Rapid fill compressed gas storage tank
11079068 · 2021-08-03
Assignee
Inventors
Cpc classification
F17C2203/0604
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2223/0123
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2223/036
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2260/021
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2265/065
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2221/012
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2205/0305
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2260/025
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2201/058
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2270/0184
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2209/232
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2250/0439
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2201/0109
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2260/023
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2201/056
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C5/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2260/026
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02E60/32
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F17C13/026
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2250/043
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
A method for rapidly filling a compressed gas storage tank with a moderated temperature rise using a Coanda nozzle to inject the feed gas into the tank and using the Coanda nozzle to direct the feed gas along the inner surface of the storage tank; entraining the stored gas with the feed gas that is flowing under the influence of the Coanda effect to flow along the inner surface of the gas storage tank; and transferring heat from the flowing gas to the external walls of the tank. Also, a compressed gas storage tank for rapid filling with a moderated temperature rise comprising: a gas storage tank and a Coanda nozzle capable of directing feed gas that is injected into the gas storage tank along the inner surface of the gas storage tank.
Claims
1. A method for rapidly filling a compressed gas storage tank with a moderated temperature rise, comprising: a. providing a gas storage tank, wherein the gas storage tank has an inner surface, an outer surface, a proximal end, a distal end, and a midpoint between the proximal end and the distal end; b. providing a stored gas, wherein the stored gas is contained inside the gas storage tank; c. providing a feed gas; d. providing a Coanda nozzle to inject the feed gas into the gas storage tank, wherein the Coanda nozzle is effectively connected to the proximal end of the gas storage tank; e. injecting the feed gas into the gas storage tank through the Coanda nozzle; f. using the Coanda nozzle to direct the feed gas along a curved surface of the Coanda nozzle, wherein a Coanda effect causes the feed gas to flow along the inner surface of the gas storage tank; g. providing a gas mixing zone at the proximal end of the gas storage tank that is in fluid communication with the feed gas; h. entraining the stored gas with the feed gas in the gas mixing zone to form a mixed gas using inertia of the feed gas that is flowing under influence of the Coanda effect to direct the mixed gas to flow along the inner surface of the gas storage tank; i. transferring heat from the mixed gas to the gas storage tank; j. providing a phase change material along the inner surface of the gas storage tank; k. transferring heat from the flowing gas to the phase change material; l. providing an inner liner and providing a gap, wherein the inner liner is positioned inside the gas storage tank such that it forms the gap between the inner surface of the gas storage tank and the inner liner, wherein the mixed gas flows through the gap; and, wherein providing the inner liner provides the gap for the mixed gas to flow through that is continuous from the proximal end to at least 15% of a length from the proximal end to the distal end of the gas storage tank.
2. The method of claim 1, wherein providing the inner liner provides the gap for the mixed gas to flow through that is continuous from the proximal end to at least to the midpoint of the gas storage tank.
3. The method of claim 2, wherein providing the inner liner provides the gap for the mixed gas to flow through that is continuous from the proximal end to at least 90% of a distance from the proximal end to the distal end of the gas storage tank.
4. The method of claim 3, wherein the inner liner comprises a phase change material and m. transferring heat from the mixed gas to the inner liner.
5. A compressed gas storage tank for rapid filling with a moderated temperature rise, the gas storage tank comprising: a gas storage tank comprising a pressure vessel, an inner surface, an outer surface, a proximal end, a distal end and a midpoint between the proximal end and the distal end; a Coanda nozzle, wherein the Coanda nozzle is operably connected to the gas storage tank at the proximal end, and wherein the Coanda nozzle comprises a curved surface capable of directing feed gas that is injected into the gas storage tank along the inner surface of the gas storage tank; an inner liner, wherein the inner liner is positioned inside the gas storage tank such that it forms a gap that injected gas can flow through, the gap being located between the inner surface of the gas storage tank and the inner liner; wherein the inner liner comprises an orifice that defines a mixing zone adjacent to the Coanda nozzle, wherein the mixing zone can operably mix feed gas with gas inside the gas storage tank; wherein the inner liner extends from the proximal end of the gas storage tank to at least 15% of a distance from the proximal end to the distal end.
6. The gas storage tank of claim 5, wherein the inner liner extends from the proximal end of the gas storage tank to at least the midpoint of the gas storage tank.
7. The gas storage tank of claim 6, wherein the inner liner extends from the proximal end of the gas storage tank to at least 90% of a distance from the proximal end to the distal end.
