High-temperature and flame-resistant colored adhesive tape, use of a substrate for its manufacture, and cable harness including such an adhesive tape
11081255 · 2021-08-03
Assignee
Inventors
Cpc classification
C09J183/00
CHEMISTRY; METALLURGY
C09J9/00
CHEMISTRY; METALLURGY
C08L33/06
CHEMISTRY; METALLURGY
C09J2301/41
CHEMISTRY; METALLURGY
C09J133/00
CHEMISTRY; METALLURGY
C08K5/0041
CHEMISTRY; METALLURGY
International classification
H01B7/29
ELECTRICITY
C09K5/00
CHEMISTRY; METALLURGY
C09J183/00
CHEMISTRY; METALLURGY
C09J133/00
CHEMISTRY; METALLURGY
H01B7/00
ELECTRICITY
Abstract
A colored adhesive tape (1), in particular a yellow, orange-colored, or black adhesive tape (1), preferably a cable wrapping tape, with a temperature class of at least T3 (LV 312), including a textile substrate with a polymer plastic substrate (4, 4a, 4b), on which an adhesive material (5, 5a, 5b) is applied. In order to improve the temperature stability of the tape, while maintaining advantageous properties, the color of at least a part of the substrate (4, 4a, 4b) is formed by the inherent color of the polymer plastic material. The tape is preferably substrate formed of a polymer plastic materials which are aromatic, nitrogen-containing polymers from the group of polyoxadiazoles (POD), polybenzobisoxazoles (PBO) or polybenzimidazoles (PBI) (4, 4a, 4b). The adhesive tape (1) may be used as a cable harness (3).
Claims
1. A colored adhesive tape for use as a cable-wrapping tape, with a temperature class of at least T3 according to LV 312, comprising, a textile substrate including at least one polymer plastic material, on which an adhesive layer is applied at least on one side of the substrate, wherein the at least one polymer plastic material of the textile substrate is, or at least comprises, an aromatic, nitrogen-containing polymer from a group of polyoxadiazoles (POD); wherein the textile substrate is manufactured from a woven fabric having a yarn that comprises the at least one polymer plastic material.
2. The adhesive tape according to claim 1, wherein the at least one polymer plastic material of the textile substrate further comprises an aromatic, nitrogen-containing polymer from a group of polybenzobisoxazoles (PBO), polybenzimidazoles (PBI), or a combination thereof either as a mixture with the polyoxadiazoles (POD) or formed as a copolymer therewith.
3. The adhesive tape according to claim 2 further comprising in that the proportion of polyoxadiazole (POD), polybenzobisoxazole (PBO), polybenzimidazole (PBI), or the copolymer formed therewith inside the textile substrate falls in the range from 50 to 100 mass percent.
4. The adhesive tape according to claim 2, wherein the polybenzobisoxazoles (PBO) is in the form of poly(p-phenylen-2,6-benzobisoxazole) or the polyoxadiazoles (POD) is in the form of poly-1,4-phenylen-1,3,4-oxadiazole.
5. The adhesive tape according to claim 1, wherein the yarn contains fibers of a further textile or non-textile material, or that the fabric of the textile substrate contains yarns of a further textile or non-textile material.
6. The adhesive tape according to claim 5, wherein the fibers or yarns of the further textile material are comprised of one or more of a synthetic polymer, a natural polymer, a polyamide (PA), a polyester (PES), a special polyethylene terephthalate (PET), poly(p-phenylene terephtalamide) (PPTA), poly(m-phenylene terephthalamide) (PMPI), rayon, polyvinyl alcohol (PVAL), polyvinyl acetate (PVAC), polyether-etherketone (PEEK), polyphenylene (PPP), polyphenylene oxide (PPO), polyphenylene sulfide (PPS), and/or polyphenylene ether (PPE).
7. The adhesive tape according to claim 5, wherein the fibers of the further, non-textile material are metal fibers, carbon fibers, glass fibers, or basalt fibers.
8. The adhesive tape according to claim 1 further comprising in that the at least one polymer plastic material of the textile substrate has a yellow, orange, or black color.
