Color laser marking of security document and a method for producing such security document
11084315 · 2021-08-10
Assignee
Inventors
Cpc classification
B42D25/45
PERFORMING OPERATIONS; TRANSPORTING
B42D25/382
PERFORMING OPERATIONS; TRANSPORTING
B42D25/387
PERFORMING OPERATIONS; TRANSPORTING
B42D25/41
PERFORMING OPERATIONS; TRANSPORTING
International classification
B42D25/41
PERFORMING OPERATIONS; TRANSPORTING
B42D25/45
PERFORMING OPERATIONS; TRANSPORTING
B42D25/351
PERFORMING OPERATIONS; TRANSPORTING
B42D25/382
PERFORMING OPERATIONS; TRANSPORTING
B42D25/387
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The present invention relates generally to a data carrier and a method for making the data carrier. More particularly, this invention relates to color laser marking of article, especially security documents. The present invention proposes a security document comprising a multilayers assembly instead of a single color component mixture in a layer. The multilayer assembly comprises at least two laser sensitive layer. Each layer comprises at least one coloring agent component. The order arrangement of the multilayers of bleachable coloring agent component is made so that each layer behaves as a wavelength filter configured to selectively transmit longer wavelengths and block or attenuate shorter wavelengths while protecting the underneath coloring agent component from bleaching interference.
Claims
1. A multilayer assembly, said multilayer assembly comprising: at least a first layer and a second layer, wherein one of said first and second layer is arranged to be located above the other of said first and second layers, wherein the layers are arranged so that: the first layer has a first color-forming component of a first concentration and acts as an absorptive optical filter configured to selectively transmit the light of a first range of wavelengths and block or attenuate the light outside the first range of wavelengths, the second layer has a second color-forming component of a second concentration and acts as an absorptive optical filter configured to selectively transmit the light of a second range of wavelengths and block or attenuate the light outside the second range of wavelengths, a sensitive layer above the upper layer of the first layer and the second layer, said sensitive layer comprising a color component mixture of at least the first and second color-forming components in a concentration lower than the first and second concentration of the color-forming components in the first and second layers of the multilayer assembly, respectively, and that during the irradiation of a selected color-forming component by a selected laser wavelength, an untargeted radiation exposure of the color forming component underneath the selected color-forming component is avoided or at least minimized.
2. The multilayer assembly according to claim 1 wherein, arrangement of the layers is determined according to two parameters: an absorption coefficient of each color-forming component of the layers at a given wavelength, an effective laser reactivity of each color-forming component of the layers, said effective laser reactivity corresponding to the minimum energy input of the given wavelength required to achieve a targeted color change of the color-forming component.
3. The multilayer assembly according to claim 2 wherein, the layers are arranged so that: according to the coefficient of absorption of each color-forming component, each layer acts as a longpass filter wherein laser irradiation of longer wavelength is transmitted whereas laser irradiation of shorter wavelength is blocked or attenuated, and according to the effective laser reactivity of each color-forming component, each layer allows to minimize the untargeted radiation exposure of the underneath color-forming components.
4. The multilayer assembly according to claim 3 wherein, the color component is a chromatic color which pass from one chromatic color to a different chromatic color when exposed to a given wavelength, or a bleachable color component which is bleached under given wavelength.
5. The multilayer assembly according to claim 1, wherein the layers are separated by a layer transparent to laser irradiation.
6. The multilayer assembly according to claim 1, wherein the color-forming component is color component or dye or “latent pigment”.
7. The multilayer assembly according to claim 6, wherein: the first layer is arranged above the second layer and wherein the first color-forming component is a bleachable color-forming component yellow which is able to block or attenuate blue-light wavelength band, while other color wavelengths pass through, a second layer arranged below the first layer and wherein the second color-forming component is a bleachable color-forming component cyan, said second layer being able to block or attenuate red-light wavelength band while other wavelengths pass through, a third layer arranged below the second layer with a third color-forming component being a bleachable color-forming component magenta, said third layer being able to block or attenuate green-light wavelength band while other color wavelengths pass through.