8. The gas storage tank of claim 7, wherein the inner liner comprises a phase change material.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE INVENTION
(17) Fuel Cell Electric Vehicles (FCEVs) are now commercially available, but their commercial success will require significant reductions in the cost of hydrogen fueling. Capital and maintenance costs of the hydrogen refueling stations are major contributors to the higher costs of hydrogen for the FCEVs. About 15% of the cost of fueling stations is due to the pre-cooling equipment that chills the hydrogen to −40° C. so that fills can be completed in three minutes, in compliance with the SAE J2601 Fueling Protocol for Light-Duty Gaseous Hydrogen Surface Vehicles. Pre-cooling to these temperatures increases the complexity and cost of the hydrogen dispensers, which account for 14% of station's cost (and constitute the second largest cause of station maintenance issues). The requirement to pre-cool hydrogen gas to −40° C. is driven by the need to offset the temperature rise caused by the heat of compression during fueling, since the polymer liner of conventional 700 bar compressed tanks is limited to a maximum temperature of 85° C. If the −40° C. precooling requirement could be reduced or even eliminated without significantly impacting the performance of the hydrogen storage system the cost of delivered hydrogen could be significantly reduced.
(18) Hence, there is a need for a gas (hydrogen) storage tank that incorporates novel cooling schemes to quickly dissipate/absorb the heat of compression and keep the hydrogen gas temperature well below the hydrogen tank design temperature of 85° C. with minimal impact on the cost, weight, volume, fill time, and well-to-power plant efficiency.
(19) The present invention: 1) incorporates novel cooling schemes with the use of phase change media (PCM) to quickly absorb the heat of compression, and 2) microstructures in the tank inlet and wall to provide active gas circulation (2-20× the refueling rate) inside the tank during refueling to keep the hydrogen gas temperature at or under temperatures well below the hydrogen tank's design temperature of 85° C. The invention eliminates the need to precool the gas and can use gas at temperatures up to ambient (25° C.), while keeping the refueling times to 3 minutes or less and providing a higher ending state of charge (SOC) or with same SOC a lower end of refueling pressure when using ambient temperature gas during refueling.
(20) The new design for the gas storage tank maximizes the heat transfer area and the heat transfer coefficients to quickly dissipate the heat throughout the refueling process. While there are passive tank designs that use phase change media to absorb the heat of compression in prior art, in these designs the gas temperature still exceeds the 85° C. limit during re-fueling, which both exceeds the maximum use temperature and reduces the capacity of the tank by 12% or more. The main drawback of these designs is not that they lack the ability to store the heat of compression, but that the heat transfer area and the heat transfer coefficients are not large enough to pull the heat out of the gas and into the phase change media during the three minute charge (refueling) time. The present invention not only maximizes the heat transfer area and the heat transfer coefficients to transfer the heat to the PCM, it also employs active cooling of the hot gas through the use of a Coanda nozzle at the inlet end of the gas storage tank as shown in 2A and
(21) The present invention allows the inlet hydrogen temperature to be increased to 0° C. from the −40° C. currently used with a 0.25″ increase in tank diameter (from the current 10.57″) and 5% increase in tank volume. The inlet hydrogen temperature can be further increased to 25° C. with 0.5″ increase in tank diameter and 9% increase tank in volume. The present invention has minimal impact on the weight, and volume of the gas storage tank while keeping the same fill time. Most importantly, we can provide a much higher (>15%) well-to-power plant efficiency for the hydrogen refilled due to elimination of the pre-cooling need.
(22) The present invention teaches the use of Coanda effect to provide active gas recirculation in a gas storage tank during refilling from another gas storage tank to increase the heat transfer from the bulk gas to the tank wall and/or a phase change media, which can be housed anywhere in the tank including on the outside of the exterior wall. The present invention is a compressed gas storage tank for rapid filling with a modulated temperature rise, the gas storage tank uses a Coanda nozzle, wherein the Coanda nozzle comprises a curved surface capable of directing feed gas that is injected into the gas storage tank along the inner surface of the gas storage tank; wherein the Coanda nozzle is operably connected to the gas storage tank at the feed (proximal) end to direct the feed gas along a curved surface of the Coanda nozzle, wherein a Coanda effect causes the feed gas to flow along the inner surface of the storage tank; providing a gas mixing zone at the proximal end of the gas storage tank in fluid communication with the feed gas; entraining the stored gas with the feed gas in the gas mixing zone to form a mixed gas using the feed gas that is flowing under the influence of the Coanda effect to direct the mixed gas to flow along the inner surface of the gas storage tank; and transferring heat from the flowing gas to the external walls of the tank.