9. The adhesive tape according to claim 1 further comprising in that the textile substrate at least sectionally has a color according to RAL corresponding to a number code 2000 yellow-orange, 2001 red-orange, 2002 blood-orange, 2003 pastel orange, 2004 pure orange, 2005 light orange, 2007 light-bright orange, 2008 bright-red orange, 2009 traffic orange, 2010 signal orange, 2011 deep orange, 2012 salmon orange, or 2013 pearl orange.
10. The adhesive tape according to claim 1 further comprising in that the at least one polymer plastic material of the textile substrate contains additional stabilizers for increasing UV resistance.
11. The adhesive tape according to claim 1 further comprising in that the textile substrate is free of colorants.
12. The adhesive tape according to claim 1, further comprising in that the textile substrate contains a colorant composed of a dye, a pigment, or carbon black.
13. The adhesive tape according to claim 1 further comprising in that the at least one polymer plastic material of the substrate contains auxochromic functional groups having the chemical formulas —OH, —NH.sub.2, —NHR, —NR.sub.2, or —OR with R as an aliphatic or aromatic group, such that a bathochromic shift occurs.
14. The adhesive tape according to claim 1 further comprising in that the textile substrate is composed of a copolymerisate of poly-1,4-phenylen-1,3,4-oxadiazole with poly-4,4′-azobenzole-1,3,4-oxadiazole or poly-3,3′-azobenzole-1,3,4-oxadiazole, wherein the proportion of the poly-4,4′-azobenzole-1,3,4-oxadiazole or of the poly-3,3′-azobenzole-1,3,4-oxadiazole, based on the mass of the poly-1,4-phenylen-1,3,4-oxadiazole, falls in the range from 0.5-5 mass percent.
15. The adhesive tape according to claim 1, wherein the woven fabric of the textile substrate comprises warp threads having a warp-thread count and weft threads having a weft-thread count, wherein the warp-thread count and weft-thread count of the woven fabric is each greater than 20 per cm, and wherein an upper limit of the warp-thread count and weft-thread count of the woven fabric each fall at 80 per cm.
16. The adhesive tape according to claim 1, wherein the textile substrate comprises the woven fabric having a warp and weft yarn weight that is less than 600 dtex.
17. The adhesive tape according to claim 1, wherein the textile substrate comprises the woven fabric having a width-related warp yarn weight that falls in the range from 6000 dtex/cm to 25000 dtex/cm.
18. The adhesive tape according to claim 1, wherein the textile substrate comprises the woven fabric having a length-related weft yarn weight that falls in the range from 4000 dtex/cm to 17000 dtex/cm.
19. The adhesive tape according to claim 1 further comprising in that the adhesive layer comprises a pressure-sensitive self-adhering adhesive, the pressure-sensitive self-adhering adhesive being a silicone adhesive, an acrylate adhesive, or a rubber-based adhesive.
20. The adhesive tape according to claim 1 further comprising in that the adhesive layer has a specific surface mass in the range from 60 g/m.sup.2 to 200 g/m.sup.2.
21. The adhesive tape according to claim 1 further comprising in that the adhesive tape has a thickness in the range from 0.15 mm to 1.50 mm according to the standard EN 1942.
22. The adhesive tape according to claim 1 further comprising in that the adhesive tape has an elongation at break in the range of 20% to 50%, according to the standard EN 14410.
23. The adhesive tape according to claim 1 further comprising in that the adhesive tape has a breaking force in the range of 100 N/cm to 600 N/cm, according to the standard EN 14410.
24. The adhesive tape according to claim 1 further comprising in that the adhesive tape has an adhesive force on steel in the range of 2.0 N/cm to 6.0 N/cm, according to the standard DIN EN 1939.
25. The adhesive tape according to claim 1 further comprising in that the adhesive tape has an adhesive force on a tape back in the range of 1.5 N/cm to 5.0 N/cm according to the standard DIN EN 1939.
26. The adhesive tape according to claim 1 further comprising in that the adhesive tape has a noise damping of at least class B according to the standard LV 312.
27. The adhesive tape according to claim 1 further comprising in that the adhesive tape has an abrasion resistance of at least class B according to the standard LV 312.
28. The adhesive tape according to claim 1, wherein the substrate or the adhesive layer comprises a plurality of layers connected to one another.