8. The multilayer assembly according to claim 1, wherein the multilayer assembly is covered by a lamination layer transparent to the laser wavelengths.
9. A multilayered security document comprising: a body support over which is arranged a multilayer assembly, said multilayer assembly having at least a first layer and a second layer, wherein one of said first and second layer is arranged to be located above the other of said first and second layers, wherein the layers are arranged so that: the first layer has a first color-forming component of a first concentration and acts as an absorptive optical filter configured to selectively transmit the light of a first range of wavelengths and block or attenuate the light outside the first range of wavelengths, the second layer has a second color-forming component of a second concentration and acts as an absorptive optical filter configured to selectively transmit the light of a second range of wavelengths and block or attenuate the light outside the second range of wavelengths, a sensitive layer is above the upper layer of the first layer and the second layer, said sensitive layer comprising a color component mixture of at least the first and second color-forming components in a concentration lower than the first and second concentration of the color-forming components in the first and second layers of the multilayer assembly, respectively, and that during the irradiation of a selected color-forming component by a selected laser wavelength, an untargeted radiation exposure of the color forming component underneath the selected color-forming component is avoided or at least minimized.
10. A multilayered security document according to claim 9, wherein the body support comprises an opaque white core support, a white opacifying layer coated onto a transparent polymeric support, a colored core support or a transparent core support.
11. The multilayered security document according to claim 9, wherein the security document comprises an infrared laser markable layer for generating different optical densities of grey to black, said infrared laser markable layer being arranged between the multilayer assembly and the body support.
12. The multilayered security document according to claim 9, wherein the security document comprises one or more other security features arranged on a layer between the body support and the multilayer assembly or over the multilayer assembly.
13. The multilayered security document according to claim 9, wherein the multilayers of the security document are laminated on the body support of the security document.
14. The multilayered security document according to claim 9, wherein the security document is a physical media selected from the group contacted smart cards, contactless smart cards, driver's licenses, passports, government-issued identity cards, bankcards, employee identification cards, security documents, personal value papers such as registrations, proofs of ownership, visas, immigration documentation, security badges, certificates, voter registration cards, police ID cards or border crossing cards.
15. A method of color laser marking of a multilayered security document having a multilayer assembly, said multilayer assembly comprising at least two layers, each layer comprises at least one color-forming component, a color marking is produced on the multilayer assembly of the security document, the method comprising: arranging at least a first layer and a second layer, wherein one of said first and second layer is arranged to be located above the other of said first and second layers, wherein the layers are arranged so that: the first layer has a first color-forming component of a first concentration and acts as an absorptive optical filter configured to selectively transmit the light of a first range of wavelengths and block or attenuate the light outside the first range of wavelengths, the second layer has a second color-forming component of a second concentration and acts as an absorptive optical filter configured to selectively transmit the light of a second range of wavelengths and block or attenuate the light outside the second range of wavelengths, wherein a sensitive layer is added over the upper layer of the first layer and the second layer, said sensitive layer comprising a color component mixture of at least the first and second color-forming components in the first and second layers of the multilayer assembly in a concentration lower than the first and second concentration of the color-forming components in the first and second layers of the multilayer assembly, respectively, and that during the irradiation of a selected color-forming component by a selected laser wavelength, an untargeted radiation exposure of the color forming component underneath the selected color-forming component is avoided or at least minimized; and selectively transforming the color-forming components of the layers by irradiation at selected laser wavelengths.
16. The method of color laser marking of a multilayered security document of claim 15, further comprising: determining arrangement of the layers according to two parameters: an absorption coefficient of each color-forming component of the layers at a given wavelength, an effective laser reactivity of each color-forming component of the layers, said effective laser reactivity corresponding to the minimum energy input of the given wavelength required to achieve a targeted color change of the color-forming component.