(23) The ratio of the sum of the induced gas and incoming gas mass flow rate divided by the mass flow rate of the incoming or motive gas is defined as the “Coanda ratio”. The gas storage tank contains a phase change material anywhere in the inner surface, outer surface or the bulk of the tank. The gas storage tank further comprises an inner liner, wherein the inner liner is positioned inside the gas storage tank such that it forms a gap that gas can flow through, the gap being located between the inner surface of the tank and the inner liner. The inner liner comprises an orifice that defines a mixing zone at the Coanda nozzle, wherein the mixing zone can operably mix feed gas with storage (bulk) gas. The inner liner extends from the proximal end of the gas storage tank to at least 15% of the distance from the proximal end to the distal end. This allows the Coanda effect to produce an induced flow in the liner gap (microchannel) that is 2 to 20 times the feed gas flow rate (referred to as Coanda ratio) allowing the thorough mixing of the stored gas, which is at a higher temperature with the cold feed gas. The high recirculation rate of the stored gas increases the heat transfer coefficient and transfers the heat from the bulk of the gas to both the tank wall direction and the inner liner allowing us to absorb that heat into phase change material which is housed on one or both of these directions. Another alternative is to leave the PCM material on the exterior of the gas storage tank there by allowing the heat to be moved through the tank layers and finally stored in the phase change material. Another alternative is to house the phase change material in the bulk of the tank.
(24) The state of charge (SOC) for the gas tank is defined as the ratio of hydrogen density at a given temperature and pressure to that at 15° C. and the nominal working pressure (NWP), NWP is 700 bar for the gas tanks used in hydrogen fuel cell vehicles.
(25) In the claims, the term “flow” should be understood to mean a moving gas, such as gas transporting from one location to another.
(26) In the claims, the term “gap” should be understood to mean a space for the gas to occupy, which is between two solid materials, such as the tank inner surface and the insert.
(27) In the claims, the term “phase change material” (PCM) means a substance which releases/absorbs sufficient energy at phase transition to provide useful heat/cooling. Non-limiting examples include sodium acetate (such as ClimSem C58), paraffin waxes, solid-solid PCM solutions, clathrates, eutectics, salt hydrates, organic materials, and high temperature salts, and the like. Examples of PCMs and theft respective transition temperatures are: Paraffin 20-Carbons/36.7° C. (98.1° F.); Caprylone/40° C. (104° F.); Paraffin 21-Carbons/40.2° C. (104.4° F.); 4-Heptadacanone/41° C. (106° F.); Paraffin 22-Carbons/44° C. (111° F.); Lauric acid/44.2° C. (111.6° F.); 2-Heptadecanone/48° C. (118° F.); Barium hydroxide hydrate/48° C. (118° F.); Paraffin 25-Carbons/49.4° C. (120.9° F.); Camphene/50° C. (122° F.); Paraffin 24-Carbons/50.6° C. (123.1° F.); 9-Heptadecanone/51° C. (124° F.); Diphenyl amine/52.9° C. (127.2° F.); p-Dichlorobenzene/53.1° C. (127.6° F.); Chloroacetic acid/56° C. (133° F.); Tristearin/56° C. (133° F.); Paraffin 26-Carbons/56.3° C. (133.3° F.); Nitro naphthalene/56.7° C. (134.1° F.); Myristic acid/58° C. (136° F.); Paraffin 27-Carbons/58.8° C. (137.8° F.); Sodium acetate hydrate/58° C. (136° F.); Heptaudecanoic acid/60.6° C. (141.1° F.); Paraffin 28-Carbons/61.6° C. (142.9° F.); Bees wax/61.8° C. (143.2° F.); Paraffin 29-Carbons/63.4° C. (146.1° F.); p-Bromophenol/63.5° C. (146.3° F.); Paraffin 30-Carbons/65.4° C. (149.7° F.); Azobenzene/67.1° C. (152.8° F.); and Paraffin 31-Carbons/68° C. (154° F.)