29. The adhesive tape according to claim 1 further comprising the adhesive tape having a temperature resistance at least of class T4 according to LV 312.
30. The adhesive tape according to claim 1 further comprising the adhesive tape having a flame resistance of at least class B, according to LV 312.
31. A cable harness, comprising the adhesive tape according to claim 1 and a line set comprised of a plurality of strands, which line set is wound by the adhesive tape, wherein the plurality of strands include a casing comprised of a plastic.
32. The cable harness according to claim 31, wherein the casing of the plurality of strands is comprised of a halogen-containing plastic, or of a halogen-free plastic.
33. The cable harness according to claim 31 characterized by the cable harness having a temperature resistance at least of class T4, according to LV 312.
34. The cable harness according to claim 31 characterized by the cable harness having a flame resistance at least of class B, according to LV 312.
35. The cable harness according to claim 31 further comprising in that the adhesive tape or the textile substrate forms a cuff or a clip with an interior around the line set comprised of the plurality of strands.
36. A method of manufacturing a colored adhesive tape for use as a cable-wrapping tape, having a temperature class of at least T3 according to LV 312, wherein the method comprises: manufacturing a textile substrate from a woven fabric having a yarn that comprises at least one polymer plastic material, wherein the at least one polymer plastic material is, or at least comprises, an aromatic, nitrogen-containing polymer from the group of polyoxadiazoles (POD); and applying an adhesive layer on at least one side of the textile substrate.
37. The method according to claim 36, wherein the at least one polymer plastic material is comprised exclusively of polyoxadiazoles (POD), a copolymer of polyoxadiazoles (POD) with polybenzobisoxazoles (PBO) or polybenzimidazoles (PBI), or a mixture of polyoxadiazoles (POD) with polybenzobisoxazoles (PBO) or polybenzimidazoles (PBI).
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The invention shall be explained in more detail based on the exemplary embodiments depicted in the drawings.
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(14) In the various Figures of the drawings identical parts are always provided with the same reference numbers, so that they are each generally described only once.
DETAILED DESCRIPTION
(15) For the subsequent description it is emphasized that the invention is not limited to the exemplary embodiment and not to one or more features here of described feature combinations, rather each individual feature of the exemplary embodiment, even detached from all others in the context of partial features described therewith, is in itself of meaning for the object of the invention. Thus, for example, the features of the adhesive-tape properties listed in Tables 4 and 5 below are not necessarily associated with one another.
(16) In particular the use of an inventive textile substrate whose polymer plastic material is an aromatic, nitrogen-containing polymer preferably from the group of polyoxadiaxoles (POD) or also from the group of polybenzobisoxazoles (PBO) or of polybenzimidazoles (PBI), in particular of the inventive adhesive tape, is also attributed an independent inventive meaning.
(17) As
(18) The inventive adhesive tape 1 here comprises a band-shaped textile colored substrate 4 and an adhesive layer 5 applied one-side on the substrate 4, preferably comprised of a pressure-sensitive adhesive. The textile substrate 4 comprises at least one polymer plastic material, wherein the color of the substrate 4 is formed preferably completely, but at least but portions thereof, by the inherent color of the polymer plastic material.
(19) The inventive adhesive tape 1 combines a high abrasion resistance, such as is known from cable winding tapes manufactured on the basis of polyester woven fabrics, with an increased temperature and flame resistance, wherein the adhesive tape 1 is preferably embodied in the colors yellow, orange, or black, and the polymer plastic material of the substrate 4 is a textile, in particular a woven fabric based on an aromatic, nitrogen-containing polymer from the group of polybenzobisoxazoles (PBO), the polybenzimidazoles (PBI), or the polyoxadiaxoles (POD).
