ELECTRODE ASSEMBLY

Abstract

An electrode assembly, in which positive electrodes, separators, and negative electrodes are repeatedly stacked, and a positive electrode tab, through which the positive electrodes are connected to each other, and a negative electrode tab, through which the negative electrodes are connected to each other, are provided, includes a heat transfer layer made of a material having thermal conductivity greater than that of the separator and stacked between the positive electrode and the separator or between the negative electrode and the separator to disperse heat generated at a relatively high temperature point to a relatively low temperature point.

Claims

1. An electrode assembly comprising: positive electrodes, separators, and negative electrodes repeatedly stacked; a positive electrode tab, through which the positive electrodes are connected to each other; a negative electrode tab, through which the negative electrodes are connected to each other; and a heat transfer layer made of a material having a thermal conductivity greater than thermal conductivity of the separator and stacked between the positive electrode and the separator or between the negative electrode and the separator to disperse heat generated at a first temperature point to a second temperature point, the first temperature point being higher than the second temperature point.

2. The electrode assembly of claim 1, wherein the heat transfer layer is made of graphite.

3. The electrode assembly of claim 1, wherein the heat transfer layer has an area less than an area of the separator and is stacked so as not to protrude from the separator.

4. The electrode assembly of claim 3, wherein the negative electrode has an area equal to or greater than an area of the positive electrode, and the area of the heat transfer layer is equal to or greater than the area of the negative electrode.

5. The electrode assembly of claim 1, wherein the heat transfer layer has plurality of punched holes through which ions pass.

6. The electrode assembly of claim 5, wherein the punched holes are disposed to be regularly arranged in the heat transfer layer.

7. The electrode assembly of claim 1, wherein the heat transfer layer is stacked on each of both sides of the separator.

8. The electrode assembly of claim 1, wherein the heat transfer layer is stacked to contact only one side surface of the separator.

9. The electrode assembly of claim 1, wherein at least two or more heat transfer layers are provided, and a first heat transfer layer has a thickness greater than a thickness of a second heat transfer layer.

10. The electrode assembly of claim 1, wherein the separator is provided in a state in which a heat transfer material is applied on a surface of the separator so that the heat transfer material forms the heat transfer layer in the electrode assembly.

11. The electrode assembly of claim 1, wherein the heat transfer layer is provided in the form of a plate stacked between the positive electrode and the separator or between the negative electrode and the separator.

12. The electrode assembly of claim 1, wherein the positive electrode tab and the negative electrode tab are disposed to protrude in directions opposite to each other.

13. A secondary battery in which the electrode assembly of claim 1 is embedded in a pouch.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0024] FIG. 1a is an exploded view of a secondary battery module and a perspective view illustrating an assembled state of the secondary battery module.

[0025] FIG. 1b is a perspective view of a secondary battery mounted in FIG. 1a and a cross-sectional view taken along line F-F.

[0026] FIG. 2 is a cross-sectional view illustrating an inner configuration of the secondary battery according to the present invention.

[0027] FIG. 3 is a plan view illustrating a state in which a heat transfer layer is stacked on one surface of a separator according to a first embodiment of the present invention.

[0028] FIG. 4a is a plan view of a heat transfer layer according to a second embodiment of the present invention.

[0029] FIG. 4b is a plan view of a heat transfer layer according to a third embodiment of the present invention.

[0030] FIG. 4c is a plan view of a heat transfer layer according to a third embodiment of the present invention.

[0031] FIG. 5 is a cross-sectional view illustrating an inner configuration of a secondary battery in which a heat transfer layer is stacked according to a fifth embodiment of the present invention.

[0032] FIG. 6a is a perspective view of a secondary battery in which a heat transfer layer is not provided, i.e., a perspective view illustrating points A to E listed in Table 1 and a cross-sectional view taken along line G-G (displayed with a relatively dark color at a low temperature).

[0033] FIG. 6b is a perspective view of a secondary battery in which a heat transfer layer is additionally stacked, i.e., a perspective view illustrating the points A to E listed in Table 1 and a cross-sectional view taken along line H-H according to the present invention.

MODE FOR CARRYING OUT THE INVENTION

[0034] Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings in such a manner that the technical idea of the present invention may easily be carried out by a person with ordinary skill in the art to which the invention pertains. The present invention may, however, be embodied in different forms and should not be construed as limited to the embodiments set forth herein.

[0035] In order to clearly illustrate the present invention, parts that are not related to the description are omitted, and the same or similar components are denoted by the same reference numerals throughout the specification.