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(31) Additional variations are shown in
(32) EXAMPLE 1: Computational Fluid Dynamic (CFD) simulations of the Coanda effect was carried out with Solidworks Flowsim® module for a sub-scale tank fitted with a Coanda nozzle at a tank pressure of 200 bar during refilling process with an inlet flow of hydrogen of 0.0033 kg/sec. The gas velocity and the pressure contours in the proximal end of the storage tank where the Coanda nozzle directs the inlet gas flow were simulated. The Coanda effect causes the inlet gas flow to stay along the curved surface and creates a negative pressure in the inlet end of the gas tank which results in the the stored gas getting mixed with inlet flow and pulled along the curved surface of the Coanda nozzle/tank. This mixed flow then gets directed through the gap between the tank wall and the inner liner. In these simulations several key parameters in the Coanda nozzle design were changed and found to influence the Coanda ratio: 1) the Coanda curve radius (dimension A in
(33) EXAMPLE 2: CFD simulations of the Coanda nozzle in Fluent ANSYS® with a throat width (gap width) of 0.0762 mm (0.003 inches) and a hydrogen flow rate of 0.022 kg/s into a 120 L tank. The steady state simulations were repeated for several time “snapshots” with tank pressure and temperature initialized to those that would be seen during the actual fill. Two inlet gas temperatures of 0 and 27° C. were also considered. The results (shown in
(34) EXAMPLE 3: CFD simulations of the tank refill process were carried out with the inlet gas at 0° C. for three different scenarios: 1) adiabatic fill—a regular gas storage tank with no Coanda nozzle present to direct the flow or a phase change material (PCM) to absorb the heat of compression; 2) coanda flow with PCM layer next to wall—tank equipped with a Coanda nozzle to direct the inlet flow and a PCM layer next to tank wall (liner) to absorb the heat of compression; wherein coanda flow (sum of the inlet gas flow and the induced gas flow) is in the gap between the PCM and the bulk gas; and, 3) Coanda flow with PCM layer next to bulk gas—tank equipped with a Coanda nozzle to direct the inlet flow and a PCM layer between bulk gas and the Coanda flow; wherein Coanda flow is in the gap between the tank wall (liner) and the PCM
(35) PCM selected for these simulations was ClimSel C58, which has a melting point of 58° C. ClimSel C58 is a PCM manufactured by Climator Sweeden AB and is mainly composed of sodium acetate, water and additives. The CFD simulations showed that for both the Coanda flow cases the gas temperature was maintained well below the liner temperature limit of 85° C. while for the adiabatic fill case the gas temperature increases to 97° C. When having the Coanda flow between the tank liner (wall) and the PCM layer; where in PCM layer is both next to bulk gas and the coanda flow, provided better heat transfer and kept the gas temperature to less than 61° C. while the case (scenario) where the coanda flow is between the bulk gas and the PCM layer; wherein the PCM layer is next to tank liner (wall), provided lower heat transfer and the gas temperature reached 72° C. In both the coanda flow cases the tank liner (wall) temperature was maintained at 58° C. compared to 93° C. for the adiabatic fill. These simulations were carried out to 100% SOC so all the cases resulted in the same SOC, however the final pressures were different for each of the cases (scenarios). In addition to being able to use higher inlet gas temperatures of 0 to 25° C. The final fill pressure was lower for the coanda flow cases demonstrating the energy savings due to lower compression energy needs.
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(38) The final gas and liner temperatures and the fill pressures for the three cases) 9 scenarios) are summarized in the table below. The final gas temperature for the two coanda flow cases with phase change material are between 25 to 40% lower while liner temperature is 40% lower when using an inlet hydrogen gas available at 0° C. for the refill.
(39) TABLE-US-00001 Gas Liner/PCM Gas Temperature Temperature at Pressure at 100% 100% SOC at 100% Case SOC (° C.) (° C.) SOC (bar) 1 97 94 875 2 72 58 834 3 61 58 807
(40) EXAMPLE 4: In this example the impact of Coanda ratio on the gas temperature is shown when using an inlet gas temperature of 25° C. Simulations were carried out with different Coanda flow ratios from 0 to 15. The results in
(41) Although the present invention has been described in considerable detail with reference to certain preferred versions thereof, other versions are possible. For example other gasses could be used instead of hydrogen, such as natural gas, etc. Therefore, the spirit and scope of the appended claims should not be limited to the description of the preferred versions contained herein, except where required by 35 U.S.C. § 112 ¶6 or 35 U.S.C. § 112 (f).
(42) All the features in this specification (including any accompanying claims, abstract, and drawings) may be replaced by alternative features serving the same, equivalent or similar purpose, unless expressly stated otherwise. Thus, unless expressly stated otherwise, each feature disclosed in one example only of a generic series of equivalent of similar features. Any element in a claim that does not explicitly state “means for” performing a specified function, or “step for” performing a specific function, is not to be interpreted as a “means” or “step” clause as specified in 35 U.S.C. § 112 ¶6 or 35 U.S.C. § 112 (f). Any element in a claim that does explicitly state “means for” performing a specified function, or “step for” performing a specific function, is to be interpreted as a “means” or “step” clause as specified in 35 U.S.C. § 112 ¶6 or 35 U.S.C. § 112 (f).