(20) As an example for polybenzobisoxazoles (PBO) a general structural formula of poly (2,6-benzobisoxazole) is depicted in
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(22) Finally
(23) However, in the context of the inventive use of in particular colorless or also colored polyoxadiazoles (POD) it can optionally be provided that a coloring or color change using dyes or pigments occurs. Thus, for example, colorless or also orange colored POD fibers or POD woven fabrics can be colored as needed with black dyes or pigments, such as, for example, carbon black, without the advantageous high temperature stability, flame resistance, and abrasion resistance thereby being lost. A dispersion or spinning-jet-coloring with color pigments can occur. If dye is used as colorant then depending on the solubility properties of the dye the coloring can take place in an aqueous solvent or in an organic solvent, such as an alcohol, ketone, or oil, or in suitable mixtures. Basic or acidic solutions can be used. Furthermore, coloring accelerants, so-called carriers, can optionally be used together with surfactants, which carriers cause a swelling of the fiber material and can thereby facilitate the diffusion of the dyes. Aromatic compounds, such as, for example, phenol, phenylphenol, salicylic acid, including their derivatives or xylols, come into consideration as such coloring accelerants. However, it is to be noted that the aromatic, nitrogen containing polymers from the group of the polyxoadiazoles (POD), the polybenzobisoxazoles (PBO) or the polybenzimidazoles (PBI) represent material groups that are difficult to dye. However a carrier can advantageously be used here that contains N-cyclohexyl-2-pyrrolidone. Here a mixture of N-cyclohexyl-2-pyrrolidone with an alkyl- or aryl-benzoate, in particular with methyl benzoate, is preferred, wherein the mixture can be used as a solution or suspension. A preferred mass ratio of N-cyclohexyl-2-pyrrolidone to the alkyl- or aryl-benzoate here can fall in the range from 2:3 to 8:1.
(24) Table 4 gives an overview of the woven fabrics usable as polymer plastic materials of the substrate 4 for the manufacture of inventive adhesive tapes 1 and the properties of these woven fabrics.
(25) It can be seen from table 4 that the thread counts of the warp of a preferred fabric for the substrate 4 can vary in the range from 8 per cm to 42 per cm. The thread counts of the weft can vary in the range from 6 per cm to 30 per cm. The yarn strength of the warp as well as of the weft can preferably each fall in the range from 250 dtex to 2800 dtex.
(26) TABLE-US-00004 TABLE 4 Fabric structure and fiber description Fabric 1 Fabric 2 Fabric 3 Fabric 3 Fabric 4 Fabric 5 Fabric PBO POD POD POD POD POD (Zylon) (Arselon (Arselon (Arselon (Arselon (Arselon S) S) S) S) Color honey orange orange orange yellow orange yellow Weave — plain plain plain plain twill 2/1 twill 2/1 weave weave weave weave Yarn type — filament filament filament filament staple filament fiber Warp- 1/cm 8 8 22 39 26 42 thread count Weft-thread 1/cm 6 15 16 22 24 30 count Yarn weight dtex 2800 2000 294 294 385 294 warp Yarn weight dtex 2800 1000 294 294 385 294 weft Filament count 1800 1000 200 200 200 200 count warp Filament count 1800 1000 200 200 200 200 count weft Width- dtex/cm 22400 16000 6488 11466 10010 12348 realted warp thread weight Length- dtex/cm 16800 15000 4704 6468 9240 8820 related warp thread weight Surface EN g/m.sup.2 430 310 166 200 212 225 weight 2288 Thickness EN mm 0.45-0.48 0.62 0.25 0.28-0.29 0.29-0.30 0.29-0.30 1942 Elongation EN % 15-30 11-18 19-20 22-23 22-23 24-27 at break 14410 Breaking EN N/cm 1000-2000 570-640 400-480 350-500 235-238 400-500 force 14410 Air ISO l/m.sup.2s 16-17 95-100 35-40 8-11 230-280 220-290 permeability 9237 Abrasion LV 312 B B B B/C B/C D class with adhesive Use known fabrics Example Example 1 2 + 3 *deviating from ISO 9237 a differential pressure of 500 Pa was used
(27) In the yarns of the substrate 4 the fibers are preferably predominantly processed into filament yarns in an advantageous manner. Such woven fabrics made from filament yarns have a higher abrasion resistance than woven fabrics with yarns made from staple fiber yarns. The dense weave with a twill weave or plain weave is advantageous here.
(28) As table 4 also shows the filament counts of a filament yarn can also preferably fall in the range from 200 to 1800 per cm. The fiber fineness of the filaments here can preferably fall in a range from 2 dtex to 3 dtex. This applies; independent from each other, both for the warp and for the weft.
