (comprised in the heat conduction member, and/or the heat sink means, and/or the thermal barrier layer) that is biodegradable (and/or compostable), and may have the aspect of being readily compostable, or recycled, and environmentally friendly. In some examples, the cooling elements may be substantially entirely biodegradable (and/or compostable). Certain example cooling elements may be capable of being re-used one or more times; and in some examples, the carrier, and/or the heat sink means, and/or the thermal barrier layer, and/or the heat conduction layer may comprise or consist essentially of recycled cardboard (or other biodegradable and/or compostable material).

[0062] Various example heat sink means may be impregnated, or impregnable, with water, and have the aspect of being readily frozen by means of a domestic refrigerator. Certain example cooling elements may comprise relatively few different kinds of material, and relatively few components having relatively simple shapes, and may have the aspect of being relatively straightforward to manufacture using simple equipment, potentially consuming relatively little energy in the process.

[0063] As used herein, ‘wetting’ refers to the ability of a liquid to maintain contact with the surface of a solid body, resulting from intermolecular interactions when the two are brought together. Wettability may be measured by a method involving placing a drop of the liquid onto the surface of the body, and determining the angle between the surface and a plane tangent to the surface of the drop, where the surface of the drop meets the surface of the body. The angle is included within the drop, and may be referred to as the ‘contact angle’. In general, the lower the contact angle (that is, the more the drop tends to spread out over the surface of the body), the greater the wettability of the liquid in relation to the material of the body; and the higher the wetting angle, (that is, the more the drop tends to adopt a shape that reduces the area of contact with the body), the lower the wettability. As used herein, a ‘wetting contact’ corresponds to a contact angle of less than 90° (in air).

[0064] As used herein, the phrase “consists essentially of” means “consists of, apart from a non-substantial content of practically unavoidable impurities”.