[0036] Also, terms or words used in this specification and claims should not be restrictively interpreted as ordinary meanings or dictionary-based meanings, but should be interpreted as meanings and concepts conforming to the scope of the present invention on the basis of the principle that an inventor can properly define the concept of a term to describe and explain his or her invention in the best ways.

[0037] The present invention relates to an electrode assembly, in which positive electrodes 10, separators 30, and negative electrodes 20 are repeatedly stacked, and a positive electrode tab 11, through which the positive electrodes 10 are connected to each other, and a negative electrode tab 21, through which the negative electrodes 20 are connected to each other, are provided so as to be embedded in a pouch 40.

[0038] An object of the present invention is to prevent performance from being deteriorated due to heat. That is, a main point of the present invention is to improve heat dissipation performance and minimize a thermal deviation when cooling is performed by a cooling means at one side in a state in which a plurality of secondary batteries 100 are stacked.

[0039] Thus, as illustrated in FIG. 2, which illustrates an inner configuration of the secondary battery according to the present invention, the electrode assembly according to the present invention comprises a heat transfer layer 50 made of a material having thermal conductivity greater than that of the separator 30 and stacked between the positive electrode 10 and the separator 30 or between the negative electrode 20 and the separator 30 to disperse heat generated at a relatively high temperature point to a relatively low temperature point. In the present invention, the heat transfer layer 50 contains a material having high thermal conductivity such as graphite and is provided with a plurality of punched holes 51 through which electrons and ions pass.

[0040] Here, the heat transfer layer 50 has an area less than that of the separator 30 so as not to protrude from the electrode assembly. However, the heat transfer layer 50 may have an area equal to or greater than that of the negative electrode 20 so that an entire heat-exchange area of the negative electrode 20 and the positive electrode 10 is maximized in consideration of the fact that the negative electrode 20 is larger than the positive electrode 10 to prevent the lithium from being extracted due to overcharging when lithium gets out of the positive electrode 10 to move to the negative electrode 20. The heat transfer layer 50 may be stacked on each of both side surfaces with the separator therebetween or stacked to contact only one side surface of the separator 30 in one or more separators.

[0041] Also, the punched holes 51 may be disposed to form a constant arrangement in the heat transfer layer 50, i.e., may be variously arranged according to specifications and characteristics of the secondary battery.

[0042] Hereinafter, embodiments according to the present invention will be described with reference to the accompanying drawings.

First Embodiment

[0043] Referring to FIG. 3 which illustrates a state in which a heat transfer layer 50 is stacked on one surface of a separator 30 according to a first embodiment of the present invention, this embodiment is characterized in that the heat transfer layer 50 stacked on the separator 30 is provided with punched holes 51 having the same size are regularly arranged at a constant interval.

[0044] That is, in this embodiment, the punched holes 51 are disposed at a constant interval throughout the heat transfer layer 50 so that ions and charges moving between a negative electrode 20 and a positive electrode 10 uniformly passes therethrough. This may be the most basic arrangement structure of the punched holes 50 and be applied together with an arrangement structure to be described later. That is, a plurality of heat transfer layers 50 are provided in an electrode assembly, but the arrangement structure of the punched holes 51 according to the first embodiment may be applied to the most heat transfer layers.

Second Embodiment

[0045] As illustrated in FIG. 4a, which illustrates a plan view of a heat transfer layer 50 according to a second embodiment of the present invention, the heat transfer layer 50 according to this embodiment may have punched holes 51, which increase in size at a specific position. For example, when a passing rate of ions and charges at a specific position is more important than heat transfer, the punched hole 51 may further increase in size so that the passing rate of the ions and charges further increases.

Third and Fourth Embodiments

[0046] As illustrated in FIGS. 4b and 4c, which illustrate a plan view of a heat transfer layer according to third and fourth embodiments of the present invention, a heat transfer layer 50 according to this embodiment is provided with a punched hole 51 that extends in a longitudinal direction (a left and right direction in the drawings) and/or a width direction (an upward and downward direction in the drawings). As described above, the structure in which the punched hole 51 extends length-wise may further simplify a coating process in a coating method of the heat transfer layer 50 to be described later.

Fifth Embodiment

[0047] As illustrated in FIG. 5, which illustrates an inner configuration of a secondary battery in which a heat transfer layer 50 is stacked according to a fifth embodiment of the present invention, at least two or more heat transfer layers 50 are disposed in an electrode assembly. Here, one heat transfer layer 50 has a thickness greater than that of the other heat transfer layer 50.