(29) The width-related warp-yarn strength can advantageously fall in the range from 6000 dtex/cm to 25000 dtex/cm. The length-related weft-yarn strength can advantageously fall in the range from 4000 dtex/cm to 17000 dtex/cm. The specific surface-based mass (“grammage”) can fall in the range from 200 g/m.sup.2 to 450 g/m.sup.2. The thickness can fall in the range from 0.20 mm to 0.65 mm, preferably in the range from 0.25 mm to 0.30 mm.
(30) Silicone adhesive, as already mentioned, is particularly suited as temperature-resistant pressure-sensitive adhesive for the adhesive layer 5. Surprisingly, however, it is also possible to achieve good results with adhesives based on polyacrylates or synthetic rubber. To be sure with extreme temperature load a hardening of the adhesive mass results; however, the helical protective wrapping applied with overlap around the strands 2 of the cable set 3 endures due to the good adhesion on the tape pack in the bending test prescribed according to the aging test according to LV 312. In principle the use of solvent acrylates or even the use of acrylate-monomer mixtures or acrylate-prepolymers is also possible. After the coating these are optionally polymerized and cross linked either thermally or using UV radiation.
(31) The adhesive layer 5 can have an application weight (specific surface mass) in the range from 60 g/m.sup.2 to 200 g/m.sup.2, preferably an application weight in the range from 90 g/m.sup.2 to 150 g/m.sup.2, particularly preferably to 100 g/m.sup.2.
(32) TABLE-US-00005 TABLE 5 Adhesive tape overview Example Example Example Example Example Comparison Comparison Unit Standard 1 2 3 4 5 1 2 Fabric — — POD POD POD PBO POD PET Glass material Substrate 1/cm — 26 42 42 8 8 45 47 construction warp thread count Substrate 1/cm — 24 30 30 6 15 25 21 construction weft thread count Yarn type staple filament filament filament filament filament E glass warp/weft fiber yarn yarn yarn yarn yarn yarn Substrate g/m.sup.2 EN ISO 212 225 225 430 310 130 130 weight 2286-2 Adhesive — — acrylate silicone acrylate acrylate acrylate acrylate silicone Adhesive g/m.sup.2 EN ISO 100 100 100 150 150 90 150 application 2286-2 Thickness mm DIN EN 0.30-0.31 0.30-0.32 0.30-0.32 0.50-0.52 0.60-0.65 0.24-0.25 0.15-0.16 1942 Elongation % DIN EN 25-30 30-35 28-35 20-40 10-20 36-44 7.5-8.0 at break 14410 Breaking N/cm DIN EN 250-270 450-500 450-480 1500-2500 570-640 241-285 280-330 force 14410 Adhesive N/cm DIN EN 2.0-2.5 2.0-3.5 2.5-3.5 2.5-4.0 2.4-3.8 4.0-6.5 2.3-3.5 strength on 1939 steel Adhesive N/cm DIN EN 2.0-2.5 2.5-3.0 2.0-3.0 2.0-3.0 3.0-3.5 7.0-9.5 2.0-3.5 strength on 1939 tape backs Unrolling N DIN EN 2-9 2-9 2-9 2-9 2-9 3-7 2-8 force 1944 Fire — LV 312 A A A A A B A resistance Noise — LV 312 B B B B B A A damping class Abrasion — LV 312 B/C D D B B D A/B class Temperature — LV 312 E E E E E D E class
(33) Table 5 lists various inventive adhesive tapes 1 including their properties in comparison to existing adhesive tapes. The inventive adhesive tapes 1 embodied in this table are the following:
(34) Example 1: Substrate 4 made from staple fiber woven fabric made from a copolymer made from poly-1,4-phenylene-1,3,4-oxadiazole and poly-4,4′-azobenzole-1,3,4-oxadiazole (orange-colored) according to
(35) Example 2: Substrate 4 made from filament fiber woven fabric made from a copolymer made from poly-1,4-phenylene-1,3,4-oxadiazole and poly-4,4′-azobenzole-1,3,4-oxadiazole (orange-colored) according to
(36) Example 3: Substrate 4 made from filament fiber woven fabric made from a copolymer made from poly-1,4-phenylene-1,3,4-oxadiazole and poly-4,4′-azobenzole-1,3,4-oxadiazole (orange-colored) according to
(37) The two further examples 4 and 5 of the table relate to inventive adhesive tapes 1 including substrates 4 made from typical known orange-colored woven fabrics ZYLON (Example 4) and ARSELON S (Example 5). These examples 4 and 5 show which values can be achieved with the use of common PBO/POD woven fabrics having coarse weave.