17. The method of color laser marking of a multilayered security document of claim 16, comprising: arranging the layers so that: according to the coefficient of absorption of each color-forming component, each layer acts as a longpass filter wherein laser irradiation of longer wavelength is transmitted whereas laser irradiation of shorter wavelength is blocked or attenuated, and according to the effective laser reactivity of each color-forming component, each layer allows to minimize the untargeted radiation exposure of the underneath color-forming components.
18. The method of color laser marking of a multilayered security document of claim 17 wherein, the color component is a chromatic color which pass from one chromatic color to a different chromatic color when exposed to a given wavelength, or a bleachable color component which is bleached under given wavelength.
19. The method of color laser marking of a multilayered security document of claim 15, comprising separating the layers by a layer transparent to laser irradiation.
20. The method of color laser marking of a multilayered security document of claim 15, wherein the color-forming component is color component or dye or “latent pigment”.
21. The method of color laser marking of a multilayered security document of claim 20, wherein: the first layer is arranged above the second layer and wherein the first color-forming component is a bleachable color-forming component yellow which is able to block or attenuate blue-light wavelength band, while other color wavelengths pass through, the second layer arranged below the first layer and wherein the second color-forming component is a bleachable color-forming component cyan, said second layer being able to block or attenuate red-light wavelength band while other wavelengths pass through, a third layer arranged below the second layer with a third color-forming component being a bleachable color-forming component magenta, said third layer being able to block or attenuate green-light wavelength band while other color wavelengths pass through.
22. The method of color laser marking of a multilayered security document of claim 15, further comprising: covering the multilayer assembly with a lamination layer transparent to the laser wavelengths.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The following detailed description will be better understood with the drawings, in which:
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DETAILED DESCRIPTION OF THE EMBODIMENTS OF THE INVENTION
(10) In order to overcome the problems described above, preferred embodiments of the present invention provide a simple and cost-effective method of color laser marking articles as described herein.
(11) It is a further object of the present invention to provide security documents having an improved image quality and which are more difficult to falsify.
(12) Further advantages and embodiments of the present invention will become apparent from the following description.
(13) It is to be understood that various other embodiments and variations of the invention may be produced without departing from the scope of the invention. The following is provided to assist in understanding the practical implementation of particular embodiments of the invention.
(14) The same elements have been designated with the same referenced numerals in the different drawings. For clarity, only those elements which are useful to the understanding of the present invention have been shown in the drawings and will be described.
(15) Reference throughout the specification to “an embodiment” or “another embodiment” means that a particular feature, structure, or characteristic described in connection with an embodiment is included in at least one embodiment of the subject matter disclosed. Thus, the appearance of the phrases “in an embodiment” or “in another embodiment” in various places throughout the specification is not necessarily referring to the same embodiment. Further, the particular features, structures or characteristics may be combined in any suitable manner in one or more embodiments.
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(17) An embodiment of the present invention provides a mechanism by which physical media such as identification cards, bank cards, smart cards, passports, value papers, etc. may be personalized in a post-manufacturing environment. This technology may be used to place images onto such articles inside a lamination layer after the lamination layer has been applied.
(18) Herein, with the purpose of providing a clear narrative, the term security document is used to refer to the entire class of physical media to which the herein-described techniques may be applied even if some such physical media are not “cards” in a strict sense. Without limiting the application of the term security document, it is intended to include all such alternatives including but not limited to smart cards (both contact and contactless smart cards), driver's licenses, passports, government issued identity cards, bankcards, employee identification cards, security documents, personal value papers such as registrations, proofs of ownership, visas, immigration documentation, security badges, certificates, voter registration cards, police ID cards, border crossing cards, etc.
(19) The security document carries certain items of personalized information which relate to the identity of the bearer. Examples of such personalized information include name, address, birth date, signature and photographic image; the security document may in addition carry other variable data (i.e., data specific to a particular card or document, for example an employee number) and invariant data (i.e., data common to a large number of cards, for example the name of an employer).