[0048] That is, an intermediate position within the electrode assembly may be relatively difficult to dissipate heat rather than the outer side and thus may increase in temperature. Here, the heat transfer layer 50 disposed at the intermediate layer to increase in heat transfer efficiency may have a thickness greater than that of the heat transfer layer 50 disposed at the other layer.

[0049] The heat transfer layer 50 having the above-described configuration may be provided in a state applied on a surface of a separator 30 or in the form of a separate plate.

[0050] That is, a heat transfer material may be applied on the surface of the separator 30, and after the heat transfer material is cured, the heat transfer material may be stacked together with the separator 30 within the electrode assembly to form the heat transfer layer 50.

[0051] Alternatively, the heat transfer layer 50 may be previously manufactured in the form of a plate having a size capable of being stacked between a positive electrode 10 and a separator 30 or between a negative electrode 20 and the separator 30. The previously manufactured heat transfer layer 50 is stacked together when the positive electrode 10, the separator 30, and the negative electrode 10 are stacked.

[0052] The method for providing the heat transfer layer 50 may be selected according to the number of punched holes 51 or an arranged state of the punched holes 51. For example, a method, in which the heat transfer layer 50 disposed at a specific position is formed in a coating manner, and the heat transfer layer 50 disposed at another position is stacked in the form of a plate, may be applied.

[0053] The electrode assembly according to the present invention is embedded in a pouch 40, and a positive electrode tab 11 and a negative electrode tab 21 are disposed in directions opposite to each other, and an end of each of the tabs protrudes from the pouch 40.

[0054] FIG. 6a is a perspective view of a secondary battery in which the heat transfer layer is not provided, i.e., a perspective view illustrating points A to E listed in Table 1 and a cross-sectional view taken along line G-G (displayed with a relatively dark color at a low temperature), and FIG. 6b is a perspective view of a secondary battery in which a heat transfer layer is additionally stacked, i.e., a perspective view illustrating the points A to E listed in Table 1 and a cross-sectional view taken along line H-H according to the present invention (in FIGS. 6a and 6b, although one secondary battery is illustrated, temperature distribution illustrated in the cross-sectional view is shown when secondary batteries are mounted as a secondary battery module as illustrated in FIG. 1a). Table 1 below shows a temperature difference between when the heat transfer layer is not stacked and when the heat transfer layer is stacked at five points illustrated in FIGS. 6a and 6b.

TABLE-US-00001 TABLE 1 Maximum temperature Point A Point B Point C Point D Point E deviation Non-stack of heat 39.5° C. 36.6° C. 39.1° C. 35.1° C. 31.3° C. 8.2° C. transfer layer (FIG. 6a) Stack of heat 33.3° C. 33.0° C. 33.2° C. 32.8° C. 32.5° C. 0.8° C. transfer layer (FIG. 6b) ** Experimental conditions - cell capacity: 78 Ah, current load: 100 A 10 sec pulse, initial status of charge: 50%, initial temperature: 25° C., coolant temperature: 22° C.

[0055] As seen from data in Table 1, when the heat transfer layer 50 is provided in an electrode assembly, it may be confirmed that the temperature deviation decreases in an entire region of the secondary battery. That is, when the heat transfer layer 50 is not provided, if heat is generated, cooling is easily performed in the vicinity of a cooling plate, but heat dissipation is difficult at a point that is relatively far from the cooling plate, resulting in a relatively high temperature. Also, here, the heat dispersion is not achieved to cause the heat deviation. However, when the heat transfer layer 50 is added according to the present invention, it may be confirmed that heat generated at a relatively high temperature point is dispersed to a relatively low temperature point, and thus, a heat exposure area to the outside increases to reduce the overall temperature as well as the temperature deviation.

[0056] Therefore, since the structure according to the present invention reduces the temperature deviation and improves the cooling efficiency, the charging/discharging performance and the reliability of the product may be improved.

[0057] The heat transfer layer 50 may be provided with the plurality of punched holes 51 through which the ions pass so as not to interfere with the ion and electron transfer, and the arrangement of the punched holes may vary according to the specifications of the electrode assembly.

[0058] Since the heat transfer layer 50 is stacked so that the heat transfer layers 50 are stacked on each of both sides with the separator 30 therebetween or stacked to contact only one side surface in one or more separators 30, the above-described configurations may be selected in consideration of the heat dispersion effect and the increase in thickness of the electrode assembly.

[0059] Furthermore, since any one heat transfer layer 50 has a thickness greater than that of the other heat transfer layer 50, the heat dispersion effect at the specific location may be more improved.

[0060] While the embodiments of the present invention have been described with reference to the specific embodiments, it will be apparent to those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention as defined in the following claims.