(38) Comparison example 1: substrate 4 made from filament fiber woven fabric made from polyethylene terephthalate (PET) with UV acrylate adhesive in the adhesive layer 5.
(39) Comparison example 2: substrate 4 made from filament fiber woven fabric made from glass fibers with silicone adhesive in the adhesive layer 5.
(40) Inventive adhesive tapes 1 can thus advantageously combine the following properties:
(41) High temperature resistance: >175° C. (class T5 or E according to LV 312), Best flame resistance: class A according to LV 312/ISO 3795.
(42) Good abrasion resistance, in particular class C or D according to LV 312/ISO 6722.
(43) With respect to a comparison with the temperature classes achieved according to the prior art it is noteworthy in particular here that the temperature class T5, not just T3 as according to EP 2 546 317 B1, could advantageously be inventively achieved, and in fact while avoiding the use of health-hazardous anthraquinone. Here the limitation to the continuous use temperature of 175° C. is due to the fact that the relevant standard LV 312 currently lists this as the highest temperature class. In an analogous text with high-temperature-resistant silicone-jacketed lines, resistances with a continuous use temperature of 225° C. could also be seen with example 2.
(44) The line set comprised of a plurality of strands 2 is wrapped with the inventive adhesive tape 1, wherein the strands 2 can include a casing comprised of polyvinyl chloride (PVC), which in
(45) The invention is not limited to the depicted and described exemplary embodiments, but rather also includes all functionally identical embodiments in the sense of the invention. This applies, for example, to the application weight of the adhesive layer 5, which can vary in wide ranges, but also for other parameters that are adaptable in wide ranges to the respective application case; independent of the color of the inventive adhesive tape 1 and the type of the woven fabric of its substrate 4.
(46) In addition to those already mentioned, in particular for the substrate 4, the following parameter ranges appear as particularly advantageous for the widest application range of an inventive adhesive tape 1:
(47) a thickness in the range from 0.15 mm to 1.50 mm, preferably from 0.20 mm to 0.60 mm, according to the standard EN 1942,
(48) an elongation at break in the range of 20% to 50%, preferably from 25% to 35%, according to the standard EN 14410,
(49) a breaking force in the range from 100 N/cm to 600 N/cm, preferably in the range from 250 N/cm to 500 N/cm, according to the standard EN 14410,
(50) an adhesive force on steel in the range from 2.0 N/cm to 6.0 N/cm, preferably in the range from 2.5 N/cm to 3.5 N/cm, according to the standard DIN EN 1939,
(51) an adhesive force on a tape back in the range from 1.5 N/cm to 5.0 N/cm, preferably in the range from 2.0 N/cm to 3.0 N/cm, according to the standard DIN EN 1939,
(52) a noise damping of at least class B according to the standard LV 312,
(53) an abrasion resistance at least of class B, preferably of class C or D, according to the standard LV 312.
(54) In the depiction shown in
(55) The two further embodiments of the invention shown in
(56) In the embodiment depicted in
(57) it is expressly noted that the exemplary embodiments are not limited to all features in combination, rather each individual feature can also have an inventive meaning in itself separate from all other partial features.
(58) Thus a similar depiction of an adhesive tape 1 as in
(59) For example, in the embodiment according to
(60) Furthermore the invention is also thus far not limited to the feature combinations in claim 1 and in the other independent claims, but can also be defined by any other desired combination of specific features of all individual features disclosed overall. This means that in principle practically any individual feature of claim 1 and of the other independent claims can be omitted or replaced by at least one individual feature disposed at another point in the application.
(61) While the above description constitutes the preferred embodiment of the present invention, it will be appreciated that the invention is susceptible to modification, variation and change without departing from the proper scope and fair meaning of the accompanying claims.