(20) The security document 10 illustrated in
(21) The structure of the security document 10 is described in detail hereinafter with reference to the Figures, and also the laser treatment with which it is possible to produce a laser-induced image component in the form of a full-color image.
(22) The security document 10 comprises a laminated structure comprising various papers or plastic laminates and layers in which a plurality of different color markings can be specifically produced by way of laser treatment, and preferably markings of all desired colors can be produced in the manner of a full-color image.
(23) In an embodiment, the security document comprises a body 21. The body 21 can comprise an opaque white core support. The advantage of an opaque white core support is that any personalized information present on the security document 10 is more easily readable and that a color image is more appealing by having a white background.
(24) In an embodiment, the opaque white core support can comprise coated paper supports, such as polyethylene coated paper, polypropylene coated paper; synthetic paper supports, polymeric supports such as opaque white polyesters, . . . .
(25) In another embodiment, instead of an opaque white core support, a white opacifying layer can be coated onto a transparent polymeric support to form the body 21 of the security document. The opacifying layer may comprise a white pigment. The white pigments may be employed singly or in combination.
(26) In an embodiment, the body 21 can comprise a colored core support. In an embodiment, the body 21 can comprise a transparent core support.
(27) In an embodiment, the security document 10 comprises a multilayer assembly 20 arranged on the body 21 of the security document 10. The multilayer assembly 20 comprises at least two layers 20a, 20b, 20c.
(28) As non-limiting examples, the layers 20a, 20b, 20c of the multilayer assembly 20 may be based on such materials as polycarbonates, polyacrylates, certain treated polyvinyl chlorides (PVCs), treated acrylonitrile-butadiene-styrenes (ABSs), or polyethylene terephthalates (PETs), polysiloxanes, epoxy resins, as well as or copolymers or blends thereof. The layers 20a, 20b, 20c may comprise any other suitable plastic material with an incorporated color component compound which can react with laser light to produce desirable markings.
(29) In an embodiment as illustrated in
(30) one related to an absorption coefficient. The absorption coefficient characterizes which part of the incident light has been absorbed and not reflected/refracted/transmitted by a unit thickness of the target medium. It can be considered as constant at a given wavelength
(31) the second related to an effective laser reactivity corresponding to the lowest energy level of the defined laser at the specified wavelength needed by the color-forming component to detect said wavelength. The second one is more system-dependent
(32) The color-forming component can be a chromatic color which can be responsive to a particular wavelength by for example changing its color from one chromatic color to a different chromatic color.
(33) The color-forming components in the illustrated implementation are a ‘bleachable color-forming components’. The bleachable color component is one colorant from, for example, pigments or eventually dyes or “latent pigments”. In an embodiment, the bleachable color component is one color component from, for example, the three primary colors of the subtractive color mixture consisting of yellow, magenta and cyan, or any other chromatic color such as red, green, blue, orange, purple, etc.
(34) In an embodiment illustrated in
(35) It should be noted that there may be at least one layer transparent to the laser beam arranged between the layers. The transparent layer can comprise fillers. The fillers can be unrelated to colorants, bleachable colorants or chromatic colors. The transparent layer can be arranged on either side of the multilayer assembly 20. The material of such layer, their number and their order depend on the implementation.
(36) In an embodiment as illustrated in
(37) According to an implementation of the present invention, the security document 10 can comprise a multilayer assembly 20 without a lamination layer 22 covering the layers 20a, 20b and 20c.
(38) It should be noted that there may be multiple layers between the body 21 of the security document 10 and the multilayer assembly 20. There should be noted that there may be multiple layers over the multilayer assembly 20 The material of such layers and their order depend on the implementation.
(39) In the embodiment illustrated at
(40) In an embodiment illustrated in
(41) During personalization, the laser beam carbonizes the infrared laser markable layer 23 in its bulk volume, thereby forming non-reflective black volumes so as to form the gray levels of the personalized image. The energy delivered by the laser is adjusted so as to produce all of the shades of gray required to enhance the formation of an attractive and contrasted color laser image.
(42) In an embodiment, the infrared laser markable layer 23 could be from the multilayer assembly 20 by another layer 24. The layer 24 is transparent to the infrared laser beam used to produce the final personalized image in the infrared laser markable layer 23.
(43) The assembly of the multilayers of the security document 10 is bonded under pressure on the core assembly of the security document 10. This bonding operation is known as “lamination” by the person skilled in the art. In other words, the multilayer are laminated on the body 21 of the security document 10.
(44) In an embodiment, the multilayer of the security document 10 is preferably combined with one or more other security features to increase the difficulty for falsifying the document.
(45) To prevent forgeries, different means of securing can be used. One solution can consist in superimposing lines or guilloches on an identification picture such as a photograph. In that way, if any material is printed subsequently, the guilloches appear in white on added black background. Other solutions can consist in adding security elements such as information printed with ink that reacts to ultraviolet radiation, micro-letters concealed in an image or text etc.
(46) Suitable other known security features, such as anti-copy patterns, guilloches, endless text, miniprint, microprint, nanoprint, rainbow coloring, 1D-barcode, 2D-barcode, colored fibres, fluorescent fibres, fluorescent pigments, OVD and DOVID such as holograms, 2D and 3D holograms, relief embossing, perforations, metallic pigments, magnetic material, images made with OVI (Optically Variable Ink) such as iridescent and photochromic ink, images made with thermochromics ink, phosphorescent pigments and dyes, watermarks including duotone and multitone watermarks, ghost images and security threads, can be added to the multilayer of the security document 10.
(47) In the example illustrated in
(48) In another implementation, the security feature can be arranged over the multilayer assembly 20.
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(50) The multilayer assembly 20, according to the present invention, comprises at least two separate layers 20a, 20b, 20c, but preferably can comprise three or more separate layers. The separate layers of the multilayer assembly 20 are positioned over the opaque white core support of the body 21 for producing a multicolored security document 10.
(51) In an embodiment as illustrated in
(52) At least one color-forming component is transferred into each of the layer 20a, 20b, 20c of the multilayer assembly 20 according to any known color transfer technique.
(53) The order layout of the layers of the multilayer assembly 20 is determined according to the recorded absorption spectra/absorption coefficients and the effective laser reactivity of each of the color-forming components of each layer. The order layout is determined so that an undesirable bleaching of a given color-forming component is prevented.
(54) With the order layout as proposed by the present invention, a chosen color is easily obtained because during bleaching of a selected color-forming component, a bleaching interference of the others color-forming components is minimized. Indeed, with the present invention, one wavelength can bleach one color-forming component extending by this way the attainable color space. With the order layouts as proposed by the present invention, the color gamut is improved.
(55) A first order layout is determined according to the absorption coefficients of the bleachable color-forming components of each layer at the defined laser wavelengths. Each layer of the multilayer assembly 20 acts as a filter for a specific wavelength. Said filter is configured to selectively transmit predefined wavelengths and block or attenuate other wavelengths. The final optimized order layout is determined according to the relative effective laser reactivity of the bleachable color-forming component of each layer. Determination of the effective laser reactivity of the bleachable color-forming components leads to changing the first order layout in the aim to protect bleachable color-forming components with the highest effective laser reactivity.
(56) In the final order layout, the color-forming component of each color-forming layer is selected to block or attenuate the laser light at the wavelengths according to their absorption coefficients while protecting color-forming components with the highest effective laser reactivity from “untargeted” bleaching. The effective laser reactivity of a color-forming component is an empirical characteristic of the pigment-laser pair within the system in question, accounting of the entire range of the laser-induced physico-chemical processes resulting in color component discoloration.
(57) The final layout is determined so that, the first wavelength blocked is the one able to bleach at least substantially a majority of the color-forming components of the layers of the multilayer assembly 20. The color-forming component of the upper layer of the multilayer assembly 20 is selected with the purpose of screening off or reducing the light intensity of the first wavelength in the aim to prevent from bleaching the color-forming components of the underneath layers. The selection of the color-forming component is therefore determined layer by layer successively in the aim to block or attenuate laser light at applied wavelengths thus preventing them from bleaching the color components with the highest effective laser reactivity. The color component with the highest effective laser reactivity is the color component having the lower energy threshold to be bleached.
(58) The present invention with the multilayer assembly allows to expand the achievable color gamut, in which color images are generated, as shown in
(59) As illustrated in
(60) For bleaching the first color-forming component 31, there is a first laser condition, for example a first specific laser wavelength 37; for bleaching the second color-forming component there is a second laser condition, for example a second specific laser wavelength 36, and for bleaching the third color-forming component there is a third laser condition, for example a third specific laser wavelength 38. Those specific laser conditions or laser wavelengths used for bleaching the various components are respectively different from each other.
(61) The color-forming components (one or more) are selected for each layer according to their absorption properties and their effective laser reactivity.
(62) The color-forming components of the layers underneath the first layer can absorb in the range where the first color-forming component 31 absorbs,—even if it could be considerably less. To avoid this unwanted exposure the color component of the first color-forming component 31 is selected to act as a filter of the first wavelength 37 in the aim to block it or attenuate it into bleaching the color-forming components located underneath. The first color-forming component 31 acting as a filter for the first wavelength 37 allows to minimize the “side-effect” bleaching of the underneath color-forming components while keeping the “targeted” bleaching as complete as possible.
(63) The color-forming components of the layers underneath the second layer can absorb in the range where the second color-forming component 33 absorbs,—even if it could be considerably less. To avoid this unwanted exposure the color component of the second color-forming component 33 is selected to act as a filter of the second wavelength 36 in the aim to block it or attenuate it into bleaching the underneath color-forming components.
(64) The third color-forming component 35 is selected as the one with the highest effective laser reactivity towards the “improper” lasers. The present invention allows to determine the best compromise between «bleaching» and «protecting», so that the bleaching is most complete and at the same time most selective—in order to expand the attainable color gamut/the range of attainable colors.
(65) The predefined order of arranging each color-forming component into the multilayer assembly 20 located over the body 21 allows that under the respective specific laser conditions for a color component, for example the specific laser wavelength, only that one color component can be bleached and in that procedure the other color components cannot be bleached or their bleaching is significantly minimized. In that way it is possible for only one respective color component to be specifically bleached in the laser treatment, while the others are left unaltered.
(66) In an embodiment of the present invention, the first color-forming component 31 of the first color-forming layer 30 is selected so that wavelength in the blue range for example under 470 nm is effectively blocked or attenuated by the pigments, operating by this way as optical low-pass filter, and consequently widen the color gamut, improving then the range of possible output colors.
(67) Herein after is described an example of implementation of the present invention during a process production of a full-color image of personalized information in a laser-induced process. In order to be able to operate with few color component components but to be able to produce as many colors as possible and preferably all colors, the preferred color-forming components correspond to the three primary colors, such as a cyan pigment, a magenta color component and a yellow pigment. All colors can be produced with these three primary colors using the subtractive color scheme by targeted bleaching of the selective color-forming component.
(68) In order to bleach the yellow pigment, blue laser light is used for that purpose. In order to bleach the magenta pigment, green laser light is used for that purpose. In order to bleach the cyan pigment, red laser light is used for that purpose. A given minimum intensity is required for the bleaching operation.
(69) According to the absorption coefficient of each color-forming component of each layer and also their effective laser reactivity, the first color-forming component 31 comprises yellow color component acting like a filter of the blue laser light. The yellow color component of the first layer 30 of the multilayer assembly 20 blocks or attenuates the blue light reducing considerably its bleaching impact on the other color-forming components of the second and the third layers. The green laser light and the red laser light are transmitted without attenuation through the first layer 30 containing the yellow pigment.
(70) The second color-forming component 33 comprises the cyan color component acting like a filter of the said red laser. The second layer comprises the cyan pigment. The cyan color component of the second layer 32 blocks or attenuates the red laser and the transmitted portion of the blue laser light reducing considerably their bleaching impact on the magenta color component of the third layer 34. The green laser light is transmitted without attenuation through the second layer 20 comprising the cyan pigment.
(71) During the process for the production of a multicolor image, only the yellow color component is bleached by the blue laser irradiation. The red laser light, irradiating the body 21 of the security document, is transmitted without attenuation through the yellow-first layer 30 and bleaches only the cyan color component of the second layer 32. The green laser, irradiating the body 21 of the security document 10, is practically transmitted without attenuation through the yellow- and the cyan-first and second layers to bleach the magenta color component inside the third layer 34.
(72) The multicolor image is accordingly formed by the combination of the residual (unbleached) color components of the first, second and third layers after the laser treatment.
(73) In an embodiment, the laser treatment can be carried out with the aid of one or more laser apparatuses, which irradiate laser light of a single wavelength that corresponds to the wavelength value chosen on the basis of the desired color of the mark.
(74) In another embodiment, the laser treatment is carried out with the aid of a laser apparatus with an adjustable wavelength. With such an apparatus the wavelength required for the color chosen for the mark can easily be set. It is then also possible to obtain a mark containing more than one color with the aid of one apparatus.
(75) In an embodiment, the bleaching operation of each specific wavelength can be done simultaneously or sequentially.
(76) Even though a wider color gamut has been reached, it has been observed that the quality perception of the resulting multicolor image resulting from the laser treatment is not as good as expected. It appears that defining a specific order based on optimized laser selectivity for each color-forming component of each layer of the multilayer assembly 20, isn't sufficient for a good visual quality perception. The color perception is indeed affected by the reflection or interference from the color of the first layer 30 after the laser treatment.
(77) As the top most layer bears a chromatic color (that is it does not uniformly absorb across the visible region)—which is the case for the embodiment with the upper yellow layer, then the visual perception is impacted by the selective reflection of the daylight from the bulk of the said layer. Thus, the image is perceived as tinted into the color of the upper layer.
(78) When the color-forming component 31 of the upper layer 30 is yellow, a yellowish aspect in the final multicolor image is observed.
(79) To overcome this drawback, in an embodiment, the multilayer assembly 20 comprises a fourth layer 39. The fourth layer 39 is arranged over the first upper layer 30. In an embodiment, the forth layer 39 comprises a color component mixture 40 of at least two color-forming components. The overall observed color of the color component mixture 40 can be a neutral grey. The color component mixture 40 can comprise a mixture of the underneath three color-forming components. The color component mixture 40 can comprise a mixture of at least two different color-forming components.
(80) In an embodiment, the concentration of the color component mixture 40 can be lower compared to the concentration of the color-forming components in the other layers of the multilayer assembly 20.
(81) In an embodiment, the color component concentration of the color component mixture 40 can be selected so that the visual colored tint caused by the chromatic color underneath is minimized. In another embodiment, the color component concentration of the color component mixture 40 can be selected so that its pigments could be (preferably completely) bleached without significantly affecting the bleaching process in the layers underneath.
(82) The coloring effect of this fourth layer is produced as a subtractive color scheme with those three primary colors by specific bleaching of the individual color component of each color-forming component.
(83) After the laser treatment, all three components of the fourth layer 39 have been bleached or have been bleached more or less, according to the respective degree of bleaching. Therefore, depending on a possible colored background layer or also possible further components in the body or in the same layer of the body, the above-mentioned location of the body appears colorless or tinted, and in the limit case it can appear white when the background is white. In an embodiment, this fourth mixed layer 39 allows to reduce considerably the visual yellowish appearance without destroying the benefits of the multilayer assembly 20.
(84) It will be appreciated by those skilled persons that changes could be made to the embodiments described above without departing from the broad inventive concept thereof. It is understood, therefore, that this invention is not limited to the particular embodiments disclosed, but it is intended to cover modifications, variations, combinations and equivalents within the scope of the present invention.